ETS Economic Oxygen Cleaner (EN)

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ETS Economic Oxygen Cleaner

Safety Data Sheet


according to Regulation (EU) 2015/830
Date of issue: 8/24/2017 Version: 1.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier
Product form : Mixture
Product name : ETS Economic Oxygen Cleaner
Product code : 2184-O

1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Use of the substance/mixture : Professional cleaning agents for oxygen equipment - oil degreaser

1.2.2. Uses advised against


Restrictions on use : No data available

1.3. Details of the supplier of the safety data sheet


ETS Ekolojik Teknolojik Temizlik Çözümleri Ltd. Şti.
Ordu Sk. No 15A Soğanlık - Kartal / Istanbul / Turkey
T +90 (0) 216 606 06 66 - F +90 (0) 216 606 21 41 {
HYPERLINK mailto:info@etsturkiye.com } {HYPERLINK
htp:/www.etsturkiye.com}

1.4. Emergency telephone number


Emergency number : +90 (0) 216 606 06 66

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Serious eye damage/eye irritation, Category 2 H319
Full text of H statements : see section 16

Adverse physicochemical, human health and environmental effects


Causes serious eye irritation.

2.2. Label elements


Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :

GHS07
Signal word (CLP) : Warning
Hazard statements (CLP) : H319 - Causes serious eye irritation
Precautionary statements (CLP) : P264 - Wash hands, forearms and face thoroughly after handling
P280 - Wear eye protection, protective gloves
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing
P337+P313 - If eye irritation persists: Get medical advice/attention
2.3. Other hazards
No additional information available

SECTION 3: Composition/information on ingredients


3.1. Substances
Not applicable

3.2. Mixtures
Name Product identifier % Classification (CLP)
Detergents, C9-11 ethoxylated (CAS-No.) 68439-46-3 <5 Acute Tox. 4 (Oral), H302
Eye Dam. 1, H318
2-(2-butoxyethoxy)ethanol (CAS-No.) 112-34-5 <3 Eye Irrit. 2, H319
(EC-No.) 203-961-6
(EC Index-No.) 603-096-00-8

8/24/2017 EN (English) SDS Ref.: 2184-O 1/6


ETS Economic Oxygen Cleaner
Safety Data Sheet
according to Regulation (EU) 2015/830
Date of issue: 8/24/2017 Version: 1.0

Name Product identifier % Classification (CLP)


Sodium hydroxide (CAS-No.) 1310-73-2 < 0.5 Skin Corr. 1A, H314
(EC-No.) 215-185-5
(EC Index-No.) 011-002-00-6

Full text of H-statements: see section 16

SECTION 4: First aid measures


4.1. Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing.
First-aid measures after skin contact : Wash skin with plenty of water.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Call a poison center or a doctor if you feel unwell.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: Firefighting measures


5.1. Extinguishing media
Suitable extinguishing media : The product is not flammable. Use extinguishing media appropriate for surrounding fire.
Unsuitable extinguishing media : None known.

5.2. Special hazards arising from the substance or mixture


Hazardous decomposition products in case of : Toxic fumes may be released.
fire;

5.3. Advice for firefighters


Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Protective equipment : Wear recommended personal protective equipment. Safety glasses, Gloves.
Emergency procedures : Ventilate spillage area. Avoid contact with skin and eyes.

6.1.2. For emergency responders


Protective equipment : Do not attempt to take action without suitable protective equipment. For further information
refer to section 8: "Exposure controls/personal protection".
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Take up liquid spill into absorbent material.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
For further information refer to section 13.

SECTION 7: Handling and storage


7.1. Precautions for safe handling
Precautions for safe handling : Ensure good ventilation of the work station. Avoid contact with skin and eyes. Wear personal
protective equipment.
Hygiene measures : Do not eat, drink or smoke when using this product. Always wash hands after handling the
product.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Keep container tightly closed and dry. Keep in a cool, well-ventilated place away from
incompatible materials.
7.3. Specific end use(s)
No additional information available

8/24/2017 EN (English) SDS Ref.: 2184-O {


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ETS Economic Oxygen Cleaner
Safety Data Sheet
according to Regulation (EU) 2015/830
Date of issue: 8/24/2017 Version: 1.0

SECTION 8: Exposure controls/personal protection


8.1. Control parameters
Sodium hydroxide (1310-73-2)
United Kingdom WEL STEL (mg/m³) 2 mg/m³
2-(2-butoxyethoxy)ethanol (112-34-5)
EU IOELV TWA (mg/m³) 67.5 mg/m³
EU IOELV TWA (ppm) 10 ppm
EU IOELV STEL (mg/m³) 101.2 mg/m³
EU IOELV STEL (ppm) 15 ppm

8.2. Exposure controls


Appropriate engineering controls:
Ensure good ventilation of the work station. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any
potential exposure.

Hand protection:
Standard EN 374 - Protective gloves against chemicals. Choosing the proper glove is a decision that depends not only on the type of material, but
also on other quality features, which differ for each manufacturer. Wear protective gloves.

Eye protection:
Safety glasses with side shields. Standard EN 166 - Personal eye-protection.

Skin and body protection:


Wear suitable protective clothing
Respiratory protection:
In case of insufficient ventilation, wear suitable respiratory equipment

Environmental exposure controls:


Avoid release to the environment.

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties
Physical state : Liquid
Colour : Transparent
Odour : Characteristics
Odour threshold : No data available
pH : 11 - 13
Relative evaporation rate (butylacetate=1) : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Not applicable
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available
Relative density : No data available
Density : 1 g/cm³ (20 °C)
Solubility : Completely soluble.
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available

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ETS Economic Oxygen Cleaner
Safety Data Sheet
according to Regulation (EU) 2015/830
Date of issue: 8/24/2017 Version: 1.0

9.2. Other information


No additional information available

SECTION 10: Stability and reactivity


10.1. Reactivity
The product is non-reactive under normal conditions of use, storage and transport.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4. Conditions to avoid
None under recommended storage and handling conditions (see section 7).
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be produced.

SECTION 11: Toxicological information


11.1. Information on toxicological effects
Acute toxicity : Not classified
Sodium hydroxide (1310-73-2)
LD50 oral rat > 2000 mg/kg
2-(2-butoxyethoxy)ethanol (112-34-5)
LD50 oral rat 5660 mg/kg
LD50 dermal rabbit 2700 - 4120 mg/kg
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified

SECTION 12: Ecological information


12.1. Toxicity
Ecology - general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse
effects in the environment.
Acute aquatic toxicity : Not classified
Chronic aquatic toxicity : Not classified

Sodium hydroxide (1310-73-2)


EC50 daphnia 40.4 mg/l (Ceriodaphnia spec)
2-(2-butoxyethoxy)ethanol (112-34-5)
LC50 fish 1300 mg/l 96h (Lepomis macrochirus)
EC50 daphnia > 100 mg/l 48h (Daphnia magna)
EC50 algae 1170 mg/l 16h (Pseudomonus putida)

12.2. Persistence and degradability


No additional information available

12.3. Bioaccumulative potential


No additional information available

12.4. Mobility in soil


No additional information available

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ETS Economic Oxygen Cleaner
Safety Data Sheet
according to Regulation (EU) 2015/830
Date of issue: 8/24/2017 Version: 1.0

12.5. Results of PBT and vPvB assessment


No additional information available

12.6. Other adverse effects


No additional information available

SECTION 13: Disposal considerations


13.1. Waste treatment methods
Waste treatment methods : Dispose in a safe manner in accordance with local/national regulations.

SECTION 14: Transport information


In accordance with ADR / RID / IMDG / IATA / ADN
ADR IMDG IATA ADN RID
14.1. UN number
Not applicable Not applicable Not applicable Not applicable Not applicable
14.2. UN proper shipping name
Not applicable Not applicable Not applicable Not applicable Not applicable
14.3. Transport hazard class(es)
Not applicable Not applicable Not applicable Not applicable Not applicable
14.4. Packing group
Not applicable Not applicable Not applicable Not applicable Not applicable
14.5. Environmental hazards
Not applicable Not applicable Not applicable Not applicable Not applicable

14.6. Special precautions for user

- Overland transport
Not applicable

- Transport by sea
Not applicable

- Air transport
Not applicable

- Inland waterway transport


Not applicable

- Rail transport
Not applicable
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable

SECTION 15: Regulatory information


15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations

Contains no REACH substances with Annex XVII restrictions


Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances

15.1.2. National regulations

Germany
VwVwS Annex reference : Water hazard class (WGK) 1, low hazard to waters (Classification according to VwVwS, Annex
4)
12th Ordinance Implementing the Federal : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Immission Control Act - 12.BImSchV

Netherlands
SZW-lijst van kankerverwekkende stoffen : None of the components are listed
SZW-lijst van mutagene stoffen : None of the components are listed
NIET-limitatieve lijst van voor de voortplanting : None of the components are listed
giftige stoffen – Borstvoeding

8/24/2017 EN (English) SDS Ref.: 2184-O {


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ETS Economic Oxygen Cleaner
Safety Data Sheet
according to Regulation (EU) 2015/830
Date of issue: 8/24/2017 Version: 1.0

NIET-limitatieve lijst van voor de voortplanting : None of the components are listed
giftige stoffen – Vruchtbaarheid
NIET-limitatieve lijst van voor de voortplanting : None of the components are listed
giftige stoffen – Ontwikkeling

15.2. Chemical safety assessment


No chemical safety assessment has been carried out

SECTION 16: Other information


Abbreviations and acronyms:
ADN European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
ADR European Agreement concerning the International Carriage of Dangerous Goods by Road
CLP Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
EC50 Median effective concentration
IATA International Air Transport Association
IMDG International Maritime Dangerous Goods
LC50 Median lethal concentration
LD50 Median lethal dose
OECD Organisation for Economic Co-operation and Development
PBT Persistent Bioaccumulative Toxic
REACH Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006
RID Regulations concerning the International Carriage of Dangerous Goods by Rail
SDS Safety Data Sheet
vPvB Very Persistent and Very Bioaccumulative

Full text of H- and EUH-statements:


Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Eye Dam. 1 Serious eye damage/eye irritation, Category 1
Eye Irrit. 2 Serious eye damage/eye irritation, Category 2
Skin Corr. 1A Skin corrosion/irritation, Category 1A
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H319 Causes serious eye irritation

SDS EU (REACH Annex II)

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental
requirements only. It should not therefore be construed as guaranteeing any specific property of the product

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