I PUC ANNUAL EXAMINATION FEBRUARY/MARCH-2014

SUBJECT: CHEMISTRY (33)

Time: 3.15 Hours Maximum Marks: 70

Instructions:
a. The question paper has FOUR parts A,B,C and D. All parts are
compulsory.
b. Write balanced chemical equations and draw labeled diagram wherever
required.
c. Use log tables and simple calculators if necessary.
d. (use of Scientific calculator is not allowed)

PART-A
I. Answer ALL the following questions: 𝟏𝟎 × 𝟏 = 𝟏𝟎
1. Write S. I unit of temperature.
2. What is the value of gas constant (R) in S.I. Unit.
3. Define the pH of a solution.
4. Name a metal belongs to d-block elements.
5. Define oxidizing agent.
6. Write the general electronic configuration of alkali metals
7. Mention one use of chromatography.
8. What are Silicones?
9. Mention the principles of chromatography.
10. Write the Newman Projection of Eclipsed form of ethane.

PART-B
II. Answer any FIVE of the following questions: 𝟓 × 𝟐 = 𝟏𝟎
(Each question carries two marks)
11. Calculate the mass of 220 𝐶𝑚3 of Oxygen at S.T.P.
12. State and explain Boyle’s law
13. Explain Polar and non-polar covalent bonds.
14. Give any two biological importance of Magnesium and Calcium.
15. What is the action of alkali on aluminum?
16. How is alkenes are obtained from alkyl halides?
17. How do you convert Ethanal from Ethyne?
18. How Acid rain is caused in the nature?
 PART-C
III. Answer any Five of the following questions: 𝟓 × 𝟑 = 𝟏𝟓
(Each question carries Three marks)
19. Define ionization enthalpy. How does varies in periodic table.
20. Explain the SP2 hybridisation with an example.
21. Draw the Lewis dot’s structure for
a) N2 b)CO2 c)O2
22. Distinguish between bonding and antibonding molecular orbital.
23. (a)Give two uses of heavy water (D2O)
(b) Write the structure of hydrogen peroxide (H2O2)
24. Write any three rules for assigning oxidation number to atoms in
ions and in molecules.
25. Give any three properties of Lithium resembles with magnesium.
26. Give any three anomalous properties of Boron.

PART-D (IV and V)

IV. Answer any FIVE of the following questions: 𝟓 × 𝟓 = 𝟐𝟓
(Each question carries five marks)
27. (a) Explain the significance of the quantum numbers.
(b) What is the shape of p-orbital
28. (a) Describe Rutherford experiment. What are its conclusions?
(b) Write de-broglie’s equation.
29. (a) A hydro carbon contains 75% of carbon. What is it’s empirical
formula?
(b) define (i) Molarity (ii) Homogeneous mixture.
30. (a) Write any three Postulates of Kinetic theory of gases.
(b) Define Dipole-dipole forces.
31. (a) Calculate the work done when 3 moles of an ideal gas expand
isothermally and reversibly form 15 litre to 30 litre at 270 C.
(b) Define enthalpy of a reaction.
32. (a) state Hess’s law of heat summation. Illustrate with an example.
(b) Define entropy. What is the S.I. Unit of entropy.
33. (a) Explain Solid-liquid equilibrium with an example.
(b) state the equilibrium law.
34. (a) Discuss the effect of temperature on equilibrium 2NO2⇌2N2O4;
∆𝐻 = −𝑣𝑒 with the help of Lechatelier’s Principle.
(b) Explain common ion effect with an example.

V. Answer any TWO of the following questions: 𝟐 × 𝟓 = 𝟏𝟎

35. (a) Give the IUPAC names of the following
CH3
|
(i) CH3−𝐶𝐻 −CH3 (ii) CH3CHO (iii) CH3-CH-COOH
|
Cl
b) What is an Electrophile? Give an example.
36. a) how do you estimate nitrogen in the organic compound using
Kjeldhal’s method? Write its principle.
b)Explain position isomer with an example.
37. a) explain the mechanism of nitration of benzene.
b) How is ethene convert to ethane 1, 2 diol.

*************
 I PUC ANNUAL EXAMINATION FEBRUARY/MARCH-2015
SUBJECT: CHEMISTRY
Time: 3.15 Hours Maximum Marks: 70
Instructions:
a) The question paper has FOUR parts A,B,C and D. All parts are
compulsory.
b) Write balanced chemical equations and draw labeled diagram wherever
required.
c) Use log tables and simple calculators if necessary.
(use of Scientific calculator is not allowed)

PART-A
I. Answer ALL the following questions: 𝟏𝟎 × 𝟏 = 𝟏𝟎
(Each question carries 1 mark)
1. Define molality.
2. Write vander Waals equation for ‘n’ moles of a real gas.
3. What is common ion effect?
4. State Modern periodic table?
5. What happens to oxidation number of an element during reduction.
6. Identify the products A and B in the equation. 2𝑁𝑎 + 2𝐻2 𝑂 → 𝐴 + 𝐵.
7. Mention the state of hybridization of carbon in graphite.
8. What is dry ice?
9. Write the IUPAC name of 𝐶𝐻3 − 𝐶𝐻 − 𝐶𝐻2 − 𝐶𝐻2 𝑂𝐻
|
𝐶𝐻3
10. Give the general equation for Wurtz reaction.

PART-B
II. Answer any FIVE of the following questions: 𝟓 × 𝟐 = 𝟏𝟎
(Each question carries Two marks)
11. Calculate the number of atoms present in 40g of Sulphur.
(Given: Atomic mass of S= 32)
12. State Gaylussac’s law and give its mathematical form.
13. Write the Lewis dot structure of oxygen atom and chlorine molecule.
 14. Mention the reasons for the anomalous behavior of Lithium.
15. What is the repeating unit in organo silicon polymer? Name the
starting material used in the manufacture of organo silicon polymer.
16. State and explain the Markownikov rule with a suitable example.
17. Explain the Friedel Craft alkylation of Benzene with the equation.
18. What is BOD? Name the compound formed when CO combines with
blood.

PART-C
III. Answer any FIVE of the following questions: 𝟓 × 𝟑 = 𝟏𝟓
(Each question carries Three marks)
19. What happens to ionization energy along the period and down the
group in the periodic table? Why?

20. a) Define dipole moment.

b) Mention the shape, bond angle and number of lone pair of electrons
of Ammonia molecule.

21. Explain the SP3 hybridization by taking Methane as example.

22. a) What is bond order?

b) Draw the molecular energy level diagram for hydrogen molecule and
calculate its bond order.

23. Balance the following redox reaction by oxidation number method in

acid medium .

𝐶𝑟2 𝑂32− + 𝑆𝑂32− → 𝐶𝑟 3+ + 𝑆𝑂42− + 𝐻2 𝑂 (Acid medium)

24. a) What are hydrides? Mention its types.

b) Explain temporary hardness of water.

25. Explain the manufacture of sodium carbonate by solvay process.

26. a) Among Boron and Aluminum, Boron can not have covalency more
than 4 but Aluminum can have. Give reason.
b) Explain the reaction of Diborane with water.
 PART-D (IV and V)
IV. Answer any FIVE of the following questions: 𝟓 × 𝟓 = 𝟐𝟓
(Each question carries five marks)
27. (a) (i) What is limiting reagent?
(ii) Convert 390 C to Kelvin temperature.
(b) Write the postulates of Dalton’s atomic theory.
28. (a) What are isotopes? Give an example.
(b) Explain Bohr’s Theory of an atomic model.
29. (a) A yellow light emitted from the lamp has a wavelength (𝜆) of 580
nm. Calculate the frequency (𝑣) of yellow light. (C= 3 × 108 𝑚/𝑠)
(b) (i) State Hund’s rule of maximum multiplicity.
(ii) write the significance of principle quantum number.
30. (a) write any three Postulates of Kinetic theory of gases.
(b) Calculate the temperature of 6.0 moles of a gas occupying 4𝑑𝑚3
at 2 bar pressure (𝑅 = 0.0825 𝑏𝑎𝑟 𝑑𝑚3 𝐾 −1 𝑚𝑜𝑙 −1 ).
31. (a) what is an extensive property? Given an example.
(b) (i) State and explain the first law of thermodynamics.
(ii) Give an example for exothermic reaction.
32. (a) Write Born Haber cycle for the manufacture of 1mole of NaCl
Crystal.
(b) Calculate the enthalpy of Benzene liquid. Given that enthalpy of
formation of Benzene, Carbon dioxide and water are 48.51 kJ,
−393.5𝑘𝐽 and −285.83𝑘𝐽𝑚𝑜𝑙 −1 respectively.
33. (a) Define equilibrium constant. Derive expression for the equilibrium
constant 𝐾𝑐 for a reaction aA + bB cC + dD

(b) Calculate the PH of a solution whose hydrogen ion concentration

(𝐻 + ) is 1.6 × 10−4 𝑚𝑜𝑙𝑑𝑚−3
34. (a) Explain conjugate acid base pair with an example.
(b) Give an example for basic buffer solution.
V. Answer any TWO of the following questions: 𝟐 × 𝟓 = 𝟏𝟎
(Each question carries five marks)
35. (a) (i) Write the bond line formula 𝐶𝐻3 (𝐶𝐻2 )3 𝐶𝐻𝑂.
(ii) Identify the hybridization type of each carbon atom in
𝐶𝐻3 − 𝐶𝐻2 − 𝐶𝐻 = 𝐶𝐻2
(b) (i) Explain chain isomerism with an example.
(𝑖𝑖) What are free radicals?
36. (a) Write any two differences between Inductive effect and
Mesomeric effect.
(b) How do you estimate Carbon and Hydrogen present in the organic
compound by Leibigs method?
37. (a) Explain the mechanism of Chlorinaiton of Methane.
(b) Complete the reactions.

*************
 I PUC ANNUAL EXAMINATION FEBRUARY/MARCH-2016
SUBJECT: CHEMISTRY (34)
Time: 3.15 Hours Maximum Marks: 70

Instructions:
a) The question paper has FOUR parts, A,B,C and D. All parts are compulsory.
b) Write balanced chemical equations and draw labeled diagrams whenever asked.
c) Use log tables and simple calculators if necessary.
(use of Scientific Calculator is not allowed).

PART-A
I. Answer all the questions:
(Answer each question in one word or in one sentence each.) 𝟏𝟎 × 𝟏 = 𝟏𝟎
1. Write the S.I. unit for density.
2. Mention the type of attraction that exists between non polar molecules.
3. What is conjugate acid-base pair?
4. State modern periodic law.
5. Calculate the oxidation number of ‘Mn’ in Mn𝑂4− .
6. Which alkali metal is the strongest reducing agent?
7. Mention the type of hybridization of carbon in diamond.
8. Give the composition of water gas.
9. Give an example for heterocyclic compound.
10. What are alkanes?

PART-B
II. Answer any FIVE questions:
(Each questions carries two marks only) 𝟓 × 𝟐 = 𝟏𝟎
11. Calculate the mass percent of different elements present in 𝑁𝑎2 𝑆𝑂4
12. State Charles’ Law. Give its mathematical form.
13. Write the Lewi’s dot symbol for chlorine and methane.
14. Lithium resembles magnesium in some properties. Mention two such
properties.
15. What is catenation? Among carbon and silicon which has maximum
catenation?
16. Explain Wurtz’s reaction with an example.
17. Give two tests to distinguish between alkane and alkene.
18. How is Ozone layer formed in the stratosphere? Name a chief chemical
that causes its depletion.

PART-C
III. Answer any FIVE questions:
(Each question carries three marks) 𝟓 × 𝟑 = 𝟏𝟓
19. (a) The size of sodium ion is smaller than neutral sodium. Why?
(b) What are representative elements? 2+1
20. Explain 𝑆𝑃3 hybridisation in methane molecule. 3
21. Write the electronic configuration of oxygen molecule. Predict its magnetic
property. 2+1

22. Define hydrogen bond. Mention the types of hydrogen bonding in the
following compounds. (i) Water (ii) Ortho nitrophenol 1+2

23. Balance the Redox reaction using oxidation number method. 3

2− 3+
𝐶𝑟2 𝑂7(𝑎𝑞) + 𝑆𝑂32− → 𝐶𝑟(𝑎𝑞) + 𝑆𝑂42− (in acidic medium)

24. Mention the types of water. What is the cause for the temporary hardness
of water? 2+1

25. Give the chemical formula for the following

(i) Washing soda
(ii) Plaster of Paris.
(iii) Lime Stone. 1+1+1
26. Classify the following as Neutral Oxide, Acidic Oxide and Amphoteric
Oxide.
i) 𝑃𝑏𝑂2
ii) 𝐶𝑂
iii) 𝑆𝑖𝑂2
 PART-D (IV and V)
IV. Answer any FIVE questions:
(Each question carries five marks) 𝟓 × 𝟓 = 𝟐𝟓
27. a) A compound contains 4.07% of hydrogen, 24.47% carbon and 71.65%
chlorine. Its molecular mass is 98.96 g 𝑚𝑜𝑙 −1 .What is its empirical
formula and molecular formula.
b) Mention any two postulates of Dalton’s atomic theory. 3+2
28. a) The atomic number and mass number of copper are 29 and 64
respectively. Find the number of protons and neutrons.
b) Mention the shapes of ‘P’ orbital and ‘d’ orbital.
c) Write De-broglie equation. 2+2+1
29. a) Using S,P, and ‘d’ notations. Describe the orbital with the following
quantum numbers.
i) 𝑛 = 1, 𝑙 = 0
ii) 𝑛 = 3, 𝑙 = 1
iii) 𝑛 = 4, 𝑙 = 2
b) State Pauli’s exclusion principle.
is it possible to have the configuration of 1𝑆 3 3+2
30. a)Write any four postulates of kinetic theory of gases.
b) State Boyle’s law. 4+1
31. a) What is extensive property? Give an example.
b) Calculate the enthalpy of formation of methane. Given that, enthalpies
of combustion of methane, carbon and hydrogen are −890.30𝑘𝐽, −393.5𝑘𝐽
and −286𝑘𝐽 respectively. 2+3
32. a) Define enthalpy of combustion.
b) What is spontaneous process. Mention the thermodynamic criteria for
spontaneous process. 2+3
33. a)State Le chatalier’s principle.
What is the effect of increase in temperature for the reaction,
2𝑁𝑂2(𝑔) ⇌ 𝑁2 𝑂4(𝑔) ; ∆𝐻 = −𝑉𝑒
b) show that 𝑃𝐻 + 𝑃𝑂𝐻 = 14 3+2
34. a) calculate the 𝑃𝐻 of 0.001 M HC𝑙 assuming complete dissociation of the
acid.
b) What is common ion effect? Give an example.
c) Write the relationship between solubility and solubility product for AB
type salt. 2+2+1

V. Answer any TWO questions: 𝟐 × 𝟓 = 𝟏𝟎

(Each question carries five marks)
35. For the compound 𝐶𝐻 ≡ 𝐶 − 𝐶𝐻 = 𝐶𝐻 − 𝐶𝐻3
i) Write its complete formula 1+1+1+1+1
ii) Identify the number of sigma bond and pi bonds.
iii) Write the bond line formula of the compound.
iv) Identify the type of hybridization of each carbon atom.
v) Mention whether the compound is saturated or unsaturated.
36. a)Give any two difference between inductive effect and electrometric
effect.
b) Explain functional isomerism with an example
c) Write the IUPAC name for the compound 𝐶𝐻3 − 𝐶𝐻 = 𝐶𝐻 − 𝐶𝐻2 − 𝐶𝐻3
2+2+1
36. a) How is benzene prepared from ethyne?
b) Explain the free radical mechanism of chlorination of methane. 2 + 3

************
 I PUC ANNUAL EXAMINATION FEBRUARY/MARCH-2017
SUBJECT: CHEMISTRY (34)
Time: 3.15 Hours Maximum Marks: 70

General Instructions:
i) The question paper has four parts A, B, C and D. All parts are
compulsory.
ii) Write balanced chemical equations and draw labeled diagrams
wherever necessary.
iii) Use log tables and simple calculators if necessary. (Use of scientific
calculators is not allowed).
PART-A
I. Answer all the following questions in one word or in a sentence. Each
question carries one mark. 𝟏𝟎 × 𝟏 = 𝟏𝟎
1. How many significant figures are present in 3.0667 g?
2. State Dalton’s law of partial pressure.
3. Mention the conjugate base of 𝐻𝐶𝑂3−
4. Write the valence shell electronic configuration of p-block elements.
5. Assign the oxidation number of oxygen in 𝑂2 𝐹2 .
6. Why compounds of alkaline earth metals are more extensively hydrated than
those of alkali metals?
7. What is the chemical composition of borazine?
8. Complete the following equation 𝐻𝐶𝑂𝑂𝐻 373k
Conc. 𝐻2 𝑆𝑂4
9. Write the IUPAC name of 𝐶𝑙2 − 𝐶𝐻 − 𝐶𝐻2 − 𝐶𝐻2 𝑂𝐻.
10. Draw the Newman projection for staggered conformation of ethane.

PART-B
II. Answer any FIVE of the following questions, Each question carries 2
marks. 𝟓 × 𝟐 = 𝟏𝟎
11. A solution is prepared by adding 4.0 g of a substance ‘A’ to 36 g of water.
Calculate the mass percent of the solute.
12. Write the expression of pressure correction term and volume correction term
in real gases.
13. Give any two limitations of octet rule.
 14. Write the reaction taking place at cathode and anode in the preparation of
caustic soda using Castner-kellner cell.
15. Diamond is covalent, yet it has high melting point. Why?
16. Explain Markovanikov rule with an example.
17. What is decarboxylation? Give one example.
18. List the gases which are responsible for greenhouse effects.

PART-C
III. Answer any FIVE of the following questions, Each question carries 3
marks. 𝟓 × 𝟑 = 𝟏5
19. a) What is Ionisation enthalpy? How does it varies down a group in the
periodic table? 2
b) Give the increasing order of their metallic character for the elements B,
𝐴𝑙, 𝑀𝑔, 𝐾. 1
20. a) Write any two postulates of VSEPR theory. 2
b) Define dipole moment. 1

21. Explain 𝑆𝑃2 hybridisation in 𝐵𝐶𝑙3 . 3

22. Based on MOT give the electronic configuration, bond order and magnetic

property of Lithium molecule. 3

23. Balance the following redox reaction using oxidation number method in basic

medium.
−
𝑀𝑛𝑂4− (𝑎𝑞) + 𝐵𝑟(𝑎𝑞) → 𝑀𝑛𝑂2 (𝑠) + 𝐵𝑟𝑂3− (In acid medium) 3

24. a) What causes the temporary and permanent hardness of water? 2

b) Give one example for Ionic hydride. 1

25. a) Complete the following equation 2

i) 2𝐶𝑎(𝑂𝐻)2 + 2𝐶𝑙2 → (ii) 𝐶𝑎𝐶𝑂3 + 𝐻2 𝑆𝑂4 →

b) Beryllium shows diagonal relationship with aluminum. Give reason. 1

26. a) Explain the action of heat on borax. 2

b) What are silicones? 1

 PART-D
IV. Answer any FIVE of the following questions, Each question carries 5marks.
𝟓 × 𝟓 = 𝟐𝟓
27. a) Give any two postulates of Daltons atomic theory. 2
b) i) Calculate the number of moles in 3.01 × 1022 molecules of 𝐶𝑂2 . 2
ii) What is limiting reagent? 1
28. a) What are the observations made in Rutherford’s 𝛼 −particles scattering
experiment? 3
b) State Heisenberg’s uncertainty principle and write its mathematical form. 2
29. a) Using s,p, d notations, describe the orbital with the following quantum
numbers. (i) 𝑛 = 1 𝑙 = 0 (ii) 𝑛 = 3, 𝑙 = 1 (iii) 𝑛 = 4, 𝑙 = 2 3
b) Explain Hund’s rule of maximum multiplicity. 2
30. a) Calculate the volume occupied by 8.8 g 𝐶𝑂2 at 31.10 𝐶 and 1 bar pressure.

(𝑅 = 0.083 𝑏𝑎𝑟 𝐿𝐾 −1 𝑚𝑜𝑙 −1 ) 3

b) i) What is Boyle temperature? 1

ii) Falling liquid drops are spherical in shape. Why? 1

31. a) What is intensive property? Give one example. 2

b) Derive the relationship between 𝐶𝑝 𝑎𝑛𝑑 𝐶𝑣 for an ideal gas. 3

32. a) Calculate the standard enthalpy of formation of 𝐶𝐻3 𝑂𝐻(𝑙) . If standard

enthalpy of combustion of methanol, carbon and hydrogen are −726 𝐾𝐽 𝑚𝑜𝑙 −1,

−393 𝐾𝐽 𝑚𝑜𝑙 −1 𝑎𝑛𝑑 − 286 𝐾𝐽 𝑚𝑜𝑙 −1 respectively. 4

b) What is the effect of entropy for a reaction, 𝐻2(𝑔) → 2𝐻(𝑔)𝑗 . 1

33. a) Write the expression for the equation constant (𝐾𝑐 ) for the reaction

𝑁𝑖(𝑠) + 4𝐶𝑂(𝑔) ⇋ 𝑁𝑖(𝐶𝑂)4(𝑔) 1

𝑏) How do you predict the direction of reaction interms of equilibrium

constant (𝐾𝑐 ) and reaction quotient (𝑄𝑐 )? 2

c) Explain the effect of pressure on the equilibrium

𝐶𝑂(𝑔) + 3𝐻2(𝑔) ⇋ 𝐶𝐻4(𝑔) + 𝐻2 𝑂(𝑔) 2

34. a) Assuming complete dissociation, calculate the pH value of 0.005 M NaOH.2

b) i) What is common ion effect? Give an example. 2

 ii) Write Henderson-Hasselbalch equation for acidic buffer. 1

V. Answer any TWO of the following questions, Each question carries 5

marks. 𝟐 × 𝟓 = 𝟏𝟎
35. a) i) Explain functional group isomerism with suitable example. 2
OH
|
ii) Write a bond line formula for a compound 𝑁 ≡ 𝐶 − 𝐶𝐻 − 𝐶 ≡ 𝑁 1
b) What is positive resonance (+R) effect? Illustrate with an example. 2
36. a) Describe the estimation of sulphur by Carius method. 3
b) i) Name a suitable technique of separation of the components from a
mixture of aniline and water. 1
ii) Indicate the colour formed in the Lassaigne’s test for the detection of
nitrogen. 1
37. a) Explain the mechanism of nitration of benzene. 3
b) Write the major product formed in the following reaction. 2

i) 𝐶𝐻3 − 𝐶 ≡ 𝐶𝐻 + 𝐻2 𝑂 𝐻𝑔2+ /𝐻+ ii) 3𝐶𝐻 ≡ 𝐶𝐻 Red hot Iron tube

333K 873K

*****
 I PUC – CHEMISTRY
FEBRUARY – 2018
Time : 3hrs 15 Mins] [Maximum Marks : 70

Instructions:
a) The question paper has FOUR parts A,B,C and D. All parts are compulsory.
b) Write balanced chemical equations and draw labeled diagrams wherever necessary.
c) Use log table and simple calculator if necessary. (Use of Scientific Calculator is not
allowed).
PART-A
I. Answer ALL of the questions in one word or in one sentence each
10×01=10
1. State Avogadro’s law.
2. Give the Van der waal’s equation for ‘n’ moles of a gas.
3. What is the PH of 0.001 M NaOH?
4. Give the IUPAC name of elements having atomic number 106.
5. What is the oxidation state of ‘N’ in 𝐻𝑁𝑂3 ?
6. Name the gas liberated when sodium metal reacts with water.
7. Give the chemical formula of Borax.
8. What is meant by catenation?
9. Write the IUPAC name of

10. Name the organic product obtained when sodium benzoate is treated with
sodalime.
PART-B
II. Answer any FIVE questions: (Each question carries two marks)
05 × 02=10
11. a) Express 0.0024 in scientific notation.
b) How many moles are present in 11 g of carbon dioxide?
12. Calculate the value of ‘R’ the gas constant for one mole of an ideal gas.
13. Dipole moment of 𝑁𝐻3 is greater than 𝑁𝐹3 molecule. Explain.
14. Give any one each biological importance of sodium and potassium.
15. Give a reason why carbon monoxide is poisonous.
16. Explain geometrical isomerism in But-2-ene with structure.
17. Give the eclipsed and staggered conformation of Newman projections of
ethane.
 18. Mention any two particulate pollutants.
PART-C
III. Answer any FIVE questions: (Each question carries three marks)
05 × 03=15
19. a) Define ionization enthalpy. How does it varies along period? 2
b) State ‘Modern periodic law’. 1
20. Give any three postulates of VSEPR theory. 3
21. Discuss 𝑆𝑃2 hybridization in 𝐵𝐶𝑙3 molecule. Give the orbital picture. 3
22. Write the molecular orbital electronic electronic configuration of carbon
molecule.
Calculate its bond order and comment on its magnetic property. 3
23. Balance the redox reaction by oxidation number method.
𝑀𝑛𝑂4− (𝑎𝑞) + 𝐵𝑟 − (𝑎𝑞) ⟶ 𝑀𝑛𝑂2 (𝑠) + 𝐵𝑟𝑂3− (𝑎𝑞)
(Basic medium) 3
24. Complete the following reactions
(i) 𝐶(𝑠) + 𝐻2 𝑂(𝑔) ∆
(ii) 𝐶𝑂(𝑔) + 𝐻2 𝑂(𝑔) ∆
(iii) 𝑍𝑛(𝑠) + 2𝐻 + (𝑎𝑞)

25. Write the chemical equations involved in the preparation of sodium carbonate
by ‘Solvary’ process
26. a) What is the composition of producer gas? 1
b) Mention the type of hybrisation in graphite 1
c) Give the chemical formula of borazine. 1
PART-D
IV. Answer any FIVE questions : (Each question carries five marks)
𝟎𝟓 × 𝟎𝟓 = 𝟐𝟓
27. a) An organic compound contains 4.07% hydrogen, 24.27% carbon and
71.65%. Chlorine. Its molecular mass is 98.86. What are its empirical and
molecular formula? (Atomic mass → 𝐶 − 12, 𝐻 − 1, 𝑎𝑛𝑑 𝐶𝑙 − 35.45) 3
b) Write any two postulates of Dalton’s atomic theory. 2
28. a) Name the four quantum numbers and write their significance. 4
b) State ‘Aufbau’ principle. 1
29. a) Draw the shape of ‘S’ and ‘P’ orbitals 2
56
b) How many neutrons and protons are there in 26𝐹𝑒? 2
c) Write the electronic configuration of an element having atomic
number 28.
 30. a) Mention any two properties of gases. 2
b) Calculate mole fraction of neon gas if it contains 70.6g of oxygen and
167.5 g of neon mixture.
(Atomic mass of oxygen is 32 and neon is 20). 3
31. a) Calculate the standard enthalpy of formation of benzene, if standard
enthalpy of formation of 𝐶𝑂2 𝑎𝑛𝑑 𝐻2 𝑂 are −393.5𝑘𝐽 𝑚𝑜𝑙 −1 and −285.8 𝑘𝐽𝑚𝑜𝑙 −1
respectively and combustion of 1 mole of benzene is −3267.0 𝐾𝐽 𝑚𝑜𝑙 −1.
4
b) What is the change in entropy when ice melts to give water. 1
32. a) 2 mol of an ideal gas undergoes a reversible and isothermal expansion
from volume 2.5L to 10L at 270 𝐶. Calculate the work done by the gas in this
expansion. (Given 𝑅 = 8.314 𝐽𝐾 −1 𝑚𝑜𝑙 −1 ). 3
b) What is an extensive property? Give one example. 2
33. a) Derive the expression of ionization constant of weak acid 𝐾𝑎 . 3
b) What happens to the pH of water when 𝑁𝐻4 𝐶𝑙 solid is dissolved in it and
why? 2
34. a) If the 𝐾𝑎 value of weak acid is found to be 1.78 × 10−5 , What is its pKa
value? 2
b) Define conjugate acid base pair with example. 2
c) Give an example of acidic buffer solution. 1

V. Answer any TWO questions : (Each question carries five marks)

0𝟐 × 𝟎𝟓 = 𝟏𝟎
35. a) What are electrophiles? Give an example 2
b) Explain position isomerism with an example. 2
c) Give the resonance structure of benzene. 1
36. a) Explain how sulphur is estimated by Carius method. 3
(molar mass of 𝐵𝑎𝑆𝑂4 = 233 𝑔 𝑎𝑛𝑑 𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑆 = 32 𝑔)
b) How nitrogen is detected in an organic compound? 2
37. a) Give the mechanism of nitration of benzene. 3
b) Explain ‘Wurtz reaction’ with an example. 2

************
 I P.U.C. ANNUAL EXAMINATION JANUARY/FEBRUARY-2019
SUBJECT: CHEMISTRY(34)
Time: 3 Hours 15 minutes Maximum Marks:
70
Instructions:
1. The question paper has four parts A, B, C and D. All parts are compulsory.
2. Write balanced chemical equations and draw diagrams wherever necessary.
3. Use log tables and simple calculator if necessary (Use of scientific calculator is not
allowed).
PART-A
I. Answer ALL the questions. Each question carries 1 mark. (Answer each question in
one word or in one sentence) : 𝟏𝟎 × 𝟏 = 𝟏𝟎
1. Express 0.00025 in scientific notation.
2. How does viscosity varies with temperature?
3. Write the solubility product expression for 𝐵𝑎𝑆𝑂4 .
4. What would be the IUPAC name for the element with atomic number 104?
5. Define oxidation in terms of electron transfer.
6. Which alkali metal gives golden yellow colour to the flame?
7. Write the molecular formula of Borax.
8. What is dry ice?
9. Suggest a method to separate a mixture of chloroform and aniline.
10. Name the catalyst used in Friedel-crafts reaction.
PART-B
II. Answer any FIVE of the following. Each question carries 2 marks. 0𝟓 × 𝟎𝟐 = 𝟏𝟎
11. Mention any two postulates of Daltons atomic theory.
12. (a) State Gay-Lussac’s law.
(b) Write Vander Waal’s equation for ‘n’ mole of a gas.
13. Give any two differences between sigma bond and pi bond.
14. Complete the following reactions:
a) 2(𝐶𝑎𝑆𝑂4 . 2𝐻2 𝑂) ⟶...................+3𝐻2 𝑂
b) 𝐶𝑎𝐶𝑂3 𝐻𝑒𝑎𝑡 … … … .. + 𝐶𝑂2 .
15. How to obtained diborane from boron trifluoride? Write the equation.
16. Give the IUPAC name of the major product formed when HBr is added to propene. Write
its equation.
17. Explain Wurtz reaction with an example.
18. Write any two common chemicals of photochemical smog.
PART-C
III. Answer any FIVE of the following. Each question carries 3 marks. 𝟎𝟓 × 𝟎𝟑 = 𝟏𝟓
19. a) Define ionisation enthalpy. How does it vary down the group in the periodic table?
b) Among 𝐴𝑙 +3 and 𝑁𝑎 + ion, which one has smaller ionic radius? 2+1
20. a) Mention any two factors which influence the formation of ionic bond. 2
b) Name the type of hydrogen bond present in water. 1
21. a) With respect to the formation of Ethene molecule mention. 2
i) hybridisation of carbon.
ii) number of sigma bonds in the molecules
b) write Lewis dot structure of nitrogen molecules. 1

22. Write the molecule orbital electronic configuration for oxygen molecule.
Calculate its bond order and comment on its magnetic property. 3
23. Balance the following redox reaction by using half reaction method.
2+ 2− 3+ 3+
𝐹𝑒(𝑎𝑞) + 𝐶𝑟2 𝑂7(𝑎𝑞) ⟶ 𝐹𝑒(𝑎𝑞) + 𝐶𝑟(𝑎𝑞) 3
(𝐴𝑐𝑖𝑑𝑖𝑐 𝑚𝑒𝑑𝑖𝑢𝑚)
24. a) How does dihydrogen prepared in the laboratory ?Write the equation. 2
b) Give an example for saline hybride. 1
25. Write the equations during the preparation of sodium carbonate by “Solvay’s process”. 3
26. a) Give an example of element of group-14.
(i) Which reacts with water.
(ii) Shows maximum catenation property. 2
b) Give one example for man made silicates. 1
PART-D (IV and V)
IV. Answer any FIVE of the following. Each question carries 5 marks. 05X05=25
27. a) Define morality. How many grams of water is produced by the complete combustion of
methane? 2
b) A hydrocarbon contains 75% of carbon and 25% of hydrogen. What is its empirical
formula? 2
 c) State law of definite proportion. 1
28. a) Write any three postulates of Bohr’s model of an atom. 3
b) State Paulie’s exclusion principle. Among 4s and 3d orbital which one has lower

energy? 2

29. a) Name the quantum number that specifies.

(i) Shape of an orbital

(ii) Size of an orbital 2

b) State Heisenberg’s uncertainty principle. Write its mathematical form 2

c) How many Orientations are possible for ‘p’ orbital? 1

30. a) Mention any three assumptions of Kinetic theory of gases. 3

b) On ship sailing in pacific ocean, where temperature is 23.40 𝐶 a balloon is filled with

2L air, what will be the volume of the balloon when ship reaches Indian Ocean. Where

temperature is 26.10 C. 2

31. a) Calculate the enthalpy formation of methane from the following data.

𝐶(𝑠) + 𝑂2(𝑔) ⟶ 𝐶𝑂2(𝑔) ∆𝐻 0 = −393.5 𝑘𝐽

1
𝐻2(𝑔) + 2 𝑂2(𝑔) ⟶ 𝐻2 𝑂(𝑙) ∆𝐻 0 = −285.9 𝑘𝐽

𝐶𝐻4(𝑔) + 2𝑂2(𝑔) ⟶ 𝐶𝑂2(𝑔) + 𝐻2 𝑂(𝑙) ∆𝐻 0 = −890 𝑘𝐽 3

b) State Hess’s law of constant heat summation. 2

32. a) Define (i) Isolated system (ii) Molar heat capacity. 2

b) What is entropy? How does it vary in a spontaneous process? 2

c) Write Gibb’s energy equation. 1

33. a) Define acid and base according to Bronsted-Lowry concept. 2

b) Calculate the pH of 0.002 M 𝐶𝐻3 𝐶𝑂𝑂𝐻. 2

c) Write Henderson’s –Hesselblach equation for acidic buffer. 1
34. a) Write any three applications of equilibrium constant 𝐾𝑝 (𝑜𝑟) 𝐾𝑐 . 3
c) What is homogenous equilibrium? Give an example for solid-vapour equilibrium. 2
V. Answer any TWO of the following. Each question carries 5 marks. 02 x 05 =10
35. a) Explain chain isomerism with an example. 2
b) Given any two differences between inductive effect and Mesomeric effect 2
OH
|
c) Write the IUPAC name of 𝐻3 𝐶 − 𝐶 − 𝐶𝐻3 1
|
𝐶𝐻3

36. a) Write the principle and formula involved in the estimation of sulphur by Carius method
3
b) What are nucleophiles? Give an example. 2

37. a) Write the steps involved in the Mechanism of the nitration of benzene. 3
b) How do you prepare ethene from calcium carbide? Write the equation. 2