SAFETY DATA SHEET

US

Haas Liquid Grease

Version Revision Date: Date of last issue: - Print Date:
1.0 06/23/2021 Date of first issue: 06/23/2021 06/23/2021

SECTION 1. IDENTIFICATION

Product name : Haas Liquid Grease

Article-No. : 320734
Manufacturer or supplier's details
Company name of supplier : Klüber Lubrication NA LP
9010 CR 2120
Tyler, Texas 75707
Phone: (903) 534-8021
Fax: (903) 581-4376

32 Industrial Drive
Londonderry, NH 03053
Phone: (603) 647-4104
Fax: (603) 647-4106

E-mail address of person : mcm@us.kluber.com

responsible for the SDS Material Compliance Management

Emergency telephone num- : +1-517-545-7070 NCEC

ber

Recommended use of the chemical and restrictions on use

Recommended use : Grease

Restrictions on use : Restricted to professional users.

SECTION 2. HAZARDS IDENTIFICATION

GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR
1910.1200)
Not a hazardous substance or mixture.
GHS label elements
This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Other hazards
None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Chemical nature : Synthetic hydrocarbon oil

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SAFETY DATA SHEET
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Haas Liquid Grease

Version Revision Date: Date of last issue: - Print Date:
1.0 06/23/2021 Date of first issue: 06/23/2021 06/23/2021

ester oil
special lithium soap

Components
Chemical name CAS-No. Concentration (% w/w)
lithium 12-hydroxystearate 7620-77-1 Trade secret (>= 1 - < 5)
Hydrocarbon waxes (petroleum), 68602-85-7 Trade secret (>= 1 - < 5)
oxidized, Me esters
Actual concentration is withheld as a trade secret

SECTION 4. FIRST AID MEASURES

If inhaled : Remove person to fresh air. If signs/symptoms continue, get

medical attention.
Keep patient warm and at rest.
If breathing is irregular or stopped, administer artificial respira-
tion.

In case of skin contact : Remove contaminated clothing. If irritation develops, get med-
ical attention.
In case of contact, immediately flush skin with plenty of water.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids,
for at least 10 minutes.
If eye irritation persists, consult a specialist.

If swallowed : Move the victim to fresh air.

Do NOT induce vomiting.
Rinse mouth with water.

Most important symptoms : May cause an allergic skin reaction.

and effects, both acute and Allergic appearance
delayed

Notes to physician : The first aid procedure should be established in consultation

with the doctor responsible for industrial medicine.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or car-
bon dioxide.

Unsuitable extinguishing : High volume water jet

media

Hazardous combustion prod- : Carbon oxides

ucts Metal oxides

Further information : Standard procedure for chemical fires.

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SAFETY DATA SHEET
US

Haas Liquid Grease

Version Revision Date: Date of last issue: - Print Date:
1.0 06/23/2021 Date of first issue: 06/23/2021 06/23/2021

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters Use personal protective equipment.
Exposure to decomposition products may be a hazard to
health.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Evacuate personnel to safe areas.

tive equipment and emer- Use personal protective equipment.
gency procedures Refer to protective measures listed in sections 7 and 8.

Environmental precautions : Try to prevent the material from entering drains or water
courses.
Prevent further leakage or spillage if safe to do so.
Local authorities should be advised if significant spillages
cannot be contained.

Methods and materials for : Contain spillage, and then collect with non-combustible ab-
containment and cleaning up sorbent material, (e.g. sand, earth, diatomaceous earth, ver-
miculite) and place in container for disposal according to local
/ national regulations (see section 13).

SECTION 7. HANDLING AND STORAGE

Advice on safe handling : For personal protection see section 8.

Persons with a history of skin sensitisation problems or asth-
ma, allergies, chronic or recurrent respiratory disease should
not be employed in any process in which this mixture is being
used.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Wash hands and face before breaks and immediately after
handling the product.
Do not get in eyes or mouth or on skin.
Do not get on skin or clothing.

Conditions for safe storage : Store in original container.

Keep container closed when not in use.
Keep in a dry, cool and well-ventilated place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Store in accordance with the particular national regulations.
Keep in properly labelled containers.

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SAFETY DATA SHEET
US

Haas Liquid Grease

Version Revision Date: Date of last issue: - Print Date:
1.0 06/23/2021 Date of first issue: 06/23/2021 06/23/2021

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value type Control parame- Basis
(Form of ters / Permissible
exposure) concentration
lithium 12-hydroxystearate 7620-77-1 TWA (Inhal- 10 mg/m3 ACGIH
able particu-
late matter)
TWA (Res- 3 mg/m3 ACGIH
pirable par-
ticulate mat-
ter)
Engineering measures : none

Personal protective equipment

Respiratory protection : Not required; except in case of aerosol formation.

Filter type : Filter type P

Hand protection
Material : Nitrile rubber
Break through time : > 10 min
Protective index : Class 1

Remarks : Wear protective gloves. The break through time depends

amongst other things on the material, the thickness and the
type of glove and therefore has to be measured for each
case.

Eye protection : Safety glasses with side-shields

Protective measures : The type of protective equipment must be selected according

to the concentration and amount of the dangerous substance
at the specific workplace.
Choose body protection in relation to its type, to the concen-
tration and amount of dangerous substances, and to the spe-
cific work-place.

Hygiene measures : Wash face, hands and any exposed skin thoroughly after
handling.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Colour : yellow

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SAFETY DATA SHEET
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Haas Liquid Grease

Version Revision Date: Date of last issue: - Print Date:
1.0 06/23/2021 Date of first issue: 06/23/2021 06/23/2021

Odour : mild

Odour Threshold : No data available

pH : Not applicable

Melting point/range : No data available

Boiling point/boiling range : No data available

Flash point : >= 320 °F / 160 °C

Method: open cup

Evaporation rate : No data available

Flammability (solid, gas) : Not applicable

Self-ignition : No data available

Upper explosion limit / Upper : No data available

flammability limit

Lower explosion limit / Lower : No data available

flammability limit

Vapour pressure : < 0.001 hPa (68 °F / 20 °C)

Relative vapour density : No data available

Relative density : 0.86 (68 °F / 20 °C)

Reference substance: Water
The value is calculated

Bulk density : No data available

Solubility(ies)
Water solubility : insoluble

Solubility in other solvents : No data available

Partition coefficient: n- : No data available

octanol/water

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Viscosity
Viscosity, dynamic : No data available

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SAFETY DATA SHEET
US

Haas Liquid Grease

Version Revision Date: Date of last issue: - Print Date:
1.0 06/23/2021 Date of first issue: 06/23/2021 06/23/2021

Viscosity, kinematic : No data available

Explosive properties : Not explosive

Oxidizing properties : No data available

Sublimation point : No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity : No hazards to be specially mentioned.

Chemical stability : Stable under normal conditions.

Possibility of hazardous reac- : No dangerous reaction known under conditions of normal use.
tions

Conditions to avoid : No conditions to be specially mentioned.

Incompatible materials : No materials to be especially mentioned.

Hazardous decomposition : No decomposition if stored and applied as directed.

products

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity

Product:
Acute oral toxicity : Remarks: This information is not available.

Acute inhalation toxicity : Remarks: This information is not available.

Acute dermal toxicity : Symptoms: Redness, Local irritation

Components:

lithium 12-hydroxystearate:
Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg
Method: OECD Test Guideline 401

Acute dermal toxicity : LD50 (Rabbit): > 3,000 mg/kg

Assessment: The substance or mixture has no acute dermal
toxicity

Hydrocarbon waxes (petroleum), oxidized, Me esters:

Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg

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SAFETY DATA SHEET
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Haas Liquid Grease

Version Revision Date: Date of last issue: - Print Date:
1.0 06/23/2021 Date of first issue: 06/23/2021 06/23/2021

Assessment: The substance or mixture has no acute oral tox-

icity

Skin corrosion/irritation

Product:
Remarks : This information is not available.

Components:

lithium 12-hydroxystearate:
Assessment : No skin irritation
Method : OECD Test Guideline 439
Result : No skin irritation

Hydrocarbon waxes (petroleum), oxidized, Me esters:

Species : human skin
Assessment : No skin irritation
Result : No skin irritation

Serious eye damage/eye irritation

Product:
Remarks : This information is not available.

Components:

lithium 12-hydroxystearate:
Species : Rabbit
Result : No eye irritation
Assessment : No eye irritation
Method : OECD Test Guideline 405

Hydrocarbon waxes (petroleum), oxidized, Me esters:

Species : Human
Result : Irritating to eyes.
Assessment : Irritating to eyes.

Respiratory or skin sensitisation

Product:
Remarks : This information is not available.

Components:

lithium 12-hydroxystearate:
Exposure routes : Dermal
Species : Mouse

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SAFETY DATA SHEET
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Haas Liquid Grease

Version Revision Date: Date of last issue: - Print Date:
1.0 06/23/2021 Date of first issue: 06/23/2021 06/23/2021

Method : OECD Test Guideline 429

Result : negative

Hydrocarbon waxes (petroleum), oxidized, Me esters:

Test Type : Buehler Test
Species : Guinea pig
Assessment : Does not cause skin sensitisation.
Result : Does not cause skin sensitisation.

Germ cell mutagenicity

Product:
Genotoxicity in vitro : Remarks: No data available

Genotoxicity in vivo : Remarks: No data available

Carcinogenicity

Product:
Remarks : No data available

IARC No component of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.

IARC
OSHA No component of this product present at levels greater than or equal to 0.1% is
on OSHA’s list of regulated carcinogens.

NTP No component of this product present at levels greater than or equal to 0.1% is
identified as a known or anticipated carcinogen by NTP.

Reproductive toxicity

Product:
Effects on fertility : Remarks: No data available

Effects on foetal develop- : Remarks: No data available

ment

Repeated dose toxicity

Product:
Remarks : This information is not available.

Aspiration toxicity

Product:
This information is not available.

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SAFETY DATA SHEET
US

Haas Liquid Grease

Version Revision Date: Date of last issue: - Print Date:
1.0 06/23/2021 Date of first issue: 06/23/2021 06/23/2021

Further information

Product:
Remarks : Information given is based on data on the components and
the toxicology of similar products.

Components:

Hydrocarbon waxes (petroleum), oxidized, Me esters:

Remarks : Information given is based on data on the components and
the toxicology of similar products.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Product:
Toxicity to fish :
Remarks: No data available

Toxicity to daphnia and other :

aquatic invertebrates Remarks: No data available

Toxicity to algae/aquatic :
plants Remarks: No data available

Toxicity to microorganisms : Remarks: No data available

Components:

lithium 12-hydroxystearate:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/l
Exposure time: 96 h
Test Type: semi-static test
Method: OECD Test Guideline 203
GLP: yes

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 100 mg/l
aquatic invertebrates Exposure time: 48 h

Toxicity to algae/aquatic : EC50 (Pseudokirchneriella subcapitata (green algae)): > 160

plants mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201

NOEC (Pseudokirchneriella subcapitata (green algae)): 160

mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201

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SAFETY DATA SHEET
US

Haas Liquid Grease

Version Revision Date: Date of last issue: - Print Date:
1.0 06/23/2021 Date of first issue: 06/23/2021 06/23/2021

Persistence and degradability

Product:
Biodegradability : Remarks: No data available

Physico-chemical removabil- : Remarks: No data available

ity

Components:

lithium 12-hydroxystearate:
Biodegradability : Primary biodegradation
Inoculum: activated sludge
Result: rapidly biodegradable
Biodegradation: 74.7 %
Exposure time: 28 d
Method: OECD Test Guideline 301C

Bioaccumulative potential

Product:
Bioaccumulation : Remarks: This mixture contains no substance considered to
be persistent, bioaccumulating and toxic (PBT).
This mixture contains no substance considered to be very
persistent and very bioaccumulating (vPvB).

Components:

lithium 12-hydroxystearate:
Partition coefficient: n- : log Pow: 2.6
octanol/water

Hydrocarbon waxes (petroleum), oxidized, Me esters:

Bioaccumulation : Remarks: This substance is not considered to be persistent,
bioaccumulating and toxic (PBT).
This substance is not considered to be very persistent and
very bioaccumulating (vPvB).

Mobility in soil

Product:
Mobility : Remarks: No data available

Distribution among environ- : Remarks: No data available

mental compartments

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SAFETY DATA SHEET
US

Haas Liquid Grease

Version Revision Date: Date of last issue: - Print Date:
1.0 06/23/2021 Date of first issue: 06/23/2021 06/23/2021

Other adverse effects

Product:
Ozone-Depletion Potential : Regulation: 40 CFR Protection of Environment; Part 82 Pro-
tection of Stratospheric Ozone - CAA Section 602 Class I
Substances
Remarks: This product neither contains, nor was manufac-
tured with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).

Additional ecological infor- : No information on ecology is available.

mation

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : The product should not be allowed to enter drains, water
courses or the soil.

Contaminated packaging : Packaging that is not properly emptied must be disposed of as

the unused product.
Dispose of waste product or used containers according to
local regulations.

SECTION 14. TRANSPORT INFORMATION

International Regulations

UNRTDG
Not regulated as a dangerous good
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
National Regulations

49 CFR
Not regulated as a dangerous good

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SAFETY DATA SHEET
US

Haas Liquid Grease

Version Revision Date: Date of last issue: - Print Date:
1.0 06/23/2021 Date of first issue: 06/23/2021 06/23/2021

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity

Components CAS-No. Component RQ Calculated product RQ
(lbs) (lbs)
Ethyl acrylate 140-88-5 1000 *
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.

SARA 302 Extremely Hazardous Substances Threshold Planning Quantity

This material does not contain any components with a section 302 EHS TPQ.
SARA 311/312 Hazards : No SARA Hazards

SARA 313 : This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.

Clean Air Act

This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by
the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean
Air Act Section 112 (40 CFR 61).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for
Accidental Release Prevention (40 CFR 68.130, Subpart F).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111
SOCMI Intermediate or Final VOC's (40 CFR 60.489).
Clean Water Act
This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act,
Section 311, Table 116.4A.
This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act,
Section 311, Table 117.3.
This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section
307
This product does not contain any priority pollutants related to the U.S. Clean Water Act
US State Regulations

Massachusetts Right To Know

Ethyl acrylate 140-88-5
Pennsylvania Right To Know
Dec-1-ene, homopolymer, hydrogenated 68037-01-4
1-Octene, homopolymer, hydrogenated 70693-43-5
diisotridecyl adipate 26401-35-4
Maine Chemicals of High Concern
Product does not contain any listed chemicals

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SAFETY DATA SHEET
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Haas Liquid Grease

Version Revision Date: Date of last issue: - Print Date:
1.0 06/23/2021 Date of first issue: 06/23/2021 06/23/2021

Vermont Chemicals of High Concern

Product does not contain any listed chemicals
Washington Chemicals of High Concern
Product does not contain any listed chemicals
New York City Hazardous Substances
Naphtha (petroleum), hydrotreated heavy 64742-48-9
Ethyl acrylate 140-88-5
California Prop. 65
This product does not contain any chemicals known to State of California to cause cancer, birth
defects, or any other reproductive harm.
TSCA list
No substances are subject to a Significant New Use Rule.

No substances are subject to TSCA 12(b) export notification requirements.

SECTION 16. OTHER INFORMATION

Further information

Full text of other abbreviations

ACGIH : USA. ACGIH Threshold Limit Values (TLV)
ACGIH / TWA : 8-hour, time-weighted average

AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensa-
tion, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of
the German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic
Substances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely
Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency
Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration asso-
ciated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Har-
monized System; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification
System; IARC - International Agency for Research on Cancer; IATA - International Air Transport
Association; IBC - International Code for the Construction and Equipment of Ships carrying Dan-
gerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil
Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - In-
ternational Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Indus-
trial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI -
Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population;
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International
Convention for the Prevention of Pollution from Ships; MSHA - Mine Safety and Health Admin-
istration; n.o.s. - Not Otherwise Specified; NFPA - National Fire Protection Association; NO(A)EC
- No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level;
NOELR - No Observable Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New
Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Develop-
ment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumu-

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SAFETY DATA SHEET
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Haas Liquid Grease

Version Revision Date: Date of last issue: - Print Date:
1.0 06/23/2021 Date of first issue: 06/23/2021 06/23/2021

lative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substanc-
es; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA - Resource Conservation and
Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the
Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ -
Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund
Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Sub-
stance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations;
UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB -
Very Persistent and Very Bioaccumulative

Revision Date : 06/23/2021

This safety data sheet applies only to products as originally packed and labelled. The information
contained therein may not be reproduced or modified without our express written permission. Any
forwarding of this document is only permitted to the extent required by law. Any further, in particu-
lar public, dissemination of the safety data sheet (e.g. as a document for download from the In-
ternet) is not permitted without our express written consent. We provide our customers with
amended safety data sheets as prescribed by law. The customer is responsible for passing on
safety data sheets and any amendments contained therein to its own customers, employees and
other users of the product. We provide no guarantee that safety data sheets received by users
from third parties are up-to-date. All information and instructions in this safety data sheet have
been compiled to the best of our knowledge and are based on the information available to us on
the day of publication. The information provided is intended to describe the product in relation to
the required safety measures; it is neither an assurance of characteristics nor a guarantee of the
product's suitability for particular applications and does not justify any contractual legal relation-
ship. The existence of a safety data sheet for a particular jurisdiction does not necessarily mean
that import or use within that jurisdiction is legally permitted. If you have any questions, please
contact your responsible sales contact or authorized trading partner.

14 / 14
SAFETY DATA SHEET
US

Haas Liquid Grease CASE

Version Revision Date: Date of last issue: - Print Date:
1.0 06/23/2021 Date of first issue: 06/23/2021 12/13/2021

SECTION 1. IDENTIFICATION

Product name : Haas Liquid Grease CASE

Article-No. : 320735
Manufacturer or supplier's details
Company name of supplier : Klüber Lubrication NA LP
9010 CR 2120
Tyler, Texas 75707
Phone: (903) 534-8021
Fax: (903) 581-4376

32 Industrial Drive
Londonderry, NH 03053
Phone: (603) 647-4104
Fax: (603) 647-4106

E-mail address of person : mcm@us.kluber.com

responsible for the SDS Material Compliance Management

Emergency telephone num- : +1-517-545-7070 NCEC

ber

Recommended use of the chemical and restrictions on use

Recommended use : Grease

Restrictions on use : Restricted to professional users.

SECTION 2. HAZARDS IDENTIFICATION

GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR
1910.1200)
Not a hazardous substance or mixture.
GHS label elements
This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Other hazards
None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Chemical nature : Synthetic hydrocarbon oil

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SAFETY DATA SHEET
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Haas Liquid Grease CASE

Version Revision Date: Date of last issue: - Print Date:
1.0 06/23/2021 Date of first issue: 06/23/2021 12/13/2021

ester oil
special lithium soap

Components
Chemical name CAS-No. Concentration (% w/w)
lithium 12-hydroxystearate 7620-77-1 Trade secret (>= 1 - < 5)
Hydrocarbon waxes (petroleum), 68602-85-7 Trade secret (>= 1 - < 5)
oxidized, Me esters
Actual concentration is withheld as a trade secret

SECTION 4. FIRST AID MEASURES

If inhaled : Remove person to fresh air. If signs/symptoms continue, get

medical attention.
Keep patient warm and at rest.
If breathing is irregular or stopped, administer artificial respira-
tion.

In case of skin contact : Remove contaminated clothing. If irritation develops, get med-
ical attention.
In case of contact, immediately flush skin with plenty of water.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids,
for at least 10 minutes.
If eye irritation persists, consult a specialist.

If swallowed : Move the victim to fresh air.

Do NOT induce vomiting.
Rinse mouth with water.

Most important symptoms : May cause an allergic skin reaction.

and effects, both acute and Allergic appearance
delayed

Notes to physician : The first aid procedure should be established in consultation

with the doctor responsible for industrial medicine.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or car-
bon dioxide.

Unsuitable extinguishing : High volume water jet

media

Hazardous combustion prod- : Carbon oxides

ucts Metal oxides

Further information : Standard procedure for chemical fires.

2 / 14
SAFETY DATA SHEET
US

Haas Liquid Grease CASE

Version Revision Date: Date of last issue: - Print Date:
1.0 06/23/2021 Date of first issue: 06/23/2021 12/13/2021

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters Use personal protective equipment.
Exposure to decomposition products may be a hazard to
health.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Evacuate personnel to safe areas.

tive equipment and emer- Use personal protective equipment.
gency procedures Refer to protective measures listed in sections 7 and 8.

Environmental precautions : Try to prevent the material from entering drains or water
courses.
Prevent further leakage or spillage if safe to do so.
Local authorities should be advised if significant spillages
cannot be contained.

Methods and materials for : Contain spillage, and then collect with non-combustible ab-
containment and cleaning up sorbent material, (e.g. sand, earth, diatomaceous earth, ver-
miculite) and place in container for disposal according to local
/ national regulations (see section 13).

SECTION 7. HANDLING AND STORAGE

Advice on safe handling : For personal protection see section 8.

Persons with a history of skin sensitisation problems or asth-
ma, allergies, chronic or recurrent respiratory disease should
not be employed in any process in which this mixture is being
used.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Wash hands and face before breaks and immediately after
handling the product.
Do not get in eyes or mouth or on skin.
Do not get on skin or clothing.

Conditions for safe storage : Store in original container.

Keep container closed when not in use.
Keep in a dry, cool and well-ventilated place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Store in accordance with the particular national regulations.
Keep in properly labelled containers.

3 / 14
SAFETY DATA SHEET
US

Haas Liquid Grease CASE

Version Revision Date: Date of last issue: - Print Date:
1.0 06/23/2021 Date of first issue: 06/23/2021 12/13/2021

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value type Control parame- Basis
(Form of ters / Permissible
exposure) concentration
lithium 12-hydroxystearate 7620-77-1 TWA (Inhal- 10 mg/m3 ACGIH
able particu-
late matter)
TWA (Res- 3 mg/m3 ACGIH
pirable par-
ticulate mat-
ter)
Engineering measures : none

Personal protective equipment

Respiratory protection : Not required; except in case of aerosol formation.

Filter type : Filter type P

Hand protection
Material : Nitrile rubber
Break through time : > 10 min
Protective index : Class 1

Remarks : Wear protective gloves. The break through time depends

amongst other things on the material, the thickness and the
type of glove and therefore has to be measured for each
case.

Eye protection : Safety glasses with side-shields

Protective measures : The type of protective equipment must be selected according

to the concentration and amount of the dangerous substance
at the specific workplace.
Choose body protection in relation to its type, to the concen-
tration and amount of dangerous substances, and to the spe-
cific work-place.

Hygiene measures : Wash face, hands and any exposed skin thoroughly after
handling.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Colour : yellow

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Haas Liquid Grease CASE

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Odour : mild

Odour Threshold : No data available

pH : Not applicable

Melting point/range : No data available

Boiling point/boiling range : No data available

Flash point : >= 320 °F / 160 °C

Method: open cup

Evaporation rate : No data available

Flammability (solid, gas) : Not applicable

Self-ignition : No data available

Upper explosion limit / Upper : No data available

flammability limit

Lower explosion limit / Lower : No data available

flammability limit

Vapour pressure : < 0.001 hPa (68 °F / 20 °C)

Relative vapour density : No data available

Relative density : 0.86 (68 °F / 20 °C)

Reference substance: Water
The value is calculated

Bulk density : No data available

Solubility(ies)
Water solubility : insoluble

Solubility in other solvents : No data available

Partition coefficient: n- : No data available

octanol/water

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Viscosity
Viscosity, dynamic : No data available

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Viscosity, kinematic : No data available

Explosive properties : Not explosive

Oxidizing properties : No data available

Sublimation point : No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity : No hazards to be specially mentioned.

Chemical stability : Stable under normal conditions.

Possibility of hazardous reac- : No dangerous reaction known under conditions of normal use.
tions

Conditions to avoid : No conditions to be specially mentioned.

Incompatible materials : No materials to be especially mentioned.

Hazardous decomposition : No decomposition if stored and applied as directed.

products

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity

Product:
Acute oral toxicity : Remarks: This information is not available.

Acute inhalation toxicity : Remarks: This information is not available.

Acute dermal toxicity : Symptoms: Redness, Local irritation

Components:

lithium 12-hydroxystearate:
Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg
Method: OECD Test Guideline 401

Acute dermal toxicity : LD50 (Rabbit): > 3,000 mg/kg

Assessment: The substance or mixture has no acute dermal
toxicity

Hydrocarbon waxes (petroleum), oxidized, Me esters:

Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg

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Assessment: The substance or mixture has no acute oral tox-

icity

Skin corrosion/irritation

Product:
Remarks : This information is not available.

Components:

lithium 12-hydroxystearate:
Assessment : No skin irritation
Method : OECD Test Guideline 439
Result : No skin irritation

Hydrocarbon waxes (petroleum), oxidized, Me esters:

Species : human skin
Assessment : No skin irritation
Result : No skin irritation

Serious eye damage/eye irritation

Product:
Remarks : This information is not available.

Components:

lithium 12-hydroxystearate:
Species : Rabbit
Result : No eye irritation
Assessment : No eye irritation
Method : OECD Test Guideline 405

Hydrocarbon waxes (petroleum), oxidized, Me esters:

Species : Human
Result : Irritating to eyes.
Assessment : Irritating to eyes.

Respiratory or skin sensitisation

Product:
Remarks : This information is not available.

Components:

lithium 12-hydroxystearate:
Exposure routes : Dermal
Species : Mouse

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Version Revision Date: Date of last issue: - Print Date:
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Method : OECD Test Guideline 429

Result : negative

Hydrocarbon waxes (petroleum), oxidized, Me esters:

Test Type : Buehler Test
Species : Guinea pig
Assessment : Does not cause skin sensitisation.
Result : Does not cause skin sensitisation.

Germ cell mutagenicity

Product:
Genotoxicity in vitro : Remarks: No data available

Genotoxicity in vivo : Remarks: No data available

Carcinogenicity

Product:
Remarks : No data available

IARC No component of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.

IARC
OSHA No component of this product present at levels greater than or equal to 0.1% is
on OSHA’s list of regulated carcinogens.

NTP No component of this product present at levels greater than or equal to 0.1% is
identified as a known or anticipated carcinogen by NTP.

Reproductive toxicity

Product:
Effects on fertility : Remarks: No data available

Effects on foetal develop- : Remarks: No data available

ment

Repeated dose toxicity

Product:
Remarks : This information is not available.

Aspiration toxicity

Product:
This information is not available.

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Haas Liquid Grease CASE

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Further information

Product:
Remarks : Information given is based on data on the components and
the toxicology of similar products.

Components:

Hydrocarbon waxes (petroleum), oxidized, Me esters:

Remarks : Information given is based on data on the components and
the toxicology of similar products.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Product:
Toxicity to fish :
Remarks: No data available

Toxicity to daphnia and other :

aquatic invertebrates Remarks: No data available

Toxicity to algae/aquatic :
plants Remarks: No data available

Toxicity to microorganisms : Remarks: No data available

Components:

lithium 12-hydroxystearate:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/l
Exposure time: 96 h
Test Type: semi-static test
Method: OECD Test Guideline 203
GLP: yes

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 100 mg/l
aquatic invertebrates Exposure time: 48 h

Toxicity to algae/aquatic : EC50 (Pseudokirchneriella subcapitata (green algae)): > 160

plants mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201

NOEC (Pseudokirchneriella subcapitata (green algae)): 160

mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201

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Haas Liquid Grease CASE

Version Revision Date: Date of last issue: - Print Date:
1.0 06/23/2021 Date of first issue: 06/23/2021 12/13/2021

Persistence and degradability

Product:
Biodegradability : Remarks: No data available

Physico-chemical removabil- : Remarks: No data available

ity

Components:

lithium 12-hydroxystearate:
Biodegradability : Primary biodegradation
Inoculum: activated sludge
Result: rapidly biodegradable
Biodegradation: 74.7 %
Exposure time: 28 d
Method: OECD Test Guideline 301C

Bioaccumulative potential

Product:
Bioaccumulation : Remarks: This mixture contains no substance considered to
be persistent, bioaccumulating and toxic (PBT).
This mixture contains no substance considered to be very
persistent and very bioaccumulating (vPvB).

Components:

lithium 12-hydroxystearate:
Partition coefficient: n- : log Pow: 2.6
octanol/water

Hydrocarbon waxes (petroleum), oxidized, Me esters:

Bioaccumulation : Remarks: This substance is not considered to be persistent,
bioaccumulating and toxic (PBT).
This substance is not considered to be very persistent and
very bioaccumulating (vPvB).

Mobility in soil

Product:
Mobility : Remarks: No data available

Distribution among environ- : Remarks: No data available

mental compartments

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Other adverse effects

Product:
Ozone-Depletion Potential : Regulation: 40 CFR Protection of Environment; Part 82 Pro-
tection of Stratospheric Ozone - CAA Section 602 Class I
Substances
Remarks: This product neither contains, nor was manufac-
tured with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).

Additional ecological infor- : No information on ecology is available.

mation

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : The product should not be allowed to enter drains, water
courses or the soil.

Contaminated packaging : Packaging that is not properly emptied must be disposed of as

the unused product.
Dispose of waste product or used containers according to
local regulations.

SECTION 14. TRANSPORT INFORMATION

International Regulations

UNRTDG
Not regulated as a dangerous good
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
National Regulations

49 CFR
Not regulated as a dangerous good

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Haas Liquid Grease CASE

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SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity

Components CAS-No. Component RQ Calculated product RQ
(lbs) (lbs)
Ethyl acrylate 140-88-5 1000 *
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.

SARA 302 Extremely Hazardous Substances Threshold Planning Quantity

This material does not contain any components with a section 302 EHS TPQ.
SARA 311/312 Hazards : No SARA Hazards

SARA 313 : This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.

Clean Air Act

This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by
the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean
Air Act Section 112 (40 CFR 61).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for
Accidental Release Prevention (40 CFR 68.130, Subpart F).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111
SOCMI Intermediate or Final VOC's (40 CFR 60.489).
Clean Water Act
This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act,
Section 311, Table 116.4A.
This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act,
Section 311, Table 117.3.
This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section
307
This product does not contain any priority pollutants related to the U.S. Clean Water Act
US State Regulations

Massachusetts Right To Know

Ethyl acrylate 140-88-5
Pennsylvania Right To Know
Dec-1-ene, homopolymer, hydrogenated 68037-01-4
1-Octene, homopolymer, hydrogenated 70693-43-5
diisotridecyl adipate 26401-35-4
Maine Chemicals of High Concern
Product does not contain any listed chemicals

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Vermont Chemicals of High Concern

Product does not contain any listed chemicals
Washington Chemicals of High Concern
Product does not contain any listed chemicals
New York City Hazardous Substances
Naphtha (petroleum), hydrotreated heavy 64742-48-9
Ethyl acrylate 140-88-5
California Prop. 65
This product does not contain any chemicals known to State of California to cause cancer, birth
defects, or any other reproductive harm.
TSCA list
No substances are subject to a Significant New Use Rule.

No substances are subject to TSCA 12(b) export notification requirements.

SECTION 16. OTHER INFORMATION

Further information

Full text of other abbreviations

ACGIH : USA. ACGIH Threshold Limit Values (TLV)
ACGIH / TWA : 8-hour, time-weighted average

AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensa-
tion, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of
the German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic
Substances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely
Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency
Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration asso-
ciated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Har-
monized System; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification
System; IARC - International Agency for Research on Cancer; IATA - International Air Transport
Association; IBC - International Code for the Construction and Equipment of Ships carrying Dan-
gerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil
Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - In-
ternational Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Indus-
trial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI -
Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population;
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International
Convention for the Prevention of Pollution from Ships; MSHA - Mine Safety and Health Admin-
istration; n.o.s. - Not Otherwise Specified; NFPA - National Fire Protection Association; NO(A)EC
- No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level;
NOELR - No Observable Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New
Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Develop-
ment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumu-

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Haas Liquid Grease CASE

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lative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substanc-
es; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA - Resource Conservation and
Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the
Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ -
Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund
Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Sub-
stance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations;
UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB -
Very Persistent and Very Bioaccumulative

Revision Date : 06/23/2021

This safety data sheet applies only to products as originally packed and labelled. The information
contained therein may not be reproduced or modified without our express written permission. Any
forwarding of this document is only permitted to the extent required by law. Any further, in particu-
lar public, dissemination of the safety data sheet (e.g. as a document for download from the In-
ternet) is not permitted without our express written consent. We provide our customers with
amended safety data sheets as prescribed by law. The customer is responsible for passing on
safety data sheets and any amendments contained therein to its own customers, employees and
other users of the product. We provide no guarantee that safety data sheets received by users
from third parties are up-to-date. All information and instructions in this safety data sheet have
been compiled to the best of our knowledge and are based on the information available to us on
the day of publication. The information provided is intended to describe the product in relation to
the required safety measures; it is neither an assurance of characteristics nor a guarantee of the
product's suitability for particular applications and does not justify any contractual legal relation-
ship. The existence of a safety data sheet for a particular jurisdiction does not necessarily mean
that import or use within that jurisdiction is legally permitted. If you have any questions, please
contact your responsible sales contact or authorized trading partner.

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