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Aarambh NEET (2024)

Redox Reactions and Volumetric Analysis NEET
Revision Practice Sheet

Single Correction Type Questions (1 to 20) 6. If an element is in its lowest oxidation state, under
1. In the chemical reaction, proper conditions, it can act as:
Ag2O + H2O + 2e–  2Ag + 2OH– (1) A reducing agent
(1) Hydrogen is oxidized (2) An oxidizing agent
(2) Oxygen are reduced (3) Oxidizing as well as reducing agent
(3) Silver is oxidized (4) Neither oxidizing nor reducing agent
(4) Silver is reduced
7. Oxidation states of P in H4P2O5, H4P2O6, H4P2O7 are
2. Which is not a disproportionation reaction? respectively:
(1) +3, +5, +4 (2) +5, +3, +4
(3) +5, +4, +3 (4) +3, +4, +5
(1)
8. Which of the following is not a reducing agent?
(1) SO2 (2) H2O2
(2) (3) CO2 (4) NO2

(3) NaH + H2O  NaOH + H2 9. For the redox reaction,

(4) All of the above MnO4– + C2O42– + H+  Mn2+ + CO2 + H2O
the correct coefficients of the reactants for the
3. In which of the following processes is nitrogen balanced equation are:
oxidised? MnO4– C2O42– H+
(1) NH4  N2 (2) NO3  NO (1) 2 5 16
(2) 16 5 2
(3) NO2  NO2 (4) NO3  NH4 (3) 5 16 2
(4) 2 16 5
4. For the reaction
H3PO2 + NaOH  NaH2PO2 + H2O 10. An element, which never has a positive oxidation
What is the equivalent weight of H3PO2? (mol. wt. state in any of its compounds, is:
is M) (1) Boron (2) Oxygen
(1) M (2) M/2 (3) Chlorine (4) Fluorine
(3) M/3 (4) None of these
11. If three electrons are lost by a metal ion, M3+, its
5. In which one of the following changes, there is final oxidation number would be:
transfer of five electrons? (1) Zero (2) +6
(1) MnO4  Mn 2 (3) +2 (4) +4

(2) CrO24  Cr3 12. The missing term in the following equation is:
(3) MnO4  MnO2 2Fe3+ + Sn2+  2Fe2+ + ……
(1) Sn4+ (2) Sn3+
(4) Cr2O72  2Cr3
(3) Sn2+ (4) Sn+
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13. When BrO3– ion reacts with Br– in acidic medium, 20. Which of the following species cannot show
Br2 is liberated. The equivalent weight of Br 2 in this disproportionation reaction?
reaction is: (1) BrO– (2) BrO2–
–
5M 5M (3) BrO3 (4) BrO4–
(1) (2)
8 3 Assertion & Reason Type Questions (21 to 25)
3M 4M
(3) (4) 21. Assertion: I2  IO3– + I–. This reaction is a
5 6 disproportionation reaction,
Reason: Oxidation number of I can vary from –1 to
14. In the ethylene molecule the two carbon atoms have +7.
the oxidation numbers: (1) Both Assertion and Reason are true and the
(1) –1, –1 (2) –2, –2 Reason is the correct explanation of the Assertion
(3) –1, –2 (4) +2, –2 (2) Both Assertion and Reason are true but the
Reason is not the correct explanation of the
15. Balance the following equation and choose the
Assertion
correct value of sum of coefficient of the products:
(3) Assertion is true statement but Reason is false
CS2 + Cl2  CCl4 + S2Cl2
(4) Both Assertion and Reason are false statements
(1) 5 (2) 3
(3) 6 (4) 2
22. Assertion: In CrO5 oxidation number Of Cr is +6.
Reason: CrO5 has butterfly structure in which
16. In the titration of oxalic acid with potassium
peroxide bonds are present.
permanganate, the oxalic acid is oxidised to
(1) Carbon dioxide
(2) Carbon monoxide
(3) Elemental carbon
(4) Any of the above depending upon the medium (1) Both Assertion and Reason are true and the
Reason is the correct explanation of the Assertion
17. The redox reaction takes place when acidic (2) Both Assertion and Reason are true but the
potassium permanganate is titrated with ferrous Reason is not the correct explanation of the
ammonium sulphate. The one which is undergoing
Assertion
oxidation is
(3) Assertion is true statement but Reason is false
(1) Ferrous ion
(4) Both Assertion and Reason are false statements
(2) Manganese of permanganate ion
(3) Sulphur of sulphate ion
23. Assertion: MnO2 can acts as an oxidizing agent as
(4) Nitrogen of ammonium ion
well as reducing agent.
Reason: Oxidation state of Mn lies between highest
18. In the redox reaction , which
and lowest oxidation state.
of the following is not correctly matched?
(1) Both Assertion and Reason are true and the
(1) Na ; Reductant Reason is the correct explanation of the Assertion
(2) H2 ; Oxidant (2) Both Assertion and Reason are true but the
(3) Na in NaH is present as cation Reason is not the correct explanation of the
(4) Na in NaH is present as anion Assertion
(3) Assertion is true statement but Reason is false
19. The type of reaction denoted in the given reaction is (4) Both Assertion and Reason are false statements

(1) Decomposition reaction

(2) Metal displacement reaction
(3) Non-metal displacement
(4) Disproportionation reaction
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24. Assertion: 0.1 M H3PO3(aq) solution has normality A B C D

equal to 0.3 N when completely reacted with NaOH. (1) P R Q S
Reason: H3PO3 is a tribasic acid. (2) S P R R, Q
(1) Both Assertion and Reason are true and the (3) R P P, S Q
Reason is the correct explanation of the Assertion (4) S P, Q P S
(2) Both Assertion and Reason are true but the
Reason is not the correct explanation of the 28. Match the following:
Assertion Column – I Column – II
(3) Assertion is true statement but Reason is false (Reaction) (Equivalent
(4) Both Assertion and Reason are false statements mass of
reactant)
25. Assertion: In the balanced redox reaction, (A) NH3  NO3– (P) M/20
xAs2S3 + yNO3– + 4H2O  aAsO43– + bNO + (B) Fe2S3  FeSO4 + SO2 (Q) M/2
cSO42– + 8H+ then n-factor of As2S3 and NO3– is 28 (C) CaCO3 + 2HCl  (R) M/8
and 3 respectively. CaCl2 + H2O + CO2
Reason: Molar ratio is reciprocal of n-factor’s ratio so (D) CuS  CuSO4 (S) 50
x : y is 3 : 28.
(1) Both Assertion and Reason are true and the (M = Molar weight)
Reason is the correct explanation of the Assertion A B C D
(2) Both Assertion and Reason are true but the (1) P R Q S
Reason is not the correct explanation of the (2) S P Q R
Assertion (3) R P S, Q R
(3) Assertion is true statement but Reason is false (4) S Q P R
(4) Both Assertion and Reason are false statements
29. Match the following:
Match the Column Type Questions (26 to 30) Column – I Column – II
26. Match the following: (Compound) (Oxidation state of
Column – I Column – II nitrogen)
(Compound) (Oxidation state) (A) N2O5 (P) –2
(A) CrO5 (P) +6 (B) NaN3 (Q) +5
(B) H2SO4 (Q) +1 (C) NO (R) –1/3
(C) CaOCl2 (R) –1 (D) N2H4 (S) +2
(D) (CH3)2SO (S) 0 A B C D
A B C D (1) Q R S P
(1) P P Q, R S (2) P Q R S
(2) P S Q R (3) S P Q R
(3) S Q S P (4) R P S Q
(4) P S P, Q R
30. Match the following:
27. Match the following: Column – I Column – II
Column – I Column – II (Acid) (Equivalent wt.)
(Acid) (Information) (A) H4P2O6 (P) M/3
(A) CH3COOH (P) Tribasic (B) H3PO4 (Q) M
(E = M/3) (C) H3BO3 (R) M/2
(B) H3PO4 (Q) Dibasic reducing (D) H2SO4 (S) M/4
(C) H2SO4 (R) Dibasic A B C D
(E = M/2) (1) P R Q S
(D) H3PO3 (S) Monobasic (2) S P Q R
(E = M) (3) P Q S R
(E = Equivalent weight, M = Molar weight) (4) S Q P R
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Answer Key
1. (4) 16. (1)
2. (3) 17. (1)
3. (1) 18. (4)
4. (1) 19. (2)
5. (1) 20. (4)
6. (1) 21. (2)
7. (4) 22. (1)

8. (3) 23. (1)

9. (1) 24. (4)

25. (1)
10. (4)
26. (1)
11. (2)
27. (2)
12. (1)
28. (3)
13. (3)
29. (1)
14. (2)
30. (2)
15. (4)
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Hints and Solutions

1. (4) 4 + 2x – 14 = 0
Silver cation is taking up the electron. Hence it is 2x = 10
reduced. Rest of all the atoms neither accepting x = +5
electron nor donating. Thus oxidation states of P in H4P2O5, H4P2O6,
H4P2O7, are +3, +4 and +5
2. (3)
In a disproportionation reaction an element in one 8. (3)
oxidation state is simultaneously oxidised and Oxidation state of C in CO2 is +4, which is
reduced. The first reaction is Tishchenko and the maximum So it does not undergo oxidation, and
hence, it is not a reducing agent.
second one is Cannizzaro. Both are the examples of
disproportionation reaction.
9. (1)
2MnO4  5C2O42  16H  10CO2  8H2O  2Mn 2
3. (1)
Oxidation process, in terms of electron transfer, is
the loss of electron. 10. (4)
An element that never has a positive oxidation state
in any of its compound is fluorine. Fluorine only
4. (1)
shows negative oxidation states whereas other
is monobasic acid. Its equivalent weight is
halogens shows negative as well as positive
equal to molar weight divided by number of acidic oxidation state.
hydrogen. Therefore, both the weights are equal.
11. (2)
5. (1) When M3+ losses 3 electrons, It becomes M6+. Hence
MnO4– + 8H + 5e–  Mn2++ 7H2O the oxidation number of M will be +6.

6. (1) 12. (1)

If an element is in its lowest oxidation state, it means Sn4+ is correct as it balances the charge and it is a p-
it is electron rich and donate it. Hence, behaves as block element so the two oxidation states differ by 2
reducing agent.

7. (4) 13. (3)

Oxidation state of H is +1 and that of O is –2 Given,
Let the oxidation state of P in the given compound BrO3 reacts with Br– in acidic medium
x. The reaction involved is
In H4P2O5 BrO3  5Br   6H  3Br2  3H 2O
(+1) × 4 + 2X × + (–2) × 5 = 0 Here, in BrO3 Br has +5 oxidation state & BrO3
4 + 2x – 10 = 0
 reduction is 5
2x = 6
Also, in 5Br–  3Br2 oxidation is 5
x=3
In H4P2O6  n factor = 5
Now, we know, Equivalent weight
(+1) X 4 + 2X × + (–2) × 6 = 0
Molecular weight
4x + 2x – 12 = 0 =
2x = 8 n factor
x=4 3  M 3M
Equivalent weight of 3Br2 
In H4P2O7 5 5
(+1) × 4 × 2X × + (–2) × 7 = 0
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14. (2) 21. (2)

Formula of ethylene = C2H4 Given reaction, I2  IO3– + I–
Let oxidation number of C is x and we know Disproportion reaction is in which, an element
oxidation number of H is +1. goes both oxidation and reduction.
( 5 ) ( 1 )
So, 2(x) + 4(+1) = 0 (o)
I 2  IO3  I
x = –2
So oxidation number of each carbon is –2 I has oxidation from 0 to 5 and reduced from o to 1.
Oxidation number of I are –1, +1, +3, +5, +7
15. (4)
The balanced equation is: 22. (1)
In the structure of CrO5, it has four O atoms as
CS2 + 3Cl2  CCl4 + S2Cl2
peroxide which have oxidation number = –1 and
Sum of the coefficients of products = 1 + 1 = 2.
one O as oxide (double bonded O) atom with
oxidation number = –1
16. (1)
Let the oxidation number of Cr is x.
C2O4  2CO2  2e Then, x + 4 × (–1) + 1 × (–2) = 0
or x = +6
17. (1) The oxidation number of Cr in CrO5 is + 6
2KMnO4 + 8H2SO4 + 10FeSO4 (NH4)2 SO4. 6H2O 23. (1)
 K2SO4 + 3MnSO4 + 5Fe2(SO4)3 + 10(NH4)2SO4 The electronic configuration of Mn is 1s2 2s2 p6
+ 68H2O 3s2p6d54s2.
Therefore, it can lose 7 electrons and oxidation
18. (4) state can very in between 0 to 7.
In ionic NaH, Na is present as monovalent cation. In MnO2, oxidation state of Mn is +4, which lies
between highest and lowest oxidation state, so it
19. (2) can act as an oxidation agent as well reducing
A metal in a compound can be displaced by another agent.
metal in the uncombined state is known as metal
displacement reaction. A decomposition reaction 24. (4)
leads to the breakdown of a compound into two or H3PO3 is dibasic acid and so, it will give 2H+ ion in
solution.
more components at least one of which must be in
0.1 MH3PO3 (aq) solution has normality equal to 0.2
the elemental state. The nonmetal displacement
N when completely reacted with NaOH.
redox reactions include hydrogen displacement and
a rarely occurring reaction involving oxygen
displacement. Disproportionation reactions are a
special type of redox reactions. In a
disproportionation reaction an element in one
oxidation state is simultaneously oxidised and
reduced.
25. (1)
20. (4)
Disproportionation reactions are a special type of xAs2 S3  yNO3  4 H 2O  aAsO43
redox reactions. In a disproportionation reaction an  bNO  cSO42  8H 
element in one oxidation state is simultaneously n-factor of As2S3 is 28 and NO3 is 3.
oxidised and reduced. In BrO4- , the Br-atom is in
As number of equivalents of all reactants are
maximum oxidation state (+7) same, their molar ratio is reciprocal of n-factor's
ratio.
Therefore, x : y = 3:28
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26. (1) 29. (1)

The oxidation state of Cr in CrO5 is+6, of S in 1. N2O5
is +6 , of Cl in is +1 and -1, of S in Oxidation state of oxygen = –2
( ) is zero So oxidation state of nitrogen = +5
2. NaN3
27. (2) Oxidation state of sodium = +1
Equivalent weight = So oxidation state of nitrogen = –1/3
3. NO
Oxidation state of oxygen = –2
So oxidation state of nitrogen = +2
4. N2H4
Oxidation state of hydrogen = +1
28. (3) So, oxidation state of nitrogen = –2
Equivalent weight
= 30. (2)

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