

Cl
 F   10; SO24  100; NO3  50

NO3 SO24 NO3

SO24

   
h uv
  O H(g)  Cl(g)   Cl(g)  CF2 Cl(g)
 
 ClO(g)  O(g)  Cl(g)  O2 (g)

H 3C–C–OONO2
O
 
(4) in the stratophere, CFCs release chlorine free radicals (Cl)


(Cl)
UV
  Cl (g)  CF
 Cl(g)
2


(ClO)  )
(ClO 2

  O (g)  ClO(g)
Cl(g)   O2 (g)
3
 740 ºC
 
10H2 O





Hydrolysis
 

Excess NH
   3 
low temperature


 





 







hydrolysis



,
 


H2O
  
condensati on

Me Me Me Me Me
| | | | |
Cl — Si — Cl  OH — Si — O H  OH — Si — OH  OH — Si — O — Si — OH .
H2O

| | | | |
Me Me Me Me Me


 

| | |
CH – OH CH – O O – CH
| | B |
CH – OH CH – O O – CH
| | |



 
 
 
 

   
   
 

2
2–
Sr C2  
 

 
     


     

       


  
  
Na
 





heated
    
ti tan ium metal filament



10H2O






OH  

H

Column-I Column-I
(A) Silica gel (i) Transistor
(B) Silicon (ii) Ion-exchanger
(C) Silicone (iii) Drying agent
(D) Silicate (iv) Sealant

B2 H6  O2 
 B2 O3  H2O

B2 H6  H2 O 
 H3 BO3  H2

 


673K
Catalyst 
1270 K
Ni



1270K
 
1273K


CO(g)  H 2 O(g) 

673K
catalyst
 CO 2( g)  H 2(g)

CH 4(g)  H 2 O (g) 

1270K
Ni
 CO(g)  3H 2(g)

C (s)  H 2 O ( g)   CO ( g )  H 2( g)
1270 K

2C(s)  O2(g)  4N2(g) 

1270K
 2CO(g)  4N 2(g)
 

CH 4  H 2 O  CO  3H 2  both reactions are carried out at
C3H 8  H 2 O  3CO  H 2  1270K temp. with Ni catalyst

CaO, BaO = Basic Nature

B2O 3, SiO2 = Acidic Nature
N2O = Neutral oxide
(3) SiO

Me Me
| |
— O — Si — O — Si — O —
| |
O O
| |
— O — Si — O — Si — O —
| |
Me Me
 R
–(Si–O)–n (R=Me)
R


H 3 N3 B3 Cl3  3LiBH 4 
In tetrahydrofurane
(T.H.F.)
 H3 N3 B3 H3 3LiCl
(B)
Inorganic Benzene 3BH 3 .THF
(A)
(Borazene)


H 3 N 3 B3 Cl3  3CH 3 MgBr   H 3 N 3 B3 (CH 3)3  3MgBrCl
(A) ( C)

H
H  90 H
2 B 1 B
H H
H
2 > 1
  

 


20 12
 

  
  

 





I I I I I I I I
Ans. (C)
Sol. 
 



 

        


 






 



  

 



    

  

 
 


   
 
   

   







1

 

2



 


 






(liquid)
 


 

   
   

[ C  C ]2 
 

Column I Column II
(i) Na2CO3·10 H2O (P) Portland cement
ingredient
(ii) Mg(HCO3)2 (Q) Castner-Keller
process
(iii) NaOH (R) Solvay process
(iv) Ca3 Al2 O6 (S) Temporary
hardness

       
       





 


2Mg  O2 
 2MgO

3Mg  N 2 
 Mg 3N 2


  

393K 1 3
CaSO 4 .2H 2 O   CaSO 4 . H2O  H 2 O
Gypsum 2 2
Plaster of paris
All alkali metal hydrogen carbonate exist in solid state except LiHCO



 
 


 [M(NH3 )x ]  [e (NH3 )y ]
M(g )  (x  y)NH3 

~ 30 times




 
3Mg + N2 Mg3N2
(
(A) (B)
6H2O
3Mg(OH)2 + 2NH3
colourless gas
CuSO4 + 4NH3 [Cu(NH3)4]SO4
deep blue solution


 3NaH 2 PO 2
(X)


 H3 PO2
( Y)

O
P (mono basic acid)
HO H
H

S.No. Column  I S.No. Column  II

(I) Ca(OH)2 (A) casts of statues
(II) NaCl (B) white wash
1
(III) CaSO 4 . H 2O (C) antacid
2
washing soda
(IV) CaCO3 (D)
preparation



 

 
1
2

List-I List-II
(Salt) (Flame colour
wavelength)
(a) LiCl (i) 455.5 nm
(b) NaCl (ii) 670.8 nm
(c) RbCl (iii) 780.0 nm
(d) CsCl (iv) 589.2 nm

Colour /nm
Li Crimson red 670.8
Na Yellow 589.2
Rb Red violet 780.0
Cs Blue 455.5


CaCl 2 .6H 2O   CaCl 2  6H 2 O
(Anhydrous)


MgCl2 .8H2 O   MgO  2HCl  6H 2O


MgO
CaO
 All are basic oxide
SrO
BaO
 
573K


O O 2
+ +
K Mn 2K Mn
O O O O
O O
Tetrahedral Tetrahedral
unit unit
diamagnetic paramagnetic

1
H2O
2

1
 H2O
2





(B) 2KO 
Not To Be Discussed in Class
 Not To Be Discussed in Class

H4




(A) Al(OH)Cl



Hydrolysis


 











 Excess NH
   3 
low temperature







    
 Hydrolysis
  
Hydrolysis
  
 



 

2B  3O 2 
 B2 O3 (white powder)
2B N 2 
 2BN (white powder)
'A' 'B'

2H3BO3 heat
strongly
 B2O3  3H 2O
'C' 'E '

  



on

s tan ding

 



3HCl

 



 Si2O76

 


CH3
Cu powder |
    

2 H2 O
HO – Si – OH
570 ºC – 2HCl
|
CH3

CH3 CH3 CH3

|

nHO – Si – OH  HO Si O Si O
– n H2 O
|
CH3 CH3 n
CH3
linear silicone
(thermoplastic polymer)


 1400 º C
  

 
  





Na 2B 4 O 7 .10H2 O  Na 2B 4 O 7 Na 2B 4 O 7  2HCl  2NaCl  H2B 4 O 7

red hot
H2B 4 O 7  5H2O  4H3BO 3 2H3BO3    B 2O 3  3H2O
Boric acid Boric anhydride

Fusion
B 2O 3  3Mg   2B  3MgO 
 10H2O
  


10H2O
  





ether
3NaBH 4  4BF3   3NaBF4  2B 2H6

100
B 2H6  2NH3  B 2H6 .2NH3
tempt .

o
200 C
B 2H6 .2NH3  
 B 3N3H6  H2
 2B  6HNO3 (or H2 SO 4 )  2H3BO 3  6NO 2

4H3BO 3  Na 2CO 3  Na 2B 4 O 7  6H2 O  CO 2

p p

 

COOH
P4 O10
CH2  
 C3O2 (Carbon suboxide) + 2H2O

COOH








 
 10 H2O
 BF 


Statement

 
  


 Not To Be Discussed in Class

 
 


 





 







  


 


1

2
1

2
 

  

) )


  

  


   


  
 












 








 1  1
    
2 2
 1 
     
2
 

 




(C)









 Al (SO )
 
2 43
aq.



  


 



CaCO3
NH3 + H2O

H2O CaO + CO2

B

A NaHCO3 + D NaCl

C + H2O
NH3+ H2O + E












SO 2 Na CO elemental S 2
  
2

3
 
 


H2 O




I  I
Statement-II

 
   

 
 