ISO 9328-2-2018 - en
ISO 9328-2-2018 - en
ISO 9328-2-2018 - en
STANDARD 9328-2
Fourth edition
2018-02
Reference number
ISO 9328-2:2018(E)
© ISO 2018
ISO 9328-2:2018(E)
Contents Page
Foreword......................................................................................................................................................................................................................................... iv
1 Scope.................................................................................................................................................................................................................................. 1
2 Normative references....................................................................................................................................................................................... 1
3 Terms and definitions...................................................................................................................................................................................... 1
4 Classification and designation................................................................................................................................................................ 1
4.1 Classification.............................................................................................................................................................................................. 1
4.2 Designation................................................................................................................................................................................................. 2
5 Information to be supplied by the purchaser......................................................................................................................... 2
5.1 Mandatory information.................................................................................................................................................................... 2
5.2 Options............................................................................................................................................................................................................ 2
5.3 Example for ordering.......................................................................................................................................................................... 3
6 Requirements........................................................................................................................................................................................................... 3
6.1 Steelmaking process............................................................................................................................................................................ 3
6.2 Delivery condition................................................................................................................................................................................. 3
6.3 Chemical composition....................................................................................................................................................................... 4
6.4 Mechanical properties....................................................................................................................................................................... 5
6.5 Surface condition................................................................................................................................................................................... 5
6.6 Internal soundness............................................................................................................................................................................... 5
6.7 Weldability................................................................................................................................................................................................... 5
6.8 Dimensions and tolerances on dimensions..................................................................................................................... 6
6.9 Calculation of mass............................................................................................................................................................................... 6
6.10 Resistance to hydrogen-induced cracking....................................................................................................................... 6
6.11 Embrittlement of CrMo steels..................................................................................................................................................... 6
7 Inspection..................................................................................................................................................................................................................... 6
7.1 Types of inspection and inspection documents.......................................................................................................... 6
7.2 Tests to be carried out....................................................................................................................................................................... 6
7.3 Retests, sorting and reprocessing............................................................................................................................................ 6
8 Sampling......................................................................................................................................................................................................................... 6
9 Test methods.............................................................................................................................................................................................................. 6
10 Marking........................................................................................................................................................................................................................... 7
Annex A (normative) Chemical composition and mechanical properties of products based
on European standards................................................................................................................................................................................... 8
Annex B (normative) Chemical composition and mechanical properties of products based
on ASTM/ASME or JIS standards........................................................................................................................................................17
Annex C (informative) Steel designations in accordance with this document and
designation of comparable steel grades in national or regional standards.........................................22
Annex D (informative) Guidelines for heat treatment.....................................................................................................................24
Annex E (informative) Critical time-temperature parameter Pcrit. and possible
combinations of stress relieving temperature and holding time....................................................................26
Annex F (informative) Reference data relating to strength for 1 % (plastic) creep strain and
creep rupture.........................................................................................................................................................................................................27
Annex G (informative) Evaluation of resistance to hydrogen-induced cracking..................................................33
Annex H (informative) Step cooling test.........................................................................................................................................................34
Bibliography.............................................................................................................................................................................................................................. 35
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www.iso.org/directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www.iso.org/patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation on the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO's adherence to the
World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT) see the following
URL: www.iso.org/iso/foreword.html.
This document was prepared by Technical Committee ISO/TC 17, Steel, Subcommittee SC 10, Steel for
pressure purposes.
This fourth edition cancels and replaces the third edition (ISO 9328-2:2011), which has been technically
revised. The following changes have been made:
— the term “product thickness” has been replaced with “nominal thickness”;
— normalizing rolling is also considered for steel grade 16Mo3 (see Annex A);
— the technical data in Annex A have been aligned with EN 10028-2;
— in Table B.1, “B ≤ 0,001 0” has been added and the specifications of “P” and “S” have been changed.
A list of all the parts in the ISO 9328 series can be found on the ISO website.
1 Scope
This document specifies the technical delivery conditions for plates and strip for pressure equipment
made of non-alloy and alloy steels as specified in Tables A.1 and B.1. The requirements and definitions
of ISO 9328-1 also apply to this document.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
ISO 4948-1, Steels — Classification — Part 1: Classification of steels into unalloyed and alloy steels based
on chemical composition
ISO 4948-2, Steels — Classification — Part 2: Classification of unalloyed and alloy steels according to main
quality classes and main property or application characteristics
ISO 9328-1:2018, Steel flat products for pressure purposes — Technical delivery conditions — Part 1:
General requirements
4.1 Classification
In accordance with ISO 4948-1 and ISO 4948-2, the steel grades P235GH, P265GH, P295GH and P355GH
(see Annex A) and PT410GH, PT450GH and PT480GH (see Annex B) are non-alloy-quality steels. All
other grades are alloyed special steels.
4.2 Designation
Shall be in accordance with ISO 9328-1.
NOTE 1 Non-alloy grades in Annex A are classified in accordance with their yield strength, non-alloy grades in
Annex B are classified in accordance with their tensile strength.
NOTE 2 Information on the designation of comparable steel grades in national or regional standards is given
in Annex C.
5.2 Options
A number of options are specified in this document. These are listed below under a) to t). Additionally,
the relevant options of ISO 9328-1 apply. If the purchaser does not indicate a wish to implement any of
these options at the time of enquiry and order, the products shall be supplied in accordance with the
basic specification (shall be in accordance with ISO 9328-1):
a) tests in the simulated normalized condition (see 6.2.2);
b) products delivered untreated (see 6.2.4 and 6.2.5);
c) maximum carbon-equivalent value for P235GH, P265GH, P295GH and P355GH (see 6.3.3);
d) specification of an impact energy value of 40 J (see Table A.2, footnote h);
e) test on simulated heat-treated samples (see 6.7.2);
f) hydrogen-induced cracking (HIC) test in accordance with Annex G (see 6.10);
g) step cooling test in accordance with Annex H (see 6.11);
h) mid-thickness test pieces for the impact test and/or tensile test (see Clause 8);
i) lower copper content and maximum tin content (see Table A.1, footnote b);
j) minimum chromium content of 0,80 % (see Table A.1, footnote f );
k) maximum carbon content of 0,17 % for nominal thicknesses greater than 150 mm (see Table A.1,
footnote g);
l) maximum contents of Al (≤ 0,020 %), Ti (≤ 0,01 %) and Zr (≤ 0,01 %) (see Table A.1, footnote i);
m) mechanical properties for nominal thicknesses > 250 mm (see Table A.2, footnote a);
n) specification of the delivery condition +QT where the usual delivery condition is +NT (see Table A.2,
footnote c and Table A.3, footnote c);
o) additional impact energy values (see Table A.2, footnote i);
p) 0,2 % proof strength (Rp0,2) values at elevated temperature for increased nominal thicknesses (see
Table A.3, footnote b);
q) increased carbon content for grades PT410GH, PT450GH and PT480GH (see Table B.1, footnote c);
r) Al additions not permitted (see Table B.1, footnote d);
s) specification of the delivery condition +NT for the grade 14CrMo9-10 and of the delivery condition
+QT for the grades 14CrMoV9-10 and 13CrMoV12-10 (see Table B.2, footnote j);
t) requirement for impact tests and values (see Table B.2, footnote i).
6 Requirements
6.2.1 Unless otherwise agreed at the time of enquiry and order, the products covered by this document
shall be supplied in the usual conditions given in Tables A.2 and B.2.
6.2.2 Normalizing may, at the discretion of the manufacturer, be replaced with normalizing rolling for
the steel grades P235GH, P265GH, P295GH, P355GH and 16Mo3 (see Annex A). In this case, additional
tests in the simulated normalized condition with an agreed frequency of testing may be agreed upon
at the time of enquiry and order to verify that the obtained properties also comply with the standard
requirements (see 5.2, Option 1).
6.2.3 For products made of steel grades PT410GH, PT450GH, PT480GH, 19MnMo4-5, 19MnMo5-5 and
19MnMoNi5-5 (see Table B.2), the requested delivery condition normalized (+N) or untreated (+AR) (but
see 6.2.5) or, where applicable, quenched and tempered (+QT) shall be specified at the time of enquiry
and order.
6.2.4 If so agreed at the time of enquiry and order, products made of steel grades P235GH, P265GH,
P295GH, P355GH and 16Mo3 (see Table A.2) may also be delivered in the untreated condition (but see
6.2.5). Products made of one of the other alloy grades may be supplied in the tempered or normalized
condition or in the untreated condition, if so agreed.
The plates delivered in untreated conditions shall be appropriately marked (+AR) to denote that heat
treatment has not been performed. Steel grades containing more than 2 % Cr (inclusive) shall be
supplied in a stress relieved condition as a minimum.
NOTE Annex D contains heat treatment information for the purchaser.
6.2.5 For products delivered untreated in accordance with 6.2.3 and 6.2.4, testing shall be carried out
by the processor on test pieces in usual delivery condition as indicated in Tables A.2 and B.2.
NOTE Tests in a simulated heat-treated condition are made to verify the suitability of the delivered product
in the delivery condition +N, or +NT or +QT, as appropriate. However, they do not discharge the processor from
the obligation of providing proof of the specified properties in the finished product when adequately heat treated.
6.3.1 The requirements of Tables A.1 and B.1 shall apply for the chemical composition according to the
cast (heat) analysis.
6.3.2 The product analysis shall not deviate from the values for the cast (heat) analysis specified in
Tables A.1 and B.1 by more than the values given in Table 1.
6.3.3 A maximum value for the carbon equivalent may be agreed upon at the time of enquiry and order
for steel grades P235GH, P265GH, P295GH and P355GH (see Annex A) and PT410GH, PT450GH and
PT480GH (see Annex B). In this case, Formula (1) shall apply for calculation of the carbon-equivalent
value (CEV):
Mn Cr + Mo + V Ni + Cu
CEV = C + + + (1)
6 5 15
Table 1 — Permissible product analysis tolerances on the limiting values given in Tables A.1
and B.1 for the cast (heat) analysis
Specified value in the cast (heat)
Permissible deviation
analysis according to
Element of the product analysisa
Tables A.1 and B.1
% by mass % by mass
Cb ≤ 0,31 ±0,02
≤ 0,35 ±0,05
Si
> 0,35 to ≤ 1,00 ±0,06
≤ 1,00 ±0,05
Mn
> 1,00 to ≤ 1,70 ±0,10
≤ 0,015 +0,003
Pb
> 0,015 to ≤ 0,030 +0,005
Sb ≤ 0,010 +0,003
Al ≥ 0,010 ±0,005
B ≤ 0,003 +0,000 5
Ca ≤ 0,015 +0,003
≤ 0,020 +0,002
N
> 0,020 to ≤ 0,070 ±0,005
≤ 2,00 ±0,05
Cr
> 2,00 to ≤ 10,00 ±0,10
≤ 0,30 ±0,05
Cu
> 0,30 to ≤ 0,80 ±0,10
≤ 0,35 ±0,03
Mo
> 0,35 to ≤ 1,10 +0,04
Nb ≤ 0,10 ±0,01
≤ 0,30 +0,05
Ni
> 0,30 to ≤ 1,30 ±0,10
a If several product analyses are carried out on one cast, and the contents of an individual element determined lie
outside the permissible range of the chemical composition specified for the cast analysis, then it is only allowed to exceed
the permissible maximum value or fall short of the permissible minimum value, but not both for one cast.
b In the case of steel grades specified in Annex B, the maximum values listed in Table B.1 also apply for the product
analysis, except that Boron shall be 0,001 5 % for PT410GH, PT450GH, PT480GH, 19MnMo4-5, 19MnMo5-5, 19MnMo6-5,
19MnMoNi5-5, 19MnMoNi6-5 and 0,003 % for 14CrMoV9-10.
Table 1 (continued)
Specified value in the cast (heat)
Permissible deviation
analysis according to
Element of the product analysisa
Tables A.1 and B.1
% by mass % by mass
Cr+Cu+Mo+Ni ≤ 1,00 +0,05
Ti ≤ 0,035 ±0,01
≤ 0,05 ±0,01
V
> 0,05 to ≤ 0,30 ±0,03
a If several product analyses are carried out on one cast, and the contents of an individual element determined lie
outside the permissible range of the chemical composition specified for the cast analysis, then it is only allowed to exceed
the permissible maximum value or fall short of the permissible minimum value, but not both for one cast.
b In the case of steel grades specified in Annex B, the maximum values listed in Table B.1 also apply for the product
analysis, except that Boron shall be 0,001 5 % for PT410GH, PT450GH, PT480GH, 19MnMo4-5, 19MnMo5-5, 19MnMo6-5,
19MnMoNi5-5, 19MnMoNi6-5 and 0,003 % for 14CrMoV9-10.
6.4.1 The values given in Tables A.2, A.3 and B.2 (see also ISO 9328-1) shall apply.
6.4.2 Annex F gives, for the grades in Annex A, mean values as preliminary data for the purchaser on
the strength for 1 % (plastic) creep strain and creep rupture.
6.7 Weldability
6.7.1 The steel grades specified in this document shall be suitable for welding processes in current use
(see also the Note to 6.7.2).
6.7.2 Information on welding can be found in appropriate documents, e.g. EN 1011-1 and EN 1011-2
or IIS/IIW 382‑71.
Excessive post-weld heat treatment (PWHT) conditions can decrease the mechanical properties. When
in stress relieving, the intended time-temperature parameter shown by Formula (2):
P = Ts ( 20 + lg t ) × 10 −3 (2)
where
Where appropriate, tests on simulated heat-treated samples may be agreed at the time of enquiry and
order to check whether, after such a treatment, the properties specified in this document can still be
regarded as valid (see 5.2, Option 5).
7 Inspection
8 Sampling
Shall be in accordance with ISO 9328-1.
For an impact test (and/or the tensile test), that deviates from ISO 9328-1:2018, Table 3, footnote e, test
pieces taken from the mid-thickness may be agreed upon at the time of enquiry and order. In this case,
test temperatures and minimum impact energy values shall also be agreed upon.
9 Test methods
9.2 For the steel grades specified in Annex B, the impact test shall only be carried out if so agreed at
the time of enquiry and order. Requirements and test conditions shall then also be agreed (see Table B.2,
footnote l).
10 Marking
Shall be in accordance with ISO 9328-1.
Annex A
(normative)
16Mo3
0,12 to
≤ 0,35 0,40 to 0,90 0,025 0,010 e ≤ 0,012 ≤ 0,30 ≤ 0,30
0,25
— ≤ 0,30 — — —
0,20 to 0,35
18MnMo4-5 ≤ 0,20 ≤ 0,40 0,90 to 1,50 0,015 0,005 e ≤ 0,012 ≤ 0,30 ≤ 0,30
0,45
— ≤ 0,30 — — —
to 0,60
20MnMoNi4-5
0,15 to
≤ 0,40
1,00 to
0,020 0,010 e ≤ 0,012 ≤ 0,20 ≤ 0,20
0,45
—
0,40
— ≤ 0,02 —
0,23 1,50 to 0,60 to 0,80
15NiCuM- 0,25 0,80 to 0,50 0,25 0,015 1,00
≤ 0,17 0,025 0,010 ≥ 0,015 ≤ 0,020 ≤ 0,30 — — —
oNb5-6-4 to 0,50 1,20 to 0,80 to 0,50 to 0,045 to 1,30
13CrMo4-5
0,08 to
≤ 0,35
0,40 to
0,025 0,010 e ≤ 0,012
0,70f
≤ 0,30
0,40
— — — — —
0,18 1,00 to 1,15 to 0,60
a Elements not listed in this table shall not be intentionally added to the steel without the agreement of the purchaser, except for finishing the cast. All appropriate measures
shall be taken to prevent the addition from scrap or other materials used in steelmaking of these elements which may affect the mechanical properties and usability.
b A lower maximum copper content and/or a maximum sum of copper and tin content, e.g. (Cu + 6Sn) ≤ 0,33 %, may be agreed upon at the time of enquiry and order, e.g. with
regard to hot formability for the grades where only a maximum copper content is specified.
c For nominal thicknesses < 6 mm, a minimum manganese content of 0,20 % lower than specified is permitted.
d A ratio Al:N ≥ 2 shall apply.
e The Al content of the cast shall be determined and given in the inspection document.
f If resistance to pressurized hydrogen is of importance, a minimum content of 0,80 % Cr may be agreed upon at the time of enquiry and order.
g For nominal thicknesses greater than 150 mm, a maximum content of 0,17 % C may be agreed upon at the time of enquiry and order.
h This grade may be produced with additions of either Ti + B or Nb + Ca. The following minimum contents shall apply: Ti ≥ 0,015 % and B ≥ 0,001 % in the case of additions of
Ti + B; Nb ≥ 0,015 % and Ca ≥ 0,000 5 % in the case of additions of Nb + Ca.
i If so agreed at the time of enquiry and order, the Al content shall be ≤ 0,020 %, the Ti content shall be ≤ 0,01 %, and a Zr content of ≤ 0,01 % is specified.
ISO 9328-2:2018(E)
9
Table A.1 (continued)
10
Steel grade C Si Mn P S Altotal N Cr Mo Nb Ni Ti V Others
% by massa
Cub
max. max. max.
0,60c
P235GH ≤ 0,16 ≤ 0,35 0,025 0,010 ≥ 0,020d ≤ 0,012d ≤ 0,30 ≤ 0,30 ≤ 0,08 ≤ 0,020 ≤ 0,30 0,03 ≤ 0,02 —
to 1,20
ISO 9328-2:2018(E)
13CrMoSi5-5 ≤ 0,17
0,50 0,40 to
0,015 0,005 e ≤ 0,012
1,00
≤ 0,30
0,45
— ≤ 0,30 — — —
to 0,80 0,65 to 1,50 to 0,65
10CrMo9-10
0,08 to
≤ 0,50
0,40 to
0,020 0,010 e ≤ 0,012
2,00
≤ 0,30
0,90
— — — — —
0,14g 0,80 to 2,50 to 1,10
X12CrMo5
0,10 to
≤ 0,50
0,30 to
0,020 0,005 e ≤ 0,012
4,00
≤ 0,30
0,45
— ≤ 0,30 — — —
0,15 0,60 to 6,00 to 0,65
≤ 0,002
e
0,11 to 0,30 to 2,00 0,90 0,25
13CrMoV9-10 ≤ 0,10 0,015 0,005 — ≤ 0,20 ≤ 0,07 ≤ 0,25 0,03 B ≤ 0,015
0,15 0,60 to 2,50 to 1,10 to 0,35
Ca
≤ 0,003
12CrMoV12-10
0,10 to
≤ 0,15
0,30 to
0,015 0,005 e ≤ 0,012
2,75
≤ 0,25
0,90
≤ 0,07h ≤ 0,25 0,03h
0,20
Bh ≤ 0,015
0,15 0,60 to 3,25 to 1,10 to 0,30
Cah
X10CrMoVNb9-1
0,08 to
≤ 0,50
0,30 to
0,020 0,005 ≤ 0,040i
0,030 8,00
≤ 0,30
0,85 0,06
≤ 0,30 i 0,18
—
0,12 0,60 to 0,070 to 9,50 to 1,05 to 0,10 to 0,25
a Elements not listed in this table shall not be intentionally added to the steel without the agreement of the purchaser, except for finishing the cast. All appropriate measures
shall be taken to prevent the addition from scrap or other materials used in steelmaking of these elements which may affect the mechanical properties and usability.
b A lower maximum copper content and/or a maximum sum of copper and tin content, e.g. (Cu + 6Sn) ≤ 0,33 %, may be agreed upon at the time of enquiry and order, e.g. with
regard to hot formability for the grades where only a maximum copper content is specified.
c For nominal thicknesses < 6 mm, a minimum manganese content of 0,20 % lower than specified is permitted.
d A ratio Al:N ≥ 2 shall apply.
e The Al content of the cast shall be determined and given in the inspection document.
f If resistance to pressurized hydrogen is of importance, a minimum content of 0,80 % Cr may be agreed upon at the time of enquiry and order.
g For nominal thicknesses greater than 150 mm, a maximum content of 0,17 % C may be agreed upon at the time of enquiry and order.
h This grade may be produced with additions of either Ti + B or Nb + Ca. The following minimum contents shall apply: Ti ≥ 0,015 % and B ≥ 0,001 % in the case of additions of
Ti + B; Nb ≥ 0,015 % and Ca ≥ 0,000 5 % in the case of additions of Nb + Ca.
i
Table A.3 — Minimum values for the 0,2 % proof strength at elevated temperaturesa
Nominal Minimum 0,2 % proof strength, Rp0,2
thicknessb,c MPaf
Steel grade t at a temperature in °C of
mm 50 100 150 200 250 300 350 400 450 500
≤ 16 227 214 198 182 167 153 142 133 — —
16 < t ≤ 40 218 205 190 174 160 147 136 128 — —
40 < t ≤ 60 208 196 181 167 153 140 130 122 — —
P235GHd
60 < t ≤ 100 193 182 169 155 142 130 121 114 — —
100 < t ≤ 150 179 168 156 143 131 121 112 105 — —
150 < t ≤ 250 164 155 143 132 121 111 103 97 — —
≤ 16 256 241 223 205 188 173 160 150 — —
16 < t ≤ 40 247 232 215 197 181 166 154 145 — —
40 < t ≤ 60 237 223 206 190 174 160 148 139 — —
P265GHd
60 < t ≤ 100 208 196 181 167 153 140 130 122 — —
100 < t ≤ 150 193 182 169 155 142 130 121 114 — —
150 < t ≤ 250 179 168 156 143 131 121 112 105 — —
≤ 16 285 268 249 228 209 192 178 167 — —
16 < t ≤ 40 280 264 244 225 206 189 175 165 — —
40 < t ≤ 60 276 259 240 221 202 186 172 162 — —
P295GHd
60 < t ≤ 100 251 237 219 201 184 170 157 148 — —
100 < t ≤ 150 227 214 198 182 167 153 142 133 — —
150 < t ≤ 250 213 200 185 170 156 144 133 125 — —
≤ 16 343 323 299 275 252 232 214 202 — —
16 < t ≤ 40 334 314 291 267 245 225 208 196 — —
40 < t ≤ 60 324 305 282 259 238 219 202 190 — —
P355GHd
60 < t ≤ 100 305 287 265 244 224 206 190 179 — —
100 < t ≤ 150 285 268 249 228 209 192 178 167 — —
150 < t ≤ 250 271 255 236 217 199 183 169 159 — —
≤ 16 273 264 250 233 213 194 175 159 147 141
16 < t ≤ 40 268 259 245 228 209 190 172 156 145 139
40 < t ≤ 60 258 250 236 220 202 183 165 150 139 134
16Mo3
60 < t ≤ 100 238 230 218 203 186 169 153 139 129 123
100 < t ≤ 150 218 211 200 186 171 155 140 127 118 113
150 < t ≤ 250 208 202 191 178 163 148 134 121 113 108
≤ 60 330 320 315 310 295 285 265 235 215 —
18MnMo4-5e 60 < t ≤ 150 320 310 305 300 285 275 255 225 205 —
150 < t ≤ 250 310 300 295 290 275 265 245 220 200 —
a The values correspond to the lower band of the relevant trend curve determined in accordance with EN 10314 with a
confidence limit of about 98 % (2 s).
b For nominal thicknesses exceeding the specified maximum thicknesses, Rp0,2 values at elevated temperatures may be
agreed upon.
c Delivery condition as given in Table A.2 (but see footnote c to Table A.2).
d The values reflect the minimum values for furnace-normalized test pieces.
e Rp0,2 not determined in accordance with EN 10314. These are minimum values of the scatter band considered up
until now.
f 1 MPa = 1 N/mm2.
Annex B
(normative)
18
Steel grade Si Mn Altotal Cr Cu Mo Nb Ni Ti V B Others
% by massa
Cb Pb Sb
max. max. max. max. max. max.
0,40
PT410GH 0,20c ≤ 0,40 0,020 0,020 ≥ 0,020d ≤ 0,30 0,40 ≤ 0,12 0,02 ≤ 0,40 0,03 ≤ 0,03 ≤ 0,001 0 Cr+C+Mo+Ni: ≤ 1,00
ISO 9328-2:2018(E)
to 1,40
0,60
PT450GH 0,20c ≤ 0,40 0,020 0,020 ≥ 0,020d ≤ 0,30 0,40 ≤ 0,12 0,02 ≤ 0,40 0,03 ≤ 0,03 ≤ 0,001 0 Cr+C+Mo+Ni: ≤ 1,00
to 1,60
0,60
PT480GH 0,20c ≤ 0,55 0,020 0,020 ≥ 0,020d ≤ 0,30 0,40 ≤ 0,12 0,02 ≤ 0,40 0,03 ≤ 0,03 ≤ 0,001 0 Cr+C+Mo+Ni: ≤ 1,00
to 1,60
0,95 0,45
19MnMo4-5 0,25 ≤ 0,40 0,020 0,020 — ≤ 0,30 0,40 0,02 ≤ 0,40 0,03 ≤ 0,03 ≤ 0,001 0 —
to 1,30 to 0,60
0,95 0,45
19MnMo5-5 0,25 ≤ 0,40 0,020 0,020 — ≤ 0,30 0,40 0,02 ≤ 0,40 0,03 ≤ 0,03 ≤ 0,001 0 —
to 1,50 to 0,60
1,15 0,45
19MnMo6-5 0,25 ≤ 0,40 0,020 0,020 — ≤ 0,30 0,40 0,02 ≤ 0,40 0,03 ≤ 0,03 ≤ 0,001 0 —
to 1,50 to 0,60
0,95 0,45 0,40
19MnMoNi5-5 0,25 ≤ 0,40 0,020 0,020 — ≤ 0,30 0,40 0,02 0,03 ≤ 0,02 ≤ 0,001 0 —
to 1,50 to 0,60 to 0,70
1,15 0,45 0,40
19MnMoNi6-5 0,25 ≤ 0,40 0,020 0,020 — ≤ 0,20 0,40 0,02 0,03 ≤ 0,02 ≤ 0,001 0 —
to 1,50 to 0,60 to 0,70
0,40 0,80 0,45
14CrMo4-5e 0,17 ≤ 0,40 0,020 0,020 — 0,40 0,02 ≤ 0,40 0,03 ≤ 0,03 — —
to 0,65 to 1,15 to 0,65
0,50 0,40 1,00 0,45
14CrMoSi5-6e 0,17 0,020 0,020 — 0,40 0,02 ≤ 0,40 0,03 ≤ 0,03 — —
to 0,80 to 0,65 to 1,50 to 0,60
0,30 2,00 0,90
13CrMo9-10e 0,17 ≤ 0,50 0,020 0,020 — 0,40 0,02 ≤ 0,40 0,03 ≤ 0,03 — —
to 0,60 to 2,50 to 1,10
a Elements not listed in this table shall not intentionally be added to the steel without agreement of the purchaser, except for finishing the cast. All appropriate measures shall
be taken to prevent the addition from scrap or other materials used in steelmaking of these elements which may affect the mechanical properties and usability.
b The maximum values also apply to the product analysis.
c By agreement at the time of enquiry and order, the maximum carbon content may be increased up to 0,31 % in the case of PT410GH, 0,33 % in the case of PT450GH
and 0,35 % in the case of PT480GH.
d On cast analysis, the aluminium content shall not be less than 0,020 % total aluminium or, alternately, 0,015 % acid soluble aluminium. If so agreed at the time of enquiry and
order, aluminium shall not be used in order to restrain graphitization.
e See Table B.2 for complete steel names.
and 0,35 % in the case of PT480GH.
d On cast analysis, the aluminium content shall not be less than 0,020 % total aluminium or, alternately, 0,015 % acid soluble aluminium. If so agreed at the time of enquiry and
order, aluminium shall not be used in order to restrain graphitization.
e See Table B.2 for complete steel names.
f REM: Rare earth metals.
ISO 9328-2:2018(E)
19
ISO 9328-2:2018(E)
6 ≤ t ≤ 50
19MnMoNi6-5 +QTf 480 620 to 790 15
50 ≤ t ≤ 200
14CrMo4-5+NT1 +NTg 6 ≤ t ≤ 200 225 380 to 550 20
14CrMo4-5+NT2 +Nt g 6 ≤ t ≤ 200 275 450 to 590 20
14CrMoSi5-6+NT1 +Ng 6 ≤ t ≤ 200 235 410 to 590 20
14CrMoSi5-6+NT2 +NTg 6 ≤ t ≤ 200 315 520 to 690 20
13CrMo9-10+NT1 +NTg 6 ≤ t ≤ 300 205 410 to 590 17
13CrMo9-10+NT2 +NTg 6 ≤ t ≤ 300 315 520 to 690 17
14CrMo9-10 +QT h (+NTi)j 6 ≤ t ≤ 300 380 580 to 760 17
14CrMoV9-10 +NTi (+QTg)j 6 ≤ t ≤ 300 415 580 to 760 17
Annex C
(informative)
Table C.1 — Steel designations in accordance with this document a and designation of
comparableb steel grades in national or regional standards
Steel designation in
ASTM A302, A387, A515, JIS G3103, G3118, G3119,
ISO 9328‑2 EN 10028‑2c
A516, A533, A542, A832 G3120, G4109
P235GH 1.0345
P265GH 1.0425
P295GH 1.0481
P355GH 1.0473
PT410GH A515-60, A516-60 SB410, SGV410
PT450GH A515-65, A516-65 SB450, SGV450
PT480GH A515-70, A516-70 SB480, SGV480
16Mo3 1.5415
18MnMo4-5 1.5414
19MnMo4-5 A302A SBV1A
19MnMo5-5 A302B, A533A1 SBV1B, SQV1A
19MnMo6-5 A533A2 SQV1B
20MnMoNi4-5 1.6311
19MnMoNi5-5 A302C, A533B1 SBV2, SQV2A
19MnMoNi6-5 A533B2 SQV2B
15NiCuMoNb5-6-4 1.6368
13CrMo4-5 1.7335
14CrMo4-5+NT1 A387-12-1 SCMV2-1
14CrMo4-5+NT2 A387-12-2 SCMV2-2
13CrMoSi5-5 1.7336
14CrMoSi5-6+NT1 A387-11-1 SCMV3-1
14CrMoSi5-6+NT2 A387-11-2 SCMV3-2
10CrMo9-10 1.7380
12CrMo9-10 1.7375
13CrMo9-10+NT1 A387-22-1 SCMV4-1
13CrMo9-10+NT2 A387-22-2 SCMV4-2
14CrMo9-10 A542B4 SCMQ4E
X12CrMo5 1.7362
a In accordance with ISO/TS 4949.
b “Comparable” covers both identical or similar steel grades.
c In addition to the steel name (identical to the corresponding steel name used in this document), the listed steel number
is specified.
Annex D
(informative)
Tables D.1 and D.2 give reference data for heat treatment temperatures. For stress relief annealing, see
Annex E.
NOTE In addition to the temperature, there are other parameters, such as type of heating, heating rate,
holding time and cooling method which have to be taken into account.
Annex E
(informative)
Examples for stress relieving temperatures and the corresponding maximum holding time calculated
on the basis of the equation in 6.7 for a given critical time-temperature parameter Pcrit. are given in
Table E.1.
Table E.1 — Pcrit. value and permissible holding time for a given stress relieving temperature
Pcrit. condition fulfilled with stress reliev-
Steel type ing temperature in °C for a holding timea of
Pcrit.
or steel grade
1h 2h
C, CMn steels 17,3 580 575
16Mo3 17,5 590 585
18MnMo4-5 17,5 590 585
20MnMoNi4-5 17,5 590 585
15NiCuMoNb5-6-4 17,5 590 585
13CrMo4-5 18,5 640 630
13CrMoSi5-5 18,7 650 640
10CrMo9-10 19,2 675 665
12CrMo9-10 19,3 680 670
X12CrMo5 19,5 690 680
13CrMoV9-10 19,4 685 675
12CrMoV12-10 19,4 685 675
X10CrMoVNb9-1 20,5 740 730
a Selected pairs of stress relieving temperature and holding time for guidance.
Annex F
(informative)
NOTE The values given in Table F.1 have been derived as mean values in accordance with ISO 6303 with a
scatter band of ±20 %.
The strength values for 1 % (plastic) creep strain and creep rupture given up to the elevated
temperatures listed in Table F.1 do not mean that the steels can be used in continuous duty up to
these temperatures. The governing factor is the total stressing during operation. Where relevant, the
oxidation conditions should also be taken into account.
Table F.1 — Strength for 1 % (plastic) creep strain and creep rupture
Tempera- Strength for 1 % (plastic)
Creep rupture strength in MPa for
Steel grade ture creep strain in MPa for
°C 10 000 h 100 000 h 10 000 h 100 000 h 200 000 h
380 164 118 229 165 145
390 150 106 211 148 129
400 136 95 191 132 115
410 124 84 174 118 101
420 113 73 158 103 89
P235GH,
430 101 65 142 91 78
P265GH
440 91 57 127 79 67
450 80 49 113 69 57
460 72 42 100 59 48
470 62 35 86 50 40
480 53 30 75 42 33
380 195 153 291 227 206
390 182 137 266 203 181
400 167 118 243 179 157
410 150 105 221 157 135
420 135 92 200 136 115
430 120 80 180 117 97
P295GH,
440 107 69 161 100 82
P355GH
450 93 59 143 85 70
460 83 51 126 73 60
470 71 44 110 63 52
480 63 38 96 55 44
490 55 33 84 47 37
500 49 29 74 41 30
Annex G
(informative)
G.1 If agreed at the time of enquiry and order, a test to evaluate the resistance of steel products to
hydrogen-induced cracking shall be performed.
G.2 The test procedure specified in EN 10229 or another appropriate procedure with specified
acceptance criteria (e.g. in accordance with NACE TM0284) shall be applied.
G.3 The procedure to be applied, the test solution, the frequency of testing and the corresponding
acceptance criteria shall be agreed upon at the time of enquiry and order.
In the case of the procedure specified in EN 10229, the acceptance criteria for the test solution A (with
pH ≈ 3) apply for the classes indicated in Table G.1 where the given values are minimum average values
from all tested cross sections from one plate.
Table G.1 — Acceptance classes for the HIC test (test solution A)
CLR a CTR a CSR a
Acceptance class
% % %
I ≤5 ≤ 1,5 ≤ 0,5
II ≤ 10 ≤3 ≤1
III ≤ 15 ≤5 ≤2
a CLR: crack length ratio, CTR: crack thickness ratio, CSR: crack sensitivity ratio.
Annex H
(informative)
For the step cooling test, a procedure to check step cooling embrittlement shall be agreed. This
procedure shall include temperatures, T, and holding times, t, to be considered. The procedure given in
Figure H.1 is recommended.
Bibliography