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INTERNATIONAL ISO

STANDARD 9328-2

Fourth edition
2018-02

Steel flat products for pressure


purposes — Technical delivery
conditions —
Part 2:
Non-alloy and alloy steels with
specified elevated temperature
properties
Produits plats en acier pour service sous pression — Conditions
techniques de livraison —
Partie 2: Aciers non alliés et aciers alliés avec caractéristiques
spécifiées à température élevée

Reference number
ISO 9328-2:2018(E)

© ISO 2018
ISO 9328-2:2018(E)


COPYRIGHT PROTECTED DOCUMENT


© ISO 2018
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
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Published in Switzerland

ii  © ISO 2018 – All rights reserved


ISO 9328-2:2018(E)


Contents Page

Foreword......................................................................................................................................................................................................................................... iv
1 Scope.................................................................................................................................................................................................................................. 1
2 Normative references....................................................................................................................................................................................... 1
3 Terms and definitions...................................................................................................................................................................................... 1
4 Classification and designation................................................................................................................................................................ 1
4.1 Classification.............................................................................................................................................................................................. 1
4.2 Designation................................................................................................................................................................................................. 2
5 Information to be supplied by the purchaser......................................................................................................................... 2
5.1 Mandatory information.................................................................................................................................................................... 2
5.2 Options............................................................................................................................................................................................................ 2
5.3 Example for ordering.......................................................................................................................................................................... 3
6 Requirements........................................................................................................................................................................................................... 3
6.1 Steelmaking process............................................................................................................................................................................ 3
6.2 Delivery condition................................................................................................................................................................................. 3
6.3 Chemical composition....................................................................................................................................................................... 4
6.4 Mechanical properties....................................................................................................................................................................... 5
6.5 Surface condition................................................................................................................................................................................... 5
6.6 Internal soundness............................................................................................................................................................................... 5
6.7 Weldability................................................................................................................................................................................................... 5
6.8 Dimensions and tolerances on dimensions..................................................................................................................... 6
6.9 Calculation of mass............................................................................................................................................................................... 6
6.10 Resistance to hydrogen-induced cracking....................................................................................................................... 6
6.11 Embrittlement of CrMo steels..................................................................................................................................................... 6
7 Inspection..................................................................................................................................................................................................................... 6
7.1 Types of inspection and inspection documents.......................................................................................................... 6
7.2 Tests to be carried out....................................................................................................................................................................... 6
7.3 Retests, sorting and reprocessing............................................................................................................................................ 6
8 Sampling......................................................................................................................................................................................................................... 6
9 Test methods.............................................................................................................................................................................................................. 6
10 Marking........................................................................................................................................................................................................................... 7
Annex A (normative) Chemical composition and mechanical properties of products based
on European standards................................................................................................................................................................................... 8
Annex B (normative) Chemical composition and mechanical properties of products based
on ASTM/ASME or JIS standards........................................................................................................................................................17
Annex C (informative) Steel designations in accordance with this document and
designation of comparable steel grades in national or regional standards.........................................22
Annex D (informative) Guidelines for heat treatment.....................................................................................................................24
Annex E (informative) Critical time-temperature parameter Pcrit. and possible
combinations of stress relieving temperature and holding time....................................................................26
Annex F (informative) Reference data relating to strength for 1 % (plastic) creep strain and
creep rupture.........................................................................................................................................................................................................27
Annex G (informative) Evaluation of resistance to hydrogen-induced cracking..................................................33
Annex H (informative) Step cooling test.........................................................................................................................................................34
Bibliography.............................................................................................................................................................................................................................. 35

© ISO 2018 – All rights reserved  iii


ISO 9328-2:2018(E)


Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www​.iso​.org/​directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www​.iso​.org/​patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation on the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO's adherence to the
World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT) see the following
URL: www​.iso​.org/​iso/​foreword​.html.
This document was prepared by Technical Committee ISO/TC 17, Steel, Subcommittee SC 10, Steel for
pressure purposes.
This fourth edition cancels and replaces the third edition (ISO 9328-2:2011), which has been technically
revised. The following changes have been made:
— the term “product thickness” has been replaced with “nominal thickness”;
— normalizing rolling is also considered for steel grade 16Mo3 (see Annex A);
— the technical data in Annex A have been aligned with EN 10028-2;
— in Table B.1, “B ≤ 0,001 0” has been added and the specifications of “P” and “S” have been changed.
A list of all the parts in the ISO 9328 series can be found on the ISO website.

iv  © ISO 2018 – All rights reserved


INTERNATIONAL STANDARD ISO 9328-2:2018(E)

Steel flat products for pressure purposes — Technical


delivery conditions —
Part 2:
Non-alloy and alloy steels with specified elevated
temperature properties

1 Scope
This document specifies the technical delivery conditions for plates and strip for pressure equipment
made of non-alloy and alloy steels as specified in Tables A.1 and B.1. The requirements and definitions
of ISO 9328-1 also apply to this document.

2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
ISO 4948-1, Steels — Classification — Part 1: Classification of steels into unalloyed and alloy steels based
on chemical composition
ISO 4948-2, Steels — Classification — Part 2: Classification of unalloyed and alloy steels according to main
quality classes and main property or application characteristics
ISO 9328-1:2018, Steel flat products for pressure purposes — Technical delivery conditions — Part 1:
General requirements

3 Terms and definitions


For the purposes of this document, the terms and definitions given in ISO 9328-1 apply.
ISO and IEC maintain terminological databases for use in standardization at the following addresses:
— IEC Electropedia: available at http://​w ww​.electropedia​.org/​
— ISO Online browsing platform: available at https://​w ww​.iso​.org/​obp

4 Classification and designation

4.1 Classification
In accordance with ISO 4948-1 and ISO 4948-2, the steel grades P235GH, P265GH, P295GH and P355GH
(see Annex A) and PT410GH, PT450GH and PT480GH (see Annex B) are non-alloy-quality steels. All
other grades are alloyed special steels.

© ISO 2018 – All rights reserved  1


ISO 9328-2:2018(E)


4.2 Designation
Shall be in accordance with ISO 9328-1.
NOTE 1 Non-alloy grades in Annex A are classified in accordance with their yield strength, non-alloy grades in
Annex B are classified in accordance with their tensile strength.

NOTE 2 Information on the designation of comparable steel grades in national or regional standards is given
in Annex C.

5 Information to be supplied by the purchaser

5.1 Mandatory information


Shall be in accordance with ISO 9328-1 and 6.2.3.

5.2 Options
A number of options are specified in this document. These are listed below under a) to t). Additionally,
the relevant options of ISO 9328-1 apply. If the purchaser does not indicate a wish to implement any of
these options at the time of enquiry and order, the products shall be supplied in accordance with the
basic specification (shall be in accordance with ISO 9328-1):
a) tests in the simulated normalized condition (see 6.2.2);
b) products delivered untreated (see 6.2.4 and 6.2.5);
c) maximum carbon-equivalent value for P235GH, P265GH, P295GH and P355GH (see 6.3.3);
d) specification of an impact energy value of 40 J (see Table A.2, footnote h);
e) test on simulated heat-treated samples (see 6.7.2);
f) hydrogen-induced cracking (HIC) test in accordance with Annex G (see 6.10);
g) step cooling test in accordance with Annex H (see 6.11);
h) mid-thickness test pieces for the impact test and/or tensile test (see Clause 8);
i) lower copper content and maximum tin content (see Table A.1, footnote b);
j) minimum chromium content of 0,80 % (see Table A.1, footnote f );
k) maximum carbon content of 0,17 % for nominal thicknesses greater than 150 mm (see Table A.1,
footnote g);
l) maximum contents of Al (≤ 0,020 %), Ti (≤ 0,01 %) and Zr (≤ 0,01 %) (see Table A.1, footnote i);
m) mechanical properties for nominal thicknesses > 250 mm (see Table A.2, footnote a);
n) specification of the delivery condition +QT where the usual delivery condition is +NT (see Table A.2,
footnote c and Table A.3, footnote c);
o) additional impact energy values (see Table A.2, footnote i);
p) 0,2 % proof strength (Rp0,2) values at elevated temperature for increased nominal thicknesses (see
Table A.3, footnote b);
q) increased carbon content for grades PT410GH, PT450GH and PT480GH (see Table B.1, footnote c);
r) Al additions not permitted (see Table B.1, footnote d);

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ISO 9328-2:2018(E)


s) specification of the delivery condition +NT for the grade 14CrMo9-10 and of the delivery condition
+QT for the grades 14CrMoV9-10 and 13CrMoV12-10 (see Table B.2, footnote j);
t) requirement for impact tests and values (see Table B.2, footnote i).

5.3 Example for ordering


An order of 10 plates with nominal dimensions thickness = 50 mm, width = 2 000 mm, length =
10 000 mm, made of a steel grade with the name 16Mo3 as specified in this document, with inspection
certificate 3.1 as specified in ISO 10474, is designated as follows:
10 plates – 50 × 2 000 × 10 000 – ISO 9328‑2 16Mo3 – Inspection certificate 3.1

6 Requirements

6.1 Steelmaking process


Shall be in accordance with ISO 9328-1.

6.2 Delivery condition

6.2.1 Unless otherwise agreed at the time of enquiry and order, the products covered by this document
shall be supplied in the usual conditions given in Tables A.2 and B.2.

6.2.2 Normalizing may, at the discretion of the manufacturer, be replaced with normalizing rolling for
the steel grades P235GH, P265GH, P295GH, P355GH and 16Mo3 (see Annex A). In this case, additional
tests in the simulated normalized condition with an agreed frequency of testing may be agreed upon
at the time of enquiry and order to verify that the obtained properties also comply with the standard
requirements (see 5.2, Option 1).

6.2.3 For products made of steel grades PT410GH, PT450GH, PT480GH, 19MnMo4-5, 19MnMo5-5 and
19MnMoNi5-5 (see Table B.2), the requested delivery condition normalized (+N) or untreated (+AR) (but
see 6.2.5) or, where applicable, quenched and tempered (+QT) shall be specified at the time of enquiry
and order.

6.2.4 If so agreed at the time of enquiry and order, products made of steel grades P235GH, P265GH,
P295GH, P355GH and 16Mo3 (see Table A.2) may also be delivered in the untreated condition (but see
6.2.5). Products made of one of the other alloy grades may be supplied in the tempered or normalized
condition or in the untreated condition, if so agreed.

The plates delivered in untreated conditions shall be appropriately marked (+AR) to denote that heat
treatment has not been performed. Steel grades containing more than 2 % Cr (inclusive) shall be
supplied in a stress relieved condition as a minimum.
NOTE Annex D contains heat treatment information for the purchaser.

6.2.5 For products delivered untreated in accordance with 6.2.3 and 6.2.4, testing shall be carried out
by the processor on test pieces in usual delivery condition as indicated in Tables A.2 and B.2.
NOTE Tests in a simulated heat-treated condition are made to verify the suitability of the delivered product
in the delivery condition +N, or +NT or +QT, as appropriate. However, they do not discharge the processor from
the obligation of providing proof of the specified properties in the finished product when adequately heat treated.

© ISO 2018 – All rights reserved  3


ISO 9328-2:2018(E)


6.3 Chemical composition

6.3.1 The requirements of Tables A.1 and B.1 shall apply for the chemical composition according to the
cast (heat) analysis.

6.3.2 The product analysis shall not deviate from the values for the cast (heat) analysis specified in
Tables A.1 and B.1 by more than the values given in Table 1.

6.3.3 A maximum value for the carbon equivalent may be agreed upon at the time of enquiry and order
for steel grades P235GH, P265GH, P295GH and P355GH (see Annex A) and PT410GH, PT450GH and
PT480GH (see Annex B). In this case, Formula (1) shall apply for calculation of the carbon-equivalent
value (CEV):

Mn Cr + Mo + V Ni + Cu
CEV = C + + + (1)
6 5 15

Table 1 — Permissible product analysis tolerances on the limiting values given in Tables A.1
and B.1 for the cast (heat) analysis
Specified value in the cast (heat)
Permissible deviation
analysis according to
Element of the product analysisa
Tables A.1 and B.1
% by mass % by mass
Cb ≤ 0,31 ±0,02
≤ 0,35 ±0,05
Si
> 0,35 to ≤ 1,00 ±0,06
≤ 1,00 ±0,05
Mn
> 1,00 to ≤ 1,70 ±0,10
≤ 0,015 +0,003
Pb
> 0,015 to ≤ 0,030 +0,005
Sb ≤ 0,010 +0,003
Al ≥ 0,010 ±0,005
B ≤ 0,003 +0,000 5
Ca ≤ 0,015 +0,003
≤ 0,020 +0,002
N
> 0,020 to ≤ 0,070 ±0,005
≤ 2,00 ±0,05
Cr
> 2,00 to ≤ 10,00 ±0,10
≤ 0,30 ±0,05
Cu
> 0,30 to ≤ 0,80 ±0,10
≤ 0,35 ±0,03
Mo
> 0,35 to ≤ 1,10 +0,04
Nb ≤ 0,10 ±0,01
≤ 0,30 +0,05
Ni
> 0,30 to ≤ 1,30 ±0,10
a If several product analyses are carried out on one cast, and the contents of an individual element determined lie
outside the permissible range of the chemical composition specified for the cast analysis, then it is only allowed to exceed
the permissible maximum value or fall short of the permissible minimum value, but not both for one cast.
b In the case of steel grades specified in Annex B, the maximum values listed in Table B.1 also apply for the product
analysis, except that Boron shall be 0,001 5 % for PT410GH, PT450GH, PT480GH, 19MnMo4-5, 19MnMo5-5, 19MnMo6-5,
19MnMoNi5-5, 19MnMoNi6-5 and 0,003 % for 14CrMoV9-10.

4  © ISO 2018 – All rights reserved


ISO 9328-2:2018(E)


Table 1 (continued)
Specified value in the cast (heat)
Permissible deviation
analysis according to
Element of the product analysisa
Tables A.1 and B.1
% by mass % by mass
Cr+Cu+Mo+Ni ≤ 1,00 +0,05
Ti ≤ 0,035 ±0,01
≤ 0,05 ±0,01
V
> 0,05 to ≤ 0,30 ±0,03
a If several product analyses are carried out on one cast, and the contents of an individual element determined lie
outside the permissible range of the chemical composition specified for the cast analysis, then it is only allowed to exceed
the permissible maximum value or fall short of the permissible minimum value, but not both for one cast.
b In the case of steel grades specified in Annex B, the maximum values listed in Table B.1 also apply for the product
analysis, except that Boron shall be 0,001 5 % for PT410GH, PT450GH, PT480GH, 19MnMo4-5, 19MnMo5-5, 19MnMo6-5,
19MnMoNi5-5, 19MnMoNi6-5 and 0,003 % for 14CrMoV9-10.

6.4 Mechanical properties

6.4.1 The values given in Tables A.2, A.3 and B.2 (see also ISO 9328-1) shall apply.

6.4.2 Annex F gives, for the grades in Annex A, mean values as preliminary data for the purchaser on
the strength for 1 % (plastic) creep strain and creep rupture.

6.5 Surface condition


Shall be in accordance with ISO 9328-1.

6.6 Internal soundness


Shall be in accordance with ISO 9328-1.

6.7 Weldability

6.7.1 The steel grades specified in this document shall be suitable for welding processes in current use
(see also the Note to 6.7.2).

6.7.2 Information on welding can be found in appropriate documents, e.g. EN 1011-1 and EN 1011-2
or IIS/IIW 382‑71.

Excessive post-weld heat treatment (PWHT) conditions can decrease the mechanical properties. When
in stress relieving, the intended time-temperature parameter shown by Formula (2):

P = Ts ( 20 + lg t ) × 10 −3 (2)

where

Ts is the stress relieving temperature, in kelvins;

t is the holding time, in hours.


exceeds the critical (Pcrit .) values in Annex E, or where regarded as necessary in the case of Annex B
steel grades, the purchaser should, in his enquiry and order, inform the manufacturer accordingly.

© ISO 2018 – All rights reserved  5


ISO 9328-2:2018(E)


Where appropriate, tests on simulated heat-treated samples may be agreed at the time of enquiry and
order to check whether, after such a treatment, the properties specified in this document can still be
regarded as valid (see 5.2, Option 5).

6.8 Dimensions and tolerances on dimensions


Shall be in accordance with ISO 9328-1.

6.9 Calculation of mass


Shall be in accordance with ISO 9328-1.

6.10 Resistance to hydrogen-induced cracking


Since carbon and low-alloy steels may be susceptible to cracking when exposed to corrosive H2S-
containing environments, usually referred to as “sour service”, a test to evaluate the resistance to
hydrogen-induced cracking in accordance with Annex G or another test method may be agreed at the
time of enquiry and order.

6.11 Embrittlement of CrMo steels


CrMo steels may tend to become brittle in service at temperatures between approximately 400 °C and
500 °C. This possible tendency for embrittlement can be simulated in the laboratory with the so-called
step cooling test. In this test, a specimen is exposed to a temperature-time cycle as given in Figure H.1.
The shift of a transition curve before and after the step cooling test is a measure for the embrittlement.
A step cooling test in accordance with Annex H may be agreed upon at the time of enquiry and order.
NOTE The step cooling test is primarily applicable to the weld metal and the heat-affected zone.

7 Inspection

7.1 Types of inspection and inspection documents


Shall be in accordance with ISO 9328-1.

7.2 Tests to be carried out


Shall be in accordance with ISO 9328-1 and 6.10 and 6.11.

7.3 Retests, sorting and reprocessing


Shall be in accordance with ISO 9328-1.

8 Sampling
Shall be in accordance with ISO 9328-1.
For an impact test (and/or the tensile test), that deviates from ISO 9328-1:2018, Table 3, footnote e, test
pieces taken from the mid-thickness may be agreed upon at the time of enquiry and order. In this case,
test temperatures and minimum impact energy values shall also be agreed upon.

9 Test methods

9.1 Shall be in accordance with ISO 9328-1, and Annexes D and E.

6  © ISO 2018 – All rights reserved


ISO 9328-2:2018(E)


9.2 For the steel grades specified in Annex B, the impact test shall only be carried out if so agreed at
the time of enquiry and order. Requirements and test conditions shall then also be agreed (see Table B.2,
footnote l).

10 Marking
Shall be in accordance with ISO 9328-1.

© ISO 2018 – All rights reserved  7


ISO 9328-2:2018(E)


Annex A
(normative)

Chemical composition and mechanical properties of products


based on European standards

8  © ISO 2018 – All rights reserved


Table A.1 — Chemical composition [cast (heat) analysis]

Steel grade C Si Mn P S Altotal N Cr Mo Nb Ni Ti V Others


% by massa
Cub
max. max. max.
0,60c
P235GH ≤ 0,16 ≤ 0,35 0,025 0,010 ≥ 0,020d ≤ 0,012d ≤ 0,30 ≤ 0,30 ≤ 0,08 ≤ 0,020 ≤ 0,30 0,03 ≤ 0,02 —
to 1,20
0,80 to

© ISO 2018 – All rights reserved


P265GH ≤ 0,20 ≤ 0,40 0,025 0,010 ≥ 0,020d ≤ 0,012d ≤ 0,30 ≤ 0,30 ≤ 0,08 ≤ 0,020 ≤ 0,30 0,03 ≤ 0,02
1,40
Cr+C+
0,08 to
P295GH ≤ 0,40 0,90 to 1,50 0,025 0,010 ≥ 0,020d ≤ 0,012d ≤ 0,30 ≤ 0,30 ≤ 0,08 ≤ 0,020 ≤ 0,30 0,03 ≤ 0,02 Mo+Ni:
0,20
≤ 0,70
0,10 to
P355GH ≤ 0,60 1,10 to 1,70 0,025 0,010 ≥ 0,020d ≤ 0,012d ≤ 0,30 ≤ 0,30 ≤ 0,08 ≤ 0,040 ≤ 0,30 0,03 ≤ 0,02
0,22

16Mo3
0,12 to
≤ 0,35 0,40 to 0,90 0,025 0,010 e ≤ 0,012 ≤ 0,30 ≤ 0,30
0,25
— ≤ 0,30 — — —
0,20 to 0,35

18MnMo4-5 ≤ 0,20 ≤ 0,40 0,90 to 1,50 0,015 0,005 e ≤ 0,012 ≤ 0,30 ≤ 0,30
0,45
— ≤ 0,30 — — —
to 0,60


20MnMoNi4-5
0,15 to
≤ 0,40
1,00 to
0,020 0,010 e ≤ 0,012 ≤ 0,20 ≤ 0,20
0,45

0,40
— ≤ 0,02 —
0,23 1,50 to 0,60 to 0,80
15NiCuM- 0,25 0,80 to 0,50 0,25 0,015 1,00
≤ 0,17 0,025 0,010 ≥ 0,015 ≤ 0,020 ≤ 0,30 — — —
oNb5-6-4 to 0,50 1,20 to 0,80 to 0,50 to 0,045 to 1,30

13CrMo4-5
0,08 to
≤ 0,35
0,40 to
0,025 0,010 e ≤ 0,012
0,70f
≤ 0,30
0,40
— — — — —
0,18 1,00 to 1,15 to 0,60
a Elements not listed in this table shall not be intentionally added to the steel without the agreement of the purchaser, except for finishing the cast. All appropriate measures
shall be taken to prevent the addition from scrap or other materials used in steelmaking of these elements which may affect the mechanical properties and usability.
b A lower maximum copper content and/or a maximum sum of copper and tin content, e.g. (Cu + 6Sn) ≤ 0,33 %, may be agreed upon at the time of enquiry and order, e.g. with
regard to hot formability for the grades where only a maximum copper content is specified.
c For nominal thicknesses < 6 mm, a minimum manganese content of 0,20 % lower than specified is permitted.
d A ratio Al:N ≥ 2 shall apply.
e The Al content of the cast shall be determined and given in the inspection document.
f If resistance to pressurized hydrogen is of importance, a minimum content of 0,80 % Cr may be agreed upon at the time of enquiry and order.
g For nominal thicknesses greater than 150 mm, a maximum content of 0,17 % C may be agreed upon at the time of enquiry and order.
h This grade may be produced with additions of either Ti + B or Nb + Ca. The following minimum contents shall apply: Ti ≥ 0,015 % and B ≥ 0,001 % in the case of additions of
Ti + B; Nb ≥ 0,015 % and Ca ≥ 0,000 5 % in the case of additions of Nb + Ca.
i If so agreed at the time of enquiry and order, the Al content shall be ≤ 0,020 %, the Ti content shall be ≤ 0,01 %, and a Zr content of ≤ 0,01 % is specified.
ISO 9328-2:2018(E)

9


Table A.1 (continued)

10
Steel grade C Si Mn P S Altotal N Cr Mo Nb Ni Ti V Others
% by massa
Cub
max. max. max.
0,60c
P235GH ≤ 0,16 ≤ 0,35 0,025 0,010 ≥ 0,020d ≤ 0,012d ≤ 0,30 ≤ 0,30 ≤ 0,08 ≤ 0,020 ≤ 0,30 0,03 ≤ 0,02 —
to 1,20
ISO 9328-2:2018(E)

13CrMoSi5-5 ≤ 0,17
0,50 0,40 to
0,015 0,005 e ≤ 0,012
1,00
≤ 0,30
0,45
— ≤ 0,30 — — —
to 0,80 0,65 to 1,50 to 0,65

10CrMo9-10
0,08 to
≤ 0,50
0,40 to
0,020 0,010 e ≤ 0,012
2,00
≤ 0,30
0,90
— — — — —
0,14g 0,80 to 2,50 to 1,10

0,10 to 0,30 to 0,010 2,00 0,90


12CrMo9-10 ≤ 0,30 0,015 0,010 ≤ 0,012 ≤ 0,25 — ≤ 0,30 — — —
0,15 0,80 to 0,040 to 2,50 to 1,10

X12CrMo5
0,10 to
≤ 0,50
0,30 to
0,020 0,005 e ≤ 0,012
4,00
≤ 0,30
0,45
— ≤ 0,30 — — —
0,15 0,60 to 6,00 to 0,65
≤ 0,002
e


0,11 to 0,30 to 2,00 0,90 0,25
13CrMoV9-10 ≤ 0,10 0,015 0,005 — ≤ 0,20 ≤ 0,07 ≤ 0,25 0,03 B ≤ 0,015
0,15 0,60 to 2,50 to 1,10 to 0,35
Ca
≤ 0,003
12CrMoV12-10
0,10 to
≤ 0,15
0,30 to
0,015 0,005 e ≤ 0,012
2,75
≤ 0,25
0,90
≤ 0,07h ≤ 0,25 0,03h
0,20
Bh ≤ 0,015
0,15 0,60 to 3,25 to 1,10 to 0,30
Cah

X10CrMoVNb9-1
0,08 to
≤ 0,50
0,30 to
0,020 0,005 ≤ 0,040i
0,030 8,00
≤ 0,30
0,85 0,06
≤ 0,30 i 0,18

0,12 0,60 to 0,070 to 9,50 to 1,05 to 0,10 to 0,25
a Elements not listed in this table shall not be intentionally added to the steel without the agreement of the purchaser, except for finishing the cast. All appropriate measures
shall be taken to prevent the addition from scrap or other materials used in steelmaking of these elements which may affect the mechanical properties and usability.
b A lower maximum copper content and/or a maximum sum of copper and tin content, e.g. (Cu + 6Sn) ≤ 0,33 %, may be agreed upon at the time of enquiry and order, e.g. with
regard to hot formability for the grades where only a maximum copper content is specified.
c For nominal thicknesses < 6 mm, a minimum manganese content of 0,20 % lower than specified is permitted.
d A ratio Al:N ≥ 2 shall apply.
e The Al content of the cast shall be determined and given in the inspection document.
f If resistance to pressurized hydrogen is of importance, a minimum content of 0,80 % Cr may be agreed upon at the time of enquiry and order.
g For nominal thicknesses greater than 150 mm, a maximum content of 0,17 % C may be agreed upon at the time of enquiry and order.
h This grade may be produced with additions of either Ti + B or Nb + Ca. The following minimum contents shall apply: Ti ≥ 0,015 % and B ≥ 0,001 % in the case of additions of
Ti + B; Nb ≥ 0,015 % and Ca ≥ 0,000 5 % in the case of additions of Nb + Ca.
i

© ISO 2018 – All rights reserved


If so agreed at the time of enquiry and order, the Al content shall be ≤ 0,020 %, the Ti content shall be ≤ 0,01 %, and a Zr content of ≤ 0,01 % is specified.
ISO 9328-2:2018(E)


Table A.2 — Mechanical properties (applicable to the transverse direction)a


Tensile properties
Impact energy
at room temperature
Nominal Elonga- KV
Usual thickness Yield Tensile
tion after J
Steel grade delivery strength strength
fracture min.
conditionb,c ReH Rm
t A at a temperature in °C of
mm MPag MPag % –20 0 +20
min. min.
≤ 16 235
16 < t ≤ 40 225
360 to 480
40 < t ≤ 60 215
P235GH +Nd,e 24 27h 34h 40
60 < t ≤ 100 200
100 < t ≤ 150 185 350 to 480
150 < t ≤ 250 170 340 to 480
≤ 16 265
16 < t ≤ 40 255
410 to 530
40 < t ≤ 60 245
P265GH +Nd,e 22 27h 34h 40
60 < t ≤ 100 215
100 < t ≤ 150 200 400 to 530
150 < t ≤ 250 185 390 to 530
≤ 16 295
16 < t ≤ 40 290
460 to 580
40 < t ≤ 60 285
P295GH +Nd,e 21 27h 34h 40
60 < t ≤ 100 260
100 < t ≤ 150 235 440 to 570
150 < t ≤ 250 220 430 to 570
≤ 16 355
16 < t ≤ 40 345 510 to 650
40 < t ≤ 60 335
P355GH +Nd,e 20 27h 34h 40
60 < t ≤ 100 315 490 to 630
100 < t ≤ 150 295 480 to 630
150 < t ≤ 250 280 470 to 630
a For nominal thicknesses > 250 mm (except for grades 12CrMo9-10 and 15NiCuMoNb5-6-4), property values may be
agreed upon.
b As rolled (untreated) by agreement, see 6.2.4; +N: normalized; +NT: normalized and tempered; +QT: quenched and
tempered.
c For nominal thicknesses where the usual delivery condition is +NT, higher strength and impact energy values may be
agreed for the delivery condition +QT.
d See 6.2.2.
e See 6.2.4.
f This steel may also be supplied in the +NT condition at the discretion of the manufacturer.
g 1 MPa = 1 N/mm2.
h An impact energy value of 40 J may be agreed upon at the time of enquiry and order.
i A value may be agreed upon at the time of enquiry and order.

© ISO 2018 – All rights reserved  11


ISO 9328-2:2018(E)


Table A.2 (continued)


Tensile properties
Impact energy
at room temperature
Nominal Elonga- KV
Usual thickness Yield Tensile
tion after J
Steel grade delivery strength strength
fracture min.
conditionb,c ReH Rm
t A at a temperature in °C of
mm MPag MPag % –20 0 +20
min. min.
< 16 275
16 < t ≤ 40 270 440 to 590
40 < t ≤ 60 260
16Mo3 +Nd,e,f 22 i i 31h
60 < t ≤ 100 240 430 to 580
100 < t ≤ 150 220 420 to 570
150 < t ≤ 250 210 410 to 570
≤ 60 345
+NT 510 to 650
18MnMo4-5 60 < t ≤ 150 325 20 27h 34h 40
+QT 150 < t ≤ 250 310 480 to 620
≤ 40 470 590 to 750
40 < t ≤ 60 460 590 to 730
20MnMoNi4-5 +QT 60 < t ≤ 100 450 18 27h 40 50
570 to 710
100 < t ≤ 150 440
150 < t ≤ 250 400 560 to 700
≤ 40 460
610 to 780
+NT 40 < t ≤ 60 440
15NiCuM-
60 < t ≤ 100 430 600 to 760 16 27h 34h 40
oNb5-6-4
+NT or +QT 100 < t ≤ 150 420 590 to 740
+QT 150 < t ≤ 200 410 580 to 740
≤ 16 300
450 to 600 i 31h
+NT 16 < t ≤ 60 290
13CrMo4-5 60 < t ≤ 100 270 440 to 590 19 i

+NT or +QT 100 < t ≤ 150 255 430 to 580 i 27h


+QT 150 < t ≤ 250 245 420 to 570
a For nominal thicknesses > 250 mm (except for grades 12CrMo9-10 and 15NiCuMoNb5-6-4), property values may be
agreed upon.
b As rolled (untreated) by agreement, see 6.2.4; +N: normalized; +NT: normalized and tempered; +QT: quenched and
tempered.
c For nominal thicknesses where the usual delivery condition is +NT, higher strength and impact energy values may be
agreed for the delivery condition +QT.
d See 6.2.2.
e See 6.2.4.
f This steel may also be supplied in the +NT condition at the discretion of the manufacturer.
g 1 MPa = 1 N/mm2.
h An impact energy value of 40 J may be agreed upon at the time of enquiry and order.
i A value may be agreed upon at the time of enquiry and order.

12  © ISO 2018 – All rights reserved


ISO 9328-2:2018(E)


Table A.2 (continued)


Tensile properties
Impact energy
at room temperature
Nominal Elonga- KV
Usual thickness Yield Tensile
tion after J
Steel grade delivery strength strength
fracture min.
conditionb,c ReH Rm
t A at a temperature in °C of
mm MPag MPag % –20 0 +20
min. min.
≤ 60 310 510 to 690
+NT i 27h 34h
60 < t ≤ 100 300 480 to 660
13CrMoSi5-5 ≤ 60 400 510 to 690 20
+QT 60 < t ≤ 100 390 500 to 680 27h 34h 40
100 < t ≤ 250 380 490 to 670
≤ 16 310
+NT 16 < t ≤ 40 300 480 to 630 18 i i 31h
40 < t ≤ 60 290
10CrMo9-10
+NT or +QT 60 < t ≤ 100 280 470 to 620
100 < t ≤ 150 260 460 to 610 17 i i 27h
+QT
150 < t ≤ 250 250 450 to 600
12CrMo9-10 +NT or +QT ≤ 250 355 540 to 690 18 27h 40 70
≤ 60 320 510 to 690
+NT
X12CrMo5 60 < t ≤ 150 300 480 to 660 20 27h 34h 40
+QT 150 < t ≤ 250 300 450 to 630
≤ 60 455 600 to 780
+NT
13CrMoV9-10 60 < t ≤ 150 435 590 to 770 18 27h 34h 40
+QT 150 < t ≤ 250 415 580 to 760
≤ 60 455 600 to 780
+NT
12CrMoV12-10 60 < t ≤ 150 435 590 to 770 18 27h 34h 40
+QT 150 < t ≤ 250 415 580 to 760
≤ 60 445 580 to 760
X10Cr- +NT
60 < t ≤ 150 435 550 to 730 18 27h 34h 40
MoVNb9-1
+QT 150 < t ≤ 250 435 520 to 700
a For nominal thicknesses > 250 mm (except for grades 12CrMo9-10 and 15NiCuMoNb5-6-4), property values may be
agreed upon.
b As rolled (untreated) by agreement, see 6.2.4; +N: normalized; +NT: normalized and tempered; +QT: quenched and
tempered.
c For nominal thicknesses where the usual delivery condition is +NT, higher strength and impact energy values may be
agreed for the delivery condition +QT.
d See 6.2.2.
e See 6.2.4.
f This steel may also be supplied in the +NT condition at the discretion of the manufacturer.
g 1 MPa = 1 N/mm2.
h An impact energy value of 40 J may be agreed upon at the time of enquiry and order.
i A value may be agreed upon at the time of enquiry and order.

© ISO 2018 – All rights reserved  13


ISO 9328-2:2018(E)


Table A.3 — Minimum values for the 0,2 % proof strength at elevated temperaturesa
Nominal Minimum 0,2 % proof strength, Rp0,2
thicknessb,c MPaf
Steel grade t at a temperature in °C of
mm 50 100 150 200 250 300 350 400 450 500
≤ 16 227 214 198 182 167 153 142 133 — —
16 < t ≤ 40 218 205 190 174 160 147 136 128 — —
40 < t ≤ 60 208 196 181 167 153 140 130 122 — —
P235GHd
60 < t ≤ 100 193 182 169 155 142 130 121 114 — —
100 < t ≤ 150 179 168 156 143 131 121 112 105 — —
150 < t ≤ 250 164 155 143 132 121 111 103 97 — —
≤ 16 256 241 223 205 188 173 160 150 — —
16 < t ≤ 40 247 232 215 197 181 166 154 145 — —
40 < t ≤ 60 237 223 206 190 174 160 148 139 — —
P265GHd
60 < t ≤ 100 208 196 181 167 153 140 130 122 — —
100 < t ≤ 150 193 182 169 155 142 130 121 114 — —
150 < t ≤ 250 179 168 156 143 131 121 112 105 — —
≤ 16 285 268 249 228 209 192 178 167 — —
16 < t ≤ 40 280 264 244 225 206 189 175 165 — —
40 < t ≤ 60 276 259 240 221 202 186 172 162 — —
P295GHd
60 < t ≤ 100 251 237 219 201 184 170 157 148 — —
100 < t ≤ 150 227 214 198 182 167 153 142 133 — —
150 < t ≤ 250 213 200 185 170 156 144 133 125 — —
≤ 16 343 323 299 275 252 232 214 202 — —
16 < t ≤ 40 334 314 291 267 245 225 208 196 — —
40 < t ≤ 60 324 305 282 259 238 219 202 190 — —
P355GHd
60 < t ≤ 100 305 287 265 244 224 206 190 179 — —
100 < t ≤ 150 285 268 249 228 209 192 178 167 — —
150 < t ≤ 250 271 255 236 217 199 183 169 159 — —
≤ 16 273 264 250 233 213 194 175 159 147 141
16 < t ≤ 40 268 259 245 228 209 190 172 156 145 139
40 < t ≤ 60 258 250 236 220 202 183 165 150 139 134
16Mo3
60 < t ≤ 100 238 230 218 203 186 169 153 139 129 123
100 < t ≤ 150 218 211 200 186 171 155 140 127 118 113
150 < t ≤ 250 208 202 191 178 163 148 134 121 113 108
≤ 60 330 320 315 310 295 285 265 235 215 —
18MnMo4-5e 60 < t ≤ 150 320 310 305 300 285 275 255 225 205 —
150 < t ≤ 250 310 300 295 290 275 265 245 220 200 —
a The values correspond to the lower band of the relevant trend curve determined in accordance with EN 10314 with a
confidence limit of about 98 % (2 s).
b For nominal thicknesses exceeding the specified maximum thicknesses, Rp0,2 values at elevated temperatures may be
agreed upon.
c Delivery condition as given in Table A.2 (but see footnote c to Table A.2).
d The values reflect the minimum values for furnace-normalized test pieces.
e Rp0,2 not determined in accordance with EN 10314. These are minimum values of the scatter band considered up
until now.
f 1 MPa = 1 N/mm2.

14  © ISO 2018 – All rights reserved


ISO 9328-2:2018(E)


Table A.3 (continued)


Nominal Minimum 0,2 % proof strength, Rp0,2
thicknessb,c MPaf
Steel grade t at a temperature in °C of
mm 50 100 150 200 250 300 350 400 450 500
≤ 40 460 448 439 432 424 415 402 384 — —
40 < t ≤ 60 450 438 430 423 415 406 394 375 — —
20MnMoNi4-5 60 < t ≤ 100 441 429 420 413 406 398 385 367 — —
100 < t ≤ 150 431 419 411 404 397 389 377 359 — —
150 < t ≤ 250 392 381 374 367 361 353 342 327 — —
≤ 40 447 429 415 403 391 380 366 351 331 —
40 < t ≤ 60 427 410 397 385 374 363 350 335 317 —
15NiCuMoNb5-6-4 60 < t ≤ 100 418 401 388 377 366 355 342 328 309 —
100 < t ≤ 150 408 392 379 368 357 347 335 320 302 —
150 < t ≤ 200 398 382 370 359 349 338 327 313 295 —
≤ 16 294 285 269 252 234 216 200 186 175 164
16 < t ≤ 60 285 275 260 243 226 209 194 180 169 159
13CrMo4-5 60 < t ≤ 100 265 256 242 227 210 195 180 168 157 148
100 < t ≤ 150 250 242 229 214 199 184 170 159 148 139
150 < t ≤ 250 235 223 215 211 199 184 170 159 148 139
≤ 60 299 283 268 255 244 233 223 218 206 —
13CrMoSi5-5+NT
60 < t ≤ 100 289 274 260 247 236 225 216 211 199 —
≤ 60 384 364 352 344 339 335 330 322 309 —
13CrMoSi5-5+QT 60 < t ≤ 100 375 355 343 335 330 327 322 314 301 —
100 < t ≤ 250 365 346 334 326 322 318 314 306 293
≤ 16 288 266 254 248 243 236 225 212 197 185
16 < t ≤ 40 279 257 246 240 235 228 218 205 191 179
40 < t ≤ 60 270 249 238 232 227 221 211 198 185 173
10CrMo9-10
60 < t ≤ 100 260 240 230 224 220 213 204 191 178 167
100 < t ≤ 150 250 237 228 222 219 213 204 191 178 167
150 < t ≤ 250 240 227 219 213 210 208 204 191 178 167
12CrMo9-10 ≤ 250 341 323 311 303 298 295 292 287 279 —
≤ 60 310 299 295 294 293 291 285 273 253 222
X12CrMo5
60 < t ≤ 250 290 281 277 275 275 273 267 256 237 208
≤ 60 410 395 380 375 370 365 362 360 350 —
13CrMoV9-10e
60 < t ≤ 250 405 390 370 365 360 355 352 350 340 —
a The values correspond to the lower band of the relevant trend curve determined in accordance with EN 10314 with a
confidence limit of about 98 % (2 s).
b For nominal thicknesses exceeding the specified maximum thicknesses, Rp0,2 values at elevated temperatures may be
agreed upon.
c Delivery condition as given in Table A.2 (but see footnote c to Table A.2).
d The values reflect the minimum values for furnace-normalized test pieces.
e Rp0,2 not determined in accordance with EN 10314. These are minimum values of the scatter band considered up
until now.
f 1 MPa = 1 N/mm2.

© ISO 2018 – All rights reserved  15


ISO 9328-2:2018(E)


Table A.3 (continued)


Nominal Minimum 0,2 % proof strength, Rp0,2
thicknessb,c MPaf
Steel grade t at a temperature in °C of
mm 50 100 150 200 250 300 350 400 450 500
≤ 60 410 395 380 375 370 365 362 360 350 —
12CrMoV12-10e
60 < t ≤ 250 405 390 370 365 360 355 352 350 340 —
≤ 60 432 415 401 392 385 379 373 364 349 324
X10CrMoVNb9-1
60 < t ≤ 250 423 406 392 383 376 371 365 356 341 316
a The values correspond to the lower band of the relevant trend curve determined in accordance with EN 10314 with a
confidence limit of about 98 % (2 s).
b For nominal thicknesses exceeding the specified maximum thicknesses, Rp0,2 values at elevated temperatures may be
agreed upon.
c Delivery condition as given in Table A.2 (but see footnote c to Table A.2).
d The values reflect the minimum values for furnace-normalized test pieces.
e Rp0,2 not determined in accordance with EN 10314. These are minimum values of the scatter band considered up
until now.
f 1 MPa = 1 N/mm2.

16  © ISO 2018 – All rights reserved


ISO 9328-2:2018(E)


Annex B
(normative)

Chemical composition and mechanical properties of products


based on ASTM/ASME or JIS standards

© ISO 2018 – All rights reserved  17



Table B.1 — Chemical composition [cast (heat) analysis]

18
Steel grade Si Mn Altotal Cr Cu Mo Nb Ni Ti V B Others
% by massa
Cb Pb Sb
max. max. max. max. max. max.
0,40
PT410GH 0,20c ≤ 0,40 0,020 0,020 ≥ 0,020d ≤ 0,30 0,40 ≤ 0,12 0,02 ≤ 0,40 0,03 ≤ 0,03 ≤ 0,001 0 Cr+C+Mo+Ni: ≤ 1,00
ISO 9328-2:2018(E)

to 1,40
0,60
PT450GH 0,20c ≤ 0,40 0,020 0,020 ≥ 0,020d ≤ 0,30 0,40 ≤ 0,12 0,02 ≤ 0,40 0,03 ≤ 0,03 ≤ 0,001 0 Cr+C+Mo+Ni: ≤ 1,00
to 1,60
0,60
PT480GH 0,20c ≤ 0,55 0,020 0,020 ≥ 0,020d ≤ 0,30 0,40 ≤ 0,12 0,02 ≤ 0,40 0,03 ≤ 0,03 ≤ 0,001 0 Cr+C+Mo+Ni: ≤ 1,00
to 1,60
0,95 0,45
19MnMo4-5 0,25 ≤ 0,40 0,020 0,020 — ≤ 0,30 0,40 0,02 ≤ 0,40 0,03 ≤ 0,03 ≤ 0,001 0 —
to 1,30 to 0,60
0,95 0,45
19MnMo5-5 0,25 ≤ 0,40 0,020 0,020 — ≤ 0,30 0,40 0,02 ≤ 0,40 0,03 ≤ 0,03 ≤ 0,001 0 —
to 1,50 to 0,60
1,15 0,45
19MnMo6-5 0,25 ≤ 0,40 0,020 0,020 — ≤ 0,30 0,40 0,02 ≤ 0,40 0,03 ≤ 0,03 ≤ 0,001 0 —
to 1,50 to 0,60


0,95 0,45 0,40
19MnMoNi5-5 0,25 ≤ 0,40 0,020 0,020 — ≤ 0,30 0,40 0,02 0,03 ≤ 0,02 ≤ 0,001 0 —
to 1,50 to 0,60 to 0,70
1,15 0,45 0,40
19MnMoNi6-5 0,25 ≤ 0,40 0,020 0,020 — ≤ 0,20 0,40 0,02 0,03 ≤ 0,02 ≤ 0,001 0 —
to 1,50 to 0,60 to 0,70
0,40 0,80 0,45
14CrMo4-5e 0,17 ≤ 0,40 0,020 0,020 — 0,40 0,02 ≤ 0,40 0,03 ≤ 0,03 — —
to 0,65 to 1,15 to 0,65
0,50 0,40 1,00 0,45
14CrMoSi5-6e 0,17 0,020 0,020 — 0,40 0,02 ≤ 0,40 0,03 ≤ 0,03 — —
to 0,80 to 0,65 to 1,50 to 0,60
0,30 2,00 0,90
13CrMo9-10e 0,17 ≤ 0,50 0,020 0,020 — 0,40 0,02 ≤ 0,40 0,03 ≤ 0,03 — —
to 0,60 to 2,50 to 1,10
a Elements not listed in this table shall not intentionally be added to the steel without agreement of the purchaser, except for finishing the cast. All appropriate measures shall
be taken to prevent the addition from scrap or other materials used in steelmaking of these elements which may affect the mechanical properties and usability.
b The maximum values also apply to the product analysis.
c By agreement at the time of enquiry and order, the maximum carbon content may be increased up to 0,31 % in the case of PT410GH, 0,33 % in the case of PT450GH
and 0,35 % in the case of PT480GH.
d On cast analysis, the aluminium content shall not be less than 0,020 % total aluminium or, alternately, 0,015 % acid soluble aluminium. If so agreed at the time of enquiry and
order, aluminium shall not be used in order to restrain graphitization.
e See Table B.2 for complete steel names.

© ISO 2018 – All rights reserved


f REM: Rare earth metals.
Table B.1 (continued)

Steel grade Si Mn Altotal Cr Cu Mo Nb Ni Ti V B Others


% by massa
Cb Pb Sb
max. max. max. max. max. max.
0,30 2,00 0,90
14CrMo9-10 0,17 ≤ 0,50 0,015 0,015 — 0,40 0,02 ≤ 0,40 0,03 ≤ 0,03 — —
to 0,60 to 2,50 to 1,10
0,30 2,00 0,90 0,25 ≤ 0,003 B; ≤ 0,015 Ca,

© ISO 2018 – All rights reserved


14CrMoV9-10 0,17 ≤ 0,10 0,015 0,010 — 0,40 0,07 ≤ 0,40 0,035 —
to 0,60 to 2,50 to 1,10 to 0,35 ≤ 0,015 REMf
0,30 2,75 to 0,90 0,20 ≤ 0,003 B; ≤ 0,015 Ca,
13CrMoV12-10 0,17 ≤ 0,15 0,015 0,010 — 0,40 0,07 ≤ 0,40 0,035 —
to 0,60 3,25 to 1,10 to 0,30 ≤ 0,015 REMf
X9Cr- 0,08 0,30 8,00 to 0,85 0,06 0,18
≤ 0,50 0,020 0,010 ≤ 0,040 0,40 ≤ 0,40 0,03 — —
MoVNb9-1 to 0,12 to 0,60 9,50 to 1,05 to 0,10 to 0,25
a Elements not listed in this table shall not intentionally be added to the steel without agreement of the purchaser, except for finishing the cast. All appropriate measures shall
be taken to prevent the addition from scrap or other materials used in steelmaking of these elements which may affect the mechanical properties and usability.
b The maximum values also apply to the product analysis.
c By agreement at the time of enquiry and order, the maximum carbon content may be increased up to 0,31 % in the case of PT410GH, 0,33 % in the case of PT450GH


and 0,35 % in the case of PT480GH.
d On cast analysis, the aluminium content shall not be less than 0,020 % total aluminium or, alternately, 0,015 % acid soluble aluminium. If so agreed at the time of enquiry and
order, aluminium shall not be used in order to restrain graphitization.
e See Table B.2 for complete steel names.
f REM: Rare earth metals.
ISO 9328-2:2018(E)

19

ISO 9328-2:2018(E)


Table B.2 — Mechanical properties


Tensile properties at room
temperatureb,c Impact
Nominal Elongation energy
Yield Tensile
Usual delivery thickness after
Steel grade strength strength
conditiona fracture
ReH Rm A
t KV
MPad MPad %
mm min. min. J
+AR 6 ≤ t ≤ 50
PT410GH 225 410 to 550 21
+N 6 ≤ t ≤ 200
+AR 6 ≤ t ≤ 50
PT450GH 245 450 to 590 19
+N 6 ≤ t ≤ 200
+AR 6 ≤ t ≤ 50
PT480GH 265 480 to 620 17
+N 6 ≤ t ≤ 200
+N, +AR 6 ≤ t ≤ 50
19MnMo4-5 315 520 to 660 17
+Ne 50 ≤ t ≤ 200
+N, +QTf, +AR 6 ≤ t ≤ 50
19MnMo5-5 345 550 to 690 17
+Ne, +QTf 6 ≤ t ≤ 200
19MnMo6-5 +QTf 6 ≤ t ≤ 200 480 620 to 790 15
19MnMoNi5-5 +N, +QTc, +AR 6 ≤ t ≤ 50
345 550 to 690 17
+Ne, +QTf 50 ≤ t ≤ 200 l

6 ≤ t ≤ 50
19MnMoNi6-5 +QTf 480 620 to 790 15
50 ≤ t ≤ 200
14CrMo4-5+NT1 +NTg 6 ≤ t ≤ 200 225 380 to 550 20
14CrMo4-5+NT2 +Nt g 6 ≤ t ≤ 200 275 450 to 590 20
14CrMoSi5-6+NT1 +Ng 6 ≤ t ≤ 200 235 410 to 590 20
14CrMoSi5-6+NT2 +NTg 6 ≤ t ≤ 200 315 520 to 690 20
13CrMo9-10+NT1 +NTg 6 ≤ t ≤ 300 205 410 to 590 17
13CrMo9-10+NT2 +NTg 6 ≤ t ≤ 300 315 520 to 690 17
14CrMo9-10 +QT h (+NTi)j 6 ≤ t ≤ 300 380 580 to 760 17
14CrMoV9-10 +NTi (+QTg)j 6 ≤ t ≤ 300 415 580 to 760 17

20  © ISO 2018 – All rights reserved


ISO 9328-2:2018(E)


Table B.2 (continued)


Tensile properties at room
temperatureb,c Impact
Nominal Elongation energy
Yield Tensile
Usual delivery thickness after
Steel grade strength strength
conditiona fracture
ReH Rm A
t KV
MPad MPad %
mm min. min. J
13CrMoV12-10 +NTi (+QTg)j 6 ≤ t ≤ 300 415 580 to 760 17
X9CrMoVNb9-1 +NTk 6 ≤ t ≤ 300 415 585 to 760 17
a +AR = as rolled (untreated), see 6.2.3 and 6.2.5; +N: normalized; +NT: normalized and tempered; +QT:
quenched and tempered. For products delivered untreated, 6.2.5 applies.
b Applicable for transverse direction.
c The reduction of area shall not be less than 45 % for steel grades 13CrMo9-10+NT1, 13CrMo9-10+NT2,
14CrMo9-10 and 13CrMoV12-10.
d 1 MPa = 1 N/mm2.
e Normalizing for steel plate > 100 mm may include accelerated cooling and subsequent tempering in the tem-
perature range of 595 °C to 705 °C.
f Plates shall be quenched and tempered, and the tempering temperature shall be a suitable temperature to
produce the specific properties, but shall not be less than 595 °C.
g In normalizing, accelerated cooling to obtain the specified mechanical properties may be performed by liq-
uid quenching, air blasting or other methods. Minimum tempering temperature shall be 620 °C for steel grades
14CrMo4-5 and 14CrMoSi5-6 and 650 °C for steel grade 13CrMo9-10.
h Minimum tempering temperature shall be 675 °C. The purchaser shall inform the manufacturer of his in-
tention to use this tempering temperature of 675 °C. In this case, the manufacturer may perform tempering at
temperatures lower than 675 °C, but not lower than 625 °C.
i Minimum tempering temperature shall be 675 °C. The purchaser shall inform the manufacturer of his in-
tention to use this tempering temperature of 675 °C. In this case, the manufacturer may perform tempering at
temperatures lower than 675 °C, but not lower than 625 °C.
j By agreement at the time of enquiry and order, the products may be delivered in the condition +NT
(14CrMo9-10) or +QT(14CrMoV9-10 and 13CrMoV12-10).
k Minimum tempering temperature shall be 730 °C.
l Impact tests with agreed minimum impact energy value(s) and test temperature(s) may be agreed at the
time of enquiry and order.

© ISO 2018 – All rights reserved  21


ISO 9328-2:2018(E)


Annex C
(informative)

Steel designations in accordance with this document and


designation of comparable steel grades in national or regional
standards

Table C.1 — Steel designations in accordance with this document a and designation of
comparableb steel grades in national or regional standards
Steel designation in
ASTM A302, A387, A515, JIS G3103, G3118, G3119,
ISO 9328‑2 EN 10028‑2c
A516, A533, A542, A832 G3120, G4109
P235GH 1.0345
P265GH 1.0425
P295GH 1.0481
P355GH 1.0473
PT410GH A515-60, A516-60 SB410, SGV410
PT450GH A515-65, A516-65 SB450, SGV450
PT480GH A515-70, A516-70 SB480, SGV480
16Mo3 1.5415
18MnMo4-5 1.5414
19MnMo4-5 A302A SBV1A
19MnMo5-5 A302B, A533A1 SBV1B, SQV1A
19MnMo6-5 A533A2 SQV1B
20MnMoNi4-5 1.6311
19MnMoNi5-5 A302C, A533B1 SBV2, SQV2A
19MnMoNi6-5 A533B2 SQV2B
15NiCuMoNb5-6-4 1.6368
13CrMo4-5 1.7335
14CrMo4-5+NT1 A387-12-1 SCMV2-1
14CrMo4-5+NT2 A387-12-2 SCMV2-2
13CrMoSi5-5 1.7336
14CrMoSi5-6+NT1 A387-11-1 SCMV3-1
14CrMoSi5-6+NT2 A387-11-2 SCMV3-2
10CrMo9-10 1.7380
12CrMo9-10 1.7375
13CrMo9-10+NT1 A387-22-1 SCMV4-1
13CrMo9-10+NT2 A387-22-2 SCMV4-2
14CrMo9-10 A542B4 SCMQ4E
X12CrMo5 1.7362
a In accordance with ISO/TS 4949.
b “Comparable” covers both identical or similar steel grades.
c In addition to the steel name (identical to the corresponding steel name used in this document), the listed steel number
is specified.

22  © ISO 2018 – All rights reserved


ISO 9328-2:2018(E)


Table C.1 (continued)


Steel designation in
ASTM A302, A387, A515, JIS G3103, G3118, G3119,
ISO 9328‑2 EN 10028‑2c
A516, A533, A542, A832 G3120, G4109
13CrMoV9-10 1.7703
14CrMoV9-10 A542D4a, A832-22V SCMQ4V
12CrMoV12-10 1.7767
13CrMoV12-10 A542E4a SCMQ5V
X9CrMoVNb9-1 A387-91
X10CrMoVNb9-1 1.4903
a In accordance with ISO/TS 4949.
b “Comparable” covers both identical or similar steel grades.
c In addition to the steel name (identical to the corresponding steel name used in this document), the listed steel number
is specified.

© ISO 2018 – All rights reserved  23


ISO 9328-2:2018(E)


Annex D
(informative)

Guidelines for heat treatment

Tables D.1 and D.2 give reference data for heat treatment temperatures. For stress relief annealing, see
Annex E.
NOTE In addition to the temperature, there are other parameters, such as type of heating, heating rate,
holding time and cooling method which have to be taken into account.

Table D.1 — Heat treatment temperatures (steel grades of Annex A)


Steel grade Temperature, °C
Steel name Steel Normalizing Quenching Temperingb
number
P235GH 1.0345 890 to 950a — —
P265GH 1.0425 890 to 950a — —
P295GH 1.0481 890 to 950a — —
P355GH 1.0473 890 to 950a — —
16Mo3 1.5415 890 to 950a — c

18MnMo4-5 1.5414 890 to 950 600 to 640


20MnMoNi4-5 1.6311 — 870 to 940 610 to 690
15NiCuMoNb5-6-4 1.6368 880 to 960 580 to 680
13CrMo4-5 1.7335 890 to 950 630 to 730
13CrMoSi5-5 1.7336 890 to 950 650 to 730
10CrMo9-10 1.7380 920 to 980 650 to 750
12CrMo9-10 1.7375 920 to 980 650 to 750
X12CrMo5 1.7362 920 to 970 680 to 750
13CrMoV9-10 1.7703 930 to 990 675 to 750
12CrMoV12-10 1.7767 930 to 1 000 675 to 750
X10CrMoVNb9-1 1.4903 1 040 to 1 100 730 to 780
a When normalizing, after the required temperatures have been attained over the whole cross-
section, no further holding is necessary and should be generally avoided.
b When tempering, the specified temperatures shall, when they have been attained over the whole
cross-section, be maintained for an appropriate time.
c In certain cases, tempering at 590 °C to 650 °C may be necessary.

24  © ISO 2018 – All rights reserved


ISO 9328-2:2018(E)


Table D.2 — Heat treatment temperatures (steel grades of Annex B)


Temperature, °C
Steel grade
Normalizing Austenitizing Tempering
PT410GH 880 to 950 — —
PT450GH 880 to 950 — —
PT480GH 880 to 950 — —
19MnMo4-5 880 to 950 — —
19MnMo5-5 880 to 950 880 to 950 595 to 690
19MnMo6-5 — 880 to 950 595 to 690
19MnMoNi5-5 880 to 950 880 to 950 595 to 690
19MnMoNi6-5 — 880 to 950 595 to 690
14CrMo4-5+NT1 880 to 980 — 620 to 710
14CrMo4-5+NT2 880 to 980 — 620 to 710
14CrMoSi5-6+NT1 880 to 980 — 620 to 710
14CrMoSi5-6+NT2 880 to 980 — 620 to 720
13CrMo9-10+NT1 900 to 980 — 650 to 760
13CrMo9-10+NT2 900 to 980 — 650 to 760
14CrMo9-10 900 to 980 900 to 980 620 to 760
14CrMoV9-10 900 to 1 000 900 to 1 000 675 to 760
13CrMoV12-10 900 to 1 000 900 to 1 000 675 to 760
X9CrMoVNb9-1 1 040 to 1 095 — 730 to 780

© ISO 2018 – All rights reserved  25


ISO 9328-2:2018(E)


Annex E
(informative)

Critical time-temperature parameter Pcrit. and possible


combinations of stress relieving temperature and holding time

Examples for stress relieving temperatures and the corresponding maximum holding time calculated
on the basis of the equation in 6.7 for a given critical time-temperature parameter Pcrit. are given in
Table E.1.

Table E.1 — Pcrit. value and permissible holding time for a given stress relieving temperature
Pcrit. condition fulfilled with stress reliev-
Steel type ing temperature in °C for a holding timea of
Pcrit.
or steel grade
1h 2h
C, CMn steels 17,3 580 575
16Mo3 17,5 590 585
18MnMo4-5 17,5 590 585
20MnMoNi4-5 17,5 590 585
15NiCuMoNb5-6-4 17,5 590 585
13CrMo4-5 18,5 640 630
13CrMoSi5-5 18,7 650 640
10CrMo9-10 19,2 675 665
12CrMo9-10 19,3 680 670
X12CrMo5 19,5 690 680
13CrMoV9-10 19,4 685 675
12CrMoV12-10 19,4 685 675
X10CrMoVNb9-1 20,5 740 730
a Selected pairs of stress relieving temperature and holding time for guidance.

26  © ISO 2018 – All rights reserved


ISO 9328-2:2018(E)


Annex F
(informative)

Reference data relating to strength for 1 % (plastic) creep strain


and creep rupture

NOTE The values given in Table F.1 have been derived as mean values in accordance with ISO 6303 with a
scatter band of ±20 %.

The strength values for 1 % (plastic) creep strain and creep rupture given up to the elevated
temperatures listed in Table F.1 do not mean that the steels can be used in continuous duty up to
these temperatures. The governing factor is the total stressing during operation. Where relevant, the
oxidation conditions should also be taken into account.

Table F.1 — Strength for 1 % (plastic) creep strain and creep rupture
Tempera- Strength for 1 % (plastic)
Creep rupture strength in MPa for
Steel grade ture creep strain in MPa for
°C 10 000 h 100 000 h 10 000 h 100 000 h 200 000 h
380 164 118 229 165 145
390 150 106 211 148 129
400 136 95 191 132 115
410 124 84 174 118 101
420 113 73 158 103 89
P235GH,
430 101 65 142 91 78
P265GH
440 91 57 127 79 67
450 80 49 113 69 57
460 72 42 100 59 48
470 62 35 86 50 40
480 53 30 75 42 33
380 195 153 291 227 206
390 182 137 266 203 181
400 167 118 243 179 157
410 150 105 221 157 135
420 135 92 200 136 115
430 120 80 180 117 97
P295GH,
440 107 69 161 100 82
P355GH
450 93 59 143 85 70
460 83 51 126 73 60
470 71 44 110 63 52
480 63 38 96 55 44
490 55 33 84 47 37
500 49 29 74 41 30

© ISO 2018 – All rights reserved  27


ISO 9328-2:2018(E)


Table F.1 (continued)


Tempera- Strength for 1 % (plastic)
Creep rupture strength in MPa for
Steel grade ture creep strain in MPa for
°C 10 000 h 100 000 h 10 000 h 100 000 h 200 000 h
450 216 167 298 239 217
460 199 146 273 208 188
470 182 126 247 178 159
16Mo3 480 166 107 222 148 130
490 149 89 196 123 105
500 132 73 171 101 84
510 115 59 147 81 69
520 99 46 125 66 55
530 84 36 102 53 45
425 392 314 421 343
430 383 302 407 330
440 360 272 380 300
450 333 240 353 265
460 303 207 325 230
470 271 176 295 196
18MnMo4-5 480 239 148 263 166
490 207 124 229 140
500 177 103 196 118
510 150 84 165 98
520 127 64 141 79
525 118 54 132 69
450 290 240
460 272 211
470 251
20MnMoNi4-5
480 225
490 194
400 324 294 402 373
410 315 279 385 349
420 306 263 368 325
430 295 245 348 300
440 281 227 328 273
15NiCuM-
oNb5-6-4 450 265 206 304 245
460 239 180 274 210
470 212 151 242 175
480 180 120 212 139
490 145 84 179 104
500 108 49 147 69

28  © ISO 2018 – All rights reserved


ISO 9328-2:2018(E)


Table F.1 (continued)


Tempera- Strength for 1 % (plastic)
Creep rupture strength in MPa for
Steel grade ture creep strain in MPa for
°C 10 000 h 100 000 h 10 000 h 100 000 h 200 000 h
450 245 191 370 285 260
460 228 172 348 251 226
470 210 152 328 220 195
480 193 133 304 190 167
490 173 116 273 163 139
500 157 98 239 137 115
510 139 83 209 116 96
520 122 70 179 94 76
13CrMo4-5 530 106 57 154 78 62
540 90 46 129 61 50
550 76 36 109 49 39
560 64 30 91 40 32
570 53 24 76 33 26
450 209 313
460 200 300
470 185 278
480 141 212
490 119 179
13CrMoSi5-5 500 113 169
510 81 122
520 66 99
530 41 62
540 33 50
550 27 40
560 23 35
570 21 31
450 240 166 306 221 201
460 219 155 286 205 186
470 200 145 264 188 169
480 180 130 241 170 152
490 163 116 219 152 136
500 147 103 196 135 120
510 132 90 176 118 105
520 119 78 156 103 91
10CrMo9-10 530 107 68 138 90 79
540 94 58 122 78 68
550 83 49 108 68 58

© ISO 2018 – All rights reserved  29


ISO 9328-2:2018(E)


Table F.1 (continued)


Tempera- Strength for 1 % (plastic)
Creep rupture strength in MPa for
Steel grade ture creep strain in MPa for
°C 10 000 h 100 000 h 10 000 h 100 000 h 200 000 h
560 73 41 96 58 50
570 65 35 85 51 43
580 57 30 75 44 37
590 50 26 68 38 32
600 44 22 61 34 28
400 382 313
410 355 289
420 333 272
12CrMo9-10 430 312 255
440 293 238
450 276 221
460 259 204
470 242 187
480 225 170
490 208 153
500 191 137
510 174 122
520 157 107
450 107
460 96
147 (475 °C)
470 87
139
480 83
123
490 78
108
500 70
510 56 94
520 50 81
X12CrMo5 530 44 71
540 39 61
550 35 53
560 31 47
570 27 41
580 24 36
590 21 32
600 18 27
610 16
620 14
625 13

30  © ISO 2018 – All rights reserved


ISO 9328-2:2018(E)


Table F.1 (continued)


Tempera- Strength for 1 % (plastic)
Creep rupture strength in MPa for
Steel grade ture creep strain in MPa for
°C 10 000 h 100 000 h 10 000 h 100 000 h 200 000 h
   400 430 383
410 414 365
420 397 346
430 380 327
440 362 309
13CrMoV9-10 450 344 290
460 326 271
470 308 253
480 290 235
490 272 218
500 255 201
510 237 184
520 221 169
530 204 144
540 188 126
550 173 108
400 430 383
410 414 365
420 397 346
430 380 327
440 362 309
450 344 290
460 326 271
470 308 253
12CrMoV12-10 480 290 235
490 272 218
500 255 201
510 237 184
520 221 169
530 204 144
540 188 126
550 173 108

© ISO 2018 – All rights reserved  31


ISO 9328-2:2018(E)


Table F.1 (continued)


Tempera- Strength for 1 % (plastic)
Creep rupture strength in MPa for
Steel grade ture creep strain in MPa for
°C 10 000 h 100 000 h 10 000 h 100 000 h 200 000 h
500 289 258 246
510 271 239 227
520 252 220 208
530 234 201 189
540 216 183 171
550 199 166 154
560 182 150 139
570 166 134 124
X10CrMoVNb
580 151 120 110
9-1
590 136 106 97
600 123 94 86
610 110 83 75
620 99 73 65
630 89 65 57
640 79 56 49
650 70 49 42
660 62 42 35
670 55 36 —

32  © ISO 2018 – All rights reserved


ISO 9328-2:2018(E)


Annex G
(informative)

Evaluation of resistance to hydrogen-induced cracking

G.1 If agreed at the time of enquiry and order, a test to evaluate the resistance of steel products to
hydrogen-induced cracking shall be performed.

G.2 The test procedure specified in EN 10229 or another appropriate procedure with specified
acceptance criteria (e.g. in accordance with NACE TM0284) shall be applied.

G.3 The procedure to be applied, the test solution, the frequency of testing and the corresponding
acceptance criteria shall be agreed upon at the time of enquiry and order.

In the case of the procedure specified in EN 10229, the acceptance criteria for the test solution A (with
pH ≈ 3) apply for the classes indicated in Table G.1 where the given values are minimum average values
from all tested cross sections from one plate.

Table G.1 — Acceptance classes for the HIC test (test solution A)
CLR a CTR a CSR a
Acceptance class
% % %
I ≤5 ≤ 1,5 ≤ 0,5
II ≤ 10 ≤3 ≤1
III ≤ 15 ≤5 ≤2
a CLR: crack length ratio, CTR: crack thickness ratio, CSR: crack sensitivity ratio.

© ISO 2018 – All rights reserved  33


ISO 9328-2:2018(E)


Annex H
(informative)

Step cooling test

For the step cooling test, a procedure to check step cooling embrittlement shall be agreed. This
procedure shall include temperatures, T, and holding times, t, to be considered. The procedure given in
Figure H.1 is recommended.
  

Figure H.1 — Recommended procedure for the step cooling test

34  © ISO 2018 – All rights reserved


ISO 9328-2:2018(E)


Bibliography

[1] ISO/TS 4949, Steel names based on letter symbols


[2] ISO 6303, Pressure vessel steels not included in ISO 2604, Parts 1 to 6 — Derivation of long-time
stress rupture properties
[3] ISO 10474, Steel and steel products — Inspection documents
[4] EN 1011-1, Welding — Recommendations for welding of metallic materials — Part 1: General
guidance for arc welding
[5] EN 1011-2, Welding — Recommendations for welding of metallic materials — Part 2: Arc welding of
ferritic steels
[6] EN 10229, Evaluation of resistance of steel products to hydrogen induced cracking (HIC)
[7] EN 10314, Method for the derivation of minimum values of proof strength of steel at elevated
temperatures
[8] IIS/IIW 382‑71, Guide to the welding and weldability of C-Mn steels and C-Mn microalloyed steels
[9] NACE TM0284, Standard test method — Evaluation of pipeline and pressure vessel steels for
resistance to hydrogen-induced cracking

© ISO 2018 – All rights reserved  35


ISO 9328-2:2018(E)


ICS 77.140.50; 77.140.30


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© ISO 2018 – All rights reserved 

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