MR 311r Msds
MR 311r Msds
MR 311r Msds
Call Day or Night within USA and Canada: 1 800 424 9300
Outside USA and Canada: 001 703 527 3887
In-Country Emergency Number for:
Germany: 0800-181-7059
Australia: +61 433 289 052 (English)
Hong Kong: 800 968 793 (Cantonese)
India: 000 800 100 7141 (Hindi)
South Africa: 0 800 983 611 (English)
GHS02 flame
Aerosol 1 H222-H229 Extremely flammable aerosol. Pressurised container: May burst if heated.
(Contd. on page 2)
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GHS07
GHS02 GHS07
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CAS: 102-71-6 2,2',2''-nitrilotriethanol < 1.0%
EINECS: 203-049-8 substance with a Community workplace exposure limit
CAS: 111-76-2 2-butoxyethanol < 1.0%
EINECS: 203-905-0 Acute Tox. 4, H302; Acute Tox. 4, H312; Acute Tox. 4, H332; Skin
Irrit. 2, H315; Eye Irrit. 2, H319
· Propellant: Propane-Butane
· Additional information: For the wording of the listed hazard phrases refer to section 16.
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111-76-2 2-butoxyethanol
IOELV (EU) Short-term value: 246 mg/m³, 50 ppm
Long-term value: 98 mg/m³, 20 ppm
Skin
WEL (Great Britain) Short-term value: 246 mg/m³, 50 ppm
Long-term value: 123 mg/m³, 25 ppm
Sk, BMGV
AGW (Germany) Long-term value: 49 mg/m³, 10 ppm
4(II);H, Y, AGS
· DNELs
112-34-5 2-(2-butoxyethoxy)ethanol
Dermal Long-term - systemic effects, worker 20 mg/kg bw/day (worker)
Inhalative Acute - local effects, worker 101.2 mg/m³ (worker)
Long-term - systemic effects, worker 67.5 mg/m³ (worker)
Long-term - local effects, worker 67.5 mg/m³ (worker)
102-71-6 2,2',2''-nitrilotriethanol
Dermal Long-term - systemic effects, worker 6.3 mg/kg bw/day (worker)
Inhalative Long-term - systemic effects, worker 5 mg/m³ (worker)
Long-term - local effects, worker 5 mg/m³ (worker)
· PNECs
112-34-5 2-(2-butoxyethoxy)ethanol
Aquatic compartment, freshwater 1 mg/L (freshwater)
Aquatic compartment - marine water 0.1 mg/L (marine water)
Aquatic compartment - water intermittent releases 3.9 mg/L (intermittent release water)
Aquatic compartment- sediment in freshwater 4 mg/kg sed dw (sediment fresh water)
Aquatic compartment sediment in marine water 0.4 mg/kg sed dw (sediment marine water)
Terrestrial compartment - soil 0.4 mg/kg dw (soil)
Oral secondary poisoning 56 mg/kg food (food secundary poisoning)
102-71-6 2,2',2''-nitrilotriethanol
Aquatic compartment, freshwater 0.32 mg/L (freshwater)
Aquatic compartment - marine water 0.032 mg/L (marine water)
Aquatic compartment - water intermittent releases 5.12 mg/L (intermittent release water)
Aquatic compartment- sediment in freshwater 1.7 mg/kg sed dw (sediment fresh water)
Aquatic compartment sediment in marine water 0.17 mg/kg sed dw (sediment marine water)
Terrestrial compartment - soil 0.151 mg/kg dw (soil)
Sewage treatment plant 10 mg/L (sewage treatment plant)
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
· Respiratory protection:
Filter A2 - P 2 EN 141, 143, 371
For good ventilation provide, this can be achieved by local or space exhaust. If the concentration
lies over the job limit values, then, a certified respirator suitable for this purpose must be used.
(Contd. on page 6)
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· Protection of hands:
Check the permeability prior to each anewed use of the glove.
For the permanent contact in work areas with heightened risk of injury (mechanical hazard) no
recommendation for a suitable glove material can be given.
Protective gloves
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves
Fluorocarbon rubber (Viton)
Nitrile rubber, NBR
Butyl rubber, BR
Recommended thickness of the material: ≥ 0.5 mm
The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore
to be checked prior to the application.
· Penetration time of glove material
Value for the permeation: Level ≤ 6
Supplier for suitable protection gloves:
ASD ArbeitsSicherheit Dortmund
Torstr. 101 - 37355 Niederorschel OT Rüdigershagen
Tel.: 02301 / 919543 - Fax: 02301 / 9453893
E-Mail: m.schnellhardt@t-online.de - http://www.arbeitssicherheitdortmund.de
The exact break trough time has to be found out by the manufacturer of the protective gloves and
has to be observed.
· Eye protection: Safety glasses
· Body protection: Protective work clothing
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· Explosion limits:
Lower: 0.9 Vol %
Upper: 10.9 Vol %
· Vapour pressure at 20 °C: 8300 hPa
Basis: propellant
· Density at 20 °C: 0.97 g/cm³
Basis: active substance
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not applicable.
· Solubility in / Miscibility with
water: Not miscible or difficult to mix.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Organic solvents: 95.6 %
VOC (EU) 97.2 %
· 9.2 Other information No further relevant information available.
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· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.
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· IMDG AEROSOLS
· IATA AEROSOLS, flammable
· 14.3 Transport hazard class(es)
· ADR
· Class 2 5F Gases.
· Label 2.1
· IMDG, IATA
· Class 2.1
· Label 2.1
· 14.4 Packing group
· ADR, IMDG, IATA Void
· 14.5 Environmental hazards:
· Marine pollutant: No
· 14.6 Special precautions for user Warning: Gases.
· Danger code (Kemler): -
· EMS Number: F-D,S-U
· Stowage Code SW1 Protected from sources of heat.
SW22 For AEROSOLS with a maximum capacity
of 1 litre: Category A. For AEROSOLS with a
capacity above 1 litre: Category B. For WASTE
AEROSOLS: Category C, Clear of living quarters.
· Segregation Code SG69 For AEROSOLS with a maximum capacity of
1 litre: Segregation as for class 9. Stow "separated
f rom " c lass 1 ex cept f or divis ion 1.4. For
AEROSO LS with a c apacity above 1 litre:
Segregation as for the appropriate subdivision of
class 2. For WASTE AEROSOLS: Segregation as
for the appropriate subdivision of class 2.
· 14.7 Transport in bulk according to Annex II
of Marpol and the IBC Code Not applicable.
· Transport/Additional information:
· ADR
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· Transport category 2
· Tunnel restriction code D
· IMDG
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
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