(1001CJA101022240016) Test Pattern

CLASSROOM CONTACT PROGRAMME JEE (Advanced)

UNIT TEST
(Academic Session : 2024 - 2025)
20-10-2024

JEE(Main + Advanced) : ENTHUSIAST COURSE (PHASE : II)

ANSWER KEY PAPER-2 (OPTIONAL)
PART-1 : PHYSICS
Q. 1 2 3 4 5 6
SECTION-I (i)
A. A,B,C C,D C,D A,D A,C,D A,C
Q. 7 8 9 10
SECTION-I (ii)
A. A C A C
Q. 1 2 3 4 5 6 7 8
SECTION-II
A. 440.00 153.00 354.00 2.00 0.50 1.41 4.00 9.00

PART-2 : CHEMISTRY
Q. 1 2 3 4 5 6
SECTION-I (i)
A. A,B,C,D C,D A,B,C A,B B,D C,D

Q. 7 8 9 10
SECTION-I (ii)
A. A C B B
Q. 1 2 3 4 5 6 7 8
SECTION-II
A. 3.00 3.00 6.00 3.00 4.00 7.00 4.00 2.00

PART-3 : MATHEMATICS
Q. 1 2 3 4 5 6
SECTION-I (i)
A. B,C,D A,C D A,B A,B,C,D A,B,C
Q. 7 8 9 10
SECTION-I (ii)
A. A B C C
Q. 1 2 3 4 5 6 7 8
SECTION-II
A. 2.00 9.00 0.00 4.00 8.00 11.00 3.00 8.00

HINT – SHEET
PART-1 : PHYSICS 4. Ans ( A,D )
v
SECTION-I (i) f = fs ( )
v−u
3. Ans ( C,D ) (A) f = f0 ( v ) = 5f0
y = A sin ω t v − 0.8v

or y = A sin( 2π t) (B) f = 2f0 ( v ) = 10f0

v − 0.8v
T
y = A sin(
2π T
× ) at t =
T (C) f = 0.5f0 ( v ) = 2.5f0
v − 0.8v
T 8 8
y = A sin π /4 (D) f = 1.5f0 ( v ) = 3f0
v − 0.5v
A
y=
√2
All node energy density is zero and at antinode
All odd harmonics are available in closed pipe
it is maximum therefore it is not possible to
equal after T second. therefore
12
Note: It is point where displacement of particle correct Ans (A,D)
become zero.
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PART-1 : PHYSICS 3. Ans ( 354.00 )
SECTION-I (ii) E0 = 200
7. Ans ( A ) 1
I= ε0 E02 ⋅ C
2
Theoretical
Radiation pressure
8. Ans ( C ) 2I
nh P=
mvr = C
2π 2 1
mv2 K = ( ) ( ε0 E02 C)
= C 2
r r2 2
2 = ε0 E0
mv r = K
1 = 8.85 × 10−12 × 2002
v∝
n
= 8.85 × 10−8 × 4
r ∝ n2
354
1 =
ω∝ 109
n3
T ∝ n3 5. Ans ( 0.50 )
3ℓ2 − 5ℓ1
(e = )
PART-1 : PHYSICS 2
3 × 74 − 5 × 44
SECTION-II e=
2
1. Ans ( 440.00 ) 6. Ans ( 1.41 )
Secondary minimum 1 √T 1 √ T
f= =
2L μ 2L a0 ρ
nλ
sin θ = 1
α f∝
nλr √ρ
sin θ =
d
=√
f1 ρ2 2ρ
n=1 =√ = √2 = 1.41
f2 ρ1 ρ
λr
sin θ = ...... (i) 7. Ans ( 4.00 )
α
= R[ 2 − 2 ]
1 1 1
Secondary maximum
λ n1 n2
(2n + 1)λ
sin θ = n1 = 3 for Paschen series
2α
n=1 PART-2 : CHEMISTRY
3λ SECTION-I (i)
sin θ = ..... (ii)
2d 2. Ans ( C,D )
(i) = (ii) 3SiF4 + 4H2O → Si(OH)4 + 2H2[SiF6]
λr 3λ Option (C) is correct.
=
d 2d Partial hydrolysis takes place.
2λr
λ= Since there is complex formation of SiF4
3
2 × 660 × 10−9 SiF4 + 4H2O → Si(OH)4 + 4HF4
=
3 2SiF4 + 4HF4 → 2H2 [SiF6]
λ = 440 nm Option (D) is also correct.
Option (C, D) is correct.
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3. Ans ( A,B,C ) 8. Ans ( C )
1° amines can be prepared by Gabriel synthesis on standing
(A) CrO5 −−−−−−→ Cr+3 + O2
but 1° anmalie amine cannot. H+
7 + C2 O4 −−
(B) Cr2 O2− 2−
→ Cr+3 + CO2
5. Ans ( B,D ) (C) MnO2 + conc. KOH + O2 K2MnO4 +
Use initial rate law method, let the reaction be H2O
(D)
first order, KMnO4 + conc. KOH → K2 MnO4 + O2 + H2 O

2.303 a 10. Ans ( B )

So, k = log
t a−x 0.059 (PH2 )c [H + ]2a
2.303 0.4
(P) Ecell = – log ,
2
(B) At t = 20 s, k1 = log ( ) (PH2 )a [H + ]2c
20 0.2 0.01 × (0.1)
2
0
Ecell = – 0.059 log
and at t = 40 s, k2 = 2.303 log ( 0.4 ) = k1 2 (0.1) × (1)
2
40 0.1
0.059
= × 3 = +ve
⇒ Assumption is correct (k1 = k2) 2

0.693 (Q) Cell reaction Ag+c (10–2) → Ag+a (10–9)

Rate at 20s = k[A] = × 0.2
20
0 0.059 10−9
Ecell = Ecell – log
= 0.0063 ≈ 7 × 10–3 Ms–1 1 10−2
0 0.059
= Ecell + ×7>0
Clearly, half life t1/2 = 20s 1

6. Ans ( C,D )
0
Ecell ≠ 0 and not conc. cell

In AgNO3 solution, the solubility of AgCN will 0.059 [Cu+2 ]a

(R) Ecell = 0 – log
2 [Cu+2 ]c
decrease as compared to pure water because of 0.059 0.1
=− log = –ve
2 0.01
common ion effect of Ag+ ion 0.059 [Cl− ]c 0.059 0.2
(D) Ecell = – log = log
2 −
[Cl ]a 2 0.1
In NH3 solution and buffer of pH = 5, the
0
Ecell =0
solubility of AgCN will increase due to
PART-2 : CHEMISTRY
complex formation in case of NH3 solution and
SECTION-II
in case of buffer of pH = 5. 1. Ans ( 3.00 )
A, D, E
PART-2 : CHEMISTRY
2. Ans ( 3.00 )
SECTION-I (ii)
P = 2 [Cu, Sn]
7. Ans ( A )
Q = 1 [Cr]
(P)-(1,2,3); (Q)-(4); (R)-(1,4); (S)-(1,5)
P+Q=3

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3. Ans ( 6.00 ) 3. Ans ( D )
a, b, e, f, g, h Put x = 1
5. Ans ( 4.00 )
b, c, i, k 3n = 243 gives n = 5
5
2
6. Ans ( 7.00 ) (x2 + ) , term independent of x is
o o 0.059 x3
ECl − /AgCl/Ag = EAg + /Ag + log Ksp r
2
1 ( )
10−2r
Tr+1 = 5 Cr (x) ;∴r=2
0.21 = 0.80 + 0.059 log Ksp x3
1 2
T3 = 5 C2 (2) = 40
∵ Ksp = 10 – 10
4. Ans ( A,B )
Let solubility of AgCl in 0.01 M NaCl be x ƒ(x) = xsinx
AgCl ⇌ [Ag+] [Cl–] ƒ'(x) = sinx.xsinx – 1 + xsinx(logex)cosx
π
f ′ ( ) = 1 , f ′ (π) = −loge π
10–10 = x(x + 0.01) 2
5. Ans ( A,B,C,D )
x = 10–8 mol/lit Each of the given options are identical
functions.
Moles of AgCl dissolved in 10 L = 10–8 × 10 = 10–7
PART-3 : MATHEMATICS
∵y=7
SECTION-I (ii)
7. Ans ( 4.00 ) 7. Ans ( A )
Theoritical
According to Le-Chatelier principle (P) Vector coplanner with a & b
(i), (ii), (iii), (v) are correct. is λ→a + μ→b = (λ + μ)i^ + (λ − μ)j^ + (−λ + μ)k^
PART-3 : MATHEMATICS
which is ⊥ to →a if
SECTION-I (i)
(λ + μ) + (λ − μ) + (−λ + μ)(−1) = 0
2. Ans ( A,C )
3λ = μ
|A| = x3 + x2 – 5x
(Q) Let required vector is xi^ + yj^ + zk^
ƒ(x) = x3 + x2 – 5x
then 2x – y + z = 0 ........(i)
ƒ'(x) = 3x2 + 2x – 5 = 0
x+y=0 ........(ii)
3x2 + 5x – 3x – 5 = 0 by (i) & (ii) x = 0, y = z
5 →b × →c = −i^ + 2j^ + 3k^
⇒x=− & x = 1, f (1) (− 5 ) < 0 (R)
3 3
(S) →a × →c = ^i + k^
Three distinct real roots.

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8. Ans ( B )
cos θ − sin θ 0 −1 (S) y = Axm + Bx – n is solution of
A (θ) = [ ] ⇒ A( ) = [ ]
π
sin θ cos θ 2 1 0 d2y dy
0 −1 0 −1 −1 0 x2 + 2x = 12y ...(1)
A2 ( ) = [ ][ ]=[ ] = −I
π
(P) 2 dx2 dx
1 0 1 0 0 −1
(Q) B2 = (A X AT)(A X AT) = A X dy
= mAxm−1 − nBx−n−1
(ATA)XAT dx
= AX2AT ( ∵ A is orthogonal) d2y
= AAT ( ∵ X2 = I) = m(m − 1)Axm−2 − n(n + 1)Bx−n−2
dx2
=I
(R) BA = (A X AT)A = AX = m(m – 1)Axm – 2 + n(n + 1)Bx – n – 2
⇒ A – 1BA = A – 1AX = X
(S) ∵ X2 = I and B2 = I
∴ Put in equation (1)
⇒ B2 – X2 = 0
9. Ans ( C )
⇒ x2(m(m – 1)Axm – 2 + n(n + 1)Bx – n – 2) +
(P) y= e4x + 2e – x
dy
= 4e4x − 2e−x 2x(mAxm – 1 – nBx – n – 1)
dx
d2y
= 16e4x + 2e−x
dx 2
d3y = 12(Axm + Bx – m)
= 64e4x − 2e−x
dx 3

∴ m(m – 1)Axm + n(n + 1)Bx – n + 2mAxm – 2nBx – n

d3y dy
− 13 = (64e4x − 2e−x ) − 13 (4e4x − 2e−x )
dx3 dx = 12Axm + 12Bx – m

= 12e4x + 24e – x
∴ m(m – 1)A + 2mA = 12A
= 12(e4x + 2e – x)
= 12y
⇒ m(m − 1) + 2m = 12 ⇒ m = 3
K = 12 P →2
(Q) Two lines are possible Q→3
n(n + 1)B – 2nB = 12B
dy
(R) 2x y + y 4 = 4x6
4
dx
y = um ⇒ n(n + 1) − 2n = 12 ⇒ n = – 3
dy du
= mum−1
dx dx m+n=0 S→4
4 m m−1 du
2x u mu + u4m = 4x6
dx
m2x4 u2m−1 ( ) + (u)4m = 4 (x6 )
du
dx
∴ 2m – 1 + u = 4m = 6
3
⇒ m= , 2m = 3 R→1
2
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10. Ans ( C ) PART-3 : MATHEMATICS
(P) Let f(x) = sin−1 x2 + tan−1 x2 is ↑ even function SECTION-II
and domain is [–1. 1]
1. Ans ( 2.00 )
f(x)|min = f(0) = 0
∣→a + →b∣ = ∣−→c − →d∣
π π 3π ∣ ∣ ∣ ∣
f(x) |max = f(1) = + =
2 4 4 1 1 1 1 1 1
3π ⇒ + + 2. . cos θ1 = + 1 + 2. .1 cos θ2
f(x) ∈ [0, ] 4 9 2 3 36 6
4
If k = 0, 2k + 1 = 1, possible
⇒ cos θ1 − cos θ2 = 2
If k = 1, 2k + 1 = 3 > 3π Not possible
4
i.e. only one integral value of k is possible. 2. Ans ( 9.00 )
(Q) T = tan ( k8 ) = tan 2 = tan
K
−1 −1 −1 2
Let l, m, n be the direction cosines of the line
1 + ( 2 − 1) ( 2 + 1)
2 k2 k k
4

TK = tan−1 ( + 1) − tan−1 ( − 1)
k k MN which is perpendicular to each of the given
2 2
3 −1
T1 = tan7 − tan−1 ( ) lines
2 2
4
T2 = tan−1 − tan−1 0 ∴ – 4l + 3m + 2n = 0 and – 4l + m + n = 0
2
−1 5 1 l m n
T3 = tan − tan−1 Solving = =
2 2 2 −8 + 4 −4 + 12
−1 6 −1 2
T4 = tan − tan l m n √ l 2 + m2 + n 2 1
2 2 ⇒ = = = =
−1 7 −1 3 1 −4 8 √1 + 16 + 64 9
T5 = tan − tan
2 2 1 4 8
: ⇒ l = , m = − ,n =
9 9 9
: It is obvisous that the points P( – 3, 6, 0) and
Sum = 2π − (− tan 12 + tan 12 + tan 1) = 74π
−1 −1 −1
⇒ p = 7, q = 4

(2π is sum of last four term) Q( – 2, 0, 7) are situated on the given line
(R) we know tan−1 x + cot−1 y = π ⇒ x=y
Length of shortest distance
2
according to question
= Projection of PQ on the common

Only posssible ⇒ sin θ − 1 = −2 perpendicular MN

sin θ = −1 1 4 8
2 2
{(−2) − 3)} + (− ) [0 − 6] + [7 − 0] = 9
sec y = 1 ⇒ cos y = 1 9 9 9
cos2 y − sin θ = 2 3. Ans ( 0.00 )
1 − |x| 1 − |x| 2 3
(S) sec−1 ( ) ⩾ 0 ⇒ ⩾1 It is possible when =
2 2 x x
1 − |x| ⇒ Not possible
or ⩽ −1
2
1 – | x | ≥ 2 or 3 ≤ | x | 4. Ans ( 4.00 )
∞ ∞
– 1 ≥ | x | or x ∈ (−∞, −3] ∪ [3, ∞) dx ex π
∫ ∫
∞
= dx = (tan−1 ex )0 =
Not possible ex + e−x 1+e 2x 4
0 0
least positive integer is 3

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5. Ans ( 8.00 ) 7. Ans ( 3.00 )
Area 2 OR loga + logb + logc
∵ a, b, c are distinct
⇒ loga + logb + logc = 0

2
⇒ abc = 1
= 2 ∫ [x√4 − x2 − (x2 − 4)]dx = 16 ⇒ b3 = 1 ( ∵ b2 = ac)
0
1
⇒ b=1 ⇒ ac = 1 ⇒ c=
6. Ans ( 11.00 ) a
dy ⇒ System become
= 2ax − b = 2a − b = 3
dx
3+b (loga)x – (loga)z = 0
a=
2
– (loga)y + (loga)z = 0
∵ 5 ⩽ a ⩽ 10
– (loga)x – (loga)y = 0
3+b x–z=0
⇒ 5⩽ ⩽ 10 ⇒ 10 ⩽ 3 + b ⩽ 20 ⇒
2
y–z=0
⇒ 7 ⩽ b ⩽ 17
x–y=0
7. Ans ( 3.00 )
⇒ x=y=z
∴ VA = 0 (Null matrix) x y z
⇒ solutions lie on = =
1 1 1
⇒ (loga)x + (logb)y + (logc)z = 0
⇒ α:β:γ=1:1:1
(logb)x + (logc)y + (loga)z = 0 α β γ
+ + =3
β γ α
(logc)x + (loga)y + (logb)z = 0 8. Ans ( 8.00 )
x−2 y+1 z−2
which is homogenesis system of linear = = =λ
3 4 12
x = 3λ + 2
equations in x, y and z.
y = 4λ – 1
∵ x, y, z ≠ 0 z = 12 λ + 2

⇒ system posseses non trivial solutions. ∴ (3 λ + 2) – (4 λ – 1) + (12 λ + 2) = 5

∣ log a log b log c ∣ 11 λ + 5 = 5

∣ ∣
λ=0
⇒ D = ∣∣ log b log c
∣
log a ∣ = 0
∣ ∣ hence point of intersection is (2, – 1,2)
∣ log c log a log b ∣
d = √9 + 16 + 144
⇒ loga + logb + logc = 0
d = 13

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