PRACTICE

TEST
 CHEMISTRY
1. 7.65 × 10–3 moles of NaNO3 require 3.06 × 10–2 moles of reducing agent to get reduced to NH3. What is n-factor of
reducing agent?
(1) 4 (2) 3
(3) 2 (4) 5
2. Which of the following reactions is not a redox reaction ?
(1) H2 + Br2  2HBr
(2) 2I– + Cl2  2Cl– + I2
(3) 2NO3–+8H++3CuS3Cu+2+ 2NO + 4H2O+3S
(4) CaOCl2  Ca+2 + OCl– + Cl–
3. 8Al + 3Fe3O4  4Al2O3 + 9Fe
In the reaction how many total electrons will be transferred :-
(1) 12 (2) 24
(3) 20 (4) 14
N
4. In acidic medium 20ml solution of KMnO4 completely reacts with 20ml of H2O2 solution. What is volume
0.28
strength of H2O2 :-
(1) 10 (2) 20
(3) 30 (4) 40
5. AB4– + C+2  C+3 + A+2
If the O.N. of B is –2. Choose the true statement for the above change :-
(1) O.N. of A decreases by –5
(2) O.N. of C decreases by +1
(3) O.N. of A decreases by +5 and that of C increases by +1
(4) O.N. of A decreases by +5 and that of C decreases by +1
6. When one mole NO3– is converted into 1 mole NO2, 0.5 mole N2 and 0.5 mole N2O respectively. It accepts x, y and
z mole of electrons- x, y, and z are respectively :-
(1) 1, 5, 4 (2) 1, 2, 3
(3) 2, 1, 3 (4) 2, 3, 4
7. In the redox titration 50ml of 0.4M Ce4+ solution is needed to convert 100ml of 0.1M Sn2+ to Sn4+. What is the
oxidation number of Ce in the reduced product ?
(1) +1 (2) +2
(3) +3 (4) 0
8. How many moles of nitrogen is produced by the oxidation of one mole of hydrazine by 2/3 mole bromate ion :-

1
(1) (2) 1
3
(3) 1.5 (4) 10
9. 9.8 ml of 0.1N K2Cr2O7 + 2 ml of 0.01N K2Cr2O7 solution is needed for the complete oxidation of 10 ml ferrous
ammonium sulphate solution. What is the normality of Fe(II) ?
(1) 1N (2) 0.01N
(3) 0.1N (4) 0.001N

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10. WO3+8CN–+2H2O[W(CN)8]4– + 1/2 O2 + 4OH– In the above process, oxidant is :-
(1) WO3 (2) CN–
(3) H2O (4) O 2
11. 50 ml. of 0.1M metal salt reacts completely with 25 ml. of 0.1M sodium sulphite. In the reaction SO3–2 is oxidised
to SO4–2. If the oxidation number of metal in the salt is +3, what is its new oxidation number ?
(1) 0 (2) 2
(3) 1 (4) 4
12. A current of 2.0A is passed for 5 hours through a molten metal salt deposits 22.2 gm of metal
[At. wt. = 177]. The oxidation state of the metal in the metal salt is :-
(1) +1 (2) +2
(3) +3 (4) +4
13. Oxidation number of S in H2SO5 is 6. This is observed, because :-
(1) There are five oxygen atoms in the molecule.
(2) The hydrogen atom is directly linked with non-metal
(3) There is peroxide linkage in the molecule
(4) The sulphur atom shows co-ordinate linkage
14. A, B and C have the oxidation number of +6, –2 and –1 respectively. The possible molecular formula when these
atoms combine :-
(1) A 2BC (2) AB2C 2
(3) ABC2 (4) AB 2C
15. ne mole of N2H4 loses ten moles of electron to form a new compound y. Assuming that all nitrogen appears in the
new compound, what is the oxidation number of nitrogen in y :-
(Note:- There is no change in the oxidation state of hydrogen) :
(1) –3 (2) +3
(3) –1 (4) +5
16. Compound in which the oxidation number of nitrogen is +1, is :-
(1) Nitric oxide (2) Nitrous oxide
(3) Nitrogen oxide (4) Ammonia
17. In the alkaline medium the reaction of KMnO4 is represented as :
2KMnO 4 + H 2O  MnO 2 + 2KOH + O
The molecular weight of KMnO4 is 158. What is its equivalent weight :
(1) 52.66 (2) 158
(3) 31.6 (4) 79
18. HBr and HI reduce sulphuric acid, HCl can reduce KMnO4 and HF can reduce :-
(1) H 2SO 4 (2) KMnO 4
(3) K 2Cr 2O 7 (4) None of these
19. Element or the radical that serves as oxidant in case of aqua-regia (HNO3 + HCl) would be :-
(1) NO 3– (2) Cl
(3) NO 2+ (4) H+

3
20. In the balanced equation :
2MnO4– + 6P + 10Q  2Mn+2 + 8H2O + 5Cl2 :
P and Q are respectively :
(1) Cl– and H+ (2) H+ and HCl
(3) HCl and OCl– (4) HCl and H+
21. How many moles of K2Cr2O7 are reduced by 1 mole of formic acid :-

1
(1) Mole (2) 1 Mole
3

2 4
(3) Mole (4) Mole
3 5
22. Which of the following is not a intramolecular redox ?
(1) NH 4NO 2  N 2 + 2H 2O (2) 2Mn 2O 7  4MnO 2 + 3O 2
(3) 2KClO 3  2H 2O + O 2 (4) 2H 2O 2  2H 2O + O 2
23. Oxidation state of nitrogen is incorrectly given for :-

Compound Oxidation state

(1) [Co(NH3)5Cl]Cl2 –3
(2) NH2OH –1
(3) (N2H5)2SO4 +2
(4) Mg3N2 –3

24. Equivalent mass of FeC2O4 in the change.

 Fe3  CO2
FeC2O 4 
(1) M/3 (2) M/6
(3) M/2 (4) M/1
25. In the reaction, xBrO3– + yCr3+
+ zH2O ® Br2 + HCrO4– + H+, the coefficients x, y and z are :-
(1) 6, 8, 22 (2) 6, 10, 22
(3) 6, 10, 11 (4) 6, 10, 20
26. Order of electronegativity of element F, X & Cl is as
F > X > Cl
Then calculate oxidation no. of 'X' in following structure.
Cl F
X
Cl Cl
(1) +1 (2) –1
(3) 0 (4) –2
27. In which of the following reaction H2O is working as reducing agent.
(1) 2KI + H2O2  2KOH + I2
(2) 2FeSO4 + H2SO4 + H2O2  Fe2(SO4)3 + 2H2O
(3) Ag2O + H2O2  2Ag + H2O + O2
(4) H2SO3 + H2O2  H2SO4 + H2O2
28. Which of the following acts as reducing agent :-
(1) K4[Fe(CN)6] (2) Fe(CO) 5
(3) [Co(NH3)6]2+ (4) None of these

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29. The equivalent mass of KIO3 in the reaction is :
2Cr(OH)3 + 4OH– + KIO3  2CrO42– + 5H2O + KI
(1) M (2) M/6
(3) M/3 (4) M/4
30. For decolourisation of 1 mol of KMnO4, the moles of H2O2 required is :
MnO4– + H2O2  Mn2+ + O2
(1) 1/2 (2) 3/2
(3) 5/2 (4) 7/2
31. Increasing order oxidation number of S in the compounds is:-
(1) KHSO3 < Na2SO4 < (NH4)2S2 < S8 (2) S8 < (NH4)2S2 < KHSO3 < Na2SO4
(3) (NH4)2S2 < S8 < KHSO3 < Na2SO4 (4) Na2SO4 < KHSO3 < (NH4)2S2 < S8
32. When KMnO4 acts as an oxidizing agent and ultimately forms MnO42–, MnO2, Mn2O3 & Mn2+, then the no. of e–s
gained by KMnO4 in each case respectively is :-
(1) 4, 3, 1, 5 (2) 1, 5, 3, 7
(3) 1, 3, 4, 5 (4) 3, 5, 7, 1
33. Oxidation number of carbon in C3O2, Mg2C3 are respectively :-
(1) –4/3, +4/3 (2) +4/3, –4/3
(3) –2/3, +2/3 (4) –2/3, +4/3
34. Balanced form of this reaction
N2O4 + BrO3  NO3 + Br– (in acidic medium)


(1) 2N2O4 + BrO3 + 2H2O  4 NO3 + 4H+ +Br–



(2) 3N2O4 + BrO3 + 3H2O  4 NO3 + 4H+ +Br–



(3) 3N2O4 + BrO3 + 3H2O  6 NO3 + 6H+ +Br–



(4) 3N2O4 + BrO3 + 2H2O ® 4 NO3 + 4H+ +Br–



35. 2MnO4– + 5H2O2 + 6H+  2Z + 5O2 + 8H2O. In this reaction Z is :-

(1) Mn+2 (2) Mn+4
(3) MnO2 (4) Mn
36. Which one is not correct for the reaction :-
(CN)2 + H2O  HCN + HOCN
(1) It is an auto redox change
(2) Ox. no. of C in (CN)2, HCN and HOCN are +2, +3 and +4 respectively
(3) Ox. no.of N in (CN)2, HCN and HOCN are +3, +2 and + 4 respectively
(4) none
37. Select disproportion reaction
(A) HgCl2 
NH3 (B) Hg2Cl2 
NH3

(C) HgI2 
KI
 (D) NH4NO3 


(E) K2Cr2O7 

 (F) H2O2 
KMnO 4

(G) NO2 

H 2O

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 Correct option are :-
(1) B, D, F (2) A, B, C, F, G
(3) B, G (4) C, D, E, G
38. In which reaction no colour change will be observed :-
(1) K2Cr 2O7 
CO 2 (2) K2Cr 2O7 
SO2

(3) Na2CrO4 

CO 2 (4) Na2S 
Na 2 [Fe(CN)5 NO]


39. Which of the following reactions does not involve oxidation-reduction ?
(a) 2Rb + 2H2O  2RbOH + H2
(b) 2CuI2  2CuI + I2
(c) NH4Cl + NaOH  NaCl + NH3 + H2O
(d) 4KCN + Fe(CN)2  K 4[Fe(CN)6]
(1) a, b (2) b, c
(3) c,d (4) a,b,d
40. In the reaction
P2H 4 — PH3 + P 4H 2
the equivalent mass of P 2H4 may be given as :
(M = Mol.wt of P 2H 4)
3M 5M
(1) (2)
4 6

3M 12M
(3) (4)
5 13
41. For the redox reaction,
MnO4– + C2O42– + H+ — Mn2+ + CO2 + H2O
The correct coefficients of the reactants for the balanced reaction are :-

MnO4– C2O42– H+
(1) 2 5 16
(2) 16 5 2
(3) 5 16 2
(4) 2 16 5

42. The colour of K2Cr2O7 changes from red orange to lemon-yellow on treatment with KOH (aq.), because of :-
(1) Reduction of Cr (VI) to Cr (III)
(2) Formation of chromium hydroxide
(3) Conversion of dichromate into chromate ion
(4) Oxidation of potassium hydroxide to potassium peroxide

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43. How many gram of I2 are present in a solution which requires 40 mL of 0.11 N Na2S2O3 to react with it, S2O32– + I2
— S4O62– + 2I–

(1) 12.7 g (2) 0.558 g

(3) 25.4 g (4) 11.4 g

44. One mole KMnO4 oxidises how many moles of ferrous oxalate :-

1 5
(1) (2)
5 3

1 2
(3) (4)
3 3
45. Which of the following is not a intramolecular redox ?
(1) NH 4NO 2  N 2 + 2H 2O (2) 2Mn 2O 7  4MnO 2 + 3O 2
(3) 2KClO 3  2H 2O + O 2 (4) 2H 2O 2  2H 2O + O 2
46. Statement - 1 : The oxidation state of S in H 2S2 O8 is 6
Statement - 2 : Max. oxidation state of S is 6 because the max. oxidation state of an element is it’s no. of valence
electron
(1) If both statements are correct and Statement-2 is correct explanation of statement - 1
(2) If both statements are correct but statement - 2 is not correct explanation of statement - 1
(3) If statement - 1 is correct but statement - 2 is wrong
(4) If both statements are wrong
(5) If statement - 1 is wrong but statement - 2 is correct
47. Statement - 1 : MnO 2 can act as an oxidizing agent as well as reducing agent.
Statement - 2 : Oxidation state of Mn lies between highest and lowest oxidation state.
(1) If both statements are correct and Statement-2 is correct explanation of statement - 1
(2) If both statements are correct but statement - 2 is not correct explanation of statement - 1
(3) If statement - 1 is correct but statement - 2 is wrong
(4) If both statements are wrong
(5) If statement - 1 is wrong but statement - 2 is correct
48. Statement - 1 : Equivalent volume of H 2 is 11.2 L at 1 atm and 273 K
Statement - 2 : 1/2 mole H 2 has produced when 1 mole of H (aq) accepted 1 mole of electron.
(1) If both statements are correct and Statement-2 is correct explanation of statement - 1
(2) If both statements are correct but statement - 2 is not correct explanation of statement - 1
(3) If statement - 1 is correct but statement - 2 is wrong
(4) If both statements are wrong
(5) If statement - 1 is wrong but statement - 2 is correct

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49. Statement - 1 : H 2 O 2  aq  can behave as an oxidant or reductant.

Statement - 2 : H 2 O 2  aq  can be converted into H 2 O only

(1) If both statements are correct and Statement-2 is correct explanation of statement - 1
(2) If both statements are correct but statement - 2 is not correct explanation of statement - 1
(3) If statement - 1 is correct but statement - 2 is wrong
(4) If both statements are wrong
(5) If statement - 1 is wrong but statement - 2 is correct
4
50. Statement - 1 :  Fe  CN 6   Fe3  CO2  NO3 , the equivalent weight of reactant is 3.74

Mol.wt
Statement - 2 : Equivalent weight of reactant 
61
(1) If both statements are correct and Statement-2 is correct explanation of statement - 1
(2) If both statements are correct but statement - 2 is not correct explanation of statement - 1
(3) If statement - 1 is correct but statement - 2 is wrong
(4) If both statements are wrong
(5) If statement - 1 is wrong but statement - 2 is correct
51. Statement - 1 : In the balanced redox reaction
xAs 2S3  yNO3  4H 2 O  aAsO34  BNO  cSO24   8H

the n - factor of As 2S3 and NO3 is 28 and 3 respectively..

Statement - 2 : Molar ratio is reciprocal of n - factor’s ratio so x : y is 3 : 28.
(1) If both statements are correct and Statement-2 is correct explanation of statement - 1
(2) If both statements are correct but statement - 2 is not correct explanation of statement - 1
(3) If statement - 1 is correct but statement - 2 is wrong
(4) If both statements are wrong
(5) If statement - 1 is wrong but statement - 2 is correct
52. Statement - 1 : NaOH  H 3 PO 4  NaH 2 PO 4  H 2 O in given reaction equivalent weight of H 3 PO 4 is M/3
Statement - 2 : H 3 PO 4 is tribasic acid
(1) If both statements are correct and Statement-2 is correct explanation of statement - 1
(2) If both statements are correct but statement - 2 is not correct explanation of statement - 1
(3) If statement - 1 is correct but statement - 2 is wrong
(4) If both statements are wrong
(5) If statement - 1 is wrong but statement - 2 is correct
53. Statement - 1 : In CrO 5 oxidation number of Cr is +6
Statement - 2 : CrO 5 has butterfly structure in which perioxide bonds are present

O
O O
Cr
O O

8
 (1) If both statements are correct and Statement-2 is correct explanation of statement - 1
(2) If both statements are correct but statement - 2 is not correct explanation of statement - 1
(3) If statement - 1 is correct but statement - 2 is wrong
(4) If both statements are wrong
(5) If statement - 1 is wrong but statement - 2 is correct
54. Statement - 1 : I 2  IO3  I  . This rection is a disproportionation reaction
Statement - 2 : Oxidation number of 1 can vary from - 1 to + 7
(1) If both statements are correct and Statement-2 is correct explanation of statement - 1
(2) If both statements are correct but statement - 2 is not correct explanation of statement - 1
(3) If statement - 1 is correct but statement - 2 is wrong
(4) If both statements are wrong
(5) If statement - 1 is wrong but statement - 2 is correct
55. Statement - 1 : Fluorine exists only in - 1 oxidation state
Statement - 2 : Fluorine has 2s 2 2p5 configuration.
(1) If both statements are correct and Statement-2 is correct explanation of statement - 1
(2) If both statements are correct but statement - 2 is not correct explanation of statement - 1
(3) If statement - 1 is correct but statement - 2 is wrong
(4) If both statements are wrong
(5) If statement - 1 is wrong but statement - 2 is correct
56. Statement - 1 : H 2SO 4 can not act as reducing agent
Statement - 2 : Sulphur can not increase its oxidation number beyond + 6
(1) If both statements are correct and Statement-2 is correct explanation of statement - 1
(2) If both statements are correct but statement - 2 is not correct explanation of statement - 1
(3) If statement - 1 is correct but statement - 2 is wrong
(4) If both statements are wrong
(5) If statement - 1 is wrong but statement - 2 is correct
Molecular mass
57. Statement - 1 : Equivalent mass of a base  Acidity
Statement - 2 : Acidity is the number of replaceable hydrogen atoms in one molecule of the base
(1) If both statements are correct and Statement-2 is correct explanation of statement - 1
(2) If both statements are correct but statement - 2 is not correct explanation of statement - 1
(3) If statement - 1 is correct but statement - 2 is wrong
(4) If both statements are wrong
(5) If statement - 1 is wrong but statement - 2 is correct

9
58. Statement - 1 : The oxidation state of superoxide ion in KO 2 ,CsO 2 and RbO 2 is -1/2
Bacause
Statement - 2 : Since the oxidation state of an alkali metal in any compound is always +1, the oxidation state of
oxygen is -1/2 in the O2 ion
(1) Statement - 1 is true, Statement - 2 is true; Statement - 2 is correct explanation for Statement - 1
(2) Statement - 1 is true, Statement - 2 is true; Statement - 2 is NOT correct explanation for Statement - 1
(3) Statement - 1 is true, Statement - 2 is false
(4) Statement - 1 is false, Statement - 2 is true
59. Statement - 1 : In the redox reaction 8H   aq   4NO3  6Cl  Sn  s   SnCl62  4NO2  4H 2 O
Bacause
Statement - 2 : In balancing half reaction, S2 O32  S  s  , the number of electrons added on the left is 4
(1) Statement - 1 is true, Statement - 2 is true; Statement - 2 is correct explanation for Statement - 1
(2) Statement - 1 is true, Statement - 2 is true; Statement - 2 is NOT correct explanation for Statement - 1
(3) Statement - 1 is true, Statement - 2 is false
(4) Statement - 1 is false, Statement - 2 is true
60. Statement - 1 : Among Br  ,O 22  ,H and NO3 , the ions that could not act as oxidising agents are Br  and H.
Bacause
Statement - 2 : Br  and H could not be reduced
(1) Statement - 1 is true, Statement - 2 is true; Statement - 2 is correct explanation for Statement - 1
(2) Statement - 1 is true, Statement - 2 is true; Statement - 2 is NOT correct explanation for Statement - 1
(3) Statement - 1 is true, Statement - 2 is false
(4) Statement - 1 is false, Statement - 2 is true

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