CTM 15

Sec: JR_*CO-SC Date: 08-11-20
Time: 3 Hrs Max. Marks: 300
Name of the Student: ___________________ H.T. NO:
08-11-20_JR. STAR CO-SUPER CHAINA_Jee-Main_CTM-15_SYLLABUS
PHYSICS: 100% CUMULATIVE:

SYLLABUS COVERED FROM 18-04-20 TO 07-11-20
CHEMISTRY: 100% CUMULATIVE:

MATHEMATICS: 100% CUMULATIVE:

Narayana IIT Academy 08-11-20_Jr.IIT_*CO-SC _JEE-MAIN_CTM-15_Q’P
PHYSICS MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
1. A rod of length L is pulled with a force F as shown on a smooth horizontal surface. If A
is the area of cross-section and Y the Young’s modulus of the material of the rod, the
elastic potential energy stored in the rod is
F 2L F 2L F 2L F 2L
(A) (B) (C) (D)
3YA 2YA 6YA YA
2. A small sphere and a big sphere are released from rest with a very small gap from height
h as shown in the figure. The mass of bigger sphere is very large as compared to mass of
smaller sphere the height from the point of collision of smaller sphere with the bigger
sphere to which the smaller sphere will rise if all the collisions are elastic
(A) 2h (B) 4h (C) 6h (D) 9h

3. A bob is attached to one end of a string other end of which is fixed at peg A. The bob is
taken to a position where string makes an angle of 300 with the horizontal. On the
circular path of the bob in vertical plane there is a peg ‘B’ at a symmetrical position with
respect to the position of release as shown in the figure. If VC and Va be the minimum
speeds in clockwise and anticlockwise directions respectively, given to the bob in order
to hit the peg ‘B’ then ratio Vc:Va is equal to:
(A) 1:1 (B) 1: 2 (C) 1: 2 (D) 1: 4
JR.IIT_*CO-SC Page. No. 2
The important thing in life is not the triumph but the struggle.
4. Block ‘A’ is hanging from a vertical spring and is at rest. Block ‘B’ strikes the block ‘A’
with velocity ‘v’ and sticks to it. Then the value of ‘v’ for which the spring just attains
natural length is:
60mg 2 6mg 2 10mg 2

(A) (B) (C) (D) None of these
k k k
5. A spherical object of mass 1kg and radius 1m is faling vertically downward inside a
viscous liquid in a gravity free space. At a certain instant the velocity of the sphere is
1
2 m / s . If the coefficient of viscosity of the liquid is N  s / m 2 , then velocity of ball
18
will become 0.5 m / s after a time
A) ln 4s B) 2 ln 4s C) 3ln 4s D) 2 ln 2s
6. Two heavy right circular rollers of radii R and r respectively rest on a rough horizontal
plane as shown in figure. The larger roller has a string wound around it to which a
horizontal force P can be applied as shown. Assuming that the coefficient of friction 
has the same value for all surfaces of contact and the smaller cylinder should neither roll
nor slide. The minimum coefficient of friction so that the larger roller can be pulled over
the smaller one is
(B)  
r r r r
(A) (C) 3 (D)
R R  R R
7. The moment of inertia of a square plate of side ' l ' about an axis passing through its
centre of mass and perpendicular to the plane of plate is I 0 . Then find the moment of
inertia of the shaded portion of the given lamina about AB as shown in figure. (mass per
unit area of square plate and lamina is same)
39 81 75
(A) 39I 0 (B) I0 (C) I0 (D) I0
2 2 2
8. A uniform ring of mass m and radius R is doing uniform pure rolling motion on a
horizontal surface. The velocity of the centre of the ring is V0 . The kinetic energy of the
segment AOB is
mV02 mV02 mV02 mV02 mV02

(A)  (B)  (C) (D) mV02
2  2  2
9. The rectangle shown in figure has sides parallel to the x and y axes. The position vectors
 
of two corners are A  10.0m at 530 and B  12.0m at 30.00 with positive x-axis. Find the
perimeter of the rectangle.
(A) 6.2 m (B) 24.8 m (C) 12.4 m (D) 18.6 m
10. In the shown arrangement if f1 , f 2 and T be the frictional forces on 2 kg block, 3kg block
& tension in the string respectively, then their values are:
(A) 2N,6N,3.2N (B) 2N,6N,0N
(C) 1N,6N,2N (D) Data insufficient to calculate the required values.
11. A light inelastic thread passes over a small frictionless pulley. Two blocks of masses
m = 1 kg and M = 3 kg are attached with the thread and heavy block rests on a surface.
A particle P of mass 1 kg moving upward with a velocity 10 m/s collides with the lighter
block elastically at t = 0. Choose the incorrect option, (g = 10 m/s2)
(A) Velocity with which heavy block is jerked into motion is 2.5 m/s
(B) Maximum height ascended by heavy block after it is jerked into motion is 0.625m
(C) Impulse of tension in jerk is 7.5 Ns
(D) Time after which block again strikes the surface is 2.5 s
12. An uniform chain of mass m and length l hangs by a thread and touches the surface of a
table by its lower end. The thread is cut at time t  0 . Which of the following graph best
represents the relation between force F exerted by table on the chain with time t.
(Assume that the fallen part immediately comes to rest after collision with table and do
not form heap):
(A) (B)
(C) (D)
1
13. A cart with a mass M  kg is connected by a string to a mass of m  200 g . At the initial
2
moment the cart moves to the left along a horizontal plane at a speed v0  7m / s .
 g  9.8m / s  Distance covered by cart after 5 sec is

2
(A) 3.75 (B) 17.5 (C) 20 (D) Zero
14. Block of mass m  10kg is suspended by two springs vertically as shown in the
diagram.The block is at rest initially. Find the acceleration of block just after cutting the
right spring.
5 3
(A) m / s2 (B) 10m / s 2 (C) 5 3m / s 2 (D) 5m / s 2
2
15. A large tank filled with water of density  and surface tension  is being siphoned out
using a glass capillary tube of cross-sectional radius r . If the siphon action starts without
any external agent, then (angle of contact is zero).
 2 2 
(A) H  (B) H  (C) H  h  (D) H 2  h 2 
 gr  gr  gr  gr
16. A hollow sphere of radius R is filled completely with an ideal liquid of density  .
Sphere is moving horizontally with an acceleration 2g, where g is acceleration due to
gravity in the space. If minimum pressure of liquid is P0 , then pressure at the centre of
sphere is:-
 gR
(A) P0   gR (B) P0   gR 2 (C) P0   gR 5 (D) P0 
5
17. For the arrangement as shown in the figure, the maximum force F, for no relative motion
between blocks is
(A) 12 N (B) 8 N (C) 20 N (D) 24 N
18. Consider three systems, each with three masses, m1 , m2 , m3  m1  m2  m3  with centre of
mass at point A, as shown in the figure-1, figure-2 and figure-3 respectively. The same

force F is applied on the each system separately to just one of the three masses as
shown. Which of the following statements is true.
(A) The magnitude of acceleration of centre of mass of the system is largest in figure-1.
(B) The magnitude of acceleration of centre of mass of the system is largest in figure-2.
(C) The magnitude of acceleration of centre of mass of the system is largest in figure-3.
(D) In all cases, the centre of mass of system has same acceleration.
19. Figure shows a soap film formed between two square figures made of a uniform wire.
The bigger square is held while keeping it in horizontal plane and the smaller square is
slowly allowed to drop vertically. It reaches an equilibrium state after dropping a
height h . Let surface tension of soap  T . Mass per unit length of wire   . Acceleration
due to gravity  g . Find the value of h.
3 ga 5 ga
(A) h  (B) h 
2 4T 2   2 g 2 2 4T 2   2 g 2
3 ga 3 ga
(C) h  (D) h 
2 2T   g
2 2 2
4T 2   2 g 2
20. A solid object of uniform cross section area and relative density 0.2 is pressed down and
held at rest inside water surface so that its upper surface is in level with the water
surface. Length of the object is l  1.2m . When released the object jumps out of water
moving vertically. The velocity of the object (in m/s) when it just comes out completely
from the water is (Take g  10m / s 2 )
(A) 6 m/s (B) 5 m/s (C) 4 m/s (D) 3 m/s
SECTION-II
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical value. If the numerical value has
more than two decimal places, Truncate/Round-off the value of Two decimal places. Answer to each
question will be evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, 0 in all other cases.
21. A dense liquid is completely filled in a closed large container and kept at rest on a
horizontal surface. A steel ball is moving downward with a constant speed of 0.5 cm/sec.
Find the momentum of dense liquid in C.G.S unit, if its density is 3gm / cm3 . Given that
volume of steel ball of 1.5cm3
22. A uniform rod of length L (in between the supports) and mass m=1.2kg is placed on two
supports A and B. The rod breaks suddenly at length L/10 from the support B. Find the
reaction at support A immediately after rod beaks.
23. A bead moves along straight horizontal wire of length L, starting from the left end with a
velocity v0 . Its retardation is proportional to the distance from the right end of the wire.
Find the initial retardation (in m / s 2 ) (at left end of the wire) if the bead reaches the right
v0
end of the wire with a velocity . (given v0  5m / s and L=1m)
2
24. A stick of mass density   8kg / m rests on a disc of radius R=20 cm as shown in the
figure. The stick makes an angle   370 with the horizontal and is tangent to the disc at
its upper end. Friction exists at all points of contact and assume that it is large enough to
keep the system at rest. Find the friction force (in Newton) between the ground and the
disc. (take g  10m / s 2 )
25. A screw gauge with a pitch of 0.5 mm and a circular scale with 50 divisions is used to
measure the diameter of a uniform wire. Before starting the measurement, it is found that
when the two jaws of the screw gauge are brought in contact, the 47th division of the
circular scale coincides with the main scale line and that the zero of the main scale is
barely visible When the diameter of wire is measured by this screw gauge the main scale
reads 1.10 cm and the 12th division of the circular scale coincides with the main scale
line Find the diameter (in mm) of the cylinder
CHEMISTRY MAX.MARKS: 100
SECTION – I
26. Identify the correct order?
A) Ionic radius of Zr 4  Hf 4
B) Ionic radius of Cl  K 
C) Electron gain enthalpy of oxygen is more negative than sulphur
D) First ionization enthalpy of fluorine is less than chlorine
27. The de-Broglie wavelength    associated with a photoelectron varies with the
frequency    of the incident radiation as (  0 -threshold frequency)
1 1 1 1
A)   B)   C)   D)  
  0    0 
1
2
   0 
1
4
   o 
3
2
28. The bond energies in NO  , NO and NO  follow the order?
A) NO  NO   NO  B) NO   NO   NO
C) NO   NO  NO  D) NO   NO  NO 
29. Which of the following is incorrect combination
A) n-Butyl alcohol and isobutyl alcohol are chain isomers
B) anisole and benzyl alcohol are functional isomers
C) Salicylaldehyde and benzoic acids are functional isomers
D) n-propyl alcohol and isopropyl alcohols are chain isomers
30. Select the incorrect statement regarding the following compounds?
(neglect the change in bond angle due to lone pair repulsions of Cl – Cl)
(  r  resultant dipolemoment)
Cl Cl
Cl Cl Cl
Cl Cl
I) Cl II) III) Cl Cl IV) Cl
I)  r  II   0 II)  r  II   3   r  I 
III)  r  IV   0 IV)  r  III   0
A) only I B) only III and IV C) only I and II D) only III
31. Among the statements (I) – (IV), the correct ones are
I) Lithium ion has the highest hydration enthalpy among the alkali metals
II) LiCl is insoluble in pyridine
III) Lithium cannot form ethynide upon its reaction with ethyne
IV) Both Li and Mg react slowly with H2O
A) II and III only B) I, II and IV only C) I and IV only D) I, III and IV only
32. Total number of isomers possible with the molecular formula C2 FClBr I is
A) 2 B) 4 C) 6 D) 8
33. Three centred – two electron bond (3c – 2e) is present in
I) Al2  CH 3 6 II) Be  BH 4 2 III) Al  BH 4 3 IV) Al2Cl6
A) In II only B) In II and IV only C) In I, II and III only D) In IV only
34. Which of the following is correct combination with respect to their IUPAC name?
CHO
OHC
A) CHO (2 - formyl pentane – 1, 5 – dial)
CH 3  CH 2  C  CH 2  C  H  3  oxopen tan al 
|| ||
B) O O
C)  CH 3 2 CHCHO  Isobutyraldehyde 
D) CH 3CHO  Acetal dehyde 
35. Egyptian blue CaCu IISi 4O10 is an example of
A) soro – silicate B) neso –silicate C) Pyroxene D) Phyllo – silicate
36. The correct IUPAC name of the following compound is
Br
A) 3 – Bromo – 2 – methyl but – 1 – ene B) 2 – Bromo – 3 – methyl but – 1 – ene
C) 2 – Bromo – 2 – methylene butane D) 3 – bromo – 2, 3 – dimethyl but – 1 – ene
37. For the reaction 2H 2  g   2NO  g   N 2  g   2H 2O  g  the observed rate expression is,
rate  K f  NO   H 2  . The rate expression for the reverse reaction is

2
K  N  H 2O 
2
A) K b  N 2  H 2O 
2
B) b 2
H2 
K  N  H 2O 
2
C) K b  N 2  H 2O  D) b 2
 NO
1 1
38. For the Balmer series in the spectrum of H atom,   R H  2  2  , the correct
 n1 n 2 
statements among (I) to (III) are
(I) The lines of longest wavelength corresponds to n 2  3
(II) The integer n1 is equal to 2
(III) As wavelength decreases, the lines in the series converge.
A) II and III only B) I and III only C) I, II and III D) II only
39. For the following Assertion and Reason, the correct option is
Assertion : The pH of water increases with increase in temperature
Reason : The dissociation of water into H  and OH  is an exothermic reaction
A) Assertion is not true, but reason is true
B) Both assertion and reason are true, and reason is the correct explanation for the
assertion
C) Both assertion and reason are true, but reason is not the correct explanation for the
assertion
D) Both assertion and reason are false
40. If the spin - only magnetic moment of a dioxygen species is 1.73 BM, it may be
A) O 2 ,O 2 and O 2 B) O 2 or O 2 C) O 2 or O 2 D) O 2 or O 2
41. An ideal gaseous mixture of ethane and ethene occupies 28L at STP. The mixture reacts
completely with 128 gm oxygen to produce CO2 and H2O. Mole fraction of C2H4 in the
given mixture is
A) 0.6 B) 0.4 C) 0.5 D) 0.8
42. The alkali earth metal nitrate that does not crystallise with water molecules is
A) Ca  NO3 2 B) Ba  NO3 2 C) Mg  NO3 2 D) Sr  NO3 2
43. The ratio of activities of two radioactive nuclides x and y in a mixture at time t = 0 was
found to be
4 : 1. After 2 hours, the ratio of activities become 1 : 1. If the t 1 of radioactive nuclide

2
‘x’ is 20 minutes, then t 1 (in minutes) of radioactive nuclide ‘y’ is

2
A) 50 B) 30 C) 45 D) 65
44. During an adiabatic process, the pressure of gas is found to be proportional to the cube
Cp ,m
of its absolute temperature. The ratio of for gas is
C v ,m
3 5 7 4
A) B) C) D)
2 3 2 3
45. The initial rate of hydrolysis of methyl acetate (1M) by a weak acid (HA, 1M) is
th
 1  0
  of that of a strong acid (HX, 1M) at 25 C . Then choose the incorrect
 1000 
statement?
A) pH of 0.1 M NaA is 9.5 B) pH of 0.1 M HA is 3.5
C) Ka of HA is 105 D) P Kb of A  is 8
SECTION-II

46. How many of the following reaction(s) produces ammonia?
i) AlN  H 2O  ii) Li3 N  H 2O 
iii) CaCN 2  H 2O  iv) B3 N 3H 6  H 2O 
v) Ca 3 N 2  dilute HCl  vi) Mg 3 N 2  H 2O 

vii) NH 4 NO 2   viii) Ca 3 N 2  H 2O 
ix) NH 4Cl  Ca  OH 2  x)  NH 4 2 Cr2O7 



47. The volume strength of 8.9 M H2O2 solution calculated at 273 K and 1 atm is____
 R  0.0821L atm K 1

mol1 (rounded off to the nearest integer)
48. If 250cm3 of an aqueous solution containing 0.73 gm of a protein A is isotonic with one
litre of another aqueous solution containing 1.46 gm of a protein B, at 298 K, the ratio of
the molecular masses of A and B is y. Then y is______
49. For a reaction A  B  2Z, 1.0 mol of A, 1.5 mol of B and 0.5 and of z where taken in a
1L vessel and allowed to react. At equilibrium, the concentration of Z was 1.0mol L1 .
x
The equilibrium constant of the reaction is . The value of ‘x’ is____
15
50. At constant volume, 4 mol of an ideal gas when heated from 300 K to 500 K changes its
internal energy by 5000 J. The molar heat capacity at constant volume is___
MATHEMATICS MAX.MARKS: 100
SECTION – I
2x 1 
51. If f : R  R is a function defined by f ( x)   x  cos    , where  x  denotes the greatest
 2 
integer function, then f is
A) continuous for every real x
B) discontinuous only at x  0
C) discontinuous only at non-zero integral values of x
D) continuous only at x  0
52. The real number k for which the equation, 2 x3  3x  k  0 has two distinct real roots in
[0, 1]
A) lies between 1 and 2 B) lies between 2 and 3
C) lies between -1 and 0 D) does not exist
53. Let f : (1, 1)  R be a differentiable function with f (0)  1 and f '(0)  1 . If
g ( x)   f  2 f ( x)  2   , then g '(0) is equal to

2
A) 4 B) 4 C) 0 D) 2
54. Let f ( x)  15  x  10 , x  R then set of values of x, at which the function g ( x)  f  f ( x)  is

not differentiable is
A) 5, 10, 15, 20 B) 5, 10, 15 C) 10 D) 10, 15
1
55. If g is the inverse of a function f and f '( x)  , then g '( x) is equal to
1  x5
1
A) 1  x5 B) 5x 4 C) D) 1   g ( x)5
1   g ( x)
5
56. If f : R  R be a function defined for all x  R by f ( x)  x3  f '(1) x 2  f ''(2) x  f '''(3) then
the area (in sq.units) of the triangle formed by X-axis, the tangent and the normal drawn
to the curve y  f ( x) at x = 0 is
A) 18 B) 45 C) 90 D) 180
57. Water is dropped at the rate of 3m3 / sec into a cone of semi vertical angle 300 . Then the
rate at which periphery of water surface changes, when height of water in the cone is
3m, is
2 4 1 5
A) m / sec B) m / sec C) m / sec D) m / sec
3 3 3 3
58. Let f ( x) be differentiable on [1, 6] and f (1)  2 . If f ( x) has only one root in (1, 6),
then there exists c  (1, 6) such that
1 2 1 2
A) f '(c)  B) f '(c)  C) f '(c)  D) f '(c) 
10 5 5 5
59. If a1  (28)1/ 3  3  b1 , then  a1 , b1  is
A)  ,  B)  ,  D)  , 
1 1 1 1 1 1
C) (27, 28)

28 27  
27 28  
27 26 
60. The greatest of the numbers 1, 21/ 2 , 31/ 3 , 41/ 4 , 51/ 5 , 61/ 6 and 71/ 7 is
A) 21/ 2 B) 31/ 3 C) 71/ 7 D) 41/ 4
61. If x 2  y 2  25 , then log5  max(3x  4 y ) is
A) 2 B) 3 C) 4 D) 5
62. The height of a cylinder of the greatest volume that can be inscribed in a sphere of radius
3 is
A) 3 3 B) 2 3 C) 3 D) 2
1
63. If m and M are the minimum and the maximum values of 4  sin 2 2 x  2 cos 4 x , x  R ,
2
then M  m is equal to
9 15 7 1
A) B) C) D)
4 4 4 4
64. The total number of local maxima and local minima of the function
 2  x 3 , 3  x  1
f ( x)   is
 x ,
2/3
1  x  2
A) 0 B) 1 C) 2 D) 3
1 0 0 
65. Let A  1 1 0  and B  A20 . Then the sum of the elements of the first column of B is
1 1 1 
A) 210 B) 211 C) 231 D) 251

1 0 0 1  0
66. Let A   2 1 0  . If u1 and u2 are column matrices such that Au1  0  and Au2  1  ,
  
 3 2 1  0  0 
then u1  u2 equal to
 1  1  1 1
A)  1  B)  1  C)  1 D)  1
 0   1  0   1
1
67. If f : A  B is an onto function such that f ( x)  x  x  , then A and B are
x x
respectively
A)  ,   ,  0,   B)  , 0  , [2, ) C)  0,   , (2, ) D) (, 0], (0, )
68. If the lines x  y  a , and ax  y  1 intersect each other in the first quadrant, then the set
of permisible values of a is the interval
A) (0, ) B) (1, ) C) (1, ) D) [1, 1]
69. If the angle between the pair of lines x 2  2 2 xy  ky 2  0, k  0 is 450 , then the area (in
square units) of the triangle formed by the pair of bisector of angles between the given
lines and the line x  2 y  1  0 is
1 2
A) B) 1 C) D) 2
3 3
If the vertices of a triangle are  ab,   bc,   ca,  , where a, b, c are roots of the
1 1 1
70.
ab  bc  ca  
equation x  3x  6 x  1  0 , then centroid is
3 2
A) (0, 1) B) (-2, 0) C) (2, -1) D) (1, 2)
SECTION-II
71. The polynomial R( x) is the remainder upon dividing x 2007 by x 2  5 x  6 . If R(0) can be
expressed as ab  a c  bc  , then the value of  a  b  c  equals.
72. Let the equations x3  2 x 2  px  q  0 and x3  x 2  px  r  0 have two roots in common

and the third root of each equation are represented by  and  respectively.


 e x log1 x    , 1  x  0

If f ( x)   a , x0
 
 x2
 ln e   x
b , 0  x 1
 tan x
Is continuous at x  0 , then find the value of 2  a  b  .
73.
      
Let f ( x)  tan sin cos 1 sin  cos 1 x   cos sin 1 cos  sin 1 x   , x  (0, 1) and
  d  f ( x)  
g ( x)  tan x, x   0,  , then find the value of at x  .
 2 d  g ( x)  6
74. A polynomial function P( x) of degree 5 with leading coefficient one, increases in the
interval  ,1 and  3,   and decreases in the interval (1, 3). Given that P(0)  4 and
P '(2)  0 . Find the value P '(6) .
75. If 9  f ''( x)  f '( x)  x 2  f 2 ( x), where f ( x) is twice differentiable function such that
f ''( x)  0x  R and P be the point of maxima of f ( x) , then find the number of tangents
which can be drawn from P to the circle x 2  y 2  9 .
Sec: JR_*CO-SC CTM-15 Date: 08-11-20
Time: 3 Hrs Max.Marks: 300
KEY SHEET
PHYSICS
1 C 2 D 3 C 4 B 5 C
6 D 7 B 8 A 9 C 10 C
11 D 12 C 13 B 14 D 15 B
16 C 17 D 18 D 19 A 20 A
21 2.25 22 2.70 23 18.75 24 6.40 25 11.15
CHEMISTRY
26 B 27 B 28 C 29 D 30 C
31 D 32 C 33 C 34 B 35 D
36 A 37 B 38 C 39 D 40 C
41 A 42 B 43 B 44 A 45 C
46 8 47 100 48 2 49 16 50 6.25
MATHEMATICS
51 A 52 D 53 B 54 B 55 D
56 B 57 A 58 D 59 A 60 B
61 A 62 B 63 A 64 C 65 C
66 D 67 B 68 B 69 A 70 C
71 2011 72 9 73 6 74 1200 75 0
Narayana IIT Academy 08-11-20_Jr.IIT_*CO-SC _JEE-Main_CTM-15_Key&Sol
SOLUTIONS
PHYSICS
1.
2. Conservation of momentum
m 2 gh  m 2 gh  MV1  mV2 1
V1  V2
1   2
2 2 gh
V2  3 2 gh
V22
h'   9h
2g
3.
JR.IIT_CO-SC Page. No. 2
Believe you can and you’re halfway there.

4.
5.
6.

7.
8.
9.

10.
11.
12.

13.
16. g eff  5 g
   5gR
17.


 F net
18. a CM 
 mi
19.
20.
21.

22.
23.
24.
25.

CHEMISTRY
4 4
26. Ionic radii : Zr  Hf
h h
27.  
mv 2m  KE 
h  h 0  KE
28. NO : B.O  2.5
NO  : B.O  3.0
NO  : B.O  2.0
31. LiCl is also soluble in pyridine
33. Al2Cl6  bridge bond : 3c-4e
4
35. neso – silicate : SiO 4
6
soro – silicate : Si 2O 7
pyroxene :  SiO3 n
2n 
phyllo – silicate :  Si 2O5 n

2n 
 rate 
 
Kf    NO 2
 H  
2 
37. K 
Kb Kb
 N 2  H 2O 2
rate
 H 2   NO Kb  NO2  H 2 
2 2
rate  Kb
 N 2  H 2O 
2
H2 
40.   1.73BM (1 unpaired electron)
O 2 ,O 2
7
41. C2 H 6  O 2  2CO 2  2H 2O
2
C2 H 4  3O 2  2CO 2  2H 2O
42. Ba  NO3 2
43. Activity = N
0.693
t1/ 2 

2.303 N
 log O
t N
44. PT 3

 1
 T1   P2 
   
 T2   P1 
C
 P
CV
r1 K H


  1
 
50.
r2 K H 
2
 H   from weak acid


 1
 H    from strong acid
2
 H   K a  C (weak acid)

 
P Ka  P Kb  14 at 250 C  
pH  
1 Ka
2

P  log c (c = concentration of weak acid)
 1

pH  7  P Ka  log c (c = concentration of salt)
2
21.  i  ,  ii  ,  iii  ,  iv  ,  v  ,  vi  ,  viii  ,  ix   NH 3
 vii  ,  x   N 2
Volume strength
22. M
11.2
23. 1  C1ST
2  C2ST
1  2
MATHS
51. f ( x)  [ x] sin  x
52. f '0  f 
53. g1 ( x)  2 f 1  2 f ( x)  2  . f 1  2 f ( x)  2  . 2 f 1 ( x)
54. f not diff. at x  10

f ( x)  10  x  5, 15
 f  f ( x)  not diff. whenever f ( x)  10 as well

55. gof  Id , g1  f ( x)  . f 1 ( x)  1
1
 g1  f ( x)   1
 1  x5
f ( x)
56. f ( x)  x3  5 x 2  2 x  6
57. hr 3
1
v(r )   r 2 r 3
3
 
1 dr
 v1 (r )   3r 2 . 3
3 dt
dr
3   r2 . 3
dt
dr 3 2 3 2 3
  2 . 2  2 
dt r r 3
58. By I.V.T. f (6)  0
By LMVT
f (6)  f (1)
CE (1, 6) s.t.  f 1 (c )  5 f 1 (c )  2  0
5
59. Use LMVT on f ( x)  x1/ 3 in [27, 28]
60. Maximize x1/ x

61. x  5cos  , y  5sin 
Max. max (3 x  4 y )  max (15cos   20sin  )  25
h2
62. V ( h )   r 2 h, r 2   R2  9
4
 1 0 0 1   1 
66. A   2 1 0  , A 1    1
1  1  
 1 2 0  0   0 
67. For D : x  x  0  x   , 0 
1
R: t 2 Range is [2, )
t
 a 1 a a 1 
68. Point of intersection is  , 
 a  1 a 1 

a 1 a a 1
 0, 0
a 1 a 1
69.  
k  1 , Bisector are h x 2  y 2   a  b  xy
i.e., x 2  y 2  0
0 0 1
1 1
A  1 1 1 
2 3
11 11 0
 1 
  ab  ab 
70. C  . 
 3 3 

 
 a  3,  ab  6, abc  1
     3
1 a 3
ab abc 1
71. x 2007  p ( x) ( x  2) ( x  3)  R ( x)

B  3.R (2)  2. R(3)  3.22007  2.32007  2.3 22006  32007 
72. Let Roots are m, n,  and m, n,  substracting x 2  q  r  0
 mn  0   2,   1


 e x log1 x 3 , x0

f ( x)   a , x0
 
 x2
 A. ln e  2 x
 , 0  x 1
 tan x
73. f ( x)  tan 2 x
p1 ( x)  5  x  1  x  3  x  2 
2
74.
 p1 (6)  1200
75. P is interior point as f 1  0 and f 11  0

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Sec: JR_*CO-SC Date: 08-11-20

Time: 3 Hrs Max. Marks: 300

Name of the Student: ___________________ H.T. NO:

08-11-20_JR. STAR CO-SUPER CHAINA_Jee-Main_CTM-15_SYLLABUS

PHYSICS: 100% CUMULATIVE:

CHEMISTRY: 100% CUMULATIVE:

MATHEMATICS: 100% CUMULATIVE:

(A) 2h (B) 4h (C) 6h (D) 9h

(A) 1:1 (B) 1: 2 (C) 1: 2 (D) 1: 4

JR.IIT_*CO-SC Page. No. 2

60mg 2 6mg 2 10mg 2

JR.IIT_*CO-SC Page. No. 3

mV02 mV02 mV02 mV02 mV02

(A) 6.2 m (B) 24.8 m (C) 12.4 m (D) 18.6 m

JR.IIT_*CO-SC Page. No. 4

(A) 2N,6N,3.2N (B) 2N,6N,0N

(C) 1N,6N,2N (D) Data insufficient to calculate the required values.

(C) Impulse of tension in jerk is 7.5 Ns

JR.IIT_*CO-SC Page. No. 5

 g  9.8m / s  Distance covered by cart after 5 sec is

(A) 3.75 (B) 17.5 (C) 20 (D) Zero

(A) 12 N (B) 8 N (C) 20 N (D) 24 N

JR.IIT_*CO-SC Page. No. 7

JR.IIT_*CO-SC Page. No. 8

(A) 6 m/s (B) 5 m/s (C) 4 m/s (D) 3 m/s

JR.IIT_*CO-SC Page. No. 9

JR.IIT_*CO-SC Page. No. 10

A) Ionic radius of Zr 4  Hf 4

B) Ionic radius of Cl  K 

C) Electron gain enthalpy of oxygen is more negative than sulphur

D) First ionization enthalpy of fluorine is less than chlorine

frequency    of the incident radiation as (  0 -threshold frequency)

28. The bond energies in NO  , NO and NO  follow the order?

29. Which of the following is incorrect combination

A) n-Butyl alcohol and isobutyl alcohol are chain isomers

B) anisole and benzyl alcohol are functional isomers

C) Salicylaldehyde and benzoic acids are functional isomers

D) n-propyl alcohol and isopropyl alcohols are chain isomers

JR.IIT_*CO-SC Page. No. 11

I) Cl II) III) Cl Cl IV) Cl

III)  r  IV   0 IV)  r  III   0

A) only I B) only III and IV C) only I and II D) only III

II) LiCl is insoluble in pyridine

IV) Both Li and Mg react slowly with H2O

33. Three centred – two electron bond (3c – 2e) is present in

I) Al2  CH 3 6 II) Be  BH 4 2 III) Al  BH 4 3 IV) Al2Cl6

A) In II only B) In II and IV only C) In I, II and III only D) In IV only

JR.IIT_*CO-SC Page. No. 12

A) CHO (2 - formyl pentane – 1, 5 – dial)

D) CH 3CHO  Acetal dehyde 

35. Egyptian blue CaCu IISi 4O10 is an example of

A) soro – silicate B) neso –silicate C) Pyroxene D) Phyllo – silicate

36. The correct IUPAC name of the following compound is

A) 3 – Bromo – 2 – methyl but – 1 – ene B) 2 – Bromo – 3 – methyl but – 1 – ene

C) 2 – Bromo – 2 – methylene butane D) 3 – bromo – 2, 3 – dimethyl but – 1 – ene

rate  K f  NO   H 2  . The rate expression for the reverse reaction is

JR.IIT_*CO-SC Page. No. 13

(I) The lines of longest wavelength corresponds to n 2  3

(II) The integer n1 is equal to 2

(III) As wavelength decreases, the lines in the series converge.