Xii-Iit GT - 3 Final - Question Paper - 27.03.2024
Xii-Iit GT - 3 Final - Question Paper - 27.03.2024
Xii-Iit GT - 3 Final - Question Paper - 27.03.2024
Marking Scheme :
For each question in Section-1, you will be awarded 4 marks if you darken the
bubble corresponding to only the correct answer and zero mark if no bubbles
are darkened. In all other cases (–1) minus one will be awarded.
For each question in Section-2 will be evaluated according to the following
scheme.
Full Marks : +4 If ONLY the correct numerical value is write as answer.
Zero Marks : 0 in all other cases.
4mv 2 2mv 2
A) 0 B) C) D) None of these
d d
6. Shown in the figure is a small loop that is kept co-axially with the bigger loop. If
the slider moves from A to B, then
7. Power P is given as P a bt
2 c t3
. If t represents the time, then
d
Column-I Column-II
a) Dimension of [a] (i) ML T
2 5
Now, match the following columns and mark the correct code given below.
Column-I Column-II
(i) S1 (p) Q
0
(ii) S 2
(q) 0
(iii) S (r) Q
3
0
(iv) S (s) 2Q
4
0
Codes :
A) i-s, ii-q, iii-r, iv-p B) i-q, ii-s, iii-r, iv-p
C) i-q, ii-r, iii-s, iv-p D) i-r, ii-s, iii-p, iv-q
13. Choose the wrong statement from the following :
A) Zero velocity of a particle does not necessarily mean that its acceleration is zero
B) Zero acceleration of a particle does not necessarily mean that its velocity is zero
C) If speed of a particle is constant, its acceleration must be zero
D) If velocity of a particle changes with time, its tangential acceleration is not equal
to zero
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VELAMMAL BODHI CAMPUS, PONNERI IIT/NEET ACADEMY
GT - 3 XII-IIT JEE MAINS MODEL_27.03.2024
–––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––
14. The equivalent resistance of the arrangement of resistances shown in adjoining
figure between the points A and B is
If the average power radiated by the star is 1016W , the deuteron supply of the star
is exausted in a time of the order of
A) 106 sec B) 108 sec C) 1012 sec D) 1016 sec
The masses of the nuclei are as follows :
M(H2) = 2.014 amu, M(p) = 1.007 amu; M(n) = 1.008; M(He4)=4.001 amu.
17. Read the following statements carefully :
Y : the resistivity of a semiconductor decreases with increase of temperature.
Z : In a conducting solid, the rate of collisions between free electrons and ions
increases with increase of temperature.
A) Y is true but Z is false B) Y is false but Z is true
C) Y is true and Z is the correct reason for Y D) Both Y and Z are true
18. An ideal gas at pressure P and volume V is expanded to volume 2V. Column A
represents the thermodynamic processes used during expansion. Column B
represents the work done during these processes in the random order.
Column A Column B
(p) Isobaric (x) 1 21
PV
1
(q) Isothermal (y) PV
(r) Adiabatic (z) PV ln 2
The correct matching of column A and column B is
A) p-y, q-z, r-x B) p-y, q-x, r-z C) p-x, q-y, r-z D) p-z, q-y, r-x
19. A particle is projected from the mid-point of the line joining two fixed particles each
of mass m. If the separation between the fixed particles is l, the minimum velocity
of projection of the particle so as to escape is equal to
Gm Gm 2Gm 2Gm
A) B) C) D) 2
l 2l l l
20. Two short magnets of magnetic moment 2 Am2 and 5 Am2 are placed along two
lines drawn at right angle to each other on the sheet of paper as shown in the
figure. What is the magnetic field at the point of intersection of their axis?
22. When entire Young’s double slit apparatus is immersed in a liquid the fringe width
decreases by 20%. The refractive index of the liquid is 20/x. The value of x.
23. Infinite number of bricks are placed one over the other as shown in the figure.
Each succeeding brick having half the length and breadth of its preceding brick
and the mass of each succeeding bricks being (1/4)th of the preceding one. Taking
‘O’ as the origin, the x coordinate of centre of mass of the system of bricks is at
Pa
. The value of P is
7
28. A sailor in a boat, which is going due east with a speed of 8 m/s, observes that a
submarine is heading towards north at a speed of 12m/s and sinking at a rate of
2m/s. The commander of submarine observes a helicopter ascending at a rate of
5m/s and heading towards west with 4m/s. The actual speed of the helicopter is
______m/s.
29. The figure shows a network of capacitance consisting of several repetitive units
shown by dotted square and a capacitor of capacitance C1 connected at end as
shown in the figure. The value of C1 such that the equivalent capacitance between
A and B is independent of the number of units is xC. The value of x is
2C 2C 2C
A
2C
C C C C C1
B
3t 2
30. Power supplied to a particle of mass 2 kg varies with time as P . Here t is in
2
second. If velocity of particle at t = 0 is v = 0, the velocity of particle x in m/s at
time t = 2s will be
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VELAMMAL BODHI CAMPUS, PONNERI IIT/NEET ACADEMY
GT - 3 XII-IIT JEE MAINS MODEL_27.03.2024
–––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––
CHEMISTRY
I. Single Answer Type Questions :
31. From the given set of species, point out the species from each set having highest Zeff
(a) O2–, F–, Na+ (b) Li, Be, C (c) He, Li+, H–
a b c a b c
A) Na + C Li+ B) O 2– Li H–
C) F– Na He D) Na+ Be He
32. The conversion of propan-1-ol to n-butylamine involves the sequential addition of
reagents. The correct sequential order of reagents is
A) (i) SOCl2 (ii) KCN (iii) H2/Ni
B) (i) HCI (ii) H2/Ni, (iii) Na(Hg)/C2H5OH
C) (i) SOCl2 (ii) KCN (iii) CH3NH2
D) (i) HCI (ii) CH3NH2
33. In the chemical reaction, K2Cr2O7 + X H2SO4 + Y SO2 K2SO4 + Cr2(SO4)3 +
Z H2O X, Y and Z are :
A) 1, 3, 1 B) 4, 1, 4 C) 3, 2, 3 S) 2, 1, 2
34. ASSERTION : cis-isomer molecules have a higher melting point than trans- isomers.
REASON : Trans- isomers molecules are packed in a U-bending shape.
A) Both Assertion (A) and Reason (R) are the true and Reason (R) is a correct
explanation of Assertion (A).
B) Both Assertion (A) and Reason (R) are the true but Reason (R) is not a correct
explanation of Assertion (A).
C) Assertion (A) is true and Reason (R) is false.
D) Both Assertion and Reason are false
35. In the reaction : Na2S2O3 + 4Cl2 + 5H2O Na2SO4 + H2SO4 + 8HCl, the
equivalent weight of Na2 S2 O3 will be : (M = molecular weight of Na2S2O3)
A) M/4 B) M/8 C) M/1 D) M/2
36. The product(s) of the following reaction will be (choose the best )
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VELAMMAL BODHI CAMPUS, PONNERI IIT/NEET ACADEMY
GT - 3 XII-IIT JEE MAINS MODEL_27.03.2024
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41. For the following gases equilibrium, N2O4 (g) 2NO2 (g), Kp is found to be equal
to Kc. This is attained when :
A) 0oC B) 273 K C) 1 K D) 12.19 K
42. The predominant intermolecular forces present in ethyl acetate, a liquid, are :
A) hydrogen bonding and London dispersion
B) Dipole-dipole and hydrogen bonding
C) London dispersion and dipole-dipole
D) London dispersion, dipole-dipole and hydrogen bonding
43. Which one of the following does not correctly represent the correct order of the
property indicated against it?
A) Ti < V <Mn<Cr : increasing 2nd ionization enthalpy
B) Ti < V < Cr <Mn : increasing number of oxidation states
C) Ti3+< V3+< Cr3+< Mn3+ : increasing magnetic moment
D) Ti < V < Cr <Mn : increasing melting points
44. Assertion (A) : -halocarboxylic acid on reaction with dil. NH3 gives good yield of -
amino carboxylic acid whereas the yield of amines is very low when prepared from
alkyl halides.
Reason (R) : Amino acids exist in zwitter ion form in aqueous medium.
A) Both Assertion (A) and Reason (R) are the true and Reason (R) is a correct
explanation of Assertion (A).
B) Both Assertion (A) and Reason (R) are the true but Reason (R) is not a correct
explanation of Assertion (A).
C) Assertion (A) is true and Reason (R) is false.
D) Assertion (A) is false and Reason (R) is true.
3
45. Which of these statements about [Co(CN)6 ] is true?
3
A) [Co(CN)6 ] has no unpaired electrons and will be in a low-spin configuration
3
B) [Co(CN)6 ] has four unpaired electrons and will be in a low-spin configuration
3
C) [Co(CN)6 ] has four unpaired electrons and will be in a high-spin configuration
3
D) [Co(CN)6 ] has no unpaired electrons and will be in a high-spin configuration
46. Which of the following gives carbylamines reaction?
A) N-methyl aniline B) N-methyl ethanamine
C) Anilinium chloride D) Benzene diazonicum chloride
47. The rate constant of a reaction doubles when its temperature changes from 300K to
310k.Activation energy of such reaction will be (R=8.314j/k.mol & log2=0.301)
A)53.6 Kj/mol B)48.6 KJ/mol C) 58.6Kj/mol D) 68.6kj/mol
48. Arrange the following alcohols in the decreasing order of their ease of dehydration
with H2SO4
A) (iii)>(ii)>(iv)>(i)>(v) B) (iii)>(ii)>(i)>(iv)>(v)
C) (ii)>(iii)>(iv)>(i)>(v) D) (iii)>(ii)>(iv)>(v)>(i)
49. Match the metals given in Column-I with their characteristic color of flame in
oxidizing flame given in Column-II using the codes given.
Column-I Column-II
a) Li P) Apple green
b) Na Q) Brick red
c) Ba R) Golden yellow
d) Ca S) Crimson red
(a) (b) (c) (d) (a) (b) (c) (d)
A) s p q r B) s r p q
C) s r q p D) r s p q
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VELAMMAL BODHI CAMPUS, PONNERI IIT/NEET ACADEMY
GT - 3 XII-IIT JEE MAINS MODEL_27.03.2024
–––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––
50. The conformations of n-butane, commonly known as eclipsed, gauche and anti-
conformations can be interconverted by:
A) rotation around C2-C3 linkage. B) rotation around C-H of an methyl group
C) rotation around C-H of an methylene group
D) rotation around C1-C2 linkage.
II. Numerical Answer Questions :
51. Standard entropies of X2, Y2 and XY3 are 60, 40 and 50 JK–1 mol–1 respectively.
1 3
For the reaction X2 + Y XY3 ; H = – 30 kJ, to be at equilibrium, the
2 2 2
temperature should be……Kelvin
52. Total number of hydroxyl groups present in a molecule of the major product P is.
C) f x log x x 2 1 and g x
x2
2
D) f x x and g x log x x 2 1
/4
1 1 1 1
A) B) C) D)
5 10 11 5
dy 1
67. The differential equation sin 2 y x 3 cos 2 y represents a family of curves given by
dx x
the equation
A) x 6 6 x 2 C tan y B) 6 x 2 tan y x 6 C
C) sin 2 y x3 cos 2 y C D) None of these
2
68. Greatest value of the function, f x 1 x2 is
2 1
A) 1 B) 3/2 C) 2/3 D) 0
69. For each x R , let [x] be the greatest integer less than or equal to x. Then
x x x sin x
lim is equal to
x 0 x
A) – sin1 B) 0 C) 1 D) sin1
k x 1, 0 x 3
70. If the function g x is differentiable, then the value of k + m is :-
mx 2, 3 x 5
16 10
A) 2 B) C) D) 4
5 3
71. Two circles whose radii are equal to 4 and 8 intersects at right angles. The length of
their common chord is:-
8 5 16
A) 8 B) 4 6 C) D)
3 5
72. The equation of parabola whose vertex is (1, - 2) and focus is (1, - 1) is:-
A) x 1 4 y 2 B) x 1 4 y 2 C) x 1 4 y 2 D) x 1 8 y 2
2 2 2 2
73. S1, S2 are foci of an ellipse whose major axis is of length 10 units and P is any point
on the ellipse such that perimeter of triangle PS1S2 is 15. The eccentricity of the
ellipse is
A) 0.5 B) 0.25 C) 0.28 D) 0.75
74. The mean deviation about the mean of the set of first n natural numbers, when ‘n’ is
odd number is
n2 1 n2 1 n2 3 n2 3
A) B) C) D)
4n 4n 5n 5n
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VELAMMAL BODHI CAMPUS, PONNERI IIT/NEET ACADEMY
GT - 3 XII-IIT JEE MAINS MODEL_27.03.2024
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x2 y2 1
75. Let 1, a b be an ellipse, whose eccentricity is and the length of
a2 b2 2
x2 y2
latusrectum is 14 . Then the square of the eccentricity of 2 2 1 is _________.
a b
7 3 5
A) 3 B) C) D)
2 2 2
76. For , , 0 , if sin sin sin
1 1 1
and 3 , then
equals to ____.
3 1 3 1
A) B) C) D) 3
2 2 2 2
77. Let R be a relation on Z x Z defined by (a,b) R (c,d) if any only if (ad – bc) is divisible
by 5. Then R is __________.
A) Reflexive, symmetric and transitive
B) Reflexive, symmetric but not transitive
C) Reflexive, but neither symmetric nor transitive
D) Symmetric, transitive but not reflexive.
78. Let S 2 , 2 : 2 cos 2 3sin 0 ;. Then the sum of the elements of S is ____
13 5
A) B) C) D) 2
6 3
x 3 y 4 z 1
79. Let P and Q be points on the line which are at a distance of 6 units
8 2 2
from the point R 1, 2,3 . If the centroid of 𝛥 𝑃𝑄𝑅 is , , , then 2 2 2 is______
A) 26 B) 36 C) 18 D) 24
80. Let a a1iˆ a2 ˆj a3kˆ and b b1iˆ b2 ˆj b3kˆ be two vectors such that a 1, a.b 2 and
b 4 . If c 2 a b 3b , then the angle between b and c is equal to –
2 1 1
1 3
2
A) cos 1 B) cos C) cos
D) cos 1
3 3 2 3
II. Numerical Answer Questions :
81. If z1 2, z2 3, z3 4 and 2 z1 3z2 4 z3 9 , then value of 8 z2 z3 27 z3 z1 64 z1 z2 is equal
to
6
82. The number of rational terms in the expansion of 1 2 3 3 is ______.
1 2
83. The number of values of e x dx is: (where [ ] represents G.I.F)
0
84. The area bounded by the curve y x 1 x 2 and y 3 is equal to ______.
x 2 25
85. If the domain of the function f x log10 x 2 2 x 15 is , , , then
4 x2
the value of 2 3 equals to ______.
86. Let f x x 3 . x 2 , x 4.4 .
2 3
If M and m are the maximum and minimum
values of f, respectively in [ -4, 4], then the value of ( M – m) is
87. The value of a for which the image of the point (a, a – 1) w.r.t the line mirror 3x +y =
6a is the point (a2 +1, a) is
5 5
x 10 5 x 10
2
88. If i and i 25 ,then standard deviation of observations
i 1 i 1
2 x1 7, 2 x2 7, 2 x3 7, 2 x4 7 and 2 x5 7 is equal to –
3 5 9 11 13
89. The value of 128 sin sin sin sin sin sin is
14 14 14 14 14 14
90. If Z 2 Z 1 0 , where Z is a complex number, then the value of
2 2 2 2
1 2 1 3 1 6 1
Z Z 2 Z 3 ................................ Z 6 is ……………
Z Z Z Z