MATERIAL SAFETY DATA SHEET

1. IDENTIFICATION

PRODUCT NAME: GLUE DEVIL PU FILFOAM

PRODUCT DESCRIPTION: Polyurethane foam is a one component, self- expanding, ready to use.

2. COMPOSITION

 Dangerous Substance : Diphenylmethane-4,4’-di-isocyanate

 EINECS : 202-966-0
 CAS : 101-68-8
 Range (%) : 5-<25%
 Symbol : Xn
 R-Phrase : R20-36/37/38-42

3. HAZARDS IDENTIFICATION

 R12: Exteremely flammable

 R36/37/38: Irritating to eyes, respiratory system and skin.
 R42: May cause sensitization by inhalition

4. FIRST AID MEASURES

 GENERAL INFORMATION:
Remove affected person from danger area, lay down.

 INHALATION:
Remove the casualty into fresh air and keep him calm.
In the event symptoms refer for medical treatment.

 SKIN CONTACT:
In case of contact with skin wash off immediately with soap and water.
Consult a doctor if skin irrititation persists.

 EYE CONTACT:
In case of contact with eyes throughly with plenty of water and seek medical advice.

 INGESTION:
Not applicable

 ADVICE TO DOCTOR/TREATMENT:
Treat symptomatically

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5. FIRE-FIGHTING MEASURES

 SUITABLE EXTINGUISHING MEDIA:

Water spray jet, dry powder, foam, sand

 EXTINGUISHING MEDIA THAT MUST NOT BE USED FOR SAFETY REASONS:

Full water jet

 SPECIAL EXPOSURE HAZARDS ARISING FROM THE SUBSTANCE OR PREPARATION ITSELF OR

COMBUSTION PRODUCTS:
Risk of formation of toxic pyrolis products.
In the event of fire the following can be released : Hydrogen cyanide(HCN)
Nitrogen oxides(NOX)

 SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:

Do not inhale explosion and /or combustion gases.
Wear full protective suit and self contained breathing apparatus.

 ADDITIONAL INFORMATION:
Fire residues and contaminated fire fighting water must be disposed of in accordance with the local regulations.

6. ACCIDENTAL RELEASE MEASURES

 PERSONEL PRECAUTION:
Use breathing apparatus if exposed to vapors/dust/aerosol
Ensure adequate ventilation. Keep away sources of ignition

 ENVIRONMENTAL PRECAUTIONS:
Not applicable

 METHODS FOR CLEANING UP/TAKING UP:

Take up mechanically and use of a mild solvent.
Dispose as plastic waste (foam plastic) in accordance with all applicable quidelines and regulations.
Before diaposing of containers, reileve container of any remaining foam and pressure.Allow foam to fully cure before
disposing.

7. HANDLING AND STORAGE

 ADVICE ON SAFE HANDLING:

Provide good room ventilation even at ground level (vaporous are heavier than air )
Handle with care-avoid shock, friction and impact.

 ADVICE ON PROTECTION AGAINST FIRE AND EXPLOSION:

Emergency cooling must be provided for the eventuality of a fire in the viomity.

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 Keep away from sources of ignition-refrain from smoking.

 REQUIREMENTS FOR STORAGE ROOMS AND VESSELS:

Store in a cool and dry place

 ADVICE ON STORAGE COMPALIBILITY:

Do not store together with oxidizing agents.Do not store with combustible materials.

 FURTHER INFORMATION ON STORAGE CONDITIONS:

Protect from heat / overheating. Keep in a cool, heat causes increase in presssure and risk of bursting.

8. PERSONAL PROTECTION / EXPOSURE CONTROLS

ADDITIONAL ADVICE ON SYSTEM DESIGN:

 EXPROSURE LIMITS
Substance: Diphenylmethane-4,4ı-di-isocynate
Eınecs: 202-966-0
CAS: 101-68-8
VALUE: MAK:0,005 ppm

 RESPIRATORY PROTECTION:
Breathing apparatus in the event of aerosol or mist formation
Short term: filter apparatus, combinatıon filter A-P2

 HAND PROTECTION:
Protective gloves

 EYE PROTECTION:
Protective goggles

 SKIN PROTECTION:
Long sleeve work clothes.

 GENERAL PROTECTIVE MEASURES:

Do not inhale aerosols.Avoid contact with eyes and skin.

 HYGIENE MEASURES:
At work do not eat, smoke or take drugs. Wash hands before breaks and after work. Use barrier skin cream

9. PHYSICAL AND CHEMICAL PROPERTIES

 FORM: Aerosol
 LOWER EXPLOSION LIMIT
 COLOUR
 UPPER EXPOLSION LIMIT

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  ODOUR: Characteristic
 COMBUSTIBLE PROPERTIES: Not applicable
 Ph-VALUE: Not applicable
 VAPOR PRESSURE: 200C
 MELTING POINT
 DENSİTY: 17±2 kg/m3
 BOILING POINT
 SOLUBILITY IN WATER: Insoluble
 FLASH POINT: Not applicable
 PARTITION COEFFICIENT: (n-octanol/water)
 FLAMMABILITYAUTO
IGNITION TEMPERATURE
 VISCOSITY: Not applicable

10. STABILITY AND REACTIVITY

 HAZARDOUS REACTIONS:
Risk of bursting

 HAZARDOUS DECOMPOSITION PRODUCTS:

No hazardous decomposition products known.

11. TOXICOLOGICAL INFORMATION

 ACUTE ORAL TOXICITY: LD50 rat

 ACUTE INHALATION TOXICITY: LD50 rat
 IRRITANT EFFECT ON SKIN: ACUTE DERMAL TOXICITY LD50 rabbit
 IRRITANT EFFECT ON EYE
 SENSITIZATION: SUBACUTE TOXICITY
 CHRONIC TOXICITY: SUBCHRONIC TOXICITY
 MUTAGENICITY: REPRODUCTION TOXICITY
 CARCINOGENICITY
 EXPERIENCES MADE IN PRACTICE: none

GENERAL REMARKS
The product was classified on the basis of the calculation procedure of the preparation directive (88/379/EEC)
No toxicological data are available.

12. ECOLOGICAL INFORMATION

 PHYSICO CHEMICAL ELIMINABILITY: BIOLOGICAL DEGRADABILITY

BIOLOGICAL ELIMINABILITY
DEGRADABILITY ACCORDING TO LAW OF WASH AND CLEANING AGENT (WRMG)

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 Not applicable

 BEHAVIOR IN ENVIRONMENT COMPARTMENTS

First toxicity

 DAPHANIA TOXICITY: ALGAE TOXICITY

BACTERIA TOXICITY
BEHAVIOR IN SEWAGE PLANT
Not applicable

 CHEMICAL OXYGEN DEMAND (COD): BIOCHEMICAL OXYGEN DEMAND(BOD5)

AOX-ADVISE
No dangerous components

 CONTAIN FOLLOWING HEAVY METALS AND COMPOUNDS OF 76/464/EWG

No dangerous components

 GENERAL INFORMATION
Ecologıcal data are not available.

13. DISPOSAL CONSIDERATIONS

 DISPOSAL / PRODUCT:
Dispose of as hazardous waste.

 DISPOSAL / CONTAMINATED PACKING:

Packing that cannot be cleaned should be disposed of as for product

14. TRANSPORT INFORMATION

 LAND TRANSPORT ADR/RID:

Class/Division/Group : 2 5 A
Hazard-no
UN-No: 1950
ADR-exceptions: Rn 2201 a
Description: Aerosols

15. INLAND WATERWAYS TRANSPORT

 MARINE TRANSPORT / IMDG

Class: 2.1
UN-Nr: 1950
Packing group
EmS: 2-13
MFAG: 4.2

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 Marine
Proper shipping name: Aerosols

 AIR TRANSPORT / ICAQ / IATA-DGR

Class: 2.1
UN-Nr: 1950
Proper shipping name: Aerosols, 20

16. REGULATORY INFORMATION

 LABELING:
The product is classified and labeled in accordance with EC directives / German regulations on dangerous substances.

Hazard symbols

Xn F+

Harmful Extremely flammable

CONTAINS: Diphenylmethane-4.4’-di-isocyanete

 R PHRASES:
R12: Extremely flammable
R36/37/38: Irritating to eyes, respiratory system and skin.
R42: May cause sensitization by inhalation.

 S PHRASES:
S2: Keep out of the reach of children.
S23.4: Do not breathe spray.
S28.2: After contact with skin, wash immediately with water and soap.
S51: Use only in well ventilated areas.

 SPECIAL LABELING FOR CERTAIN PREPARATIONS:

Contaıner is under pressure.Protect from sun and temperatures above 50 0C.
Do not open with force or incinerate even after use.

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 Do not spray against an open flame or glowing hot objects.Keep away from sources of ignition-No smoking.
Observe manufacturer’s instructions.

17. NATIONAL REGULATIONS (GERMAN ONLY)

Restriction of occupation: Yes

Decree for case of interference, observe limits: Yes

Classifications according to Vbf: Not applicable

Classifications according to TA-Luft: 3.1.7

Water hazard class : WGK 2

Water hazard class / source

Waste no: 51 06

Other regulations, restrictions and prohibition regulations

18. OTHER INFORMATION

The information and recommendations set forth herein are presented in good faith and believed to be correct as of the date
hereof. The manufacturer makes no representations as to the completeness or accuracy thereof. Information is supplied
upon the condition that the persons receiving it will make their own determination as to its suitability for their purposes prior
to use. In no event will the manufacturer be responsible for damages of any nature whatsoever resulting from the use of or
reliance upon information. No representations or warranties, either expressed or implied, of merchantability or fitness for a
particular use are made hereunder with respect to this information or the product to this information or the product to which
information refers.

Legal Disclaimer:

All the information of Material Safety Data Sheet is provided on the basis in good faith, and is believed to be
trustworthy but is for reference only. National Adhesive Distributors cc cannot accept any liability for the results
whatsoever arising from the use of National Adhesive Distributors products due that the utilization of these
products is simply out of our control. The users are responsible for selecting the suitability of the products and
methods of use.

REVISED JUNE 2019

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