SAFETY DATA SHEET

(in accordance with Regulation (EU) 2015/830)

Astral pH Minus
Version: 1 Page 1 of 8
Revision date: 11/01/2017 Print date: 11/01/2017

SECTION 1: IDENTIFICATION OF THE SUBSTANCE AND OF THE

COMPANY/UNDERTAKING.

1.1 Product identifier.

Product Name: Astral pH Minus

Chemical Name: sodium hydrogensulphate
Index No: 016-046-00-X
CAS No: 7681-38-1
EC No: 231-665-7
Registration No: 01-2119552465-36-XXXX

1.2 Relevant identified uses of the substance and uses advised against.

pH regulator

Uses advised against:

Uses other than those recommended.

1.3 Details of the supplier of the safety data sheet.

Company: FLUIDRA COMMERCIAL, S.A.U.

Address: Avda. Francesc Macià, 60, 20ª planta
City: 08208 Sabadell
Province: (Barcelona) Spain
Telephone: Tel: +34 93 724 39 00
Fax: Fax: +34 93 724 29 93
E-mail: fds@inquide.com
Web: www.astralpool.com

1.4 Emergency telephone number:

Anti poisoning centre:

ITALY (Rome): 06/305 43 43

ITALY (Milan): 02/66 10 10 29

SPAIN: +34 91 562 04 20

FRANCE (Paris): 01 40 05 48 48
FRANCE (Tolousse): 05 61 77 74 47
FRANCE (Marseille): 04 91 75 25 25

PORTUGAL: 808 250 143

SECTION 2: HAZARDS IDENTIFICATION.

2.1 Classification of the substance.

In accordance with Regulation (EU) No 1272/2008:
Eye Dam. 1 : Causes serious eye damage.

2.2 Label elements.

.
.

Labelling in accordance with Regulation (EU) No 1272/2008:

Pictograms:

Signal Word:
Danger

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H statements:
H318 Causes serious eye damage.

P statements:
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or a doctor

Contains:
sodium hydrogensulphate

2.3 Other hazards.

In normal use conditions and in its original form, the product itself does not involve any other risk for health and the environment.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS.

3.1 Substances.
Chemical Name: sodium hydrogensulphate
Index No: 016-046-00-X
CAS No: 7681-38-1
CE No: 231-665-7
Registration No: 01-2119552465-36-XXXX

3.2 Mixtures.
Not Applicable.

SECTION 4: FIRST AID MEASURES.

4.1 Description of first aid measures.

In case of doubt or when symptoms of feeling unwell persist, get medical attention. Never administer anything orally to persons
who are unconscious.

Inhalation.
Take the victim into open air; keep them warm and calm. If breathing is irregular or stops, perform artificial respiration. Do not
administer anything orally. If unconscious, place them in a suitable position and seek medical assistance.

Eye contact.
Wash eyes with plenty of clean and cool water for at least 10 minutes while pulling eyelids up, and seek medical assistance.

Skin contact.
Remove contaminated clothing. Wash skin vigorously with water and soap or a suitable skin cleaner. NEVER use solvents or
thinners.

Ingestion.
If accidentally ingested, seek immediate medical attention. Keep calm. NEVER induce vomiting.

4.2 Most important symptoms and effects, both acute and delayed.
Corrosive Product, contact with eyes or skin can cause burns; ingestion or inhalation can cause internal damage, if this occurs
immediate medical assistance is required.

4.3 Indication of any immediate medical attention and special treatment needed.
In case of doubt or when symptoms of feeling unwell persist, get medical attention. Never administer anything orally to persons
who are unconscious.

SECTION 5: FIREFIGHTING MEASURES.

The product does not present any particular risk in case of fire.

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5.1 Extinguishing media.

Recommended extinguishing methods.
Extinguisher powder or CO2. In case of more serious fires, also alcohol-resistant foam and water spray. Do not use a direct
stream of water to extinguish.

5.2 Special hazards arising from the substance.

Special risks.
Fire can cause thick, black smoke. As a result of thermal decomposition, dangerous products can form: carbon monoxide, carbon
dioxide. Exposure to combustion or decomposition products can be harmful to your health.

5.3 Advice for firefighters.

Use water to cool tanks, cisterns, or containers close to the heat source or fire. Take wind direction into account. Prevent the
products used to fight the fire from going into drains, sewers, or waterways.
Fire protection equipment.
According to the size of the fire, it may be necessary to use protective suits against the heat, individual breathing equipment,
gloves, protective goggles or facemasks, and gloves.

SECTION 6: ACCIDENTAL RELEASE MEASURES.

6.1 Personal precautions, protective equipment and emergency procedures.

For exposure control and individual protection measures, see section 8.

6.2 Environmental precautions.

Prevent the contamination of drains, surface or subterranean waters, and the ground.

6.3 Methods and material for containment and cleaning up.

The contaminated area should be immediately cleaned with an appropriate de-contaminator. Pour the decontaminator on the
remains in an opened container and let it act various days until no further reaction is produced.

6.4 Reference to other sections.

For exposure control and individual protection measures, see section 8.
For later elimination of waste, follow the recommendations under section 13.

SECTION 7: HANDLING AND STORAGE.

7.1 Precautions for safe handling.

For personal protection, see section 8. Never use pressure to empty the containers. They are not pressure-resistant containers.
In the application area, smoking, eating, and drinking must be prohibited.
Follow legislation on occupational health and safety.
Keep the product in containers made of a material identical to the original.

7.2 Conditions for safe storage, including any incompatibilities.

Store according to local legislation. Observe indications on the label. Store the containers between 5 and 35º C, in a dry and
well-ventilated place, far from sources of heat and direct solar light. Keep far away from ignition points. Keep away from
oxidising agents and from highly acidic or alkaline materials. Do not smoke. Prevent the entry of non-authorised persons. Once
the containers are open, they must be carefully closed and placed vertically to prevent spills.
The product is not affected by Directive 2012/18/EU (SEVESO III).
7.3 Specific end use(s).
None in particular.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION.

8.1 Control parameters.

The product does NOT contain substances with Professional Exposure Environmental Limit Values.The product does NOT contain
substances with Biological Limit Values.
8.2 Exposure controls.

Measures of a technical nature:

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Provide adequate ventilation, which can be achieved by using good local exhaust-ventilation and a good general exhaust system.

Concentration: 100 %
Uses: pH regulator
Breathing protection:
If the recommended technical measures are observed, no individual protection equipment is necessary.
Hand protection:
PPE: Work gloves.
Characteristics: «CE» marking, category I.
CEN standards: EN 374-1, En 374-2, EN 374-3, EN 420
Keep in a dry place, away from any sources of heat, and avoid exposure to sunlight as much as possible.
Maintenance: Do not make any changes to the gloves that may alter their resistance, or apply paints, solvents or
adhesives.
Gloves should be of the appropriate size and fit the user's hand well, not being too loose or too tight.
Observations:
Always use with clean, dry hands.
Breakthrough time Material thickness
Material: PVC (polyvinyl chloride) > 480 0,35
(min.): (mm):
Eye protection:
PPE: Protective goggles against particle impacts.
Characteristics: «CE» marking, category II. Eye protector against dust and smoke.
CEN standards: EN 165, EN 166, EN 167, EN 168
Visibility through lenses should be ideal. Therefore, these parts should be cleaned daily. Protectors should
Maintenance:
be disinfected periodically following the manufacturer's instructions.
Some signs of wear and tear include: yellow colouring of the lenses, superficial scratching of the lenses,
Observations:
scraping etc.
Skin protection:
PPE: Protective clothing.
«CE» marking, category II. Protective clothing should not be too tight or loose in
Characteristics:
order not to obstruct the user's movements.
CEN standards: EN 340
In order to guarantee uniform protection, follow the washing and maintenance instructions provided by
Maintenance:
the manufacturer.
The protective clothing should offer a level of comfort in line with the level of protection provided in
Observations: terms of the hazard against which it protects, bearing in mind environmental conditions, the user's level
of activity and the expected time of use.
PPE: Work footwear.
Characteristics: «CE» marking, category II.
CEN standards: EN ISO 13287, EN 20347
This product adapts to the first user's foot shape. That is why, as well as for hygienic reasons, it should
Maintenance:
not be used by other people.
Work footwear for professional use includes protection elements aimed at protecting users against any
Observations:
injury resulting from an accident

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES.

9.1 Information on basic physical and chemical properties.

Appearance:Solid
Colour: Slightly yellowish
Odour:Odourless
Odour threshold:N.A./N.A.
pH:N.A./N.A.
Melting point:180 ºC
Boiling Point: >200 ºC
Flash point: N.A./N.A.
Evaporation rate: N.A./N.A.
Inflammability (solid, gas): N.A./N.A.
Lower Explosive Limit: N.A./N.A.
Upper Explosive Limit: N.A./N.A.
Vapour pressure: N.A./N.A.
Vapour density:N.A./N.A.
Relative density:1.4 - 1.45 g/cm3
Solubility:N.A./N.A.

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Liposolubility: N.A./N.A.
Hydrosolubility: 1080 g/l (20 ºC)
Partition coefficient (n-octanol/water): N.A./N.A.
Auto-ignition temperature: N.A./N.A.
Decomposition temperature: N.A./N.A.
Viscosity: N.A./N.A.
Explosive properties: N.A./N.A.
Oxidizing properties: No

N.A./N.A.= Not Available/Not Applicable due to the nature of the product

9.2 Other information.

Pour point: N.A./N.A.
Blink: N.A./N.A.
Kinematic viscosity: N.A./N.A.
N.A./N.A.= Not Available/Not Applicable due to the nature of the product

SECTION 10: STABILITY AND REACTIVITY.

10.1 Reactivity.
The product does not present hazards by their reactivity.

10.2 Chemical stability.

Stable under the recommended handling and storage conditions (see section 7).

10.3 Possibility of hazardous reactions.

The product does not present possibility of hazardous reactions.

10.4 Conditions to avoid.

Avoid any improper handling.

10.5 Incompatible materials.

Keep away from oxidising agents and from highly alkaline or acidic materials in order to prevent exothermic reactions.

10.6 Hazardous decomposition products.

No decomposition if used for the intended uses.

SECTION 11: TOXICOLOGICAL INFORMATION.

11.1 Information on toxicological effects.

Repeated or prolonged contact with the product can cause the elimination of oil from the skin, giving rise to non-allergic contact
dermatitis and absorption of the product through the skin.

Toxicological information.

Acute toxicity
Name
Type Test Kind Value
LD50 Rat 2140 mg/kg
Oral
sodium hydrogensulphate
Dermal
LD50 Rat >2.4 mg/l (4 h)
Inhalation
CAS No: 7681-38-1 EC No: 231-665-7
a) acute toxicity;
Not conclusive data for classification.

b) skin corrosion/irritation;
Not conclusive data for classification.

c) serious eye damage/irritation;

Product classified:
Serious eye damage, Category 1: Causes serious eye damage.

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d) respiratory or skin sensitisation;

Not conclusive data for classification.

e) germ cell mutagenicity;

Not conclusive data for classification.

f) carcinogenicity;
Not conclusive data for classification.

g) reproductive toxicity;
Not conclusive data for classification.

h) STOT-single exposure;
Not conclusive data for classification.

i) STOT-repeated exposure;
Not conclusive data for classification.

j) aspiration hazard;
Not conclusive data for classification.

SECTION 12: ECOLOGICAL INFORMATION.

12.1 Toxicity.

Ecotoxicity
Name
Type Test Kind Value
LC50 Fish 7960 mg/l (96h)
Fish
sodium hydrogensulphate Aquatic LC50 Daphnia 1766 mg/l (48 h)
invertebrates
LC50 Algae 1900 mg/l (120 h)
Aquatic plants
CAS No: 7681-38-1 EC No: 231-665-7

12.2 Persistence and degradability.

No information is available about persistence and degradability of the product.

12.3 Bioaccumulative potencial.

No information is available regarding the bioaccumulation.

12.4 Mobility in soil.

No information is available about the mobility in soil.
The product must not be allowed to go into sewers or waterways.
Prevent penetration into the ground.

12.5 Results of PBT and vPvB assessment.

No information is available about the results of PBT and vPvB assessment of the product.

12.6 Other adverse effects.

No information is available about other adverse effects for the environment.

SECTION 13 DISPOSAL CONSIDERATIONS.

13.1 Waste treatment methods.

Do not dump into sewers or waterways. Waste and empty containers must be handled and eliminated according to current,
local/national legislation.
Follow the provisions of Directive 2008/98/EC regarding waste management.

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SECTION 14: TRANSPORT INFORMATION.

Transportation is not dangerous. In case of road accident causing the product’s spillage, proceed in accordance with point 6.
14.1 UN number.
Transportation is not dangerous.

14.2 UN proper shipping name.

Description:
ADR: Transportation is not dangerous.
IMDG: Transportation is not dangerous.
ICAO: Transportation is not dangerous.

14.3 Transport hazard class(es).

Transportation is not dangerous.

14.4 Packing group.

Transportation is not dangerous.

14.5 Environmental hazards.

Transportation is not dangerous.

14.6 Special precautions for user.

Transportation is not dangerous.

14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code.
Transportation is not dangerous.

SECTION 15: REGULATORY INFORMATION.

15.1 Safety, health and environmental regulations/legislation specific for the substance.
The product is not affected by the Regulation (EC) No 1005/2009 of the European Parliament and of the Council of 16 September
2009 on substances that deplete the ozone layer.

The product is not affected by Directive 2012/18/EU (SEVESO III).

The product is not affected by Regulation (EU) No 528/2012 concerning the making available on the market and use of biocidal
products.
The product is not affected by the procedure established Regulation (EU) No 649/2012, concerning the export and import of
dangerous chemicals.

15.2 Chemical safety assessment.

There has been no evaluation a chemical safety assessment of the product.

SECTION 16: OTHER INFORMATION.

Classification codes:

Eye Dam. 1 : Serious eye damage, Category 1

It is advisable to carry out basic training with regard to health and safety at work in order to handle this product correctly.

Information on the TSCA Inventory (Toxic Substances Control Act) USA:

CAS No Name State

7681-38-1 sodium hydrogensulphate Registered

Abbreviations and acronyms used:

CEN: European Committee for Standardization.

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EC50: Half maximal effective concentration.

PPE: Personal protection equipment.
LC50: Lethal concentration, 50%.
LD50: Lethal dose, 50%.

Key literature references and sources for data:

http://eur-lex.europa.eu/homepage.html
http://echa.europa.eu/
Regulation (EU) 2015/830.
Regulation (EC) No 1907/2006.
Regulation (EU) No 1272/2008.

The information given in this Safety Data Sheet has been drafted in accordance with COMMISSION REGULATION (EU) 2015/830
of 28 May 2015 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive
1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council
Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC.

The information in this Safety Data Sheet on the Preparation is based on current knowledge and on current EC and national
laws, as far as the working conditions of the users is beyond our knowledge and control. The product must not be used for
purposes other than those that are specified without first having written instructions on how to handle. It is always the
responsibility of the user to take the appropriate measures in order to comply with the requirements established by current
legislation. The information contained in this Safety Sheet only states a description of the safety requirements for the
preparation, and it must not be considered as a guarantee of its properties.

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