SOLUTIONS

PHYSICS
1. I max  I1  4 I1  2 I1 4 I1  9I1
I min  I1  4 I1  2 I1 4 I1  I1
I1  I1 10 5 2  1
  
9 I1  I1 8 4   1
  2  1
 2
  2
 1
1
2. Total mechanical energy = - (potential energy)
2
[for circular orbits under central forces]
SQ T .M .E.A :T .M .EB
GMm1 GMm2
= : 
2r1 2 r2
= m1r1 : M 2 r2 = (4m) (4r) : (3m) (3r) = 16 : 9
 
3. F AB  F CD
1
4. I   0cE 2
2
 2 L  2M
5. New magnetic moment M '  m  2 R   m  
  

  
2u 50
6. Time of flight =  = 5 sec
g 10

r  f
foot ball
 
 2iˆ  5 ˆj  5 = 10iˆ  25 ˆj

r  f
player
   
 5iˆ  8 ˆj  2iˆ  4 ˆj  6 ˆj  2iˆ  3 ˆj = 9iˆ  21 ˆj

distance = 12  42 = 17
C
7. V2  , Q2  2C V2
C  2C
8. Conceptual
9.

N – mg = 0, f= N
f = ma  a =  g = 4 m / s2
22  02
u=0, =2   u = 2as  s 
2 2
= 0.5 m
2 4

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 V0 4V0
10. (i) V  t V t
T /4 T
1/ 2
 T /4 2 
4V0  0
 t dt 
 V0
 Vrms = V 2  =  T /4  =
T  3.
dt 
 0 
11. In equilibrium, mg = Fe
FB  V 0 g and mass = volume x density
4 4
  R 3  r 3  0 g   R3  w g
3 3
 27
Given , relative density, 0 
w 8
  r 3  27
 1     W  W
  R   8
r3 8
 1 
R 3 27
r3 8 r3 8 19
1 3   3  1 
R 27 R 27 27
8
 r = 0.89 R = R.
9
12.   BA   0 ni  A = 0 n  kt e  t  A
d d
e   0 nAk  te t 
dt dt
= - 0 nAk t   a  e  e  t  = - 0 nAk  e  t 1   t  
 t

e  0 nAk  t
i=   e 1  t  
R R 
At t = 0 ,i  - ve
at t = 1 sec ,i  0

13. Surface energy per nucleon,

r 2 A2/3 1 a1
bs  
A A
 1/3  1/3
A A
 r  r0 A1/3 
A is incorrect
Contribution to binding energy by columbic forces is given by
a Z  Z  1
bc  2 1/3
A
B is incorrect
Volume energy, bv  A
C is correct
For (D), if we consider only surface energy contribution then option is correct.
Contribution then option is correct.
For € only 3 interactions contribute to surface energy.
14. Zero error = - (10 – 7) x 0.1 = - 0.3 mm diameter = 77.0 + 8 x 0.1 – (- 0.3) = 78.1 mm

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15.

Effectively , 25 cm column of water from top of right vessel entered the left a = mgh
(h is height reduced of the COM)
= (16) (25) 10 3 g (25) x 10 2 = 1J
16. In the case of Vrms  of mixture,
N1  N 2
M mix  ( N1 , N 2 are number of molecules of gaseous 1 and 2) which is Harmonic mean
N1 N 2

M1 M 2
m  m2 n1M 1  n2 M 2
But M mix  1  which is the Arithmetic mean is used in velocity
n1  n2 n1  n2
of sound expression.
17. If the particle covers a further phase of 60C , it will be at the extreme.
  = 360 – 60 = 300 .
18. PdV = nCv dT
nRT
 dV = nCv dT
V
3 dT
=
2 T
 V 2 = CT 3 , where C is a constant.
1 q1 q2
19. F
4 0 r d2
9mR 2  mR 2 4mR 2  9mR 2  mR 2  1  
20. = -   = -    4 
2  18 9  2  9  2 
9mR 2  mR2  9   9mR 2 mR 2 8mR 2
= -   2   =  = = 4m R 2
2  9  2 2 2
21. In the given circuit we can find the voltage across Zener diode which is reverse
biased

10 1K
Voltage across Zener diode (V) V  = 5 Volt
1K  1K
Thus the voltage across the Zener diode is less than the breakdown voltage
(given as 6V) i.e. V  VZ So, VO  V = 5 Volt
h h
22.  
p 2mE

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 
23. A  4 3iˆ  3 3 ˆj  5kˆ

As incident vector A makes I angle with normal z – axis and refracted vector R makes r
. angel with normal z – axis with help of direction cosine
 
1  Az  1
 5 
i  cos    cos  
 A
   
2 2
 4 3  3 3  52 
 
 5 
cos 1    i  60
 10 
By shell’s law, we have
2 sin 60 = 3 x sin r  r = 45
Difference between i and r = 60 - 45 = 15
dV
24. V 2  100 x ; 2V = 100
dx
dV
V = a = 50 , F = ma
dx
25. Mass of element,
1  R 2 d
dm   R  Rd  dm 
2 2
 /2
R 2
 2R 
 x dm  2
d 
 3
cos  

xcm  = 0  /2
 dm R 2

0 2 d 

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  /2

2R  cos  d 2R 2
 0
 /2
=  
3 3  
 d
0

4R
=  x = 4.
3
26. At t = 0 , x  0 , y = 0 , and velocity of particle is positive
 =  rad
27. When disc slides then acceleration , a1 = g sin  and, distance travelled
1 1
S  ut1  a1t12 = g sin  .t12 … (i)
2 2
Again , when disc do pure rolling
g sin  2  1 
a2  = g sin   I disc  mr 2 
I 3  2 
1 2
mr
1 1 2 g sin  2
 S = ut2  a2t22 = . g sin  .t22 = t2 … (ii)
2 2 3 3
From equation. (i) & (ii),
S g sin  t12 g sin  t22
=1= /
S 2 3
t 3
 2 =
t1 2
28. We have li  l f
Mgl YA T
 l  T   M=
YA g
2 1011  3106  2 105  50
 M=
10
 M = 60 kg
2402
29. P
36
2
P1  240
18
2
P2  240
18
2402
Ptotal  P1  P2 
9
P 1

Ptotal 4
30. Using the principal of calorimetry
M ice L f  mice  40  0  Cw  mstream Lv  mstream 100  40  Cw
 M  540   m 1 100  40  = 200  80  200 1 40
 600M = 24000
 M = 40g

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 CHEMISTRY
31. IP1 of Nitrogen is more than Oxygen
32. Reason: Pb  I bond initially formed during the reaction does not release enough energy to unpair
6S 2 electrons
33. Melting point/K : HI  HF  HBr  HCl
34. Magnetic moment more for d 5 configuration.  d1 ,d 3 ,d 4 ,d 5 
3 2 3 2
I) Fe  3d  3d 4  3d 6  3d 5
5
35. II) Cr III) Co IV) Mo
36. CH 4  0,  NF3   NH 3   H 2O
37.
OH
COOH COOH COOH

NO2 CH3
CN I
IV
II III

Electron with drawing nature: -NO 2 > -CN

38.

39. Formation of (P) allylic substitution; Formation of (Q) electrophillic aromatic substitution
40. Elemination with NaNH 2 , followed by reaction with Hg  OAC 2 / H 2O; NaBH 4
41.
O

OH Br MgBr
  
V
eth
 er

  
OMgBr
P 
Br3
 ether
Mg


W  X
Na2CrO
2 7

O
O H3O
CH3 OCl

O
OH
 Z O C CH3
V Y

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42.

43. Formation of A – Nucleophilic substitution

B – EAS, Formation of C = Clemenson’s reduction.
44. 20 amines reacts with Hinsberg’s reagent forms alkali insoluble product
45. Protein is formed by  -amino acid, B is not amino acid
46. x5  y6  x : y  6 :5
47.
E1  1.312  106 J / mol
E1 1.312 106
E2  2  J mol 1
2 4
E   E2  E1 
1 3  1 3 
48. S  S xy3   S x2  S y2   50    60   40   40 Jk 1mol 1
2 2  2 2 
G  H  T S
H
G  0  T   750 k
S
49. Higher the B.P of solvent, normally higher is its K b value
50.  Ag   C     k sp ,  Ag   0.1  1.7  1010  Ag    1.7  109
2 2
k sp   Ag    cro42  ,1.9  1012   Ag   103  Ag    1.9  109  1.9  103
In AgCl  Ag   is low  so AgCl undergoes ppt.
0.06 PH 2
51. E  E0  log 2 
 Assu min g 2 H   2e   H 2 
n  H 


0.06 1
0.18  0  log 2
2  H  
 H    103 M

C6 H 5 N H 3  H 2O  C6 H 5 NH 2  H 3O 
C  x  M xM
x 103
h   0.04
C 1
40
 h  4%

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52.
O

Cl I
NH2 SH H2N NH2
53. 4.9  5
54. RMg X reacts with acidic hydrogens forms alkane
E.g: OH ,  SH , COOH ,  NH 2 , C  CH

55. For each CH 2OH one mole of HCHO is consumed

56. Sulphur containing amino acid =2
Basic amino acid =2
Essential amino acid  6
226
M 5
2
1 492
57. Mole of O2 consumed   20 Mole of NaClO3 required = 20
0.082  300
Mass of NaClO3  20 106.5  2130 gm
58. X   NH 4 3 PO4 .12 MoO3
15th group and SP 3 hybridized atoms in X  4,  3, N  atoms  1 P  atom 
59. TB  TF  105
TB  100    0  TF   5
Tb  TF  5 Kb m  K F m  5
5 5 w  1000
m  2 ; w  68.4 gm
K b  K F 2.5 342  100
60.
SO2 g   NO2 g   SO3  NO g 
t0 1 1 1 1
t  eq 1  x 1 x 1  x 1 x

Kc 
 SO3  NO 
 16 
1 x
2

 SO2  NO2  1  x 
2

3
 x  moles  0.6 mole
5
At equi nSO2  0.4nNO2  0.4 nSO3  1.6 nNO  1.6
0.4
% of nNO2   100  10%
4

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 MATHS
61. If z  i  z  i = 8,

PF1 + PF2 = 8  z max  4

62. Has non – trivial solutions
  0
p p 1 p 1
  p 1 p p2 0
p 1 p  2 p
R2  R2  R1 ; R3  R3  R1
p p 1 p 1
1
 1 1 3 0  p
2
1 1 1
 Exactly one real value of p.
63. n(S )  100
n( E )  36
36
 PE   36%
100
64. A ' s  4 ; L ' s  2; E ' s  1; K ' s  1; H ' s  1
5!
a) 6 C4
2!
5!
b)
4!
c) AAAAELLKH
5! 5!

2! 4!
4! 5!
d) 
2! 4!
 2n  1 .2n.  2n  1 n  4n  1
2
2 n 1
65. Total ways  C3  
1.2.3 3
Let the three numbers a,b,c are drawn, where a  b  c and given a,b and c are in AP.
 2b  a  c....  i 
It is clear from Eq. (i) that a and c both are odd or both are even
 Favorable ways  n 1 C2  n C2


 n  1 n  n  n  1  n 2
1.2 1.2
n2 3n
 Required probability  
n  4n  1  4n 2  1
2

3
 Statement -2 is false

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 In statement 1, 2n 1 21
 n  10
3  10 30 10
 Required probability   
4 10   1
2
399 133
 Statement -1 is true.
66. Let f ( x )   ( x  1)( x  1)   ( x 2  1)
Integrating on both sides, we get
 x3 
f ( x)     x   c
 3 
2
Now, f (1)  1  1  c …… (1)
3
2
Similarly, f (1)  3  3  c ….. (2)
3
 From (1) and (2) , we get
2c = 2  c = 1 and  = 3

 x3 
 f ( x)  3   x   1  x 3  3x  1
 3 
dS dr 1
67. S  4 r 2 ; 8 
dt dt  r
4 dv dr dv
Now, v   r 3   4 2  4r   r
3 dt dt dt
68. We have
 
V1.V2  a  b  c  0
But a, b, c  {-2, -1, 0, 1, 2}
Now (i) if a = 1, b = -1, c = 0, number 3!=6
(ii) if a = 2, b = -2, c = 0, number = 3!=6
3!
(iii) if a = 1, b = 1, c = -2, number = 3
2!
3!
(iv) if a = -1, b = -1, c = -2, number = 3
2!
Total = 18
70. g(5) = 1 f(1) = 5
f  1
g   5   
 
 f  1 
3

x  x16  x8  2 x16  3x8  6  dx

24 1/8
71.
Put 2 x 24  3 x16  6 x8  t
   54 ,   9 ,   8

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72. Differentiate with respect to x.
y  x   y  x   2 x
dy
 y  2x
dx
I .F  e x
ye x  2 xe x dx

ye x  2  xe x  e x   C
y  2  x  1  ce  x
At x = 1, y(1) = 1,  c = e
Y = 2(x-1) +e1-x
73. 72 x3  108 x 2  46 x  5  0
Let root be a  d , a, a  d
3 1
3a  a
2 2
5 1
a  a2  d 2   d 
72 3
2
Difference .
3
74. Mean of a, 2a, 3a, ….. 50a
25a  26a 51
Median =  a
2 2
 xM  50  a 
51 51
 2a  a
50 2 2
51 51
+ ..... 25a  a  26a  a  .....
2 2
51  49a 47 a 45a a
 50a  a 2    ....    2500
2  2 2 2 2
(1  3  ....  49)a  25
25
1  49 a  25
2
25x25a=25
A=4
  k      
sin       k  1   
 6 4   6 4 
13
75. 2
    k 
k 1
sin    k  1  .sin   
4 6 4 6 
   13   
 2 cot  cot   
 4  6 4 
2  
3 1 .

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76. If elements are not repeated, then number of elements in A1  A2  A3 .....  A30 is 30x5
30  5
But each elements is used 10 times, so S   15
10
If elements in B1, B2, ….., Bn are not repeated, then total number of elements is 3n but each elements
3n 3n
is repeated 9 times, so S   15 
9 9
n = 45.
78. Pn  Pn 1   n   n    n 1   n 1 
  n  2  2      n  2   2   
 4  n  2   n  2 
 Pn  Pn 1  4 Pn  2
 P15  P14  P16  P15   16
P13 P14
1
80.  4 tan 2
x   a  b  c  a  b  c 
2
81.
2 2 2 2
x  a  ab  ac  ab  b  bc  ca  cb  c ….. (1)
y   a  b  c 2  a  b 2  c
2
 
2 2 2 2
y  a  ab 2  ac  ba  b  bc 2  ca 2  cb  c ----- (2)
z   a  b  c 2  a  b  c 2
2
  ---- (3)
2 2
 x  y  z 3 a  b  c
2
 2 2 2

(As (1+  +  2 =0)
2 2 2
x  y z
 2 2 2
3
a b c
82. We have f  x   ax3  9 x 2  9 x  3
 f   x   3ax 2  18 x  9  3  ax 2  6 x  3
As f  x  is strictly increasing on R, So a  0 and Disc < 0  36 -12 a  0  a  3
So, a  [3,  )
Hence, number of integral values of a, a  [-5, 100] are 98.
x y z x y 1 z
83. The lines are   ,  
1 1 1 1 1 0

S .D 

C  a . bd  
bd

h   2 k  2 2    2  1
2

84.  
1 1 2
h  1  2 ----- (1)
k  2 1 ---- (2)
Put value of  from (1) and (2)

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 2
 h 1 
 ; 4  y  1   x  1 .
2
k 1  
 2 
Hence, a = -1, b = 4 and c = 1.
85.

Let ABC be the given equilateral triangle. Then C must lie on the y – axis.
Let C   0, a  , Also, AC = AB. Therefore,

1  a2  2 or 1+a2 = 4 or a  3
 1 
Then, the centroid of ABC is  0, .
 3
But in an equilateral triangle, the circumcenter coincides with the centroid. Therefore, the
 1 
circumcenter is  0, .
 3
Also, Radius of circumcircle = C1B
2
 1  1 2
1  0    0    1  
2

 3 3 3
Therefore, the equation of circumcircle is
2 2
 1   2 
 x  0   y     
2

 3  3
2y 1 4
or x 2  y 2   
3 3 3
2y
or x 2  y 2  1  0
3
1 1 1 1
86.  1  x7  4 dx   1  x 4 7
 dx
0 0

y  f ( x)  (1  x 7 )1/4  y 4  1  x7   x  1  y 4 
1/7

Hence functions are inverse of each other

1 1 1 0
I   f  x  dx   g  y  dy   f  x  dx   xf   x  dx
0 0 0 1

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 1

Hence I    f  x   xf   x   dx  xf  x ]10  f 1  0

0

Aliter:
b b

As,  f ( x)dx   g  y  dy   bd  ac  where g  f 1

a c

(property of definite intergral)

  = 0.
1 0 1

 1 x   1 x  0   1  x7  7 1  x 4
4 7 7 4 4
So,
0 1 0

87. Clearly required area

0 4

 16  x  dx    x  4
2
 2
dx
4 0

4
 x  4
0 3
 x3 
 16 x   
 3 4 3
0

64 64
 64    64 square units.
3 3
3 r
88. Tr 1 9 Cr a 9 r b r x 2

 r  3 (for term independent of x)

 Term independent at x is equal to
9
Cr a 6 b 3
To get the maximum value of a6b3 use AM  GM

 a2   b 
3   3  1
3  
3  a b 
6 3 3
i.e,.    6 
6  3 
  a 6b 3  1  Answer = 9 C3
max

89. lim x
a x 2
 x4  1  2x2 
x 
x  1/ 2
2
 x4  1  2x

 lim x
a  x4  1  x2 
 2
  
x  1/ 2

 x  x 1  2x 
4

 

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  1 
 1 4  4
a
 x 
 lim x 1 1/ 2

x 
 1 
1  1  4   2
 x 
1  1 1
 1 
 lim x 1  . 4  ........  1
2 2 x 
 2 x 
 For limit to exist and has value non – zero, we must have   1  4    3
1 1 1
and L   
2 2 2 4 2
1
L2 
32

  3  32  96
L2
90. Derangement
So, D (4) = 9

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