Solution
Solution
Solution
9610ZJA801444240009 JA
PART-1 : PHYSICS
SECTION-I (i)
–5t
(A) The current through the battery as a function of time is i0 = 16 – 16e
–5t
(B) The current through the 15H inductor is i2 = 24 (1 – e )
(C) The potential difference across the 3H inductor is 120e–5t
(D) The current through the 3H inductor is 24 (1 – e–5t)
2) A source of current i0 sinωt, with i0 as constant, is connected to the circuit shown in the diagram.
(A)
For very small ω (but non zero), reading of voltmeter is
For very small ω( but not zero), reading of voltmeter is
(B)
(C)
For very large ω, reading of voltmeter is
(D)
For very large ω, reading the voltmeter is
3) Mass density of a planet varies as where R is radius of planet and r is distance from
center of planet : -
A particle of mass m is to be projected from surface so as to escape the planet, its velocity of
(A)
projection relative to surface is
A particle of mass m is to be projected from surface so as to escape the planet, its velocity of
(B)
projection relative to surface is
(C) Gravitational intensity on surface of planet is πGp0R.
Time period of a satellite in circular orbit very close to planet is
(D)
4) Six dipoles of dipole moment are arranged at corners of a hexagon of side a (value of a is
much more greater than size of dipole). Coordinates of point A and B are (0, 0, a) and (0, 0, –a):
(A)
Electric field at origin O is
(B) Potential at origin O is zero.
(C)
Potential at point A is
(D)
Potential at point B is
5) In a situation, a board is moving with a velocity v with respect to earth, while a man A and man B
are running with a velocity 2v with respect to earth and both men are running from the opposite
ends of the board at the same time, as shown. Length of the board is L. If they meet after time T,
then
Value of T is
(A)
Value of T is
(B)
6) Half portion of a spherical capacitor is filled with a dielectric of dielectric constant k = 2 and
conductivity σ. The charge given to spherical capacitor is Q0. Choose the correct options:
Due to the conductivity of dielectric, charge leaks and the time constant for the discharge
(A)
circuit is .
Due to the conductivity of dielectric, charge leaks and the time constant for the discharge
(B)
circuit is .
(C)
Resistance of this system will be .
(D)
Resistance of this system will be .
(A)
(B)
(C)
(D)
8) In the shown figure inside a fixed hollow cylinder with vertical axis a pendulum is moving
conically with its axis same as that of the cylinder with uniform angular velocity. Radius of cylinder
is 30 cm, length of string is 50 cm and mass of bob is 400 gm. The bob makes contact with the inner
frictionless wall of the cylinder while moving :-
(A) The minimum value of angular velocity of the bob so that it does not leave contact is 5 rad/s
(B) Tension in the string is 5N for all values of angular velocity
(C) For angular velocity of 10 rad/s the bob pushes the cylinder with a force of 9N
(D) For angular velocity of 10 rad/s, tension in the string is 20N
SECTION-I (ii)
1) When the value of d chosen is such that TIR just takes place then time for which light remains
inside the cylinder is :- (c = speed of light in vacuum)
(A)
(B)
(C)
(D)
2) What can the maximum value of d be so that the light ray can still leave the other side of the semi
cylinder ?
d=
(A)
d=
(B)
d=
(C)
3) The correct graph for irms versus angular frequency w through tweeter and woofer is shown by :-
(A)
(B)
(C)
(D)
(A)
(B)
(C)
(D)
SECTION-III
1) There are two thin symmetrical lenses, one is converging, with refractive index n1 = 1.70, and the
other is diverging with refractive index n2 = 1.50. Both lenses have the same curvature radius of
their surface equal to R = 10 cm. The lenses are put close together and submerged into water. The
focal length of lens system is found to be in water. What is the value of x. (R.I. of water =
4/3)
4) Consider a configuration of n identical units, each consisting of three layers. The first layer is a
column of air of height h = cm, and the second and third layers are of equal thickness
light emerges from the bottom of the configuration at a distance cm, as shown in the figure.
5) Each of the double pulleys shown has a centroidal mass moment of inertia of ‘mr2’, inner radius r
and an outer radius 2r. Assuming that the bearing friction of hinge at A and at B is equivalent to
torque of magnitude , then the tension (in N) in the string connecting the pulleys is n/10 find n :
6) In the circuit shown, switch S2 is open and S1 is closed since long. Take E = 20V, L = 0.5 H and R
= 10Ω. The magnitude of rate of change Energy of stored in the magnetic field inside the inductor,
7) A neutral particle of mass 3m is kept in gravity free space. It decays into two particles A and C
moving in opposite direction along X-axis. Magnetic field is along Z-axis. Particle A has mass m and
charge –q. If the angle of rotation of A after which A and C will meet for the first time is radians,
what is the value of n (Disregard the electro magnetic interaction between A and C) ?
8) A large spherical mass M is fixed at one position and two identical point masses m are kept on a
line passing through the centre of M (see figure). The point masses are connected by a rigid
massless rod of length ℓ and this assembly is free to move along the line connecting them. All three
masses interact only through their mutual gravitational interaction. When the point mass nearer to
M is at a distance r = 3ℓ from M, the tension in the rod is zero for . The value of k is :
PART-2 : CHEMISTRY
SECTION-I (i)
(A)
(B)
(C)
(D)
3) Re-orient the molecule at the left to match the partially drawn perspective at the right. Find the
two missing substituents at their correct positions.
(A)
(B)
(C)
(D)
4) Which of the following compounds has one of the stereoisomer as a meso compound?
(A)
(B)
(C)
(A)
(B)
(C)
(D)
7)
Which statements is/are correct about photochemical bromination of the above compound ?
(A) Al2O3
(B) SnO
(C) ZnO
(D) Fe2O3
SECTION-I (ii)
Consider the reaction represented by the equation : CH3Cl(g) + H2O(g) → CH3OH(g) + HCl(g)
These kinetic data were obtained for the given reaction concentrations :
Initial conc. (M) Initial rate of disappearance of
[CH3Cl] [H2O] CH3Cl M s–1
0.2 0.2 1
0.4 0.2 2
0.4 0.4 8
Answer the following question based on these data :
(A) sec–1
(B) litre2 mol–2 sec–1
(C) litre mol–1 sec–1
(D) mol litre–1sec–1
(A)
(B)
(C)
(D)
4–
(A) [Fe(CN)6]
3–
(B) [Cu(CN)4]
2+
(C) [Ni(NH3)6]
2–
(D) [Cu(CN)4]
(A) 5
(B) 9
(C) 10
(D) 6
SECTION-III
2) How many groups will show resonance with phenyl ring when attached with it?
(a) – CH2 – CH = CH2 (b)
(c) (d) – N = O
(e) – Cl (f)
4) Find the total number of monodentate ligands. gly, en, Cl–, H2O, NH3, OX–2, dien,
5) How many of the following compounds cannot decolourise alkaline KMnO4 solution?
(a) HC ≡ CH (b) CH3CH2OH (c) CH3CHO (d) CH3COOH
(e) CH3―O―CH3 (f) CH3 ― CH3 (g) CH3COOCH3 (h) PhCH = CH2
6) Titanium shows magnetic moment of 1.73 BM in its compound. What is the oxidation state of
titanium in the compound ?
7) Among the known Actinides, how many actinides are classified as natural elements.
8) How many of the following elements have either half filled or fully filled 4f subhsell. (Atomic
numbers are given)
Eu = 63, Gd = 64 , Tm = 69, Yb = 70, Lu = 71, Cm = 96, Lr = 103, Sm = 62
PART-3 : MATHEMATICS
SECTION-I (i)
(A) –2
(B) 2
(C) 4
(D) 6
2)
If M be a non-singular matrix of order 3 such that M–1 = , then choose the correct
option(s) -
(where |X| represent determinant of matrix X, adj(X) denotes adjoint of matrix X and Tr(X) denotes
trace of matrix X)
(A) Absolute value of (15tr(adjM)) is 5
(B)
|M| =
(C)
M–2 =
(D)
3) Let A is a non-singular matrix of order n × n such that 3ABA–1 + A = 2A–1BA, then which is/are
correct
(where |A| = det(A)) :–
(A)
(B) x = – 2 is the point of local minimum.
(C)
the equation f(x) = c will have three real and distinct roots for .
(D) the line y = 1 intersects the graph of f(x) at exactly one point.
6)
(D) or for a = b
(A) a = –3, b = 0
(B) a = 2, b = 1
(C) a = 2, b = 0
(D) a = –3, b = 1
8)
If sec2α + 6cos2α = p & tan2α – 5sinα = π – 8 where , then which can be true -
(A) cosec2α = 4
(B) cot2α = 8
(C)
(D)
SECTION-I (ii)
(A)
(B)
(C)
(D)
2) The total number of words which can be formed using all the letters of the word W such that all H
& all R are separated is -
(A)
(B)
(C)
(D)
If , then-
3)
ƒ(ƒ(50)) is-
(A) 60
(B) 50
(C) 32
(D) 48
4)
ƒ(x) is-
(A) periodic
(B) even
(C) odd
(D) neither even nor odd
SECTION-III
1) is equal to
2)
3) Let ƒ(x) be a non constant thrice differentiable function defined on 'R' such that ƒ(x) = ƒ(6 – x) and
ƒ'(0) = 0 = ƒ'(2) = ƒ'(5). If n is the minimum number of roots of ƒ"(x)2 + ƒ'(x)ƒ"'(x) = 0 in [0, 6] then
value of is
4) If , then is equal to
5) Number of ordered pairs (x,y) satisfying the equation tan2x + cot2x – 1– siny = 0, where x satisfy
the inequality and y satisfy the inequality .
6) A square with side 5 × 5 is divided into squares of unit length by drawing parallel lines, then
number of possible rectangles with one side odd and another side of even length is 3(k)2, then value
of 'k' is
PART-1 : PHYSICS
SECTION-I (i)
Q. 1 2 3 4 5 6 7 8
A. A,C,D A,D A,C,D B,C A,C,D A,C B,D A,B,C
SECTION-I (ii)
Q. 9 10 11 12
A. A A C A
SECTION-III
Q. 13 14 15 16 17 18 19 20
A. 3 1 5 4 1 4 4 7
PART-2 : CHEMISTRY
SECTION-I (i)
Q. 21 22 23 24 25 26 27 28
A. A,B,C,D A,B,C,D A,B A,B A,D A,B,D A,B A,B,C
SECTION-I (ii)
Q. 29 30 31 32
A. B C D C
SECTION-III
Q. 33 34 35 36 37 38 39 40
A. 6 5 2 4 4 3 3 6
PART-3 : MATHEMATICS
SECTION-I (i)
Q. 41 42 43 44 45 46 47 48
A. A,C A,B,C,D B,C A,B,C,D A,B B,C,D A,B A,B,C,D
SECTION-I (ii)
Q. 49 50 51 52
A. A B B D
SECTION-III
Q. 53 54 55 56 57 58 59 60
A. 6 2 6 3 8 6 8 7
SOLUTIONS
PART-1 : PHYSICS
1)
i0 = 16 – 16e–5t
for parallel combinations,
i0 = i1 + i2
80e–5t = –2
i2 = 8(e–5t – 1)
3) Mass of planet is
4) Electric field at origin =
Potential at origin = 6(0) = 0
5)
6)
7)
is poynting vector which denotes flow of energy per unit area per unit time.
N + Tsinθ =
9) For TIR
d>
⇒ dmin = (just)
µ=
⇒V=
time =
t=
10)
As d increases, 'i' increases,
For d to be maximum, 'i' should be
maximum i.e., equal to critical angle
⇒ < r = 90°
⇒ µ sin i = 1 sin 90°
sin i =
⇒ i = 45°
sin i =
⇒ dmax =
11) i =
it =
12)
13)
Now
⇒x=3
14)
15) Let v1 and v2 are the velocities along the spring of A and B when spring regains it natural
length then
...(i)
...(ii)
16)
⇒ θ1 = 45°
= θ2 = 30°
h tan60° + d tan45° + d tan 30°
n=4
17)
mg –T = ma = mαr ....(i)
{a = αr}
Solving T’ = = 10N
18)
19)
by momentum conservation
VC = 2 VA
... (i)
Force eq. for mass away from larger mass
... (ii)
from equation (i) & (ii)
⇒K=7
PART-2 : CHEMISTRY
21) Both Artificial radioactive decay and Natural radioactive decay along with decan position
of N2O is 1st order reaction and inversion of cane sugar is pseudo 1st order reaction.
22)
23)
24)
⇒ No chiral centre ⇒ Not meso (c) and (d) so no meso compound
25)
26)
27)
Major free radical is benzylic.
28)
29) Unit K =
n = 3 = n1 + n2
K = litre2 mol–2 sec–1
30)
32)
33)
A → 2B + C
t=0 a - -
t=t a –x 2x x
7a = 8x
∴
…..(1)
…..(2)
Form (1) & (2)
t=
35)
37)
Alkaline KMnO4 reacts with double, triple bond, alcohols and aldehydes and colour of KMnO4 is
discharged
38)
m = 1.73 i.e. one unpaired electron, Ti (E.C.) = [Ar]18 3d2, 4s2 , so it will lose three electrons to
have one unpaired electron and thus the oxidation state of titanium is +3
39)
In actinide series, all elements after Uranium are synthetic element and all actinides are
radioactive elements.
Natural elements among actinides :
Th → Thorium
Pa → Protactinium
U → Uranium
40) Eu : [Xe]4f7,6s2
Gd : [Xe]4f7,5d1,6s2
Tm : [Xe]4f13,6s2
Yb : [Xe]4f14, 6s2
Lu : [Xe]4f14, 5d1, 6s2
Cm : [Rn]5f7, 6d1, 7s2
Lr : [Rn]5f14, 6d1, 7s2
Sm : [Xe]4f6, 6s2
PART-3 : MATHEMATICS
41)
⇒ b = –2, 4
42)
∴ adjM = |M|M–1 =
& Tr(adjM) =
∴ Absolute value of (15tr(adjM)) = 5
⇒
⇒ 3n|x| = 2n|x| (as |A| ≠ 0)
⇒ |x| = 0 or |A + B| = 0
Let M = ABA–1 – A–1BA
∴ AM = A2BA–1 – BA
⇒ BA = A2BA–1 – AM
Now 3ABA–1 + A = 2A–1BA = 2A–1(A2BA–1 – AM)
= 2ABA–1 – 2M
⇒ ABA–1 + A = –2M
⇒ A(BA–1 + I) = –2M
A(A + B)A–1 = –2M
Taking determinants both sides |–2M| = |A||A + B||A–1| = 0
⇒ |AB A–1 – AB–1 A| = 0
44)
Graph of f(x).
Now, verify alternatives.
x3 + 4x2 + px + r = 0
∴ 6x2 + (q – r) = 0 ⇒a+b=0
and γ = – 10 and d = – 4.
At
then by observation
option (B), (C) and (D) are correct.
47) and
48)
⇒ (2 sina – 1) (3sina – 1) = 0
⇒ or
49)
f(x) =
g(x) = tan–1 x
f(x) – g(x) =
x2 = |f(x) – g(x)|
clearly number of solutions are 2.
50) Total such words = all the words when all H are separated – all the words when all H
separated & all R are together.
51)
4cos4x – 2(2cos2x – 1)
we have
⇒ g(g(x)) = x ⇒ g(g(50)) = 50
52)
4cos4x – 2(2cos2x – 1)
we have
⇒ g(g(x)) = x ⇒ g(g(50)) = 50
54)
⇒ (4c – 9) (–4x2 – 6x – c) = 0
has a root
⇒D≥0
⇒ 36 – 16c ≥ 0
55)
ƒ(x) = ƒ(6 – x)
ƒ'(0) = ƒ'(2) = ƒ'(5) = 0
ƒ'(x) = –ƒ'(6 – x)
ƒ'(6) = ƒ'(4) = ƒ'(1) = 0 = ƒ'(3)
h(x) = ƒ"(x)2 + ƒ'(x)ƒ"'(x)
56)
30(–2 + 3)9 = 30
57) We have, (tanx – cot x)2 + (1–siny) = 0
∴ tan x = cot x and sin y = 1
⇒ and .
∴ Number of ordered pair(s) (x,y) = 4 × 2 = 8
DC at
ND at
∴ Total 7 points.