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Exercise – I

Concentration Terms 9. Normality of 0.3 M phosphorous acid is:

(1) 0.15 (2) 0.6 (3) 0.9 (4) 0.1
1. What is the normality of 2M H3PO2
solution?
10. Molarity of 720 gm of pure water:
(1) 0.5 N (2) 1.0 N (1) 40M
(3) 2.0 N (4) 3.0 N (2) 4M
(3) 55.5M
2. How many grams of HNO3 is required to (4) Can't be determined
prepare 400 ml solution of 0.2 M HNO3?
(1) 5.04 g (2) 5040 g 11. Equal weight of NaCl and KCl are
(3) 25.2 g (4) 2.52 g dissolved separately in equal volumes of
solutions molarity of the two solutions
3. Calculate normality of 2.1% (w/V) H2SO4 will be:
solution? (1) Equal
(1) 2.14 N (2) 4.28 N (2) That of NaCl will be less than that of
(3) 0.428 N (4) 0.214 N KCl
(3) That of NaCl will be more than that of
4. 20.6 g NaBr is dissolved in 500ml solution KCl Solution
what is the molarity of resulting solution? (4) That of NaCl will be half of that of KCl
(1) 0.6 (2) 0.4 solution
(3) 1 (4) None
12. A 500 g tooth paste sample has 0.02 gm
fluoride concentration. What is the
5. Density of 2.03 M aqueous solution of
concentration of fluorine in terms of ppm
acetic acid is 1.017 g mL–1 molecular mass
level:
of acetic acid is 60. Calculate the molality
(1) 250 (2) 40
of solution?
(3) 400 (4) 1000
(1) 2.27 (2) 1.27 (3) 3.27 (4) 4.27
13. Mole fraction of ethanol in ethanol water
6. A molar solution is one that contains one mixture is 0.25. Hence percentage
mole of solute in: concentration of ethanol by weight of
(1) 1000 g of the solvent mixture is:
(2) one litre of the solution (1) 25% (2) 75%
(3) 1000 g of the solution (3) 46% (4) 54%
(4) 22.4 litres of the solution
14. H2O2 solution used for hair bleaching is sold
7. Mole fraction of glycerine(C3H5(OH)3) in a as a solution of approximately 5.0 gm H2O2
solution of 36 g of water and 46 g of per 100 mL of the solution. The molecular
glycerine is: mass of H2O2 is 34. The molarity of this
(1) 0.46 (2) 0.36 solution is approximately:
(3) 0.20 (4) 0.40 (1) 0.15 M (2) 1.5 M
(3) 3.0 M (4) 3.4 M
8. 1000 g aqueous solution of CaCO3 contains
10 g of calcium carbonate concentration 15. Equal volumes of 0.1M AgNO3 and 0.2M
of the solution is: NaCl are mixed. The concentration of
(1) 10 ppm (2) 100 ppm NO3– ions in the mixture will be:
(3) 1000 ppm (4) 10,000 ppm (1) 0.1M (2) 0.05M
(3) 0.2M (4) 0.15M
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16. Which of the following solutions has the 23. Increasing the temperature of an aqueous
highest normality? solution will cause:
(1) 8 grams of KOH per litre (1) Decrease in molality
(2) N phosphoric acid (2) Decrease in molarity
(3) 6 gms of NaOH per 100 ml (3) Decrease in mole fraction
(4) 0.5 M H2SO4 (4) Decrease in % w/w

17. An aqueous solution of glucose is 10% in Henry's Law

strength. The volume in which 2 gm mole
of it is dissolved will be: 24. Henry's law constant for dissolution of
(1) 18 litre (2) 3.6 litre CH4 in benzene at 298 K is 2×105 mm of
(3) 0.9 litre (4) 1.8 litre Hg . Then solubility of CH4 in benzene at
298 K under 760 mm of Hg is:
18. A sugar syrup of mass 214.2 gm contains (1) 1.2 × 10–5 (2) 3.8 × 10–3
34.2 gm of sugar. Calculate mole fraction (3) 4 × 10 –7
(4) 1 × 10–2
of sugar in syrup.
(1) 0.556 (2) 0.01 25. Which of the following gas will have most
(3) 9.90 ×10–3 (4) 0.156 solubility in water ?
(1) NH3 (2) H2 (3) O2 (4) He
19. The molarity of a solution obtained by
mixing 750 mL of 0.5(M)HCl with 250 mL
26. Which of the gas will not follow Henry's
of 2(M) HCl will:
law?
(1) 0.875 M (2) 1.00 M
(1) HCl (2) He (3) O2 (4) H2
(3) 1.75 M (4) 0.975 M
27. In solubility of gas 'X' is 0.5 gL–1 at 1 bar
20. The concentration of a solution of H2O2 is then its solubility at 3 bar pressure will
6.8% then the volume strength of the be:
solution is: (1) 0.5 gL–1 (2) 1.5 gL–1
(1) 22.4 (2) 11.2 (3) 20 (4) 5 (3) 3.0 gL –1
(4) 2 gL–1

21. Which of the following statement is true:- Vapour Pressure and Raoult's Law
(a) Molarity is the no. of moles of solute (Liquid Liquid Mixture)
dissolved per litre of solvent.
(b) The molarity and normality of a 28. The boiling point of C6H6, CH3OH, C6H5NH2
solution of sodium carbonate are and C6H5NO2 are 800C, 650C, 1840C and
same. 2120C
(c) Molality (m) of a solution is defined as respectively. Which will show highest
the number of moles of solute vapour pressure at room temperature:
dissolved is 1000 gm of solution (1) C6H6 (2) CH3OH
(d) The ratio of mole fraction of solute (3) C6H5NH2 (4) C6H5NO2
and solvent is in the ratio of there
respective moles. 29. At 88 °C benzene has a vapour pressure
(1) a & c (2) a & d of 900 torr and toluene has a vapour
(3) b & c (4) Only d pressure of 360 torr. What is the mole
fraction of benzene in the mixture with
22. The volume of water added to 500 ml., toluene that will boil at 88 °C at 1 atm.
0.5 M NaOH so that its strength becomes pressure, benzene - toluence form an
10 mg NaOH per ml: ideal solution:
(1) 100 ml (2) 200 ml (1) 0.416 (2) 0.588
(3) 250 ml (4) 500 ml (3) 0.688 (4) 0.740
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30. 1 mole of heptane (V. P. = 92 mm of Hg) Ideal and Non-Ideal Solution

was mixed with 4 moles of octane (V. P.
36. Among the following that forms an ideal
= 31mm of Hg). The vapour pressure of
solution:
resulting ideal solution is:
(1) water and methanol
(1) 46.2 mm of Hg (2) 40.0 mm of Hg
(2) acetone and ethanol
(3) 43.2 mm of Hg (4) 38.4 mm of Hg
(3) benzene and toluene
(4) water and HCl
31. If PA0 and PB0 are 108 and 36 torr respectively.
37. On mixing 10 mL of acetone with 40 ml of
What will be the mole fraction of A in
chloroform the total volume of the
vapour phase if B has mole fraction in
solution is:
solution 0.5?
(1) <50 ml
(1) 0.25 (2) 0.75 (2) > 50 ml
(3) 0.60 (4) 0.35 (3) = 50 ml
(4) cannot be predicted
32. The vapour pressure of two pure liquids
(A) and (B) are 100 and 80 torr 38. Among the following, that does not form
respectively. The total pressure of the an ideal solution is:
solution obtained by mixing 2 mol of (A) (1) C6H6 and C6H5CH3
and 3 mol of (B) would be: (2) C2H5Cl and C6H5OH
(1) 20 torr (2) 36 torr (3) C6H5Cl and C6H5Br
(3) 88 torr (4) 180 torr (4) C2H5Br and C2H5I

33. Mole fraction of A vapours above solution 39. Which condition is not satisfied by an
in mixture of A and B (XA = 0.4) will be: ideal solution?
(PA° = 100mm, PB° = 200mm) (1)  H mixing = 0
(1) 0.4 (2) 0.8 (2)  V mixing = 0
(3) 0.25 (4) None (3)  S mixing = 0
(4) Obeyance of Raoult's law
34. The vapour pressure of ethanol and
methanol are 42.0 mm and 88.5 mm Hg 40. A mixture of liquid showing positive
respectively. An ideal solution is formed deviation in Raoult's law is:
at the same temperature by mixing 46.0 (1) (CH3)2 CO + C2H5OH
(2) (CH3)2CO + CHCl3
g of ethanol with 16.0 g of methanol. The
(3) (C2H5)2O + CHCl3
mole fraction of methanol in the vapour
(4) (CH3)2CO + C6H5NH2
is:
(1) 0.467 (2) 0.502 41. Which of the following plots does not
(3) 0.513 (4) 0.556 represent the behaviour of an ideal binary
liquid solution:
35. What is correct relation between mole (1) Plot of PA versus XA (mole fraction of
fraction in vapour phase (YA) of A in terms A in liquid phase) is linear
of XA. If mole fraction in solution of A is: (2) Plot of PB versus XB is linear
(3) Plot of ptotal versus XA (or XB) is linear
(XA) (If PA0 is vapour pressure of A is pure
(4) Plot of ptotal versus XA is non linear
state)
42. For a solution of two liquids A and B, it
XA 0
(1) (1 − XA )P 0
(2) P was proved that P = XA (PA0 – PB0) + PB0.
A
1 − XA A
The solution is:
1 − XA PA0 X A (1) Ideal
(3) PA0 (4) (2) Non ideal
XA PS
(3) Semi ideal
(4) None of the above
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Azeotropic Mixture 48. The molal elevation constant is the ratio

of the elevation in B.P. to:
43. Azeotropic mixture are: (1) Molarity
(2) Molality
(1) Mixture of two solids (3) Mole fraction of solute
(2) Those which boil at different (4) Mole fraction of solvent
temperatures
(3) Those which can be fractionally 49. The vapour pressure of a solution having
distilled solid as solute and liquid as solvent is:
(1) Directly proportional to mole fraction
(4) Constant boiling mixtures
of the solvent
(2) Inversely proportional to mole
44. An azeotropic mixture of two liquids boil
fraction of the solvent
at a lower temperature than either of
(3) Directly proportional to mole fraction
them when:
of the solute
(1) It is saturated (4) Inversely propartional to mole
(2) It does not deviate from Raoult's law fraction of the solute
(3) It shows negative deviation from
Raoult's law 50. If P0 and PS are the vapour pressure of
(4) It shows positive deviation from solvent and its solution respectively. N1
Raoult's law and N2 are the mole fraction of solvent
and solute respectively then:
45. The azeotropic mixture of water (B.P P0
1000C) and HCl (B.P. 850C) boils at 108.50C. (1) PS =
N2
When this mixture is distilled, it is
(2) P0 – PS = P0N2
possible to obtain:
(3) PS = P0N2
(1) Pure HCl
(2) Pure water (4)
(P
0
- PS )
=
N1
(3) Pure water as well as HCl PS (N
1
+ N2 )
(4) Neither HCl nor H2O in their pure
states 51. Which inorganic precipitate acts as
semipermeable membrane ?
46. An azeotropic mixture of two liquids has (1) Calcium sulphate
b.p. lower than either of them when it: (2) Barium oxalate
(1) shows a (+ve) deviation from Raoult's (3) Nickel phosphate
law (4) Copper ferrocyanide
(2) shows no deviation from Raoult's law
(3) shows (+ve) deviation from Henry's 52. The osmotic pressure of solution
law increases if:
(4) shows (-ve) deviation from Henry's (1) Temperature is decreased
law (2) Concentration is decreased
(3) Number of solute particle is increased
Colligative Properties (4) Volume is increased
53. The best colligative property used for the
47. Which is not a colligative property ? determination of molecular masses of
polymers is:
(1) Osmotic pressure
(1) Relative lowering in vapour pressure
(2) Lowering in vapour pressure
(2) Osmotic pressure
(3) Depression in freezing point (3) Elevation in boiling point
(4) Refractive index (4) Depression in freezing point
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54. If mole fraction of the solvent in solution 59. If 0.1 M solution of glucose and 0.1 M urea
decreases then: solution are placed on two sides of a
(1) Vapour pressure of solution increases semipermeable membrane to equal
heights, then it will be correct to say that:
(2) B. P. decreases
(1) There will be not net movement
(3) Osmotic pressure increases
across the membrane
(4) All are correct (2) Glucose will flow towards urea
solution
55. In osmosis phenomenon net flow of: (3) Urea will flow towards glucose
(1) Solvent molecules move from higher solution
concentration to lower concentration (4) Water will flow from urea solution
(2) Solvent molecules move from lower towards glucose solution.
concentration to higher concentration
60. One mole of non volatile solute is
(3) Solvent molecules move from higher dissolved in two moles of water. The
concentratioin to lower concentration vapour pressure of the solution relative
(4) Solute molecules move from lower to that of water is:
concentration to higher concentration 2 1 1 3
(1) (2) (3) (4)
3 3 2 2
56. At constant temperature the osmotic
61. The vapour pressure of a dilute aqueous
pressure of a solution is:
solution of Glucose is 750 mm of mercury
(1) Directly proportional to the at 373 K. The mole fraction of solute is:
concentration 1 1 1 1
(2) Inversely proportional to the (1) (2) (3) (4)
10 7.6 35 76
concentration
(3) Directly proportional to the square of 62. The vapour pressure of water at room
concentration temperature is 23.8 mm of Hg. The vapour
(4) Directly proportional to the square pressure of an aqueous solution of sucrose
root of concentration with mole fraction 0.1 is equal to:
(1) 23.9 mm Hg (2) 24.2 mm Hg
(3) 21.42 mm Hg (4) 31.44 mm Hg
57. If a thin slice of sugar beet is placed in 63. The vapour pressure of pure A is 10 torr
concentrated solution of NaCl then: and at the same temperature when 1 g of
(1) Sugar beet will lose water from its B is dissolved in 20 gm of A, its vapour
cells pressure is reduced to 9.0 torr. If the
(2) Sugar beet will absorb water from molecular mass of A is 200 amu, then the
solution molecular mass of B is:
(3) Sugar beet will neither absorb nor (1) 100 amu (2) 90 amu
lose water (3) 75 amu (4) 120 amu
(4) Sugar beet will dissolve in solution

64. The freezing point of a 0.05 molal

58. Camphor is used as solvent to determine
solution of a non electrolyte in water is:
the molecular weight of nonvolatile
(Kf = 1.86 K molality–1)
solute by Rast method because for
camphor: (1) –1.86 °C (2) –0.93 °C
(1) Molal depresion constant is high (3) –0.093 °C (4) 0.093 °C
(2) Melting point is high
(3) Being cheap
(4) All
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65. Molal depression constant of water is 1.86 72. Osmotic pressure of a sugar solution at
K Kg mol–1. 0.02 mol of urea dissolved in 240C is 2.5 atmosphere. The concentration
100 g of water will produce a depression of the solution in mole per litre is:
in freezing point of: (1) 10.25 (2) 1.025
(1) 0.186 °C (2) 0.372 °C (3) 1025 (4) 0.1025
(3) 1.86 °C (4) 3.72 °C
73. A solution containing 4 g of a non volatile
66. What would be the freezing point of organic solute per 100 ml was found to
aqueous solution containing 17 g of C2H5OH have an osmotic pressure equal to 500
in 1000 g of water Kf = 1.86 K molality–1 ? cm of mercury at 270C. The molecular
(1) – 0.69°C (2) – 0.34°C weight of solute is:
(3) 0.0°C (4) 0.34°C (1) 14.97 (2) 149.7
(3) 1697 (4) 1.497
67 Elevation in boiling point was 0.52 °C
when 6 g of a compound x was dissolved 74. If a 6.84% (wt. / vol.) solution of cane-
in 100 g of water. Molecular weight of x sugar (mol. wt. 342) is isotonic with 1.52%
is:(K = 5.2 K mol–1 100 g H2O) (wt./vol.) solution of thiocarbamide, then
(1) 120 (2) 60 (3) 100 (4) 342 the molecular weight of thiocarbamide is:
(1) 152 (2) 76 (3) 60 (4) 180
68. Pure benzene freezes at 5.45 °C at a
certain place but a 0.374 m solution of 75. A solution containing 500 g of a protein
tetrachloroethane in benzene freezes at per litre is isotonic with a solution
3.55 °C. The Kf for benzene is: containing 3.42 g of sucrose per litre. The
(1) 5.08 K Kg mol–1 (2) 508 K Kg mol–1 molecular mass of protein is:
(3) 0.508 K Kg mol –1
(4) 50.8 °C Kg mol–1 (1) 5 (2) 146
(3) 34200 (4) 50000
69. An aqueous solution containing 1g of urea
boils at 100.25 °C. The aqueous solution 76. The osmotic pressure of blood is 7.65
containing 3g of glucose in the same atm. at 310 K. an aqueous solution of
volume will boil at: Glucose that will be isotonic with blood
(1) 100.75 °C (2) 100.5 °C is .............wt/Vol:
(3) 100 °C (4) 100.25 °C (1) 5.41% (2) 54.1%
70. An aqueous solution freezes at – (3) 3.5% (4) 4.53%
0.186 °C (Kf = 1.86° ; Kb = 0.512°). What is 77. If density of 2 molal sucrose solution is
the elevation in boiling point? 1.4 gm/ml at 250C, find osmotic pressure?
(1) 0.186 (2) 0.512 (1) 4.06 atm (2) 2 atm
0.512 (3) 40.6 atm (4) 3.4 atm
(3) (4) 0.0512
1.86
78. The vapour pressure of a solvent
decreases by 10mm. of Hg when a non
71. Osmotic pressure of a solution (density is
volatile solute was added to the solvent.
1g/ml) containg 3 g of glucose (molecular
The mole fraction of the solute in the
weight = 180) in 60 g of water at 150C is:
solution is 0.2. What should be the mole
fraction of the solvent if the decrease in
(1) 0.34 atm (2) 0.65 atm vapour pressure is to be 20 mm. of Hg:
(3) 6.25 atm (4) 5.57 atm (1) 0.2 (2) 0.4 (3) 0.6 (4) 0.8
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79. The vapour pressure of a solution of 5gm. 87. Solute A is ternary electrolyte and solute
of non electrolyte in 100gm. of water at a B is non-electrolyte. If 0.1 M solution of
particular temperature is 2985 Nm–2. The solute B produces an osmotic pressure of
vapour pressure of pure water at that 2P, then 0.05M solution of A at the same
temperature is 3000Nm2. The molecular temperature will produce an osmotic
weight of the solute is: pressure equal to:
(1) 180 (2) 90 (3) 270 (4) 200 (1) P (2) 1.5 P (3) 2 P (4) 3 P

80. The vapour pressure of a pure liquid 88. The value of observed and calcutated
solvent (X) is decreased to 0.60 atm. from molecular weight of silver nitrate are
0.80 atm on addition of a non volatile 92.64 and 170 respectively. The degree of
substance (Y). The mole fraction of (Y) in dissociation of silver nitrate is:
the solution is: (1) 60% (2) 83.5 %
(3) 46.7% (4) 60.23%
(1) 0.20 (2) 0.25 (3) 0.5 (4) 0.75

Abnormal Colligative Property and 89. A 0.004M solution of Na2SO4 is isotonic

Vant Hoff Factor with a 0.010M solution of glucose at the
25°C temperature. The apparent degree
81. Equimolal solutions of A and B show of dissociation of Na2SO4 is:
depression in freezing point in the ratio of (1) 25% (2) 50% (3) 75% (4) 85%
2: 1. A remains in normal state in solution.
90. Which of the following solutions at the
B will be in ......... state in solution:
same temperature will be isotonic?
(1) Normal (2) Associated
(1) 3.42 g of cane sugar in one litre water
(3) Hydrolysed (4) Dissociated
and 0.18 g of glucose in one litre
water.
82. Van't Hoff factor is: (2) 3.42 g of cane sugar in one litre water
(1) Less than one in case of dissociation and 0.18 g of glucose in 0.1 litre water.
(2) More than one in case of association (3) 3.42 g of cane sugar in one litre water
(3) Always less than one and 0.585g of NaCl in one litre water.
(4) Less than one in case of association (4) 3.42 g of cane sugar in one litre water
and 1.17 g of NaCl in one litre water.
83. The Vant Hoff factor (i) for a dilute
solution of K3[Fe(CN)6] is: 91. The freezing point order of the soution of
(1) 10 (2) 4 (3) 5 (4) 0.25
glucose is:

84. The experimental molecular weight of an (1) 10% > 3% > 2% > 1%
electrolyte will always be less than its (2) 1% > 2% > 3% > 10%
calculated value because the value of (3) 1% > 3% > 10% > 2%
vant Hoff factor, 'i' is:
(4) 10% > 1% > 3% > 2%
(1) Less than 1 (2) Greater than 1
(3) One (4) Zero

85. The Vant Hoff factor (i) for a dilute 92. In cold countries, ethylene glycol is added
aqueous solution of Glucose is: to water in the radiators of cars during
(1) Zero (2) 1.0 (3) 1.5 (4) 2.0 winters. It result in reducing:
86. The substance A when dissolved in (1) viscosity (2) specific heat
solvent B shows the molecular mass (3) freezing point (4) boiling point
corresponding to A3. The vant Hoff's
factor will be:
1
(1) 1 (2) 2 (3) 3 (4)
3
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93. Calculate the molal depression constant 99. The osmotic pressure of equimolor
of a solvent, which has freezing point 16.6 solutions of BaCl2, NaCl, and glucose will
oC and latent heat of fusion 180.75 Jg-1: be in the order:
(1) 2.68 (2) 3.86 (1) Glucose > NaCl > BaCl2
(3) 4.68 (4) 2.86 (2) BaCl2 > NaCl > Glucose
(3) NaCl > BaCl2 > Glucose
94. The osmotic pressure of a solution at 00C (4) NaCl > Glucose > BaCl2
is 4 atm. What will be its osmotic pressure
at 546 K under similar condition? 100. Which one of the following pairs of
(1) 4 atm (2) 2 atm solutions will be expected to be isotonic
(3) 8 atm (4) 1 atm under the same temperature ?
(1) 0.1M urea and 0.1 M NaCl

95. The lowering of vapour pressure of 0.1M (2) 0.1M urea and 0.2 M MgCl2
aqueous solutions of NaCl, CuSO4 and (3) 0.1M NaCl and 0.1M Na2SO4
K2SO4 are: (4) 0.1M Ca(NO3)2 and 0.1M Na2SO4
(1) All equal
(2) In the ratio of 1: 1: 1.5 101. When mercuric Iodide is added to the
aqueous solution of potassium iodide ?
(3) In the ratio of 3: 2: 1
(1) The boiling point does not change
(4) In the ratio of 1.5: 1: 2.5
(2) Freezing point is raised
(3) The freezing point is lowered
96. The molal elevation constant of water is
0.51. The boiling point of 0.1 molal (4) Freezing point does not change
aqueous NaCl solution is nearly:
102. Two solutions of KNO3 and CH3COOH are
(1) 100.05 °C (2) 100.1 °C
prepared separately. Molarity of both is
(3) 100.2° C (4) 101.0° C 0.1M and osmotic pressures are P1 and P2
97. Which is the correct relation between respectively. The correct relationship
osmotic pressure of 0.1M NaCl solution between the osmotic pressures is:
and 0.1M Na2SO4 solution? (1) P2 > P1
(1) The osmotic pressure of Na2SO4 is (2) P1 = P2
less than NaCl solution (3) P1 > P2
(2) The osmotic pressure Na2SO4 is more P2
P
than NaCl solution (4) =
P1 + P2 P1 + P2
(3) Both have same osmotic pressure
(4) None of the above 103. The correct relationship between the
boiling points of very dilute solutions of
98. The following aqueous solution in the
AlCl3(T1) and CaCl2(T2), having the same
correct order of decreasing freezing point
molar concentration is:
is:
(1) T1 = T2 (2) T1 > T2
(1) 0.2M BaCl2, 0.2M KCl, 0.1M Na2SO4
(3) T2 = T1 (4) T2  T1
(2) 0.2M KCl, 0.1M Na2SO4, 0.2M BaCl2
(3) 0.1M Na2SO4, 0.2M KCl, 0.2M BaCl2
(4) 0.1M Na2SO4, 0.2M BaCl2, 0.2M KCl
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104. Which solution will have least vapour 111. The van't Hoff factor for 0.1 M Ba(NO3)2
pressure: solution is 2.74. The degree of dissociation
(1) 0.1 M BaCl2 (2) 0.1 M urea
is:
(3) 0.1 M Na2SO4 (4) 0.1 M Na3PO4
(1) 91.3% (2) 87% (3) 100% (4) 74%
105. Which has maximum freezing point:
(1) 1 molar of NaCl solution 112. Among 0.1M solutions of urea,Na3PO4 and
(2) 1 molar of KCl solution Al2(SO4)3:
(3) 1 molar of CaCl2 solution
(a) The vapour pressure and freezing
(4) 1 molar of urea solution
point are the lowest for urea
106. Which of the following solutions will have (b) The vapour pressure and freezing
highest boiling point? point are the highest for urea
(1) 1% Glucose in water
(c) The elevation in boiling point is the
(2) 1% Sucrose in water
(3) 1% NaCl in water highest for Al2(SO4)3
(4) 1% Urea in water (d) The depression in freezing point is the
highest for Al2(SO4)3
107. The freezing point of equimolal aqueous
(1) Only a (2) b & c both
solution will be highest for:
(1) C6H5NH3Cl (3) b, c and d (4) a, b, c and d
(2) Ca(NO3)2
(3) La(NO3)3 113. What is the freezing point of a solution
(4) C6H12O6(Glucose) containing 8.1 gm of HBr in 100gm. water
assuming the acid to be 90% ionised:
108. Which one has the highest boiling point:
(1) 0.1N Na2SO4 (Kf for water = 1.86 K molality–1):-
(2) 0.1N MgSO4 (1) 0.85°C (2) –3.53°C
(3) 0.1M Al2(SO4)3 (3) 0°C (4) –0.35°C
(4) 0.1M BaSO4
109. Arrange the following aqueous solutions
114. The substance when dissolved in water
in the order of their increasing boiling
would decrease the vapour pressure of
points:
water to the greatest extent is:
(i) 10–4 M NaCl (ii) 10–4 M Urea
(1) 0.1 M KCl (2) 0.1 M urea
(iii) 10–3 M MgCl2 (iv) 10–2 M NaCl
(3) 0.1 M BaCl2 (4) 0.1 M NaCl
(1) (i) < (ii) < (iv) < (iii)
(2) (ii) < (i) = (iii) < (iv) 115. Which one has same Van't Hoff factor i as
(3) (ii) < (i) < (iii) < (iv) that of Hg2Cl2:
(4) (iv) < (iii) < (i) = (ii) (1) NaCl (2) Na2SO4
(3) Al(NO3)3 (4) Al2(SO4)3

110. The relationship between the values of 116. If  is the degree of dissociation of
osmotic pressure of solutions obtained K4[Fe(CN6)], then abnormal mass of complex
by dissolving 6.00 gL–1 of CH3COOH (1) in the solution will be:
and 7.45 gL–1 of KCl (2) is: (1) Mnormal (1+2)–1
(2) Mnormal (1+3)–1
(1) 1 > 2 (2) 1 < 2
(3) Mnormal (1+)–1
(3) 1 = 2 (4) None of these
(4) Mnormal (1+4)–1
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117. Calculate the percentage degree of 118. A 1.17% solution of NaCl is isotonic with
7.2% solution of glucose calculate the
dissociation of an electrolyte AB2 (normal value of i of NaCl:
(1) 1 (2) 2
molar mass = 164) in H2O if observed
(3) 3 (4) 4
molar mass is 65.6
119. Van't Hoff factor of Hg2Cl2 in its aqueous
(1) 50% solution will be: (Hg2Cl2 is 80% ionized in
the solution)
(2) 25% (1) 1.6 (2) 2.6
(3) 3.6 (4) 4.6
(3) 75%

(4) None

ANSWER KEY
Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25
Ans. 3 1 3 2 1 2 3 4 2 3 3 2 3 2 2 3 2 3 1 1 4 4 2 2 1
Que. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50
Ans. 1 2 2 4 3 2 3 3 3 4 3 1 2 3 1 4 1 4 4 4 1 4 2 1 2
Que. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
Ans. 4 3 2 3 2 1 1 1 1 1 4 3 2 3 2 1 2 1 4 4 3 4 2 2 4
Que. 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100
Ans. 1 3 3 1 2 2 4 2 2 2 4 4 2 3 2 2 3 2 3 2 2 2 3 2 4
Que. 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119
Ans. 2 3 2 4 4 3 4 3 3 2 2 3 2 3 2 4 3 2 2
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Exercise – II

1. An X molal solution of a compound in 7. How many grams of a non volatile solute

benzene has mole fraction of solute having a molecular weight of 90 are to be
equal to 0.2. The value of X is: dissolved in 97.5 g water in order to
(1) 14 (2) 3.2 (3) 1.4 (4) 2 decrease the vapour pressure of water by
2.5 percent:
(1) 25 (2) 18 (3) 12.5 (4) 9
2. Two bottles of A and B contains 1M and
1m aqueous solution (d 1g/mL) of
8. A 0.2 molal aqueous solution of a weak
sulphuric acid respectively: acid (HX) is 20% ionised. The freezing
(1) A is more concentrated than B point of this solution is:
(2) B is more concentrated than A (Given: Kf = 1.86°C/m for water)
(3) Concentration of A = conc. of B (1) – 0.31°C (2) – 0.45°C
(4) It is not possible to compare the (3) – 0.53°C (4) – 0.90°C
concentration
9. The average osmotic pressure of human
3. Molar concentration of a solution in water blood is 7.8 bar at 37°C. What is the
concentration of an aqueous NaCl solution
is:
that could be used in the blood stream:
(1) Always equal to normality
(1) 0.16 mol/L (2) 0.32 mol/L
(2) More than molality of the solution (3) 0.60 mol/L (4) 0.45 mol/L
(3) Equal to molality of the solution
(4) Less than the molality of the solution 10. The mole fraction of the solute in one
molal aqueous solution is:
4. An ideal solution was obtained by mixing (1) 0.027 (2) 0.036
methanol and ethanol. If the partial (3) 0.018 (4) 0.009
vapour pressure of methanol and ethanol
are 2.619 K Pa and 4.556 K Pa respectively, 11. A solution of urea (mol. mass 56 g mol–1)
the composition of vapour (in terms of boils at 100.18°C at the atomospheric
mole fraction) will be: pressure. If Kf and Kb for water are 1.86
(1) 0.635 MeOH, 0.365 EtOH and 0.512K kg mol–1 respectively, the
(2) 0.365 MeOH, 0.635 EtOH above solution will freeze at:
(3) 0.574 MeOH, 0.326 EtOH (1) –6.54°C (2) –0.654°C
(3) 6.54°C (4) 0.654°C
(4) 0.173 MeOH, 0.827 EtOH

5. The vapour pressure of pure benzene and 12. A solution has a 1: 4 mole ratio of pentane
toluene are 160 and 60 torr respectively. to hexane. The vapour pressures of the
The mole fraction of toluene in vapour pure hydrocarbons at 20°C are 440
mmHg for pentane and 120 mmHg for
phase in contact with equimolar solution
hexane. The mole fraction of pentane in
of benzene and toluene is:
the vapour phase would be:
(1) 0.50 (2) 0.6 (3) 0.27 (4) 0.73 (1) 0.200 (2) 0.478
(3) 0.549 (4) 0.786
6. The boiling point of an aqueous solution
of a non volatile solute is 100.15 °C. What 13. The degree of dissociation () of a weak
is the freezing point of an aqueous electrolyte, AxBy is related to van't Hoff
solution obtained by diluting the above factor (i) by the expression:
solution with an equal volume of water? x + y -1 x + y +1
(1)  = (2)  =
The values of Kb and Kf for water are 0.512 i -1 i -1
and 1.86 K molality–1: i -1 i -1
(1) –0.544 °C (2) –0.512 °C (3)  = (4)  =
(x + y - 1) x + y +1
(3) –0.272 °C (4) –1.86 °C
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14. Ethylene glycol is used as an antifreeze in 20. Which of the following solution will have
a cold climate. Mass of ethylene glycol highest freezing point?
which should be added to 4 kg of water (1) 2 M NaCI
to prevent it from freezing at – 6°C will
(2) 1.5 M AlCl3
be:
(Kf for water = 1.86 K kgmol–1, and molar (3) 1M AI2(SO4)3
mass of ethylene glycol = 62 gmol–1) (4) 3M urea
(1) 400.00 g (2) 304.60 g
(3) 800.00 g (4) 204.30 g 21. A solution containing 28 g phosphorus in
315 gm CS2 (b.p. = 46.3°C) boils at 47.9°C
15. The molality of a urea solution in which
(Kb for CS2 is 2.34).
0.0100g of urea, [(NH2)2CO] is added to
What will be the molecular formula of
0.3000 dm3 of water at STP is:
(1) 0.555 m (2) 5.55 × 10–4 m phosphorus (Assume complete association)?
(3) 33.3 m (4) 3.33 × 10–2 m (1) P4 (2) P2
(3) P2 (4) None of these
16. Kf for water is 1.86 K kg mol–1. If your
automobile radiator holds 1.0 kg of water,
22. An aqueous solution contains 5% and 10%
how many grams of ethylene glycol
(C2H6O2) must you add to get the freezing of urea and glucose respectively (by wt.).
point of the solution lowered to If Kf for water is 1.86, the freezing point
–2.8°C? of solution is:
(1) 27 g (2) 72 g (1) 1.40 K
(3) 93 g (4) 39 g
(2) 1.40°C
(3) –3.03°C
17. Relative lowering in vapour pressure of an
(4) –3.03 K
aqueous solution containing 2 moles
[Cu(NH3)3CI]Cl in 3 moles H2O is 0.50. On
23. Consider the following statements:
reaction with AgNO3, this solution will
form: (i) Osmotic pressure method is the most
(1) 0.5 mol AgCl useful method to determining the
(2) 0.25 mol AgCl molecular weight of macromolecules.
(3) 2 mol AgCl (ii) The molecular weight of the
(4) 0.40 mol AgCl macromolecules does not change in
presence of an electrolyte in the
18. Depression in freezing point of 0.01 molal solution.
aqueous HCOOH solution is 0.02046. 1 (iii) Colligative properties are helpful to
molal aqueous urea solution freezes at – determine moleculer weight of
1.86°C. Assuming molality equal to macromolecules.
molarity, pH of HCOOH solution is: (iv) Chloroform - Acetone is a negative
(1) 2 (2) 3 (3) 4 (4) 5 deviation azeotropic mixtures.
19. The freezing point of a solution containing Which of the above statement is/are
0.2 g of acetic acid in 20 g benzene is correct?
lowered by 0.45°C, calculate the degree of (1) i
dimerisation of acetic acid is benzene. Kf (2) i, ii, iii
for benzene is 5.12 Kmol Kg:
–1
(3) ii, iii
(1) 0.527 (2) 0.80 (4) ii, iv
(3) 0.945 (4) None of these
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24. Which of the following statement is / are 25. Which of the following is correct for an
correct? ideal solution?
(i) For ideal solution (Van't Hoff factor), i (i) Gmix = 0 and Hmix >0
(ii) Hmix = 0 and Vmix = 0
=1
(iii) Vmix = 0 and Smix >0
(ii) For non electrolyte, i = 1
(iv) Hmix > 0 and Smix >0
(iii) For electrolyte undergoing dissociation,
Correct option is:
i>1 (1) i, ii, iii (2) ii, iii
(iv) For electrolyte undergoing association, (3) i, ii, iv (4) i, ii, iii, iv
i<1
Correct option is:- 26. The molar mass of NaCl determined by
the osmotic pressure method will be:
(1) ii
(1) Higher than the theoretical value
(2) iii, iv (2) Lower than the theoretical value
(3) i, ii, iii (3) The same as the theoretical value
(4) All of these (4) None of these

ANSWER KEY
Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25
Ans. 2 1 4 2 3 3 3 2 1 3 2 2 3 3 2 3 1 2 3 4 1 3 2 4 2
Que. 26
Ans. 2
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Exercise – III (Previous Year Questions)

1. A 0.0020 m aqueous solution of an ionic 6. The freezing point depression constant

compound Co(NH3)5(NO2)Cl freezes at – for water is 1.86°C m–1. If 5.00 g Na2SO4 is
0.00732°C. Number of moles of ions dissolved in 45.0 g H2O, the freezing point
which 1mol of ionic compound produces is changed by –3.82°C. Calculate the van't
on being dissolved in water will be Hoff factor for Na2SO4: [AIIMS 2010]
(Kf = 1.86°C/m): [AIPMT 2009] (1) 2.05 (2) 2.63
(1) 1 (2) 2 (3) 3 (4) 4 (3) 3.11 (4) 0.381

2. 25.3 g of sodium carbonate, Na2CO3 is 7. The van't Hoff factor i for a compound
dissolved in enough water to make 250 mL which undergoes dissociation in one
of solution. If sodium carbonate dissociates solvent and association in other solvent
completely, molar concentration of sodium
is respectively: [AIIMS 2010]
ion, Na+ and carbonate ions, CO32– are
(1) Less than one and greater than one
respectively:
(2) Less than one and less than one
(Molar mass of Na2CO3 = 106 g mol–1)
(3) Greater than one and less than one
[AIPMT 2010]
(4) Greater than one and greater than on
(1) 0.477 M and 0.477 M
(2) 0.955 M and 1.910 M
(3) 1.910 M and 0.955 M 8. Mole fraction of the solute in a 1.00 molal
(4) 1.90 M and 1.910 M aqueous solution is: [AIIMS 2010]
(1) 0.1770 (2) 0.0177
3. An aqueous solution is 1.00 molal in KI. (3) 0.0344 (4) 1.7700
Which change will cause the vapour
pressure of the solution of increase? 9. 200 mL of an aqueous solution of a
[AIPMT 2010] protein contain its 1.26 g. The Osmotic
(1) Addition of water pressure of this solution at 300 K is found
(2) Addition of NaCl to be 2.57 × 10–3 bar. The molar mass of
(3) Addition of Na2SO4 protein will be: [AIPMT Mains 2011]
(4) Addition of 100 molal KI (R = 0.083 L bar mol K–1)
–1

(1) 61038 g mol–1 (2) 51022 g mol–1

4. A solution of sucrose (molar mass = 342 (3) 122044 g mol–1 (4) 31011 g mol–1
g mol-1) has been prepared by dissolving
68.5 g of sucrose in 1000 g of water. The 10. pA and pB are the vapour pressure of pure
freezing point of the solution obtained liquid components, A and B, respectively
will be: [AIPMT 2010] of an ideal binary solution. If xA represents
(Kf for water = 1.86 K kg mol–1) the mole fraction of component A, the
(1) –0.570°C (2) –0.372°C total pressure of the solution will be:
(3) –0.520°C (4) +0.372°C [AIPMT Pre 2012]
(1) pB + xA (pB – pA) (2) pB + xA (pA – pB)
5. For an ideal solution of A and B which (3) pA + xA (pB – pA) (4) pA + xA (pA – pB)
statement is incorrect: [AIIMS 2010]
(1) The enthalpy change of mixing of A 11. Which of the following compounds can be
and B is zero used as antifreeze in automobile radiators:
(2) The volume change of solution A and [AIPMT Mains 2012]
B is zero (1) Nitrophenol
(3) The intermolecular forces of A and B
(2) Ethyl alcohol
is same as that of A–A and B–B
(3) Methyl alcohol
(4) The entropy change of mixture of A
(4) Glycol
and B is zero
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12. Vapour pressure of chloroform (CHCl3) 18. The boiling point of 0.2 mol kg–1 solution
and dichloromethane (CH2Cl2) at 25°C are of X in water is greater than equimolal
200 mmHg and 41.5 mmHg respectively. solution of Y in water. Which one of the
Vapour pressure of the solution obtained following statements is true in this case?
by mixing 25.5 g of CHCl3 and 40g of [AIPMT 2015]
CH2Cl2 at the same temperature will be: (1) Molecular mass of X is greater than
(Molecular mass of CHCl3 = 119.5 u and the molecular mass of Y.
molecular mass of CH2Cl2 = 85 u) (2) Molecular mass of X is less than the
[AIPMT Mains 2012] molecular mass of Y.
(3) Y is undergoing dissociation in water
(1) 90.93 mmHg (2) 285.5 mmHg
while X undergoes no change.
(3) 173.9 mmHg (4) 615 mmHg
(4) X is undergoing dissociation in water
while Y undergoes no change.
13. 6.02 × 1020 molecules of urea are present
in 100 mL of its solution. The concentration
19. Which one is not equal to zero for an ideal
of solution is: [NEET (UG) 2013]
solution? [AIPMT 2015]
(1) 0.1 M (2) 0.02 M
(1) Smix
(3) 0.01 M (4) 0.001 M
(2) Vmix
(3) P = Pobserved - PRaoult
14. Boiling point of benzene is 353.23 K.
(4) Hmix
When 1.8 g of non-volatile solute is
dissolved in 90 g of benzene. Then boiling
20. Which one of the following electrolytes
point raised to 354.11 K. Given Kb has the same value of van't Hoff's factor
(benzene) = 2.53 Kkgmol-1. Then (i) as that of the Al2(SO4)3 (if all are 100%
molecular mass of non volatile substance ionised)? [AIPMT 2015]
is: [AIIMS 2013] (1) K3[Fe(CN)6] (2) Al(NO3)3
(1) 58g mol–1
(2) 120 g mol–1 (3) K4[Fe(CN)6] (4) K2SO4
(3) 116 g mol –1
(4) 60 g mole–1
21. What is the mole fraction of the solute in
15. Strength of H2O2 is 15.18 gL–1, then it is a 1.00m aqueous solution?
equal to: [AIIMS 2013] [Re-AIPMT 2015]
(1) 1 volume (2) 10 volume (1) 0.0354 (2) 0.0177
(3) 5 volume (4) 7 volume (3) 0.177 (4) 1.770

16. Of the following 0.10 m aqueous 22. Osmotic pressure of a solution containing
solutions, which one will exhibit the 1 g protein in 100 mL solution at 300 K is
largest freezing point depression? 1.66 bar. What is the molecular weight of
[AIPMT 2014] protein:
(1) KCl (2) C6H12O6 (R = 0.083 L bar mol–1 K–1) [AIIMS 2015]
(1) 150 (2) 120 (3) 130 (4) 300
(3) Al2(SO4)3 (4) K2SO4

23. On adding a non volatile solute to a

17. Addition of 1 kg of non volatile solute in
solvent, the vapour pressure of solvent
volatile solvent increases the boiling
decreases and becomes z × [vapour
point from 350 K to 355 K and decreases
pressure of solvent) where z is:
the freezing point form 250 K to 220 K. If
[AIIMS 2015]
Kb is 15.5 K Kg/mol, then Kf will be: (1) mole fraction of solvent
[AIIMS 2014] (2) mole fraction of solute
(1) 2.1 K kg mol –1
(2) 93.01 K kg mol–1 (3) molality
(3) 76 K kg mol –1
(4) 10 K kg mol–1 (4) molarity
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24. The van't Hoff factor (i) for a dilute 30. If we dissolve non volatile solute in
aqueous solution of the strong solvent then lowering in vapour pressure
electrolyte barium hydroxide is depends on? [AIIMS 2016]
[NEET (II) 2016]
number of mole of solute
(1) 2 (2) 3 (3) 0 (4) 1 (1)
number of mole of solvent
25. Which one of the following is incorrect for number of mole of solvent
(2)
ideal solution? [NEET (II) 2016] number of mole of solute
(1) P = Pobs – Pcalculated by Roult's law =0 number of mole of solvent
(2) Gmix = 0 (3)
number of mole of solution
(3) Hmix = 0
number of mole of solution
(4) Umix = 0 (4)
number of mole of solute
26. Which of the following statement about
the composition of the vapour over an 31. 0.5 mole NaCl has dissolved in 500 gm
ideal 1: 1 molar mixture of benzene and H2O then find out its freezing point and
toluene is correct? Assume that the boiling point. [AIIMS 2016]
temperature is constant at 25°C. (Given:
Given- (K f ) = 1.8 K kg/mol
Vapour Pressure Data at 25°C, benzene = H2O

12.8 kPa, Toluene = 3.85 kPa)

[NEET I 2016]
(K )
b H O
2
= 0.5K kg/mol

(1) The vapour will contain a higher (1) -1.8°C, 100.5°C (2) -3.6°C, 101°C
percentage of benzene (3) -3.6°C, 99°C (4) 0°C, 100°C
(2) The vapour will contain a higher
percentage of toluene
32. Density of a pure liquid is 1.25gm/ml, if
(3) The vapour will contain equal
molecular weight is 62.5gm/mol, then
amounts of benzene and toluene
find out its molarity: [AIIMS 2016]
(4) Not enough information is given to
(1) 2M (2) 5 M
make a predication.
(3) 50 M (4) 20 M

27. At 100°C the vapour pressure of a

33. If molality of the dilute solution is
solution of 6.5g of a solute in 100g water
doubled, the value of molal depression
is 732 mm. If Kb =0.52, the boiling point of
constant (Kf) will be: [NEET 2017]
this solution will be: [NEET I 2016]
(1) doubled (2) halved
(1) 101°C (2) 100°C
(3) tripled (4) unchanged
(3) 102°C (4) 103°C
34 Which of the following is dependent on
28. On dissolve 1gm solute in 50gm benzene,
temperature? [NEET 2017]
then depression in freezing point is 0.4K.
(1) Molality
Find out molecular weight of solute?
(2) Molarity
(Kf=5.12 K kg/mol) [AIIMS 2016]
(3) Mole fraction
(1) 512 (2) 256
(4) Weight percentage
(3) 728 (4) 528
35. When 45 gm solute is dissolved in 600 gm
29. If density of methanol is 0.8 kg L–1. Find
water freezing point lower by 2.2 K,
out its required volume to prepare 0.4M,
calculate molar mass of solute (Kf = 1.86
2.5 L solution: [AIIMS 2016]
K kg mol–1). [AIIMS 2018]
(1) 0.4 L (2) 4.0 L
(1) 63.4 (2) 80 gm
(3) 0.04 L (4) 40 L
(3) 90 gm (4) 21 gm
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36. Ethylene glycol is used as antifreeze to 42. The density of 2M aqueous solution of
reduce freezing point of water to – NaOH is 1.28 g/cm3. The molality of the
2.4°C,what mass of antifreeze is required
solution is [Given that molecular mass of
for 2L water ?
NaOH = 40 g mol–1]
Kkg 
 Kf water = 1.86  [AIIMS 2018] [NEET (UG)(ODISHA) 2019]
 mole 
(1) 1.20 m (2) 1.56 m
(1) 16 kg (2) 160 g
(3) 1.67 m (4) 1.32 m
(3) 1.60 kg (4) 16 g

37. 1 gm of polymer having molar mass 43. The freezing point depression constant
1,60,000 gm dissolve in 800 ml water, so (kf) of benzene is 5.12 K kg mol–1. The
calculate osmotic pressure in pascal at
freezing point depression for the solution
27°C (R = 8.314 J/K mole): [AIIMS 2018]
(1) 19.4 (2) 0.90 of molality 0.078 m containing a non-
(3) 0.50 (4) 1.20 electrolyte solute in benzene is (rounded
off upto two decimal places):
38. Freezing point of 0.04 m solution of a weak [NEET (UG) 2020]
monoprotc acid is –0.1°C. What is its Van't
(1) 0.60 K (2) 0.20 K
Hoff factor i ? (Kf = 1.86 K kg mol–1).
[AIIMS 2018] (3) 0.80 K (4) 0.40 K
(1) 1.5 (2) 1.6 (3) 1.34 (4) 1.1
44. The mixture which shows positive
39. The mixture that forms maximum boiling
deviation from Raoult's law is:-
azeotrope is: [NEET 2019]
[NEET (UG) 2020]
(1) Acetone + Carbon disulphide
(2) Heptane + Octane (1) Chloroethane + Bromoethane
(3) Water + Nitric Acid (2) Ethanol + Acetone
(4) Ethanol + Water (3) Benzene + Toluene
(4) Acetone + Chloroform
40. For an ideal solution, the correct option
is: [NEET 2019]
(1) mix H = 0 at constant T and P 45. If 8g of a non-electrolyte solute is
(2) mix G = 0 at constant T and P dissolved in 114 g of n-octane to reduce
(3) mix S = 0 at constant T and P its vapour pressure to 80% the molar
(4) mix V 0 at constant T and P mass (in g mol–1) of the solute is:
[Given that molar mass of n-octane is 114
41. Which of the following statements is
correct regarding a solution of two g mol–1] [NEET (UG) 2020 (COVID-19)]
compounds A and B exhibiting positive (1) 40 (2) 60
deviation from ideal behaviour? (3) 80 (4) 20
[NEET (UG)(ODISHA) 2019]
(1) Intermolecular attractive forces
46. Isotonic solution shave same
between A-A and B-B are stronger
than those between A-B. [NEET (UG) 2020 (COVID-19)]
(2) mix H = 0 at constant T and P (1) vapour pressure
(3) mix V = 0 at constant T and P (2) freezing temperature
(4) Intermolecular attractive forces
(3) osmotic pressure
between A-A and B-B are equal to
(4) boiling temperature
those between A-B.
 For classes 6th to 12th
EWS Coaching 38
[ Proud to be associated with Ramkrishna Mission JEE (Mains & advanced) | NEET | NTSE | OLYMPIAD
Vidyapith, Deoghar]

47. The following solutions were prepared by 48. The correct option for the value of vapour
dissolving 10 g of glucose (C6H12O6) in 250 pressure of a solution at 45°C with
ml of water (P1), benzene to octane in molar ratio 3: 2 is:
10 g of urea (CH4N2O) IN 250 ml of water [At 45°C vapour pressure of benzene is
(P2) and 10 g of sucrose (C12H22O11) in 250 280 mm Hg and that of octane is 420 mm
ml of water (P3). The right option for the Hg. Assume Ideal gas] [NEET (UG) 2021]
decreasing order of osmotic pressure of (1) 160mm of Hg (2) 168 mm of Hg
these solutions is: [NEET (UG) 2021] (3) 336 mm of Hg (4) 350 mm of Hg
(1) P2 > P1 > P3
(2) P1 > P2 > P3 49. In one molal solution that contains
(3) P2 > P3 > P1 0.5 mole of a solute, there is
(4) P3 > P1 > P2 (1) 500 mL of solvent [NEET (UG) 2022]
(2) 500 g of solvent
(3) 100 mL of solvent
(4) 1000 g of solvent

ANSWER KEY
Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25
Ans. 2 3 1 2 4 2 3 2 1 2 4 1 3 1 3 3 2 4 1 3 2 1 1 2 2
Que. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49
Ans. 1 1 2 3 1 2 4 4 2 1 2 1 3 3 1 1 3 4 2 1 3 1 3 2