The Structure of The Atom

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Atomic Structure

The Structure of the Atom


v Atoms are the simplest particle of an element that retains all
the properties of that element.
• Three sub-atomic particles:
s electrons = "-" negative charge
s protons = "+" positive charge
s neutrons = neutral (a charge of zero)

• Protons and neutrons are always in the center of atom


(the nucleus).
• The electrons are found whizzing around the nucleus in
areas called orbitals.
The Electrons
v Electrons were discovered by Joseph John Thomson in 1897
• He sealed the gases in glass tubes with metal disks called
electrodes in each end which are connected to a high voltage
source of electricity.
• A glowing beam (cathode ray) formed and travels from cathode
to the anode.
s The cathode ray was attracted to the metal plate that carry a
positive electrical charge and repelled by the metal plate
carrying a negatively charge.
The Electrons
v The Millikan Oil Drop Experiment was designed to obtain
the charge of an electron which would then allow for the
calculation of the electron’s mass.
• Robert A. Millikan of the
University of Chicago used
droplets of oil for the suspension
measurement.
• The electron has a very small
mass.
The Electrons
v Negatively charged high energy particles with negligible
mass of 9.10938215 x10-28 g.
v Travel at very high speeds at various distances (energy
levels) from the nucleus
v Electrons in the same energy level are approximately the
same distance from the nucleus
v Outer energy levels have more energy than inner levels
v The currently accepted most accurate value for the
electron’s charge in coulombs is 1.602176487 x10-19 C or
simply, -1.
The Nucleus
v The nucleus is a dense central core within the atom
• It consists of positive charged
protons and neutral neutrons
• According to Rutherford, most of
the mass of the atom and all its
positive charge reside in a very
small, extremely dense region which
he called the NUCLEUS.
The Protons
v Protons were discovered by Ernest Rutherford in 1919, when
studying the nature of radioactivity.
• The positively charged particles in the
nucleus has a mass of 1.672621637 x 10-24
g, which is about 1800 times the mass of
an electron.
• The charge is 1.602176487 x10-19 C
(represented by +1), equal in size, but
opposite in sign, to the charge on an
electron.
The Neutrons
v The neutrons were discovered by James Chadwick (1932)
• They are electrically neutral particles in the nucleus of an
atom with no charge and a mass of 1.674927211 x10-24 g,
nearly the same as the mass of a proton.
• The number of neutrons varies slightly among atoms of
the same element.
The Structure of the Atom
• Sub-atomic particles
Atom

Electrons
Nucleus
(-charge)

Protons Neutrons
(+charge) (no charge)
Ions
v An ion is an atom or a group of atoms that has a net positive or
negative charge.
v During a chemical reaction, the number of positively charged
protons in the nucleus of an atom remains the same but negatively
charged electrons may be lost or gained.
v Cation is a positively charged ion and formed when the neutral
atom loses one or more electrons.
• Example: Magnesium atom can readily lose 2 electrons to
become Magnesium ion (Mg+2)
Mg atom: 12 electrons Mg+2 ion: 10 electrons
12 protons 12 protons
Ions
v Anion is a negatively charged ion and formed when the neutral
atom gains electrons
• Example: Oxygen atom can gain 2 electrons to become Oxygen
ion (O-2)
O atom: 8 electrons O-2 ion: 10 electrons
8 protons 8 protons
v With very few exceptions, metals tend to lose electrons and form
cations and nonmetals gain the electrons and form anions.
• Mg - 2e Mg+2 OR Mg Mg+2 + 2e
• O + 2e O-2 OR O O-2 - 2e

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