2406 PCM Test Paper Evening Final

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FINAL JEE–MAIN EXAMINATION – JUNE, 2022

(Held On Friday 24th June, 2022) TIME : 3 : 00 PM to 6 : 00 PM

PHYSICS TEST PAPER


SECTION-A 5. A Carnot engine take 5000 kcal of heat from a
1. Identify the pair of physical quantities that have reservoir at 727°C and gives heat to a sink at
127°C. The work done by the engine is :
same dimensions :
(A) 3 × 106 J (B) Zero
(A) velocity gradient and decay constant 6
(C) 12.6 × 10 J (D) 8.4 × 106 J
(B) wien's constant and Stefan constant
(C) angular frequency and angular momentum 6. Two massless springs with spring constants 2 k
(D) wave number and Avogadro number and 2 k, carry 50 g and 100 g masses at their free
ends. These two masses oscillate vertically such
that their maximum velocities are equal. Then, the
2. The distance between Sun and Earth is R. The
ratio of their respective amplitudes will be :
duration of year if the distance between Sun and (A) 1 : 2 (B) 3 : 2
Earth becomes 3R will be : (C) 3 : 1 (D) 2 : 3
(A) 3 years (B) 3 years
7. What will be the most suitable combination of
(C) 9 years (D) 3 3 years three resistors A = , B = , C = 6so that
 22 
 3   is equivalent resistance of combination?
3. A stone of mass m, tied to a string is being whirled  
in a vertical circle with a uniform speed. The (A) Parallel combination of A and C connected in
series with B.
tension in the string is :
(B) Parallel combination of A and B connected in
(A) the same throughout the motion
series with C.
(B) minimum at the highest position of the circular (C) Series combination of A and C connected in
path parallel with B.
(C) minimum at the lowest position of the circular (D) Series combination of B and C connected in
parallel with A.
path
(D) minimum when the rope is in the horizontal
8. The soft-iron is a suitable material for making an
position electromagnet. This is because soft-iron has :
(A) low coercively and high retentively
4. Two identical charged particles each having a mass (B) low coercively and low permeability
(C) high permeability and low retentively
10 g and charge 2.0 × 10–7 C area placed on a
(D) high permeability and high retentively
horizontal table with a separation of L between
then such that they stay in limited equilibrium. 9. A proton, a deuteron and an -particle with same
If the coefficient of friction between each kinetic energy enter into a uniform magnetic field
particle and the table is 0.25, find the value of L. at right angle to magnetic field. The ratio of the
[Use g = 10 ms–2] radii of their respective circular paths is :
(A) 1: 2 : 2 (B) 1:1: 2
(A) 12 cm (B) 10 cm
(C) 8 cm (D) 5 cm (C) 2 :1:1 (D) 1: 2 :1

1
10. Given below are two statements : 14. A 100 g of iron nail is hit by a 1.5 kg hammer
Statement-I : The reactance of an ac circuit is striking at a velocity of 60 ms–1. What will be the
zero. It is possible that the circuit contains a rise in the temperature of the nail if one fourth of
energy of the hammer goes into heating the nail?
capacitor and an inductor.
[Specific heat capacity of iron = 0.42 Jg–1 °C–1]
Statement-II : In ac circuit, the average poser
(A) 675°C (B) 1600°C
delivered by the source never becomes zero. (C) 160.7°C (D) 6.75°C
In the light of the above statements, choose the
correct answer from the options given below : 15. If the charge on a capacitor is increased by 2 C, the
(A) Both Statement I and Statement II are true. energy stored in it increases by 44%. The original
charge on the capacitor is (in C) :
(B) Both Statement I and Statement II are false.
(A) 10 (B) 20
(C) Statement I is true but Statement II in false.
(C) 30 (D) 40
(D) Statement I is false but Statement II is true.

16. A long cylindrical volume contains a uniformly


11. Potential energy as a function of r is given by
distributed charge of density . The radius of
A B
U  10  5 , where r is the interatomic distance, cylindrical volume is R. A charge particle (q)
r r
revolves around the cylinder in a circular path. The
A and B are positive constants. The equilibrium
kinetic of the particle is :
distance between the two atoms will be :
qR 2 qR 2
1 1 (A) (B)
A 5  B 5 4 0 2 0
(A)   (B)  
 B A
q 4 0 R 2
1 1 (C) (D)
4 0 R 2 q
 2A  5  B 5
(C)   (D)  
 B   2A 
17. An electric bulb is rated as 200 W. What will be
12. An object of mass 5 kg is thrown vertically the peak magnetic field at 4 m distance produced
upwards from the ground. The air resistance by the radiations coming from this bulb? Consider
produces a constant retarding force of 10 N this bulb as a point source with 3.5% efficiency.
throughout the motion. The ratio of time of (A) 1.19 × 10–8 T (B) 1.71 × 10–8 T
ascent to the time of descent will be equal to : (C) 0.84 × 10–8 T (D) 3.36 × 10–8 T
[Use g = 10 ms–2]
(A) 1 : 1 (B) 2: 3 18. The light of two different frequencies whose

(C) 3: 2 (D) 2 : 3 photons have energies 3.8 eV and 1.4 eV


respectively, illuminate a metallic surface whose

13. A fly wheel is accelerated uniformly from rest and work function is 0.6 eV successively. The ratio of
rotates through 5 rad in the first second. The angle maximum speeds of emitted electrons for the two
rotated by the fly wheel in the next second, will be : frequencies respectivly will be :
(A) 7.5 rad (B) 15 rad (A) 1 : 1 (B) 2 : 1
(C) 20 rad (D) 30 rad (C) 4 : 1 (D) 1 : 4

2
19. Two light beams of intensities in the ratio of 9 : 4 4. Two travelling waves of equal amplitudes and
are allowed to interfere. The .ratio of the intensity equal frequencies move in opposite directions

of maxima and minima will be : along a string. They interfere to produce a

(A) 2 : 3 (B) 16 : 81 stationary wave whose equation is given by

(C) 25 : 169 (D) 25 : 1 2 t


y = (10 cos  x sin ) cm
T

4
20. In Bohr's atomic model of hydrogen, let K. P and E The amplitude of the particle at x = cm will be
3
are the kinetic energy, potential energy and total
_______ cm.
energy of the electron respectively. Choose the
correct option when the electron undergoes
5. In the given circuit- the value of current IL will be
transitions to a higher level :
______ mA.
(A) All K. P and E increase.
(When RL = lk)
(B) K decreases. P and E increase.
800
(C) P decreases. K and E increase.
(D) K increases. P and E decrease. IL
5V RL = 1k
SECTION-B 10V

1. A body is projected from the ground at an angle of


6. A sample contains 10–2 kg each of two substances
45° with the horizontal. Its velocity after 2s is
A and B with half lives 4 s and 8 s respectively.
20 ms–1. The maximum height reached by the body
The ratio of then atomic weights is 1 : 2. The ratio
–2
during its motion is _______m. (use g = 10ms ) x
of the amounts of A and B after 16 s is . the
2. An antenna is placed in a dielectric medium of 100
value of x is _______.
dielectric constant 6.25. If the maximum size of

that antenna is 5.0 mm. it can radiate a signal of


7. A ray of ligh is incident at an angle of incidence
minimum frequency of ______GHz.
60° on the glass slab of refractive index 3 . After
(Given r= 1 for dielectric medium) refraction, the light ray emerges out from other
parallel faces and lateral shift between incident ray
and emergent ray is 4 3 cm. The thickness of the
3. A potentiometer wire of length 10 m and resistance
glass slab is _______ cm.
20 is connected in series with a 25 V battery and

an external resistance 30  . A cell of emf E in


8. A circular coil of 1000 turns each with area 1m2 is
secondary circuit is balanced by 250 cm long
rotated about its vertical diameter at the rate of one
potentiometer wire. The value of E (in volt) is revolution per second in a uniform horizontal
x magnetic field of 0.07T. The maximum voltage
. The value of x is _______.
10 generation will be _______V.

3
Q
9. A monoatomic gas performs a work of where
4
Q is the heat supplied to it. The molar heat
capaticy of the gas will be ________R during this
transformation.
Where R is the gas constant.

10. In an experment ot verify Newton's law of cooling,


a graph is plotted between, the temperature
difference (T) of the water and surroundings and
time as shown in figure. The initial temperature of
water is taken as 80°C. The value of t2 as
mentioned in the graph will be _______.

T(°C)
60

40

20

0 6 t2 Time (minute)

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FINAL JEE–MAIN EXAMINATION – JUNE, 2022
(Held On Friday 24th June, 2022) TIME : 3 : 00 PM to 6 : 00 PM

CHEMISTRY TEST PAPER


SECTION-A 6. Metals generally melt at very high temperature.
1. 120 of an organic compound that contains only Amongst the following, the metal with the highest
carbon and hydrogen gives 330g of CO2 and 270g melting point will be
of water on complete combustion. The percentage
(A) Hg (B) Ag
of carbon and hydrogen, respectively are.
(A) 25 and 75 (B) 40 and 60 (C) Ga (D) Cs

(C) 60 and 40 (D) 75 and 25 7. Which of the following chemical reactions


represents Hall-Heroult Process?

2. The energy of one mole of photons of radiation of (A) Cr2O3 + 2Al  Al2O3 + 2Cr
wavelength 300 nm is
(B) 2Al2O3 + 3C  4Al + 3CO2
(Given : h = 6.63 × 10–34 Js, NA = 6.02 × 1023mol–1,
c = 3 × 108 ms–1) (C) FeO + CO  Fe + CO2

(A) 235 kJ mol–1 (B) 325 kJ mol–1 (D) 2 Au  CN 2   Zn(s)  2Au(s)  Zn  CN4  2–

 aq 
(C) 399 kJ mol–1 (D) 435 kJ mol–1
8. In the industrial production of which of the

The correct order of bound orders of C2– 2– following, molecular hydrogen is obtained as a
3. 2 , N 2 and
byproduct?
O2–
2 is, respectively.
(A) NaOH (B) NaCl
2  N2  O2
(A) C2– 2  N 2  C2
2– 2–
(B) O2– 2– 2–

(C)Na metal (D) Na2CO3


2  O2  N 2
(C) C2– 2  C2  O2
2– 2–
(D) N2– 2– 2–

9. Which one of the following compounds is used as


a chemical in certain type of fire extinguishers?
4. At 25°C and 1 atm pressure, the enthalpies of
combustion are as given below: (A) Baking Soda (B) Soda ash
Substance H2 C(graphite) C2H6(g)
(C) Washing Soda (D) Caustic Soda
C H  –286.0 –394.0 –1560.0
10. PCl5 is well known. but NCl5 is not. Because.
kJmol –1
(A) nitrogen is less reactive than phosphorous.
The enthalpy of formation of ethane is
(A) +54.0 kJ mol–1 (B) –68.0 kJ mol–1 (B) nitrogen doesn't have d-orbitals in its valence
(C) –86.0 kJ mol–1 (D) +97.0 kJ mol–1
shell.
5. For a first order reaction, the time required for
(C) catenation tendency is weaker in nitrogen than
completion of 90% reaction is 'x' times the half life
of the reaction. The value of 'x' is phosphorous.
(Given: ln 10 = 2.303 and log 2 = 0.3010)
(D) size of phosphorous is larger than nitrogen.
(A) 1.12 (B) 2.43
(C) 3.32 (D) 33.31

1
11. Transition metal complex with highest value of 15. Which of the following reagents/ reactions will
convert 'A' to 'B'?
crystal field splitting (0) will be
CH2 CHO
3 3
(A) Cr  H 2 O 6  (B)  Mo  H 2 O 6 

H3C H3C
3 3
(C)  Fe  H 2 O 6  (D) Os  H 2 O 6  (A) (B)

12. Some gases are responsible for heating of (A) PCC oxidation

atmosphere (green house effect). Identify from the (B) Ozonolysis


(C) BH3,H2O2 / –OH followed by PCC oxidation
following the gaseous species which does not
(D)HBr, hydrolysis followed by oxidation by
cause it. K2Cr2O7 .
(A) CH4 (B) O3
16. Hex-4-ene-2-ol on treatment with PCC gives 'A'.
(C) H2O (D)N2
'A' on reaction with sodium hypoiodite gives 'B',
13. Arrange the following carbocations in decreasing which on further heating with soda lime gives 'C'.
order of stability. The compound 'C' is
(A) 2- pentene (B) proponaldehyde
 O O (C) 2-butene (D) 4-methylpent-2-ene


A B C 17. The conversion of propan-1-ol to n-butylamine
involves the sequential addition of reagents. The
(A) A > C > B (B) A > B > C correct sequential order of reagents is.

(C) C > B > A (D) C > A > B (A)(i) SOCl2 (ii) KCN (iii) H2/Ni,Na(Hg)/C2H5OH
(B) (i) HCl (ii) H2/Ni, Na(Hg)/C2H5OH
14. Given below are two statements.
(C) (i) SOCl2 (ii) KCN (iii) CH3NH2
Statement I : The presence of weaker - bonds
(D) (i) HCl (ii) CH3NH2
make alkenes less stable than alkanes.
Statement II : The strength of the double bond is
18. Which of the following is not an example of a
greater than that of carbon-carbon single bond.
condensation polymer?
In the light of the above statements, choose the
(A) Nylon 6,6 (B) Decron
correct answer from the options given below.
(C) Buna-N (D) Silicone
(A) Both Statement I and Statement II are correct.
19. The structure shown below is of which
(B) Both Statement I and Statement II are
well-known drug molecule?
incorrect.
H
(C) Statement I is correct but Statement II is CN
N
incorrect. N
(D) Statement I is incorrect but Statement II is S
N N
correct. NHCH3
H
(A) Ranitidine (B) Seldane
(C) Cimetidine (D) Codeine
2
20. In the flame test of a mixture of salts, a green 5. When 200 mL of 0.2 M acetic acid is shaken with
flame with blue centre was observed. Which one of 0.6 g of wood charcoal, the final concentration of
the following cations may be present? acetic after adsorption is 0.1 M. The mass of acetic
2+ 2+
(A) Cu (B) Sr acid adsorbed per garm of carbon is_____ g.
2+ 2+
(C) Ba (D) Ca

6. (a) Baryte, (b) Galena, (c) Zinc blende and


SECTION-B
(d) Copper pyrites. How many of these minerals
1. At 300 K, a sample of 3.0 g of gas A occupies the are sulphide based?
same volume as 0.2 g of hydrogen at 200 K at the
same pressure. The molar mass of gas A is____ g
7. Manganese (VI) has ability to disproportionate in
mol–1 (nearest integer) Assume that the behaviour
of gases as ideal. (Given: The molar mass of acidic solution. The difference in oxidation states
hydrogen (H2) gas is 2.0 g mol–1) of two ions it forms in acidic solution is______

2. A company dissolves 'X' amount of CO2 at 298 K 8. 0.2 g of an organic compound was subjected to
in 1 litre of water to prepare soda water estimation of nitrogen by Dumas method in which

X =____ × 10–3g. (nearest integer) volume of N2 evolved (at STP) was found to be

(Given: partial pressure of CO2 at 298 K= 0.835 22.400 mL. The percentage of nitrogen in the
bar. compound is____.[nearest integer]

Henry's law constant for CO2 at 298 K = 1.67 kbar. (Given: Molar mass of N2 is 28 mol–1. Molar

Atomic mass of H,C and O is 1, 12 and 6 g mol–1, volume of N2 at STP : 22.4 L)


respectively)
Cl
3. PCl5 dissociates as 9.
NaOH P
PCl 5  g  PCl3  g   Cl 2  g 
H2O (Major Product)
5 moles of PCl5 are placed in a 200 litre vessel
which contains 2 moles of N2 and is maintained at Consider the above reaction. The number of 
600 K. The equilibrium pressure is 2.46 atm. The electrons present in the product 'P' is____.
equilibrium constant Kp for the dissociation of PCl5
is_____ × 10–3. (nearest integer) 10. In alanylglycylleucylalanylvaline, the number of
peptide linkages is______.
(Given: R = 0.082 L atm K–1 mol–1 : Assume ideal
gas behaviour)

4. The resistance of conductivity cell containing


0.01 M KCl solution at 298 K is 1750 . If the
conductively of 0.01 M KCl solution at 298 K is
0.152 × 10–3 S cm–1, then the cell constant of the
conductivity cell is_______× 10–3 cm–1.

3
FINAL JEE–MAIN EXAMINATION – JUNE, 2022
(Held On Friday 24thJune, 2022) TIME : 3 : 00 PM to 6 : 00 PM

MATHEMATICS TEST PAPER


SECTION-A is the number of points where ƒ is not differentiable,
1. Let x*y = x2 + y3 and (x*1)*1 = x*(1*1). then the ordered pair (m, n) is :

(A) (3, 3) (B) (2, 4)


1 
x4  x2  2 
Then a value of 2 sin  4
 x  x 2  2 
is
  (C) (2, 3) (D) (3, 4)

 
(A) (B)
4 3 6. The value of the integral
  2
(C) (D) dx
2 6
 is equal to
 2 
1 e x
 sin 6 x  cos6 x 
2. The sum of all the real roots of the equation
(e2x – 4) (6e2x – 5ex + 1) = 0 is (A) 2 (B) 0

(A) loge3 (B) –loge3 


(C)  (D)
(C) loge6 (D) –loge6 2

3. Let the system of linear equations


7. 
n2 n2 n2 n2

x + y + z = 2 lim  2  2  2  ...  2 
 
n   n  1  n  1
    
n  4  n  2  n  9  n  3  
n  n n  n  
2

3x + y + z = 4
is equal to
x + 2z = 1
have a unique solution (x*, y*, z*). If (, x*), (y*, )  1  1
(A)  log e 2 (B)  loge 2
and (x*, –y*) are collinear points, then the sum of 8 4 4 8
absolute values of all possible values of  is :
(A) 4 (B) 3  1 
(C)  loge 2 (D)  loge 2
(C) 2 (D) 1 4 8 8

4. Let x, y > 0. If x3y2 = 215, then the least value of


3x + 2y is 8. A particle is moving in the xy-plane along a curve
(A) 30 (B) 32 C passing through the point (3, 3). The tangent to
(C) 36 (D) 40 the curve C at the point P meets the x-axis at Q. If
the y-axis bisects the segment PQ, then C is a
 sin  x   x  parabola with
 , x   2, 1
 x  x (A) length of latus rectum 3

5. 
Let ƒ  x   max 2x,3  x   , x 1 (B) length of latus rectum 6
 4 
 1 , otherwise (C) focus  , 0 
 3 

where [t] denotes greatest integer  t. If m is the  3
(D) focus  0, 
 4
number of points where ƒ is not continuous and n

1
9. Let the maximum area of the triangle that can be 14. If the shortest distance between the lines

x2 y2 x 1 y  2 z  3 x2 y4 z5


inscribed in the ellipse 2   1 , a > 2, having   and  
a 4 2 3  1 4 5
one of its vertices at one end of the major axis of the 1
is , then the sum of all possible values of  is :
ellipse and one of its sides parallel to the y-axis, be 3

6 3 . Then the eccentricity of the ellispe is : (A) 16 (B) 6


(C) 12 (D) 15
3 1 1 3
(A) (B) (C) (D)
2 2 2 4
15. Let the points on the plane P be equidistant from
the points (–4, 2, 1) and (2, –2, 3). Then the acute
10. Let the area of the triangle with vertices A(1, ), angle between the plane P and the plane 2x + y +
3z = 1 is
B(, 0) and C(0, ) be 4 sq. units. If the point
 
(, –), (–, ) and (2, ) are collinear, then  is (A) (B)
6 4
equal to
 5
(C) (D)
(A) 64 (B) –8 3 12
(C) –64 (D) 512

16. Let â and b̂ be two unit vectors such that


11. The number of distinct real roots of the equation
x7 – 7x – 2 = 0 is aˆ  bˆ   2 aˆ  bˆ   2 . If   (0, ) is the angle
(A) 5 (B) 7 (C) 1 (D) 3 between â and b̂ , then among the statements :

12. A random variable X has the following probability (S1) : 2 aˆ  bˆ  aˆ  bˆ

distribution :
X 0 1 2 3 4 
(S2) : The projection of â on â  bˆ is 1
2
P(X) k 2k 4k 6k 86
(A) Only (S1) is true
The value of P(1 < X < 4 | X  2) is equal to :
(B) Only (S2) is true
4 2
(A) (B)
7 3 (C) Both (S1) and (S2) are true

3 4 (D) Both (S1) and (S2) are false


(C) (D)
7 5
 3
17. If y = tan–1(secx3 – tanx3).  x3  , then
2 2
13. The number of solutions of the equation
(A) xy + 2y = 0
    1 3
cos  x   cos   x   cos2 2x , x  [–3, 2
(B) x y  6y  0
 3 3  4 2
3] is : (C) x2y – 6y + 3 = 0
(A) 8 (B) 5 (D) xy – 4y = 0

(C) 6 (D) 7
2
18. Consider the following statements : 3. The number of 7-digit numbers which are
A : Rishi is a judge. multiples of 11 and are formed using all the digits
1, 2, 3, 4, 5, 7 and 9 is _____.
B : Rishi is honest.
C : Rishi is not arrogant.
4. The sum of all the elements of the set
The negation of the statement "if Rishi is a judge
and he is not arrogant, then he is honest" is {  {1, 2, ..., 100} : HCF (, 24) = 1} is _____.

(A) B  (A  C)
5. The remainder on dividing 1 + 3 + 32 + 33 + ... +
(B) (~B)  (A  C)
32021 by 50 is _____.
(C) B  ((~A)  (~C))
(D) B  (A  C)
6. The area (in sq. units) of the region enclosed between
the parabola y2 = 2x and the line x + y = 4 is _____.
19. The slope of normal at any point (x, y), x > 0, y > 0
x2 7. Let a circle C : (x – h)2 + (y – k)2 = r2, k > 0, touch the
on the curve y = y(x) is given by .
xy  x 2 y 2  1 x-axis at (1, 0). If the line x + y = 0 intersects the
If the curve passes through the point (1, 1), then circle C at P and Q such that the length of the chord
e.y(e) is equal to PQ is 2, then the value of h + k + r is equal to _____.

1  tan 1
(A) (B) tan(1)
1  tan 1 8. In an examination, there are 10 true-false type
questions. Out of 10, a student can guess the answer
1  tan 1 3
(C) 1 (D) of 4 questions correctly with probability and the
1  tan 1 4
1
remaining 6 questions correctly with probability .
20. Let * be the largest value of  for which the 4
function f(x) = 4x3 – 36x2 + 36x + 48 is If the probability that the student guesses the
answers of exactly 8 questions correctly out of 10 is
increasing for all x  R. Then f*(1) + f*(–1) is
equal to : 27k
, then k is equal to _____.
(A) 36 (B) 48 410
(C) 64 (D) 72 x2 2
9. Let the hyperbola H : 2  y  1 and the ellipse
a
SECTION-B E : 3x2 + 4y2 = 12 be such that the length of latus
1. Let S = z  : z  3  1 and z  4  3i   z  4  3i   24 . rectum of H is equal to the length of latus rectum
of E. If eH and eE are the eccentricities of H and E
If  + i is the point in S which is closest to 4i,
then 25( + ) is equal to _____.
2

2
respectively, then the value of 12 e H  e E  is

equal to _____.
 1 a  
2. Let S    ;a, b 1,2,3,...100 and let
 0 b   10. Let P1 be a parabola with vertex (3, 2) and focus
Tn = {A  S : An(n + 1) = I}. Then the number of (4, 4) and P2 be its mirror image with respect to the
100
line x + 2y = 6. Then the directrix of P2 is x + 2y =
elements in Tn is _____.
n 1
_____.

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