The Supercooling of Water
The Supercooling of Water
The Supercooling of Water
Abstract
It is shown that suspension of drops at the interface of two insoluble liquids represents a
satisfactory method of studying the supercooling of water. The temperatures of
supercooling thus found depend on the volume of the sample and the rate of cooling. The
inter-relation between temperature, volume and time is derived theoretically from simple
probability considerations and is shown to be consistent with experiment.
1 Introduction
Domestic water supplies are one of the fundamental requirements for human life. Without
water, life cannot be sustained beyond a few days and the lack of access to adequate water
supplies leads to the spread of disease. Children bear the greatest health burden associated
with poor water and sanitation. Diarrhoeal diseases attributed to poor water supply,
sanitation and hygiene account for 1.73 million deaths each year and contribute over 54
million Disability Adjusted Life Years, a total equivalent to 3.7% of the global burden of
disease (WHO, 2002). This places diarrhoeal disease due to unsafe water, sanitation and
hygiene as the 6th highest burden of disease on a global scale, a health burden that is
largely preventable (WHO, 2002). Other diseases are related to poor water, sanitation and
hygiene such as trachoma, schistosomiasis, ascariasis, trichuriasis, hookworm disease,
malaria and Japanese encephalitis and contribute to an additional burden of disease.
As of 2000 it was estimated that one-sixth of humanity (1.1 billion people) lacked access
to any form of improved water supply within 1 kilometre of their home (WHO and
UNICEF, 2000). Lack of access to safe and adequate water supplies contributes to
ongoing poverty both through the economic costs of poor health and in the high
proportion of household expenditure on water supplies in many poor communities,
arising from the need to purchase water and/or time and energy expended in collection.
Access to water services forms a key component in the UNDP Human Poverty Index for
developing countries (UNDP, 1999).
The importance of adequate water quantity for human health has been recognised for
many years and there has been an extensive debate about the relative importance of water
quantity, water quality, sanitation and hygiene in protecting and improving health
(Cairncross, 1990; Esrey et al., 1985; Esrey et al., 1991). Despite this debate, international
guidelines or norms for minimum water quantities that domestic water supplies should
provide remain largely lacking. For instance, whilst the Millennium Declaration Goals
include a target to 'halve the proportion of people who are unable to reach or to afford
safe drinking water by 2015' (UN, 2000) it does not specify in what quantity such water
should be supplied. The WHO/UNICEF Joint Monitoring Programme, which produces
the Global Assessment of Water Supply and Sanitation data, describe reasonable access
as being 'the availability of at least 20 litres per person per day from a source within one
kilometre of the users dwelling' (WHO and UNICEF, 2000). However, it should be noted
that this definition relates to primarily to access and should not necessarily be taken as
evidence that 20 litres per capita per day is a recommended quantity of water for domestic
use.
Norms for quantities of water to be supplied have been proposed for certain specific
conditions. For instance the SPHERE project sets out 15 litres of water used per capita
per day as being a key indicator in meeting minimum standards for disaster relief
(SPHERE, 1998). In their guidance manual prepared for the Department for International
Development (UK), WELL (1998) suggested that a minimum criterion for water supply
should be 20 litres per capita per day, whilst noting the importance of reducing distance
and encouraging household connection. A similar figure has been suggested by other
researchers (Carter et al., 1997). Gleick (1996) suggested that the international
community adopt a figure of 50 litres per capita per day as a basic water requirement for
domestic water supply.
Many uses of water occur largely at the household (for instance drinking, eating and hand
washing); others may occur away from the home (laundry and in some cases bathing).
This therefore needs to be borne in mind when ensuring that adequate quantities of
domestic supply are available for these purposes and in interpreting and applying
minimum values.
Despite common claims of WHO standards relating to water quantity, WHO has not
previously published specific guidance on the quantities of water as targets for the health
protection and promotion. This is in contrast to the concerted effort made, for example,
in relation to establishing international standards and later guidelines for drinking-water
quality (WHO, 1985; 1993), wastewater use (Mara and Cairncross, 1989) and
recreational water quality(WHO, in finalisation).
The purpose of this paper is to review the evidence of the relationships between water
quantity, access and health and to provide a basis for the establishment of minimum
quantity and/or access targets for domestic water supplies. It does not address the
requirement of waters for specific groups (e.g. athletes), specific settings (e.g. hydration
needs during air travel or particular occupational settings) or health impacts related to
hydration derived from alcohol consumption.
The paper draws on an extensive literature review based primarily on the published
literature, but in some cases also drawing on ‘grey’ literature where the data was believed
to be of good quality and where this provided clearer information. Key word searches in
Cambridge Scientific Abstracts (including Aqualine, Water Resource Abstracts and
Bacteriology Abstracts) and Medline were employed. In addition, a review was
undertaken of available materials (papers, books, theses, conference proceedings) at
WEDC and WHO resource centres. A representative literature was captured through this
process, although as noted within the text in some areas available literature and evidence
is sparse.
2 Defining domestic water supply
In its Guidelines for Drinking-Water Quality, WHO defines domestic water as being
'water used for all usual domestic purposes including consumption, bathing and food
preparation' (WHO, 1993; 2002). This implies that the requirements with regard to the
adequacy of water apply across all these uses and not solely in relation to consumption
of water. The Guidelines exclude some specific uses (for instance dialysis and contact
lens cleaning) and elevated requirements for some particularly sensitive sub-populations
(for instance the severely immuno-compromised). Although this broad definition
provides an overall framework for domestic water usage in the context of quality
requirements, it is less useful when considering quantities required for domestic supply.
• Hygiene (including basic needs for personal and domestic cleanliness) • Amenity use
(for instance car washing, lawn watering).
In updating the Drawers of Water study, Thompson et al. (2001) suggest a fourth category
can be included of 'productive use' which was of particular relevance to poor households
in developing countries. Productive use of water includes uses such as brewing, animal
watering, construction and small-scale horticulture.
The first two categories identified by White et al. (1972): ‘consumption’ and ‘hygiene’,
have direct consequences for health both in relation to physiological needs and in the
control of diverse infectious and non-infectious water-related disease. The third
category: ‘amenity’ may not directly affect health in many circumstances. Productive
water may be critical among the urban poor in sustaining livelihoods and avoiding
poverty and therefore has considerable indirect influence on human health (Fass, 1993;
Thompson et al., 2001).
The different primary uses of water are discussed in the following sections and the
quantity requirement of each and its implication for health are reviewed.
3 Consumption
Water is a basic nutrient of the human body and is critical to human life. It supports the
digestion of food, adsorption, transportation and use of nutrients and the elimination of
toxins and wastes from the body (Kleiner, 1999). Water is also essential for the preparation
of foodstuffs and requirements for food preparation are included in the discussion of
consumption requirements.
Frequencies of Detection
Of the seven herbicides of interest, all but acetochlor were among the 10 pesticides or
pesticide transformation products detected most often in ground water during the 1993–1995
NAWQA sampling (Kolpin et al., 1998a; Barbash et al., 1999; USGS, 1999). Frequencies
of detection at or above 0.01 μg L−1 in ground water are shown in Fig. 2 These results are
displayed for the same four study components examined in Fig. 1 Variations in the
frequencies of detection among the different herbicides and study components provide clues
regarding the effects of a variety of natural and anthropogenic factors on the likelihood of
detecting these compounds in ground water. The influences of several of these factors are
examined below.
Water discussion:
Water is involved in many food processing methods and unit operations, e.g., soaking,
washing, rinsing, fluming, blanching, scalding, heating, pasteurising, chilling, cooling, steam
production, as an ingredient, and for general cleaning, sanitation and disinfection purposes.
The food industry is characterised by high water consumption per ton of food product as
exemplified by some figures from Germany, e.g., 30 m3 wastewater per ton of frozen carrot
produced, 1.2 m3 for apple juice, 4.15 m3 for
Use of food industry wastewaters for irrigation reuse is often reported (Hrudey, 1981;
Hamoda and Al-Awadi, 1996). However, it will often be more optimal and effective to reuse
these effluents within the same industry. Due to the wide variety of process steps and food
products, food process water may contain a complex mixture of constituents, and this should
be taken into account when considering recycling, reuse, reconditioning for recycling or
reuse, wastewater treatment or discharge. The
Some of the problems that may arise or stop the implementation of greater water reuse
practices in the food industry together with some suggested solutions are commented in the
following. A list of the most relevant drivers, barriers, and challenges associated with water
reuse in the food industry is found in Table 4.
Conclusions
Facing the numerous challenges to implementation of water reuse practices in food industries
is unavoidable due to increasing demands on declining freshwater supplies, environmental
and economical incentives resulting from reuse, and the great potential for water reuse at
food industries. Current legislation acknowledges the use of alternative qualities when the
product safety and the safety of the working environment are not compromised. Elaborating
and implementing HACCP plans for water
Acknowledgments
The authors would like to acknowledge the Danish Research Council for providing funding
for this investigation (project number 9800943). This study is part of the activities carried out
by CEVI (Danish Centre for Industrial Water Management).
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