Scribd Logo
Upload

Welcome to Scribd!

  • 3 views

    Organic Review 4 Marking

    Uploaded by

    vickrantselvendran

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Organic Review 4 Marking

    Uploaded by

    vickrantselvendran
    3 views3 pages

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    3 views3 pages

    Organic Review 4 Marking

    Uploaded by

    vickrantselvendran

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    You are on page 1of 3

    Organic Review – 04

    1. Br
    l
    i) CH3 CHCH3 + CH3 CH2 CH2 Br
    ii) CH3 CH2 CH2 Br
    iii) CH3 CH2 Cl
    iv) CH3 CH2 CH2 Cl
    v) CH3 CH2 CH2 OH
    vi) CH3 CH = CH2
    vii) CH3 CH2 CH2 CN
    viii) CH3 CH2 NH2
    ix) CH3 CH2 CH2 – O – CH3 (m%Odk) CH3 CH = CH2 (iq¿)
    x) CH3 CH2 C ≡ C – CH2 CH3 (m%Odk) CH2 = CH2 (iq¿)

    δ+
    2. H H H H
    δ+l l l l
    i) H – C = C – Br δ − H – C = C – H + Br − + H2 O
    δ+ l l
    H H
    −ሷOH

    δ+
    ii) CH3 CH2 CH2 – Br δ − CH3 CH2 CH2 OH + Br −

    −ሷ OH

    CH3 CH3
    l δ− l +
    iii) CH3 – C – Br CH3 – C −ሷ
    l l OH
    CH3 CH3

    CH3
    l
    CH3 – C – OH
    l
    CH3

    3.
    PBr3 / PBr5
    i) CH3 CH2 CH2 OH CH3 CH2 CH2 Br

    O HCN
    ll H + /H2 O
    CH3 CH2 CH2 – C – OH CH3 CH2 CH2 CN

    wñ, oikdhl | wdidfjka bf.k.kak


    O
    ii) NaOH(aq) PCC ll
    CH3 CH2 Br CH3 CH2 OH CH3 – C – H

    O O
    ll ① id¡ H2 SO4 ll NaOH
    CH3 CH2 CH – C – H CH3 – CH = CH – C – H
    l ② H2 O ∆
    OH
    ① LiAlH4
    ② H + /H2 O
    PBr3
    CH3 CH2 CHCH2 OH CH3 CH2 CHCH2 Br
    l l
    OH Br KCN
    CH3 CH2 CH – CH3 – CN
    l
    CN

    O
    iii) CH3 CH2 CH2 OH PCC ll
    CH3 CH2 – C – H
    Zn(Hg) NaOH
    HCl O ∆
    ll
    CH3 CH = CH – CH – CH3 CH3 CH = CH – CH– C – H
    l l
    CH3 CH3

    OH − /KMnO4 OH Br CH3
    l PBr3 l l
    CH3 CHCH – CH– CH3 CH3 CH – CH – CH3
    l l l l
    OH CH3 Br CH3

    COOH CH3 CN
    l l H + /H2 𝑂 l KCN
    CH3 CHCH – CH– CH3 CH3 CH – CH– CH3 – CH3
    l l l
    COOH CN CH3

    iv) CH3 CH2 – OH CH3 CH – CH2 CH2 – CH– CH3


    l l
    CN CN

    CN CN
    l l
    v) CH3 CH2 – OH CH3 CH – CH– CH2

    wñ, oikdhl | wdidfjka bf.k.kak


    4.
    i) CH3 CH2 OD
    OLi
    l
    ii) CH3 – C – H CH3 CH2 OH
    l
    H
    OLi OH
    l l
    iii) CH3 – C – CH3 CH3 – CH – CH3
    l
    H
    O O
    ll ll
    iv) CH3 – C – H CH3 – C – OH

    O
    ll
    v) CH3 – C – CH3

    Organic Review – 05

    5. OSO3 H OH
    l l
    i) CH3 CH2 CH – CH3 CH3 CH2 CH – CH3
    ii) CH3 CH2 OH
    iii) CH3 CH2 OH
    iv) CH3 CH2 CH2 OH
    OH
    l
    v) CH3 CH – CH3
    vi) CH3 CH2 OH
    +
    O− MgBr OH
    l l
    vii) CH3 CH2 – CH – CH3 CH3 CH2 CH – CH3
    viii) CH3 CH2 Br
    ix) CH3 CH2 Br / H3 PO3
    x) CH3 CH2 Cl / POCl3 + HCl
    xi) CH3 CH2 C − Na+ / CH3 CH2 – O – CH3
    O O
    ll ll
    xii) CH3 – C – H CH3 – C – OH

    O
    ll
    xiii) CH3 – C – CH3
    xiv) CH3 CH2 OH / N2

    wñ, oikdhl | wdidfjka bf.k.kak

    You might also like