TP2
TP2
TP2
Faculty of Science
Department of Material L2 2024-2025
Sciences
PW 02 : Solubility-complex
This practical session aims to study and compare the solubility of some chemical elements.
RAPPELS :
Definition of Solubility:
Solubility is the ability of a substance, called a solute, to dissolve in another substance, called
a solvent, to form a homogeneous mixture called a solution.
Solubility S is the maximum quantity of salt (in mol/l) or (g/l) that can dissolve in the solution.
S moles 0 0
0 moles S moles S moles
Practical part:
Concept of salt in solution and complexation:
1. Relationship of solubility and temperature:
Fill 1/4 of a test tube with distilled water, add a littel of salt, and shake the solution. Record
your observation.
Then add as many pinches of salt while stirring until it can not dissolve. Conclude
Fill 1/4 of a test tube with distilled water, add a piece of chalk, shake strongly by capping the
tube with your thumb. Record your observation.
1. Add a few drops of concentrated hydrochloric acid HCl. Record your observation.
2. Then add a few drops of concentrated NaOH until you get a change, which one?
1. Add to a tube containing a solution of copper chloride (CuCl2), a few drops of ammonia
NH3 (aq). Record your observations.
ACCOUNT
1/ Describe the experiments and note your observations using a diagram
2/ Give the results of a chemical reaction by specifying its physical state (aqueous (aq) – liquid
(l) – gaseous (g)
………………………………………….
…………………………………………
NH4+ Li+ Na+ K+ Mg2+ Ca2+ Ba2+ Al3+ Cu2+ Fe2+ Fe3+ Ni2+ Zn2+ Hg2+ Ag+ Sn2+ Pb2+
CH3COO- ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ● -- ○
NO3- ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○
Cl- ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ● ○ ●
Br- ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ● ● ○ ●
I- ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ -- ○ ○ ● ● ○ ●
négatives ions (anion)
SO42- ○ ○ ○ ○ ○ ● ● ○ ○ ○ ○ ○ ○ -- ○ ○ ●
SO32- ○ ○ ○ ○ ● ● ● -- -- ● -- -- ● -- ● -- ●
S2- ○ ○ ○ ○ -- -- -- -- ● ● ● ● ● ● ● ● ●
CO32- ○ ○ ○ ● ● ● -- ● ● -- ● ● -- ● -- ●
OH- ○ ○ ○ ○ ● ● ○ ● ● ● ● ● ● ● ● ● ●
PO43- ○ ○ ○ ○ ● ● ● ● ● ● ● ● ● ● ● -- ●
CrO42- ○ ○ ○ ○ ○ ○ ● -- ● -- ● ● ● ● ● -- ●