CHEMISTRY (SET-1)

S.No EXPECTED ANSWER / VALUE POINTS MARKS

1 a 1
2 b 1
3 d 1
4 b 1
5 d 1
6 c 1
7 b 1
8 c 1
9 a 1
10 b 1
11 d 1
12 a 1
13 b 1
14 a 1
15 c 1
16 a 1

17 ∆Tf= Kfm 1/2

∆Tf= Kf× WB / MB × WA

1.5 = 3.9× WB / 176 × 0.075 1

WB = 5.08 g 1/2

18 (a) 9 times 1
1/2+1/2
(b) Correct definition + Correct example

19

(a) Methyl tert-butyl ketone < Acetone < Acetaldehyde, 1

20
(b) (CH3)2CHCOOH < CH3CH (Br) CH2COOH <CH3CH2CH (Br) COOH 1
(Or)
 (a)

(b)

1
(a) Glucose gets oxidized to Gluconicacid . 1
21
1
(b) n – Hexane is formed .
(a) Any two correct differences 1/2 +
22 1/2
(b) t1/2 =69.3 min
[R]0 = 100
[ R] = 20
t =?
Then K=0.693/ t1/2
= 0.693/69.3 1/2
=0.01

t=2.303/K (log [R]0/[R])

1/2
= 2.303 / 0.01 log(100/20)
1/2
= 160.97 min
Or 1/2
(a) Correct definition

(b) 1

1/2

1/2

1/2

1/2
 (a) Ethylamine dissolves in water due to intermolecular H-bonding. However, 1
23 in case of aniline, due to the large hydrophobic part, i.e., hydrocarbon part, the
extent of H-bonding is very less therefore aniline is insoluble in water.
(b) Under strongly acidic condition anilinium ion is formed which is meta
directing . 1
(c) Aniline being a lewis base reacts with lewis acid AlCl3 to form salt .As a
result N of aniline acquire positive charge which act as strong deactivating 1
group for further reaction .
1
24

(b) If ∆o> P , t2g5 eg0

1/2
If ∆o< P , t2g3 eg2
1/2
(a) Correct reaction 1
25 (b) Correct reaction 1
(c) Correct reaction 1
(a) (i) [Cr (H2O)6] Cl3 1
26 (ii) Hexaaquachromium (III) chloride 1
(b) Hybridisation – dsp2 Shape – Square planar 1/2
+1/2
a) CHCl3 is stored in dark coloured bottles to cut off light because CHCl3is 1
27 slowly oxidised by air in presence of light to form an extremely poisonous gas,
carbonyl chloride, popularily known as phosgene.
(b) Both enantiomeric forms cancel the optical rotation of each other . 1
(c) Due to +R effect partial double character arises / due to sp2hybridised C of
haloarenes to which halogen is attached . 1
The limiting molar conductivity of an electrolyte can be represented as the sum 1
28 of the individual contributions of the anion and cation of the electrolyte .
Correct explanation for strong electrolyte
Correct explanation for strong electrolyte 1
1
 (a) The process of movement of solvent through a semipermeable membrane
29 from the solution to the pure solvent by applying excess pressure on the 1
solution side is called reverse osmosis.
(b) Cellulose acetate 1
(c) (i) RBC’s will shrink due to plasmolysis .
(ii) RBC’s will swell and even burst due to hemolysis . 1+1
or
because the magnitude of osmotic pressure is large even for very dilute
solution and it can be measured at room temperature . 1+1

30 (a) Hydrogen bonding 1

(b) When egg is boiled ,the protein first undergo denaturation and then
coagulation .The water present in the egg gets absorbed in the coagulated 1
proteins through H – bonding .
(c) Any two correct differences . 1+1
(Or)
Correct definition + Correct example 1+1

31 (a) Anode - Pb + SO42- → PbSO4 + 2e- 1

Cathode – PbO2 + SO42- +4H+ + 2e- → PbSO4 + 2H2O 1

(b)

1/2

1/2

(Or)
(a) Galvanic cells that are designed to convert the energy of combustion of fuel 1/2+1/2
directly into electrical energy are called fuel cells . (Ans +
-
Anode – H2 + 2OH → 2H2O + 2e - Unit)
Cathode - O2 + 2H2O + 4e- → 4OH-
1
(b) m = k × 1000 /C 1/2+
-5
= 3.905 × 10 × 1000 /0.001 1/2
2 -1
= 39.05 S cm mol
m CH3COOH = m CH3COO- + mH+ 1/2
= 40.9 + 349.6 1/2
2
= 390.5 S cm mol -1 1/2
α =  m / m
c 1/2
= 39.05/390.5 1/2
= 0.1 1/2
 (a) (i) Ethanal on heating with Tollen’s reagent form silver mirror or any other 1
32 correct difference
(ii) Benzoic acid reacts with sodium bi carbonate to give brisk 1
effervescence of CO2 .or any other correct difference .
(b) (i) Correct conversion 1
(ii) Correct conversion 1
(c) This is due to the lone pairs on oxygen atom attached to hydrogen atom in
the -COOH group are involved in resonance and hence making the carbon 1
atom less electrophilic.
or
’
(a) (i) Propanal on heating with Tollen s reagent form silver mirror . 1
or any other correct difference .
(ii) Acetophenone on heating with I2 and NaOHform yellowppt of 1
iodoform . or any other correct difference .

(b) Correct reaction with correct missing reagent or product 1 +1+1

33 (a) Both Ti3+ and Cu2+ have 1 unpaired electron, so the magnetic moment for
both will be 1.73 BM
(b) Zn, it has a more negative electrode potential so will corrode itself in place
of iron.
(c) Mn+ has 3d 54s1 configuration and configuration of Cr+ is 3d5 , therefore,
ionisation enthalpy of Mn+ is lower than Cr+ .
(d) Sc and Zn both form colourless compound and are diamagnetic.
(e) The decrease in the atomic and ionic radii with increase in atomic number
of actinoids due to poor shielding effect of 5f electrons .
(f) In both chromate and dichromate ion the oxidation state of Cr is +6 (1
(g) 10I- + 2MnO4- + 16H+ → 2Mn2+ + 8H2O + 5I2 each ,
any 5)