JMTS 24 - 25 (FST-01) (09-Dec-24) Master
JMTS 24 - 25 (FST-01) (09-Dec-24) Master
JMTS 24 - 25 (FST-01) (09-Dec-24) Master
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JMTS 24 - 25 (FST-01) (09-Dec-24) 2
5. The ends of a rod of length and mass m are 5
attached to two identical springs as shown in Y < 0 it is . The unit vector along which the
2
figure. The rod is free to rotate about its centre refracted ray moves is
O. The rod is depressed slightly at end A and
released. The time period of the resulting (1)
3iˆ 5jˆ (2)
4iˆ 3jˆ
oscillation is. Where K is spring constant 34 5
3iˆ 4ˆj 4iˆ 3jˆ
(3) (4)
5 5
Ans. 4
4r dr
2
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JMTS 24 - 25 (FST-01) (09-Dec-24) 3
(3)
(1) 5 2V (2) 5 V
(3) 10 V (4) None of these
(4) Ans. 2
Sol. Z (XL XC )2 R 2 25 25 5 2
10 / 2
Ans. 3 Irms 1
5 2
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JMTS 24 - 25 (FST-01) (09-Dec-24) 4
V 1 (XL XC ) 1 5 5 Volt (D) Nuclear forces are central and charge
independent.
14. A vernier callipers having 1 main scale division (E) Stability of nucleus is inversely proportional
= 0.1 cm is designed to have a least count of 0.02 to the value of packing fraction.
cm. If n be the number of divisions on vernier Choose the correct answer from the options
scale and m be the length of vernier scale, then given below :
(Assume that vernier calliperse is calibrated such (1) (A), (B), (C), (D) only
that length of (N-1) main scale divisions is equal (2) (A), (C), (D), (E) only
to N vernier scale divisions) (3) (A), (B), (C), (E) only
(1) n=10, m=0.5 cm (2) n=9, m=0.4 cm (4) (B), (C), (D), (E) only
(3) n=5, m=0.4 cm (4) n=10, m=0.2 cm Ans. 3
Ans. 3 Sol. Part of theory
1M.S.D
Sol. L.C and N - 1 M.S.D = NVSD 17. A projectile is projected at 30° from horizontal
No. Of V.S.D
with initial velocity 40ms1. The velocity of the
15. In an experiment, brass and steel wires of length projectile at t = 2 s from the start will be: (Given
used. The wires are connected in series and one (1) 40 3ms 1 (2) Zero
end of the combined wire is connected to a rigid (3) 20ms1 (4) 20 3ms 1
support and other end is subjected to elongation. Ans. 4
The stress required to produce a net elongation
Sol. VH 40cos30o 20 3
of 0.2 mm is, [Given, the Young’s Modulus for
steel and brass are, respectively, VV 20 10 2 0m / s
120 109 N / m 2 and 60 109 N / m 2 ] V VH 20 3m / s
180
N
8 106 2 (Answer is not matching)
m
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JMTS 24 - 25 (FST-01) (09-Dec-24) 5
A 2 A
F v 2v2
4 4
3Av 2 3 2
pressure v
(2) 4A 4
(Section-2)
This section contains 5 questions numbered 21 to 25.
The answer of each question is a numeric
value/Integer type.
21. A metal rod AB of length $10 m$ has its one end
(3)
A in ice at 0o C and the other end B in water at
100o C . If a point P on the rod is maintained at
400o C , then it is found that equal amounts of
water and ice evaporate and melt per unit time.
The latent heat of evaporation of water is 540
(4) cal/g and latent heat of melting of ice is 80 cal/g.
If the point P is at a distance of m from the ice
end A, find the value of . [Neglect any heat
loss to the surrounding]
Ans. 4
Ans. 9
Sol. In +ve half cycle
D1 FB;D2 R.B. Q 300
Sol. 10x x mL v .....(1)
0 – 0.6 V t l
KA
Vout sameasVin
Q 400
In –ve half cycle x mLf ....(2)
t w
D2 F.B;D1 R.B. KA
300 x L v
19. The fundamental frequency of a closed organ dividing
10x x 400 Lf
pipe is equal to the first overtone frequency of an
3 540
open organ pipe. If length of the open pipe is 60
cm, the length of the closed pipe will be : 4 (10 ) 80
(1) 30 cm (2) 45 cm (3) 60 cm (4) 15 cm 9(10 )
Ans. 4 10 90
V 2V 9
Sol. f
4 2(60)
1 1
4 60
15 cm
22. A small solid ball rolls without slipping along the
20. A liquid of density is coming out of a hose track shown in fig. radius of the circular part of
the track is R. If the ball starts from rest at a
pipe of radius a with horizontal speed v and hits
height of 8 R above the bottom, what is the
a mesh. 50% of the liquid passes through the
horizontal force acting on it at point P ? Given
mesh unaffected. 25% looses all of its
mass of solid ball = 0.05 kg and g =10
momentum and 25% comes back with the same
speed. The resultant pressure on the mesh will be
3 1 1
(1) v2 (2) v2 (3) v2 (4) v 2
4 4 2
Ans. 1
Sol. Let area be A.
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JMTS 24 - 25 (FST-01) (09-Dec-24) 6
Ans. 5 26. The freezing point depression of a 0.1 M aq.
1 1 7 solution of weak acid (HX) is –0.20°C. What is
Sol. Total K.E. of ball at P I2 mv2 mv2
2 2 10 the value of equilibrium constant for the
Now loss of P.E at P = K.E of the ball at P reaction: HX(aq) H (aq) X (aq)
7 [Given : K f for water = 1.8 kg mol1 K. &
? m.g. 7R mv 2
10 Molality = Molarity ]
v 10gR
2
and force acting on the ball (1) 1.46 104 (2) 1.35 103
mv m 10gR
2
(3) 1.21102 (4) 1.35 104
10mg
R R Ans. 2
23. In a single slit diffraction pattern, a light of 27. EMF of a cell is given by E (1.05 104 T 2 )
wavelength 6000 Å is used. The distance
V, where T is temperature in Kelvin. Which of
between the first and third minima in the
the following options are correct w.r.t. the
diffraction pattern is found to be 3 mm when the
galvanic cell.
screen in placed 50 cm away from slits. The
(1) H oRxn of the cell reaction will be
width of the slit is _______ x 104 m.
temperature independent.
Ans. 02.00
(2) The cell reaction involves increase in
3D D
Sol. y3 y1 randomness.
d d
(3) At all the temperatures, the cell reaction will
2D
3mm be spontaneous.
d (4) The cell reaction will be non-spontaneous at
2 6 107 50 102 T = 200K.
3 103
d Ans. 2
d 2 104
28. A saturated solution in AgA (K sp 3 1014 )
24. A satellite is launched into a circular orbit of
radius R around the earth. A second satellite is and AgB (K sp 1 1014 ) has conductivity of
launched into an orbit of radius (1.02)R. The 375 1010 Scm 1 and limiting molar
period of the second satellite is larger than the
conductivity of Ag and A are 60 Scm mol 1
2
first one by approximately how much
percentage. and 80 Scm 2 mol 1 respectively then what will
Ans. 3 be the limiting molar conductivity of B (in
Scm 2 mol 1 )
25. Electric field in a region is given as
(1) 150 (2) 180 (3) 190 (4) 270
E xiˆ 2yjˆ 3kˆ . In this region point A(3,3,1)
Ans. 4
and point B (4,2,1) are there. If the magnitude of
work done by the electric field (in joules), in 29. 0.1 M NH3 (aq) solution is titrated against 0.1
moving 2 coulomb charge from A to B is -x then
M HNO3 (aq) solution. What would be the
find x. All values given and asked are in SI units.
Ans. 3 1 3
difference in pOH between and stages of
(4,2,1) 4 4
Sol. WE 2 (3,3,1)
xdx 2ydy 3dz 3 neutralization of base?
(1) 2 log 3/4 (2) 2 log 1/4
PART- II
(3) log 1/3 (4) 2 log 3
CHEMISTRY (Section-1)
This section contains 20 questions numbered 26 to Ans. 4
45. Each question has 4 choices (1), (2), (3) and (4), out
of which ONLY ONE is correct.
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JMTS 24 - 25 (FST-01) (09-Dec-24) 7
30. Select the incorrect property for Fe4 [Fe(CN)6 ]3 (1) A and C (2) B and D
complex (3) B and C (4) C and D
Ans. 2
(1) d 2sp3 hybridisation of coordinated Fe atom
(2) Blue colour due to ligand to metal charge
34. Alcohol A is :
transfer
(3) Six electrons are present in t 2g orbital
(4) More bond length of (C – N) than in
Fe[Fe(CN)6 ] (1) Propan-1-ol
(2) Propan-2-ol
Ans. 2
(3) 2-methylpentane-2,4-diol
(4) Butan-2-ol
31. In the hydrogen spectrum, the longest
Ans. 2
wavelength in the Lyman series is xÅ and the
shortest wavelength in the Balmer series is yÅ.
Hence, the longest wavelength of light needed to Sol.
ionise a hydrogen atom from its ground state
should be 35. Distillation under reduced pressure is used for.
(1) (x + y) Å (2) (y – x) Å (1) to separate liquids with close boiling point.
xy o (x y) o (2) to separate liquids with sufficient difference
(3) A (4) A
(x y) xy in their boiling point.
Ans. 3 (3) to separate liquids which are steam volatile
and immiscible with water.
32. Which of the following statements is/are (4) to liquids which break downs at their boiling
Incorrect about the above reaction ? point.
Ans. 4
(4)
Ans. 3
Sol. Nucleophilic substitution in difficult at benzene
due to partial double bond character.
At room temperature the reaction follows SN2
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JMTS 24 - 25 (FST-01) (09-Dec-24) 8
37. 10 ml of KMnO4 solution exactly requires 100 o
40. In BF3 the B–F bond length is 1.30 A when BF3
ml of 5.6 vol H2O2 solution for reaction in
is allowed to be treated with Me3 N it forms an
acidic medium. The molarity of KMnO4
adduct, Me3 N BF3 the bond length of B–F in
solution is :
the adduct is
(1) 0.2M (2) 0.1M (3) 2M (4) 1M o o
Ans. 3 (1) greater than 1.30 A (2) smaller than 1.30 A
KMnO4 H 2 O2 H Mn 2 O2
o
Sol. (3) equal to 1.30 A (4) none of these
nf 5 nf 2
Ans. 1
n KMnO4 5 n H 2O2 2
Sol. with ammonia, octet of B will be completed and
10 5.6 100 now there will be no backbonding resulting in
M 5 2
1000 11.2 1000 the increase in bond length.
38. Select the correct order of solubility in H2O . 41. Which of the following compound give positive
(1) o-nitrophenol > p-nitrophenol test in Lassaigne’s test for detection of nitrogen
(2) CH3COONa CH3COOCH3 (1) NH2 NH2 (2) NH2OH
(3) N(CH3 )3 CH3 NH CH2 CH3 (3) CH3 NH2 (4) All of above
(4) CdS ZnS Ans. 3
Ans. 2 Sol. Lassaigne’s test is given by compounds
Sol. 1- Ortho nitro phenol will be less soluble due to containing Nitrogen along with carbon.
intra molecular hydrogen bond Hydrazine and hydroxyl amine don’t contain
2- CH3COONa is ionic in nature where as carbon and hence can’t be detected by
Lassaigne’s test
CH3COOCH3 is covalent hence order of
solubility CH3COONa CH3COOCH3 42. The electronic configuration of four elements are
3- secondary amine will be more soluble in water
(1) [Xe]6s1 (2) [Xe]4f 14 ,5d1 ,6s 2
due formation if more hydrogen bonds than
tertiary amine 4- CdS in precipetated in second (3) [Ar]4s 2 4p 5 (4) [Ar]3d 7 , 4s 2 Which
group and ZnS in fourth group, we know that one of the following statements about these
fourth group sulphides are more soluble than elements is not correct
second group sulphides (1) 1 is strong reducing agent
(2) 2 is a d-block element
39. A zero order reaction : X Y . At the end of 50 (3) 3 has high electron affinity
min, X is 75% reacted. How much of it will be (4) The compound formed betwteen 1 and 3 is
left unreacted at the end of 2 hour. ionic
(1) 6.25 % (2) 12.5 % (3) 3.12 % (4) 0 % Ans. 2
Ans. 4 Sol. [Xe]4f 14 ,5d1 ,6s 2 -It is belong to f-block- Lu
Sol. For zero order : [A]0 [A]t Kt element
[A]0
[A]0 K(50)
4 43. ZnCl2 reacts with excess of NH3 solution to
3[A]0 produce.
K
200 (1) A ppt of Zn(OH)2
[A]0 [A]0 200 200
t100% min after 120 (2) A complex ion Zn(OH 3 ) 4 2 of tetrahedral
K 3[A]0 3
geometry
minute , % X will be unreacted = 0
(3) A complex ion Zn(NH 3 ) 4 2 of tetrahedral
geomtry
(4) A complex ion Zn(NH 3 ) 4 2 of square planar
geometry
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JMTS 24 - 25 (FST-01) (09-Dec-24) 9
Ans. 3
Sol. ZnCl2 NH3 [Zn(NH3 ) 4 ]2 Cl2
[Zn(NH 3 ) 4 ]2 is sp 3 hybridised
(Soluble complex)
Ans. 4
44. The noble gas that does NOT occur in the
atmosphere is :
48. Write the sum of (x + y) is :
(1) Ne (2) Kr (3) He (4) Ra
Ans. 4
Sol. Radon is not present in atmosphere.
products are :
(1)
(2) Ans. 12
Sol. x = 6
(3) y=6
y
then =1
(4) x
Ans. 4
49. If Hund’s rule is not followed then how many of
(Section-2)
them are diamagnetic?
This section contains 10 questions numbered 46 to
50. The answer of each question is a numeric O 2 , N 2 , B2 ,O 2 , F2 ,C 2 , N 2 ,C 22 , F2
value/Integer type. Ans. 6
46. The progress of reaction : Sol. If Hunds rule is not followed then diamagnetic
A(g) xB(g) yC(g) with time is presented in species are
O 2 , N 2 , B2 , F2 ,C 2 ,C 22
figure. What is the value of K oc at 300 K.
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JMTS 24 - 25 (FST-01) (09-Dec-24) 10
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JMTS 24 - 25 (FST-01) (09-Dec-24) 11
60. Let 1 1
Put x dx 2 dt
e
x2 x x2 x
(4x 4x 5x 1)dx e
3 2
f (x) c. t t
1
Then f (1) is tan 1
0 1
t 1 dt cot t dt I
(1) 2 (2) 3 (3) 4 (4) 5 1 t2
(1 t) 2
Ans. 4
1 0
t
e (4x 4x 5x 1)dx
x2 x 3 2
Sol.
1
e (2x 1)(2x x) (4x 1) dx
x x
2
2
2I
2 0 (1 t) 2
dt I
4
2.99.100
?Sum 2 4 ........ 2.99 9900
2
tan 1 x
62. The value of the integral
0
x 2 1 2x
dx is
AB OB r 2
3
(1) (2) (3) (4)
2 8 4 4
Ans. 3
tan 1 x
Sol. I
0
(x 1) 2
dx
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JMTS 24 - 25 (FST-01) (09-Dec-24) 12
x
tf (t) 1 2 20
x x 2 x 3 ........x 20 1 1 2 .....1 20
65. Let f 2 (x) 1 t
0
2
dt x R where f is a
x x x
1 2 20
continuous function on R, not identically zero ? A x 210 1 1 2 .....1 20
and satisfying f(0) = 0, then the value of x x x
(1) 1 (2) 2 (3) 3 (4) 4 68. If the least area bounded by the curves
Ans. 1
x y x 2 4 and y x 12 is equal to , then
tf (t)
Sol. f (x) 1 t
2
2
0 3 represents a three digit integer whose
xf (x) digit at ten's place is
2f (x)f (x) ;f (x) 0 (not possible)
1 x2 (1) 4 (2) 5 (3) 6 (4) 2
x 1 Ans. 3
f (x) f (x) log(1 x 2 ) C Sol. For least area, 0
2(1 x )
2
4
4
f (0) 0 C 0
A min 2 12 x 2 4 dx
256
3
1 0
f (x) log(1 x 2 )
4 3 265 6
f e4 1 1 69. If the curve y ax 3 bx 2 cx 5 touches x
axis at P(2, 0) and cuts y axis at point Q where
66. A bag contain 5 balls of unknown colors. A ball
is drawn at random from it and is found to be its gradient is 3. Find c 2b a.
white. The probability that bag contains only (1) 1 (2) 0 (3) 2 (4) -1
white balls is Ans. 1
3 1 2 1 Sol. We can conclude
(1) (2) (3) (4) 8a 4b 2c 5 0
5 5 3 3
Ans. 4 12a 4b c 0
c3
Sol. Let i (i 1, 2,3, 4,5) denotes 1, 2, 3, 4, 5 white
1 3
in bag a b c3
2 4
i
P / i , (i 1, 2, 3, 4, 5) 3 1
5 c 2b a 3 1
2 2
1
P i , (i 1, 2, 3, 4, 5)
5
70. The function
P( ) P( / 5 )
Now, P / 5 5 5 x
f (x) e x 1 sin x(x 1)(x 2)(x 3) is
P(i )P( / i )
i 1
2
not differentiable at x
1 (1) {0, 1, 2, 3} (2) {1, 2, 3}
*1
5 1 (3) {0, 2, 3} (4) {1, 3}
11 2 3 4 5 3 Ans. 4
5 5 5 5 5 5 Sol. x x is differentiable at x = 0, hence 1, 3 are
points of non differentiability.
67. The coefficient of x 210 in the expression (Section-2)
(x 1)(x 2 2)(x 3 3)..........(x 20 20) is This section contains 10 questions numbered 71 to
(1) 11 (2) 111 (3) 1 (4) 0 75. The answer of each question is a numeric
Ans. 3 value/Integer type.
Sol. Let A (x 1)(x 2 2)........(x 20 20)
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JMTS 24 - 25 (FST-01) (09-Dec-24) 13
71. In a hurdle race, a runner has probability p of
jumping over a specific hurdle. Given that in 5
trials, the runner succeeded 3 times, the
conditional probability that the runner had
succeeded in the first trial is ____.
Ans. 0.6
*******
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