H$moS> Z§.

Code No. 56/2/3

amob Z§. narjmWu H$moS >H$mo CÎma-nwpñVH$m Ho$ _wI-n¥ð
Roll No. >na Adí` {bIo§ &
Candidates must write the Code on the
title page of the answer-book.

ZmoQ> NOTE
(I) H¥$n`m Om±M H$a b| {H$ Bg àíZ-nÌ _o§ _w{ÐV (I) Please check that this question
n¥ð> 19 h¢ & paper contains 19 printed pages.

(II) àíZ-nÌ _| Xm{hZo hmW H$s Amoa {XE JE H$moS (II) Code number given on the right
>Zå~a H$mo N>mÌ CÎma-nwpñVH$m Ho$ _wI-n¥ð> na hand side of the question paper
{bI| & should be written on the title page of
the answer-book by the candidate.
(III) H¥$n`m Om±M H$a b| {H$ Bg àíZ-nÌ _| (III) Please check that this question
>37 àíZ h¢ & paper contains 37 questions.
(IV) H¥$n`m àíZ H$m CÎma {bIZm ewê$ H$aZo go (IV) Please write down the Serial
nhbo, CÎma-nwpñVH$m _| àíZ H$m H«$_m§H$ Number of the question in the
Adí` {bI| & answer-book before attempting it.
(V) Bg àíZ-nÌ H$mo n‹T>Zo Ho$ {bE 15 {_ZQ >H$m (V) 15 minute time has been allotted to
g_` {X`m J`m h¡ & àíZ-nÌ H$m {dVaU read this question paper. The
nydm©• _| 10.15 ~Oo {H$`m OmEJm & question paper will be distributed
10.15 ~Oo go 10.30 ~Oo VH$ N>mÌ Ho$db at 10.15 a.m. From 10.15 a.m. to
10.30 a.m., the students will
àíZ-nÌ H$mo n‹T>|Jo Am¡a Bg Ad{Y Ho$ Xm¡amZ read the question paper only and
do CÎma-nwpñVH$m na H$moB© CÎma Zht {bI|Jo & will not write any answer on the
answer-book during this period.

agm`Z {dkmZ (g¡ÕmpÝVH$)

CHEMISTRY (Theory)

{ZYm©[aV g_` : 3 KÊQ>o A{YH$V_ A§H$ : 70

Time allowed : 3 hours Maximum Marks : 70

.56/2/3 1 P.T.O.
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gm_mÝ` {ZX}e :
{ZåZ{b{IV {ZX}em| H$mo ~hþV gmdYmZr go n{‹T>E Am¡a CZH$m g™Vr go nmbZ H$s{OE :
(i) `h àíZ-nÌ Mma IÊS>m| _| {d^m{OV {H$`m J`m h¡ – H$, I, J Ed§ K & Bg àíZ-nÌ _|
37 àíZ h¢ & g^r àíZ A{Zdm`© h¢ &
(ii) IÊS> H$ _| àíZ g§»`m 1 go 20 VH$ A{V bKw-CÎmar` àH$ma Ho$ àíZ h¢, àË`oH$ àíZ 1 A§H$ H$m
h¡ & àË`oH$ àíZ H$m CÎma EH$ eãX `m EH$ dmŠ` _| Xr{OE &
(iii) IÊS> I _| àíZ g§»`m 21 go 27 VH$ bKw-CÎmar` àH$ma Ho$ àíZ h¢, àË`oH$ àíZ 2 A§H$m| H$m
h¡ &
(iv) IÊS> J _| àíZ g§»`m 28 go 34 VH$ XrK©-CÎmar` àH$ma-I Ho$ àíZ h¢, àË`oH$ àíZ 3 A§H$m| H$m
h¡ &
(v) IÊS> K _| àíZ g§»`m 35 go 37 VH$ XrK©-CÎmar` àH$ma-II Ho$ àíZ h¢, àË`oH$ àíZ 5 A§H$m| H$m
h¡ &
(vi) àíZ-nÌ _| H$moB© g_J« {dH$ën Zht h¡ & VWm{n, Xmo-Xmo A§H$m| Ho$ Xmo àíZm| _|, VrZ-VrZ A§H$m| Hoo$
Xmo àíZm| _| VWm nm±M-nm±M A§H$m| Ho$ VrZm| àíZm| _| AmÝV[aH$ {dH$ën {X`m J`m h¡ & Eogo àíZm| _|
go Ho$db EH$ hr {dH$ën H$m CÎma Xr{OE &
(vii) BgHo$ A{V[aº$, Amdí`H$VmZwgma, àË`oH$ IÊS> Am¡a àíZ Ho$ gmW `Wmo{MV {ZX}e {XE JE h¢ &
(viii) Ho$ëHw$boQ>a AWdm bm°J Q>o~b Ho$ à`moJ H$s AZw_{V Zht h¡ &
IÊS> H$
{XE JE AZwÀN>oX H$mo n{‹T>E VWm àíZ g§»`m 1 go 5 Ho$ CÎma Xr{OE : 15=5
à~b àH$ma Ho$ ¶m¡{JH$ O¡go Eo‘rZmo Aåb, hm°‘m}Z, V§{ÌH$m-g§MmaH$, S>r.EZ.E., EoëHo$bm°BS>,
a§OH$ Am{X ‘| Eo‘rZ A{^bjH$s` g‘yh dmbo H$m~©{ZH$ ¶m¡{JH$ CnpñWV hmoVo h¢ & Am¡fY
{OZH$m ‘mZdm| na eara{H«$¶mË‘H$ à^md hmoVm h¡ O¡go {ZH$moQ>rZ, ‘m°’$s©Z, H$moS>rZ Ed§ hramoBZ,
Am{X ‘| ^r Eo‘rZmo g‘yh {H$gr Z {H$gr ê$n ‘| hmoVm h¡ & ZmBQ´>moOZ na EH$mH$s Bbo³Q´>m°Z ¶w½‘
H$s CnpñW{V Ho$ H$maU Eo‘rZ jmaH$s¶ hmoVo h¢ & H$m~©{ZH$ T>m±Mo ‘| ZmBQ´>moOZ H$m ¶moJ Eo‘rZ Am¡a
Eo‘mBS> AUwAm| Ho$ Xmo dJm] H$m {Z‘m©U H$aVm h¡ & agm¶Z {dkmZ Ho$ N>mÌ hmoZo Ho$ ZmVo, h‘|
ZmBQ´>moOZ H$s gd©Vmo‘wIr àH¥${V H$s gamhZm H$aZr Mm{hE &
1. O~ EH$ Eo‘rZmo Aåb H$m H$m~m}p³gb {gam Xÿgao Eo‘rZmo Aåb Ho$ Eo‘rZmo {gao Ho$ gmW
g§K{ZV hmoVm h¡ Vmo ~ZZo dmbo Am~ÝY H$m Zm‘ {b{IE &
2. Amdí¶H$ Eo‘rZmo Aåb ³¶m h¢ ?
3. Eo_rZmo Aåb Š`m h¢ ?
4. Eo‘rZmo Aåb C^¶Y‘u ³¶m| hmoVo h¢ ?
5. Aåbr¶ Am¡a jmaH$s¶ Eo‘rZmo Aåb ‘| EH$ A§Va Xr{OE &
.56/2/3 2
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General Instructions :
Read the following instructions very carefully and strictly follow them :
(i) This question paper comprises four Sections – A, B, C and D. There are
37 questions in the question paper. All questions are compulsory.
(ii) Section A – Questions no. 1 to 20 are very short answer type questions,
carrying 1 mark each. Answer these questions in one word or one sentence.
(iii) Section B – Questions no. 21 to 27 are short answer type questions, carrying
2 marks each.
(iv) Section C – Questions no. 28 to 34 are long answer type-I questions, carrying
3 marks each.
(v) Section D – Questions no. 35 to 37 are long answer type-II questions, carrying
5 marks each.
(vi) There is no overall choice in the question paper. However, an internal choice
has been provided in 2 questions of two marks, 2 questions of three marks and
all the 3 questions of five marks. You have to attempt only one of the choices in
such questions.
(vii) In addition to this, separate instructions are given with each section and
question, wherever necessary.
(viii) Use of calculators and log tables is not permitted.
SECTION A
Read the given passage and answer the questions number 1 to 5 that follow : 15=5
Organic compounds containing amine as functional group are present in
a vivid variety of compounds, namely amino acids, hormones,
neurotransmitters, DNA, alkaloids, dyes, etc. Drugs including nicotine,
morphine, codeine and heroin, etc. which have physiological effects on
humans also contain amino group in one form or another. Amines are
basic because of the presence of lone pair of electrons on nitrogen.
Addition of nitrogen into an organic framework leads to the formation of
two families of molecules, namely amines and amides. As chemistry
students, we must appreciate the versatility of nitrogen.
1. Name the linkage formed when carboxyl end of one amino acid condenses
with amino end of other amino acid.
2. What are essential amino acids ?
3. What are amino acids ?
4. Why are amino acids amphoteric ?
5. Give one point of difference between acidic and basic amino acid.
.56/2/3 3 P.T.O.
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àíZ g§»`m 6 go 10 EH$ eãX CÎmar¶ h¢ : 15=5
6. A¶ñH$m| Ho$ gÁOrH$aU Ho$ {bE à¶w³V Cg àH«$‘ H$m Zm‘ {b{IE Omo A¶ñH$ VWm J¢J
H$Um| Ho$ Amno{jH$ KZËd Ho$ A§Va na AmYm[aV h¡ &
7. g§Hw$b [Co(NH3)5 NO2]Cl2 Ûmam {H$g àH$ma H$s g‘md¶dVm Xem©B© OmVr h¡ ?
8. H$moB© H$m~©{ZH$ ¶m¡{JH$ {g{bH$m Oob H$s gVh na A{Yemo{fV h¡ & H$m~©{ZH$ ¶m¡{JH$ H$mo
{g{bH$m Oob go hQ>mZo Ho$ àH«$‘ H$m Zm‘ {b{IE &
9. {H$gr EH$ YmVw H$m CXmhaU Xr{OE {OgH$m emoYZ AmgdZ {d{Y Ûmam {H$¶m Om gHo$ &
10. Cg A{^{H«$¶m H$s Hw$b H$mo{Q> H$m n[aH$bZ H$s{OE {OgH$m doJ {Z¶‘ {ZåZ àH$ma {X¶m J`m
h¡ :
doJ = k[SO2]1/4 [O2]3/4 .
àíZ g§»`m 11 go 15 ~hþ{dH$ënr¶ àíZ h¢ : 15=5

11. A§VamH$mer ¶m¡{JH$m| Ho$ {df¶ ‘| µJbV H$WZ h¡

(A) do amgm¶{ZH$ Ñ{îQ> go A{^{H«$¶merb h¢ &
(B) do A˶ÝV H$R>moa h¢ &
(C) do YmpËdH$ MmbH$Vm ~ZmE aIVo h¢ &
(D) CZHo$ JbZm§H$ CÀM hmoVo h¢ &

12.

(A) tert-ã¶y{Q>b EoëH$mohm°b

(B) 2,2-S>mB‘o{WbàmonoZm°b
(C) 2-‘o{Wbã¶yQ>oZ-2-Am°b
(D) 3-‘o{Wbã¶yQ>oZ-3-Am°b
13. ½byH$mog C6H12O6 (‘moba Ð춑mZ : 180 g/‘mob) Ho$ 50 mL Obr¶ {db¶Z ‘|
6·02  1022 AUw CnpñWV h¢ & {db¶Z H$s gm§ÐVm hmoJr
(A) 0·1 M
(B) 0·2 M
(C) 1·0 M
(D) 2·0 M

.56/2/3 4
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Questions number 6 to 10 are one word answers : 15=5
6. Name the process used for the benefaction of ores which is based on the
difference in the gravities of ore and the gangue particles.
7. What type of isomerism is shown by the complex [Co(NH3)5 NO2] Cl2 ?
8. An organic compound is adsorbed on the surface of silica gel. Name the
process of removing the organic compound from silica gel.
9. Give an example of a metal which can be purified by the process of
distillation.

10. Calculate the overall order of the reaction whose rate law is given by
Rate = k[SO2]1/4 [O2]3/4.

Questions number 11 to 15 are multiple choice questions : 15=5

11. The incorrect statement about interstitial compounds is

(A) They are chemically reactive.
(B) They are very hard.
(C) They retain metallic conductivity.
(D) They have high melting point.

12.

(A) tert-butyl alcohol

(B) 2,2-Dimethylpropanol
(C) 2-Methylbutan-2-ol
(D) 3-Methylbutan-3-ol
13. 50 mL of an aqueous solution of glucose C6H12O6 (Molar mass :
180 g/mol) contains 6·02  1022 molecules. The concentration of the
solution will be
(A) 0·1 M
(B) 0·2 M
(C) 1·0 M
(D) 2·0 M

.56/2/3 5 P.T.O.
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14. Cr3+ (na‘mUw H«$‘m§H$ = 24) ‘| CnpñWV Hw$b A¶wp½‘V Bbo³Q´>m°Zm| H$s g§»¶m h¡
(A) 2
(B) 7
(C) 3
(D) 5

15. ¶{X {H$gr Bbo³Q´>moS> H$m ‘mZH$ Bbo³Q´>moS> {d^d eyݶ go A{YH$ hmo, Vmo h‘ {ZîH$f© {ZH$mb
gH$Vo h¢ {H$ BgH$m
(A) AnM{¶V ê$n hmBS´>moOZ J¡g H$s VwbZm ‘| A{YH$ ñWm¶r h¡ &
(B) Am°³grH¥$V ê$n hmBS´>moOZ J¡g H$s VwbZm ‘| A{YH$ ñWm¶r h¡ &
(C) AnM{¶V Am¡a Am°³grH¥$V ê$n g‘mZ ê$n go ñWm¶r h¢ &
(D) AnM{¶V ê$n hmBS´>moOZ J¡g go H$‘ ñWm¶r h¡ &

àíZ g§»`m 16 go 20 Ho$ {bE, Xmo H$WZ {XE JE h¢ {OZ_| EH$ H$mo A{^H$WZ (A) VWm Xÿgao
H$mo H$maU (R) Ûmam A§{H$V {H$`m J`m h¡ & BZ àíZm| Ho$ ghr CÎma ZrMo {XE JE H$moS>m| (i),
(ii), (iii) Am¡a (iv) _| go MwZH$a Xr{OE : 15=5

(i) A{^H$WZ (A) Am¡a H$maU (R) XmoZm| ghr H$WZ h¢ Am¡a H$maU (R), A{^H$WZ (A)
H$s ghr ì¶m»¶m h¡ &
(ii) A{^H$WZ (A) Am¡a H$maU (R) XmoZm| ghr H$WZ h¢, naÝVw H$maU (R),
A{^H$WZ (A) H$s ghr ì¶m»¶m Zht h¡ &
(iii) A{^H$WZ (A) ghr h¡, naÝVw H$maU (R) µJbV H$WZ h¡ &
(iv) A{^H$WZ (A) µJbV h¡, naÝVw H$maU (R) ghr H$WZ h¡ &

16. A{^H$WZ (A) : p-ZmBQ´>moµ\$sZm°b H$s Anojm o-ZmBQ´>moµ\$sZm°b Xþ~©b Aåb h¡ &
H$maU (R) : Am§VaAmpÊdH$ (A§V:AUwH$) hmBS´>moOZ Am~ÝY Am°Wm} g‘md¶d H$mo n¡am
g‘md¶d H$s Anojm Xþ~©b H$a XoVm h¡ &
17. A{^H$WZ (A) : Eoë~y{‘Z EH$ Jmo{bH$mH$ma àmoQ>rZ h¡ &
H$maU (R) : nm°{bnoßQ>mBS> H$s ûm¥§Ibm Hw§$S>br ~ZmH$a EH$ grYr ûm¥§Ibm ~Zm XoVr h¡ &

18. A{^H$WZ (A) : ~¡Ho$bmBQ> VmnÑ‹T> ~hþbH$ h¡ &

H$maU (R) : Ja‘ H$aZo na, ~hþbH$s¶ ûm§¥Ibm bå~r Am¡a grYr ûm§¥Ibm ~Z OmVr h¡ &

.56/2/3 6
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14. Total number of unpaired electrons present in Cr3+ (Atomic number = 24)
is
(A) 2
(B) 7
(C) 3
(D) 5

15. If the standard electrode potential of an electrode is greater than zero,

then we can infer that its
(A) reduced form is more stable compared to hydrogen gas.
(B) oxidised form is more stable compared to hydrogen gas.
(C) reduced and oxidised forms are equally stable.
(D) reduced form is less stable than the hydrogen gas.

For questions number 16 to 20, two statements are given  one labelled
Assertion (A) and the other labelled Reason (R). Select the correct
answer to these questions from the codes (i), (ii), (iii) and (iv) as given
below : 15=5

(i) Both assertion (A) and reason (R) are correct statements, and
reason (R) is the correct explanation of the assertion (A).

(ii) Both assertion (A) and reason (R) are correct statements, but
reason (R) is not the correct explanation of the assertion (A).
(iii) Assertion (A) is correct, but reason (R) is incorrect statement.

(iv) Assertion (A) is incorrect, but reason (R) is correct statement.

16. Assertion (A) : o-nitrophenol is a weaker acid than p-nitrophenol.

Reason (R) : Intramolecular hydrogen bonding makes ortho isomer
weaker than para isomer.

17. Assertion (A) : Albumin is a globular protein.

Reason (R) : Polypeptide chain coils around to give a straight chain.

18. Assertion (A) : Bakelite is a thermosetting polymer.

Reason (R) : On heating, polymeric chain becomes a long and straight
chain.
.56/2/3 7 P.T.O.
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19. A{^H$WZ (A) : {ZåZ àMH«$U MVwî’$bH$s¶ g§Hw$b {dabo hr XoIo OmVo h¢ &
H$maU (R) : H$jH$m| H$s {dnmQ>Z D$Om©E± BVZr A{YH$ Zht hmoVr h¢ Omo ¶w½‘Z Ho$ {bE
~mܶ H$a| &
20. A{^H$WZ (A) : EopëH$b h¡bmBS>m| Ho$ ³dWZm§H$ {ZåZ H«$‘ ‘| KQ>Vo h¢ :
R-I > R-Br > R-Cl > R-F
H$maU (R) : h¡bmoOZ na‘mUw Ho$ AmH$ma ‘| d¥{Õ Ho$ gmW dmÝS>a dmëg ~b KQ>Vo h¢ &

IÊS> I

21. {ZåZ{b{IV pñW{V¶m| ‘| {dbo¶ H$s AdñWm H$s àmJw{³V H$s{OE : 12=2
(a) àm¶mo{JH$ Vm¡a na kmV {H$¶m J¶m ‘moba Ð춑mZ dmñV{dH$ ‘mZ go A{YH$ hmoVm h¡ &
(b) ‘i’ H$m ‘mZ 0·4 hmo &

22. {H$gr {dÚwV²-amgm¶{ZH$ gob

–
F2 (g) + 2I (aq)  2F – (aq) + I2 (s)

Ho$ {bE gob {Zê$nU Xr{OE & 25C na Cn`w©³V gob Ho$ {bE ZoÝñQ>© g‘rH$aU ^r
{b{IE & 2

23. {ZåZ{b{IV amgm¶{ZH$ g‘rH$aUm| H$mo nyU© Ed§ gÝVw{bV H$s{OE : 2


(a) MnO  Fe 2   H  
4

(b) MnO  Mn 2   H2O 
4

24. {ZåZ{b{IV Ho$ ‘ܶ EH$-EH$ A§Va Xr{OE : 12=2

(a) àem§VH$ Am¡a nr‹S>mhmar

(b) ny{VamoYr Am¡a {dg§H«$m‘r (amoJmUwZmer)
AWdm
amgm¶{ZH$ g§KQ>Z Ho$ AmYma na YZm¶Zr Am¡a G Um¶Zr An‘mO©H$m| ‘| A§Va ñnîQ> H$s{OE &
à˶oH$ dJ© H$m EH$-EH$ CXmhaU ^r Xr{OE & 2

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19. Assertion (A) : Low spin tetrahedral complexes are rarely observed.
Reason (R) : The orbital splitting energies are not sufficiently large to
forcing pairing.

20. Assertion (A) : Boiling points of alkyl halides decrease in the order
R-I > R-Br > R-Cl > R-F.
Reason (R) : Van der Waals forces decrease with increase in the size of
halogen atom.

SECTION B

21. Predict the state of the solute in the following situations : 12=2
(a) Experimentally determined molar mass is more than the true value.
(b) ‘i’ value is 0·4.

22. For an electrochemical cell

–
F2 (g) + 2I (aq)  2F – (aq) + I2 (s),

give the cell representation. Also write the Nernst equation for the above
cell at 25C. 2

23. Complete and balance the following chemical equations : 2


(a) MnO  Fe 2   H  
4

(b) MnO  Mn 2   H2O 
4

24. Give one point of difference between the following : 12=2

(a) Tranquilizers and Analgesics
(b) Antiseptics and Disinfectants
OR
Differentiate on the basis of chemical composition between cationic and
anionic detergents. Also give one example of each category. 2

.56/2/3 9 P.T.O.
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25. {ZåZ{b{IV Ho$ {bE H$maU Xr{OE : 12=2

(a) EoëH$mohm°b ‘| Am~ÝY H$moU MVwî’$bH$s¶ H$moU go Oam-gm H$‘ hmoVm

h¡ &
(b) CH3OH ‘| C – OH Am~ÝY bå~mB© µ\$sZm°b ‘| C – OH Am~ÝY bå~mB© go
Oam-gr A{YH$ hmoVr h¡ &
26. A{YemofU g‘Vmnr H$s n[a^mfm {b{IE & {H$gr R>mog A{YemofH$ Ho$ BH$mB© Ð춑mZ Ûmam
EH$ {ZpíMV Vmn na A{Yemo{fV J¡g H$s ‘mÌm Ed§ Xm~ Ho$ ‘ܶ EH$ AmZw^{dH$ g§~§Y
Xr{OE & 2
AWdm
AmH$ma-daUmË‘H$ CËàoaU H$mo n[a^m{fV H$s{OE & Cg àH«$‘ H$m Zm‘ {b{IE {OgHo$ Ûmam
EoëH$mohm°bm| H$mo grYo hr J¡gmobrZ ‘| n[ad{V©V H$a {X¶m OmVm h¡ Am¡a {d{^Þ àH$ma Ho$
hmBS´>moH$m~©Z ~ZVo h¢ & 2

27. H$moB© A{^{H«$¶m A{^H$maH$ A Ho$ gmnoj àW‘ H$mo{Q> H$s h¡ Am¡a A{^H$maH$ B Ho$ gmnoj ^r
àW‘ H$mo{Q> H$s h¡ & doJ {Z¶‘ Xr{OE & Am¡gV doJ Am¡a VmËj{UH$ doJ Ho$ ~rM EH$ A§Va
^r Xr{OE & 2

IÊS> J
28. {ZåZ{b{IV ~hþbH$m| Ho$ EH$bH$m| H$s g§aMZmE± Xr{OE : 13=3
(a) àmH¥${VH$ a~a
(b) ã¶yZm-S
(c) ZmodmoboH$
AWdm
{ZåZ{b{IV ~hþbH$m| ‘| EH$bH$m| Ho$ Zm‘ {b{IE : 13=3

.56/2/3 10
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25. Give reasons for the following : 12=2

(a) Bond angle in alcohol is slightly less than the tetrahedral

angle.
(b) C – OH bond length in CH3OH is slightly more than the C – OH
bond length in phenol.

26. Define adsorption isotherm. Give the empirical relationship between the
quantity of gas adsorbed by unit mass of solid absorbent and pressure at
a particular temperature. 2
OR
Define shape-selective catalysis. Name the process by which alcohols
convert directly into gasoline and give a variety of hydrocarbons. 2

27. A reaction is first order w.r.t. reactant A as well as w.r.t. reactant B. Give
the rate law. Also give one point of difference between average rate and
instantaneous rate. 2

SECTION C

28. Give the structures of the monomers of the following polymers : 13=3

(a) Natural rubber

(b) Buna-S

(c) Novolac
OR
Write the names of monomers in the following polymers : 13=3

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29. Mm±Xr Ho$ {ZjmbZ ‘| g§~Õ amgm¶{ZH$ A{^{H«$¶mE± Xr{OE & Bg àH«$‘ ‘| Zn H$s ³¶m
^y{‘H$m h¡ ? 3

30. H$mobamD$e H$m {Z¶‘ {b{IE & Ba(OH)2 H$s ‘moba MmbH$Vm n[aH${bV H$s{OE & Ba2+
Am¡a OH– Am¶Zm| H$s ‘moba Am¶{ZH$ MmbH$Vm H«$‘e… 127 Am¡a 199 S cm2 mol–1 h¡ & 3

31. 600 gOb ‘| 31 g E{WbrZ ½bmBH$m°b (‘moba Ð춑mZ = 62 g mol–1) KmobH$a à{V{h‘
{db¶Z ~Zm¶m J¶m & {db¶Z H$m {h‘m§H$ n[aH${bV H$s{OE & 3
(Ob Ho$ {bE Kf = 1·86 K kg mol–1)

32. {ZåZ{b{IV Ho$ {bE H$maU Xr{OE : 13=3

(a) EWoZo‘rZ H$s VwbZm ‘| Eo{ZbrZ Xþ~©b jma h¡ &
(b) Eo{ZbrZ ’«$sS>ob-H«$mâQ²>g A{^{H«$¶m àX{e©V Zht H$aVr &
(c) J¡{~«Eb W¡{b‘mBS> g§íbofU Ûmam Ho$db Eo{b’¡${Q>H$ àmW{‘H$ Eo‘rZm| H$m {daMZ
{H$¶m Om gH$Vm h¡ &

33. (a) K4[Mn(CN)6] H$m AmB©.¶y.nr.E.gr. Zm‘ VWm t2g Am¡a eg Ho$ nXm| ‘| Ho$ÝÐr¶ YmVw
na‘mUw H$m Bbo³Q´>m°{ZH$ {dݶmg Xr{OE &
(b) ‘H$sboQ> à^md’ go ³¶m A{^àm¶ h¡ ? EH$ CXmhaU Xr{OE & 2+1=3
AWdm
{ZåZ{b{IV g§Hw$bm| Ho$ g§H$aU Ed§ Mwå~H$s¶ ì¶dhma {b{IE : 3

(i) [Fe(CN)6]4–

(ii) [CoF6]3–

(iii) [Ni(CO)4]
[ na_mUw H«$_m§H$ : Fe = 26, Co = 27, Ni = 28]

34. Eo{Wb ³bmoamBS>, AmBgmoàmo{nb ³bmoamBS>, V¥Vr¶H$ ã¶y{Q>b ³bmoamBS> ¶m¡{JH$m| H$mo
{ZåZ{b{IV nyN>r JB© {dñWmnZ H$s A{^{H«$¶merbVm Ho$ Amamohr H«$‘ ‘| ì¶dpñWV H$s{OE
Am¡a H$maU XoH$a AnZo CÎma H$s nw{îQ> H$s{OE : 3
(a) SN1
(b) SN2

.56/2/3 12
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29. Give the chemical reactions involved in the leaching of silver. What is the
role of Zn in this process ? 3

30. State Kohlrausch’s law. Calculate the molar conductance of Ba(OH)2.

–
The molar ionic conductance of Ba2+ and OH ions are 127 and
2 –1
199 S cm mol respectively. 3

31. An antifreeze solution is prepared by dissolving 31 g of ethylene glycol

(Molar mass = 62 g mol–1) in 600 g of water. Calculate the freezing point
of the solution. (Kf for water = 1·86 K kg mol–1) 3

32. Account for the following : 13=3

(a) Aniline is a weaker base compared to ethanamine.
(b) Aniline does not undergo Friedel-Crafts reaction.
(c) Only aliphatic primary amines can be prepared by Gabriel
Phthalimide synthesis.

33. (a) Give the IUPAC name and electronic configuration of central metal
atom in terms of t2g and eg of K4[Mn(CN)6].

(b) What is meant by ‘Chelate effect’ ? Give an example. 2+1=3

OR
Write the hybridisation and magnetic characters of the following
complexes : 3
(i) [Fe(CN)6]4–
(ii) [CoF6]3–
(iii) [Ni(CO)4]
[Atomic number : Fe = 26, Co = 27, Ni = 28]

34. Justify and arrange the following compounds namely, ethyl chloride,
isopropyl chloride, tertiary butyl chloride in increasing order of reactivity
towards the asked displacement namely : 3
(a) SN1
(b) SN2

.56/2/3 13 P.T.O.
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 IÊS> K

35. {H$arQ>mH$ma g§aMZm dmbm H$moB© A{H«$ñQ>br¶ R>mog ‘A’ dm¶w ‘| ObH$a J¡g ‘B’ ~ZmVm h¡ Omo
MyZo Ho$ nmZr H$mo Xÿ{Y¶m H$a XoVr h¡ & gë’$mBS> A¶ñH$m| Ho$ ^O©Z go ^r ‘B’ CËnm{XV hmoVr
h¡ & V2O5 H$s CnpñW{V ‘| ‘B’ Am°³grH¥$V hmoH$a ‘C’ XoVr h¡ VWm ‘C’ H$s CÀM bpãY Ho$
{bE H$‘ Vmn Am¡a CÀM Xm~ Cn¶w³V pñW{V¶m± h¢ & ‘C’, H2SO4 ‘| Ademo{fV hmoH$a ‘D’
XoVr h¡ & VËníMmV² ‘D’ H$m VZwH$aU H$aZo na A˶{YH$ ‘hÎdnyU© ¶m¡{JH$ ‘E’ àmßV hmoVm h¡ &
CÚmoJ ‘| ‘E’ {d{^Þ ¶m¡{JH$m| Ho$ {Z‘m©U Ho$ {bE ì`mnH$ ê$n go CÎmaXm¶r h¡ & ‘E’ gmÝÐ
AdñWm ‘| Cu YmVw go A{^{H«$¶m H$aHo$ ¶m¡{JH$ ‘F’ XoVm h¡ & Bg dU©Z go
1
(a) ‘A’ go ‘F’ H$s g§aMZmE± ñnîQ> H$s{OE & 6=3
2

(b) ‘E’ Ho$ ‘F’ ‘|n[adV©Z Ho$ {bE g§Vw{bV amgm¶{ZH$ g‘rH$aU {b{IE & 1
(c) ‘E’ Ho$ CZ Xmo ‘hÎdnyU© H$m¶m] H$mo {b{IE {OZH$s amgm¶{ZH$ CÚmoJ ‘| ^y{‘H$m hmoVr
1
h¡ & 2=1
2
AWdm
(a) {ZåZ{b{IV àojUm| Ho$ {bE H$maU Xr{OE : 13=3
(i) h¡bmoOZ à~b Am°³grH$maH$ h¢ &
(ii) CËH¥$îQ> J¡gm| Ho$ ³dWZm§H$ A˶{YH$ {ZåZ hmoVo h¢ &
(iii) O Am¡a Cl H$s {dÚwV²-G$UmË‘H$Vm bJ^J EH$ g‘mZ hmoVr h¡ {’$a ^r
Am°³grOZ H Am~ÝY ~ZmVm h¡ O~{H$ Cl Zht &
(b) {ZåZ{b{IV amgm¶{ZH$ g‘rH$aUm| H$mo nyU© Ed§ gÝVw{bV H$s{OE : 12=2
(i) NaOH + Cl2 
(R>§S>m VWm VZw)
(ii) I– (aq) + H2O (l) + O3 (g) 

36. (a) EH$ H$m~©{ZH$ ¶m¡{JH$ ‘A’ {OgH$m AmpÊdH$ gyÌ C5H10O h¡, G$UmË‘H$
Q>m°boÝg narjU XoVm h¡, ³br‘oÝgZ AnM¶Z go n-noÝQ>oZ ~ZmVm h¡ naÝVw Am¶moS>mo’$m°‘©
narjU Zht XoVm & ‘A’ H$s nhMmZ H$s{OE VWm g^r gå~Õ A{^{H«$¶mE±
Xr{OE & 1+1=2

.56/2/3 14
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 SECTION D

35. An amorphous solid ‘A’ which has a crown shaped structure, burns in air
to form a gas ‘B’ which turns lime water milky. ‘B’ is also produced by
roasting of sulphide ores. ‘B’ undergoes oxidation in the presence of V 2O5
to give ‘C’ and to carry out this oxidation low temperature and high
pressure is mandatory to get a good yield of ‘C’. ‘C’ is then absorbed in
H2SO4 to give ‘D’. ‘D’ is then diluted to give a very important compound
‘E’. ‘E’ is largely responsible for the manufacture of variety of compounds
in industry. ‘E’ in concentrated form, when combined with Cu metal,
gives compound ‘F’.
From this description
1
(a) Elucidate the structure of ‘A’ to ‘F’. 6=3
2
(b) Give a balanced chemical equation for the conversion of ‘E’ to ‘F’. 1
1
(c) Give two important functions of ‘E’ in the chemical industry. 2=1
2
OR

(a) Give reasons for the following observations : 13=3

(i) Halogens are strong oxidising agents.

(ii) Noble gases have very low boiling points.

(iii) O and Cl have nearly same electronegativity, yet oxygen

forms H bond while Cl doesn’t.

(b) Complete and balance the following chemical equations : 12=2

(i) NaOH + Cl2 
(cold + dil.)
–
(ii) I (aq) + H2O (l) + O3 (g) 

36. (a) An organic compound ‘A’ having molecular formula C5H10O gives
negative Tollens’ test, forms n-pentane on Clemmensen reduction
but doesn’t give iodoform test. Identify ‘A’ and give all the
reactions involved. 1+1=2

.56/2/3 15 P.T.O.
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 (b) {ZåZ{b{IV ê$nmÝVaU gånÞ H$s{OE : 12=2
(i) àmonoZm°BH$ Aåb go 2-~«mo‘moàmonoZm°BH$ Aåb
(ii) ~oݵOm°¶b ³bmoamBS> go ~oݵOp¡ ëS>hmBS>
(c) Amn ~oݵO¡pëS>hmBS> Am¡a EogrQ>¡pëS>hmBS> Ho$ ~rM H¡$go {d^oX H$a|Jo ? 1
AWdm
(a) {ZåZ{b{IV A{^{H«$¶mAm| Ho$ AZwH«$‘ H$mo nyU© H$s{OE :

1
(i) (A) go (D) H$s nhMmZ H$s{OE & 4=2
2
(ii) (A) H$m AmB©.¶y.nr.E.gr. Zm‘ {b{IE & 1

(b) Amn (i) EWoZm°b Am¡a àmonoZmoZ, VWm (ii) ~oݵOm°BH$ Aåb Am¡a µ\$sZm°b Ho$ ~rM H¡$go
{d^oX H$a|Jo ? 2

37. (a) {H$gr A{^{H«$¶m R  P Ho$ {bE {dem Zo R H$s gmÝÐVm Ed§ g‘¶ Ho$ ‘ܶ EH$
J«m’$ ItMm & Bg J«m’$ Ho$ AmYma na {ZåZ{b{IV àíZm| Ho$ CÎma Xr{OE :

(i) A{^{H«$¶m H$s H$mo{Q> H$s àmJw{³V H$s{OE &

(ii) dH«$ H$m T>mb ³¶m B§{JV H$aVm h¡ ?
(iii) doJ pñWam§H$ H$s BH$mB© ³¶m h¡ ? 13=3

.56/2/3 16
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 (b) Carry out the following conversions : 12=2
(i) Propanoic acid to 2-Bromopropanoic acid
(ii) Benzoyl chloride to benzaldehyde
(c) How will you distinguish between benzaldehyde and
acetaldehyde ? 1
OR

(a) Complete the following sequence of reactions :

1
(i) Identify (A) to (D). 4=2
2
(ii) Give the IUPAC name of (A). 1

(b) How can you distinguish between : 2

(i) Ethanol and Propanone, and
(ii) Benzoic acid and Phenol ?

37. (a) Visha plotted a graph between concentration of R and time for a
reaction R  P. On the basis of this graph, answer the following
questions :

(i) Predict the order of reaction.

(ii) What does the slope of the line indicate ?
(iii) What are the units of rate constant ? 13=3
.56/2/3 17 P.T.O.
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 (b) EH$ àW‘ H$mo{Q> H$s A{^{H«$¶m ‘| 25% {d¶moOZ hmoZo ‘| 25 {‘ZQ> bJVo h¢ &
t1/2 H$s JUZm H$s{OE & 2

[{X`m J`m h¡ : log 2 = 0·3010, log 3 = 0·4771, log 4 = 0·6021]

AWdm

(a) {H$gr àW‘ H$mo{Q> H$s A{^{H«$¶m Ho$ {bE doJ pñWam§H$ 60 s–1 h¡ & A{^H$maH$ H$mo
1
AnZr àmapå^H$ gmÝÐVm go KQ> H$a dm± ^mJ ah OmZo ‘| {H$VZm g‘¶ bJoJm ? 3
16

(b) {H$gr amgm`{ZH$ A{^{H«$¶m Ho$ doJ H$mo à^m{dV H$aZo dmbo Xmo H$maH$m| H$mo {b{IE & 1

(c) g§KÅ>m| Ho$ à^mdr g§KÅ>> hmoZo Ho$ {bE Xmo n[apñW{V¶m± {b{IE & 1

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 (b) A first order reaction takes 25 minutes for 25% decomposition.
Calculate t1/2. 2
[Given : log 2 = 0·3010, log 3 = 0·4771, log 4 = 0·6021]

OR

(a) The rate constant for a first order reaction is 60 s–1. How much
time will it take to reduce the initial concentration of the reactant
1 th
to its value ? 3
16

(b) Write two factors that affect the rate of a chemical reaction. 1

(c) Write two conditions for the collisions to be effective collisions. 1

.56/2/3 19 P.T.O.
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