27th JANUARY 2024 SHIFT-I (MATHEMATICS)

1. If (a, b) be the orthocentre of the triangle whose vertices are (1, 2), (2, 3) and (3, 1),
b b I1
and I1 = ∫a xsin⁡(4x − x 2 )dx, I2 = ∫a sin⁡(4x − x 2 )dx, then 36 is equal to:
I2

(A) 80 (B) 88 (C) 66 (D) 72

2. If S = {z ∈ C: |z − i| = |z + i| = |z − 1|}, then, n(S) is:
(A) 3 (B) 0 (C) 2 (D) 1
3. Let S = {1, 2, 3, … , 10}. Suppose M is the set of all the subsets of S, then the relation
R = {(A, B): A ∩ B ≠ ϕ; A, B ∈ M} is:
(A) symmetric and reflexive only (B) symmetric and transitive only
(C) reflexive only (D) symmetric only
dx
4. Let x = x(t) and y = y(t) be solutions of the differential equations + ax = 0 and
dt
dy
+ by = 0 respectively, a, b ∈ R. Given that x(0) = 2; y(0) = 1 and 3y(1) =
dt

2x(1, the value of t, for which x(t) = y(t), is:

(A) log 2 2 (B) log 4 3 (C) log 4 2 (D) log 3 4
3 3

5. Let a1 , a2 , … a10 be 10 observations such that ∑10

k=1 ak = 50 and ∑∀k<j ak ⋅ aj =

1100. Then the standard deviation of a1 , a2 , … , a10 is equal to:

(A) 10 (B) √115 (C) √5 (D) 5

6. Four distinct points (2k, 3k), (1, 0), (0, 1) and (0, 0) lie on a circle for k equal to:
3 1 2 5
(A) (B) (C) (D)
13 13 13 13

7. Let a⃗ = î + 2ĵ + k̂, ⃗b = 3(î − ĵ + k̂). Let c be the vector such that a⃗ × c = ⃗b and a⃗ ⋅

c = 3. Then a⃗ ⋅ ((c × ⃗b) − ⃗b − c) is equal to:

(A) 20 (B) 36 (C) 24 (D) 32
8. The function f: N − {1} → N; defined by f(n) = the highest prime factor of n, is:
(A) one-one only (B) onto only
(C) both one-one and onto (D) neither one-one nor onto

1
 cos⁡x −sin⁡x 0
9. Consider the matrix f(x) = [ sin⁡x cos⁡x 0].
0 0 1
Given below are two statements:
Statement I: f(−x) is the inverse of the matrix f(x).
Statement II: f(x)f(y) = f(x + y).
In the light of the above statements, choose the correct answer from the options given
below
(A) Statement I is true but Statement II is false
(B) Both Statement I and Statement II are true
(C) Both Statement I and Statement II are false
(D) Statement I is false but Statement II is true
x−6 y−4 z−8
10.The distance, of the point (7, −2, 11) from the line = = along the line
1 0 3
x−5 y−1 z−5
= = , is:
2 −3 6

(A) 21 (B) 18 (C) 12 (D) 14

11.The portion of the line 4x + 5y = 20 in the first quadrant is trisected by the lines L1
and L2 passing through the origin. The tangent of an angle between the lines L1 and
L2 is:
30 25 8 2
(A) (B) (C) (D)
41 41 5 5
√1+√1+x4 −√2 sin2 ⁡x
12.If a = limx→0 and b = limx→0 , then the value of ab3 is:
x4 √2−√1+cos⁡x

(A) 25 (B) 32 (C) 36 (D) 30

13.The number of common terms in the progressions 4, 9, 14, 19,∙∙∙∙∙∙, up to 25th term
and 3, 6, 9, 12,∙∙∙∙∙∙, up to 37th term is:
(A) 5 (B) 7 (C) 9 (D) 8
14.If A denotes the sum of all the coefficients in the expansion of (1 − 3x + 10x 2 )n and
B denotes the sum of all the coefficients in the expansion of (1 + x 2 )n , then:
(A) A = B 3 (B) A = 3B (C) B = A3 (D) 3 A = B
x−4 y+1 z x−λ y+1 z−2 6
15.If the shortest distance between the lines = = and = = is ,
1 2 −3 2 4 −5 √5

then the sum of all possible values of λ is:

(A) 5 (B) 8 (C) 10 (D) 7
16.⁡n−1 Cr = (k 2 − 8)⁡n Cr+1 if and only if:
(A) 2√3 < k ≤ 3√2 (B) 2√2 < k < 2√3

(C) 2√3 < k < 3√3 (D) 2√2 < k ≤ 3

a(7x−12−x2 )
, ⁡x < 3
b|x2 −7x+12|
17.Consider the function. f(x) = sin(x−3) where [x] denotes the greatest
2 x−[x] ,x > 3
{ b , x = 3,
integer less than or equal to x. If S denotes the set of all ordered pairs (a, b) such that
f(x) is continuous at x = 3, then the number of elements in S is:
(A) 4 (B) 1 (C) 2 (D) Infinitely many
18.If the shortest distance of the parabola y 2 = 4x from the centre of the circle x 2 +
y 2 − 4x − 16y + 64 = 0 is d, then d2 is equal to:
(A) 36 (B) 24 (C) 20 (D) 16
1 1
19.If ∫0 dx = a + b√2 + c√3, where a, b, c are rational numbers, then 2a +
√3+x+√1+x

3 b − 4c is equal to:
(A) 8 (B) 7 (C) 4 (D) 10
20.The length of the chord of the ellipse
x2 y2 2
+ = 1, whose mid point is (1, ), is equal to:
25 16 5

√2009 √1541 √1691 √1741

(A) (B) (C) (D)
5 5 5 5

2 0 1
21.Let A = [1 1 0] , B = [B1 , B2 , B3 ], where B1 , B2 , B3 are column matrics, and
1 0 1
1 2 3
AB1 = [0] , AB2 = [3] , AB3 = [2] If α = |B| and β is the sum of all the diagonal
0 0 1
elements of B, then α3 + β3 is equal to ________.
22.Let f(x) = x 3 + x 2 f ′ (1) + xf ′′ (2) + f ′′′ (3), x ∈. Then f ′ (10) is equal to ________.
23.Let the set of all a ∈ R such that the equation cos⁡2x + asin⁡x = 2a − 7 has a
1
solution be [p, q] and r = tan⁡9∘ − tan⁡27∘ − + tan⁡81∘ , then pqr is equal to
cot⁡63∘

________.
3
24.If α satisfies the equation x 2 + x + 1 = 0 and (1 + α)7 = A + Bα + Cα2 , A, B, C ⩾ 0,
then 5(3A − 2B − C) is equal to ________.
25.If the solution of the differential equation (2x + 3y − 2)dx + (4x + 6y − 7)dy =
0, y(0) = 3, is αx + βy + 3log e ⁡|2x + 3y − γ| = 6, then α + 2β + 3γ is equal to
_______.
x
26.Let for a differentiable function f: (0, ∞) → R, f(x) − f(y) ⩾ log e ⁡( ) + x −
y
1
y, ∀x, y ∈ (0, ∞) Then ∑20 ′
n=1 f (n2 ) is equal to ________.

27.Let the area of the region {(x, y): x − 2y + 4 ⩾ 0, x + 2y 2 ⩾ 0, x + 4y 2 ≤ 8, y ⩾ 0}

m
be , where m and n are coprime numbers. Then m + n is equal to ________.
n

28.A fair die is tossed repeatedly until a six is obtained. Let X denote the number of
tosses required and let a = P(X = 3), b = P(X ⩾ 3) and c = P(X ⩾ 6 ∣ X > 3). Then
b+c
is equal to ________.
a
1 1 1
29.If 8 = 3 + (3 + p) + (3 + 2p) + (3 + 3p) ∙∙∙∙∙∙ ∞, then the value of p is
4 42 43

________.
30.The least positive integral value of α, for which the angle between the vectors αî −
2ĵ + 2k̂ and αî + 2αĵ − 2k̂ is acute, is ________.
 27th JANUARY 2024 SHIFT-I (PHYSICS)
31.A body of mass 1000 kg is moving horizontally with a velocity 6 m/s. If 200 kg
extra mass is added, the final velocity (in m/s ) is:
(A) 2 (B) 5 (C) 6 (D) 3
32.Which of the following circuits is reverse - biased?

(A) (B)

(C) (D)
33.A proton moving with a constant velocity passes through a region of space without
any change in its velocity. If ⃗E and B
⃗ represent the electric and magnetic fields
respectively, then the region of space may have:
(a) E = 0, B = 0 (b) E = 0, B ≠ 0 (c) E ≠ 0, B = 0 (d) E ≠ 0, B ≠ 0
Choose the most appropriate answer from the options given below:
(A) (a), (c) and (d) only (B) (b), (c) and (d) only
(C) (a), (b) and (d) only (D) (a), (b) and (c) only
34.A rectangular loop of length 2.5 m and width 2 m is placed at 60∘ to a magnetic field
of 4 T. The loop is removed from the field in 10 s. The average emf induced in the
loop during this time is:
(A) +1 V (B) −2 V (C) +2 V (D) −1 V
35.Position of ant (S in metres) moving in Y − Z plane is given by S = 2t 2 ĵ + 5k̂ (where
t is in second). The magnitude and direction of velocity of the ant at t = 1 s will be:
(A) 16 m/s in y-direction (B) 9 m/s in z-direction
(C) 4 m/s in y-direction (D) 4 m/s in x-direction
36.Identify the physical quantity that cannot be measured using spherometer:
(A) Specific rotation of liquids
(B) Radius of curvature of concave surface
(C) Thickness of thin plates
(D) Radius of curvature of convex surface
5
37.A convex lens of focal length 40 cm forms an image of an extended source of light
on a photoelectric cell. A current I is produced. The lens is replaced by another
convex lens having the same diameter but focal length 20 cm. The photoelectric
current now is:
I
(A) I (B) 2I (C) 4I (D)
2

38.An electric charge 10−6 μC is placed at origin (0, 0)m of X − Y co-ordinate system.
Two points P and Q are situated at (√3, √3)m and (√6, 0)m respectively. The
potential difference between the points P and Q will be:
(A) 0 V (B) √3 V (C) √6 V (D) 3 V
39.Given below are two statements:
Statement (I): Planck's constant and angular momentum have same dimensions.
Statement (II): Linear momentum and moment of force have same dimensions.
In the light of the above statements, choose the correct answer from the options given
below:
(A) Both Statement I and Statement II are true
(B) Statement I is false but Statement II is true
(C) Both Statement I and Statement II are false
(D) Statement I is true but Statement II is false
40.The radius of third stationary orbit of electron for Bohr's atom is R. The radius of
fourth stationary orbit will be:
4 9 16 3
(A) R (B) R (C) R (D) R
3 16 9 4

41.0.08 kg air is heated at constant volume through 5∘ C. The specific heat of air at
constant volume is 0.17kcal/kg ∘ C and J = 4.18 joule/cal. The change in its internal
energy is approximately.
(A) 284 J (B) 142 J (C) 298 J (D) 318 J
42.The average kinetic energy of a monoatomic molecule is 0.414eV at temperature:
(Use K B = 1.38 × 10−23 J/mol − K)
(A) 3000 K (B) 1600 K (C) 1500 K (D) 3200 K
43.A plane electromagnetic wave propagating in x-direction is described by
Ey = (200Vm−1 )sin⁡[1.5 × 107 t − 0.05x];
The intensity of the wave is:
(Use ϵ0 = 8.85 × 10−12 C 2 N−1 m−2 )
(A) 53.1Wm−2 (B) 26.6Wm−2 (C) 35.4Wm−2 (D) 106.2Wm−2
44.Given below are two statements:
Statement (I): Viscosity of gases is greater than that of liquids.
Statement (II): Surface tension of a liquid decreases due to the presence of insoluble
impurities. In the light of the above statements, choose the most appropriate answer
from the options given below:
(A) Statement I is correct but Statement II is incorrect
(B) Both Statement I and Statement II are incorrect
(C) Statement I is incorrect but Statement II is correct
(D) Both Statement I and Statement II are correct
45.A wire of resistance R and length L is cut into 5 equal parts. If these parts are joined
parallely, then resultant resistance will be:
1 1
(A) 25R (B) 5R (C) R (D) R
25 5

46.A train is moving with a speed of 12 m/s on rails which are 1.5 m apart. To
negotiate a curve of radius 400 m, the height by which the outer rail should be raised
with respect to the inner rail is (Given, g = 10 m/s 2 ):
(A) 4.8 cm (B) 5.4 cm (C) 4.2 cm (D) 6.0 cm
47.The acceleration due to gravity on the surface of earth is g. If the diameter of earth
reduces to half of its original value and mass remains constant, then acceleration due
to gravity on the surface of earth would be:
g g
(A) (B) 2 g (C) (D) 4 g
4 2
A
48.If the refractive index of the material of a prism is cot⁡( ), where A is the angle of
2

prism then the angle of minimum deviation will be:

π π
(A) − 2 A (B) π − 2 A (C) − A (D) π − A
2 2

7
49.A wire of length 10 cm and radius √7 × 10−4 m is connected across the right gap of
a meter bridge. When a resistance of 4.5Ω is connected on the left gap by using a
resistance box, the balance length is found to be at 60 cm from the left end. If the
resistivity of the wire is R × 10−7 Ωm, then value of R is:
(A) 70 (B) 63 (C) 35 (D) 66
50.Two bodies of mass 4 g and 25 g are moving with equal kinetic energies. The ratio
of magnitude of their linear momentum is:
(A) 2: 5 (B) 5: 4 (C) 4: 5 (D) 3: 5
51.In a nuclear fission process, a high mass nuclide (A ≈ 236) with binding energy
7.6MeV/ Nucleon dissociated into middle mass nuclides (A ≈ 118), having binding
energy of 8.6MeV/Nucleon. The energy released in the process would be _______
MeV.
52.Four particles each of mass 1 kg are placed at four corners of a square of side 2 m.
Moment of inertia of system about an axis perpendicular to its plane and passing
through one of its vertex is _______ kgm2 .
53.Two coils have mutual inductance 0.002H. The current changes in the first coil
according to the relation i = i0 sin ωt, where i0 = 5 A and ω = 50πrad/s. The
π
maximum value of emf in the second coil is V. The value of α is _______.
α

54.The charge accumulated on the capacitor connected in the following circuit is

________ μC. (Given C = 150μF)

55.A particle starts from origin at t = 0 with a velocity 5î m/s and moves in x − y plane
under action of a force which produces a constant acceleration of (3î + 2ĵ)m/s 2 . If
the x-coordinate of the particle at that instant is 84 m, then the speed of the particle
at this time is √αm/s. The value of α is ________.
56.A thin metallic wire having cross sectional area of 10−4 m2 is used to make a ring of
radius 30 cm. A positive charge of 2πC is uniformly distributed over the ring, while
another positive charge of 30pC is kept at the centre of the ring. The tension in the
ring is ________ N; provided that the ring does not get deformed (neglect the
influence of gravity).
1
(given, = 9 × 109 SI units)
4πϵ0
57.Two long, straight wires carry equal currents in opposite directions as shown in
figure. The separation between the wires is 5.0 cm. The magnitude of the magnetic
field at a point P midway between the wires is ________ μT. (Given: μ0 = 4π ×
10−7 TmA−1 )

58.If average depth of an ocean is 4000 m and the bulk modulus of water is 2 ×
ΔV
109 Nm−2 , then fractional compression of water at the bottom of ocean is α ×
V

10−2 . The value of α is ________.

(Given, g = 10 ms −2 , ρ = 1000 kg m−3 )
8 3
59.Two immiscible liquids of refractive indices and respectively are put in a beaker
5 2

as shown in the figure. The height of each column is 6 cm. A coin is placed at the
α
bottom of the beaker. For near normal vision, the apparent depth of the coin is cm.
4

The value of α is

9
60.A particle executes simple harmonic motion with an amplitude of 4 cm. At the mean
position, velocity of the particle is 10 cm/s. The distance of the particle from the
mean position when its speed becomes 5 cm/s is √αcm, where α = ________.
 27th JANUARY 2024 SHIFT-I (CHEMISTRY)
61.Highest enol content will be shown by:

(A) (B)

(C) (D)
62.Two nucleotides are joined together by a linkage known as:
(A) Glycosidic linkage (B) Peptide linkage
(C) Disulphide linkage (D) Phosphodiester linkage
63.The correct statement regarding nucleophilic substitution reaction in a chiral alkyl
halide is:
(A) Racemisation occurs in SN 1 reaction and inversion occurs in SN 2 reaction.
(B) Racemisation occurs in SN 1 reaction and retention occurs in SN 2 reaction.
(C) Racemisation occurs in both SN 1 and SN 2 reactions.
(D) Retention occurs in SN 1 reaction and inversion occurs in SN 2 reaction.
64.Consider the following complex ions
P = [FeF6 ]3− ⁡⁡⁡⁡⁡⁡⁡⁡⁡
Q = [V(H2 O)6 ]2+ ⁡⁡
R = [Fe(H2 O)6 ]2+
The correct order of the complex ions, according to their spin only magnetic moment
values (in B.M.) is:
(A) R < Q < P (B) R < P < Q (C) Q < P < R (D) Q < R < P
65.Element not showing variable oxidation state is:
(A) Chlorine (B) Fluorine (C) Bromine (D) Iodine

66.Cyclohexene is ________ type of an organic compound.

(A) Acyclic (B) Alicyclic
(C) Benzenoid aromatic (D) Benzenoid non-aromatic
11
67.The electronic configuration for Neodymium is:
[Atomic Number for Neodymium 60]
(A) [Xe]4f 4 6 s 2 (B) [Xe]4f 6 6 s 2
(C) [Xe]5f 7 7 s 2 (D) [Xe]4f ′ 5 d′ 6 s 2
68.Given below are two statements: one is labelled as Assertion (A) and the other is
labelled as Reason (R).
Assertion (A): Melting point of Boron (2453 K) is unusually high in group 13
elements.
Reason (R): Solid Boron has very strong crystalline lattice.
In the light of the above statements, choose the most appropriate answer from the
options given below:
(A) Both (A) and (R) are correct and (R) is the correct explanation of (A)
(B) Both (A) and (R) are correct but (R) is not the correct explanation of (A)
(C) (A) is false but (R) is true
(D) (A) is true but (R) is false
69.Which of the following electronic configuration would be associated with the highest
magnetic moment?
(A) [Ar]3d3 (B) [Ar]3d6 (C) [Ar]3d7 (D) [Ar]3d8
70.Which of the following has highly acidic hydrogen?

(A) (B)

(C) (D)
71.Given below are two statements:
Statement (I): p-nitrophenol is more acidic than m-nitrophenol and o-nitrophenol.
Statement (II): Ethanol will give immediate turbidity with Lucas reagent.
In the light of the above statements, choose the correct answer from the options given
below:
(A) Statement I is false but Statement II is true
(B) Both Statement I and Statement II are true
(C) Both Statement I and Statement II are false
(D) Statement I is true but Statement II is false
72.Choose the polar molecule from the following:
(A) CH2 = CH2 (B) CHCl3 (C) CCl4 (D) CO2
73.Which of the following is strongest Bronsted base?

(A) (B)

(C) (D)
74.NaCl reacts with conc. H2 SO4 and K 2 Cr2 O7 to give reddish fumes (B), which react
with NaOH to give yellow solution (C). (B) and (C) respectively are:
(A) CrO2 Cl2 , Na2 CrO4 ⁡⁡⁡ (B) CrO2 Cl2 , Na2 Cr2 O7
(C) Na2 CrO4 , CrO2 Cl2 ⁡⁡⁡ (D) CrO2 Cl2 , KHSO4
75.Given below are two statements:
Statement (I): The 4f and 5f-series of elements are placed separately in the Periodic
table to preserve the principle of classification.
Statement (II): s-block elements can be found in pure form in nature.
In the light of the above statements, choose the most appropriate answer from the
options given below:
(A) Both Statement I and Statement II are false
(B) Both Statement I and Statement II are true
(C) Statement I is false but Statement II is true
(D) Statement I is true but Statement II is false
76.IUPAC name of following compound (P) is:

(A) 3-Ethyl-1, 1-dimethylcyclohexane

(B) 1-Ethyl-5, 5-dimethylcyclohexane
(C) 1, 1-Dimethyl-3-ethylcyclohexane
(D) 1-Ethyl-3, 3-dimethylcyclohexane
13
77.A solution of two miscible liquids showing negative deviation from Raoult's law will
have:
(A) decreased vapour pressure, increased boiling point
(B) decreased vapour pressure, decreased boiling point
(C) increased vapour pressure, increased boiling point
(D) increased vapour pressure, decreased boiling point
78.Yellow compound of lead chromate gets dissolved on treatment with hot NaOH
solution. The product of lead formed is a:
(A) Neutral complex with coordination number four
(B) Tetraanionic complex with coordination number six
(C) Dianionic complex with coordination number four
(D) Dianionic complex with coordination number six
79.Given below are two statements:
Statement (I): Aqueous solution of ammonium carbonate is basic.
Statement (II): Acidic/basic nature of salt solution of a salt of weak acid and weak
base depends on K a and K b value of acid and the base forming it.
In the light of the above statements, choose the most appropriate answer from the
options given below:
(A) Statement I is correct but Statement II is incorrect
(B) Both Statement I and Statement II are incorrect
(C) Both Statement I and Statement II are correct
(D) Statement I is incorrect but Statement II is correct
80.The ascending order of acidity of −OH group in the following compounds is:

(a) Bu − OH (b) (c)

(d) (e)
Choose the correct answer from the options given below:
(A) (a) < (c) < (d) < (b) < (e) (B) (c) < (d) < (b) < (a) < (e)
(C) (c) < (a) < (d) < (b) < (e) (D) (a) < (d) < (c) < (b) < (e)
81.3-Methylhex-2-ene on reaction with HBr in presence of peroxide forms an addition
product (A). The number of possible stereoisomers for 'A' is ________.
82.Consider the following data for the given reaction 2HI(g) → H2( g) + I2( g)

1 2 3

⁡HI(molL−1 ) 0.005 0.01 0.02

Rate (molL−1 S −1 ) 7.5 × 10−4 3.0 × 10−3 1.2 × 10−2

The order of the reaction is ________.
83.Mass of methane required to produce 22 g of CO2 after complete combustion is g.
(Given Molar mass in gmol−1 C = 12.0, H = 1.0, O = 16.0)
84.The mass of silver (Molar mass of Ag: 108⁡gmol−1 ) displaced by a quantity of
electricity which displaces 5600 mL of O2 at S.T.P. will be _________ g.
85.The number of electrons present in all the completely filled subshells having n = 4
1
and s = + is ________.
2

(Where n = principal quantum number and s = spin quantum number)

86.Among the given organic compounds, the total number of aromatic compounds is
________.

(A) (B) (C) (D)

87.Sum of bond order of CO and NO+ is ________.
88.From the given list, the number of compounds with +4 oxidation state of Sulphur is
________. SO3 , H2 SO3 , SOCl2 , SF4 , BaSO4 , H2 S2 O7
89.If three moles of an ideal gas at 300 K expand isothermally from 30dm3 to 45⁡dm3
against a constant opposing pressure of 80⁡kPa, then the amount of heat transferred is
________ J.
90.Among the following, total number of meta directing functional groups is (Integer
based) – OCH3 , −NO2 , −CN, −CH3 , −NHCOCH3 ,⁡
−COR, −OH, −COOH, −Cl

15
 ANSWER
MATHEMATICS

1. D 2. D 3. D 4. C 5. C 6. D 7. C 8. D 9. B 10. D
11. A 12. B 13. B 14. A 15. B 16. D 17. B 18. C 19. A 20. C
21. 0 22. 202 23. 48 24. 5 25. 29 26. 2890 27. 119 28. 12 29. 9 30. 5

PHYSICS

31. B 32. C 33. C 34. A 35. C 36. A 37. A 38. A 39. D 40. C
41. A 42. D 43. A 44. C 45. C 46. B 47. D 48. B 49. D 50. A
51. 236 52. 16 53. 2 54. 400 55. 673 56. 3 57. 160 58. 2 59. 31 60.

CHEMISTRY

61. C 62. D 63. A 64. D 65. B 66. A 67. A 68. A 69. B 70. C
71. D 72. B 73. B 74. A 75. D 76. A 77. A 78. C 79. C 80. A
81. 4 82. 2 83. 8 84. 108 85. 16 86. 3 87. 6 88. 3 89. 1200 90. 4

MATHEMATICS SOLUTIONS
1. Slope of AB = 1.
Altitude through C

y − 1 = −1(x − 3)
⇒ ⁡x + y = 4
Orthocentre (a, b) lies on this
⇒a+b=4 ⋯ (i)
b
Now, l1 = ∫a x ⋅ sin⁡(4x − x 2 )dx
b
= ∫a (a + b − x)sin⁡(4(a + b − x) − (a + b − x)2 )dx
b
= ∫a (4 − x)sin⁡(4x − x 2 )dx⁡ {using (i)}
⇒ l1 = 4 ⋅ l2 − l1
l1
⇒ = 2.
l2
l1
⇒ 36 = 72
l2
2. z will be circumcentre of the triangle with vertices i,
−i and 1 (which is unique)
⇒ z = 0 + 0i
∴ ⁡ Only one element exist in S

3. S = {1,2,3, … ,10} and R = {(A, B): A ∩ B ≠ ϕ;

A, B ∈ M}
A∈M
A∩A=A≠ϕ
So, R is not reflexive
If (A, B) ∈ R
⇒ ⁡A ∩ B = ϕ
⇒ ⁡(B, A) ∈ R
So, R is symmetric
If (A, B), (B, C) ∈ R ⇒ A ∩ B = ϕ and B ∩ C = ϕ
⇒ A ∩ C is not necessary ϕ.
Hence, A ∩ C not necessarily belongs to R.
So, R is not transitive relation.
eg:- A = {1,2}, B = {3,4}, C = {2,5}
here, A ∩ B = ϕ, B ∩ C = ϕ
but A ∩ C = {2} ≠ ϕ
So, option (D) is correct.

17
 dx
4. + ax = 0
dt

1
⇒ ⁡ ∫ ⁡ dx = − ∫ ⁡ adt
x
⇒ ⁡ln⁡|x| = −at + c
⇒ ⁡x = ±ec ⋅ e−at = λe−at
⇒ ⁡x(0) = 2 ⇒ λ = 2
⇒ ⁡x = 2e−at ⋯ (i)
dy
Now, + by = 0
dt

1
⇒⁡∫ dy = −∫ bdt ⇒ ln⁡(y) = −bt + c
y
⇒ y = ±ec ⋅ e−bt = μ ⋅ e−bt
y(0) = 1
∴μ=1

⇒ y = e−bt
3y(1) = 2x(1)
3e−b = 2(2e−a ) = 4e−a
4
e−b+a =
3
⇒ ⁡x(t) = y(t)
⇒ ⁡e−bt = 2e−at

⇒ ⁡e−bt+at = 2
⇒ ⁡e(−b+a)t = 2

4 t
⇒ ⁡( ) = 2
3
4
⇒ tln = ln 2
3
⇒ ⁡t = ln4 ⁡2
3
 ∑10 10 10
k=j ∑j=1 ak aj −∑k=1 ak ak
5. ∑∀K<j ak ⋅ aj = ( )
2

∑10
k=1 ∑j=1 ak aj ⁡ = (a1 + a2 + ⋯ + a10 )(a1 + a2 +. . +a10 )

= (50)(50) = 2500
⇒ ∑10 2
k=1 ak = 2500 − 2∑∀k<j ak aj

= 2500 − 2 × 1100 = 300

Standard deviation (σ)
2
∑ ⁡ a2x ∑ ⁡ ak
⇒σ=√ −( )
10 10

300 50 2
= √ − ( ) = √30 − 25 = √5
10 10
6. General equation of circle is
x 2 + y 2 + 2gx + 2fy + c = 0
As it passes through (0, 0)(0, 1)(1, 0)
∴ ⁡c = 0
Now 2g + 1 = 0
−1
⇒g=
2
2f + 1 = 0
−1
f=
2
Hence equation of circle is
x2 + y2 − x − y = 0
Also point (2k, 3k) lies on the circle.
∴ ⁡4k 2 + 9k 2 − 5k = 0
⇒ ⁡13k 2 − 5k = 0
5
⇒ ⁡k = 0, k =
13
5
∴ ⁡k =
13
19
7. a⃗ = î + 2ĵ + k̂, ⃗b = 3(î − ĵ + k̂)
a⃗ ⋅ c = 3 ⋯ (i)
a⃗ × c = ⃗b ⋯ (ii)
Taking cross product of a⃗ in equation (ii),
⃗
a⃗ × (a⃗ × c) = a⃗ × b
(a⃗ ⋅ c)a⃗ − (a⃗ ⋅ a⃗)c = a⃗ × ⃗b ⋯ (iii)
î ĵ k̂
⃗
a⃗ × b = |1 2 1|
3 −3 3
= î(6 + 3) − ĵ(3 − 3) + k̂(−3 − 6)
⃗ = 9î − 9k̂
a⃗ × b
a⃗ ⋅ a⃗ = (î + 2ĵ + k̂) ⋅ (î + 2ĵ + k̂)
=1+4+1=6
Putting all these values in equation (iii)
⇒ 3(î + 2ĵ + k̂) − 6c = 9î − 9k̂
⇒ 6c = 3î + 6ĵ + 3k̂ − 9î + 9k̂
⇒ 6c = −6î + 6ĵ + 12k̂
⇒ c = −î + ĵ + 2k̂
Now, a⃗ ⋅ ((c × ⃗b) − ⃗b − c)
î ĵ k̂
⃗
c × b = |−1 1 2|
3 −3 3
= î(9) − ĵ(−9) + k̂(0)
= 9î + 9ĵ
(c × ⃗b) − ⃗b − c
= 9î + 9ĵ − 3î + 3ĵ − 3k̂ + î − ĵ − 2k̂
= 7î + 11ĵ − 5k̂
a ⋅ ((c × ⃗b) − ⃗b − c)
(î + 2ĵ + k̂) ⋅ (7î + 11ĵ − 5k̂)
= 7 + 22 − 5
= 24
8. Largest prime factors of two different natural numbers can be same so it is many
one.
For example f(6) = 3, f(12) = 3
f(10) = 5, f(15) = 5
As range of f(x) is set of prime number so range of f(x) is proper subset of co-
domain so f is into.
cos⁡x −sin⁡x 0
9. f(x) = [ sin⁡x cos⁡x 0]
0 0 1
cos⁡x −sin⁡x 0 cos⁡y −sin⁡y 0
f(x) ⋅ f(x) = [ sin⁡x cos⁡x 0] [ sin⁡y cos⁡y 0]
0 0 1 0 0 1
cos⁡(x + y) −sin⁡(x + y) 0
= [ sin⁡(x + y) cos⁡(x + y) 0]
0 0 1
= f(x + y)
So, statement II is true.
f(x)f(−x) = 1
So, f(−x) is inverse of f(x).
So, statement I is true.
10.Let P(7, −2,11)
x−6 y−4 z−8
and line = =
1 0 3

Let General point be 'Q'

∴ ⁡Q ≡ (λ + 6,4,3λ + 8) ⋯ (i)
As we have to find distance along
⃗⃗⃗⃗⃗ = (1 − λ, −6, −3λ − 3)
∴ ⁡PQ
x−5 y−1 z−5
= =
2 −3 6
1 − λ −6 −3λ − 3
∴⁡ = =
2 −3 6
1−λ −3λ − 3
=2=
2 6

21
 1−λ
∴⁡ =2
2
1−λ=4
λ = −3
Putting in (I)
Q ≡ (3,4, −1)
and P ≡ (7, −2,11)

∴ PQ = √(3 − 7)2 + (4 + 2)2 + (−1 − 11)2

= √(−4)2 + (6)2 (−12)2

= √16 + 36 + 144
= √196
= 14
Option (D) is correct

11.
5(1) + 2(0) 5
Ax ≡ =
3 3
5 8
⇒A≡( , )
3 3
0(1) + 2(4) 8
Ay = =
3 3
10 4
Similarly, B ≡ ( , )
3 3
8
⇒ Slope of AO =
5
2
Slope of OB =
5
8 2 6
− 30
tan⁡θ = | 5 16
5 5
| = | 41 |=
1+ 41
25 25
 √1+√1+x4 −√2
12.a = limx→0
x4
sin2 ⁡x
and b = limx→0
√2−√1+cos⁡x

1 + √1 + x 4 − 2
a = limx→0
x4
1 √1 + x 4 − 1
= limx→0
2√2 x4
1 (1 + x 4 ) − 1
= limx→0
2√2 x 4 (√1 + x 4 + 1)
1 1 1
= ( )=
2√2 2 4√2
1
⇒a=
4√2
(1 − cos 2 ⁡x)(√2 + √1 + cos⁡x)
b = limx→0
2 − (1 + cos⁡x)
b = limx→0 (1 + cos⁡x)(√2 + √1 + cos⁡x)
⇒ b = 2(2√2)
⇒ b = 4√2
1
So, ab3 = (4√2)3
4 √2

ab3 = 32
So, option (B) is correct.
13.Given A.P.
4, 9, 14, 19, … Upto 25 terms
Here d1 = 5
an = a + (n − 1)d
a25 = 4 + (25 − 1)5
a25 = 4 + 24(5)
a25 = 124
So, A.P. is

23
 4, 9, 14, 19, … 124
Second A.P. is given as
3, 6, 9, 12, … upto 37 term.
Here d2 = 3
an = a + (n − 1)d
an = 3 + (n − 1) ⋅ 3
a37 = 3 + 36(3)
a37 = 111
So, A.P. is
3, 6, 9, 12, … ,111
L.C.M. of d1 and d2 = 15
So, A.P. of common terms becomes
9, 24, 39, … 99
an = a + (n − 1)d
99 = 9 + (n − 1)15
90
=n−1
15
n=7
14.A = sum of coefficient = (1 − 3(1) + 10(1)2 )n = 8n
(Putting x = 1)
B = Sum of coefficient = (1 + (1)2 )n = 2n
⇒ 8n = (23 )n = (2n )3 = B 3
⇒ A = B3

15.
Shortest distance PQ is given by
 ⃗V1 × ⃗V2 ⃗⃗⃗⃗⃗
AB 6
| |=
⃗ 1 × ⃗V2 |
|V √5
î ĵ k̂
⃗V1 × ⃗V2 = |1 2 −3| = 2î − ĵ
2 4 −5
⃗ 1 × ⃗V2 | = √5
⇒ |V
⃗⃗⃗⃗⃗
AB = (λ − 4)î + 2k̂
⃗V1 × ⃗V2 6 2(λ − 4) 6
⇒| ⃗⃗⃗⃗⃗ | =
⋅ AB ⇒| |=
⃗1×V
V ⃗2 √5 √5 √5
⇒ |λ − 4| = 3
⇒ λ − 4 = 3 or − 3
λ = 1 or 7
⇒ Sum of λ = 8
n
16.⁡n−1 Cr = (k 2 − 8) ⁡n−1 Cr
r+1
r+1
k2 − 8 =
n
0 < k2 − 8 ≤ 1
8 < k2 ≤ 9
2√2 < k ≤ 3 or − 3 ≤ k < −2√2
17.If f(x) is continuous at x = 3
⇒ f(3) = f(3+ ) = f(3− )
sin⁡(x−3) a (7x − 12 − x 2 )
⇒ b = lim+ 2 x−[x] = lim−
x→3 x→3 b |x 2 − 7x + 12|
sin⁡(x−3)
⇒ lim+ 2 x−[x]
x→3
sin⁡h
⇒ lim 2 h =2
h→0

(7x − 12 − x 2 ) = −(x 2 − 7x + 12) = −(x − 3)(x − 4)

⇒ (x 2 − 7x + 12) will open positive

25
 a (7x − 12 − x 2 ) −a
⇒ lim− = lim =2
x→3 b (x 2 − 7x + 12) x→3− b

⇒ −a = 2b ⇒ a = −2b = −4
⇒ (a, b) = {(−4,2)}
⇒ Only 1 ordered pair
18.Any normal to y 2 = 4x

y = mx − 2m − m3
If it passes through (2, 8)
8 = 2m − 2m − m3 .
⇒ m = −2
Feet of normal on parabola.
P(am2 , −2am) ≡ (4,4)
d2 = OP 2 = (4 − 2)2 + (4 − 8)2
= 4 + 16 = 20
1 1
19.∫0 dx = a + b√2 + c√3
√3+x+√1+x

Taking L.H.S.
Multiply and divide by √3 + x − √1 + x
1 √3 + x − √1 + x
= ∫0 dx
2
1 1
= ∫0 (√3 + x − √1 + x)dx
2
1
1 2 3/2
2(1 + x)3/2
= [ (3 + x) − ]
2 3 3 0
1
= [43/2 − 23/2 − 33/2 + 1]
3
 1
= [8 − 2√2 − 3√3 + 1]
3
1
= (9 − 2√2 − 3√3)
3
2√2
=3− − √3
3
By comparing, we get :
a=3
b = −2/3
c = −1
2a + 3b − 4c
= 6 + 3(−2/3) − 4(−1)
=6−2+4
=8

20.
2
x y (5) 1 4
T = S1 ⇒ + = +
25 16 25 16 × 25
x y 5
⇒ + =
25 40 100
5
⇒ 4x + y = 5 ⇒ 8x + 5y − 10 = 0
2
x2 y2
+ = 1 ⇒ (4x)2 + (5y)2 = 400
25 16
⇒ ⁡ (4x)2 + (8x − 10)2 = 400
⇒ 4x 2 + (4x − 5)2 = 100
⇒ 20x 2 − 40x − 75 = 0
⇒ 4x 2 − 8x − 15 = 0

27
 I = √(x2 − x1 )2 + (y2 − y1 )2
2
(10 − 8x2 ) (10 − 8x1 )
= √(x2 − x1 )2 + { − }
5 5

64
= √(x2 − x1 )2 + (x2 − x1 )2
25

89
= √ √(x2 − x1 )2
25

89
= √ √(x1 + x2 )2 − 4x1 x2
25

√89 15 1
= √4 + 4 × = √89 × √19
5 4 5

√1691
=
5
2 0 1
21.A = [1 1 0] , |A| = I
1 0 1
1 −1 −1 1 0 −1
−1
A = adj⁡(A) = [ 0 1 0 ] = [−1 1 1]
−1 1 2 −1 0 2
1 1
−1
⇒ B1 = A [0] = [−1]
0 1
2 2
−1
⇒ B2 = A [3] = [ 1 ]
0 −2
3 2
−1
⇒ B3 = A [2] = [ 0 ]
1 −1
1 2 2
⇒ B = [−1 1 0]
1 −2 −1
⇒ β = 1, α = −1 ⇒ α3 + β3 = 0
22.f(x) = x 3 + x 2 f ′ (1) + xf ′′ (2) + f ′′′ (3)
f ′ (x) = 3x 2 + 2xf ′ (1) + f ′′ (2)
f ′′ (x) = 6x + 2f ′ (1)
f ′′′ (x) = 6
⇒ f ′′′ (3) = 6
f ′′ (2) = 12 + 2f ′ (1) ⋯ (i)
f ′ (1) = 3 + 2f ′ (1) + f ′′ (2) ⋯ (ii)
adding (1) & (2)
0 = 15 + 3f ′ (x) ⇒ f ′ (1) = −5
f ′′ (2) = 12 − 10 = 2
Now
f ′ (10) = 300 + 20(−5) + 2
= 300 − 100 + 2 = 202
23.cos⁡2x + asin⁡x = 2a − 7
1 − 2sin2 ⁡x + asin⁡x = 2a − 7
Let sin⁡x = t
2t 2 − at + 2a − 8 = 0
⇒ (t − 2)(2t + 4 − a) = 0
⇒ a = 2sin⁡x + 4
∴ a ∈ [2,6] ⇒ p = 2 and q = 6.
Now
tan⁡θ + cot⁡θ = 2cosec⁡2θ
r = 2cosec⁡18∘ − 2cosec⁡54∘
4 4
= 2[ − ]
√5 − 1 √5 + 1
2
=8× = 4, = r
5−1
∴ pqr = 2 × 6 × 4 = 48.

29
24.∵ α2 + α + 1 = 0
−1 ± √1 − 4 1 √3
⇒α= =− ± i
2 2 2
α = ω, ω2
If α = ω
(1 + α)7 = (1 + ω)7 = (−ω2 )7 = −ω14 = −ω2
⇒ ⁡ −ω2 = A + Bω + Cω2
⇒ A + Bω + (C + 1)ω2 = 0
⇒ 2A − B − C = 1 and B − C = 1
⇒ B = C + 1, A = B = C + 1
⇒ 5(3A − 2B − C) = 5(3C + 3 − 2C − 2 − C) = 5
If α = ω2
(1 + α)7 = (1 + ω2 )7 = −ω7 = −ω
⇒ ⁡ −ω = A + Bω2 + Cω4 = A + Bω2 + Cω
⇒ A + Bω2 + (C + 1)ω = 0
2A − B − C = 1 and B − C = 1
⇒ B = C + 1, A = B = C + 1
⇒ 5(3A − 2B − C) = 5
25.(2x + 3y − 2)dx + (4x + 6y − 7)dy = 0
dy 2x + 3y − 2
= −( )
dx 4x + 6y − 7
Let 2x + 3y = t
dy dt
2+3 =
dx dx
1 dt t−2
[ − 2] = − ( )
3 dx 2t − 7
dt 3t − 6
− 2 = −( )
dx 2t − 7
dt 3t − 6
=2−
dx 2t − 7
dt t−8
=
dx 2t − 7
 2t − 7
∫( ) dt = ∫ dx⁡
t−8
a
= ∫ ⁡ 2dt + ∫ ⁡ dt = ∫ ⁡ dx
t−8
= 2t + 9ln⁡|t − 8| = x + c
= 2(2x + 3y) + 9|2x + 3y − 8| = x + c
∵ y(0) = 3
⇒ c = 18
= 3x + 6y + 9ln⁡(|2x + 3y − 8|) = 18
= x + 2y + 3ln⁡|2x + 3y − 8| = 6
⇒ α = 1, β = 2, γ = 8
Now
α + 2β + 3γ
= 1 + 4 + 24 = 29
x
26.f(x) − f(y) ≥ ln⁡( ) + x − y
y

Put x = x + h and y = x, where h > 0

x+h
⇒ ⁡f(x + h) − f(x) ≥ ln⁡( ) + (x + h) − x
x
x+h
f(x + h) − f(x) ln⁡( x ) + h
⇒⁡ ≥
h h
h
ln⁡(1 + )
x
⇒ ⁡f ′ (x) ≥ lim +1
h→0 h
1
⇒ ⁡f ′ (x) ≥ + 1 ⋯ (i)
x
y
∵ ⁡f(y) − f(x) ≤ ln⁡( ) + y − x
x
Put y → x + h, x → x where h > 0
x+h
f(x + h) − f(x) ≤ ln⁡( )+h
x
h
f(x + h) − f(x) ln⁡(1 + x )
≤ +1
h h

31
 1
⇒ ⁡f ′ (x) ≤ + 1 ⋯ (ii)
x

From (i) and (ii),

1 x+1
f ′ (x) = 1 + =
x x
1
⇒ f′ ( 2
) = n2 + 1
n
20
1 20 × 21 × 41
⇒ ∑ f′ ( ) = 20 + = 2890
n2 6
n=1

27.
Area between these curve will be
−1 0
−x x + 4 8−x −x
∫ (−√ + ) dx + ∫ (√ − √ ) dx
−2 2 2 −1 4 2

8
8−x 107 m
+∫ √ dx = =
0 4 12 n

⇒ m + n = 119
28.a = P(X = 3) ⇒ third toss obtains 6 at first time
1
⇒ P(A) = (obtaining a six)
6
5
P(A‾) = (not obtaining a six)
6

5 5 1 25 52
⇒ a = P(X = 3) = × × = = 3
6 6 6 216 6
⇒ b = P(X ≥ 3) =
5 5 1 5 5 5 1 5 5 5 5 1
× × + × × × + × × × × +⋯
6 6 6 6 6 6 6 6 6 6 6 6
25 52 5
⇒ It is a G.P. with first term = = and common ratio ( )
216 63 6
 25
216 25 5 2
⇒ Sum = 5 = =( )
1− 36 6
6

X≥6 P(X ≥ 6 ∩ X > 3) P(X ≥ 6)

c = P( )= =
X>3 P(X > 3) P(X > 3)
53
5 5 5 1 5 5 5 5 1 4 53
P(X > 3) = × × × + × × × × +⋯= 6 1 = 3
6 6 6 6 6 6 6 6 6 1− 6
5

6 55
5 5 5 5 5 1 5 1 66 55
P(X ≥ 6) = × × × × × + ( ) × + ⋯ = 5 = (6 5 )
6 6 6 6 6 6 6 6 1−
6
55
63 52 5 2
c= 53
= 2=( )
6 6
63
25 25
b+c + 25 216
36 36
= 25 =2× × = 12
a 36 25
216
1 1 1
29.S = 3 + (3 + p) + (3 + 2p) + (3 + 3p) + ⋯ ∞
4 42 43
1
Tn ⁡ = (3 + (n − 1)p) = t n + t ′n
4n−1
3
tn ⁡ =
4n−1
1 1
⇒ ⁡sn = 3 (1 + + 2 + ⋯ ) = 4
4 4
p 2 3
sn′ ⁡ = (1 + + 2 + ⋯ ∞)
4 4 4
2 3
Let R = 1 + + +⋯
4 42
R 1 2
= + +⋯
4 4 42
3R 1 1 4 16
⇒ =1+ + 2+⋯= ⇒R=
4 4 4 3 9
p 16
⇒S=4+ × =8
4 9
⇒p=9

33
30.(αî − 2j + 2k̂) ⋅ (αî + 2αj − 2k̂) > 0
α2 − 4α − 4 > 0
(α − 2)2 > 8
(α − 2 − 2√2)(α − 2 + 2√2) > 0
α ∈ (−∞, 2 − 2√2) ∪ (2 + 2√2, ∞)
⇒ Least integral value of α is 5

PHYSICS SOLUTIONS
31.By conservation of momentum
1000 × 6 = 1200 × V
⇒ ⁡v = 5 m/s
32.For reverse bias VP < VN , that is true for option (C)
33.For constant velocity, net force on charge particle should be zero.
That is possible for a, b and d.
Δϕ
34.Eavg = −
Δt

Δϕ = −BAcos⁡60∘
1
= −4 × 2.5 × 2
2
= −10
+10
Eavg = =1V
10
ds⃗
35.v
⃗ =
dt

⃗ = 4tĵ
v
At t = 1 s
⃗ = 4ĵ
v
36.Spherometer cannot measure specific rotation of liquids.
37.As the diameter is same, number of photons will be same.
∴ ⁡l′ = I
 KQ
38.V =
r

at P: r1 = √6
at Q: r2 = √6
∴ VP = VQ
⇒ ΔV = 0
39.[h] = [ML2 T −1 ]
[L] = [ML2 T −1 ]
[P] = [MLT −1 ]
[FL] = [MLT −2 ] × [L]
= [ML2 T −2 ]
40.For 3rd orbit
(3)2
R = r0
Z
′
(4)2
R = r0
Z
16
∴ ⁡R′ = ( ) R
9
41.ΔU⁡ = mCΔT
= 0.08 × 0.17 × 4.18 × 103 × 5
= 284 J
3
42.E = K B T
2
3
0.414 × 1.6 × 10−19 = × 1.38 × 10−23 T
2
T = 3200 K
1
43.I = ∈0 E02 C
2
1
= × 8.85 × 10−12 × (200)2 × (3 × 108 )
2
= 53.1 W m−2
44.Viscosity of liquids is greater than gas.
Surface tension decreases due to the presence of impurities.
35
 R
45.Resistance of each part =
5

1 R R
∴ ⁡R eq = ( ) ( ) =
5 5 25
v2 h
46.tan⁡θ = =
rg w

v2
∴h= w
rg
(12)2 × 1.5
=
400 × 10
= 0.054 m
= 5.4 cm
GM
47.∵ g =
R2
R
If R′ =
2

⇒ g ′ = 4g
48.For minimum deviation
(δ+A)
sin⁡ A
2
μ= A
= cot⁡( )
sin⁡( 2 ) 2

δ = π − 2A
4.5 S
49. =
60 40

ρl
∴ ⁡S = 3Ω =
A
SA
ρ= = 66 × 10−7
I
⁡∴ ⁡R = 66
P2
50.K =
2m

P12 P22
=
2m1 2m2

P1 m1 2
=√ =
P2 m2 5
51.A → 2B
ΔE = 2 × 118 × 8.6 − 236 × 7.6
ΔE = 236⁡MeV
52.I = 2(Ma2 ) + M(√2a)2
I = 4Ma2
= 4 × 1 × 4 = 16
53.ϕ2 ⁡ = Mi1
dϕ2
|E| ⁡ = | | = Mi0 ωcos⁡ωt
dt
Emax = Mi0 ω
= 0.002 × 5 × 50π
= 0.5π
10 20
54.VA = 10 − = V
3 3

VB = 10 − 6 = 4 V
8
VA − VB = V
3
8
Q = CVAB = 150 × 10−6 × = 400μC
3
1
55.x = 5t + × 3t 2 = 84
2

∴t=6s
⃗ = 5î + 6(3î + 2ĵ)
v
⃗ = 23î + 12ĵ
v
v = √673
2KλQ
56.Force on one half of the ring =
r
KλQ
∴T=
r
2π
9
30 × 10−12
= 9 × 10 × ×
2π × 0.3 0.3
=3N

37
 μ0 i
57.B = 2 × d = 160 × 10−6 T
2π( )
2

ΔP
58.B = − ΔV
( )
V

ΔV 1000 × 10 × 4000
∴− =
V 2 × 109
= 2 × 10−2
d1 d2
59.Apparent depth = +
μ1 μ2

6 6 31
= 3
+ 8
= cm
(2) (5) 4

60.v = ω√A2 − x 2

x2
⇒ v = ωA√1 −
A2

x2
⇒ 5 = 10√1 −
42

1 x2
⇒ =1− 2
4 4

3
⇒ x = √ × 42 = √12 cm
4

CHEMISTRY SOLUTIONS
61.Highest enol content will shown by

Due to formation of aromatic compound.

62.Two nucleotides are joined together by phosphodiester linkage between 5 and 3
carbon atoms of pentose sugar.

63.In SN 1 reaction carbocation is formed as intermediate. Hence both side attack is

possible, racemic product is formed.
In SN 2 reaction, nucleophile attack from back side takes place and hence inversion
in configuration takes place.
64.P = [FeF6]3−
Q = [V(H2 O)6 ]2+
R = [Fe(H2 O)6 ]2+
F ⊖ with Fe+3 , and H2 O with Fe+2 behaves as WFL and pairing does not takes
place
[FeF6 ]3− = 3d5 = t 32 g e2g

Number of unpaired electron = 5

39
 μ⁡ = √n(n + 2)BM

= √5(5 + 2)BM

= √35BM
[V(H2 O)6 ]2+ = 3d3 ⁡t 32 g eg 0

n=3

μ = √15BM
R = [Fe(H2 O)6 ]2+ = 3d6 = t 42 g e2g

n=4

μ = √24BM
Q<R<P

65.Fluorine does not show variable oxidation state due to absence of vacant d-orbital.

66.
The given compound belongs to alicyclic compounds.
67.The electronic configuration of Neodymium is
⁡60 Nd: [Xe]4f 4 6 s 2
68.Melting point of Boron is unusually high due to very strong crystalline lattice.
Both (A) and (R) are correct and (R) is correct explanation of (A).
69.[Ar] 3d6 have 4 unpaired electrons which has highest magnetic moment.
70.After removal of H+ ion, negative charge is formed, more stable the negative
charge more will be the acidic strength.

Due to cross conjugation of negative charge it is most stabilised anion.

So compound is most acidic.
71.p-Nitrophenol is more acidic than m-nitrophenol and o-nitrophenol.
The electron withdrawing group −NO2 stabilizes phenoxide ion through −R effect
at para and ortho position.
−NO2 group in meta position will show - I effect.
Presence of −NO2 group at ortho position it form hydrogen bonding with −OH
group.
Hence, acidity is less than p-nitrophenol order of acidic strength.
p-nitrophenol > o-nitrophenol > m-nitrophenol
Ethanol will not give immediate turbidity with Lucas reagent.
3∘ alcohol will give white turbidity immediately statement I is true but statement II
is false.
72.The molecule which has permanent dipole moment are said to be polar molecule.

CHCl3 is polar molecule

73.Bronsted base are those which can donate its lone pair to H+ ion.
more easily the compound can donate its lone pair to H+ strong will be basic
character

is strongest Bronsted base due to availability of lone pair.

In other option lone pair is delocalised

41
74.4NaCl + K 2 Cr2 O7 + 6H2 SO4 ⟶ 2CrO2 Cl2 + 4NaHSO4 + 2KHSO4 + 3H2 O
(B)

CrO2 Cl2 + 4NaOH ⟶ Na2 CrO4 + ⁡ 2NaCl + 2H2 O

(C)
Yellow

75.s-block elements are highly reactive and hence can't be found in pure form in
nature.
⇒ Statement II is incorrect.

76.
Numbering is done in such a way that all locants should get lowest possible
number.
Name of substituent written according to alphabetical order
3-Ethyl-1, 1-dimethylcyclohexane
77.A solution of two miscible liquids showing negative deviation due to decrease in
vapour pressure and increase in boiling point.
hot
⁡⁡NaOH⁡⁡⁡
78.PbCrO4 → Na2 CrO4 + [Pb(OH)4 ]2−
yellow complex

The complex formed is [Pb(OH)4 ]2− which has coordination number = 4 and
complex is dianionic due to presence of (−2) charge.
79.Aq solution of ammonium carbonate is basic. The salt is made from weak acid
(H2 CO3 ) and weak base (NH4 OH), acidic or basic nature depends on value of K a
of weak acid and K b of weak base
If solution is basic
K b (weak base) > K a (weak acid)
Kaa (H2 CO3 ) = 4.3 × 10−7
K b (NH4 OH) = 1.8 × 10−5
K b > K a so solution is basic
Both statements are correct
80.
Acidic strength order
Bu–OH is aliphatic alcohol.

81.
(A) has 2 chiral carbons
Possible stereoisomers = (2)2 = 4
82.Comparing rate values in experiment 2 and 3
r3 0.02 x
=4=( )
r2 0.01
x=2
Order of reaction is 2
83.CH4 + 2O2 ⟶ CO2 + 2H2 O
22 1
Moles of CO2 = =
44 2
1
Moles of CH4 =
2
1
Mass of CH4 = × 16
2

= 8⁡gm
84.2H2 O ⟶ O2 + 4H + + 4e−
5.6
moles of O2 = = 0.25
22.4

moles of electrons = (0.25 × 4) = 1

Ag + + e− ⟶ Ag
moles of Ag = 1
mass of Ag = 108⁡gm
43
 1
85.Total (n2 ) electrons present with s = +
2
1
⇒ Total 16 electrons with n = 4 and s = +
2

86.Compound (A) is not aromatic due to presence of sp3 carbon between the rings.
87.CO and NO+ both are Isoelectronic to N2 i.e. both have 14 electrons.
Both have bond order equal to 3
Bond order of CO = 3 Bond order of NO+ = 3
Sum = 3 + 3 = 6
88.H2 SO3 , SOCl2 , SF4 have +4 oxidation state of sulphur.
89.W = −Pext (ΔV)
N
= −80 × 103 (45 − 30) × 10−3 m3
m2
= −80 × (15)N. m
= −1200 J
q + W = ΔE = 0
q = +1200 J
90.Meta directing groups:
–NO2
–CN
–COR
–COOH
Total 4 groups are meta directing groups.