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DECCAN INSTITUTE DECCAN INSTITUTE,TASGAON

Civil Hospital Road, Sangli

Test / Exam Name: Assignment -1 Standard: 12th Science Subject: Chemistry


Student Name: Section: Roll No.:
Questions: 15 Time: 01:00 hh:mm Marks: 33

Q1. Which of the following have least vapour pressure? 1 Mark


1. 0.1M NaCl sol
2. 0.1M urea sol
3. 0.1M AlCl3​sol
4. 0.1M KCl sol
Q2. What weight of glycerol should be added to 600g of water in order to lower its freezing point by 10°C? 1 Mark
1. 496g
2. 297g
3. 310g
4. 426g
Q3. The mass of a non - volatile non - electrolyte solute (molar mass = 50g mol−1) needed to be dissolved 1 Mark
in 114g octane to reduce its vapour pressure to 75% is:
1. 37.5g
2. 75g
3. 150g
4. 50g
Q4. At same temperature which pair of the following solutions are isotonic? 1 Mark
1. 0.2M BaCl2​ and 0.2M urea
2. 0.1M urea and 0.1M NaCl
3. 0.1M NaCl and 0.1M K2​SO4​
4. 0.1M Ba(NO3​)2​and 0.1M Na2​SO4​
Q5. An ideal binary solution is prepared by two liquids A and B, with P ∘
A
> P

B
. Then: 1 Mark
1. A - B interactions are stronger than A - A and B - B.
2. A and B have same molecular masses.
3. A - B interactions are similar to A - A and B - B interactions.
4. Both A and B are non - polar substances.
Q6. At a certain temperature, the vapour pressure of water is 50mm. The relative lowering of vapour 1 Mark
pressure of a solution containing 36g of glucose in 900g of water is:
1. 0.1
2. 0.5
3. 0.004
4. 3.75
Q7. A drop each of two non-corrosive and nonirritating liquids A and B at a temperature of 22oC are placed 1 Mark
on the skin. Liquid A gives a more cooling sensation than liquid B. Which of the following can be said
about the liquids A and B?
1. Liquid A has higher boiling point than that of liquid B
2. Liquid A has higher latent heat of vaporisation than that of liquid B
3. Liquid A has lower latent heat of vaporisation than that of liquid B
4. The boiling points of liquid A and B are equal
Q8. The relative lowering in vapour pressure is proportional to the ratio of number of : 1 Mark
1. Solute molecules to solvent molecules.
2. Solvent molecules to solute molecules.
3. Solute molecules to the total number of molecules to the total number of molecules in solution.
4. Solvent molecules to the total number of molecules in solution.
Q9. 100 mL of liquid A and 25 mL of liquid B are mixed to formal solution of volume 125 mL. Then the 1 Mark
solution is___________.
1. ideal
2. non-ideal with positive deviation
DECCAN INSTITUTE
3. non-ideal with negative deviation
4. cannot be predicted
Q10. In comparison to a 0.01M solution of glucose, the depression in freezing point of a 0.01M MgCl2 solution 1 Mark
is __________.
1. The same.
2. About twice.
3. About three times.
4. About six times.
Q11. Calculate the amount of KCl which must be added to 1 kg of water so that the freezing point is depressed 3 Marks
by 2K. (Kf for water = 1.86 K kg mol–1).
Q12. 19.5 g of CH2FCOOH is dissolved in 500 g of water. The depression in the freezing point of water observed 5 Marks
is 1.00 C. Calculate the van’t Hoff factor and dissociation constant of fluoroacetic acid.
Q13. Answer the following question: 5 Marks
What is the freezing point of 0.4 molal solution of acetic acid in benzene in which it dimerises to the
extent of 85%? Freezing point of benzene is 278.4K and its molar heat of fusion is 10.042kJ mol-1.
Q14. Calculate the depression in the freezing point of water when 10 g of CH3CH2CHClCOOH is added to 250 g 5 Marks
of water. Ka = 1.4 × 10–3, Kf = 1.86 K kg mol–1.
Q15. Answer the following question: 5 Marks
Calculate the molality of a sulphuric acid solution in which the mole fraction of water is 0.85.

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