Q1. Which of the following have least vapour pressure? 1 Mark
1. 0.1M NaCl sol 2. 0.1M urea sol 3. 0.1M AlCl3sol 4. 0.1M KCl sol Q2. What weight of glycerol should be added to 600g of water in order to lower its freezing point by 10°C? 1 Mark 1. 496g 2. 297g 3. 310g 4. 426g Q3. The mass of a non - volatile non - electrolyte solute (molar mass = 50g mol−1) needed to be dissolved 1 Mark in 114g octane to reduce its vapour pressure to 75% is: 1. 37.5g 2. 75g 3. 150g 4. 50g Q4. At same temperature which pair of the following solutions are isotonic? 1 Mark 1. 0.2M BaCl2 and 0.2M urea 2. 0.1M urea and 0.1M NaCl 3. 0.1M NaCl and 0.1M K2SO4 4. 0.1M Ba(NO3)2and 0.1M Na2SO4 Q5. An ideal binary solution is prepared by two liquids A and B, with P ∘ A > P ∘ B . Then: 1 Mark 1. A - B interactions are stronger than A - A and B - B. 2. A and B have same molecular masses. 3. A - B interactions are similar to A - A and B - B interactions. 4. Both A and B are non - polar substances. Q6. At a certain temperature, the vapour pressure of water is 50mm. The relative lowering of vapour 1 Mark pressure of a solution containing 36g of glucose in 900g of water is: 1. 0.1 2. 0.5 3. 0.004 4. 3.75 Q7. A drop each of two non-corrosive and nonirritating liquids A and B at a temperature of 22oC are placed 1 Mark on the skin. Liquid A gives a more cooling sensation than liquid B. Which of the following can be said about the liquids A and B? 1. Liquid A has higher boiling point than that of liquid B 2. Liquid A has higher latent heat of vaporisation than that of liquid B 3. Liquid A has lower latent heat of vaporisation than that of liquid B 4. The boiling points of liquid A and B are equal Q8. The relative lowering in vapour pressure is proportional to the ratio of number of : 1 Mark 1. Solute molecules to solvent molecules. 2. Solvent molecules to solute molecules. 3. Solute molecules to the total number of molecules to the total number of molecules in solution. 4. Solvent molecules to the total number of molecules in solution. Q9. 100 mL of liquid A and 25 mL of liquid B are mixed to formal solution of volume 125 mL. Then the 1 Mark solution is___________. 1. ideal 2. non-ideal with positive deviation DECCAN INSTITUTE 3. non-ideal with negative deviation 4. cannot be predicted Q10. In comparison to a 0.01M solution of glucose, the depression in freezing point of a 0.01M MgCl2 solution 1 Mark is __________. 1. The same. 2. About twice. 3. About three times. 4. About six times. Q11. Calculate the amount of KCl which must be added to 1 kg of water so that the freezing point is depressed 3 Marks by 2K. (Kf for water = 1.86 K kg mol–1). Q12. 19.5 g of CH2FCOOH is dissolved in 500 g of water. The depression in the freezing point of water observed 5 Marks is 1.00 C. Calculate the van’t Hoff factor and dissociation constant of fluoroacetic acid. Q13. Answer the following question: 5 Marks What is the freezing point of 0.4 molal solution of acetic acid in benzene in which it dimerises to the extent of 85%? Freezing point of benzene is 278.4K and its molar heat of fusion is 10.042kJ mol-1. Q14. Calculate the depression in the freezing point of water when 10 g of CH3CH2CHClCOOH is added to 250 g 5 Marks of water. Ka = 1.4 × 10–3, Kf = 1.86 K kg mol–1. Q15. Answer the following question: 5 Marks Calculate the molality of a sulphuric acid solution in which the mole fraction of water is 0.85.
DTU, Department of Energy Engineering S in (KJ/ (KG K) ) - V in (M 3/kg) - T in (ºC) M.J. Skovrup & H.J.H Knudsen. 19-09-04 Ref:R.Döring. Klima+Kälte Ingenieur Ki-Extra 5, 1978