MSDS Aceite Gear Box

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SAFETY DATA SHEET Synthetic Gearbox Oil

97315
85136283E

Date of issue : 10/16/2014.


Version : 1

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/


UNDERTAKING
1.1 Product identifier
Product name : Synthetic Gearbox Oil 97315 3
Product no. : 85136283E
1.2 Relevant identified uses of the substance or mixture and uses advised against
Product use : Transmission oil
1.3 Details of the supplier of the safety data sheet
Supplier : Volvo Parts Corporation Telephone no.: : +46-31-66 67 50
SE 405 08 Göteborg
Sweden
E-mail address : sds@volvo.com

1.4 Emergency telephone number


Emergency phone : +46-31-66 67 50 (during office
hours)
E-mail address : sds@volvo.com
www.volvo.com/sds

2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
Product definition : Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Not classified.
Classification according to Directive 1999/45/EC [DPD]
The product is not classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : Not classified.
Human health hazards : Not relevant
See section 11 for toxicological information and section 12 for ecotoxicological information.

See Section 16 for the full text of the R phrases or H statements declared above.
2.2 Label elements
Hazard pictograms :
Signal word : No signal word.
Hazard statements : No known significant effects or critical hazards.
Precautionary statements
Prevention : Not applicable.
Response : Not applicable.
Storage : Not applicable.
Disposal : -
Supplemental label : Contains Phosphoric acid ester, amine salt. May produce an allergic reaction. Safety data
elements sheet available on request. Keep out of reach of children. If ingested, do not induce vomiting.
Seek medical advice immediately. Minimise skin contact. Protect the environment. Dispose of
used oil at designated sites. Do not mix used oil with solvents, brake fluids or coolants.
2.3 Other hazards
Other hazards which do : Not available.
not result in classification

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Synthetic Gearbox Oil 97315 85136283E

3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/mixture : Mixture

Classification
Ingredient name Identifiers % 67/548/EEC Regulation (EC) No. Type
1272/2008 [CLP]
Europe
Phosphoric acid esters/ EC: 931-384-6 1-5 Xn; R22 Flam. Liq. 3, H226 [1]
amine salt Xi; R41 Acute Tox. 4, H302
R43 Eye Dam. 1, H318
N; R51/53 Skin Sens. 1, H317
Aquatic Chronic 2, H411
See Section 16 for the See Section 16 for the
full text of the R- full text of the H
phrases declared above. statements declared
above.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations
applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
Occupational exposure limits, if available, are listed in Section 8.

4. FIRST AID MEASURES


4.1 Description of first aid measures
Inhalation : If inhaled, remove to fresh air.
Skin contact : Wash contaminated skin with soap and water.
Eye contact : In case of contact with eyes, rinse immediately with plenty of water.
Ingestion : Get medical attention.
Protection of first-aiders : Refer to protective measures listed in sections 7 and 8. No action shall be taken involving any
personal risk or without suitable training.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Inhalation : This product is not likely to volatilise rapidly into the air because of its low vapour pressure.
Skin contact : Defatting to the skin.
Eye contact : May cause slight transient irritation.
Ingestion : Ingestion may cause gastrointestinal irritation and diarrhoea.
Over-exposure signs/symptoms
Inhalation : May cause slight transient irritation.
Skin contact : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.
Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low
levels.
Eye contact : May cause slight transient irritation. ( redness )
Ingestion : Ingestion may cause gastrointestinal irritation and diarrhoea.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed
person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
See Section 11 for more detailed information on health effects and symptoms.

5. FIRE-FIGHTING MEASURES
5.1 Extinguishing media
Suitable : Recommended:, alcohol-resistant foam, CO, powders
Not suitable : Do not use water jet.
5.2 Special hazards arising from the substance or mixture
Hazardous combustion : Decomposition products may include the following materials:
products nitrogen oxides
sulfur oxides
phosphorus oxides
carbon oxides
5.3 Advice for firefighters

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Synthetic Gearbox Oil 97315 85136283E

5. FIRE-FIGHTING MEASURES
Special precautions for : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire.
fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus
(SCBA) with a full face-piece operated in positive pressure mode.

6. ACCIDENTAL RELEASE MEASURES


6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency : Refer to protective measures listed in sections 7 and 8.
personnel
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section
8 on suitable and unsuitable materials. See also the information in "For non-emergency
personnel".
6.2 Environmental : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
precautions Inform the relevant authorities if the product has caused environmental pollution (sewers,
waterways, soil or air).
6.3 Methods and materials for containment and cleaning up
Spill : Stop leak if without risk. Contain and collect spillage with non-combustible, absorbent material e.g.
sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to
local regulations.
6.4 Reference to other : See Section 1 for emergency contact information.
sections See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

7. HANDLING AND STORAGE


7.1 Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Wash hands, forearms and
face thoroughly after handling chemical products, before eating, smoking and using the lavatory
and at the end of the working period. Wash contaminated clothing before reuse.
Advice on general : Wash hands, forearms and face thoroughly after handling chemical products, before eating,
occupational hygiene smoking and using the lavatory and at the end of the working period. Wash contaminated
clothing before reuse.
7.2 Conditions for safe : Do not store in unlabelled containers. Keep container tightly closed. Keep container in a cool,
storage, including any well-ventilated area.
incompatibilities
7.3 Specific end use(s)
Recommendations : Transmission oil
Industrial sector specific : Not available.
solutions

8. EXPOSURE CONTROLS/PERSONAL PROTECTION


8.1 Control parameters
Occupational exposure limits
Ingredient name Occupational exposure limits
No exposure limit value known.

Derived effect levels


No DELs available.

Predicted effect concentrations


No PECs available.

8.2 Exposure controls


Appropriate engineering : Use only with adequate ventilation. Where reasonably practicable, this should be achieved by the
controls use of local exhaust ventilation and good general extraction. If workers are exposed to
concentrations above the exposure limit, they must use appropriate, certified respirators.
Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating,
smoking and using the lavatory and at the end of the working period.
Personal protective equipment
Respiratory protection : Provide adequate ventilation.
Hand protection : For prolonged or repeated handling, use gloves : nitrile
Eye protection : Recommended: splash goggles
Environmental exposure : Do not allow to enter drains or watercourses.
controls

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Synthetic Gearbox Oil 97315 85136283E

9. PHYSICAL AND CHEMICAL PROPERTIES


9.1 Information on basic physical and chemical properties
Appearance
Physical state : Liquid.
Colour : Amber.
Odour : Hydrocarbon.
Odour threshold : Not available.
pH : Not available.
Melting point/freezing point : Not available.
Pour point : -39
Initial boiling point and : >316°C (>600.8°F)
boiling range
Flash point : Closed cup: 200°C (392°F)
Evaporation rate : Not available.
Flammability (solid, gas) : Flammable in the presence of the following materials or conditions: heat.
Burning time : Not applicable.
Burning rate : Not applicable.
Upper/lower flammability : Lower: 0.9%
or explosive limits Upper: 7%
Vapour pressure : <0.013 kPa (<0.1 mm Hg) [room temperature]
Vapour density : >2 [Air = 1]
Relative density : Not available.
Density : 0.85 g/cm³ [16°C (60.8°F)]
Solubility : Insoluble in the following materials: cold water and hot water.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition : Not available.
temperature
Viscosity : Kinematic (40°C (104°F)): 1.15 cm2/s (115 cSt)
Explosive properties : Not available.
Oxidising properties : Not available.
9.2 Other information
No additional information.

10. STABILITY AND REACTIVITY


10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.
10.2 Chemical stability : Stable under recommended storage and handling conditions (see Section 7).
10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions
10.4 Conditions to avoid : No specific data.
10.5 Incompatible materials : Reactive or incompatible with the following materials:
oxidizing materials, acids, peroxides
10.6 Hazardous : Decomposition products may include the following materials:
decomposition products nitrogen oxides
sulfur oxides
phosphorus oxides
carbon oxides

11. TOXICOLOGICAL INFORMATION


11.1 Information on toxicological effects
Potential acute health effects
Inhalation : This product is not likely to volatilise rapidly into the air because of its low vapour pressure.
Skin contact : Defatting to the skin.
Eye contact : May cause slight transient irritation.
Ingestion : Ingestion may cause gastrointestinal irritation and diarrhoea.
Over-exposure signs/symptoms
Inhalation : May cause slight transient irritation.
Skin contact : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.
Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low
levels.
Eye contact : May cause slight transient irritation. ( redness )
Ingestion : Ingestion may cause gastrointestinal irritation and diarrhoea.

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Synthetic Gearbox Oil 97315 85136283E

11. TOXICOLOGICAL INFORMATION


Relevant information for the mixture and/or the ingredients is presented below.

Acute toxicity
Product/ingredient name Result Species Dose Exposure
Phosphoric acid ester, amine LD50 Oral - 500 mg/kg -
salt
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Phosphoric acid ester, amine Eyes - Irritant - - - -
salt
Sensitiser
Product/ingredient name Route of Species Result
exposure
Phosphoric acid ester, amine skin - Sensitising
salt Specific concentration limits have been
considered.
Potential chronic health effects
General : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.
Test data on the allergenic components in the formulation or similar formulations shows that the
product is not considered to cause sensitizing effects. Once sensitized, a severe allergic reaction
may occur when subsequently exposed to very low levels.
Other information : Not available.

12. ECOLOGICAL INFORMATION


12.1 Toxicity
Environmental effects : Not readily biodegradable. This product shows a low bioaccumulation potential. This material
may cause long lasting harmful effects to aquatic life.
Product/ingredient name Species Exposure Result
Phosphoric acid ester, amine salt Fish 96 hours Acute LC50 1 to 10 mg/l

12.2 Persistence and degradability


Not available.

12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential


Product as-supplied - >3.5 low

12.4 Mobility in soil


Soil/water partition : Not available.
coefficient (KOC)
Mobility : Non water-soluble liquid
12.5 Results of PBT and vPvB assessment
PBT : Not applicable.
vPvB : Not applicable.
12.6 Other adverse effects : No known significant effects or critical hazards.

13. DISPOSAL CONSIDERATIONS


13.1 Waste treatment methods
Product
Methods of disposal : Waste must be disposed of in accordance with federal, state and local environmental control
regulations.
Hazardous waste : Yes.
European waste catalogue (EWC)
Waste code Waste designation
13 02 06* synthetic engine, gear and lubricating oils

Packaging
Methods of disposal : Waste packaging should be recycled. Incineration or landfill should only be considered when
recycling is not feasible.
Special precautions : This material and its container must be disposed of in a safe way. Empty containers or liners may
retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil,
waterways, drains and sewers.

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Synthetic Gearbox Oil 97315 85136283E

14. TRANSPORT INFORMATION


ADR/RID IMDG IATA
14.1 UN number Not regulated. Not regulated. Not regulated.

14.2 UN proper - - -
shipping name
14.3 Transport - - -
hazard class(es)

14.4 Packing group - - -


14.5 No. No. No.
Environmental
hazards
14.6 Special Transport within user’s Transport within user’s Transport within user’s
precautions for premises: always transport in premises: always transport in premises: always transport in
user closed containers that are upright closed containers that are upright closed containers that are upright
and secure. Ensure that persons and secure. Ensure that persons and secure. Ensure that persons
transporting the product know transporting the product know transporting the product know
what to do in the event of an what to do in the event of an what to do in the event of an
accident or spillage. accident or spillage. accident or spillage.

14.7 Transport in bulk : Not available.


according to Annex II of
MARPOL 73/78 and the IBC
Code

15. REGULATORY INFORMATION


15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorisation
Substances of very high concern
None of the components are listed.
Other EU regulations
Product use : Consumer applications, Industrial applications.

16. OTHER INFORMATION


Europe
Full text of abbreviated R : R22- Harmful if swallowed.
phrases R41- Risk of serious damage to eyes.
R43- May cause sensitisation by skin contact.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Full text of classifications : Xn - Harmful
[DSD/DPD] Xi - Irritant
N - Dangerous for the environment
Full text of abbreviated H : H226 Flammable liquid and vapour.
statements H302 Harmful if swallowed.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H411 Toxic to aquatic life with long lasting effects.

Full text of classifications : Acute Tox. 4, H302 ACUTE TOXICITY: ORAL - Category 4
[CLP/GHS] Aquatic Chronic 2, H411 AQUATIC TOXICITY (CHRONIC) - Category 2
Eye Dam. 1, H318 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
Flam. Liq. 3, H226 FLAMMABLE LIQUIDS - Category 3
Skin Sens. 1, H317 SKIN SENSITIZATION - Category 1

History
Date of issue / Date of : 10/16/2014.
revision
Version : 1
Conforms to 1907/2006/EC (REACH), Article 31

Indicates information that has changed from previously issued version.

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