REDOX
REDOX
REDOX
(Cantt Campus)
Subject: Chemistry (Redox Reactions) Class/Section: XC
Name: ___________________________ Total Marks: 30
A Mg + 2HCl → MgCl 2 + H2
A Acidified manganate(VII) ions change colour from colourless to purple when reduced.
8. Aqueous potassium iodide, KI(aq), can be used as a test reagent in redox reactions.
Iodide ions are readily ……X…… . A positive result for the test is when the solution changes
colour from
……Y…… to ……Z…… .
(i) Construct an ionic equation for the oxidation of iron( II) ions to iron(III) ions.
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(ii) Describe a chemical test that can be used to confirm that iron( II) ions have been oxidised
to form
iron( III) ions.
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(b) Aqueous hydrogen peroxide was added to acidified aqueous potassium manganate( VII).
The purple solution turned colourless. Aqueous hydrogen peroxide was added to acidified
aqueous potassium iodide. The colourless solution turned brown.
What deductions can you make about hydrogen peroxide from these two observations?
Explain your answer.
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(c) K2FeO4 can be prepared in the laboratory by the reaction between iron(III) oxide, Fe2O3, chlorine, Cl2,
and potassium hydroxide, KOH.
–
During the reaction chlorine molecules, Cl2, are converted into chloride ions, Cl . Is this conversion oxidation
or reduction? Explain your answer.
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3
(d) A few drops of aqueous K2FeO4 are added to a test-tube containing 3 cm of aqueous potassium iodide. The
solution in the test-tube changes from colourless to pale brown. Given this information, what can you deduce
about the chemical properties of K2FeO4?
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2. (a) When magnesium powder is added to aqueous iron(II) sulfate, the following reaction occurs.
2+ 2+
Mg(s) + Fe (aq) Mg (aq) + Fe(s)
(i) Explain, using electron transfer, why iron(II) ions are reduced in this reaction.
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(c) An acidified aqueous solution of X reacts with aqueous potassium iodide to form iodine.
State and explain what you can conclude about the chemical nature of X.
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(d) Iron(II) sulfate thermally decomposes to form iron(III) oxide, sulfur dioxide and sulfur trioxide.
(i) Explain how the equation shows that this reaction involves oxidation.
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3. (a) Copper reacts with chlorine to make copper(II) chloride.
Cu + Cl 2 CuCl 2
2+ –
Copper(II) chloride contains Cu and Cl ions.
Explain, in terms of the movement of electrons, how CuCl 2 is formed from copper atoms and chlorine
molecules.
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(b) Copper(II) iodide decomposes to make iodine and copper( I) iodide. The
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(iv) Aluminium can also be produced on a small scale by reacting aluminium oxide with magnesium.
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