Soltex-Hydrophobic-Fumed-Silica-FS2110D-SDS

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SOLTEX Hydrophobic Fumed Silica FS2110D

Safety Data Sheet


According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To Canada
Hazardous Products Regulations (SOR/2015-17).
Revision Date: 07/17/2019 Date of issue: 07/17/2019 Version: 1.0

SECTION 1: IDENTIFICATION
Product Identifier
Synonyms: Silicon Dioxide, Synthetic Amorphous Silica, Pyrogenic (Fumed) Amorphous Silica.
Product Name: SOLTEX FS2110D.
Intended Use of the Product Various, Rheological control, Flow agent, Thickening agent, Reinforcing agent in:
Coatings, Adhesives and/or sealants, Inks and Toners, Silicone Elastomer, Rubber products, Suspension,
Dispersion, Paints, Cosmetics, Hygiene and Sanitary products, Other.
Name, Address, and Telephone of the Responsible Party
Company
Soltex, Inc. (Synthetic Oils & Lubricants of Texas)
3707 FM 1960 W Ste. 560
Houston, TX 77068
(281)-587-0900
soltexinc.com
Emergency Telephone Number
Emergency Number : (800)-424-9300 (CHEMTREC); (281)-587-0900 (Other Safety Information)
SECTION 2: HAZARDS IDENTIFICATION
Classification of the Substance or Mixture
GHS-US/CA Classification : This chemical is not considered hazardous by the US 2012 OSHA Hazardous
Communication Standard (29 CFR 1910.1200)
Label Elements
GHS-US/CA Labeling
Hazard Pictograms (GHS-US/CA) : None.
Signal Word (GHS-US/CA) : None.
Hazard Statements (GHS-US/CA) : None.
Precautionary Statements (GHS-US/CA) : None.
Other Hazards : No other hazards known.
Potential health effects
Principle Routes of Exposure: Inhalation, Skin Contact, Eye contact
Eye Contact: May cause mechanical irritation. Avoid contact with eyes.
Skin Contact: May cause mechanical irritation and skin drying. Avoid contact with skin. No cases of
sensitization in humans have been reported.
Inhalation: Dust may be irritating to respiratory tract. Provide appropriate exhaust ventilation at
machinery and at places where dust can be generated. See also Section 8.
Ingestion: Adverse health effects are not expected. See Section 11.
Carcinogenicity: Does not contain any substances greater than 0.1% listed by IARC (International Agency
for Research on Cancer), NTP (National Toxicology Program), OSHA (Occupational Safety
and Health Administration), ACGIH (American Conference for Governmental Industrial
Hygienists) or EU (European Union). See also Section 11.
Target Organ Effects: Lungs, See Section 11
Medical Conditions Aggravated by Asthma, Respiratory disorder
Exposure:
Potential Environmental Effects: None known. See Section 12.
Hazards not otherwise classified (HNOC)
Do not expose to temperatures above 150°C. Hazardous products of combustion can include carbon monoxide and carbon
dioxide.

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Soltex Hydrophobic Fumed Silica FS2110D
Safety Data Sheet
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
Synonyms: Silicon Dioxide, Synthetic Amorphous Silica, Pyrogenic (Fumed) Amorphous
Silica Name: Soltex Hydrophobic Fumed Silica FS2110D.
Name Product Identifier Weight % GHS Ingredient Classification
Silane, dichlorodimethyl-, reaction products with silica (CAS No) 68611-44-9 100 Not Classified
SECTION 4: FIRST AID MEASURES
Description of First-aid Measures
Inhalation: If coughing, shortness of breath or other breathing problems occur, move to fresh air. Seek medical attention if symptoms
persist. If necessary, restore normal breathing through standard first aid measures.
Ingestion: Do not induce vomiting. If conscious, give several glasses of water. Never give anything by mouth to an unconscious
person.
Contact skin/eyes: Wash thoroughly with soap and water. Seek medical attention if symptoms develop. Flush eyes immediately with
large amounts of water for 15 minutes. Seek medical attention if symptoms develop.
Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in Section 2 and/or in Section 11
Indication of any immediate medical attention and special treatment needed
Note to physicians: Treat symptomatically.
SECTION 5: FIRE-FIGHTING MEASURES
Suitable Extinguishing Media: Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. Water. Dry chemical. Carbon dioxide (CO2). Foam.
Unsuitable Extinguishing Media: None.
Specific hazards arising from the
chemical: None.
Hazardous combustion products: Carbon monoxide (CO). Carbon dioxide (CO2).
Protective equipment and Wear suitable protective equipment. In the event of fire, wear self-contained breathing
Precautions for firefighters: apparatus.
Risk of Dust Explosion: Not Applicable.

SECTION 6: ACCIDENTAL RELEASE MEASURES


Personal precautions, protective equipment and emergency procedures
Personal precautions: Avoid dust formation. Ensure adequate ventilation. Use personal protective equipment.
See also Section 8.
For emergency responders: Use personal protection recommended in Section 8.
Environmental Precautions: Contain spilled product on land, if possible. Local authorities should be advised if
significant spillages cannot be contained.
Methods and material for containment and cleaning up
Methods for containment: Prevent further leakage or spillage if safe to do so.
Methods for cleaning up: Clean up promptly by vacuum. Use of a vacuum with high efficiency particulate air (HEPA)
filtration is recommended. Do not create a dust cloud by using a brush or compressed air. Pick
up and transfer to properly labelled containers. See Section 13.
SECTION 7: HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling: Avoid contact with skin and eyes. Avoid dust formation. Do not breathe dust. Provide
appropriate exhaust ventilation at machinery and at places where dust can be generated. Do
not create a dust cloud by using a brush or compressed air.
Take precautionary measures against static discharges. All metal parts of the mixing and
processing equipment must be earthed/grounded. Ensure all equipment is electrically earthed/
grounded before beginning transfer operations. Fine dust is capable of penetrating electrical
equipment and may cause electrical shorts.
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Soltex Hydrophobic Fumed Silica FS2110D
Safety Data Sheet
General hygiene considerations: Handle in accordance with good industrial hygiene and safety practice
Conditions for safe storage, including any incompatibilities
Storage Conditions: Keep containers tightly closed in a dry and well-ventilated place. Do not store together with
volatile chemicals as they may be adsorbed onto product. Store at ambient conditions. Keep in
properly labeled containers.
Incompatible materials: None known.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION


Exposure guidelines: The table below is a summary. Please see the specific legislation for complete
information.
Amorphous Silica, The regulatory Australia: 2 mg/m³, TWA, Respirable
exposure limits are found under the Austria MAK 4 mg/m³, TWA, Inhalable fraction
general silica, CAS RN 7631-86-9: Finland: 5 mg/m³
Germany TRGS 900: 4 mg/m³, TWA, Inhalable fraction
India: 10 mg/m³, TWA
Ireland: 2.4 mg/m³, TWA, Respirable dust
Norway: 1.5 mg/m³, TWA, Respirable dust
Switzerland: 4 mg/m³, TWA
UK WEL: 6 mg/m³, TWA, Inhalable fraction / 2.4 mg/m³, TWA, Respirable fraction
US OSHA PEL: 6mg/m³ (54 FR2701)
Dust, or Particulates Not Otherwise Belgium: 10 mg/m³, TWA, Inhalable / 3 mg/m³ TWA, Respirable
Specified: China: 8 mg/m³, TWA / 10 mg/m³, STEL
France: 10 mg/m³, TWA Inhalable dust / 5 mg/m³, TWA Respirable dust
Italy: 10 mg/m³, TWA, Inhalable / 3 mg/m³, TWA, Respirable
Malaysia: 10 mg/m³, TWA, Inhalable / 3 mg/m³, TWA, Respirable
Spain: 10 mg/m³, VLA, Inhalable / 3 mg/m³, VLA, Respirable
US ACGIH - PNOS: 10 mg/m³, TWA, Inhalable / 3 mg/m³, TWA, Respirable
US OSHA - PEL: 15 mg/m³, TWA, Total dust / 5 mg/m³, TWA, Respirable
MAK: Maximale Arbeitsplatzkonzentration (Maximum Workplace Concentration)
PEL: Permissible Exposure Limit
PNOS: Particulate Not Otherwise Specified
STEL: Short Term Exposure Limit
TRGS: Technische Regeln für Gefahrstoffe (Technical Rule for Hazardous Materials)
TWA: Time Weighted Average
US ACGIH: United States American Conference of Governmental Industrial Hygienists
US OSHA: United States Occupational Safety and Health Administration
VLA: Valore Límite Ambientales (Environmental Limit Value)
WEL: Workplace Exposure Limit
Engineering Controls: Ensure adequate ventilation to maintain exposures below occupational limits. Provide
appropriate local exhaust ventilation at machinery and at places where dust can be generated.
Personal protective equipment [PPE]
Respiratory Protection: Approved respirator may be necessary if local exhaust ventilation is not adequate.
Hand Protection: Wear protective gloves to prevent skin drying. Use protective barrier cream before handling
the product. Wash hands and other exposed skin with mild soap and water.
Eye/face Protection: Wear eye/face protection. Wear safety glasses with side shields (or goggles).
Skin and Body Protection: Wear suitable protective clothing. Wash clothing daily. Work clothing should not be
allowed out of the workplace.
Other: Handle in accordance with good industrial hygiene and safety practice. Emergency
eyewash and safety shower should be located nearby.
Environmental exposure controls: In accordance with all local legislation and permit requirements as applicable for dusts.

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Soltex Hydrophobic Fumed Silica FS2110D
Safety Data Sheet
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Information on Basic Physical and Chemical Properties
Physical State : Solid
Appearance : White powder
Odor : None
Odor Threshold : Not applicable
pH : 3.5-5.3
Evaporation Rate : Not applicable
Melting Point/Freezing Point : 1700°C (NIOSH Pocket Guide to Chemical Hazards)
Boiling Point/Boiling Range : 2230°C (NIOSH Pocket Guide to Chemical Hazards)
Flash Point : Not applicable
Auto-ignition Temperature : Unlikely to ignite
Minimum Ignition Temperature : >790°C (ASTM E-1491 Dust cloud)
Minimum Ignition Energy : >10 J (BS 5958 Part 1, 1991)
Ignition Energy : Not available
: Not flammable. Product resists ignition and does not promote flame spread.
Flammability (solid, gas) Not readily combustible (Class 4.1) according to EU Method A10
Lower Flammable Limit : Not available
Upper Flammable Limit : Not available
Vapor Pressure : Not applicable
Vapor Density : Not applicable
Density : Not available
Bulk Gravity : Not available
Specific Gravity at 20°C : Not available
Water Solubility : Slightly soluble (According to OECD 105)
Solubility(ies) : Not available
Partition Coefficient (N-Octanol/Water) : Not applicable
Decomposition Temperature : >400°C (Bulk Powder test- Diffusion cell)
Viscosity : Not applicable
Oxidizing Properties : No oxidizing properties
Softening Point : Not applicable
VOC Content (%) : Not applicable
Dust Explosion Classification : Not applicable
End point is listed "not applicable" due to the inherent properties of the substance
"Not available" indicates testing has not been performed
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable under recommended handling and storage conditions.
Stable up to 400° C. No exotherm (BulkPowder test - Diffusion cell).
Reactivity: Not reactive. Substance is an inert inorganic solid.
Possibility of hazardous reactions: None under normal processing.
Conditions to avoid: Do not expose to temperatures above 150°C. Keep away from heat and sources of ignition.
Avoid dust formation.
Hazardous polymerization: Hazardous polymerization does not occur.
Incompatible materials: None known.
Explosion data: Will not cause dust explosion.
Sensitivity to Mechanical Impact: None
Sensitivity of Static Discharge: This material is an inorganic dust and will not create nor support conditions that would result in a
dust explosion or fire. Take precautionary measures against static discharges. Avoid dust formation. All metal parts of the mixing
and processing equipment must be earthed/grounded. Ensure all equipment is electrically earthed/grounded before beginning
transfer operations.
Hazardous decomposition products: Carbon monoxide (CO). Carbon dioxide (CO2).
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Soltex Hydrophobic Fumed Silica FS2110D
Safety Data Sheet
SECTION 11: TOXICOLOGICAL INFORMATION
Information given is based on data obtained from this substance or from similar substances.
Acute toxicity
Oral LD50: LD50/oral/rat = > 5000 mg/kg. No deaths occurred and no signs of toxicity were seen during
the observation periods after single oral administration of the substance (OECD 423).
Inhalation LC50: Due to the product's physical characteristics, no suitable testing procedure is available.
Dermal LD50: No data is available on the product itself.
Skin corrosion/irritation: Primary irritation index = 0/8 @ 24 hr. Not classified as an irritant (OECD 404).
Serious eye damage/eye irritant: Not classified as an irritant in rabbit studies (OECD 405). High dust concentrations may cause
mechanical irritation.
Sensitization: No experimental animal data are available. No cases of sensitization in humans have been
reported.
Mutagenicity: Not mutagenic in Ames test. Negative in the chromosome aberration test in Chinese hamster
ovary (CHO) cells.
Carcinogenicity: No evidence of cancer in rats exposed for 24 months at 100 mg/kg/d (diet). (ECETOC JACC
Report 051 - Synthetic Amorphous Silica, September 2006).
Synthetic Amorphous Silica: No evidence of carcinogenicity was observed in multiple animal
species following repeated oral or inhalation exposure to amorphous silica. Similarly,
Reproductive and epidemiology studies show no evidence of carcinogenicity in workers who manufacture
amorphous silica.
Developmental Toxicity : No effects on reproductive organs have been reported in animal toxicity studies. No
developmental effects observed on progeny in dietary study (doses of 0 or 500 mg/kg/d).
(ECETOC JACC Report 051 - Synthetic Amorphous Silica, September 2006).

STOT - single exposure: Specific target organ toxicity is not expected after single oral, single inhalation, or single dermal
exposure.
STOT - repeated exposure: Repeated dose toxicity: oral (rat) , 5 to 8 weeks, no significant treatment-related adverse effects
at doses of up to 2000 mg/kg/d. (ECETOC JACC Report 051 - Synthetic Amorphous Silica,
September 2006).
Synthetic Amorphous Silica. Repeated dose toxicity: oral (rat), 2 weeks to 6 months, no significant
treatment-related adverse effects at doses of up to 8% silica in the diet. Repeated dose toxicity:
inhalation (rat), 13 weeks, Lowest Observed Effect Level (LOEL) = 1.3 mg/m3 based on mild
reversible effects in the lungs.
Repeated dose toxicity: inhalation (rat), 90 days, LOEL = 1 mg/m3 based on reversible effects in
the lungs and effects in the nasal cavity.
Based on available data, a STOT-RE classification is not warranted.

Aspiration Hazard: Based on industrial experience and available data, no aspiration hazard is expected.

SECTION 12: ECOLOGICAL INFORMATION


Information given is based on data from similar substances.

Pollutant potential:
Persistence and degradability: The methods for determining biodegradability are not applicable to inorganic substances.
Bioaccumulation: Not expected due to physicochemical properties of the substance.
Mobility: Not expected to migrate.
Distribution to Environmental
Compartments: Not available.

Other adverse effects: Not available.

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Soltex Hydrophobic Fumed Silica FS2110D
Safety Data Sheet
SECTION 13: DISPOSAL CONSIDERATIONS
Disclaimer: Information in this section pertains to the product as shipped in its intended composition as described in Section 3 of
this SDS. Contamination or processing may change waste characteristics and requirements. Regulations may also apply to empty
containers, liners or rinsate. State/provincial and local regulations may be different from federal regulations.

RCRA: Unused product is not a hazardous waste under U.S. RCRA, 40 CFR 261.

Unused and Uncontaminated


Product: Product, as supplied, should be disposed of in accordance with the regulations issued by the
appropriate federal, state and local authorities. Same consideration should be given to containers
and packaging.
SECTION 14: TRANSPORT INFORMATION
Not self-heating solids (Class 4.2). per UN Transporation of Dangerous Goods.
DOT
UN/ID no Not regulated
Proper Shipping Name Not regulated
Hazard Class Not regulated
Packing Group Not regulated
ICAO (air)
UN/ID no Not regulated
Proper Shipping Name Not regulated
Hazard Class Not regulated
Packing Group Not regulated
IATA
UN/ID no Not regulated
Proper Shipping Name Not regulated
Hazard Class Not regulated
Packing Group Not regulated
IMDG
UN/ID no Not regulated
Proper Shipping Name Not regulated
Hazard Class Not regulated
Packing Group Not regulated
RID
UN/ID no Not regulated
Proper Shipping Name Not regulated
Hazard Class Not regulated
Packing Group Not regulated
ADR
UN/ID no Not regulated
Proper Shipping Name Not regulated
Hazard Class Not regulated
Packing Group Not regulated
SECTION 15: REGULATORY INFORMATION
This chemical is not considered hazardous by the US 2012 OSHA Hazardous Communication Standard (29 CFR 1910.1200)
US Federal Regulations
TSCA Section 12(b) Export Regulations
This product does not contain any chemicals which require export notification under TSCA 12(b).
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Soltex Hydrophobic Fumed Silica FS2110D
Safety Data Sheet

SARA Section 302 (40 CFR 355) Extremely Hazardous Substances


No components are listed as extremely hazardous substances under SARA Section 302.
SARA 311/312 Hazard Categories
Acute Health Hazard No Sudden release of pressure hazard No
Chronic Health Hazard No Reactive Hazard No
Fire hazard No
See GHS classification in section 2 for applicable SARA 311/312 hazard categories under the revised 40 CFR 370 (June 13, 2016).
SARA Section 313 (40 CFR 372) Toxics Release Inventory
Does not contain any of the substances identified under Section 313 as toxic chemicals in excess of the de minimis
concentrations necessary to be subject to the supplier notification requirements.
Clean Air Act Amendments of 1990 (CAA, Section 112, 40 CFR 82)
This product does not contain any components listed as a Hazardous Air Pollutant, Flammable Substance, Toxic Substance, or
Class 1 or 2 Ozone Depletor
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42).
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material.
US State Regulations

California Proposition 65
This product does not contain any Proposition 65 chemicals.
US State Right-to-Know Regulations
Chemical name New Jersey Massachusetts Pennsylvania Louisiana:
Silica X X X -
7631-86-9

Canada - WHMIS Classification (HPR, SOR/2015-17)


See Section 2 for Hazard Classification. This chemical is not considered hazardous.
International Regulations
Listed on the EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on the Canadian DSL (Domestic Substances List)/NDSL (Non-Domestic Substances List)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on TCSI (Taiwan Chemical Substance Inventory)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on the United States TSCA (Toxic Substances Control Act) Section 8(b) inventory
SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION
Revision Date : 07/17/2019
Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA
Hazard Communication Standard 29 CFR 1910.1200 and Canada’s Hazardous Products Regulations (HPR).
References:
NIOSH Pocket Guide to Chemical Hazards, September 2005. "Silica, amorphous". DHHS (NIOSH) Publication No. 2005-149.
National Technical Information Service, Springfield, VA. p. 277
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and
environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.
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