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Aldehyde and Ketone

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Prabhleen Kaur
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6 views3 pages

Aldehyde and Ketone

Uploaded by

Prabhleen Kaur
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd
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S No SECTION A Marks

Iodoform test is not given by 1


a) ethanol
b) ethanal
1
c) pentan-2-one
d) pentan-3-one

Which of the following tests/ reactions is given by aldehydes as well as ketones? 1


a) Fehling’s test
b) Tollens’ test
2
c) 2,4-DNP test
d) Cannizzaro reaction

Which of the following will not give aldol condensation? 1


a) Benzaldehyde
b) Phenyl acetaldehyde
3
c) 2-Methylpentanal
d) 1-Phenylpropanone

The reaction of an aldehyde with hydroxylamine gives a product which is called 1


a) Aminohydroxide
b) Oximes
4
c) Cyanohydrin
d) Semicarbazones

Which one of the following reactions is a method for the conversion of ketone into 1
a hydrocarbon?
a) Aldol condensation
5 b) Riemer-Tiemann reaction
c) Cannizzaro reaction
d) Wolf-Kiishner reduction

SECTION B
What happens when propanone is treated with methyl magnesium iodide and 2
6
then hydrolysed?
7 Write structures of compounds A and B in the following reaction : 2
When Cyclohexanol reacts with CrO3 to give A which further reacts with NH2-NH-
CONH2 to give B?
8 Write chemical equations for the following reactions: 2
i) Acetophenone is treated with Zn(Hg)/Conc. HCl
ii) What is the composition of Fehling’s reagent ?
9 An organic compound ‘A’ having the molecular formula C3H8O on treatment with 2
Cu at 573 K, gives ‘B’. ‘B’ does not reduce Fehling’s solution but gives a yellow
precipitate of the compound ‘C’ with I2/NaOH.
Deduce the structures of A, B and C.
10 How can you convert the following : 2
a) Acetone to Propene
b) Ethanal to propanone

SECTION C
11 Write the chemical equations to illustrate the following name reactions : 3
(i) Rosenmund reduction
(ii) Aldol reaction
(b) Out of CH3CH2 -CO-CH2 -CH3 and CH3CH2 -CH2 -CO-CH3, which gives
iodoform test?
12 Account for the following : 3
i) There are two –NH2 groups in semicarbazide (H2NNHCONH2). However, only one
is involved in the formation of Semicarbazone.
ii) Presence of alpha hydrogen in aldehydes and ketones is essential for aldol
condensation.
iii) What is the composition of Fehling’s reagent ?
13 Explain the following reactions (any 3): 3
(a) Wolff–Kishner reduction
(b) Cannizzaro reaction
(c) Clemmensen reduction
d) Acetylation
14 Write the products formed when benzaldehyde reacts with the following 3
reagents
(i) CH3CHO in presence of dilute NaOH
(ii) H2N—OH in presence of weak acid
(iii) Tollens’ reagent
15 Write the structure of major product(s) in the 3
following:
i) C6H5-CO-CH3 + NaOH/I2 ?
ii) Cyclohexanone reacts with HCN?
iii) Acetone reacts with LiAlH4

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