SAFETY DATA SHEET

THE DOW CHEMICAL COMPANY

Product name: DOWSIL™ 795 Silicone Building Sealant Dusty Issue Date: 08/23/2019
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Print Date: 10/03/2019
THE DOW CHEMICAL COMPANY encourages and expects you to read and understand the entire
(M)SDS, as there is important information throughout the document. We expect you to follow the
precautions identified in this document unless your use conditions would necessitate other appropriate
methods or actions.

1. IDENTIFICATION
Product name: DOWSIL™ 795 Silicone Building Sealant Dusty Rose

Recommended use of the chemical and restrictions on use

Identified uses: Construction materials and additives

COMPANY IDENTIFICATION
THE DOW CHEMICAL COMPANY
2030 DOW CENTER
MIDLAND MI 48674-0000
UNITED STATES

Customer Information Number: 800-258-2436

SDSQuestion@dow.com

EMERGENCY TELEPHONE NUMBER

24-Hour Emergency Contact: CHEMTREC +1 800-424-9300
Local Emergency Contact: 800-424-9300

2. HAZARDS IDENTIFICATION
Hazard classification
GHS classification in accordance with 29 CFR 1910.1200
Not a hazardous substance or mixture.

Label elements

Precautionary statements
Prevention
Use only outdoors or in a well-ventilated area.

Other hazards
No data available

3. COMPOSITION/INFORMATION ON INGREDIENTS

® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated Page 1 of 12

company of Dow
Product name: DOWSIL™ 795 Silicone Building Sealant Dusty Issue Date: 08/23/2019
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Chemical nature: Silicone elastomer

This product is a mixture.
Component CASRN Concentration

Methanol 67-56-1 >= 0.18 - <= 0.19 %

4. FIRST AID MEASURES

Description of first aid measures
General advice:
If potential for exposure exists refer to Section 8 for specific personal protective equipment.

Inhalation: Move person to fresh air; if effects occur, consult a physician.

Skin contact: Wash off with plenty of water.

Eye contact: Flush eyes thoroughly with water for several minutes. Remove contact lenses after the
initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a
physician, preferably an ophthalmologist.

Ingestion: No emergency medical treatment necessary.

Most important symptoms and effects, both acute and delayed:

Aside from the information found under Description of first aid measures (above) and Indication of
immediate medical attention and special treatment needed (below), any additional important
symptoms and effects are described in Section 11: Toxicology Information.

Indication of any immediate medical attention and special treatment needed

Notes to physician: No specific antidote. Treatment of exposure should be directed at the control of
symptoms and the clinical condition of the patient.

5. FIREFIGHTING MEASURES
Extinguishing media

Suitable extinguishing media: Water spray. Alcohol-resistant foam. Carbon dioxide (CO2).
Dry chemical.

Unsuitable extinguishing media: None known..

Special hazards arising from the substance or mixture

Hazardous combustion products: Metal oxides. Formaldehyde. Carbon oxides. Silicon

oxides.

Unusual Fire and Explosion Hazards: Exposure to combustion products may be a hazard to
health..

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Advice for firefighters

Fire Fighting Procedures: Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment. Use water spray to cool unopened
containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate
area.

Special protective equipment for firefighters: Wear self-contained breathing apparatus for
firefighting if necessary.. Use personal protective equipment..

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures: Use personal protective
equipment. Follow safe handling advice and personal protective equipment recommendations.

Environmental precautions: Discharge into the environment must be avoided. Prevent further
leakage or spillage if safe to do so. Retain and dispose of contaminated wash water. Local
authorities should be advised if significant spillages cannot be contained.

Methods and materials for containment and cleaning up: Wipe up or scrape up and contain for
salvage or disposal. Local or national regulations may apply to releases and disposal of this material,
as well as those materials and items employed in the cleanup of releases. You will need to determine
which regulations are applicable. For large spills, provide dyking or other appropriate containment to
keep material from spreading. If dyked material can be pumped, Sections 13 and 15 of this SDS
provide information regarding certain local or national requirements.
See sections: 7, 8, 11, 12 and 13.

7. HANDLING AND STORAGE

Precautions for safe handling: Do not get on skin or clothing. Do not swallow. Avoid contact with
eyes. Take care to prevent spills, waste and minimize release to the environment. Handle in
accordance with good industrial hygiene and safety practice.
Use only with adequate ventilation. See Engineering measures under EXPOSURE
CONTROLS/PERSONAL PROTECTION section.

Conditions for safe storage: Keep in properly labelled containers. Store locked up. Store in
accordance with the particular national regulations.

Do not store with the following product types: Strong oxidizing agents.
Unsuitable materials for containers: None known.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
If exposure limits exist, they are listed below. If no exposure limits are displayed, then no values are
applicable.
Component Regulation Type of listing Value
Methanol ACGIH TWA 200 ppm
Further information: headache: Headache; nausea: Nausea; dizziness: Dizziness;

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eye dam: Eye damage; BEI: Substances for which there is a Biological Exposure
Index or Indices (see BEI® section); Skin: Danger of cutaneous absorption
ACGIH STEL 250 ppm
Further information: headache: Headache; nausea: Nausea; dizziness: Dizziness;
eye dam: Eye damage; BEI: Substances for which there is a Biological Exposure
Index or Indices (see BEI® section); Skin: Danger of cutaneous absorption
OSHA Z-1 TWA 260 mg/m3 200 ppm
Further information: (b): The value in mg/m3 is approximate.
OSHA P0 STEL 325 mg/m3 250 ppm
Further information: X: Skin notation
OSHA P0 TWA 260 mg/m3 200 ppm
Further information: X: Skin notation

Although some of the components of this product may have exposure guidelines, no exposure would
be expected under normal handling conditions due to the physical state of the material.

Biological occupational exposure limits

Components CAS-No. Control Biological Sampling Permissible Basis
parameters specimen time concentration
Methanol 67-56-1 Methanol Urine End of 15 mg/l ACGIH
shift (As BEI
soon as
possible
after
exposure
ceases)

Exposure controls
Engineering controls: Use local exhaust ventilation, or other engineering controls to maintain
airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure
limit requirements or guidelines, general ventilation should be sufficient for most operations. Local
exhaust ventilation may be necessary for some operations.

Individual protection measures

Eye/face protection: Use safety glasses (with side shields).
Skin protection
Hand protection: Use gloves chemically resistant to this material. Examples of preferred glove
barrier materials include: Butyl rubber. Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR"). Ethyl
vinyl alcohol laminate ("EVAL"). Polyvinyl alcohol ("PVA"). Polyvinyl chloride ("PVC" or "vinyl"). Viton.
Examples of acceptable glove barrier materials include: Natural rubber ("latex"). NOTICE: The
selection of a specific glove for a particular application and duration of use in a workplace should also
take into account all relevant workplace factors such as, but not limited to: Other chemicals which may
be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential
body reactions to glove materials, as well as the instructions/specifications provided by the glove
supplier.
Other protection: Use protective clothing chemically resistant to this material. Selection of specific
items such as face shield, boots, apron, or full body suit will depend on the task.
Respiratory protection: Respiratory protection should be worn when there is a potential to exceed
the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or
guidelines, wear respiratory protection when adverse effects, such as respiratory irritation or
discomfort have been experienced, or where indicated by your risk assessment process. For most
conditions, no respiratory protection should be needed; however, if handling at elevated temperatures
without sufficient ventilation, use an approved air-purifying respirator.

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The following should be effective types of air-purifying respirators: Organic vapor cartridge.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance
Physical state paste
Color pink
Odor alcohol-like
Odor Threshold No data available
pH Not applicable
Melting point/range No data available
Freezing point No data available
Boiling point (760 mmHg) Not applicable
Flash point Seta closed cup 91 °C ( 196 °F)
Evaporation Rate (Butyl Acetate Not applicable
= 1)
Flammability (solid, gas) Not classified as a flammability hazard
Lower explosion limit No data available
Upper explosion limit No data available
Vapor Pressure Not applicable
Relative Vapor Density (air = 1) No data available
Relative Density (water = 1) 1.53
Water solubility No data available
Partition coefficient: n- No data available
octanol/water
Auto-ignition temperature No data available
Decomposition temperature No data available
Dynamic Viscosity Not applicable
Kinematic Viscosity Not applicable
Explosive properties Not explosive
Oxidizing properties The substance or mixture is not classified as oxidizing.
Molecular weight No data available
Particle size No data available

NOTE: The physical data presented above are typical values and should not be construed as a
specification.

10. STABILITY AND REACTIVITY

Reactivity: Not classified as a reactivity hazard.

Chemical stability: Stable under normal conditions.

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Possibility of hazardous reactions: Can react with strong oxidizing agents. Vapours may form
explosive mixture with air.

Conditions to avoid: None known.

Incompatible materials: Oxidizing agents

Hazardous decomposition products:

Decomposition products can include and are not limited to: Formaldehyde. Benzene.

11. TOXICOLOGICAL INFORMATION

Toxicological information appears in this section when such data is available.

Acute toxicity
Acute oral toxicity
Very low toxicity if swallowed. Harmful effects not anticipated from swallowing small amounts.

As product: Single dose oral LD50 has not been determined.

Based on information for component(s):

LD50, Rat, > 5,000 mg/kg Estimated.

Acute dermal toxicity

Prolonged skin contact is unlikely to result in absorption of harmful amounts.

As product: The dermal LD50 has not been determined.

Based on information for component(s):

LD50, Rabbit, > 2,000 mg/kg Estimated.

Acute inhalation toxicity

No adverse effects are anticipated from inhalation. Vapor from heated material may cause
respiratory irritation.
As product: The LC50 has not been determined.

Skin corrosion/irritation
Based on information for component(s):
Brief contact is essentially nonirritating to skin.

Serious eye damage/eye irritation

Based on information for component(s):
May cause slight temporary eye irritation.
Corneal injury is unlikely.
May cause mild eye discomfort.

Sensitization
For the major component(s):
Did not cause allergic skin reactions when tested in guinea pigs.

For respiratory sensitization:

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No relevant data found.

Specific Target Organ Systemic Toxicity (Single Exposure)

Evaluation of available data suggests that this material is not an STOT-SE toxicant.

Specific Target Organ Systemic Toxicity (Repeated Exposure)

Based on available data for the component(s), repeated exposures are not anticipated to cause
significant adverse effects.

Contains an additional component(s) that is/are encapsulated in the product and are not expected to
be released under normal processing conditions or foreseeable emergency.

Carcinogenicity
For similar material(s): Did not cause cancer in long-term animal studies which used routes of
exposure considered relevant to industrial handling. Positive results have been reported in other
studies using routes of exposure not relevant to industrial handling.

Contains an additional component(s) that is/are encapsulated in the product and are not expected to
be released under normal processing conditions or foreseeable emergency.

Teratogenicity
Contains component(s) which did not cause birth defects or any other fetal effects in lab animals.

Reproductive toxicity
Contains component(s) which did not interfere with reproduction in animal studies.

Mutagenicity
Contains a component(s) which were negative in in vitro genetic toxicity studies. Contains
component(s) which were negative in animal genetic toxicity studies.

Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.

COMPONENTS INFLUENCING TOXICOLOGY:

Methanol
Acute inhalation toxicity
Easily attainable vapor concentrations may cause serious adverse effects, even death. At
lower concentrations: May cause respiratory irritation and central nervous system depression.
Symptoms may include headache, dizziness and drowsiness, progressing to incoordination
and unconsciousness. Inhalation of methanol may cause effects ranging from headache,
narcosis and visual impairment to metabolic acidosis, blindness, and even death. Effects may
be delayed.

LC50, Rat, 4 Hour, vapour, 3 mg/l

12. ECOLOGICAL INFORMATION

Ecotoxicological information appears in this section when such data is available.

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Toxicity

Methanol
Acute toxicity to fish
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
LC50, Bluegill sunfish (Lepomis macrochirus), flow-through test, 96 Hour, 15,400 mg/l

Acute toxicity to aquatic invertebrates

LC50, Daphnia magna (Water flea), 48 Hour, > 10,000 mg/l

Acute toxicity to algae/aquatic plants

ErC50, Pseudokirchneriella subcapitata (green algae), 96 Hour, Growth rate, 22,000 mg/l,
OECD Test Guideline 201 or Equivalent

Toxicity to bacteria
IC50, activated sludge, 3 Hour, Respiration rates., > 1,000 mg/l, OECD Test Guideline 209

Chronic toxicity to fish

NOEC, Oryzias latipes (Orange-red killifish), 200 Hour, 15,800 mg/l

Persistence and degradability

Methanol
Biodegradability: Material is readily biodegradable. Passes OECD test(s) for ready
biodegradability.

Theoretical Oxygen Demand: 1.50 mg/mg

Chemical Oxygen Demand: 1.49 mg/mg Dichromate

Biological oxygen demand (BOD)

Incubation BOD
Time
5d 72 %
20 d 79 %

Photodegradation
Test Type: Half-life (indirect photolysis)
Sensitization: OH radicals
Atmospheric half-life: 8 - 18 d
Method: Estimated.

Bioaccumulative potential

Methanol
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3).
Partition coefficient: n-octanol/water(log Pow): -0.77 Measured
Bioconcentration factor (BCF): < 10 Leuciscus idus (Golden orfe) Measured

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Mobility in soil

Methanol
Potential for mobility in soil is very high (Koc between 0 and 50).
Partition coefficient (Koc): 0.44 Estimated.

13. DISPOSAL CONSIDERATIONS

Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY
OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local
laws and regulations. Regulations may vary in different locations. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR
SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE
INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS
INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR
UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed,
permitted: Incinerator or other thermal destruction device. For additional information, refer to:
Handling & Storage Information, MSDS Section 7 Stability & Reactivity Information, MSDS Section10
Regulatory Information, MSDS Section 15

Treatment and disposal methods of used packaging: Empty containers should be recycled or
otherwise disposed of by an approved waste management facility. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. Do not re-use
containers for any purpose.

14. TRANSPORT INFORMATION

DOT
Not regulated for transport

Classification for SEA transport (IMO-IMDG):

Not regulated for transport
Transport in bulk Consult IMO regulations before transporting ocean bulk
according to Annex I or II
of MARPOL 73/78 and the
IBC or IGC Code

Classification for AIR transport (IATA/ICAO):

Not regulated for transport

This information is not intended to convey all specific regulatory or operational

requirements/information relating to this product. Transportation classifications may vary by container
volume and may be influenced by regional or country variations in regulations. Additional
transportation system information can be obtained through an authorized sales or customer service

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representative. It is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.

15. REGULATORY INFORMATION

Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Sections 311 and 312
No SARA Hazards

Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Section 313
The following components are subject to reporting levels established by SARA Title III, Section 313:
Components CASRN
Cobalt titanite green spinel 68186-85-6

Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA)

Section 103
Calculated RQ exceeds reasonably attainable upper limit.
Components CASRN RQ (RCRA Code)
Methanol 67-56-1 5000 lbs RQ
Methanol 67-56-1 100 lbs RQ (F003)
Toluene 108-88-3 1000 lbs RQ
Toluene 108-88-3 100 lbs RQ (F005)
Methanol 67-56-1 5000 lbs RQ
Methanol 67-56-1 100 lbs RQ (F003)

Pennsylvania Right To Know

The following chemicals are listed because of the additional requirements of Pennsylvania law:

Components CASRN
Calcium carbonate treated with stearic acid Not available
Polydimethylsiloxane hydroxy-terminated 70131-67-8
Siloxanes and silicones, dimethyl 63148-62-9
Silicon dioxide 7631-86-9
Cobalt titanite green spinel 68186-85-6
Aluminium 7429-90-5

California Prop. 65
WARNING: This product can expose you to chemicals including Cobalt titanite green spinel, which
is/are known to the State of California to cause cancer, and Methanol, Toluene, which is/are known to
the State of California to cause birth defects or other reproductive harm. For more information go to
www.P65Warnings.ca.gov.

United States TSCA Inventory (TSCA)

All components of this product are in compliance with the inventory listing requirements of the U.S.
Toxic Substances Control Act (TSCA) Chemical Substance Inventory.

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16. OTHER INFORMATION

Hazard Rating System

NFPA
Health Flammability Instability
0 1 0
HMIS
Physical
Health Flammability
Hazard
0/ 1 0

Revision
Identification Number: 3321355 / A001 / Issue Date: 08/23/2019 / Version: 7.0
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.

Legend
ACGIH USA. ACGIH Threshold Limit Values (TLV)
ACGIH BEI ACGIH - Biological Exposure Indices (BEI)
OSHA P0 USA. OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000
OSHA Z-1 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air
Contaminants
STEL Short-term exposure limit
TWA 8-hour, time-weighted average

Full text of other abbreviations

AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic
Substances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely
Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x%
growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP
- Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC - International
Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International
Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half
maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of
Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 -
Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population
(Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships;
MSHA - Mine Safety and Health Administration; n.o.s. - Not Otherwise Specified; NFPA - National Fire
Protection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No
Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National
Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for
Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution
Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of
Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA -
Resource Conservation and Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European

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Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA -
Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical
Substance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations;
UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very
Persistent and Very Bioaccumulative

Information Source and References

This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from
information supplied by internal references within our company.

THE DOW CHEMICAL COMPANY urges each customer or recipient of this (M)SDS to study it
carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and
understand the data contained in this (M)SDS and any hazards associated with the product. The
information herein is provided in good faith and believed to be accurate as of the effective date shown
above. However, no warranty, express or implied, is given. Regulatory requirements are subject to
change and may differ between various locations. It is the buyer's/user's responsibility to ensure that
his activities comply with all federal, state, provincial or local laws. The information presented here
pertains only to the product as shipped. Since conditions for use of the product are not under the
control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the
safe use of this product. Due to the proliferation of sources for information such as manufacturer-
specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other
than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the
(M)SDS you have is current, please contact us for the most current version.
US

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