SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

Z260

Version: 3.8 Revision Date: 30.05.2023 Print Date: 16.01.2024

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Trade name : Z260

1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the Sub- : Special lubricant
stance/Mixture

1.3 Details of the supplier of the safety data sheet

Company : HASCO Hasenclever GmbH+Co KG
Römerweg 4
D-58513 Lüdenscheid
Telephone : +49 (0) 23 51 - 95 70
Telefax : +49 (0) 23 51 - 95 72 37

Contact person product safety Abteilung Produktsicherheit

Telephone : +49(0)2351 9570
E-mail address : info@hasco.com

1.4 Emergency telephone number

Emergency telephone number : NHS (National Health Service), telephone: 111

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Not a hazardous substance or mixture.
2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

Not a hazardous substance or mixture.

Additional Labelling
EUH208 Contains Naphthenic acids, zinc salts, Polysulfides, di-tert-dodecyl. May pro-
duce an allergic reaction.

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumula-
tive and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or
higher.

SECTION 3: Composition/information on ingredients

3.2 Mixtures

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Z260

Version: 3.8 Revision Date: 30.05.2023 Print Date: 16.01.2024

Chemical nature : Lubricating grease based on polymers and extreme pressure

additive

Components
Chemical name CAS-No. Classification Concentration
EC-No. (% w/w)
Index-No.
Registration number
Zinc bis[O,O-bis(2-ethylhexyl)] 4259-15-8 >= 1 - < 2.5
bis(dithiophosphate) 224-235-5
01-2119493635-27 specific concentration
limit
Eye Dam. 1; H318
> 50 %

Naphthenic acids, zinc salts 12001-85-3 >= 0.25 - < 1

Polysulfides, di-tert-dodecyl 68425-15-0 >= 0.1 - < 1

270-335-7
01-2119540516-41
For explanation of abbreviations see section 16.

SECTION 4: First aid measures

4.1 Description of first aid measures

General advice : No special precautions required.
Call a physician if symptoms occur.

If inhaled : No special precautions required.

In case of skin contact : Wash contaminated clothing before re-use.

Wash off with soap and water.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes.
Seek medical advice.

If swallowed : If symptoms persist, call a physician.

4.2 Most important symptoms and effects, both acute and delayed
Symptoms : No information available.

Risks : No information available.

4.3 Indication of any immediate medical attention and special treatment needed
Treatment : Treat symptomatically.
For specialist advice physicians should contact the Poisons
Information Service.

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Z260

Version: 3.8 Revision Date: 30.05.2023 Print Date: 16.01.2024

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media : Alcohol-resistant foam
Carbon dioxide (CO2)
Dry powder
Water spray jet

Unsuitable extinguishing : High volume water jet

media

5.2 Special hazards arising from the substance or mixture

Specific hazards during fire- : Combustion may cause:
fighting Carbon dioxide (CO2)
Carbon monoxide
sulphur dioxide (toxic).

5.3 Advice for firefighters

Special protective equipment : Wear self-contained breathing apparatus for firefighting if nec-
for firefighters essary.

Further information : Use water spray to cool unopened containers.

Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Avoid contact with skin, eyes and clothing.
Refer to protective measures listed in sections 7 and 8.

6.2 Environmental precautions

Environmental precautions : Do not let product enter drains.
Inform the relevant authorities if it enters sewers, aquatic envi-
ronment or soil.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up : Use mechanical handling equipment.
Keep in suitable, closed containers for disposal.

6.4 Reference to other sections

Refer to protective measures listed in sections 7 and 8., For disposal considerations see section 13.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on safe handling : Avoid contact with skin and eyes.
Smoking, eating and drinking should be prohibited in the ap-
plication area.

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Z260

Version: 3.8 Revision Date: 30.05.2023 Print Date: 16.01.2024

For personal protection see section 8.

Advice on protection against : No special protective measures against fire required.

fire and explosion

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage : Follow the water regulations. Containers which are opened
areas and containers must be carefully resealed and kept upright to prevent leak-
age. Keep only in the original container in a cool, well-
ventilated place.

Further information on stor- : Keep away from heat. Protect from frost.
age conditions

Advice on common storage : not required

Recommended storage tem- : 0 - 40 °C

perature

7.3 Specific end use(s)

Specific use(s) : Special lubricant

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Contains no substances with occupational exposure limit values.
Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:
Substance name End Use Exposure routes Potential health ef- Value
fects
Zinc bis[O,O-bis(2- Workers Inhalation Long-term systemic 6.6 mg/m3
ethylhexyl)] effects
bis(dithiophosphate)
8.2 Exposure controls

Personal protective equipment

Eye/face protection : Safety glasses with side-shields conforming to EN166

Hand protection
Material : Chemical resistant gloves made of butyl rubber or nitrile rub-
ber category III according to EN 374.

Remarks : The choice of an appropriate glove does not only depend on

its material but also on other quality features and is different
from one producer to the other. The exact break through time
can be obtained from the protective glove producer and this
has to be observed.

Skin and body protection : Wear suitable protective clothing.

Respiratory protection : not required

Protective measures : No special protective equipment required.

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Z260

Version: 3.8 Revision Date: 30.05.2023 Print Date: 16.01.2024

Follow the skin protection plan.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state : paste

Colour : natural colour

Odour : neutral

Drop point : > 190 °C

Method: ISO 2176

Boiling point/boiling range : > 250 °C

Upper explosion limit / Upper : not determined

flammability limit

Lower explosion limit / Lower : not determined

flammability limit

Flash point : > 200 °C

Auto-ignition temperature : not determined

pH : Not applicable

Viscosity
Viscosity, kinematic : ca. 800 mm²/s (40 °C)
Method: DIN 51562

Solubility(ies)
Water solubility : immiscible to little miscible

Partition coefficient: n- : not determined

octanol/water

Vapour pressure : not determined

Density : 0.94 g/cm³ (20 °C)

Method: DIN 51757

Relative vapour density : not determined

9.2 Other information

Explosives : no explosion risk

Flammability (liquids) : Combustible liquids

Substances and mixtures, : No data available

which in contact with water,
emit flammable gases

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Z260

Version: 3.8 Revision Date: 30.05.2023 Print Date: 16.01.2024

SECTION 10: Stability and reactivity

10.1 Reactivity
No decomposition if stored and applied as directed.
10.2 Chemical stability
The product is chemically stable.
10.3 Possibility of hazardous reactions
Hazardous reactions : No dangerous reaction known under conditions of normal use.

10.4 Conditions to avoid

Conditions to avoid : Product is stable under appropriate usage.

10.5 Incompatible materials

Materials to avoid : Strong acids and oxidizing agents

10.6 Hazardous decomposition products

No decomposition if stored and applied as directed.
In case of fire hazardous decomposition products may be produced such as:
Carbon monoxide
Carbon dioxide (CO2)
Smoke
Nitrogen oxides (NOx)
sulphur dioxide (toxic).

SECTION 11: Toxicological information

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008

Acute toxicity

Product:
Acute oral toxicity : Remarks: No data available

Acute inhalation toxicity : Remarks: No data available

Acute dermal toxicity : Remarks: No data available

Acute toxicity (other routes of :

administration) Remarks: No data available

Components:

Zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate):

Acute oral toxicity : LD50 (Rat):

Skin corrosion/irritation

Product:
Remarks : Repeated or prolonged contact with the mixture may cause

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Z260

Version: 3.8 Revision Date: 30.05.2023 Print Date: 16.01.2024

removal of natural fat from the skin resulting in desiccation of

the skin.

Serious eye damage/eye irritation

Product:
Species : Rabbit
Exposure time : 72 h
Test substance : Zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate); CAS:
4259-15-8
Remarks : This substance is not a skin irritant, is an eye irritant at 100%,
but not an eye irritant at a 50% concentration.

Respiratory or skin sensitisation

Product:
Remarks : May produce an allergic reaction.

Germ cell mutagenicity

Components:

Polysulfides, di-tert-dodecyl:
Genotoxicity in vitro : Test Type: Chromosome aberration test in vitro
Test system: Human lymphocytes
Result: negative

Carcinogenicity

Product:
Carcinogenicity - Assess- : Not classifiable as a human carcinogen.
ment

11.2 Information on other hazards

Further information

Product:
Remarks : Health injuries are not known or expected under normal use.

SECTION 12: Ecological information

12.1 Toxicity

Components:

Zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate):

Toxicity to fish : LC50 : 1 - 10 mg/l

Toxicity to daphnia and other : EC50 (Daphnia (water flea)): 1 - 10 mg/l

aquatic invertebrates

Polysulfides, di-tert-dodecyl:

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Z260

Version: 3.8 Revision Date: 30.05.2023 Print Date: 16.01.2024

Toxicity to fish : LC50 (Brachydanio rerio (Zebra danio)): > 100 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203

Toxicity to daphnia and other : NOEC (Daphnia (water flea)): < 0.1 mg/l
aquatic invertebrates Exposure time: 48 h
Test Type: Immobilization
Method: Directive 67/548/EEC, Annex V, C.2.

Toxicity to algae/aquatic : NOEC (Pseudokirchneriella subcapitata (green algae)): < 0.08

plants mg/l
Exposure time: 72 h
Test Type: Growth inhibition
Method: OECD Test Guideline 201

Toxicity to microorganisms : (Pseudomonas putida): 10,000 mg/l

Exposure time: 16 h
Test Type: Growth inhibition

12.2 Persistence and degradability

Product:
Biodegradability : Remarks: No data available

12.3 Bioaccumulative potential

Product:
Bioaccumulation : Remarks: No data available

Components:

Polysulfides, di-tert-dodecyl:
Partition coefficient: n- : log Pow: > 6.2 (22 °C)
octanol/water Method: OECD Test Guideline 117

12.4 Mobility in soil

Product:
Mobility : Remarks: No data available

Components:

Polysulfides, di-tert-dodecyl:
Distribution among environ- : Medium: Soil
mental compartments Remarks: immobile

12.5 Results of PBT and vPvB assessment

Product:
Assessment : This substance/mixture contains no components considered
to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher.

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Z260

Version: 3.8 Revision Date: 30.05.2023 Print Date: 16.01.2024

12.6 Endocrine disrupting properties

No data available
12.7 Other adverse effects

Product:
Additional ecological infor- : Do not flush into surface water or sanitary sewer system.
mation

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Product : Do not let product enter drains.
Do not dispose of with domestic refuse.
Waste codes should be assigned by the user, preferably in
discussion with the waste disposal authorities.

Contaminated packaging : Dispose of in accordance with local regulations.

Waste Code : Waste codes should be assigned by the user, preferably in

discussion with the waste disposal authorities.

SECTION 14: Transport information

14.1 UN number or ID number

ADR : Not regulated as a dangerous good

RID : Not regulated as a dangerous good
IMDG : Not regulated as a dangerous good
IATA_P : Not regulated as a dangerous good
14.2 UN proper shipping name

ADR : Not regulated as a dangerous good

RID : Not regulated as a dangerous good
IMDG : Not regulated as a dangerous good
IATA_P : Not regulated as a dangerous good
14.3 Transport hazard class(es)

ADR : Not regulated as a dangerous good

RID : Not regulated as a dangerous good
IMDG : Not regulated as a dangerous good
IATA_P : Not regulated as a dangerous good
14.4 Packing group

ADR : Not regulated as a dangerous good

RID : Not regulated as a dangerous good

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Z260

Version: 3.8 Revision Date: 30.05.2023 Print Date: 16.01.2024

IMDG : Not regulated as a dangerous good

IATA (Cargo) : Not regulated as a dangerous good
IATA_P (Passenger) : Not regulated as a dangerous good
14.5 Environmental hazards
Not regulated as a dangerous good
14.6 Special precautions for user
Not applicable
14.7 Maritime transport in bulk according to IMO instruments
Not applicable for product as supplied.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mix-
ture
UK REACH List of substances subject to authorisation : Not applicable
(Annex XIV)

UK REACH Candidate list of substances of very high : Not applicable

concern (SVHC) for Authorisation

The Persistent Organic Pollutants Regulations (retained : Not applicable

Regulation (EU) 2019/1021 as amended for Great Brit-
ain)

Other regulations:

15.2 Chemical safety assessment

A Chemical Safety Assessment is not required for this substance.

SECTION 16: Other information

Full text of other abbreviations

ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways; ADR - Agreement concerning the International Carriage of Dangerous Goods by
Road; AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Test-
ing of Materials; bw - Body weight; CLP - Classification Labelling Packaging Regulation; Regula-
tion (EC) No 1272/2008; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard
of the German Institute for Standardisation; DSL - Domestic Substances List (Canada); ECHA -
European Chemicals Agency; EC-Number - European Community number; ECx - Concentration
associated with x% response; ELx - Loading rate associated with x% response; EmS - Emergen-
cy Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration as-
sociated with x% growth rate response; GHS - Globally Harmonized System; GLP - Good La-
boratory Practice; IARC - International Agency for Research on Cancer; IATA - International Air
Transport Association; IBC - International Code for the Construction and Equipment of Ships car-
rying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - Interna-
tional Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China;
IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL
- Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization;

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Z260

Version: 3.8 Revision Date: 30.05.2023 Print Date: 16.01.2024

KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test popula-
tion; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - Interna-
tional Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified;
NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Ef-
fect Level; NOELR - No Observable Effect Loading Rate; NZIoC - New Zealand Inventory of
Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office
of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic sub-
stance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quanti-
tative) Structure Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the European
Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Re-
striction of Chemicals; RID - Regulations concerning the International Carriage of Dangerous
Goods by Rail; SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet;
SVHC - Substance of Very High Concern; TCSI - Taiwan Chemical Substance Inventory; TECI -
Thailand Existing Chemicals Inventory; TRGS - Technical Rule for Hazardous Substances; TSCA
- Toxic Substances Control Act (United States); UN - United Nations; vPvB - Very Persistent and
Very Bioaccumulative

Further information
Other information : The information provided is based on our current knowledge
and experience and apply to the product as delivered. Re-
garding the product properties, these are not guaranteed. The
delivery of this safety datasheet does not free the recipient of
the product from his own responsibility to follow the relevant
rules and regulations concerning this product.
This safety datasheet complies with the requirements of
Regulation (EC) No. 1907/2006.

GB / EN

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