JEE MAIN_PART TEST - 02_WORKSHEET-01

BEWARE OF NEGATIVE MARKING

PART-2 : CHEMISTRY
SECTION-I : (Maximum Marks: 240)
1. For the reaction
A(s) + 2B(g) C(g) + 3D(g), which of the following relation is incorrect?
(A) Kp = Kc(RT)1 (B) Kp = Kc(RT)2
3
(C) Kp (D) [C]eq [D]eq.
log − 2 log RT = 0 Kc =
Kc [B]2eq.
2. For the reaction
A(s) + 2B(g) C(g) + 3D(g), which of the following relation is incorrect ?
(A) Kp = Kc(RT)1 (B) Kp = Kc(RT)2
3
(C) Kp (D) [C]eq [D]eq.
log − 2 log RT = 0 Kc =
Kc [B]2eq.
3. In which of the following equilibrium reactions, the equilibrium would shift to right side, if total
pressure is decreased :-
(A) N2(g) + 3H2(g) ⇌ 2NH3(g) (B) N2(g) + I2 (g) ⇌ 2HI(g)
(C) N2O4 (g) ⇌ 2NO(g) (D) N2 (g) + O2(g) ⇌ 2NO(g)
4. In an equilibrium reaction for which Δ ng = 0, the equilibrium on increasing the pressure
(A) will shift forward (B) does not have any effect
(C) will shift backward (D) will decrease the equilibrium constant
5. On decreasing temperature of following system at equilibrium CO2 (s) ⇌ CO2 (g), Δ H = +ve :-
(A) There is no effect on the equilibrium state (B) More CO2 gas is formed
(C) More solid CO2 is obtained (D) None of above
6. For the following reactions, equilibrium constants are given :
S(s) + O2(g) ⇌ SO2 (g); K1 = 1052 … (1)
129
2S(s) + 3O2 (g) ⇌ 2SO3 (g); K2 = 10 … (2)
The equilibrium constant for the reaction,
2SO2 (g) + O2 (g) ⇌ 2SO3(g) K … (3)
is :
(A) 10181 (B) 10154 (C) 1025 (D) 1077
7. 1
For the reaction SO2(g) + O2(g) ⇌ SO3(g), if Kp = KC (RT)x where the symbols have usual meaning
2
then the value of x is : (assuming ideality)
(A) 1 (B) 1 (C) – 1 (D) − 1
2 2
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8. One mole of O2(g) and two moles of SO2(g) were heated in a closed vessel of one litre capacity at 1098 K.
At equilibrium 1.6 moles of SO3(g) were found. The equilibrium constant KC of the reaction would be :-
(A) 60 (B) 80 (C) 30 (D) 40
9. 56g of nitrogen and 8g of hydrogen gas are heated in a closed vessel. At equilibrium 34 g of ammonia
are present. The equilibrium number of moles of nitrogen, hydrogen and ammonia respectively are
(A) 1, 2, 2 (B) 2, 2, 1 (C) 1, 1, 2 (D) 2, 1, 2
10. Given the solubility product of F3 B2 is 2 × 10−30 . What will be the solubility in moles/litre.
(B) 1/5 (C) 1/5
(A) 1/5 2 × 10−30 10−28 (D) All
( 1.85 × 10−32 ) ( ) ( )
108 5400
11. K1 and K2 are the rate constants of forward and backward reactions. The equilibrium constant K of the
reaction is -
(A) K1 × K2 (B) K1 – K2 (C) K1 (D) K1 + K2
K2 K1 − K2
12. For the equilibrium2NO2 (g) ⇌ N2 O4 (g) + 14.6 kcal the increase in temperature would
(A) Favour the formation of N2O4 (B) Favour the decomposition of N2O4
(C) Not alter the equilibrium (D) Stop the reaction
13. Which of the following is a characteristic of a reversible reaction ?
(A) It never proceeds to completion
(B) It can be completed in finite time
(C) It proceeds only in the forward di0rection
(D) Number of moles of reactants and products are equal
14. The dissociation of CO2 can be expressed as 2CO2(g) ⇌ 2CO(g) + O2(g). If the 2 moles of CO2 is taken
initially and 40% of the CO2 is dissociated completely. What is the total number of moles at equilibrium:
(A) 2.4 (B) 2.0 (C) 1.2 (D) 5
15. x ⇌ y reaction is said to be in equilibrium, when :-
(A) Only 10% conversion of x to y takes place
(B) Complete conversion of x to y has taken place
(C) Conversion of x to y is only 50% complete
(D) The rate of change of x to y is just equal to the rate of change of y to x in the system
16. For the following three reactions, equilibrium constants are given
(1) CO(g) + H2O(g) CO2(g) + H2(g); K1
(2) CH4(g) + H2O(g) CO(g) + 3H2(g); K2
(3) CH4(g) + 2H2O(g) CO2(g) + 4H2(g); K3
Which of the following relations is correct ?
(A) K1 K2 = K3
√ (B) K2K3 = K1 (C) K3 = K1K2 (D) K3 = K23 K12
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17. In a chemical equilibrium, the rate constant for the backward reaction is 7.5 × 10 –4 and the equilibrium
constant is 1.5. The rate constant for the forward reaction is:-
(A) 2 × 10 –3 (B) 5 × 10 –4 (C) 1.125 × 10 –3 (D) 9.0 × 10 –4
18. In what manner will increase of pressure effect the following equilibrium?
C(s) + H2O(g) ⇌ CO(g) + H2(g)
(A) Shift in forward direction (B) Shift in reverse direction
(C) Increase in yield of hydrogen (D) No effect
19. Concentration v/s time curve for equilibrium can be like :
[rf = forward rate, rb = backward rate]
(B)
(A)

(C)

(D) All of these

20. The equilibrium constant for a reaction A + B C + D is 1 × 10 –2 at 298 K and is 2 at 273 K. The
⇌

chemical process resulting in the formation of C and D is :

(A) exothermic (B) endothermic
(C) unpredictable (D) there is no relationship between Δ H and K
21. Resonance is not possible in :
(A) (B) (D)
(C) CH2=CH – Cl

22. Among the following, the most stable carbocation is

(B) (C) (D)
(A) +

CH3 − CH − CH3

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23. Hyperconjugation :
Which is the correct stability order of following alkenes in the increasing order ?

(I) CH3 – CH=CH – CH3 (II) (III) (IV)

(A) I < III < IV < II (B) I < II < III < IV (C) I < IV < III < I (D) II < III < IV < I
24. Most stable resonating structure is :
(A) (B) (C) (D)

25. Select correct order regarding acidic strength of given compounds :

(1) o-methylbenzoic acid (2) m-methylbenzoic acid (3) p-methylbenzoic acid (4) benzoic
acid
(A) 1 > 2 > 3 > 4 (B) 4 > 3 > 2 > 1 (C) 1 > 4 > 2 > 3 (D) 3 > 2 > 4 > 1
26. Which of the following is weakest acid?
(A) (B)
(C)
(D)

27. The most stable carbocation among the following :

(D)
(A) (B) (C)

28. Which is the decreasing order of stability

+

(i) CH3 − C H − CH3

+

(ii) CH3 − C H − O − CH3

+

(iii) CH3 − C H − CO − CH3

(A) (i) > (iii) > (ii) (B) (i) > (ii) > (iii) (C) (iii) > (ii) > (i) (D) (ii) > (i) > (iii)
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29. Arrange the following carbocation in the increasing order of stability :

(A) I < II < III (B) II < III < I (C) III < II < I (D) III < I < II
30. Resonance energy will be maximum from the following :
(A) (B) (C)
(D)

31.

If number of resonating structure for P1 and P2 are X & Y respectively. Then (Y – X) has value.
(A) 6 (B) 4 (C) 3 (D) Zero
32. The number of α -Hydrogen in toluene is
(A) 0 (B) 1 (C) 2 (D) 3
33. Which of the following pairs are resonating structures?

(A) I (B) II (C) III (D) IV

34. Which one of the following compounds is most acidic:-
(A) (B) (C)
(D) ClCH2CH2OH

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35. Among the following most stable carbanion is
(D)
(A) (B) (C)

36. Hybridisation of nitrogen is :

(A) sp (B) sp2 (C) sp3 (D) sp3d

37. Which of the following is correct about inductive effect :
(A) It is observed in σ -bond as well as in π -bond
(B) Shared electron of σ -bond in which inductive effect is observed, do not leave their
overlapping orbital.
(C) It increases with distance.
(D) It is temporary effect.
38. Which of the following in lers stable than propene
(A) ethene (B) Butene (C) Pentene (D) But-2-ene
39. Which of the following is not acceptable as resonating structure :
(A) (B) (C)
(D) None of these

40. Which of the following group does not have – I effect?

(A) – NH2 (B) – NO2 (C) (D) – CH3
41. The ratio of wave length of photon corresponding to the α -line of Lyman series in H-atom and β -line of
Balmer series in He+ is
(A) 1 : 1 (B) 1 : 2 (C) 1 : 4 (D) 3 : 16
42. Find the wavelength of 2nd line of Balmer series of Li2+. [Given : RH = Rydberg constant]
(A) 16RH (B) 16 (C) 27RH (D) 16
27 9RH 16 27RH
43. The incorrect relationship for de-Broglie's principle is -
(A) λ = h (B) λ = h (C) λ = p (D) λ = h
p √
2m × k. e. h √ 2m × Q × V
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44. Difference in wavelength of two extreme lines of H-atom in Balmer region is:
(Where RH is Rydberg constant)
(A) 7.2 / RH (B) 0.25 / RH (C) 4 / RH (D) 3.2 / RH
45. Iodine molecules dissociates into atoms after absorbing light of wavelength 4500Å. If one quantum of
radiation is absrobed by each molecule what will be the approx. K.E. of iodine atom
[Given B.E. of I2 = 240 kJ/mol], [NA = 6 × 1023]
(A) 8.6 × 10 –36 J (B) 2.17 × 10 –20 J (C) 433 kJ (D) 4.3 J
46. Find the wavelength of 2nd line of Balmer series of Li2+. [Given : RH = Rydberg constant]
(A) 16RH (B) 16 (C) 27RH (D) 16
27 9RH 16 27RH
47. In a Bohr’s model of atom when an electron jumps from n = 1 to n = 3, how much energy will be emitted
or absorbed. (Z × 1)
(A) 2.15 × 10 –11 erg (B) 0.1911 × 10 –10 erg
(C) 2.389 × 10 –12 erg (D) 0.239 × 10 –10 erg
48. The number of waves made by a bohr electron in an orbit of maximum quantum number +2 is
(A) 3 (B) 4 (C) 2 (D) 1
49. Which state of Be3+ has the same orbit radius as that of the ground state of hydrogen atom?
(A) 3 (B) 2 (C) 4 (D) 5
50. Choose the incorrect characteristic of cathode rays among given :
(A) Cathode rays travel in straight line.
(B) They are made of negative charged particles.
(C) Charge to mass ratio is not constant.
(D) They produce x-rays when strike against heavy metal.
51. Neutrons are discovered by bombarding of α partides on which metal
(A) Boron (B) Berrylium (C) Lithium (D) Cesium
52. Orbit angular momentum of electron in 2nd orbit of H – atom will be:
(A) h (B) h (C) h (D) h
4π 2π 3π π
53. Which of the following statement is correct ?
(A) Number of angular nodes = n – ℓ – 1 (B) Number of radial nodes = ℓ
(C) Total number of nodes = n – 1 (D) All of these
54. Which of the following series belongs to visible region of H atom ?
(A) Balmer (B) Lyman (C) Paschen (D) Pfund
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55. Which d-orbital has different shape from other d-orbital?
(A) dxy (B) dzx (C) dz 2 (D) dx2 −y 2
56. Which of the following equations was suggested by de Broglie ?
(A) 2 π r = n λ (B) λ = P (C) π r2 = n λ (D) 2 π r = nh
h λ
57. What is the electronic configuration of Fe+3 ion in its ground state?
(A) [Ar]3d5 (B) [Ar]3d6 (C) [Ar]4s23d5 (D) [Ar]4s23d6
58. The plots of radial distribution functions for various orbitals of hydrogen atom against 'r' are given
below:

(A) (B)

(C) (D)

The correct plot for 3s orbital is:

(A) B (B) A (C) D (D) C
59. Uncertainty in position of a particle of 25 g in space is 10 –15 m. Hence, uncertainty in velocity (ms –1)
is:
(Planck’s constant, h = 6.63 × 10 –34 Js)
(A) 2.1 × 10 –28 (B) 2.1 × 10 –34 (C) 0.5 × 10 –34 (D) 5.0 × 10 –24
60. Magnetic moment of X3+ ion of 3d series is 2 √ 6 BM. What is the atomic number of X?
(A) 24 (B) 26 (C) 25 (D) 28
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SECTION-II : (Maximum Marks: 15)
1.
initial concentration of A is equal to that of B. The equilibrium concentration of A and C are equal.
KC of the reaction will be
2. For the reversible reaction A(g) + B(s) ⇌ 2C(g),
Kp
= (RT)x. Hence x is :
Kc
3. One mole of A reacts with one mole of B to form 0.1 mole of C and 0.1 mole of D. The value of the
1
equilibrium constant is :
x2
A+B C+D ⇌

4. Calculate kp for the reaction

A(g) ⇌ B(s) + 2C(g)
where kc = 0.2 at 305 k.
5. 5 litre vessel contains 2 moles of each gases A and B at equilibrium. If one mole each of A and B are
removed. Calculate KC for the reaction.
A(g) ⇌ B(g)
6. Number of hyperconjugation structure of following carbocation involving C – H bonds

7. How many of the following groups have + I effect :

(a) – OH (b) – O⊝ (c) – NH2
Θ
(d) − N H (e) – COOH (f) – COO⊝
(g) – Me (h) – OMe (i) – F
⊕
(j) − N F3
8. In how many of the following cases, the negative charge is delocalised?

(i) (ii) (iii) (iv)

(v) (vi) (vii) (viii)

(ix) (x)

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9. How many of the following species can show resonance.

CH2 = CH – Cl , CH2 = CH – CH2 – Cl,

10. How many number of all structurally isomeric dienes with molecular formula C5H8 are possible:
11. Number of spectral lines when e – jumps from 3rd shell to 1st shell in a sample of atoms.
12. Find out the number of angular nodes in the orbital to which the last electron of Cr enter.
13. A metal surface is exposed to 500 nm radiation. The threshold frequency of the metal for photoelectric
current is 4.3 × 1014 Hz. The velocity of ejected electron is ________× 105 ms-1(Nearest integer)
[Use : h = 6.63 × 10 –34 Js, me = 9.0 × 10 –31 kg]
14. Hydrogen atoms are excited to n = 4 state. In the spectrum of emitted radiations, the number of lines in
the ultraviolet and visible regions are in the ratio of x : 2 respectively, then x is :
15. Sum of the azimuthal quantum number for the following subshell is

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