30-40-DOC4-PR-4001 rev0

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SULFUR REMOVAL UNIT

Ilam Petrochemical Complex


National Petrochemical Co.
C5+ Cut Hydrotreatment Unit: Doc. No. : 30-40-DOC4-PR-4001
Axens Job no : 07-3091 Material Balances Rev. no. : 0
Doc no : 40-1CP/1WP/1MP Sheet no. : 1 / 68

C5+ Cut Hydrotreatment Unit :


Material Balances

0 04-04-2008 IFD Process Book Issue M.Inrad G. Zarbo G. Zarbo


C 22-02-2008 IFA With PFD review comments M. Inrad G. Zarbo G. Zarbo
B 17-01-2008 IFR First Issue M. Inrad G. Zarbo G. Zarbo
A 02-01-2008 PI Preliminary Issue M. Inrad G. Zarbo G. Zarbo
Rev Date Status Description PRE'D CHK'D APR'D
SULFUR REMOVAL UNIT
Ilam Petrochemical Complex
National Petrochemical Co.
C5+ Cut Hydrotreatment Unit: Doc. No. : 30-40-DOC4-PR-4001
Axens Job no : 07-3091 Material Balances Rev. no. : 0
Doc no : 40-1CP/1WP/1MP Sheet no. : 2 / 68

Revision Index
Rev. A B C 0 1 2 3 4 Rev. A B C 0 1 2 3 4
Sheet Sheet
1 x x x x 41 x x x x
2 x x x x 42 x x x x
3 x x x x 43 x x x x
4 x x x x 44 x x x x
5 x x x x 45 x x x x
6 x x x x 46 x x x x
7 x x x x 47 x x x x
8 x x x x 48 x x x x
9 x x x x 49 x x x x
10 x x x x 50 x x x x
11 x x x x 51 x x x x
12 x x x x 52 x x x x
13 x x x x 53 x x x x
14 x x x x 54 x x x x
15 x x x x 55 x x x x
16 x x x x 56 x x x x
17 x x x x 57 x x x x
18 x x x x 58 x x x x
19 x x x x 59 x x x x
20 x x x x 60 x x x x
21 x x x x 61 x x
22 x x x x 62 x x
23 x x x x 63 x x
24 x x x x 64 x x
25 x x x x 65 x x
26 x x x x 66 x x
27 x x x x 67 x x
28 x x x x 68 x x
29 x x x x 69 x
30 x x x x 70
31 x x x x 71
32 x x x x 72
33 x x x x 73
34 x x x x 74
35 x x x x 75
36 x x x x 76
37 x x x x 77
38 x x x x 78
39 x x x x 79
40 x x x x 80
SULFUR REMOVAL UNIT
Ilam Petrochemical Complex
National Petrochemical Co.
C5+ Cut Hydrotreatment Unit: Doc. No. : 30-40-DOC4-PR-4001
Axens Job no : 07-3091 Material Balances Rev. no. : 0
Doc no : 40-1CP/1WP/1MP Sheet no. : 3 / 68

Table of Contents

Subjects Sheet No

Cover sheet………………………………..……………….………………………….. …….. 1


Revision index…………………………………………..…………………………………… 2
Table of contents ……………………………………………………………………………. 3
1. Component properties table – ALL CASES ………………..…………………………… 4
2. Weight percent material balance table - SUMMER CASE SOR………………………. 5
3. Weight percent material balance table - SUMMER CASE EOR………………………. 13
4. Weight percent material balance table - WINTER CASE SOR………………………... 21
5. Weight percent material balance table - WINTER CASE EOR………………………... 29
6. Molar fraction material balance table - SUMMER CASE SOR………………………... 37
7. Molar fraction material balance table - SUMMER CASE EOR……………………….. 45
8. Molar fraction material balance table - WINTER CASE SOR………………………… 53
9. Molar fraction material balance table - WINTER CASE EOR………………………… 61
COMPONENT PROPERTIES
Job Number Unit Type Page
Process licensing 07-3091 40 1CP 4/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : ALL CASES 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIN GZA 0

Component Molecular Weight Density * Normal Boiling Point


kg/kmol kg/m3 °C
H2O 18.01 998.6 100
H2 2.02 69.93 -253
N2 28.01 807.3 -196
H2S 34.08 789.3 -60
METHANE 16.04 299.7 -161
ETHANE 30.07 356.0 -89
PROPANE 44.10 507.2 -42
IBUTANE 58.12 562.5 -12
BUTANE 58.12 583.8 -1
IPENTANE 72.15 622.1 28
PENTANE 72.15 630.4 36
HEXANE 86.18 663.3 69
2MPENTAN 86.18 657.3 60
CYCLOHEXANE 84.16 782.7 81
HEPTANE 100.21 687.5 98
2-MHEXANE 100.21 682.4 90
CYCLOHEPTANE 98.19 814.9 119
TOLUENE 92.14 871.0 111
OCTANE 114.23 706.1 126
2-MHEPTANE 114.23 701.4 118
CYCLOOCTANE 112.22 839.6 151
EBENZENE 106.17 871.0 136
1OCTENE 112.22 718.5 121
NONANE 128.26 721.0 151
2-MOCTANE 128.26 716.8 143
CYCLONONANE 126.24 853.6 178
N-PBENZENE 120.20 865.6 159
1NONENE 126.24 733.2 147
DECANE 142.29 733.5 174
2-MNONANE 142.28 730.0 167
CYCLODECANE 140.27 860.7 202
N-BBENZENE 134.22 863.5 183
1DECENE 140.27 744.1 171
NC11 156.31 743.6 196
N-PENTYLE-BZ 148.25 861.9 205
1-UNDECENE 154.30 754.0 193
NC12 170.34 751.9 216
M-MERCAPTAN 48.10 873.3 6
E-MERCAPTAN 62.13 824.5 35
2C3MERCAPTAN 76.16 815.6 53
1PENTANTHIOL 104.21 845.7 127
1HEXANETHIOL 118.24 846.1 153
COS 60.07 1 006 -50
DMS 62.13 853.1 37
MESD 76.16 841.5 67
DMDS 94.19 1 067 110
B-SULPHIDE 146.29 847.8 199

* Liquid density at 15°C or 60°F


REF: INRAD 4 13:19:45 AIO_1.5 P7.1 30-40-DOC4-PR-4001 rev0.doc
MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 5/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE SOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

C5+ FEED FEED TO REACTION H2 MAKE-UP RECYCLE GAS


Flow rate unit : wt % SECTION
1 2 3 4
H2O
H2 95.06 16.94
N2 2.66 0.19
H2S 9.02
METHANE 2.28 27.08
ETHANE 0.43
PROPANE 0.58 0.58 6.16
IBUTANE 1.50 1.50 6.94
BUTANE 3.53 3.53 12.39
IPENTANE 3.74 3.74 5.77
PENTANE 4.04 4.04 4.92
HEXANE 5.04 5.04 2.26
2MPENTAN 5.80 5.80 3.40
CYCLOHEXANE 0.17 0.17 0.06
HEPTANE 5.12 5.12 0.86
2-MHEXANE 5.71 5.71 1.27
CYCLOHEPTANE 3.77 3.77 0.35
TOLUENE 1.87 1.87 0.29
OCTANE 3.96 3.96 0.26
2-MHEPTANE 5.75 5.75 0.51
CYCLOOCTANE 5.75 5.75 0.16
EBENZENE 2.71 2.71 0.19
1OCTENE 0.01 0.01
NONANE 2.84 2.84 0.08
2-MOCTANE 4.01 4.01 0.14
CYCLONONANE 3.41 3.41 0.03
N-PBENZENE 3.02 3.02 0.09
1NONENE 0.03 0.03
DECANE 2.66 2.66 0.03
2-MNONANE 3.60 3.60 0.05
CYCLODECANE 0.94 0.94 0.01
N-BBENZENE 2.62 2.62 0.03
1DECENE 0.02 0.02
NC11 3.39 3.39 0.02
N-PENTYLE-BZ 2.75 2.75 0.02
1-UNDECENE 0.03 0.03
NC12 10.70 10.70 0.03
M-MERCAPTAN 0.36 0.36
E-MERCAPTAN 0.03 0.03
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL 0.28 0.28
COS
DMS 0.23 0.23 0.02
MESD
DMDS 0.02 0.02
B-SULPHIDE 0.02 0.02

Total kg/h 52 360 52 360 34 2 628


Total kmol/h 501.40 501.40 15.89 291.92

REF: INRAD 22/02/08 13:06:14 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 6/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE SOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

REACTOR FEED HEATER INLET REACTOR INLET REACTOR OUTLET


Flow rate unit : wt % EFFLUENT EXCHANGER
INLET
5 6 7 8
H2O
H2 0.81 0.81 0.81 0.77
N2 0.01 0.01 0.01 0.01
H2S 0.43 0.43 0.43 0.89
METHANE 1.29 1.29 1.29 1.52
ETHANE 0.02 0.02 0.02 0.03
PROPANE 0.85 0.85 0.85 0.85
IBUTANE 1.76 1.76 1.76 1.76
BUTANE 3.95 3.95 3.95 3.96
IPENTANE 3.83 3.83 3.83 3.83
PENTANE 4.08 4.08 4.08 4.08
HEXANE 4.90 4.90 4.90 5.10
2MPENTAN 5.69 5.69 5.69 5.69
CYCLOHEXANE 0.16 0.16 0.16 0.16
HEPTANE 4.91 4.91 4.91 4.91
2-MHEXANE 5.49 5.49 5.49 5.49
CYCLOHEPTANE 3.61 3.61 3.61 3.61
TOLUENE 1.79 1.79 1.79 1.79
OCTANE 3.78 3.78 3.78 3.79
2-MHEPTANE 5.50 5.50 5.50 5.50
CYCLOOCTANE 5.49 5.49 5.49 5.49
EBENZENE 2.59 2.59 2.59 2.59
1OCTENE 0.01 0.01 0.01
NONANE 2.70 2.70 2.70 2.73
2-MOCTANE 3.83 3.83 3.83 3.83
CYCLONONANE 3.25 3.25 3.25 3.25
N-PBENZENE 2.88 2.88 2.88 2.88
1NONENE 0.03 0.03 0.03
DECANE 2.54 2.54 2.54 2.56
2-MNONANE 3.44 3.44 3.44 3.44
CYCLODECANE 0.89 0.89 0.89 0.89
N-BBENZENE 2.49 2.49 2.49 2.49
1DECENE 0.02 0.02 0.02
NC11 3.23 3.23 3.23 3.25
N-PENTYLE-BZ 2.62 2.62 2.62 2.62
1-UNDECENE 0.02 0.02 0.02
NC12 10.19 10.19 10.19 10.19
M-MERCAPTAN 0.34 0.34 0.34
E-MERCAPTAN 0.03 0.03 0.03
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL 0.27 0.27 0.27
COS
DMS 0.22 0.22 0.22 0.02
MESD
DMDS 0.02 0.02 0.02
B-SULPHIDE 0.01 0.01 0.01

Total kg/h 54 988 54 988 54 988 54 988


Total kmol/h 793.32 793.32 793.32 792.97

REF: INRAD 22/02/08 13:06:14 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 7/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE SOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

REACTOR FEED REACTOR EFFLUENT REACTOR EFFLUENT SEPARATOR VAPOR


Flow rate unit : wt % EFFLUENT EXCHANGER AIR COOLER INLET AIR COOLER OUTLET OUTLET
OUTLET
9 10 11 12
H2O
H2 0.77 0.77 0.77 15.93
N2 0.01 0.01 0.01 0.16
H2S 0.89 0.89 0.89 9.13
METHANE 1.52 1.52 1.52 27.40
ETHANE 0.03 0.03 0.03 0.44
PROPANE 0.85 0.85 0.85 6.24
IBUTANE 1.76 1.76 1.76 7.03
BUTANE 3.96 3.96 3.96 12.55
IPENTANE 3.83 3.83 3.83 5.85
PENTANE 4.08 4.08 4.08 4.98
HEXANE 5.10 5.10 5.10 2.29
2MPENTAN 5.69 5.69 5.69 3.44
CYCLOHEXANE 0.16 0.16 0.16 0.06
HEPTANE 4.91 4.91 4.91 0.87
2-MHEXANE 5.49 5.49 5.49 1.29
CYCLOHEPTANE 3.61 3.61 3.61 0.35
TOLUENE 1.79 1.79 1.79 0.30
OCTANE 3.79 3.79 3.79 0.26
2-MHEPTANE 5.50 5.50 5.50 0.51
CYCLOOCTANE 5.49 5.49 5.49 0.16
EBENZENE 2.59 2.59 2.59 0.19
1OCTENE
NONANE 2.73 2.73 2.73 0.08
2-MOCTANE 3.83 3.83 3.83 0.15
CYCLONONANE 3.25 3.25 3.25 0.03
N-PBENZENE 2.88 2.88 2.88 0.09
1NONENE
DECANE 2.56 2.56 2.56 0.03
2-MNONANE 3.44 3.44 3.44 0.06
CYCLODECANE 0.89 0.89 0.89 0.01
N-BBENZENE 2.49 2.49 2.49 0.03
1DECENE
NC11 3.25 3.25 3.25 0.02
N-PENTYLE-BZ 2.62 2.62 2.62 0.02
1-UNDECENE
NC12 10.19 10.19 10.19 0.03
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.02 0.02 0.02 0.02
MESD
DMDS
B-SULPHIDE

Total kg/h 54 988 54 988 54 988 2 595


Total kmol/h 792.97 792.97 792.97 276.03

REF: INRAD 22/02/08 13:06:14 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 8/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE SOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

RECYCLE COMPRESSOR RECYCLE COMPRESSOR REACTED C5+CUT TO STRIPPER FEED


Flow rate unit : wt % SUCTION DISCHARGE STRIPPER
13 14 15 16
H2O
H2 15.93 15.93 0.02 0.02
N2 0.16 0.16
H2S 9.13 9.13 0.48 0.48
METHANE 27.40 27.40 0.24 0.24
ETHANE 0.44 0.44 0.01 0.01
PROPANE 6.24 6.24 0.58 0.58
IBUTANE 7.03 7.03 1.50 1.50
BUTANE 12.55 12.55 3.54 3.54
IPENTANE 5.85 5.85 3.73 3.73
PENTANE 4.98 4.98 4.04 4.04
HEXANE 2.29 2.29 5.24 5.24
2MPENTAN 3.44 3.44 5.80 5.80
CYCLOHEXANE 0.06 0.06 0.17 0.17
HEPTANE 0.87 0.87 5.11 5.11
2-MHEXANE 1.29 1.29 5.70 5.70
CYCLOHEPTANE 0.35 0.35 3.77 3.77
TOLUENE 0.30 0.30 1.87 1.87
OCTANE 0.26 0.26 3.96 3.96
2-MHEPTANE 0.51 0.51 5.75 5.75
CYCLOOCTANE 0.16 0.16 5.75 5.75
EBENZENE 0.19 0.19 2.71 2.71
1OCTENE
NONANE 0.08 0.08 2.86 2.86
2-MOCTANE 0.15 0.15 4.01 4.01
CYCLONONANE 0.03 0.03 3.41 3.41
N-PBENZENE 0.09 0.09 3.02 3.02
1NONENE
DECANE 0.03 0.03 2.68 2.68
2-MNONANE 0.06 0.06 3.60 3.60
CYCLODECANE 0.01 0.01 0.94 0.94
N-BBENZENE 0.03 0.03 2.61 2.61
1DECENE
NC11 0.02 0.02 3.41 3.41
N-PENTYLE-BZ 0.02 0.02 2.75 2.75
1-UNDECENE
NC12 0.03 0.03 10.70 10.70
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.02 0.02 0.02 0.02
MESD
DMDS
B-SULPHIDE

Total kg/h 2 595 2 595 52 393 52 393


Total kmol/h 276.03 276.03 516.94 516.94

REF: INRAD 22/02/08 13:06:14 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 9/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE SOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

STRIPPER AIR C5+ CUT AIR TRIM CONDENSER PURGED GAS


Flow rate unit : wt % CONDENSER INLET CONDENSER OUTLET OUTLET
17 18 19 20
H2O
H2 0.09 0.09 0.09 0.60
N2 0.01 0.01 0.01 0.04
H2S 3.81 3.81 3.81 12.53
METHANE 1.06 1.06 1.06 6.15
ETHANE 0.10 0.10 0.10 0.37
PROPANE 8.39 8.39 8.39 15.01
IBUTANE 31.75 31.75 31.75 28.93
BUTANE 49.23 49.23 49.23 34.64
IPENTANE 3.50 3.50 3.50 1.21
PENTANE 1.74 1.74 1.74 0.47
HEXANE 0.08 0.08 0.08 0.01
2MPENTAN 0.20 0.20 0.20 0.03
CYCLOHEXANE
HEPTANE
2-MHEXANE 0.01 0.01 0.01
CYCLOHEPTANE
TOLUENE
OCTANE
2-MHEPTANE
CYCLOOCTANE
EBENZENE
1OCTENE
NONANE
2-MOCTANE
CYCLONONANE
N-PBENZENE
1NONENE
DECANE
2-MNONANE
CYCLODECANE
N-BBENZENE
1DECENE
NC11
N-PENTYLE-BZ
1-UNDECENE
NC12
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.03 0.03 0.03 0.01
MESD
DMDS
B-SULPHIDE

Total kg/h 14 781 14 781 14 781 2 023


Total kmol/h 278.55 278.55 278.55 51.02

REF: INRAD 22/02/08 13:06:14 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 10/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE SOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

STRIPPER REFLUX STRIPPER BOTTOM STRIPPER REBOILER STRIPPER FIRE HEATER


Flow rate unit : wt % PUMPS INLET INLET
21 22 23 24
H2O
H2
N2
H2S 2.43
METHANE 0.26
ETHANE 0.06
PROPANE 7.34
IBUTANE 32.19 0.40 0.40 0.40
BUTANE 51.54 2.29 2.29 2.29
IPENTANE 3.86 3.84 3.84 3.84
PENTANE 1.95 4.18 4.18 4.18
HEXANE 0.09 5.45 5.45 5.45
2MPENTAN 0.22 6.03 6.03 6.03
CYCLOHEXANE 0.17 0.17 0.17
HEPTANE 5.32 5.32 5.32
2-MHEXANE 0.01 5.93 5.93 5.93
CYCLOHEPTANE 3.92 3.92 3.92
TOLUENE 1.94 1.94 1.94
OCTANE 4.12 4.12 4.12
2-MHEPTANE 5.98 5.98 5.98
CYCLOOCTANE 5.98 5.98 5.98
EBENZENE 2.82 2.82 2.82
1OCTENE
NONANE 2.98 2.98 2.98
2-MOCTANE 4.17 4.17 4.17
CYCLONONANE 3.54 3.54 3.54
N-PBENZENE 3.14 3.14 3.14
1NONENE
DECANE 2.79 2.79 2.79
2-MNONANE 3.75 3.75 3.75
CYCLODECANE 0.97 0.97 0.97
N-BBENZENE 2.72 2.72 2.72
1DECENE
NC11 3.55 3.55 3.55
N-PENTYLE-BZ 2.86 2.86 2.86
1-UNDECENE
NC12 11.13 11.13 11.13
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.03 0.02 0.02 0.02
MESD
DMDS
B-SULPHIDE

Total kg/h 12 758 98 557 48 187 48 187


Total kmol/h 227.53 911.63 445.72 445.72

REF: INRAD 22/02/08 13:06:14 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 11/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE SOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

STRIPPER FIRE HEATER STRIPPER TUBE SIDE STRIPPER TUBE SIDE STRIPPER AIR COOLER
Flow rate unit : wt % OUTLET EXCHANGERS INLET EXCHANGERS OUTLET OUTLET
25 26 27 28
H2O
H2
N2
H2S
METHANE
ETHANE
PROPANE
IBUTANE 0.40 0.40 0.40 0.40
BUTANE 2.29 2.29 2.29 2.29
IPENTANE 3.84 3.84 3.84 3.84
PENTANE 4.18 4.18 4.18 4.18
HEXANE 5.45 5.45 5.45 5.45
2MPENTAN 6.03 6.03 6.03 6.03
CYCLOHEXANE 0.17 0.17 0.17 0.17
HEPTANE 5.32 5.32 5.32 5.32
2-MHEXANE 5.93 5.93 5.93 5.93
CYCLOHEPTANE 3.92 3.92 3.92 3.92
TOLUENE 1.94 1.94 1.94 1.94
OCTANE 4.12 4.12 4.12 4.12
2-MHEPTANE 5.98 5.98 5.98 5.98
CYCLOOCTANE 5.98 5.98 5.98 5.98
EBENZENE 2.82 2.82 2.82 2.82
1OCTENE
NONANE 2.98 2.98 2.98 2.98
2-MOCTANE 4.17 4.17 4.17 4.17
CYCLONONANE 3.54 3.54 3.54 3.54
N-PBENZENE 3.14 3.14 3.14 3.14
1NONENE
DECANE 2.79 2.79 2.79 2.79
2-MNONANE 3.75 3.75 3.75 3.75
CYCLODECANE 0.97 0.97 0.97 0.97
N-BBENZENE 2.72 2.72 2.72 2.72
1DECENE
NC11 3.55 3.55 3.55 3.55
N-PENTYLE-BZ 2.86 2.86 2.86 2.86
1-UNDECENE
NC12 11.13 11.13 11.13 11.13
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.02 0.02 0.02 0.02
MESD
DMDS
B-SULPHIDE

Total kg/h 48 187 50 370 50 370 50 370


Total kmol/h 445.72 465.91 465.91 465.91

REF: INRAD 22/02/08 13:06:14 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 12/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE SOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

HYDROTREATED C5+
Flow rate unit : wt % CUT TO STORAGE
29
H2O
H2
N2
H2S
METHANE
ETHANE
PROPANE
IBUTANE 0.40
BUTANE 2.29
IPENTANE 3.84
PENTANE 4.18
HEXANE 5.45
2MPENTAN 6.03
CYCLOHEXANE 0.17
HEPTANE 5.32
2-MHEXANE 5.93
CYCLOHEPTANE 3.92
TOLUENE 1.94
OCTANE 4.12
2-MHEPTANE 5.98
CYCLOOCTANE 5.98
EBENZENE 2.82
1OCTENE
NONANE 2.98
2-MOCTANE 4.17
CYCLONONANE 3.54
N-PBENZENE 3.14
1NONENE
DECANE 2.79
2-MNONANE 3.75
CYCLODECANE 0.97
N-BBENZENE 2.72
1DECENE
NC11 3.55
N-PENTYLE-BZ 2.86
1-UNDECENE
NC12 11.13
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.02
MESD
DMDS
B-SULPHIDE

Total kg/h 50 370


Total kmol/h 465.91

REF: INRAD 22/02/08 13:06:14 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 13/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

C5+ FEED FEED TO REACTION H2 MAKE-UP RECYCLE GAS


Flow rate unit : wt % SECTION
1 2 3 4
H2O
H2 95.06 16.94
N2 2.66 0.19
H2S 9.02
METHANE 2.28 27.08
ETHANE 0.43
PROPANE 0.58 0.58 6.16
IBUTANE 1.50 1.50 6.94
BUTANE 3.53 3.53 12.39
IPENTANE 3.74 3.74 5.77
PENTANE 4.04 4.04 4.92
HEXANE 5.04 5.04 2.26
2MPENTAN 5.80 5.80 3.40
CYCLOHEXANE 0.17 0.17 0.06
HEPTANE 5.12 5.12 0.86
2-MHEXANE 5.71 5.71 1.27
CYCLOHEPTANE 3.77 3.77 0.35
TOLUENE 1.87 1.87 0.29
OCTANE 3.96 3.96 0.26
2-MHEPTANE 5.75 5.75 0.51
CYCLOOCTANE 5.75 5.75 0.16
EBENZENE 2.71 2.71 0.19
1OCTENE 0.01 0.01
NONANE 2.84 2.84 0.08
2-MOCTANE 4.01 4.01 0.14
CYCLONONANE 3.41 3.41 0.03
N-PBENZENE 3.02 3.02 0.09
1NONENE 0.03 0.03
DECANE 2.66 2.66 0.03
2-MNONANE 3.60 3.60 0.05
CYCLODECANE 0.94 0.94 0.01
N-BBENZENE 2.62 2.62 0.03
1DECENE 0.02 0.02
NC11 3.39 3.39 0.02
N-PENTYLE-BZ 2.75 2.75 0.02
1-UNDECENE 0.03 0.03
NC12 10.70 10.70 0.03
M-MERCAPTAN 0.36 0.36
E-MERCAPTAN 0.03 0.03
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL 0.28 0.28
COS
DMS 0.23 0.23 0.02
MESD
DMDS 0.02 0.02
B-SULPHIDE 0.02 0.02

Total kg/h 52 360 52 360 34 2 628


Total kmol/h 501.40 501.40 15.89 291.92

REF: INRAD 22/02/08 13:20:50 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 14/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

REACTOR FEED HEATER INLET REACTOR INLET REACTOR OUTLET


Flow rate unit : wt % EFFLUENT EXCHANGER
INLET
5 6 7 8
H2O
H2 0.81 0.81 0.81 0.77
N2 0.01 0.01 0.01 0.01
H2S 0.43 0.43 0.43 0.89
METHANE 1.29 1.29 1.29 1.52
ETHANE 0.02 0.02 0.02 0.03
PROPANE 0.85 0.85 0.85 0.85
IBUTANE 1.76 1.76 1.76 1.76
BUTANE 3.95 3.95 3.95 3.96
IPENTANE 3.83 3.83 3.83 3.83
PENTANE 4.08 4.08 4.08 4.08
HEXANE 4.90 4.90 4.90 5.10
2MPENTAN 5.69 5.69 5.69 5.69
CYCLOHEXANE 0.16 0.16 0.16 0.16
HEPTANE 4.91 4.91 4.91 4.91
2-MHEXANE 5.49 5.49 5.49 5.49
CYCLOHEPTANE 3.61 3.61 3.61 3.61
TOLUENE 1.79 1.79 1.79 1.79
OCTANE 3.78 3.78 3.78 3.79
2-MHEPTANE 5.50 5.50 5.50 5.50
CYCLOOCTANE 5.49 5.49 5.49 5.49
EBENZENE 2.59 2.59 2.59 2.59
1OCTENE 0.01 0.01 0.01
NONANE 2.70 2.70 2.70 2.73
2-MOCTANE 3.83 3.83 3.83 3.83
CYCLONONANE 3.25 3.25 3.25 3.25
N-PBENZENE 2.88 2.88 2.88 2.88
1NONENE 0.03 0.03 0.03
DECANE 2.54 2.54 2.54 2.56
2-MNONANE 3.44 3.44 3.44 3.44
CYCLODECANE 0.89 0.89 0.89 0.89
N-BBENZENE 2.49 2.49 2.49 2.49
1DECENE 0.02 0.02 0.02
NC11 3.23 3.23 3.23 3.25
N-PENTYLE-BZ 2.62 2.62 2.62 2.62
1-UNDECENE 0.02 0.02 0.02
NC12 10.19 10.19 10.19 10.19
M-MERCAPTAN 0.34 0.34 0.34
E-MERCAPTAN 0.03 0.03 0.03
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL 0.27 0.27 0.27
COS
DMS 0.22 0.22 0.22 0.02
MESD
DMDS 0.02 0.02 0.02
B-SULPHIDE 0.01 0.01 0.01

Total kg/h 54 988 54 988 54 988 54 988


Total kmol/h 793.32 793.32 793.32 792.97

REF: INRAD 22/02/08 13:20:50 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 15/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

REACTOR FEED REACTOR EFFLUENT REACTOR EFFLUENT SEPARATOR VAPOR


Flow rate unit : wt % EFFLUENT EXCHANGER AIR COOLER INLET AIR COOLER OUTLET OUTLET
OUTLET
9 10 11 12
H2O
H2 0.77 0.77 0.77 15.93
N2 0.01 0.01 0.01 0.16
H2S 0.89 0.89 0.89 9.13
METHANE 1.52 1.52 1.52 27.40
ETHANE 0.03 0.03 0.03 0.44
PROPANE 0.85 0.85 0.85 6.24
IBUTANE 1.76 1.76 1.76 7.03
BUTANE 3.96 3.96 3.96 12.55
IPENTANE 3.83 3.83 3.83 5.85
PENTANE 4.08 4.08 4.08 4.98
HEXANE 5.10 5.10 5.10 2.29
2MPENTAN 5.69 5.69 5.69 3.44
CYCLOHEXANE 0.16 0.16 0.16 0.06
HEPTANE 4.91 4.91 4.91 0.87
2-MHEXANE 5.49 5.49 5.49 1.29
CYCLOHEPTANE 3.61 3.61 3.61 0.35
TOLUENE 1.79 1.79 1.79 0.30
OCTANE 3.79 3.79 3.79 0.26
2-MHEPTANE 5.50 5.50 5.50 0.51
CYCLOOCTANE 5.49 5.49 5.49 0.16
EBENZENE 2.59 2.59 2.59 0.19
1OCTENE
NONANE 2.73 2.73 2.73 0.08
2-MOCTANE 3.83 3.83 3.83 0.15
CYCLONONANE 3.25 3.25 3.25 0.03
N-PBENZENE 2.88 2.88 2.88 0.09
1NONENE
DECANE 2.56 2.56 2.56 0.03
2-MNONANE 3.44 3.44 3.44 0.06
CYCLODECANE 0.89 0.89 0.89 0.01
N-BBENZENE 2.49 2.49 2.49 0.03
1DECENE
NC11 3.25 3.25 3.25 0.02
N-PENTYLE-BZ 2.62 2.62 2.62 0.02
1-UNDECENE
NC12 10.19 10.19 10.19 0.03
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.02 0.02 0.02 0.02
MESD
DMDS
B-SULPHIDE

Total kg/h 54 988 54 988 54 988 2 595


Total kmol/h 792.97 792.97 792.97 276.03

REF: INRAD 22/02/08 13:20:50 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 16/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

RECYCLE COMPRESSOR RECYCLE COMPRESSOR REACTED C5+CUT TO STRIPPER FEED


Flow rate unit : wt % SUCTION DISCHARGE STRIPPER
13 14 15 16
H2O
H2 15.93 15.93 0.02 0.02
N2 0.16 0.16
H2S 9.13 9.13 0.48 0.48
METHANE 27.40 27.40 0.24 0.24
ETHANE 0.44 0.44 0.01 0.01
PROPANE 6.24 6.24 0.58 0.58
IBUTANE 7.03 7.03 1.50 1.50
BUTANE 12.55 12.55 3.54 3.54
IPENTANE 5.85 5.85 3.73 3.73
PENTANE 4.98 4.98 4.04 4.04
HEXANE 2.29 2.29 5.24 5.24
2MPENTAN 3.44 3.44 5.80 5.80
CYCLOHEXANE 0.06 0.06 0.17 0.17
HEPTANE 0.87 0.87 5.11 5.11
2-MHEXANE 1.29 1.29 5.70 5.70
CYCLOHEPTANE 0.35 0.35 3.77 3.77
TOLUENE 0.30 0.30 1.87 1.87
OCTANE 0.26 0.26 3.96 3.96
2-MHEPTANE 0.51 0.51 5.75 5.75
CYCLOOCTANE 0.16 0.16 5.75 5.75
EBENZENE 0.19 0.19 2.71 2.71
1OCTENE
NONANE 0.08 0.08 2.86 2.86
2-MOCTANE 0.15 0.15 4.01 4.01
CYCLONONANE 0.03 0.03 3.41 3.41
N-PBENZENE 0.09 0.09 3.02 3.02
1NONENE
DECANE 0.03 0.03 2.68 2.68
2-MNONANE 0.06 0.06 3.60 3.60
CYCLODECANE 0.01 0.01 0.94 0.94
N-BBENZENE 0.03 0.03 2.61 2.61
1DECENE
NC11 0.02 0.02 3.41 3.41
N-PENTYLE-BZ 0.02 0.02 2.75 2.75
1-UNDECENE
NC12 0.03 0.03 10.70 10.70
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.02 0.02 0.02 0.02
MESD
DMDS
B-SULPHIDE

Total kg/h 2 595 2 595 52 393 52 393


Total kmol/h 276.03 276.03 516.94 516.94

REF: INRAD 22/02/08 13:20:50 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 17/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

STRIPPER AIR C5+ CUT AIR TRIM CONDENSER PURGED GAS


Flow rate unit : wt % CONDENSER INLET CONDENSER OUTLET OUTLET
17 18 19 20
H2O
H2 0.09 0.09 0.09 0.60
N2 0.01 0.01 0.01 0.04
H2S 3.81 3.81 3.81 12.53
METHANE 1.06 1.06 1.06 6.15
ETHANE 0.10 0.10 0.10 0.37
PROPANE 8.39 8.39 8.39 15.01
IBUTANE 31.75 31.75 31.75 28.93
BUTANE 49.23 49.23 49.23 34.64
IPENTANE 3.50 3.50 3.50 1.21
PENTANE 1.74 1.74 1.74 0.47
HEXANE 0.08 0.08 0.08 0.01
2MPENTAN 0.20 0.20 0.20 0.03
CYCLOHEXANE
HEPTANE
2-MHEXANE 0.01 0.01 0.01
CYCLOHEPTANE
TOLUENE
OCTANE
2-MHEPTANE
CYCLOOCTANE
EBENZENE
1OCTENE
NONANE
2-MOCTANE
CYCLONONANE
N-PBENZENE
1NONENE
DECANE
2-MNONANE
CYCLODECANE
N-BBENZENE
1DECENE
NC11
N-PENTYLE-BZ
1-UNDECENE
NC12
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.03 0.03 0.03 0.01
MESD
DMDS
B-SULPHIDE

Total kg/h 14 781 14 781 14 781 2 023


Total kmol/h 278.55 278.55 278.55 51.02

REF: INRAD 22/02/08 13:20:50 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 18/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

STRIPPER REFLUX STRIPPER BOTTOM STRIPPER REBOILER STRIPPER FIRE HEATER


Flow rate unit : wt % PUMPS INLET INLET
21 22 23 24
H2O
H2
N2
H2S 2.43
METHANE 0.26
ETHANE 0.06
PROPANE 7.34
IBUTANE 32.19 0.40 0.40 0.40
BUTANE 51.54 2.29 2.29 2.29
IPENTANE 3.86 3.84 3.84 3.84
PENTANE 1.95 4.18 4.18 4.18
HEXANE 0.09 5.45 5.45 5.45
2MPENTAN 0.22 6.03 6.03 6.03
CYCLOHEXANE 0.17 0.17 0.17
HEPTANE 5.32 5.32 5.32
2-MHEXANE 0.01 5.93 5.93 5.93
CYCLOHEPTANE 3.92 3.92 3.92
TOLUENE 1.94 1.94 1.94
OCTANE 4.12 4.12 4.12
2-MHEPTANE 5.98 5.98 5.98
CYCLOOCTANE 5.98 5.98 5.98
EBENZENE 2.82 2.82 2.82
1OCTENE
NONANE 2.98 2.98 2.98
2-MOCTANE 4.17 4.17 4.17
CYCLONONANE 3.54 3.54 3.54
N-PBENZENE 3.14 3.14 3.14
1NONENE
DECANE 2.79 2.79 2.79
2-MNONANE 3.75 3.75 3.75
CYCLODECANE 0.97 0.97 0.97
N-BBENZENE 2.72 2.72 2.72
1DECENE
NC11 3.55 3.55 3.55
N-PENTYLE-BZ 2.86 2.86 2.86
1-UNDECENE
NC12 11.13 11.13 11.13
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.03 0.02 0.02 0.02
MESD
DMDS
B-SULPHIDE

Total kg/h 12 758 98 557 48 187 48 187


Total kmol/h 227.53 911.63 445.72 445.72

REF: INRAD 22/02/08 13:20:50 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 19/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

STRIPPER FIRE HEATER STRIPPER TUBE SIDE STRIPPER TUBE SIDE STRIPPER AIR COOLER
Flow rate unit : wt % OUTLET EXCHANGERS INLET EXCHANGERS OUTLET OUTLET
25 26 27 28
H2O
H2
N2
H2S
METHANE
ETHANE
PROPANE
IBUTANE 0.40 0.40 0.40 0.40
BUTANE 2.29 2.29 2.29 2.29
IPENTANE 3.84 3.84 3.84 3.84
PENTANE 4.18 4.18 4.18 4.18
HEXANE 5.45 5.45 5.45 5.45
2MPENTAN 6.03 6.03 6.03 6.03
CYCLOHEXANE 0.17 0.17 0.17 0.17
HEPTANE 5.32 5.32 5.32 5.32
2-MHEXANE 5.93 5.93 5.93 5.93
CYCLOHEPTANE 3.92 3.92 3.92 3.92
TOLUENE 1.94 1.94 1.94 1.94
OCTANE 4.12 4.12 4.12 4.12
2-MHEPTANE 5.98 5.98 5.98 5.98
CYCLOOCTANE 5.98 5.98 5.98 5.98
EBENZENE 2.82 2.82 2.82 2.82
1OCTENE
NONANE 2.98 2.98 2.98 2.98
2-MOCTANE 4.17 4.17 4.17 4.17
CYCLONONANE 3.54 3.54 3.54 3.54
N-PBENZENE 3.14 3.14 3.14 3.14
1NONENE
DECANE 2.79 2.79 2.79 2.79
2-MNONANE 3.75 3.75 3.75 3.75
CYCLODECANE 0.97 0.97 0.97 0.97
N-BBENZENE 2.72 2.72 2.72 2.72
1DECENE
NC11 3.55 3.55 3.55 3.55
N-PENTYLE-BZ 2.86 2.86 2.86 2.86
1-UNDECENE
NC12 11.13 11.13 11.13 11.13
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.02 0.02 0.02 0.02
MESD
DMDS
B-SULPHIDE

Total kg/h 48 187 50 370 50 370 50 370


Total kmol/h 445.72 465.91 465.91 465.91

REF: INRAD 22/02/08 13:20:50 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 20/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

HYDROTREATED C5+
Flow rate unit : wt % CUT TO STORAGE
29
H2O
H2
N2
H2S
METHANE
ETHANE
PROPANE
IBUTANE 0.40
BUTANE 2.29
IPENTANE 3.84
PENTANE 4.18
HEXANE 5.45
2MPENTAN 6.03
CYCLOHEXANE 0.17
HEPTANE 5.32
2-MHEXANE 5.93
CYCLOHEPTANE 3.92
TOLUENE 1.94
OCTANE 4.12
2-MHEPTANE 5.98
CYCLOOCTANE 5.98
EBENZENE 2.82
1OCTENE
NONANE 2.98
2-MOCTANE 4.17
CYCLONONANE 3.54
N-PBENZENE 3.14
1NONENE
DECANE 2.79
2-MNONANE 3.75
CYCLODECANE 0.97
N-BBENZENE 2.72
1DECENE
NC11 3.55
N-PENTYLE-BZ 2.86
1-UNDECENE
NC12 11.13
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.02
MESD
DMDS
B-SULPHIDE

Total kg/h 50 370


Total kmol/h 465.91

REF: INRAD 22/02/08 13:20:50 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 21/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE SOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

C5+ FEED FEED TO REACTION H2 MAKE-UP RECYCLE GAS


Flow rate unit : wt % SECTION
1 2 3 4
H2O
H2 95.06 15.69
N2 2.66 0.19
H2S 9.43
METHANE 2.28 28.65
ETHANE 0.47
PROPANE 0.28 0.28 2.72
IBUTANE 1.79 1.79 7.60
BUTANE 4.24 4.24 13.67
IPENTANE 4.51 4.51 6.43
PENTANE 4.52 4.52 5.07
HEXANE 5.40 5.40 2.24
2MPENTAN 6.63 6.63 3.59
CYCLOHEXANE 0.19 0.19 0.06
HEPTANE 5.43 5.43 0.85
2-MHEXANE 6.08 6.08 1.25
CYCLOHEPTANE 4.01 4.01 0.35
TOLUENE 1.84 1.84 0.27
OCTANE 3.97 3.97 0.24
2-MHEPTANE 5.76 5.76 0.47
CYCLOOCTANE 5.61 5.61 0.15
EBENZENE 1.55 1.55 0.10
1OCTENE 0.01 0.01
NONANE 2.77 2.77 0.07
2-MOCTANE 3.92 3.92 0.13
CYCLONONANE 3.31 3.31 0.03
N-PBENZENE 3.21 3.21 0.09
1NONENE 0.03 0.03
DECANE 2.34 2.34 0.03
2-MNONANE 3.48 3.48 0.05
CYCLODECANE 0.90 0.90 0.01
N-BBENZENE 2.53 2.53 0.03
1DECENE 0.02 0.02
NC11 2.03 2.03 0.01
N-PENTYLE-BZ 2.28 2.28 0.01
1-UNDECENE 0.03 0.03
NC12 10.31 10.31 0.02
M-MERCAPTAN 0.41 0.41
E-MERCAPTAN 0.03 0.03
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL 0.27 0.27
COS
DMS 0.27 0.27 0.02
MESD
DMDS 0.02 0.02
B-SULPHIDE 0.02 0.02

Total kg/h 52 620 52 620 36 2 779


Total kmol/h 515.35 515.35 17.29 293.54

REF: INRAD 22/02/08 13:06:56 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 22/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE SOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

REACTOR FEED HEATER INLET REACTOR INLET REACTOR OUTLET


Flow rate unit : wt % EFFLUENT EXCHANGER
INLET
5 6 7 8
H2O
H2 0.79 0.79 0.79 0.75
N2 0.01 0.01 0.01 0.01
H2S 0.47 0.47 0.47 0.99
METHANE 1.44 1.44 1.44 1.70
ETHANE 0.02 0.02 0.02 0.04
PROPANE 0.40 0.40 0.40 0.40
IBUTANE 2.09 2.09 2.09 2.09
BUTANE 4.71 4.71 4.71 4.72
IPENTANE 4.60 4.60 4.60 4.60
PENTANE 4.54 4.54 4.54 4.54
HEXANE 5.24 5.24 5.24 5.43
2MPENTAN 6.48 6.48 6.48 6.48
CYCLOHEXANE 0.18 0.18 0.18 0.18
HEPTANE 5.20 5.20 5.20 5.20
2-MHEXANE 5.84 5.84 5.84 5.84
CYCLOHEPTANE 3.83 3.83 3.83 3.83
TOLUENE 1.76 1.76 1.76 1.76
OCTANE 3.79 3.79 3.79 3.79
2-MHEPTANE 5.49 5.49 5.49 5.49
CYCLOOCTANE 5.33 5.33 5.33 5.33
EBENZENE 1.47 1.47 1.47 1.47
1OCTENE 0.01 0.01 0.01
NONANE 2.63 2.63 2.63 2.66
2-MOCTANE 3.73 3.73 3.73 3.73
CYCLONONANE 3.14 3.14 3.14 3.14
N-PBENZENE 3.05 3.05 3.05 3.05
1NONENE 0.03 0.03 0.03
DECANE 2.23 2.23 2.23 2.25
2-MNONANE 3.31 3.31 3.31 3.31
CYCLODECANE 0.86 0.86 0.86 0.86
N-BBENZENE 2.41 2.41 2.41 2.41
1DECENE 0.02 0.02 0.02
NC11 1.93 1.93 1.93 1.96
N-PENTYLE-BZ 2.17 2.17 2.17 2.17
1-UNDECENE 0.02 0.02 0.02
NC12 9.79 9.79 9.79 9.79
M-MERCAPTAN 0.39 0.39 0.39
E-MERCAPTAN 0.03 0.03 0.03
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL 0.26 0.26 0.26
COS
DMS 0.26 0.26 0.26 0.02
MESD
DMDS 0.02 0.02 0.02
B-SULPHIDE 0.01 0.01 0.01

Total kg/h 55 399 55 399 55 399 55 399


Total kmol/h 808.88 808.88 808.88 808.53

REF: INRAD 22/02/08 13:06:56 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 23/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE SOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

REACTOR FEED REACTOR EFFLUENT REACTOR EFFLUENT SEPARATOR VAPOR


Flow rate unit : wt % EFFLUENT EXCHANGER AIR COOLER INLET AIR COOLER OUTLET OUTLET
OUTLET
9 10 11 12
H2O
H2 0.75 0.75 0.75 14.64
N2 0.01 0.01 0.01 0.16
H2S 0.99 0.99 0.99 9.56
METHANE 1.70 1.70 1.70 29.00
ETHANE 0.04 0.04 0.04 0.47
PROPANE 0.40 0.40 0.40 2.75
IBUTANE 2.09 2.09 2.09 7.70
BUTANE 4.72 4.72 4.72 13.85
IPENTANE 4.60 4.60 4.60 6.51
PENTANE 4.54 4.54 4.54 5.14
HEXANE 5.43 5.43 5.43 2.27
2MPENTAN 6.48 6.48 6.48 3.63
CYCLOHEXANE 0.18 0.18 0.18 0.06
HEPTANE 5.20 5.20 5.20 0.86
2-MHEXANE 5.84 5.84 5.84 1.27
CYCLOHEPTANE 3.83 3.83 3.83 0.36
TOLUENE 1.76 1.76 1.76 0.28
OCTANE 3.79 3.79 3.79 0.24
2-MHEPTANE 5.49 5.49 5.49 0.48
CYCLOOCTANE 5.33 5.33 5.33 0.15
EBENZENE 1.47 1.47 1.47 0.10
1OCTENE
NONANE 2.66 2.66 2.66 0.07
2-MOCTANE 3.73 3.73 3.73 0.13
CYCLONONANE 3.14 3.14 3.14 0.03
N-PBENZENE 3.05 3.05 3.05 0.09
1NONENE
DECANE 2.25 2.25 2.25 0.03
2-MNONANE 3.31 3.31 3.31 0.05
CYCLODECANE 0.86 0.86 0.86 0.01
N-BBENZENE 2.41 2.41 2.41 0.03
1DECENE
NC11 1.96 1.96 1.96 0.01
N-PENTYLE-BZ 2.17 2.17 2.17 0.01
1-UNDECENE
NC12 9.79 9.79 9.79 0.02
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.02 0.02 0.02 0.02
MESD
DMDS
B-SULPHIDE

Total kg/h 55 399 55 399 55 399 2 742


Total kmol/h 808.54 808.54 808.54 276.26

REF: INRAD 22/02/08 13:06:56 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 24/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE SOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

RECYCLE COMPRESSOR RECYCLE COMPRESSOR REACTED C5+CUT TO STRIPPER FEED


Flow rate unit : wt % SUCTION DISCHARGE STRIPPER
13 14 15 16
H2O
H2 14.64 14.64 0.02 0.02
N2 0.16 0.16
H2S 9.56 9.56 0.54 0.54
METHANE 29.00 29.00 0.28 0.28
ETHANE 0.47 0.47 0.02 0.02
PROPANE 2.75 2.75 0.28 0.28
IBUTANE 7.70 7.70 1.79 1.79
BUTANE 13.85 13.85 4.25 4.25
IPENTANE 6.51 6.51 4.50 4.50
PENTANE 5.14 5.14 4.51 4.51
HEXANE 2.27 2.27 5.59 5.59
2MPENTAN 3.63 3.63 6.63 6.63
CYCLOHEXANE 0.06 0.06 0.19 0.19
HEPTANE 0.86 0.86 5.43 5.43
2-MHEXANE 1.27 1.27 6.08 6.08
CYCLOHEPTANE 0.36 0.36 4.01 4.01
TOLUENE 0.28 0.28 1.83 1.83
OCTANE 0.24 0.24 3.98 3.98
2-MHEPTANE 0.48 0.48 5.75 5.75
CYCLOOCTANE 0.15 0.15 5.60 5.60
EBENZENE 0.10 0.10 1.54 1.54
1OCTENE
NONANE 0.07 0.07 2.80 2.80
2-MOCTANE 0.13 0.13 3.92 3.92
CYCLONONANE 0.03 0.03 3.30 3.30
N-PBENZENE 0.09 0.09 3.21 3.21
1NONENE
DECANE 0.03 0.03 2.36 2.36
2-MNONANE 0.05 0.05 3.48 3.48
CYCLODECANE 0.01 0.01 0.90 0.90
N-BBENZENE 0.03 0.03 2.53 2.53
1DECENE
NC11 0.01 0.01 2.06 2.06
N-PENTYLE-BZ 0.01 0.01 2.28 2.28
1-UNDECENE
NC12 0.02 0.02 10.30 10.30
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.02 0.02 0.02 0.02
MESD
DMDS
B-SULPHIDE

Total kg/h 2 742 2 742 52 656 52 656


Total kmol/h 276.25 276.25 532.28 532.28

REF: INRAD 22/02/08 13:06:56 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 25/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE SOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

STRIPPER AIR C5+ CUT AIR TRIM CONDENSER PURGED GAS


Flow rate unit : wt % CONDENSER INLET CONDENSER OUTLET OUTLET
17 18 19 20
H2O
H2 0.08 0.08 0.08 0.62
N2 0.01 0.01 0.01 0.05
H2S 4.16 4.16 4.16 14.24
METHANE 1.16 1.16 1.16 7.22
ETHANE 0.12 0.12 0.12 0.44
PROPANE 3.98 3.98 3.98 7.32
IBUTANE 35.43 35.43 35.43 32.83
BUTANE 50.01 50.01 50.01 35.69
IPENTANE 3.29 3.29 3.29 1.14
PENTANE 1.50 1.50 1.50 0.41
HEXANE 0.06 0.06 0.06 0.01
2MPENTAN 0.17 0.17 0.17 0.02
CYCLOHEXANE
HEPTANE
2-MHEXANE 0.01 0.01 0.01
CYCLOHEPTANE
TOLUENE
OCTANE
2-MHEPTANE
CYCLOOCTANE
EBENZENE
1OCTENE
NONANE
2-MOCTANE
CYCLONONANE
N-PBENZENE
1NONENE
DECANE
2-MNONANE
CYCLODECANE
N-BBENZENE
1DECENE
NC11
N-PENTYLE-BZ
1-UNDECENE
NC12
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.02 0.02 0.02 0.01
MESD
DMDS
B-SULPHIDE

Total kg/h 16 026 16 026 16 026 2 006


Total kmol/h 299.45 299.45 299.45 51.33

REF: INRAD 22/02/08 13:06:56 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 26/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE SOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

STRIPPER REFLUX STRIPPER BOTTOM STRIPPER REBOILER STRIPPER FIRE HEATER


Flow rate unit : wt % PUMPS INLET INLET
21 22 23 24
H2O
H2
N2
H2S 2.71
METHANE 0.29
ETHANE 0.07
PROPANE 3.50
IBUTANE 35.80 0.56 0.56 0.56
BUTANE 52.06 3.00 3.00 3.00
IPENTANE 3.60 4.64 4.64 4.64
PENTANE 1.66 4.68 4.68 4.68
HEXANE 0.07 5.81 5.81 5.81
2MPENTAN 0.19 6.89 6.89 6.89
CYCLOHEXANE 0.20 0.20 0.20
HEPTANE 5.64 5.64 5.64
2-MHEXANE 0.01 6.32 6.32 6.32
CYCLOHEPTANE 4.17 4.17 4.17
TOLUENE 1.91 1.91 1.91
OCTANE 4.14 4.14 4.14
2-MHEPTANE 5.98 5.98 5.98
CYCLOOCTANE 5.83 5.83 5.83
EBENZENE 1.61 1.61 1.61
1OCTENE
NONANE 2.91 2.91 2.91
2-MOCTANE 4.07 4.07 4.07
CYCLONONANE 3.43 3.43 3.43
N-PBENZENE 3.33 3.33 3.33
1NONENE
DECANE 2.46 2.46 2.46
2-MNONANE 3.62 3.62 3.62
CYCLODECANE 0.94 0.94 0.94
N-BBENZENE 2.63 2.63 2.63
1DECENE
NC11 2.14 2.14 2.14
N-PENTYLE-BZ 2.37 2.37 2.37
1-UNDECENE
NC12 10.71 10.71 10.71
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.03 0.02 0.02 0.02
MESD
DMDS
B-SULPHIDE

Total kg/h 14 020 98 917 48 267 48 267


Total kmol/h 248.12 939.29 458.33 458.33

REF: INRAD 22/02/08 13:06:56 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 27/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE SOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

STRIPPER FIRE HEATER STRIPPER TUBE SIDE STRIPPER TUBE SIDE STRIPPER AIR COOLER
Flow rate unit : wt % OUTLET EXCHANGERS INLET EXCHANGERS OUTLET OUTLET
25 26 27 28
H2O
H2
N2
H2S
METHANE
ETHANE
PROPANE
IBUTANE 0.56 0.56 0.56 0.56
BUTANE 3.00 3.00 3.00 3.00
IPENTANE 4.64 4.64 4.64 4.64
PENTANE 4.68 4.68 4.68 4.68
HEXANE 5.81 5.81 5.81 5.81
2MPENTAN 6.89 6.89 6.89 6.89
CYCLOHEXANE 0.20 0.20 0.20 0.20
HEPTANE 5.64 5.64 5.64 5.64
2-MHEXANE 6.32 6.32 6.32 6.32
CYCLOHEPTANE 4.17 4.17 4.17 4.17
TOLUENE 1.91 1.91 1.91 1.91
OCTANE 4.14 4.14 4.14 4.14
2-MHEPTANE 5.98 5.98 5.98 5.98
CYCLOOCTANE 5.83 5.83 5.83 5.83
EBENZENE 1.61 1.61 1.61 1.61
1OCTENE
NONANE 2.91 2.91 2.91 2.91
2-MOCTANE 4.07 4.07 4.07 4.07
CYCLONONANE 3.43 3.43 3.43 3.43
N-PBENZENE 3.33 3.33 3.33 3.33
1NONENE
DECANE 2.46 2.46 2.46 2.46
2-MNONANE 3.62 3.62 3.62 3.62
CYCLODECANE 0.94 0.94 0.94 0.94
N-BBENZENE 2.63 2.63 2.63 2.63
1DECENE
NC11 2.14 2.14 2.14 2.14
N-PENTYLE-BZ 2.37 2.37 2.37 2.37
1-UNDECENE
NC12 10.71 10.71 10.71 10.71
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.02 0.02 0.02 0.02
MESD
DMDS
B-SULPHIDE

Total kg/h 48 267 50 650 50 650 50 650


Total kmol/h 458.33 480.96 480.96 480.96

REF: INRAD 22/02/08 13:06:56 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 28/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE SOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

HYDROTREATED C5+
Flow rate unit : wt % CUT TO STORAGE
29
H2O
H2
N2
H2S
METHANE
ETHANE
PROPANE
IBUTANE 0.56
BUTANE 3.00
IPENTANE 4.64
PENTANE 4.68
HEXANE 5.81
2MPENTAN 6.89
CYCLOHEXANE 0.20
HEPTANE 5.64
2-MHEXANE 6.32
CYCLOHEPTANE 4.17
TOLUENE 1.91
OCTANE 4.14
2-MHEPTANE 5.98
CYCLOOCTANE 5.83
EBENZENE 1.61
1OCTENE
NONANE 2.91
2-MOCTANE 4.07
CYCLONONANE 3.43
N-PBENZENE 3.33
1NONENE
DECANE 2.46
2-MNONANE 3.62
CYCLODECANE 0.94
N-BBENZENE 2.63
1DECENE
NC11 2.14
N-PENTYLE-BZ 2.37
1-UNDECENE
NC12 10.71
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.02
MESD
DMDS
B-SULPHIDE

Total kg/h 50 650


Total kmol/h 480.96

REF: INRAD 22/02/08 13:06:56 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 29/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

C5+ FEED FEED TO REACTION H2 MAKE-UP RECYCLE GAS


Flow rate unit : wt % SECTION
1 2 3 4
H2O
H2 95.06 15.69
N2 2.66 0.19
H2S 9.43
METHANE 2.28 28.65
ETHANE 0.47
PROPANE 0.28 0.28 2.72
IBUTANE 1.79 1.79 7.60
BUTANE 4.24 4.24 13.67
IPENTANE 4.51 4.51 6.43
PENTANE 4.52 4.52 5.07
HEXANE 5.40 5.40 2.24
2MPENTAN 6.63 6.63 3.59
CYCLOHEXANE 0.19 0.19 0.06
HEPTANE 5.43 5.43 0.85
2-MHEXANE 6.08 6.08 1.25
CYCLOHEPTANE 4.01 4.01 0.35
TOLUENE 1.84 1.84 0.27
OCTANE 3.97 3.97 0.24
2-MHEPTANE 5.76 5.76 0.47
CYCLOOCTANE 5.61 5.61 0.15
EBENZENE 1.55 1.55 0.10
1OCTENE 0.01 0.01
NONANE 2.77 2.77 0.07
2-MOCTANE 3.92 3.92 0.13
CYCLONONANE 3.31 3.31 0.03
N-PBENZENE 3.21 3.21 0.09
1NONENE 0.03 0.03
DECANE 2.34 2.34 0.03
2-MNONANE 3.48 3.48 0.05
CYCLODECANE 0.90 0.90 0.01
N-BBENZENE 2.53 2.53 0.03
1DECENE 0.02 0.02
NC11 2.03 2.03 0.01
N-PENTYLE-BZ 2.28 2.28 0.01
1-UNDECENE 0.03 0.03
NC12 10.31 10.31 0.02
M-MERCAPTAN 0.41 0.41
E-MERCAPTAN 0.03 0.03
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL 0.27 0.27
COS
DMS 0.27 0.27 0.02
MESD
DMDS 0.02 0.02
B-SULPHIDE 0.02 0.02

Total kg/h 52 620 52 620 36 2 779


Total kmol/h 515.35 515.35 17.29 293.54

REF: INRAD 22/02/08 13:06:33 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 30/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

REACTOR FEED HEATER INLET REACTOR INLET REACTOR OUTLET


Flow rate unit : wt % EFFLUENT EXCHANGER
INLET
5 6 7 8
H2O
H2 0.79 0.79 0.79 0.75
N2 0.01 0.01 0.01 0.01
H2S 0.47 0.47 0.47 0.99
METHANE 1.44 1.44 1.44 1.70
ETHANE 0.02 0.02 0.02 0.04
PROPANE 0.40 0.40 0.40 0.40
IBUTANE 2.09 2.09 2.09 2.09
BUTANE 4.71 4.71 4.71 4.72
IPENTANE 4.60 4.60 4.60 4.60
PENTANE 4.54 4.54 4.54 4.54
HEXANE 5.24 5.24 5.24 5.43
2MPENTAN 6.48 6.48 6.48 6.48
CYCLOHEXANE 0.18 0.18 0.18 0.18
HEPTANE 5.20 5.20 5.20 5.20
2-MHEXANE 5.84 5.84 5.84 5.84
CYCLOHEPTANE 3.83 3.83 3.83 3.83
TOLUENE 1.76 1.76 1.76 1.76
OCTANE 3.79 3.79 3.79 3.79
2-MHEPTANE 5.49 5.49 5.49 5.49
CYCLOOCTANE 5.33 5.33 5.33 5.33
EBENZENE 1.47 1.47 1.47 1.47
1OCTENE 0.01 0.01 0.01
NONANE 2.63 2.63 2.63 2.66
2-MOCTANE 3.73 3.73 3.73 3.73
CYCLONONANE 3.14 3.14 3.14 3.14
N-PBENZENE 3.05 3.05 3.05 3.05
1NONENE 0.03 0.03 0.03
DECANE 2.23 2.23 2.23 2.25
2-MNONANE 3.31 3.31 3.31 3.31
CYCLODECANE 0.86 0.86 0.86 0.86
N-BBENZENE 2.41 2.41 2.41 2.41
1DECENE 0.02 0.02 0.02
NC11 1.93 1.93 1.93 1.96
N-PENTYLE-BZ 2.17 2.17 2.17 2.17
1-UNDECENE 0.02 0.02 0.02
NC12 9.79 9.79 9.79 9.79
M-MERCAPTAN 0.39 0.39 0.39
E-MERCAPTAN 0.03 0.03 0.03
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL 0.26 0.26 0.26
COS
DMS 0.26 0.26 0.26 0.02
MESD
DMDS 0.02 0.02 0.02
B-SULPHIDE 0.01 0.01 0.01

Total kg/h 55 399 55 399 55 399 55 399


Total kmol/h 808.88 808.88 808.88 808.53

REF: INRAD 22/02/08 13:06:33 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 31/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

REACTOR FEED REACTOR EFFLUENT REACTOR EFFLUENT SEPARATOR VAPOR


Flow rate unit : wt % EFFLUENT EXCHANGER AIR COOLER INLET AIR COOLER OUTLET OUTLET
OUTLET
9 10 11 12
H2O
H2 0.75 0.75 0.75 14.64
N2 0.01 0.01 0.01 0.16
H2S 0.99 0.99 0.99 9.56
METHANE 1.70 1.70 1.70 29.00
ETHANE 0.04 0.04 0.04 0.47
PROPANE 0.40 0.40 0.40 2.75
IBUTANE 2.09 2.09 2.09 7.70
BUTANE 4.72 4.72 4.72 13.85
IPENTANE 4.60 4.60 4.60 6.51
PENTANE 4.54 4.54 4.54 5.14
HEXANE 5.43 5.43 5.43 2.27
2MPENTAN 6.48 6.48 6.48 3.63
CYCLOHEXANE 0.18 0.18 0.18 0.06
HEPTANE 5.20 5.20 5.20 0.86
2-MHEXANE 5.84 5.84 5.84 1.27
CYCLOHEPTANE 3.83 3.83 3.83 0.36
TOLUENE 1.76 1.76 1.76 0.28
OCTANE 3.79 3.79 3.79 0.24
2-MHEPTANE 5.49 5.49 5.49 0.48
CYCLOOCTANE 5.33 5.33 5.33 0.15
EBENZENE 1.47 1.47 1.47 0.10
1OCTENE
NONANE 2.66 2.66 2.66 0.07
2-MOCTANE 3.73 3.73 3.73 0.13
CYCLONONANE 3.14 3.14 3.14 0.03
N-PBENZENE 3.05 3.05 3.05 0.09
1NONENE
DECANE 2.25 2.25 2.25 0.03
2-MNONANE 3.31 3.31 3.31 0.05
CYCLODECANE 0.86 0.86 0.86 0.01
N-BBENZENE 2.41 2.41 2.41 0.03
1DECENE
NC11 1.96 1.96 1.96 0.01
N-PENTYLE-BZ 2.17 2.17 2.17 0.01
1-UNDECENE
NC12 9.79 9.79 9.79 0.02
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.02 0.02 0.02 0.02
MESD
DMDS
B-SULPHIDE

Total kg/h 55 399 55 399 55 399 2 742


Total kmol/h 808.54 808.54 808.54 276.26

REF: INRAD 22/02/08 13:06:33 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 32/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

RECYCLE COMPRESSOR RECYCLE COMPRESSOR REACTED C5+CUT TO STRIPPER FEED


Flow rate unit : wt % SUCTION DISCHARGE STRIPPER
13 14 15 16
H2O
H2 14.64 14.64 0.02 0.02
N2 0.16 0.16
H2S 9.56 9.56 0.54 0.54
METHANE 29.00 29.00 0.28 0.28
ETHANE 0.47 0.47 0.02 0.02
PROPANE 2.75 2.75 0.28 0.28
IBUTANE 7.70 7.70 1.79 1.79
BUTANE 13.85 13.85 4.25 4.25
IPENTANE 6.51 6.51 4.50 4.50
PENTANE 5.14 5.14 4.51 4.51
HEXANE 2.27 2.27 5.59 5.59
2MPENTAN 3.63 3.63 6.63 6.63
CYCLOHEXANE 0.06 0.06 0.19 0.19
HEPTANE 0.86 0.86 5.43 5.43
2-MHEXANE 1.27 1.27 6.08 6.08
CYCLOHEPTANE 0.36 0.36 4.01 4.01
TOLUENE 0.28 0.28 1.83 1.83
OCTANE 0.24 0.24 3.98 3.98
2-MHEPTANE 0.48 0.48 5.75 5.75
CYCLOOCTANE 0.15 0.15 5.60 5.60
EBENZENE 0.10 0.10 1.54 1.54
1OCTENE
NONANE 0.07 0.07 2.80 2.80
2-MOCTANE 0.13 0.13 3.92 3.92
CYCLONONANE 0.03 0.03 3.30 3.30
N-PBENZENE 0.09 0.09 3.21 3.21
1NONENE
DECANE 0.03 0.03 2.36 2.36
2-MNONANE 0.05 0.05 3.48 3.48
CYCLODECANE 0.01 0.01 0.90 0.90
N-BBENZENE 0.03 0.03 2.53 2.53
1DECENE
NC11 0.01 0.01 2.06 2.06
N-PENTYLE-BZ 0.01 0.01 2.28 2.28
1-UNDECENE
NC12 0.02 0.02 10.30 10.30
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.02 0.02 0.02 0.02
MESD
DMDS
B-SULPHIDE

Total kg/h 2 742 2 742 52 656 52 656


Total kmol/h 276.25 276.25 532.28 532.28

REF: INRAD 22/02/08 13:06:33 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 33/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

STRIPPER AIR C5+ CUT AIR TRIM CONDENSER PURGED GAS


Flow rate unit : wt % CONDENSER INLET CONDENSER OUTLET OUTLET
17 18 19 20
H2O
H2 0.08 0.08 0.08 0.62
N2 0.01 0.01 0.01 0.05
H2S 4.16 4.16 4.16 14.24
METHANE 1.16 1.16 1.16 7.22
ETHANE 0.12 0.12 0.12 0.44
PROPANE 3.98 3.98 3.98 7.32
IBUTANE 35.43 35.43 35.43 32.83
BUTANE 50.01 50.01 50.01 35.69
IPENTANE 3.29 3.29 3.29 1.14
PENTANE 1.50 1.50 1.50 0.41
HEXANE 0.06 0.06 0.06 0.01
2MPENTAN 0.17 0.17 0.17 0.02
CYCLOHEXANE
HEPTANE
2-MHEXANE 0.01 0.01 0.01
CYCLOHEPTANE
TOLUENE
OCTANE
2-MHEPTANE
CYCLOOCTANE
EBENZENE
1OCTENE
NONANE
2-MOCTANE
CYCLONONANE
N-PBENZENE
1NONENE
DECANE
2-MNONANE
CYCLODECANE
N-BBENZENE
1DECENE
NC11
N-PENTYLE-BZ
1-UNDECENE
NC12
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.02 0.02 0.02 0.01
MESD
DMDS
B-SULPHIDE

Total kg/h 16 026 16 026 16 026 2 006


Total kmol/h 299.45 299.45 299.45 51.33

REF: INRAD 22/02/08 13:06:33 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 34/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

STRIPPER REFLUX STRIPPER BOTTOM STRIPPER REBOILER STRIPPER FIRE HEATER


Flow rate unit : wt % PUMPS INLET INLET
21 22 23 24
H2O
H2
N2
H2S 2.71
METHANE 0.29
ETHANE 0.07
PROPANE 3.50
IBUTANE 35.80 0.56 0.56 0.56
BUTANE 52.06 3.00 3.00 3.00
IPENTANE 3.60 4.64 4.64 4.64
PENTANE 1.66 4.68 4.68 4.68
HEXANE 0.07 5.81 5.81 5.81
2MPENTAN 0.19 6.89 6.89 6.89
CYCLOHEXANE 0.20 0.20 0.20
HEPTANE 5.64 5.64 5.64
2-MHEXANE 0.01 6.32 6.32 6.32
CYCLOHEPTANE 4.17 4.17 4.17
TOLUENE 1.91 1.91 1.91
OCTANE 4.14 4.14 4.14
2-MHEPTANE 5.98 5.98 5.98
CYCLOOCTANE 5.83 5.83 5.83
EBENZENE 1.61 1.61 1.61
1OCTENE
NONANE 2.91 2.91 2.91
2-MOCTANE 4.07 4.07 4.07
CYCLONONANE 3.43 3.43 3.43
N-PBENZENE 3.33 3.33 3.33
1NONENE
DECANE 2.46 2.46 2.46
2-MNONANE 3.62 3.62 3.62
CYCLODECANE 0.94 0.94 0.94
N-BBENZENE 2.63 2.63 2.63
1DECENE
NC11 2.14 2.14 2.14
N-PENTYLE-BZ 2.37 2.37 2.37
1-UNDECENE
NC12 10.71 10.71 10.71
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.03 0.02 0.02 0.02
MESD
DMDS
B-SULPHIDE

Total kg/h 14 020 98 917 48 267 48 267


Total kmol/h 248.12 939.29 458.33 458.33

REF: INRAD 22/02/08 13:06:33 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 35/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

STRIPPER FIRE HEATER STRIPPER TUBE SIDE STRIPPER TUBE SIDE STRIPPER AIR COOLER
Flow rate unit : wt % OUTLET EXCHANGERS INLET EXCHANGERS OUTLET OUTLET
25 26 27 28
H2O
H2
N2
H2S
METHANE
ETHANE
PROPANE
IBUTANE 0.56 0.56 0.56 0.56
BUTANE 3.00 3.00 3.00 3.00
IPENTANE 4.64 4.64 4.64 4.64
PENTANE 4.68 4.68 4.68 4.68
HEXANE 5.81 5.81 5.81 5.81
2MPENTAN 6.89 6.89 6.89 6.89
CYCLOHEXANE 0.20 0.20 0.20 0.20
HEPTANE 5.64 5.64 5.64 5.64
2-MHEXANE 6.32 6.32 6.32 6.32
CYCLOHEPTANE 4.17 4.17 4.17 4.17
TOLUENE 1.91 1.91 1.91 1.91
OCTANE 4.14 4.14 4.14 4.14
2-MHEPTANE 5.98 5.98 5.98 5.98
CYCLOOCTANE 5.83 5.83 5.83 5.83
EBENZENE 1.61 1.61 1.61 1.61
1OCTENE
NONANE 2.91 2.91 2.91 2.91
2-MOCTANE 4.07 4.07 4.07 4.07
CYCLONONANE 3.43 3.43 3.43 3.43
N-PBENZENE 3.33 3.33 3.33 3.33
1NONENE
DECANE 2.46 2.46 2.46 2.46
2-MNONANE 3.62 3.62 3.62 3.62
CYCLODECANE 0.94 0.94 0.94 0.94
N-BBENZENE 2.63 2.63 2.63 2.63
1DECENE
NC11 2.14 2.14 2.14 2.14
N-PENTYLE-BZ 2.37 2.37 2.37 2.37
1-UNDECENE
NC12 10.71 10.71 10.71 10.71
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.02 0.02 0.02 0.02
MESD
DMDS
B-SULPHIDE

Total kg/h 48 267 50 650 50 650 50 650


Total kmol/h 458.33 480.96 480.96 480.96

REF: INRAD 22/02/08 13:06:33 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (WEIGHT PERCENT)
Job Number Unit Type Page
Process licensing 07-3091 40 1WP 36/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4001 04/04/08 MIIN GZA 0

HYDROTREATED C5+
Flow rate unit : wt % CUT TO STORAGE
29
H2O
H2
N2
H2S
METHANE
ETHANE
PROPANE
IBUTANE 0.56
BUTANE 3.00
IPENTANE 4.64
PENTANE 4.68
HEXANE 5.81
2MPENTAN 6.89
CYCLOHEXANE 0.20
HEPTANE 5.64
2-MHEXANE 6.32
CYCLOHEPTANE 4.17
TOLUENE 1.91
OCTANE 4.14
2-MHEPTANE 5.98
CYCLOOCTANE 5.83
EBENZENE 1.61
1OCTENE
NONANE 2.91
2-MOCTANE 4.07
CYCLONONANE 3.43
N-PBENZENE 3.33
1NONENE
DECANE 2.46
2-MNONANE 3.62
CYCLODECANE 0.94
N-BBENZENE 2.63
1DECENE
NC11 2.14
N-PENTYLE-BZ 2.37
1-UNDECENE
NC12 10.71
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.02
MESD
DMDS
B-SULPHIDE

Total kg/h 50 650


Total kmol/h 480.96

REF: INRAD 22/02/08 13:06:33 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 37/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE SOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

C5+ FEED FEED TO REACTION H2 MAKE-UP RECYCLE GAS


Flow rate unit : mol fraction SECTION
1 2 3 4
H2O
H2 0.9950 0.7566
N2 0.0020 0.0006
H2S 0.0238
METHANE 0.0030 0.1520
ETHANE 0.0013
PROPANE 0.0137 0.0137 0.0126
IBUTANE 0.0270 0.0270 0.0107
BUTANE 0.0634 0.0634 0.0192
IPENTANE 0.0541 0.0541 0.0072
PENTANE 0.0585 0.0585 0.0061
HEXANE 0.0610 0.0610 0.0024
2MPENTAN 0.0703 0.0703 0.0036
CYCLOHEXANE 0.0021 0.0021 0.0001
HEPTANE 0.0533 0.0533 0.0008
2-MHEXANE 0.0595 0.0595 0.0011
CYCLOHEPTANE 0.0401 0.0401 0.0003
TOLUENE 0.0212 0.0212 0.0003
OCTANE 0.0362 0.0362 0.0002
2-MHEPTANE 0.0526 0.0526 0.0004
CYCLOOCTANE 0.0535 0.0535 0.0001
EBENZENE 0.0267 0.0267 0.0002
1OCTENE 0.0001 0.0001
NONANE 0.0231 0.0231 0.0001
2-MOCTANE 0.0327 0.0327 0.0001
CYCLONONANE 0.0282 0.0282
N-PBENZENE 0.0263 0.0263 0.0001
1NONENE 0.0003 0.0003
DECANE 0.0195 0.0195
2-MNONANE 0.0265 0.0265
CYCLODECANE 0.0070 0.0070
N-BBENZENE 0.0204 0.0204
1DECENE 0.0002 0.0002
NC11 0.0226 0.0226
N-PENTYLE-BZ 0.0194 0.0194
1-UNDECENE 0.0002 0.0002
NC12 0.0656 0.0656
M-MERCAPTAN 0.0077 0.0077
E-MERCAPTAN 0.0005 0.0005
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL 0.0025 0.0025
COS
DMS 0.0039 0.0039
MESD 0.0001 0.0001
DMDS 0.0002 0.0002
B-SULPHIDE 0.0001 0.0001

Total kmol/h 501.40 501.40 15.89 291.92


Total kg/h 52 360 52 360 34 2 628

REF: INRAD 22/02/08 16:22:08 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 38/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE SOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

REACTOR FEED HEATER INLET REACTOR INLET REACTOR OUTLET


Flow rate unit : mol fraction EFFLUENT EXCHANGER
INLET
5 6 7 8
H2O
H2 0.2784 0.2784 0.2784 0.2662
N2 0.0002 0.0002 0.0002 0.0002
H2S 0.0088 0.0088 0.0088 0.0182
METHANE 0.0559 0.0559 0.0559 0.0657
ETHANE 0.0005 0.0005 0.0005 0.0008
PROPANE 0.0133 0.0133 0.0133 0.0133
IBUTANE 0.0210 0.0210 0.0210 0.0211
BUTANE 0.0471 0.0471 0.0471 0.0473
IPENTANE 0.0368 0.0368 0.0368 0.0369
PENTANE 0.0392 0.0392 0.0392 0.0392
HEXANE 0.0394 0.0394 0.0394 0.0410
2MPENTAN 0.0457 0.0457 0.0457 0.0458
CYCLOHEXANE 0.0013 0.0013 0.0013 0.0013
HEPTANE 0.0340 0.0340 0.0340 0.0340
2-MHEXANE 0.0380 0.0380 0.0380 0.0380
CYCLOHEPTANE 0.0255 0.0255 0.0255 0.0255
TOLUENE 0.0135 0.0135 0.0135 0.0135
OCTANE 0.0229 0.0229 0.0229 0.0230
2-MHEPTANE 0.0334 0.0334 0.0334 0.0334
CYCLOOCTANE 0.0339 0.0339 0.0339 0.0339
EBENZENE 0.0169 0.0169 0.0169 0.0169
1OCTENE 0.0001 0.0001 0.0001
NONANE 0.0146 0.0146 0.0146 0.0148
2-MOCTANE 0.0207 0.0207 0.0207 0.0207
CYCLONONANE 0.0178 0.0178 0.0178 0.0178
N-PBENZENE 0.0166 0.0166 0.0166 0.0166
1NONENE 0.0002 0.0002 0.0002
DECANE 0.0124 0.0124 0.0124 0.0125
2-MNONANE 0.0167 0.0167 0.0167 0.0167
CYCLODECANE 0.0044 0.0044 0.0044 0.0044
N-BBENZENE 0.0129 0.0129 0.0129 0.0129
1DECENE 0.0001 0.0001 0.0001
NC11 0.0143 0.0143 0.0143 0.0144
N-PENTYLE-BZ 0.0123 0.0123 0.0123 0.0123
1-UNDECENE 0.0001 0.0001 0.0001
NC12 0.0415 0.0415 0.0415 0.0415
M-MERCAPTAN 0.0049 0.0049 0.0049
E-MERCAPTAN 0.0003 0.0003 0.0003
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL 0.0016 0.0016 0.0016
COS
DMS 0.0025 0.0025 0.0025 0.0002
MESD
DMDS 0.0001 0.0001 0.0001
B-SULPHIDE 0.0001 0.0001 0.0001

Total kmol/h 793.32 793.32 793.32 792.97


Total kg/h 54 988 54 988 54 988 54 988

REF: INRAD 22/02/08 16:22:08 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 39/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE SOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

REACTOR FEED REACTOR EFFLUENT REACTOR EFFLUENT SEPARATOR VAPOR


Flow rate unit : mol fraction EFFLUENT EXCHANGER AIR COOLER INLET AIR COOLER OUTLET OUTLET
OUTLET
9 10 11 12
H2O
H2 0.2662 0.2662 0.2662 0.7429
N2 0.0002 0.0002 0.0002 0.0005
H2S 0.0182 0.0182 0.0182 0.0252
METHANE 0.0657 0.0657 0.0657 0.1605
ETHANE 0.0008 0.0008 0.0008 0.0014
PROPANE 0.0133 0.0133 0.0133 0.0133
IBUTANE 0.0211 0.0211 0.0211 0.0114
BUTANE 0.0473 0.0473 0.0473 0.0203
IPENTANE 0.0369 0.0369 0.0369 0.0076
PENTANE 0.0392 0.0392 0.0392 0.0065
HEXANE 0.0410 0.0410 0.0410 0.0025
2MPENTAN 0.0458 0.0458 0.0458 0.0038
CYCLOHEXANE 0.0013 0.0013 0.0013 0.0001
HEPTANE 0.0340 0.0340 0.0340 0.0008
2-MHEXANE 0.0380 0.0380 0.0380 0.0012
CYCLOHEPTANE 0.0255 0.0255 0.0255 0.0003
TOLUENE 0.0135 0.0135 0.0135 0.0003
OCTANE 0.0230 0.0230 0.0230 0.0002
2-MHEPTANE 0.0334 0.0334 0.0334 0.0004
CYCLOOCTANE 0.0339 0.0339 0.0339 0.0001
EBENZENE 0.0169 0.0169 0.0169 0.0002
1OCTENE
NONANE 0.0148 0.0148 0.0148 0.0001
2-MOCTANE 0.0207 0.0207 0.0207 0.0001
CYCLONONANE 0.0178 0.0178 0.0178
N-PBENZENE 0.0166 0.0166 0.0166 0.0001
1NONENE
DECANE 0.0125 0.0125 0.0125
2-MNONANE 0.0167 0.0167 0.0167
CYCLODECANE 0.0044 0.0044 0.0044
N-BBENZENE 0.0129 0.0129 0.0129
1DECENE
NC11 0.0144 0.0144 0.0144
N-PENTYLE-BZ 0.0123 0.0123 0.0123
1-UNDECENE
NC12 0.0415 0.0415 0.0415
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.0002 0.0002 0.0002
MESD
DMDS
B-SULPHIDE

Total kmol/h 792.97 792.97 792.97 276.03


Total kg/h 54 988 54 988 54 988 2 595

REF: INRAD 22/02/08 16:22:08 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 40/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE SOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

RECYCLE COMPRESSOR RECYCLE COMPRESSOR REACTED C5+CUT TO STRIPPER FEED


Flow rate unit : mol fraction SUCTION DISCHARGE STRIPPER
13 14 15 16
H2O
H2 0.7429 0.7429 0.0117 0.0117
N2 0.0005 0.0005 0.0001 0.0001
H2S 0.0252 0.0252 0.0144 0.0144
METHANE 0.1605 0.1605 0.0150 0.0150
ETHANE 0.0014 0.0014 0.0005 0.0005
PROPANE 0.0133 0.0133 0.0133 0.0133
IBUTANE 0.0114 0.0114 0.0262 0.0262
BUTANE 0.0203 0.0203 0.0617 0.0617
IPENTANE 0.0076 0.0076 0.0525 0.0525
PENTANE 0.0065 0.0065 0.0567 0.0567
HEXANE 0.0025 0.0025 0.0616 0.0616
2MPENTAN 0.0038 0.0038 0.0682 0.0682
CYCLOHEXANE 0.0001 0.0001 0.0020 0.0020
HEPTANE 0.0008 0.0008 0.0517 0.0517
2-MHEXANE 0.0012 0.0012 0.0577 0.0577
CYCLOHEPTANE 0.0003 0.0003 0.0389 0.0389
TOLUENE 0.0003 0.0003 0.0205 0.0205
OCTANE 0.0002 0.0002 0.0352 0.0352
2-MHEPTANE 0.0004 0.0004 0.0510 0.0510
CYCLOOCTANE 0.0001 0.0001 0.0519 0.0519
EBENZENE 0.0002 0.0002 0.0259 0.0259
1OCTENE
NONANE 0.0001 0.0001 0.0226 0.0226
2-MOCTANE 0.0001 0.0001 0.0317 0.0317
CYCLONONANE 0.0274 0.0274
N-PBENZENE 0.0001 0.0001 0.0255 0.0255
1NONENE
DECANE 0.0191 0.0191
2-MNONANE 0.0257 0.0257
CYCLODECANE 0.0068 0.0068
N-BBENZENE 0.0197 0.0197
1DECENE
NC11 0.0221 0.0221
N-PENTYLE-BZ 0.0188 0.0188
1-UNDECENE
NC12 0.0636 0.0636
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.0002 0.0002
MESD
DMDS
B-SULPHIDE

Total kmol/h 276.03 276.03 516.94 516.94


Total kg/h 2 595 2 595 52 393 52 393

REF: INRAD 22/02/08 16:22:08 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 41/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE SOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

STRIPPER AIR C5+ CUT AIR TRIM CONDENSER PURGED GAS


Flow rate unit : mol fraction CONDENSER INLET CONDENSER OUTLET OUTLET
17 18 19 20
H2O 0.0001
H2 0.0227 0.0227 0.0227 0.1186
N2 0.0002 0.0002 0.0002 0.0006
H2S 0.0594 0.0594 0.0594 0.1458
METHANE 0.0352 0.0352 0.0352 0.1519
ETHANE 0.0018 0.0018 0.0018 0.0049
PROPANE 0.1009 0.1009 0.1009 0.1350
IBUTANE 0.2898 0.2898 0.2898 0.1974
BUTANE 0.4494 0.4494 0.4494 0.2363
IPENTANE 0.0257 0.0257 0.0257 0.0066
PENTANE 0.0128 0.0128 0.0128 0.0026
HEXANE 0.0005 0.0005 0.0005
2MPENTAN 0.0012 0.0012 0.0012 0.0001
CYCLOHEXANE
HEPTANE
2-MHEXANE
CYCLOHEPTANE
TOLUENE
OCTANE
2-MHEPTANE
CYCLOOCTANE
EBENZENE
1OCTENE
NONANE
2-MOCTANE
CYCLONONANE
N-PBENZENE
1NONENE
DECANE
2-MNONANE
CYCLODECANE
N-BBENZENE
1DECENE
NC11
N-PENTYLE-BZ
1-UNDECENE
NC12
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.0002 0.0002 0.0002 0.0001
MESD
DMDS
B-SULPHIDE

Total kmol/h 278.55 278.55 278.55 51.02


Total kg/h 14 781 14 781 14 781 2 023

REF: INRAD 22/02/08 16:22:08 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 42/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE SOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

STRIPPER REFLUX STRIPPER BOTTOM STRIPPER REBOILER STRIPPER FIRE HEATER


Flow rate unit : mol fraction PUMPS INLET INLET
21 22 23 24
H2O
H2 0.0011
N2
H2S 0.0400
METHANE 0.0090
ETHANE 0.0011
PROPANE 0.0933
IBUTANE 0.3106 0.0075 0.0075 0.0075
BUTANE 0.4972 0.0426 0.0426 0.0426
IPENTANE 0.0300 0.0575 0.0575 0.0575
PENTANE 0.0151 0.0627 0.0627 0.0627
HEXANE 0.0006 0.0683 0.0683 0.0683
2MPENTAN 0.0015 0.0756 0.0756 0.0756
CYCLOHEXANE 0.0022 0.0022 0.0022
HEPTANE 0.0574 0.0574 0.0574
2-MHEXANE 0.0001 0.0640 0.0640 0.0640
CYCLOHEPTANE 0.0432 0.0432 0.0432
TOLUENE 0.0228 0.0228 0.0228
OCTANE 0.0390 0.0390 0.0390
2-MHEPTANE 0.0566 0.0566 0.0566
CYCLOOCTANE 0.0576 0.0576 0.0576
EBENZENE 0.0287 0.0287 0.0287
1OCTENE
NONANE 0.0251 0.0251 0.0251
2-MOCTANE 0.0351 0.0351 0.0351
CYCLONONANE 0.0304 0.0304 0.0304
N-PBENZENE 0.0283 0.0283 0.0283
1NONENE
DECANE 0.0212 0.0212 0.0212
2-MNONANE 0.0285 0.0285 0.0285
CYCLODECANE 0.0075 0.0075 0.0075
N-BBENZENE 0.0219 0.0219 0.0219
1DECENE
NC11 0.0246 0.0246 0.0246
N-PENTYLE-BZ 0.0209 0.0209 0.0209
1-UNDECENE
NC12 0.0706 0.0706 0.0706
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.0002 0.0003 0.0003 0.0003
MESD
DMDS
B-SULPHIDE

Total kmol/h 227.53 911.63 445.72 445.72


Total kg/h 12 758 98 557 48 187 48 187

REF: INRAD 22/02/08 16:22:08 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 43/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE SOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

STRIPPER FIRE HEATER STRIPPER TUBE SIDE STRIPPER TUBE SIDE STRIPPER AIR COOLER
Flow rate unit : mol fraction OUTLET EXCHANGERS INLET EXCHANGERS OUTLET OUTLET
25 26 27 28
H2O
H2
N2
H2S
METHANE
ETHANE
PROPANE
IBUTANE 0.0075 0.0075 0.0075 0.0075
BUTANE 0.0426 0.0426 0.0426 0.0426
IPENTANE 0.0575 0.0575 0.0575 0.0575
PENTANE 0.0627 0.0627 0.0627 0.0627
HEXANE 0.0683 0.0683 0.0683 0.0683
2MPENTAN 0.0756 0.0756 0.0756 0.0756
CYCLOHEXANE 0.0022 0.0022 0.0022 0.0022
HEPTANE 0.0574 0.0574 0.0574 0.0574
2-MHEXANE 0.0640 0.0640 0.0640 0.0640
CYCLOHEPTANE 0.0432 0.0432 0.0432 0.0432
TOLUENE 0.0228 0.0228 0.0228 0.0228
OCTANE 0.0390 0.0390 0.0390 0.0390
2-MHEPTANE 0.0566 0.0566 0.0566 0.0566
CYCLOOCTANE 0.0576 0.0576 0.0576 0.0576
EBENZENE 0.0287 0.0287 0.0287 0.0287
1OCTENE
NONANE 0.0251 0.0251 0.0251 0.0251
2-MOCTANE 0.0351 0.0351 0.0351 0.0351
CYCLONONANE 0.0304 0.0304 0.0304 0.0304
N-PBENZENE 0.0283 0.0283 0.0283 0.0283
1NONENE
DECANE 0.0212 0.0212 0.0212 0.0212
2-MNONANE 0.0285 0.0285 0.0285 0.0285
CYCLODECANE 0.0075 0.0075 0.0075 0.0075
N-BBENZENE 0.0219 0.0219 0.0219 0.0219
1DECENE
NC11 0.0246 0.0246 0.0246 0.0246
N-PENTYLE-BZ 0.0209 0.0209 0.0209 0.0209
1-UNDECENE
NC12 0.0706 0.0706 0.0706 0.0706
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.0003 0.0003 0.0003 0.0003
MESD
DMDS
B-SULPHIDE

Total kmol/h 445.72 465.91 465.91 465.91


Total kg/h 48 187 50 370 50 370 50 370

REF: INRAD 22/02/08 16:22:08 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 44/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE SOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

HYDROTREATED C5+
Flow rate unit : mol fraction CUT TO STORAGE
29
H2O
H2
N2
H2S
METHANE
ETHANE
PROPANE
IBUTANE 0.0075
BUTANE 0.0426
IPENTANE 0.0575
PENTANE 0.0627
HEXANE 0.0683
2MPENTAN 0.0756
CYCLOHEXANE 0.0022
HEPTANE 0.0574
2-MHEXANE 0.0640
CYCLOHEPTANE 0.0432
TOLUENE 0.0228
OCTANE 0.0390
2-MHEPTANE 0.0566
CYCLOOCTANE 0.0576
EBENZENE 0.0287
1OCTENE
NONANE 0.0251
2-MOCTANE 0.0351
CYCLONONANE 0.0304
N-PBENZENE 0.0283
1NONENE
DECANE 0.0212
2-MNONANE 0.0285
CYCLODECANE 0.0075
N-BBENZENE 0.0219
1DECENE
NC11 0.0246
N-PENTYLE-BZ 0.0209
1-UNDECENE
NC12 0.0706
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.0003
MESD
DMDS
B-SULPHIDE

Total kmol/h 465.91


Total kg/h 50 370

REF: INRAD 22/02/08 16:22:08 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 45/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

C5+ FEED FEED TO REACTION H2 MAKE-UP RECYCLE GAS


Flow rate unit : mol fraction SECTION
1 2 3 4
H2O
H2 0.9950 0.7566
N2 0.0020 0.0006
H2S 0.0238
METHANE 0.0030 0.1520
ETHANE 0.0013
PROPANE 0.0137 0.0137 0.0126
IBUTANE 0.0270 0.0270 0.0107
BUTANE 0.0634 0.0634 0.0192
IPENTANE 0.0541 0.0541 0.0072
PENTANE 0.0585 0.0585 0.0061
HEXANE 0.0610 0.0610 0.0024
2MPENTAN 0.0703 0.0703 0.0036
CYCLOHEXANE 0.0021 0.0021 0.0001
HEPTANE 0.0533 0.0533 0.0008
2-MHEXANE 0.0595 0.0595 0.0011
CYCLOHEPTANE 0.0401 0.0401 0.0003
TOLUENE 0.0212 0.0212 0.0003
OCTANE 0.0362 0.0362 0.0002
2-MHEPTANE 0.0526 0.0526 0.0004
CYCLOOCTANE 0.0535 0.0535 0.0001
EBENZENE 0.0267 0.0267 0.0002
1OCTENE 0.0001 0.0001
NONANE 0.0231 0.0231 0.0001
2-MOCTANE 0.0327 0.0327 0.0001
CYCLONONANE 0.0282 0.0282
N-PBENZENE 0.0263 0.0263 0.0001
1NONENE 0.0003 0.0003
DECANE 0.0195 0.0195
2-MNONANE 0.0265 0.0265
CYCLODECANE 0.0070 0.0070
N-BBENZENE 0.0204 0.0204
1DECENE 0.0002 0.0002
NC11 0.0226 0.0226
N-PENTYLE-BZ 0.0194 0.0194
1-UNDECENE 0.0002 0.0002
NC12 0.0656 0.0656
M-MERCAPTAN 0.0077 0.0077
E-MERCAPTAN 0.0005 0.0005
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL 0.0025 0.0025
COS
DMS 0.0039 0.0039
MESD 0.0001 0.0001
DMDS 0.0002 0.0002
B-SULPHIDE 0.0001 0.0001

Total kmol/h 501.40 501.40 15.89 291.92


Total kg/h 52 360 52 360 34 2 628

REF: INRAD 22/02/08 16:21:58 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 46/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

REACTOR FEED HEATER INLET REACTOR INLET REACTOR OUTLET


Flow rate unit : mol fraction EFFLUENT EXCHANGER
INLET
5 6 7 8
H2O
H2 0.2784 0.2784 0.2784 0.2662
N2 0.0002 0.0002 0.0002 0.0002
H2S 0.0088 0.0088 0.0088 0.0182
METHANE 0.0559 0.0559 0.0559 0.0657
ETHANE 0.0005 0.0005 0.0005 0.0008
PROPANE 0.0133 0.0133 0.0133 0.0133
IBUTANE 0.0210 0.0210 0.0210 0.0211
BUTANE 0.0471 0.0471 0.0471 0.0473
IPENTANE 0.0368 0.0368 0.0368 0.0369
PENTANE 0.0392 0.0392 0.0392 0.0392
HEXANE 0.0394 0.0394 0.0394 0.0410
2MPENTAN 0.0457 0.0457 0.0457 0.0458
CYCLOHEXANE 0.0013 0.0013 0.0013 0.0013
HEPTANE 0.0340 0.0340 0.0340 0.0340
2-MHEXANE 0.0380 0.0380 0.0380 0.0380
CYCLOHEPTANE 0.0255 0.0255 0.0255 0.0255
TOLUENE 0.0135 0.0135 0.0135 0.0135
OCTANE 0.0229 0.0229 0.0229 0.0230
2-MHEPTANE 0.0334 0.0334 0.0334 0.0334
CYCLOOCTANE 0.0339 0.0339 0.0339 0.0339
EBENZENE 0.0169 0.0169 0.0169 0.0169
1OCTENE 0.0001 0.0001 0.0001
NONANE 0.0146 0.0146 0.0146 0.0148
2-MOCTANE 0.0207 0.0207 0.0207 0.0207
CYCLONONANE 0.0178 0.0178 0.0178 0.0178
N-PBENZENE 0.0166 0.0166 0.0166 0.0166
1NONENE 0.0002 0.0002 0.0002
DECANE 0.0124 0.0124 0.0124 0.0125
2-MNONANE 0.0167 0.0167 0.0167 0.0167
CYCLODECANE 0.0044 0.0044 0.0044 0.0044
N-BBENZENE 0.0129 0.0129 0.0129 0.0129
1DECENE 0.0001 0.0001 0.0001
NC11 0.0143 0.0143 0.0143 0.0144
N-PENTYLE-BZ 0.0123 0.0123 0.0123 0.0123
1-UNDECENE 0.0001 0.0001 0.0001
NC12 0.0415 0.0415 0.0415 0.0415
M-MERCAPTAN 0.0049 0.0049 0.0049
E-MERCAPTAN 0.0003 0.0003 0.0003
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL 0.0016 0.0016 0.0016
COS
DMS 0.0025 0.0025 0.0025 0.0002
MESD
DMDS 0.0001 0.0001 0.0001
B-SULPHIDE 0.0001 0.0001 0.0001

Total kmol/h 793.32 793.32 793.32 792.97


Total kg/h 54 988 54 988 54 988 54 988

REF: INRAD 22/02/08 16:21:58 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 47/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

Flow rate unit : mol fraction REACTOR FEED REACTOR EFFLUENT REACTOR EFFLUENT SEPARATOR VAPOR
EFFLUENT EXCHANGER AIR COOLER INLET AIR COOLER OUTLET OUTLET
OUTLET
9 10 11 12
H2O
H2 0.2662 0.2662 0.2662 0.7429
N2 0.0002 0.0002 0.0002 0.0005
H2S 0.0182 0.0182 0.0182 0.0252
METHANE 0.0657 0.0657 0.0657 0.1605
ETHANE 0.0008 0.0008 0.0008 0.0014
PROPANE 0.0133 0.0133 0.0133 0.0133
IBUTANE 0.0211 0.0211 0.0211 0.0114
BUTANE 0.0473 0.0473 0.0473 0.0203
IPENTANE 0.0369 0.0369 0.0369 0.0076
PENTANE 0.0392 0.0392 0.0392 0.0065
HEXANE 0.0410 0.0410 0.0410 0.0025
2MPENTAN 0.0458 0.0458 0.0458 0.0038
CYCLOHEXANE 0.0013 0.0013 0.0013 0.0001
HEPTANE 0.0340 0.0340 0.0340 0.0008
2-MHEXANE 0.0380 0.0380 0.0380 0.0012
CYCLOHEPTANE 0.0255 0.0255 0.0255 0.0003
TOLUENE 0.0135 0.0135 0.0135 0.0003
OCTANE 0.0230 0.0230 0.0230 0.0002
2-MHEPTANE 0.0334 0.0334 0.0334 0.0004
CYCLOOCTANE 0.0339 0.0339 0.0339 0.0001
EBENZENE 0.0169 0.0169 0.0169 0.0002
1OCTENE
NONANE 0.0148 0.0148 0.0148 0.0001
2-MOCTANE 0.0207 0.0207 0.0207 0.0001
CYCLONONANE 0.0178 0.0178 0.0178
N-PBENZENE 0.0166 0.0166 0.0166 0.0001
1NONENE
DECANE 0.0125 0.0125 0.0125
2-MNONANE 0.0167 0.0167 0.0167
CYCLODECANE 0.0044 0.0044 0.0044
N-BBENZENE 0.0129 0.0129 0.0129
1DECENE
NC11 0.0144 0.0144 0.0144
N-PENTYLE-BZ 0.0123 0.0123 0.0123
1-UNDECENE
NC12 0.0415 0.0415 0.0415
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.0002 0.0002 0.0002
MESD
DMDS
B-SULPHIDE

Total kmol/h 792.97 792.97 792.97 276.03


Total kg/h 54 988 54 988 54 988 2 595

REF: INRAD 22/02/08 16:21:58 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 48/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

RECYCLE COMPRESSOR RECYCLE COMPRESSOR REACTED C5+CUT TO STRIPPER FEED


Flow rate unit : mol fraction SUCTION DISCHARGE STRIPPER
13 14 15 16
H2O
H2 0.7429 0.7429 0.0117 0.0117
N2 0.0005 0.0005 0.0001 0.0001
H2S 0.0252 0.0252 0.0144 0.0144
METHANE 0.1605 0.1605 0.0150 0.0150
ETHANE 0.0014 0.0014 0.0005 0.0005
PROPANE 0.0133 0.0133 0.0133 0.0133
IBUTANE 0.0114 0.0114 0.0262 0.0262
BUTANE 0.0203 0.0203 0.0617 0.0617
IPENTANE 0.0076 0.0076 0.0525 0.0525
PENTANE 0.0065 0.0065 0.0567 0.0567
HEXANE 0.0025 0.0025 0.0616 0.0616
2MPENTAN 0.0038 0.0038 0.0682 0.0682
CYCLOHEXANE 0.0001 0.0001 0.0020 0.0020
HEPTANE 0.0008 0.0008 0.0517 0.0517
2-MHEXANE 0.0012 0.0012 0.0577 0.0577
CYCLOHEPTANE 0.0003 0.0003 0.0389 0.0389
TOLUENE 0.0003 0.0003 0.0205 0.0205
OCTANE 0.0002 0.0002 0.0352 0.0352
2-MHEPTANE 0.0004 0.0004 0.0510 0.0510
CYCLOOCTANE 0.0001 0.0001 0.0519 0.0519
EBENZENE 0.0002 0.0002 0.0259 0.0259
1OCTENE
NONANE 0.0001 0.0001 0.0226 0.0226
2-MOCTANE 0.0001 0.0001 0.0317 0.0317
CYCLONONANE 0.0274 0.0274
N-PBENZENE 0.0001 0.0001 0.0255 0.0255
1NONENE
DECANE 0.0191 0.0191
2-MNONANE 0.0257 0.0257
CYCLODECANE 0.0068 0.0068
N-BBENZENE 0.0197 0.0197
1DECENE
NC11 0.0221 0.0221
N-PENTYLE-BZ 0.0188 0.0188
1-UNDECENE
NC12 0.0636 0.0636
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.0002 0.0002
MESD
DMDS
B-SULPHIDE

Total kmol/h 276.03 276.03 516.94 516.94


Total kg/h 2 595 2 595 52 393 52 393

REF: INRAD 22/02/08 16:21:58 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 49/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

STRIPPER AIR C5+ CUT AIR TRIM CONDENSER PURGED GAS


Flow rate unit : mol fraction CONDENSER INLET CONDENSER OUTLET OUTLET
17 18 19 20
H2O 0.0001
H2 0.0227 0.0227 0.0227 0.1186
N2 0.0002 0.0002 0.0002 0.0006
H2S 0.0594 0.0594 0.0594 0.1458
METHANE 0.0352 0.0352 0.0352 0.1519
ETHANE 0.0018 0.0018 0.0018 0.0049
PROPANE 0.1009 0.1009 0.1009 0.1350
IBUTANE 0.2898 0.2898 0.2898 0.1974
BUTANE 0.4494 0.4494 0.4494 0.2363
IPENTANE 0.0257 0.0257 0.0257 0.0066
PENTANE 0.0128 0.0128 0.0128 0.0026
HEXANE 0.0005 0.0005 0.0005
2MPENTAN 0.0012 0.0012 0.0012 0.0001
CYCLOHEXANE
HEPTANE
2-MHEXANE
CYCLOHEPTANE
TOLUENE
OCTANE
2-MHEPTANE
CYCLOOCTANE
EBENZENE
1OCTENE
NONANE
2-MOCTANE
CYCLONONANE
N-PBENZENE
1NONENE
DECANE
2-MNONANE
CYCLODECANE
N-BBENZENE
1DECENE
NC11
N-PENTYLE-BZ
1-UNDECENE
NC12
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.0002 0.0002 0.0002 0.0001
MESD
DMDS
B-SULPHIDE

Total kmol/h 278.55 278.55 278.55 51.02


Total kg/h 14 781 14 781 14 781 2 023

REF: INRAD 22/02/08 16:21:58 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 50/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

STRIPPER REFLUX STRIPPER BOTTOM STRIPPER REBOILER STRIPPER FIRE HEATER


Flow rate unit : mol fraction PUMPS INLET INLET
21 22 23 24
H2O
H2 0.0011
N2
H2S 0.0400
METHANE 0.0090
ETHANE 0.0011
PROPANE 0.0933
IBUTANE 0.3106 0.0075 0.0075 0.0075
BUTANE 0.4972 0.0426 0.0426 0.0426
IPENTANE 0.0300 0.0575 0.0575 0.0575
PENTANE 0.0151 0.0627 0.0627 0.0627
HEXANE 0.0006 0.0683 0.0683 0.0683
2MPENTAN 0.0015 0.0756 0.0756 0.0756
CYCLOHEXANE 0.0022 0.0022 0.0022
HEPTANE 0.0574 0.0574 0.0574
2-MHEXANE 0.0001 0.0640 0.0640 0.0640
CYCLOHEPTANE 0.0432 0.0432 0.0432
TOLUENE 0.0228 0.0228 0.0228
OCTANE 0.0390 0.0390 0.0390
2-MHEPTANE 0.0566 0.0566 0.0566
CYCLOOCTANE 0.0576 0.0576 0.0576
EBENZENE 0.0287 0.0287 0.0287
1OCTENE
NONANE 0.0251 0.0251 0.0251
2-MOCTANE 0.0351 0.0351 0.0351
CYCLONONANE 0.0304 0.0304 0.0304
N-PBENZENE 0.0283 0.0283 0.0283
1NONENE
DECANE 0.0212 0.0212 0.0212
2-MNONANE 0.0285 0.0285 0.0285
CYCLODECANE 0.0075 0.0075 0.0075
N-BBENZENE 0.0219 0.0219 0.0219
1DECENE
NC11 0.0246 0.0246 0.0246
N-PENTYLE-BZ 0.0209 0.0209 0.0209
1-UNDECENE
NC12 0.0706 0.0706 0.0706
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.0002 0.0003 0.0003 0.0003
MESD
DMDS
B-SULPHIDE

Total kmol/h 227.53 911.63 445.72 445.72


Total kg/h 12 758 98 557 48 187 48 187

REF: INRAD 22/02/08 16:21:58 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 51/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

STRIPPER FIRE HEATER STRIPPER TUBE SIDE STRIPPER TUBE SIDE STRIPPER AIR COOLER
Flow rate unit : mol fraction OUTLET EXCHANGERS INLET EXCHANGERS OUTLET OUTLET
25 26 27 28
H2O
H2
N2
H2S
METHANE
ETHANE
PROPANE
IBUTANE 0.0075 0.0075 0.0075 0.0075
BUTANE 0.0426 0.0426 0.0426 0.0426
IPENTANE 0.0575 0.0575 0.0575 0.0575
PENTANE 0.0627 0.0627 0.0627 0.0627
HEXANE 0.0683 0.0683 0.0683 0.0683
2MPENTAN 0.0756 0.0756 0.0756 0.0756
CYCLOHEXANE 0.0022 0.0022 0.0022 0.0022
HEPTANE 0.0574 0.0574 0.0574 0.0574
2-MHEXANE 0.0640 0.0640 0.0640 0.0640
CYCLOHEPTANE 0.0432 0.0432 0.0432 0.0432
TOLUENE 0.0228 0.0228 0.0228 0.0228
OCTANE 0.0390 0.0390 0.0390 0.0390
2-MHEPTANE 0.0566 0.0566 0.0566 0.0566
CYCLOOCTANE 0.0576 0.0576 0.0576 0.0576
EBENZENE 0.0287 0.0287 0.0287 0.0287
1OCTENE
NONANE 0.0251 0.0251 0.0251 0.0251
2-MOCTANE 0.0351 0.0351 0.0351 0.0351
CYCLONONANE 0.0304 0.0304 0.0304 0.0304
N-PBENZENE 0.0283 0.0283 0.0283 0.0283
1NONENE
DECANE 0.0212 0.0212 0.0212 0.0212
2-MNONANE 0.0285 0.0285 0.0285 0.0285
CYCLODECANE 0.0075 0.0075 0.0075 0.0075
N-BBENZENE 0.0219 0.0219 0.0219 0.0219
1DECENE
NC11 0.0246 0.0246 0.0246 0.0246
N-PENTYLE-BZ 0.0209 0.0209 0.0209 0.0209
1-UNDECENE
NC12 0.0706 0.0706 0.0706 0.0706
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.0003 0.0003 0.0003 0.0003
MESD
DMDS
B-SULPHIDE

Total kmol/h 445.72 465.91 465.91 465.91


Total kg/h 48 187 50 370 50 370 50 370

REF: INRAD 22/02/08 16:21:58 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 52/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : SUMMER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

HYDROTREATED C5+
Flow rate unit : mol fraction CUT TO STORAGE
29
H2O
H2
N2
H2S
METHANE
ETHANE
PROPANE
IBUTANE 0.0075
BUTANE 0.0426
IPENTANE 0.0575
PENTANE 0.0627
HEXANE 0.0683
2MPENTAN 0.0756
CYCLOHEXANE 0.0022
HEPTANE 0.0574
2-MHEXANE 0.0640
CYCLOHEPTANE 0.0432
TOLUENE 0.0228
OCTANE 0.0390
2-MHEPTANE 0.0566
CYCLOOCTANE 0.0576
EBENZENE 0.0287
1OCTENE
NONANE 0.0251
2-MOCTANE 0.0351
CYCLONONANE 0.0304
N-PBENZENE 0.0283
1NONENE
DECANE 0.0212
2-MNONANE 0.0285
CYCLODECANE 0.0075
N-BBENZENE 0.0219
1DECENE
NC11 0.0246
N-PENTYLE-BZ 0.0209
1-UNDECENE
NC12 0.0706
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.0003
MESD
DMDS
B-SULPHIDE

Total kmol/h 465.91


Total kg/h 50 370

REF: INRAD 22/02/08 16:21:58 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 53/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

C5+ FEED FEED TO REACTION H2 MAKE-UP RECYCLE GAS


Flow rate unit : mol fraction SECTION
1 2 3 4
H2O
H2 0.9950 0.7368
N2 0.0020 0.0006
H2S 0.0262
METHANE 0.0030 0.1691
ETHANE 0.0015
PROPANE 0.0065 0.0065 0.0058
IBUTANE 0.0315 0.0315 0.0124
BUTANE 0.0745 0.0745 0.0223
IPENTANE 0.0638 0.0638 0.0084
PENTANE 0.0639 0.0639 0.0067
HEXANE 0.0640 0.0640 0.0025
2MPENTAN 0.0786 0.0786 0.0039
CYCLOHEXANE 0.0023 0.0023 0.0001
HEPTANE 0.0553 0.0553 0.0008
2-MHEXANE 0.0620 0.0620 0.0012
CYCLOHEPTANE 0.0417 0.0417 0.0003
TOLUENE 0.0203 0.0203 0.0003
OCTANE 0.0355 0.0355 0.0002
2-MHEPTANE 0.0514 0.0514 0.0004
CYCLOOCTANE 0.0510 0.0510 0.0001
EBENZENE 0.0149 0.0149 0.0001
1OCTENE 0.0001 0.0001
NONANE 0.0220 0.0220 0.0001
2-MOCTANE 0.0312 0.0312 0.0001
CYCLONONANE 0.0267 0.0267
N-PBENZENE 0.0273 0.0273 0.0001
1NONENE 0.0002 0.0002
DECANE 0.0168 0.0168
2-MNONANE 0.0250 0.0250
CYCLODECANE 0.0066 0.0066
N-BBENZENE 0.0193 0.0193
1DECENE 0.0002 0.0002
NC11 0.0133 0.0133
N-PENTYLE-BZ 0.0157 0.0157
1-UNDECENE 0.0002 0.0002
NC12 0.0618 0.0618
M-MERCAPTAN 0.0087 0.0087
E-MERCAPTAN 0.0005 0.0005
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL 0.0024 0.0024
COS
DMS 0.0045 0.0045
MESD 0.0001 0.0001
DMDS 0.0002 0.0002
B-SULPHIDE 0.0001 0.0001

Total kmol/h 515.35 515.35 17.29 293.54


Total kg/h 52 620 52 620 36 2 779

REF: INRAD 22/02/08 16:22:43 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 54/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

REACTOR FEED HEATER INLET REACTOR INLET REACTOR OUTLET


Flow rate unit : mol fraction EFFLUENT EXCHANGER
INLET
5 6 7 8
H2O
H2 0.2674 0.2674 0.2674 0.2538
N2 0.0002 0.0002 0.0002 0.0002
H2S 0.0095 0.0095 0.0095 0.0199
METHANE 0.0613 0.0613 0.0613 0.0725
ETHANE 0.0005 0.0005 0.0005 0.0009
PROPANE 0.0062 0.0062 0.0062 0.0062
IBUTANE 0.0246 0.0246 0.0246 0.0246
BUTANE 0.0555 0.0555 0.0555 0.0557
IPENTANE 0.0437 0.0437 0.0437 0.0437
PENTANE 0.0431 0.0431 0.0431 0.0432
HEXANE 0.0416 0.0416 0.0416 0.0432
2MPENTAN 0.0515 0.0515 0.0515 0.0515
CYCLOHEXANE 0.0015 0.0015 0.0015 0.0015
HEPTANE 0.0355 0.0355 0.0355 0.0356
2-MHEXANE 0.0399 0.0399 0.0399 0.0399
CYCLOHEPTANE 0.0267 0.0267 0.0267 0.0267
TOLUENE 0.0131 0.0131 0.0131 0.0131
OCTANE 0.0227 0.0227 0.0227 0.0228
2-MHEPTANE 0.0329 0.0329 0.0329 0.0329
CYCLOOCTANE 0.0326 0.0326 0.0326 0.0326
EBENZENE 0.0095 0.0095 0.0095 0.0095
1OCTENE 0.0001 0.0001 0.0001
NONANE 0.0141 0.0141 0.0141 0.0142
2-MOCTANE 0.0199 0.0199 0.0199 0.0199
CYCLONONANE 0.0170 0.0170 0.0170 0.0171
N-PBENZENE 0.0174 0.0174 0.0174 0.0174
1NONENE 0.0002 0.0002 0.0002
DECANE 0.0107 0.0107 0.0107 0.0108
2-MNONANE 0.0159 0.0159 0.0159 0.0159
CYCLODECANE 0.0042 0.0042 0.0042 0.0042
N-BBENZENE 0.0123 0.0123 0.0123 0.0123
1DECENE 0.0001 0.0001 0.0001
NC11 0.0085 0.0085 0.0085 0.0086
N-PENTYLE-BZ 0.0100 0.0100 0.0100 0.0100
1-UNDECENE 0.0001 0.0001 0.0001
NC12 0.0394 0.0394 0.0394 0.0394
M-MERCAPTAN 0.0055 0.0055 0.0055
E-MERCAPTAN 0.0003 0.0003 0.0003
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL 0.0015 0.0015 0.0015
COS
DMS 0.0029 0.0029 0.0029 0.0002
MESD
DMDS 0.0001 0.0001 0.0001
B-SULPHIDE 0.0001 0.0001 0.0001

Total kmol/h 808.88 808.88 808.88 808.53


Total kg/h 55 399 55 399 55 399 55 399

REF: INRAD 22/02/08 16:22:43 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 55/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

REACTOR FEED REACTOR EFFLUENT REACTOR EFFLUENT SEPARATOR VAPOR


Flow rate unit : mol fraction EFFLUENT EXCHANGER AIR COOLER INLET AIR COOLER OUTLET OUTLET
OUTLET
9 10 11 12
H2O
H2 0.2538 0.2538 0.2538 0.7207
N2 0.0002 0.0002 0.0002 0.0006
H2S 0.0199 0.0199 0.0199 0.0278
METHANE 0.0725 0.0725 0.0725 0.1794
ETHANE 0.0009 0.0009 0.0009 0.0016
PROPANE 0.0062 0.0062 0.0062 0.0062
IBUTANE 0.0246 0.0246 0.0246 0.0132
BUTANE 0.0557 0.0557 0.0557 0.0236
IPENTANE 0.0437 0.0437 0.0437 0.0090
PENTANE 0.0432 0.0432 0.0432 0.0071
HEXANE 0.0432 0.0432 0.0432 0.0026
2MPENTAN 0.0515 0.0515 0.0515 0.0042
CYCLOHEXANE 0.0015 0.0015 0.0015 0.0001
HEPTANE 0.0356 0.0356 0.0356 0.0009
2-MHEXANE 0.0399 0.0399 0.0399 0.0013
CYCLOHEPTANE 0.0267 0.0267 0.0267 0.0004
TOLUENE 0.0131 0.0131 0.0131 0.0003
OCTANE 0.0228 0.0228 0.0228 0.0002
2-MHEPTANE 0.0329 0.0329 0.0329 0.0004
CYCLOOCTANE 0.0326 0.0326 0.0326 0.0001
EBENZENE 0.0095 0.0095 0.0095 0.0001
1OCTENE
NONANE 0.0142 0.0142 0.0142 0.0001
2-MOCTANE 0.0199 0.0199 0.0199 0.0001
CYCLONONANE 0.0171 0.0171 0.0171
N-PBENZENE 0.0174 0.0174 0.0174 0.0001
1NONENE
DECANE 0.0108 0.0108 0.0108
2-MNONANE 0.0159 0.0159 0.0159
CYCLODECANE 0.0042 0.0042 0.0042
N-BBENZENE 0.0123 0.0123 0.0123
1DECENE
NC11 0.0086 0.0086 0.0086
N-PENTYLE-BZ 0.0100 0.0100 0.0100
1-UNDECENE
NC12 0.0394 0.0394 0.0394
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.0002 0.0002 0.0002
MESD
DMDS
B-SULPHIDE

Total kmol/h 808.54 808.54 808.54 276.26


Total kg/h 55 399 55 399 55 399 2 742

REF: INRAD 22/02/08 16:22:43 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 56/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

RECYCLE COMPRESSOR RECYCLE COMPRESSOR REACTED C5+CUT TO STRIPPER FEED


Flow rate unit : mol fraction SUCTION DISCHARGE STRIPPER
13 14 15 16
H2O
H2 0.7207 0.7207 0.0116 0.0116
N2 0.0006 0.0006 0.0001 0.0001
H2S 0.0278 0.0278 0.0157 0.0157
METHANE 0.1794 0.1794 0.0170 0.0170
ETHANE 0.0016 0.0016 0.0006 0.0006
PROPANE 0.0062 0.0062 0.0063 0.0063
IBUTANE 0.0132 0.0132 0.0305 0.0305
BUTANE 0.0236 0.0236 0.0723 0.0723
IPENTANE 0.0090 0.0090 0.0618 0.0618
PENTANE 0.0071 0.0071 0.0619 0.0619
HEXANE 0.0026 0.0026 0.0642 0.0642
2MPENTAN 0.0042 0.0042 0.0761 0.0761
CYCLOHEXANE 0.0001 0.0001 0.0022 0.0022
HEPTANE 0.0009 0.0009 0.0536 0.0536
2-MHEXANE 0.0013 0.0013 0.0600 0.0600
CYCLOHEPTANE 0.0004 0.0004 0.0404 0.0404
TOLUENE 0.0003 0.0003 0.0197 0.0197
OCTANE 0.0002 0.0002 0.0345 0.0345
2-MHEPTANE 0.0004 0.0004 0.0498 0.0498
CYCLOOCTANE 0.0001 0.0001 0.0494 0.0494
EBENZENE 0.0001 0.0001 0.0144 0.0144
1OCTENE
NONANE 0.0001 0.0001 0.0216 0.0216
2-MOCTANE 0.0001 0.0001 0.0302 0.0302
CYCLONONANE 0.0259 0.0259
N-PBENZENE 0.0001 0.0001 0.0264 0.0264
1NONENE
DECANE 0.0164 0.0164
2-MNONANE 0.0242 0.0242
CYCLODECANE 0.0064 0.0064
N-BBENZENE 0.0187 0.0187
1DECENE
NC11 0.0130 0.0130
N-PENTYLE-BZ 0.0152 0.0152
1-UNDECENE
NC12 0.0598 0.0598
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.0003 0.0003
MESD
DMDS
B-SULPHIDE

Total kmol/h 276.25 276.25 532.28 532.28


Total kg/h 2 742 2 742 52 656 52 656

REF: INRAD 22/02/08 16:22:43 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 57/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

STRIPPER AIR C5+ CUT AIR TRIM CONDENSER PURGED GAS


Flow rate unit : mol fraction CONDENSER INLET CONDENSER OUTLET OUTLET
17 18 19 20
H2O
H2 0.0215 0.0215 0.0215 0.1199
N2 0.0002 0.0002 0.0002 0.0007
H2S 0.0653 0.0653 0.0653 0.1633
METHANE 0.0388 0.0388 0.0388 0.1759
ETHANE 0.0021 0.0021 0.0021 0.0058
PROPANE 0.0483 0.0483 0.0483 0.0649
IBUTANE 0.3262 0.3262 0.3262 0.2208
BUTANE 0.4605 0.4605 0.4605 0.2401
IPENTANE 0.0244 0.0244 0.0244 0.0062
PENTANE 0.0111 0.0111 0.0111 0.0022
HEXANE 0.0004 0.0004 0.0004
2MPENTAN 0.0011 0.0011 0.0011 0.0001
CYCLOHEXANE
HEPTANE
2-MHEXANE
CYCLOHEPTANE
TOLUENE
OCTANE
2-MHEPTANE
CYCLOOCTANE
EBENZENE
1OCTENE
NONANE
2-MOCTANE
CYCLONONANE
N-PBENZENE
1NONENE
DECANE
2-MNONANE
CYCLODECANE
N-BBENZENE
1DECENE
NC11
N-PENTYLE-BZ
1-UNDECENE
NC12
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.0002 0.0002 0.0002 0.0001
MESD
DMDS
B-SULPHIDE

Total kmol/h 299.45 299.45 299.45 51.33


Total kg/h 16 026 16 026 16 026 2 006

REF: INRAD 22/02/08 16:22:43 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 58/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

STRIPPER REFLUX STRIPPER BOTTOM STRIPPER REBOILER STRIPPER FIRE HEATER


Flow rate unit : mol fraction PUMPS INLET INLET
21 22 23 24
H2O
H2 0.0012
N2
H2S 0.0450
METHANE 0.0104
ETHANE 0.0013
PROPANE 0.0448
IBUTANE 0.3480 0.0102 0.0102 0.0102
BUTANE 0.5061 0.0544 0.0544 0.0544
IPENTANE 0.0282 0.0677 0.0677 0.0677
PENTANE 0.0130 0.0683 0.0683 0.0683
HEXANE 0.0005 0.0710 0.0710 0.0710
2MPENTAN 0.0012 0.0842 0.0842 0.0842
CYCLOHEXANE 0.0024 0.0024 0.0024
HEPTANE 0.0593 0.0593 0.0593
2-MHEXANE 0.0664 0.0664 0.0664
CYCLOHEPTANE 0.0447 0.0447 0.0447
TOLUENE 0.0218 0.0218 0.0218
OCTANE 0.0381 0.0381 0.0381
2-MHEPTANE 0.0551 0.0551 0.0551
CYCLOOCTANE 0.0547 0.0547 0.0547
EBENZENE 0.0159 0.0159 0.0159
1OCTENE
NONANE 0.0239 0.0239 0.0239
2-MOCTANE 0.0334 0.0334 0.0334
CYCLONONANE 0.0286 0.0286 0.0286
N-PBENZENE 0.0292 0.0292 0.0292
1NONENE
DECANE 0.0182 0.0182 0.0182
2-MNONANE 0.0268 0.0268 0.0268
CYCLODECANE 0.0070 0.0070 0.0070
N-BBENZENE 0.0207 0.0207 0.0207
1DECENE
NC11 0.0144 0.0144 0.0144
N-PENTYLE-BZ 0.0169 0.0169 0.0169
1-UNDECENE
NC12 0.0662 0.0662 0.0662
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN 0.0001 0.0001 0.0001
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.0002 0.0003 0.0003 0.0003
MESD
DMDS
B-SULPHIDE

Total kmol/h 248.12 939.29 458.33 458.33


Total kg/h 14 020 98 917 48 267 48 267

REF: INRAD 22/02/08 16:22:43 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 59/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

STRIPPER FIRE HEATER STRIPPER TUBE SIDE STRIPPER TUBE SIDE STRIPPER AIR COOLER
Flow rate unit : mol fraction OUTLET EXCHANGERS INLET EXCHANGERS OUTLET OUTLET
25 26 27 28
H2O
H2
N2
H2S
METHANE
ETHANE
PROPANE
IBUTANE 0.0102 0.0102 0.0102 0.0102
BUTANE 0.0544 0.0544 0.0544 0.0544
IPENTANE 0.0677 0.0677 0.0677 0.0677
PENTANE 0.0683 0.0683 0.0683 0.0683
HEXANE 0.0710 0.0710 0.0710 0.0710
2MPENTAN 0.0842 0.0842 0.0842 0.0842
CYCLOHEXANE 0.0024 0.0024 0.0024 0.0024
HEPTANE 0.0593 0.0593 0.0593 0.0593
2-MHEXANE 0.0664 0.0664 0.0664 0.0664
CYCLOHEPTANE 0.0447 0.0447 0.0447 0.0447
TOLUENE 0.0218 0.0218 0.0218 0.0218
OCTANE 0.0381 0.0381 0.0381 0.0381
2-MHEPTANE 0.0551 0.0551 0.0551 0.0551
CYCLOOCTANE 0.0547 0.0547 0.0547 0.0547
EBENZENE 0.0159 0.0159 0.0159 0.0159
1OCTENE
NONANE 0.0239 0.0239 0.0239 0.0239
2-MOCTANE 0.0334 0.0334 0.0334 0.0334
CYCLONONANE 0.0286 0.0286 0.0286 0.0286
N-PBENZENE 0.0292 0.0292 0.0292 0.0292
1NONENE
DECANE 0.0182 0.0182 0.0182 0.0182
2-MNONANE 0.0268 0.0268 0.0268 0.0268
CYCLODECANE 0.0070 0.0070 0.0070 0.0070
N-BBENZENE 0.0207 0.0207 0.0207 0.0207
1DECENE
NC11 0.0144 0.0144 0.0144 0.0144
N-PENTYLE-BZ 0.0169 0.0169 0.0169 0.0169
1-UNDECENE
NC12 0.0662 0.0662 0.0662 0.0662
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN 0.0001 0.0001 0.0001 0.0001
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.0003 0.0003 0.0003 0.0003
MESD
DMDS
B-SULPHIDE

Total kmol/h 458.33 480.96 480.96 480.96


Total kg/h 48 267 50 650 50 650 50 650

REF: INRAD 22/02/08 16:22:43 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 60/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

HYDROTREATED C5+
Flow rate unit : mol fraction CUT TO STORAGE
29
H2O
H2
N2
H2S
METHANE
ETHANE
PROPANE
IBUTANE 0.0102
BUTANE 0.0544
IPENTANE 0.0677
PENTANE 0.0683
HEXANE 0.0710
2MPENTAN 0.0842
CYCLOHEXANE 0.0024
HEPTANE 0.0593
2-MHEXANE 0.0664
CYCLOHEPTANE 0.0447
TOLUENE 0.0218
OCTANE 0.0381
2-MHEPTANE 0.0551
CYCLOOCTANE 0.0547
EBENZENE 0.0159
1OCTENE
NONANE 0.0239
2-MOCTANE 0.0334
CYCLONONANE 0.0286
N-PBENZENE 0.0292
1NONENE
DECANE 0.0182
2-MNONANE 0.0268
CYCLODECANE 0.0070
N-BBENZENE 0.0207
1DECENE
NC11 0.0144
N-PENTYLE-BZ 0.0169
1-UNDECENE
NC12 0.0662
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN 0.0001
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.0003
MESD
DMDS
B-SULPHIDE

Total kmol/h 480.96


Total kg/h 50 650

REF: INRAD 22/02/08 16:22:43 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 61/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

C5+ FEED FEED TO REACTION H2 MAKE-UP RECYCLE GAS


Flow rate unit : mol fraction SECTION
1 2 3 4
H2O
H2 0.9950 0.7368
N2 0.0020 0.0006
H2S 0.0262
METHANE 0.0030 0.1691
ETHANE 0.0015
PROPANE 0.0065 0.0065 0.0058
IBUTANE 0.0315 0.0315 0.0124
BUTANE 0.0745 0.0745 0.0223
IPENTANE 0.0638 0.0638 0.0084
PENTANE 0.0639 0.0639 0.0067
HEXANE 0.0640 0.0640 0.0025
2MPENTAN 0.0786 0.0786 0.0039
CYCLOHEXANE 0.0023 0.0023 0.0001
HEPTANE 0.0553 0.0553 0.0008
2-MHEXANE 0.0620 0.0620 0.0012
CYCLOHEPTANE 0.0417 0.0417 0.0003
TOLUENE 0.0203 0.0203 0.0003
OCTANE 0.0355 0.0355 0.0002
2-MHEPTANE 0.0514 0.0514 0.0004
CYCLOOCTANE 0.0510 0.0510 0.0001
EBENZENE 0.0149 0.0149 0.0001
1OCTENE 0.0001 0.0001
NONANE 0.0220 0.0220 0.0001
2-MOCTANE 0.0312 0.0312 0.0001
CYCLONONANE 0.0267 0.0267
N-PBENZENE 0.0273 0.0273 0.0001
1NONENE 0.0002 0.0002
DECANE 0.0168 0.0168
2-MNONANE 0.0250 0.0250
CYCLODECANE 0.0066 0.0066
N-BBENZENE 0.0193 0.0193
1DECENE 0.0002 0.0002
NC11 0.0133 0.0133
N-PENTYLE-BZ 0.0157 0.0157
1-UNDECENE 0.0002 0.0002
NC12 0.0618 0.0618
M-MERCAPTAN 0.0087 0.0087
E-MERCAPTAN 0.0005 0.0005
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL 0.0024 0.0024
COS
DMS 0.0045 0.0045
MESD 0.0001 0.0001
DMDS 0.0002 0.0002
B-SULPHIDE 0.0001 0.0001

Total kmol/h 515.35 515.35 17.29 293.54


Total kg/h 52 620 52 620 36 2 779

REF: INRAD 22/02/08 16:22:43 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 62/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

REACTOR FEED HEATER INLET REACTOR INLET REACTOR OUTLET


Flow rate unit : mol fraction EFFLUENT EXCHANGER
INLET
5 6 7 8
H2O
H2 0.2674 0.2674 0.2674 0.2538
N2 0.0002 0.0002 0.0002 0.0002
H2S 0.0095 0.0095 0.0095 0.0199
METHANE 0.0613 0.0613 0.0613 0.0725
ETHANE 0.0005 0.0005 0.0005 0.0009
PROPANE 0.0062 0.0062 0.0062 0.0062
IBUTANE 0.0246 0.0246 0.0246 0.0246
BUTANE 0.0555 0.0555 0.0555 0.0557
IPENTANE 0.0437 0.0437 0.0437 0.0437
PENTANE 0.0431 0.0431 0.0431 0.0432
HEXANE 0.0416 0.0416 0.0416 0.0432
2MPENTAN 0.0515 0.0515 0.0515 0.0515
CYCLOHEXANE 0.0015 0.0015 0.0015 0.0015
HEPTANE 0.0355 0.0355 0.0355 0.0356
2-MHEXANE 0.0399 0.0399 0.0399 0.0399
CYCLOHEPTANE 0.0267 0.0267 0.0267 0.0267
TOLUENE 0.0131 0.0131 0.0131 0.0131
OCTANE 0.0227 0.0227 0.0227 0.0228
2-MHEPTANE 0.0329 0.0329 0.0329 0.0329
CYCLOOCTANE 0.0326 0.0326 0.0326 0.0326
EBENZENE 0.0095 0.0095 0.0095 0.0095
1OCTENE 0.0001 0.0001 0.0001
NONANE 0.0141 0.0141 0.0141 0.0142
2-MOCTANE 0.0199 0.0199 0.0199 0.0199
CYCLONONANE 0.0170 0.0170 0.0170 0.0171
N-PBENZENE 0.0174 0.0174 0.0174 0.0174
1NONENE 0.0002 0.0002 0.0002
DECANE 0.0107 0.0107 0.0107 0.0108
2-MNONANE 0.0159 0.0159 0.0159 0.0159
CYCLODECANE 0.0042 0.0042 0.0042 0.0042
N-BBENZENE 0.0123 0.0123 0.0123 0.0123
1DECENE 0.0001 0.0001 0.0001
NC11 0.0085 0.0085 0.0085 0.0086
N-PENTYLE-BZ 0.0100 0.0100 0.0100 0.0100
1-UNDECENE 0.0001 0.0001 0.0001
NC12 0.0394 0.0394 0.0394 0.0394
M-MERCAPTAN 0.0055 0.0055 0.0055
E-MERCAPTAN 0.0003 0.0003 0.0003
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL 0.0015 0.0015 0.0015
COS
DMS 0.0029 0.0029 0.0029 0.0002
MESD
DMDS 0.0001 0.0001 0.0001
B-SULPHIDE 0.0001 0.0001 0.0001

Total kmol/h 808.88 808.88 808.88 808.53


Total kg/h 55 399 55 399 55 399 55 399

REF: INRAD 22/02/08 16:22:43 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 63/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

REACTOR FEED REACTOR EFFLUENT REACTOR EFFLUENT SEPARATOR VAPOR


Flow rate unit : mol fraction EFFLUENT EXCHANGER AIR COOLER INLET AIR COOLER OUTLET OUTLET
OUTLET
9 10 11 12
H2O
H2 0.2538 0.2538 0.2538 0.7207
N2 0.0002 0.0002 0.0002 0.0006
H2S 0.0199 0.0199 0.0199 0.0278
METHANE 0.0725 0.0725 0.0725 0.1794
ETHANE 0.0009 0.0009 0.0009 0.0016
PROPANE 0.0062 0.0062 0.0062 0.0062
IBUTANE 0.0246 0.0246 0.0246 0.0132
BUTANE 0.0557 0.0557 0.0557 0.0236
IPENTANE 0.0437 0.0437 0.0437 0.0090
PENTANE 0.0432 0.0432 0.0432 0.0071
HEXANE 0.0432 0.0432 0.0432 0.0026
2MPENTAN 0.0515 0.0515 0.0515 0.0042
CYCLOHEXANE 0.0015 0.0015 0.0015 0.0001
HEPTANE 0.0356 0.0356 0.0356 0.0009
2-MHEXANE 0.0399 0.0399 0.0399 0.0013
CYCLOHEPTANE 0.0267 0.0267 0.0267 0.0004
TOLUENE 0.0131 0.0131 0.0131 0.0003
OCTANE 0.0228 0.0228 0.0228 0.0002
2-MHEPTANE 0.0329 0.0329 0.0329 0.0004
CYCLOOCTANE 0.0326 0.0326 0.0326 0.0001
EBENZENE 0.0095 0.0095 0.0095 0.0001
1OCTENE
NONANE 0.0142 0.0142 0.0142 0.0001
2-MOCTANE 0.0199 0.0199 0.0199 0.0001
CYCLONONANE 0.0171 0.0171 0.0171
N-PBENZENE 0.0174 0.0174 0.0174 0.0001
1NONENE
DECANE 0.0108 0.0108 0.0108
2-MNONANE 0.0159 0.0159 0.0159
CYCLODECANE 0.0042 0.0042 0.0042
N-BBENZENE 0.0123 0.0123 0.0123
1DECENE
NC11 0.0086 0.0086 0.0086
N-PENTYLE-BZ 0.0100 0.0100 0.0100
1-UNDECENE
NC12 0.0394 0.0394 0.0394
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.0002 0.0002 0.0002
MESD
DMDS
B-SULPHIDE

Total kmol/h 808.54 808.54 808.54 276.26


Total kg/h 55 399 55 399 55 399 2 742

REF: INRAD 22/02/08 16:22:43 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 64/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

RECYCLE COMPRESSOR RECYCLE COMPRESSOR REACTED C5+CUT TO STRIPPER FEED


Flow rate unit : mol fraction SUCTION DISCHARGE STRIPPER
13 14 15 16
H2O
H2 0.7207 0.7207 0.0116 0.0116
N2 0.0006 0.0006 0.0001 0.0001
H2S 0.0278 0.0278 0.0157 0.0157
METHANE 0.1794 0.1794 0.0170 0.0170
ETHANE 0.0016 0.0016 0.0006 0.0006
PROPANE 0.0062 0.0062 0.0063 0.0063
IBUTANE 0.0132 0.0132 0.0305 0.0305
BUTANE 0.0236 0.0236 0.0723 0.0723
IPENTANE 0.0090 0.0090 0.0618 0.0618
PENTANE 0.0071 0.0071 0.0619 0.0619
HEXANE 0.0026 0.0026 0.0642 0.0642
2MPENTAN 0.0042 0.0042 0.0761 0.0761
CYCLOHEXANE 0.0001 0.0001 0.0022 0.0022
HEPTANE 0.0009 0.0009 0.0536 0.0536
2-MHEXANE 0.0013 0.0013 0.0600 0.0600
CYCLOHEPTANE 0.0004 0.0004 0.0404 0.0404
TOLUENE 0.0003 0.0003 0.0197 0.0197
OCTANE 0.0002 0.0002 0.0345 0.0345
2-MHEPTANE 0.0004 0.0004 0.0498 0.0498
CYCLOOCTANE 0.0001 0.0001 0.0494 0.0494
EBENZENE 0.0001 0.0001 0.0144 0.0144
1OCTENE
NONANE 0.0001 0.0001 0.0216 0.0216
2-MOCTANE 0.0001 0.0001 0.0302 0.0302
CYCLONONANE 0.0259 0.0259
N-PBENZENE 0.0001 0.0001 0.0264 0.0264
1NONENE
DECANE 0.0164 0.0164
2-MNONANE 0.0242 0.0242
CYCLODECANE 0.0064 0.0064
N-BBENZENE 0.0187 0.0187
1DECENE
NC11 0.0130 0.0130
N-PENTYLE-BZ 0.0152 0.0152
1-UNDECENE
NC12 0.0598 0.0598
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.0003 0.0003
MESD
DMDS
B-SULPHIDE

Total kmol/h 276.25 276.25 532.28 532.28


Total kg/h 2 742 2 742 52 656 52 656

REF: INRAD 22/02/08 16:22:43 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 65/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

STRIPPER AIR C5+ CUT AIR TRIM CONDENSER PURGED GAS


Flow rate unit : mol fraction CONDENSER INLET CONDENSER OUTLET OUTLET
17 18 19 20
H2O
H2 0.0215 0.0215 0.0215 0.1199
N2 0.0002 0.0002 0.0002 0.0007
H2S 0.0653 0.0653 0.0653 0.1633
METHANE 0.0388 0.0388 0.0388 0.1759
ETHANE 0.0021 0.0021 0.0021 0.0058
PROPANE 0.0483 0.0483 0.0483 0.0649
IBUTANE 0.3262 0.3262 0.3262 0.2208
BUTANE 0.4605 0.4605 0.4605 0.2401
IPENTANE 0.0244 0.0244 0.0244 0.0062
PENTANE 0.0111 0.0111 0.0111 0.0022
HEXANE 0.0004 0.0004 0.0004
2MPENTAN 0.0011 0.0011 0.0011 0.0001
CYCLOHEXANE
HEPTANE
2-MHEXANE
CYCLOHEPTANE
TOLUENE
OCTANE
2-MHEPTANE
CYCLOOCTANE
EBENZENE
1OCTENE
NONANE
2-MOCTANE
CYCLONONANE
N-PBENZENE
1NONENE
DECANE
2-MNONANE
CYCLODECANE
N-BBENZENE
1DECENE
NC11
N-PENTYLE-BZ
1-UNDECENE
NC12
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.0002 0.0002 0.0002 0.0001
MESD
DMDS
B-SULPHIDE

Total kmol/h 299.45 299.45 299.45 51.33


Total kg/h 16 026 16 026 16 026 2 006

REF: INRAD 22/02/08 16:22:43 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 66/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

STRIPPER REFLUX STRIPPER BOTTOM STRIPPER REBOILER STRIPPER FIRE HEATER


Flow rate unit : mol fraction PUMPS INLET INLET
21 22 23 24
H2O
H2 0.0012
N2
H2S 0.0450
METHANE 0.0104
ETHANE 0.0013
PROPANE 0.0448
IBUTANE 0.3480 0.0102 0.0102 0.0102
BUTANE 0.5061 0.0544 0.0544 0.0544
IPENTANE 0.0282 0.0677 0.0677 0.0677
PENTANE 0.0130 0.0683 0.0683 0.0683
HEXANE 0.0005 0.0710 0.0710 0.0710
2MPENTAN 0.0012 0.0842 0.0842 0.0842
CYCLOHEXANE 0.0024 0.0024 0.0024
HEPTANE 0.0593 0.0593 0.0593
2-MHEXANE 0.0664 0.0664 0.0664
CYCLOHEPTANE 0.0447 0.0447 0.0447
TOLUENE 0.0218 0.0218 0.0218
OCTANE 0.0381 0.0381 0.0381
2-MHEPTANE 0.0551 0.0551 0.0551
CYCLOOCTANE 0.0547 0.0547 0.0547
EBENZENE 0.0159 0.0159 0.0159
1OCTENE
NONANE 0.0239 0.0239 0.0239
2-MOCTANE 0.0334 0.0334 0.0334
CYCLONONANE 0.0286 0.0286 0.0286
N-PBENZENE 0.0292 0.0292 0.0292
1NONENE
DECANE 0.0182 0.0182 0.0182
2-MNONANE 0.0268 0.0268 0.0268
CYCLODECANE 0.0070 0.0070 0.0070
N-BBENZENE 0.0207 0.0207 0.0207
1DECENE
NC11 0.0144 0.0144 0.0144
N-PENTYLE-BZ 0.0169 0.0169 0.0169
1-UNDECENE
NC12 0.0662 0.0662 0.0662
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN 0.0001 0.0001 0.0001
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.0002 0.0003 0.0003 0.0003
MESD
DMDS
B-SULPHIDE

Total kmol/h 248.12 939.29 458.33 458.33


Total kg/h 14 020 98 917 48 267 48 267

REF: INRAD 22/02/08 16:22:43 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 67/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

STRIPPER FIRE HEATER STRIPPER TUBE SIDE STRIPPER TUBE SIDE STRIPPER AIR COOLER
Flow rate unit : mol fraction OUTLET EXCHANGERS INLET EXCHANGERS OUTLET OUTLET
25 26 27 28
H2O
H2
N2
H2S
METHANE
ETHANE
PROPANE
IBUTANE 0.0102 0.0102 0.0102 0.0102
BUTANE 0.0544 0.0544 0.0544 0.0544
IPENTANE 0.0677 0.0677 0.0677 0.0677
PENTANE 0.0683 0.0683 0.0683 0.0683
HEXANE 0.0710 0.0710 0.0710 0.0710
2MPENTAN 0.0842 0.0842 0.0842 0.0842
CYCLOHEXANE 0.0024 0.0024 0.0024 0.0024
HEPTANE 0.0593 0.0593 0.0593 0.0593
2-MHEXANE 0.0664 0.0664 0.0664 0.0664
CYCLOHEPTANE 0.0447 0.0447 0.0447 0.0447
TOLUENE 0.0218 0.0218 0.0218 0.0218
OCTANE 0.0381 0.0381 0.0381 0.0381
2-MHEPTANE 0.0551 0.0551 0.0551 0.0551
CYCLOOCTANE 0.0547 0.0547 0.0547 0.0547
EBENZENE 0.0159 0.0159 0.0159 0.0159
1OCTENE
NONANE 0.0239 0.0239 0.0239 0.0239
2-MOCTANE 0.0334 0.0334 0.0334 0.0334
CYCLONONANE 0.0286 0.0286 0.0286 0.0286
N-PBENZENE 0.0292 0.0292 0.0292 0.0292
1NONENE
DECANE 0.0182 0.0182 0.0182 0.0182
2-MNONANE 0.0268 0.0268 0.0268 0.0268
CYCLODECANE 0.0070 0.0070 0.0070 0.0070
N-BBENZENE 0.0207 0.0207 0.0207 0.0207
1DECENE
NC11 0.0144 0.0144 0.0144 0.0144
N-PENTYLE-BZ 0.0169 0.0169 0.0169 0.0169
1-UNDECENE
NC12 0.0662 0.0662 0.0662 0.0662
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN 0.0001 0.0001 0.0001 0.0001
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.0003 0.0003 0.0003 0.0003
MESD
DMDS
B-SULPHIDE

Total kmol/h 458.33 480.96 480.96 480.96


Total kg/h 48 267 50 650 50 650 50 650

REF: INRAD 22/02/08 16:22:43 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc


MATERIAL BALANCE (MOLAR FRACTION)
Job Number Unit Type Page
Process licensing 07-3091 40 1MP 68/68
Client : ILAM PETROCHEMICAL Co. Date By Check by Iss.
SULFUR REMOVAL UNIT - ILAM, IRAN 02/01/08 MIN GZA A
Unit : C5+ CUT HYDROTREATMENT UNIT 17/01/08 MIN GZA B
Run case : WINTER CASE EOR 22/02/08 MIN GZA C
Document no : 30-40-DOC4-PR-4002 04/04/08 MIIN GZA 0

HYDROTREATED C5+
Flow rate unit : mol fraction CUT TO STORAGE
29
H2O
H2
N2
H2S
METHANE
ETHANE
PROPANE
IBUTANE 0.0102
BUTANE 0.0544
IPENTANE 0.0677
PENTANE 0.0683
HEXANE 0.0710
2MPENTAN 0.0842
CYCLOHEXANE 0.0024
HEPTANE 0.0593
2-MHEXANE 0.0664
CYCLOHEPTANE 0.0447
TOLUENE 0.0218
OCTANE 0.0381
2-MHEPTANE 0.0551
CYCLOOCTANE 0.0547
EBENZENE 0.0159
1OCTENE
NONANE 0.0239
2-MOCTANE 0.0334
CYCLONONANE 0.0286
N-PBENZENE 0.0292
1NONENE
DECANE 0.0182
2-MNONANE 0.0268
CYCLODECANE 0.0070
N-BBENZENE 0.0207
1DECENE
NC11 0.0144
N-PENTYLE-BZ 0.0169
1-UNDECENE
NC12 0.0662
M-MERCAPTAN
E-MERCAPTAN
2C3MERCAPTAN 0.0001
1PENTANTHIOL
1HEXANETHIOL
COS
DMS 0.0003
MESD
DMDS
B-SULPHIDE

Total kmol/h 480.96


Total kg/h 50 650

REF: INRAD 22/02/08 16:22:43 AIO_1.4 P7.1 30-40-DOC4-PR-4001 rev0.doc

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