Redox Reactions st
Redox Reactions st
Redox Reactions st
Zinc is extracted from zinc blende by roasting it in air to form zinc oxide.
The zinc oxide is then heated with carbon to form zinc.
The equations for the reactions are shown.
1 2ZnS + 3O2 → 2ZnO + 2SO2
2 ZnO + C → Zn + CO
Which statement about reactions 1 and 2 is not correct?
A In reaction 1 the oxidation state of sulfur increases and it is oxidised.
B In reaction 1 the oxidation state of zinc increases and it is oxidised.
C In reaction 2 the carbon acts as a reducing agent and it is oxidised.
D In reaction 2 the oxidation state of zinc decreases and it is reduced.
The ionic equation for the reaction between zinc and aqueous copper ions
is shown.
Zn(s) + Cu2+(aq) → Zn2+(aq) + Cu(s)
Which statement about this reaction is correct?
A Copper ion are oxidised and their oxidation state changes.
B Copper ions are reduced because they lose electrons.
C Zinc atoms are oxidised and their oxidation state changes.
D Zinc atoms are reduced because they gain electrons.
The thermite reaction can be used to produce iron from iron (III) oxide.
The equation for the reaction is shown.
2Al + Fe2O3 → 2Fe + Al 2O3
Which statements about this reaction are correct?
1 Aluminium is the oxidising agent.
2 Aluminium is less reactive than iron.
3 Electrons are transferred from aluminium to iron.
4 The iron in the iron (III) oxide is reduced.
A 1 and 3 B 1 and 4 C 2 and 3 D 3 and 4
The ionic equation for the reaction of aqueous potassium bromide with
chlorine gas is shown.
2Br– + Cl 2 → Br2 + 2Cl–
Which statement is correct?
A Bromide ions are oxidised by gaining electrons.
B Bromide ions are oxidised by losing electrons.
C Chlorine is oxidised by gaining electrons.
D Chlorine is oxidised by losing electrons.
Q28/J10 P31 Q7
Titanium (IV) chloride is made by heating the oxide with coke and chlorine.
TiO2 + 2Cl 2 ⇋TiCl 4 + O2
2C + O2 ⇋ 2CO
(c) Explain why the change, titanium (IV) chloride to titanium, is reduction.
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Q29/J10 P32 Q3
Q31/N10 P31 Q5
(b) Iron has two oxidation states +2 and +3. There are two possible
equations for the redox reaction between iron and bromine.
Fe + Br2 → Fe2+ + 2Br–
2Fe + 3Br2 → 2Fe3+ + 6Br–
(i) Indicate, on the fi rst equation, the change which is oxidation. Give a
reason for your
choice.
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(ii) Which substance in the first equation is the reductant (reducing agent)?
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Q32/N10 P31 Q6
The table below shows the elements in the second period of the Periodic
Table and some of their oxidation states in their most common compounds.
(a) (i) What does it mean when the only oxidation state of an element is
zero?
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(ii) Explain why some elements have positive oxidation states but others
have negative ones.
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Q33/J12 P31 Q4
Q34/J13 P31 Q5
(iii) Explain why the positive ions are likely to be oxidants (oxidising agents).
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[1]
Q35/J13 P33 Q4
The following reactivity series shows both familiar and unfamiliar elements
in order of
decreasing reactivity. Each element is represented by a redox equation.
Rb ⇋ Rb+ + e–
Mg ⇋ Mg2+ + 2e–
Mn ⇋ Mn2+ + 2e–
Zn ⇋ Zn2+ + 2e–
H2 ⇋ 2H+ + 2e–
Cu ⇋ Cu2+ + 2e–
Hg ⇋ Hg2+ + 2e–
Two of the uses of the series are to predict the thermal stability of
compounds of the metals and to explain their redox reactions.
(b) (i) Define in terms of electron transfer the term oxidation.
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(ii) Explain why the positive ions in the above equations are oxidising agents.
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Q37/J14 P31 Q7
Q38/J15 P31 Q3
(a) The reactions between metals and acids are redox reactions.
Zn + 2H+ → Zn2+ + H2
(i) Which change in the above reaction is oxidation, Zn to Zn2+ or 2H+ to H2?
Give a reason for your choice.
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(ii) Which reactant in the above reaction is the oxidising agent? Give a
reason for your choice.
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Q39/J15 P32 Q2
Calcium reacts with nitrogen to form the ionic compound calcium nitride,
Ca3N2.
(b) The reaction between calcium and nitrogen to form calcium nitride is a
redox reaction.
In terms of electron transfer, explain why calcium is the reducing agent.
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Q40/N15 P31 Q7
Q41/J16 P43 Q4
4(c)(i) 2
start colour: colourless;
1
end colour: brown;
1
4(c)(ii) 2
M1 iodide / I–;
1
M2 it is oxidised OR it loses electrons / it increases
oxidation number / it reduces the chlorine; 1
Q42/M17 P42 Q2
Marking Scheme:
2(b)(i) 2– 1
Q43/N17 P41 Q3
gains electrons 1
Q44/M18 P42 Q4
Marking Scheme:
Q46/N18 P41 Q4
(c) The gas hydrogen sulfide, H2S, is produced when concentrated sulfuric
acid is added to solid potassium iodide.
The reaction involves oxidation.
(i) Define the term oxidation in terms of electron transfer.
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Marking Scheme:
Marking Scheme:
3(e)(ii) 1+ 1
Q48/J19 P42 Q7
Marking Scheme:
7(a)(ii) redox 1