NAME : ________________

SUBJECT : CHEMISTRY

SOLUTIONS
1. What is the molarity of 𝐻2 𝑆𝑂4 solution that has a density of 1.84 g/cc and
contains 98% by mass of 𝐻2 𝑆𝑂4 ? (Given atomic mass of S = 32)
(a) 4.18 M (b) 8.14 M (c) 18.4 M (d) 18 M

2. Mole fraction of ethyl alcohol in aqueous ethyl alcohol (𝐶2 𝐻6 𝑂𝐻)

solution is 0.25. Hence percentage of ethyl alcohol by weight is
(a) 54% (b) 25% (c) 75% (d) 46%

3. Mole fraction of in 𝐻2 𝑂 is 0.2. The molality of A in 𝐻2 𝑂 is

(a) 13.9 (b) 15.5 (c) 14.5 (d) 16.8

4. The molarity of the solution containing 2.8% (mass/volume) solution of

KOH is: (Given atomic mass of K = 39) is
(a) 0.1 M (b) 0.5 M (c) 0.2 M (d) 1 M

5. The molality of a sulphuric acid solution is 0.2. Calculate the total weight
of the solution having 1000 gm of solvent
(a) 1000 g (b) 1098.6 g (c) 980.4 g (d) 1019.6 g

6. Find the mass of KOH needed to prepare 100 𝑚𝑙 1 M KOH solution .

[At mass K = 39]
(a) 5.6 g (b) 2.8 g (c) 7.2 g (d) 3.6 g

7. Which of the following concentration factor is affected by change in

temperature?
(a) Molarity (b) Molality
(c) Mole fraction (d) Weight fraction

8. What is the quantity of water that should be added to 16 g. Methanol to

make the mole fraction of methanol as 0.25
(a) 27 g (b) 12 g (c) 18 g (d) 36 g

9. 1000 g aqueous solution of 𝐶𝑎𝐶𝑂3 contains 10g of calcium carbonate.

Concentration of solution is
(a) 10 ppm (b) 100 ppm
(c) 1000 ppm (d) 10000 ppm
10.Mole fraction of 𝐶𝐻3 𝑂𝐻 in mixture containing 𝐶𝐻3 𝑂𝐻 𝑎𝑛𝑑 𝐶2 𝐻5 𝑂𝐻
is 0.5. Hence mass percentage of 𝐶𝐻3 𝑂𝐻 in the mixture is
(a) 41% (b) 59% (c) 50% (d) 25%

11.At 5 atm pressure mass of 𝑆𝑂2 gas dissolved in water is 5 × 10−3 𝑔𝑟𝑎𝑚𝑠.
Calculate the mass of 𝑆𝑂2 dissolved in water at 1 atm pressure if
temperature is constant
(a) 2 × 10−3 𝑔 (b) 3 × 10−3 𝑔 (c) 1 × 10−3 𝑔 (d) 5 × 10−3 𝑔

12.If 𝑁2 gas is bubbled through water at 293 K , how many millimoles of 𝑁2

gas would dissolve in 1 litre of water. Assume that 𝑁2 exerts a partial
pressure of 0.987 bar. Given that Henry’s law constant for 𝑁2 at 293
K is 76.48 kbar
(a) 0.716 (b) 7.16 (c) 0.355 (d) 3.55

13.The air is a mixture of a number of gases. The major components are

oxygen and nitrogen with approximate proportion of 20% and 79%
respectively by volume at 298K. The water is in equilibrium with air at a
pressure of 10 𝑎𝑡𝑚. At 298 K if the Henry’s law constants for oxygen
and nitrogen at 298 K are 3.30 × 107 𝑚𝑚 and 6.51 × 107 𝑚𝑚
respectively , calculate the mole fraction of 𝑂2 in solution
(a) 4.6 × 10−5 (b) 2.3 × 10−6 (c) 6.6 × 10−5 (d) 7.6 × 10−6

14.Henry’s law constant of 𝐶𝑂2 in water is 1.6 × 108 Pa at 298 K. The

quantity of 𝐶𝑂2 in 500 g of soda water when packed under 3.2 bar
pressure at 298 K , is
(a) 2.44 g (b) 24.4 g (c) 0.244 g (d) 0.61 g

15.The vapour pressure of pure liquid (molecular weight = 50) at 25℃ is

640 mm of Hg and the vapour pressure of a solution of a solute in the
liquid at the same temperature is 600 mm of Hg. Molality of solution is
(a ) 3/4 (b) 3/8 (c) 4/3 (d) 4/6

16.The vapour pressure of pure A is 10 torr and at the same temperature

when 1g of non-volatile solute B is dissolved in 20 g of A , its vapour
pressure is reduced to 9.0 torr. If the molecular mass of A is 200 amu ,
then the molecular mass of B is
(a) 100 amu (b) 90 amu (c) 75 amu (d) 120 amu

17.For a dilute solution , Raoult’s law states that

(a) the lowering of vapour pressure is equal to the mole fraction of solute
(b) the relative lowering of vapour pressure is equal to the mole fraction
of non-volatile solute
 (c) the relative lowering of vapour pressure is proportional to the amount
of solute in solution
(d) the vapour pressure of the solution is equal to the mole fraction of
solvent

18.A sample of 20.0 g of a compound (molecular weight 120) which is a

non-electrolyte is dissolved in 10.0 g. of ethanol (𝐶2 𝐻5 𝑂𝐻). If the vapour
pressure of pure ethanol at the temperature is 0.250 atm , what is the
vapour pressure of ethanol above the solution?
(a) 0.250 atm (b) 0.83 atm (c) 0.125 atm (d) 0.14 atm

19.The vapour pressure of benzene at 80℃ is lowered by 10 mm when 2.0 g

of a non-volatile substance is dissolved in 78 g of benzene. The vapour
pressure of pure benzene at 80℃ is 750 mm. The molar mass of the non-
volatile substance is
(a) 148 (b) 1050 (c) 1500 (d) 1550

20.Vapour pressure of pure water is 40 mm. If a non-volatile solute is added

to it , vapour pressure falls by 4 mm. Hence , molality of solution is
(a) 6.173 molal (b) 3.0864 molal (c) 1.543 molal (d) 0.772 molal

21.The vapour pressure of a solution of a solution of a non-volatile

electrolyte B in a solvent A is 95% of the vapour pressure of the solvent
at the same temperature. If the molecular weight of the solvent is 0.3
times the molecular weight of solute , the weight ratio of the solvent and
solute are
(a) 0.15 (b) 5.7 (c) 0.2 (d) 0.8

22.The vapour pressure of a solvent decreased by 10 mm of Hg when a non-

volatile solute was added to the solvent. The mole fraction of solute in
solution is 0.2 , what would be mole fraction of the solvent if decrease in
vapour pressure is 20 mm of Hg
(a) 0.2 (b) 0.4 (c) 0.6 (d) 0.8

23.The vapour pressure of solvent ‘A’ is 0.80 atm. When a non-volatile

solution ‘B’ is added to solvent A , its vapour pressure becomes 0.6 atm.
The mole fraction of ‘B’ in solution is
(a) 0.25 (b) 0.50 (c) 0.75 (d) 0.90

24.Benzene and toluene form an ideal solution. The vapour pressure of

benzene and toluene are respectively 75 mm and 22 mm at 20℃. If the
mole fraction of benzene and toluene in vapour phase are 0.60 and 0.40
respectively , then:
 (i) The vapour pressure of mixture is
(a) 38.17 mm (b) 79.32 mm (c) 58.56 mm (d)29.24 mm
(ii) Mole fraction of benzene & toluene in liquid phase is
15 21 14 22 13 23 11 25
(a) , (b) , (c) , (d) ,
36 36 36 36 36 36 36 36

25.Mole fraction of a liquid A in an ideal mixture with another liquid B is

𝑋𝐴 . If 𝑋𝐴′ is the mole fraction of component A in the vapour in
equilibrium , the total pressure of the liquid mixture is
𝑋𝐴′ 𝑃𝐴0 𝑋𝐴 𝑃𝐵0 𝑋𝐴′ 𝑃𝐵0 𝑋𝐴
(a) 𝑃𝐴𝑜 (b) (c) (d)
𝑋𝐴 𝑋𝐴′ 𝑋𝐴 𝑋𝐴′

26.Two liquids A and B have 𝑃𝐵0 = 1: 3 at a certain temperature. If the mole

fraction ratio of 𝑋𝐴 : 𝑋𝐵 = 1: 3 , the mole fraction of A in vapour in
equilibrium with the solution at a given temperature is
(a) 0.1 (b) 0.2 (c) 0.5 (d) 1.0

27.Which of the following plots does not represent the behaviour of an idela
binary liquid solution?
(a) plot of 𝑃𝐴 versus 𝑋𝐴 (mole fraction of a liquid phase ) is linear
(b) plot of 𝑃𝐵 versus 𝑋𝐵 is linear
(c) plot of 𝑝𝑡𝑜𝑡𝑎𝑙 versus 𝑋𝐴 (𝑜𝑟 𝑋𝐵 ) is linear
(d) plot of 𝑝𝑡𝑜𝑡𝑎𝑙 versus 𝑋𝐴 is non-linear

28.Mixture of volatile components A and B has total vapour pressure

(in Torr): 𝑝 = 254 − 119 𝑥𝐴 where 𝑋𝐴 is mole fraction of A in mixture.
Hence 𝑃𝐴0 𝑎𝑛𝑑 𝑃𝐵0 are (in Torr)
(a) 254 , 119 (b) 119 , 254 (c) 135 , 254 (d) 154 , 119

29. The vapour pressure of the solution of two liquids 𝐴(𝑃𝑜 =

80 𝑚𝑚)𝑎𝑛𝑑 𝐵(𝑃𝑜 = 120 𝑚𝑚) is found to be 100 mm when
𝑋𝐴 = 0.4. The result shows that
(a) Solution exhibits ideal behaviour
(b) solution shows positive deviations
(c) solution shows negative deviations
(d) solution will show positive deviations for lower concentration and
negative deviations for higher concentrations

30.Which of the following liquid pairs shows a positive deviation from

Raoult’s law?
(a) Water – hydrochloric acid (b) Benzene – methanol
(c) water – nitric acid (d) Acetone – chloroform
31.In a mixture of A and B , components show negative deviation when
(a) A – B interaction is stronger than A – A and B – B interaction
(b) A – B interaction is weaker than A – A and B – B interaction
(c) ∆𝑉𝑚𝑎𝑥 > 0 , ∆𝑆𝑚𝑎𝑥 > 0
(d) ∆𝑉𝑚𝑎𝑥 = 0 , ∆𝑆𝑚𝑎𝑥 > 0

32.A binary liquid solution of n-heptane and ethyl alcohol is prepared.

Which of the following statements correctly represents the behaviour of
this liquid solution ?
(a) The solution formed is an ideal solution
(b) The solution formed is a non-ideal solution with positive deviations
from Raoult’s law
(c) The solution formed is non-ideal solution with negative deviations
from Raoult’s law
(d) Normal-heptane exhibits positive deviations , whereas ethyl alcohol
exhibits negative deviations from Raoult’s law

33.Given P-x curve for a non-ideal liquid mixture (Fig.). Identify the correct
T-x curve for the same mixture

(a) (b) (c) (d)

34.An azeotropic solution of two liquids has boiling point lower than either
of them when it
(a) shows negative deviation from Raoult’s law
(b) shows no deviation from Raoult’s law
(c) shows positive deviation from Raoults’law
(d) is saturated

35.The diagram given below is a vapour pressure composition diagram for a

binary solution of A and B in the solution , A – B interactions are
 (a) similar to A – A and B – B interactions
(b) greater than A – A and B – B interaction
(c) smaller than A – A and B – B interaction
(d) unpredictable

36.Which of the following is/are not a characteristic property of the polar

liquids?
(a) They have high boiling points
(b) They have high heat of evaporation
(c) They have low viscosity
(d) They have low vapour pressure

37.The intermolecular attraction in liquid A is considerably larger than in

liquid B. Which is not expected to be larger for liquid A than for liquid
B?
(a) Vapour pressure at 20℃ (b) Critical temperature
(c) enthalpy of vaporisation
(d) Temperature at which the vapour pressure is 0.50 atm

38.Which of the following liquid pairs shows a positive deviation from

Raoult’s law?
(a) Water – nitric acid (b) Benzene – methanol
(c) Water – hydrochloric acid (d) Acetone – chloroform

39.Among the following mixture , dipole-dipole as the major interaction , is

present in
(a) KCl and water (b) Benzene and carbon tetrachloride
(c) Benzene and ethanol (d) Acetonitrile and acetone

40.When 0.6 g of urea (mol.wt 60) is dissolved in 100 g of water , The water
will boil at (𝐾𝑏 for water = 0.52 𝑘𝑚−1 ) and normal boiling point
of water = 100℃
(a) 372.48 K (b) 373.52 K (c) 373.052 K (d) 273.52 K

41.An aqueous solution of glucose boils at 100.01℃. The molal elevation

constant for water is 0.5 𝐾 𝑚𝑜𝑙 −1 𝑘𝑔. The number of molecules of
glucose in the solution containing 100 g of water is
(a) 6.023 × 1023 (b) 6.023 × 1022
(c) 12.046 × 1020 (d) 12.046 × 1023

42.0.48 g of a non electrolyte substance is dissolved in 10.6 g of 𝐶6 𝐻5 . The

freezing point of benzene is lowered by 1.8℃. What will be the mol. Wt.
of the substance e (𝐾1 𝑓𝑜𝑟 𝑏𝑒𝑛𝑧𝑒𝑛 𝑒 = 5)
(a) 250.2 (b) 90.8 (c) 125.79 (d) 102.5
43.If 𝑇0 is the boiling point of a solvent and ∆𝐻𝑉 is the latent heat of
vapourisation , the molal depression constant is given by the expression
𝑀1 𝑅𝑇02 1000𝑅𝑇02 1000𝑀1 𝑇02 ∆𝐻𝑣
(a) (b) (c) (d)
1000∆𝐻𝑣 𝑀1 ∆𝐻𝑣 𝑅∆𝐻𝑣 1000𝑀1 𝑅𝑇02

44.On freezing an aqueous solution of sugar , the solid which separates out is
(a) sugar
(b) ice
(c) a solution with the same composition
(d) a solution with a different composition

45.If the elevation in boiling point of solution of 10g of a solute (𝑀 = 100)

in 100 g of water is ∆𝑇𝑏 the ebullioscopic constant of water is
(a) 10 (b) 10∆𝑇𝑏 (c) ∆𝑇𝑏 (d) ∆𝑇𝑏 /10

46.4.00 g of substance A , dissolved in 100 𝑔 𝐻2 𝑂 depressed the f. pt. of

water by 0.1℃. While 4g of another substance B , in 100 gm 𝐻2 𝑂
depressed the f. pt. by 0.2℃. What is the relation between molecular
weights of the two substance
(a) 𝑀𝐴 = 4𝑀𝐵 (b) 𝑀𝐴 = 𝑀𝐵
(c) 𝑀𝐴 = 0.5 𝑀𝐵 (d) 𝑀𝐴 = 2𝑀𝐵

47.The amount of ice that will separate out from a solution containing 25 g
of ethylene glycol in 100 g of water and is cooled to −10℃ , will be
[Given : 𝐾𝑓 𝑓𝑜𝑟 𝐻2 𝑂 = 1.86 𝐾 𝑚𝑜𝑙 −1 𝑘𝑔]
(a) 50.0 g (b) 25.0 g (c) 12.5 gm (d) 30.0 gm

48.Elevation in b.p of a solution of non-electrolyte in 𝐶𝐶𝑙4 is 0.60. What is

depression inf. P. for the same solution ? 𝐾𝑓 (𝐶𝐶𝑙4 ) =
30.00 𝑘𝑔 𝑚𝑜𝑙 −1 𝑘 ; 𝐾𝑏 (𝐶𝐶𝑙4 ) = 5.02 𝑘𝑔 𝑚𝑜𝑙 −1 𝐾
(a) 0° (b) 5.39° (c) 3.59° (d) 2.49°

49.Elevation of boiling point of 1 molar aqueous glucose solution (density =

1.2 𝑔. 𝑚𝑙) is
(a) 𝐾𝑏 (b) 1.20 𝐾𝑏 (c) 1.02 𝐾𝑏 (d) 0.98 𝐾𝑏

50.An aqueous solution boils at 100.51℃. The freezing point of the solution
would be (𝐾𝑏 for water = 0.51°𝐶/𝑚) , (𝐾𝑓 𝑓𝑜𝑟 𝑤𝑎𝑡𝑒𝑟 = 1.86℃ 𝐶/𝑚)
[No association or dissociation]
(a) 0℃ (b) −1.86℃ (c) −1.82℃ (d) +1.82℃
51.The osmotic pressure of a solution containing 100 ml of 0.3% solution
(𝑤/𝑣) of urea (m. wt. 60) and 100 ml of 1.71% solution (w/v) of cane-
sugar (m. wt 342) at 27℃ is
(a) 10.56 atm (b) 8.98 atm (c) 17.06 atm (d) 1.23 atm

52.5g of a polymer of molecular weight 50 𝑘𝑔 𝑚𝑜𝑙 −1 is dissolved in 1 𝑑𝑚3

solution. If the density of this solution is 0.96 𝑘𝑔 𝑑𝑚−3 𝑎𝑡 300 𝐾 , the
height of solution that will represent this pressure is
(a) 28.13 mm (b) 28.85 mm (c) 26 mm (d) 24.94 mm

53.Solution A contains 6g of urea (𝑁𝐻2 𝐶𝑂𝑁𝐻2 ) per litre and solution B

contains 18 g glucose (𝐶5 𝐻12 𝑂5 ) per litre. At a temperature TK , the
osmotic pressure of
(a) solution A is more than that of solution B
(b) solution A is less than that of solution B
(c) both solution is equal
(d) both the solutions is 1 atm

54.A solution of glucose (𝐶6 𝐻12 𝑂6 ) is isotonic with of 4g urea

(𝑁𝐻2 𝐶𝑂𝑁𝐻2 ) per litre of solution. The concentration of glucose is
(a) 4 𝑔/𝑙 (b) 8 𝑔/𝑙 (c) 12 𝑔/𝑙 (d) 14 𝑔/𝑙

𝑊 𝑊
55.A 10% urea solution is isotonic with a 20% solution of non-volatile
𝑉 𝑉
solute , at the same temperature. Calculate the molecular weight of the
solute
(a) 240 (b) 120 (c) 360 (d) 480

56.Two aqueous solutions 𝑆1 𝑎𝑛𝑑 𝑆2 are separated by a semipermeable

membrane. 𝑆1 has lower vapour pressure than 𝑆2 . Then
(a) more solvent will flow from 𝑆1 𝑡𝑜 𝑆2
(b) more solvent will flow from 𝑆2 𝑡𝑜 𝑆1
(c) Solvent from 𝑆1 𝑡𝑜 𝑆2 will flow at equal rates
(d) no flow of solvent will take place

57.The solution containing 4.0 g of PVC in 1L of dioxane was found to have

osmotic pressure of 0.006 atm at 300 K. The molecular mass of the
polymer PVC is
(a) 16,420 (b) 1642 (c) 1,64,200 (d) 4105

58.A semi-permeable membrane separates a solution that is 0.012 M in

glucose from one that is 0.250 M in glucose. On which of these solutions
must pressure be applied to prevent a net flow of water through the
membrane ?
 (a) On the 0.012 M solution
(b) On the 0.250 M solution
(c) Equal pressure on both the solutions
(d) The pressure on 0.012 M solution should be double the pressure on
0.250 M solution

59.A solution having 54 g of glucose per litre has an osmotic pressure of

4.56 bar. If the osmotic pressure of a urea solution is 1.52 bar at the same
temperature , what would be its concentration?
(a) 1.0 M (b) 0.5 M (c) 0.3 M (d) 0.1 M

60.A quantity of 10g of solute ‘A’ and 20 g of solute ‘B’ is dissolved in 500
ml water. The solution is isotonic with the solution obtained by
dissolving 6.67 g of ‘A’ and 30 g of ‘B’ in 500 ml water at the same
temperature. The ratio of molar masses 𝑀𝐴 : 𝑀𝐵 is
(a) 1 : 1 (b) 3 : 1 (c) 1 : 3 (d) 2 : 3

61.Calculate Van’t Hoff factor i of the compound 𝐾4 [𝐹𝑒(𝐶𝑁)6 ] If their

𝛼 = 80%
(a) 4.2 (b) 4 (c) 5 (d) 2.5

62.Calculate Van’t Hoff factor i of the compound Acetic acid in benzene if

their 𝛼 = 50%
(a) 0.25 (b) 1.5 (c) 0.75 (d) 2

63.When 𝐶𝑢𝑆𝑂4 is added to a solution of ammonia

(a) f.p. is lowered (b) f.p. I sraised
(c) b.p. is raised (d) both (a) & (c)

64.If ‘A’ contains 2% NaCl and is separated by a semi-permeable membrane

from ‘B’ which contains 10% NaCl , which event will occur?
(a) NaCl will flow from ‘A’ to ‘B’ (b) NaCl will flow from ‘B’ to ‘A’
(c) Water will from ‘A’ to ‘B’ (d) Water will flow from ‘B’ to ‘A’

65.Which salt may show the same value of vant Hoff factor (i) as that of
𝐾4 [𝐹𝑒(𝐶𝑁)6 ] in very dilute solution state
(a) 𝐴𝑙2 (𝑆𝑂4 )3 (b) NaCl
(c) 𝐴𝑙(𝑁𝑂3 )3 (d) 𝑁𝑎2 𝑆𝑂4

66.What will be the molecular weight of 𝐶𝑎𝐶𝑙2 determined in its aq.

Solution experimentally from depression of freezing point?
(a) 111 (b) <111 (c) >111 (d) data insufficient
67.1.0 molal aqueous solution of an electrolyte 𝐴2 𝐵3 is 60% ionised. The
boiling point of the solution at 1 atm is (𝐾𝑏 (𝐻 𝑂) = 0.52 𝐾 𝑘𝑔𝑚𝑜𝑙 −1 )
2
(a) 274.76 K (b) 377 K (c) 376.4 K (d) 374.76 K

68.0.48 g of a non electrolyte substance is dissolved in 10.6 g of 𝐶6 𝐻6 . The

freezing point of benzene is lowered by 1.8℃. What will be the mol. Wt.
of the substance (𝐾𝑓 𝑓𝑜𝑟 𝑏𝑒𝑛𝑧𝑒𝑛𝑒 = 5)
(a) 250.2 (b) 90.8 (c) 125.79 (d) 102.5

𝑇𝑓 1
69.What weight of NaCl is added to one 1 kg of water so that ∆ = ?
𝐾𝑓 500
(a) 5.85g (b) 0.585 g
(c) 0.0585 g (d) 0.0855 g

70.Which of the following has been arranged in order of decreasing freezing

point?
(a) 0.05 𝑀 𝐾𝑁𝑂3 > 0.04 𝑀 𝐶𝑎𝐶𝑙2 > 0.140 𝑀𝑠𝑢𝑔𝑎𝑟 > 0.075 𝑀𝐶𝑢𝑆𝑂4
(b) 0.04𝑀 𝐵𝑎𝐶𝑙2 > 0.140𝑀𝑠𝑢𝑐𝑟𝑜𝑠𝑒 > 0.075𝑀𝐶𝑢𝑆𝑂4 > 0.05𝑀𝐾𝑁𝑂3
(c) 0.075𝑀 𝐶𝑢𝑆𝑂4 > 0.140𝑀𝑠𝑢𝑐𝑟𝑜𝑠𝑒? 0.04𝑀𝐵𝑎𝐶𝑙2 > 0.05𝑀𝐾𝑁𝑂3
(d) 0.075𝑀 𝐶𝑢𝑆𝑂4 > 0.05𝑀𝑁𝑎𝑁𝑂3 > 0.140𝑀𝑠𝑢𝑐𝑟𝑜𝑠𝑒 > 0.04𝑀𝐵𝑎𝐶𝑙2

71.If 𝑝𝐾𝑎 = − log 𝑘𝑎 = 4 , 𝑎𝑛𝑑 𝐾𝑎 = 𝐶𝑥 2 then van’t Hoff factor for weak
monobasic acid when 𝐶 = 0.01 𝑀 is (where x = degree of dissociation)
(a) 1.01 (b) 1.02 (c) 1.10 (d) 1.20

72.Vapour density of 𝑃𝐶𝑙5 (𝑔) dissociating into 𝑃𝐶𝑙3 (𝑔)𝑎𝑛𝑑 𝐶𝑙2 (𝑔) is 100.
Hence , van’t Hoff factor for the case

(a) 1.85 (b) 3.70 (c) 1.085 (d) 1.0425

73.Which of the following aqueous solution will show maximum vapour

pressure at 300K ?
(a) 1𝑀 𝑁𝑎𝐶𝑙 (b) 1 𝑀 𝐶𝑎𝐶𝑙2
(c) 1𝑀 𝐴𝑙𝐶𝑙3 (d) 1𝑀 𝐶12 𝐻22 𝑂11

74.A 0.001 molal solution of a complex [𝑀𝐴8 ] in water has the freezing
point of −0.0054℃. Assuming 100% ionization of the complex salt and
𝐾𝑓 𝑓𝑜𝑟 𝐻2 𝑂 = 1.86 𝑘𝑚−1 , write the correct representation for the
complex
(a) [𝑀𝐴8 ] (b) [𝑀𝐴7 ]𝐴
(c) [𝑀𝐴6 ]𝐴2 (d) [𝑀𝐴5 ]𝐴3
75.The vapour pressure of a saturated solution of sparingly soluble salt
(𝑋𝐶𝑙3 ) was 17.20 mm Hg at 27℃. If the vapour pressure of pure 𝐻2 𝑂 is
17.25 mm Hg at 300K , what is the solubility of sparingly soluble salt
𝑋𝐶𝑙3 in mole/Litre.
(a) 4.04 × 10−2 (b) 8.08 × 10−2
(c) 2.02 × 10−2 (d) 4.04 × 10−3

ANSWER KEY

1 2 3 4 5 6 7 8 9 10
c d a b d a a a d a
11 12 13 14 15 16 17 18 19 20
c a a a c b b d a b
21 22 23 24 25 26 27 28 29 30
b c a (i)-a b a d c c b
(ii)-d
31 32 33 34 35 36 37 38 39 40
a b b c c c a b d c
41 42 43 44 45 46 47 48 49 50
b c a b c d b c d b
51 52 53 54 55 56 57 58 59 60
d c c c b b a b d c
61 62 63 64 65 66 67 68 69 70
a c b c a b d c c a
71 72 73 74 75
c d d c a