EI Corrosion Management
EI Corrosion Management
EI Corrosion Management
Second edition
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL
AND GAS PRODUCTION AND PROCESSING
Second edition
March 2019
Published by
Energy Institute, London
The Energy Institute is a professional membership body incorporated by Royal Charter 2003
Registered charity number 1097899
This document is issued with a single user licence to the EI registered subscriber: bob.conder@neptuneenergy.com. It has been issued as part of the [TECH PARTNER] Technical Partner membership of the Energy Institute.
IMPORTANT: This document is subject to a licence agreement issued by the Energy Institute, London, UK. It may only be used in accordance with the licence terms and conditions. It must not be forwarded to, or stored, or accessed by, any unauthorised user. Enquiries: e:pubs@energyinst.org t:
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
CONTENTS
Page
Foreword ���������������������������������������������������������������������������������������������������������������������������������� 16
Acknowledgements������������������������������������������������������������������������������������������������������������������ 18
Executive summary������������������������������������������������������������������������������������������������������������������ 20
1 Introduction�������������������������������������������������������������������������������������������������������������������� 25
1.1 Purpose ������������������������������������������������������������������������������������������������������������������ 25
1.2 Scope of application������������������������������������������������������������������������������������������������ 25
1.2.1 Management system scope���������������������������������������������������������������������� 25
1.2.2 Production facilities scope������������������������������������������������������������������������ 25
1.2.3 Deterioration processes scope������������������������������������������������������������������ 26
1.2.4 Structured framework for corrosion management support function���������� 26
This document is issued with a single user licence to the EI registered subscriber: bob.conder@neptuneenergy.com. It has been issued as part of the [TECH PARTNER] Technical Partner membership of the Energy Institute.
IMPORTANT: This document is subject to a licence agreement issued by the Energy Institute, London, UK. It may only be used in accordance with the licence terms and conditions. It must not be forwarded to, or stored, or accessed by, any unauthorised user. Enquiries: e:pubs@energyinst.org t:
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
Contents continued
Page
3 Human factors���������������������������������������������������������������������������������������������������������������� 58
3.1 Introduction������������������������������������������������������������������������������������������������������������ 58
3.2 PLAN ���������������������������������������������������������������������������������������������������������������������� 61
3.2.1 Policy ������������������������������������������������������������������������������������������������������ 61
3.2.2 Planning�������������������������������������������������������������������������������������������������� 62
3.3 DO�������������������������������������������������������������������������������������������������������������������������� 62
3.3.1 Risk profiling�������������������������������������������������������������������������������������������� 62
3.3.2 Organisation�������������������������������������������������������������������������������������������� 63
3.3.3 Implementing the plan ���������������������������������������������������������������������������� 63
3.4 CHECK�������������������������������������������������������������������������������������������������������������������� 63
3.4.1 Measuring performance �������������������������������������������������������������������������� 63
3.4.2 Investigating accidents/incidents/near misses�������������������������������������������� 64
3.5 ACT������������������������������������������������������������������������������������������������������������������������ 64
3.5.1 Reviewing performance���������������������������������������������������������������������������� 64
3.5.2 Learning lessons�������������������������������������������������������������������������������������� 64
Annexes
Annex B
Legal basis for corrosion management�������������������������������������������������������������� 68
B.1 List of UK and EU Regulatory requirements relating to
corrosion management���������������������������������������������������������������������������� 68
B.2 UK statutory compliance�������������������������������������������������������������������������� 70
B.3 Risk assessment and management ���������������������������������������������������������� 73
B.3.1 MHSWR������������������������������������������������������������������������������������ 73
B.3.2 SCR15 2015������������������������������������������������������������������������������ 73
B.3.3 COMAH 2015�������������������������������������������������������������������������� 74
B.3.4 PSR 1996���������������������������������������������������������������������������������� 75
B.4 Integrity management������������������������������������������������������������������������������ 75
B.4.1 PUWER ������������������������������������������������������������������������������������ 75
B.4.2 DCR 1996 �������������������������������������������������������������������������������� 75
B.4.3 PFEER 1995������������������������������������������������������������������������������ 75
B.4.4 PSSR 2000�������������������������������������������������������������������������������� 75
B.4.5 PSR 1996���������������������������������������������������������������������������������� 75
B.5 European union legislation ���������������������������������������������������������������������� 76
B.6 Sections from the regulations relevant to corrosion
management ������������������������������������������������������������������������������������������ 76
B.6.1 Health and safety at work etc act 1974 ������������������������������������ 76
B.6.2 Management of health and safety at work
regulations 1999���������������������������������������������������������������������� 77
B.6.3 Provision and use of work equipment regulations 1998������������ 78
B.6.4 The dangerous substances and explosive atmospheres
regulations 2002���������������������������������������������������������������������� 80
B.6.5 Offshore installations (offshore safety directive)
(safety case) regs 2015�������������������������������������������������������������� 82
B.6.6 The offshore installations (Prevention of Fire, Explosion,
and Emergency Response) regulations (PFEER) �������������������������� 84
B.6.7 Offshore installations and wells (design and construction
etc) regulations 1996���������������������������������������������������������������� 84
This document is issued with a single user licence to the EI registered subscriber: bob.conder@neptuneenergy.com. It has been issued as part of the [TECH PARTNER] Technical Partner membership of the Energy Institute.
IMPORTANT: This document is subject to a licence agreement issued by the Energy Institute, London, UK. It may only be used in accordance with the licence terms and conditions. It must not be forwarded to, or stored, or accessed by, any unauthorised user. Enquiries: e:pubs@energyinst.org t:
+44 (0)207 467 7100
GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
Contents continued
Page
B.6.8 The pipelines safety regulations 1996���������������������������������������� 85
B.6.9 The pressure safety systems safety regulations 2000������������������ 86
B.6.10 The Control Of Major Accident Hazards (COMAH)
regulations�������������������������������������������������������������������������������� 89
Annex D
Approaches to good practice������������������������������������������������������������������������������ 97
D.1 Introduction �������������������������������������������������������������������������������������������� 97
D.2 Why manage corrosion?�������������������������������������������������������������������������� 97
D.3 PLAN�������������������������������������������������������������������������������������������������������� 99
D.3.1 Policy���������������������������������������������������������������������������������������� 99
D.3.2 Purpose������������������������������������������������������������������������������������ 99
D.3.3 Policy format�������������������������������������������������������������������������� 100
D.3.4 Planning���������������������������������������������������������������������������������� 101
D.3.5 New builds������������������������������������������������������������������������������ 102
D.4 Existing Infrastructure���������������������������������������������������������������������������� 104
D.5 DO�������������������������������������������������������������������������������������������������������� 106
D.5.1 Risk profiling �������������������������������������������������������������������������� 106
D.5.2 Organisation �������������������������������������������������������������������������� 106
D.5.3 Implementing the plan������������������������������������������������������������ 106
D.6 CHECK�������������������������������������������������������������������������������������������������� 106
D.6.1 Measuring performance���������������������������������������������������������� 106
D.6.2 Investigating accidents/incidents/near misses �������������������������� 107
D.7 ACT ������������������������������������������������������������������������������������������������������ 107
D.7.1 Reviewing performance���������������������������������������������������������� 107
Annex E
Organisation ������������������������������������������������������������������������������������������������������ 108
E.1 Introduction ������������������������������������������������������������������������������������������ 108
E.2 PLAN������������������������������������������������������������������������������������������������������ 108
E.2.1 Policy�������������������������������������������������������������������������������������� 108
E.2.2 Planning���������������������������������������������������������������������������������� 108
E.2.3 Contracted services ���������������������������������������������������������������� 111
E.3 DO�������������������������������������������������������������������������������������������������������� 112
E.3.1 Risk profiling �������������������������������������������������������������������������� 112
E.3.2 Organisation �������������������������������������������������������������������������� 112
E.3.3 Implementing the plan������������������������������������������������������������ 114
E.3.4 Competence system���������������������������������������������������������������� 114
E.3.5 Competency guidelines ���������������������������������������������������������� 115
E.3.6 Technical authority and the integrity team leader
competencies�������������������������������������������������������������������������� 115
E.3.7 Corrosion engineer competencies������������������������������������������� 115
E.3.8 Inspection engineering and NDT technician
competencies�������������������������������������������������������������������������� 116
E.3.9 Operator and management competencies for corrosion
related responsibilities ������������������������������������������������������������ 116
E.3.10 Competence in contract services �������������������������������������������� 117
This document is issued with a single user licence to the EI registered subscriber: bob.conder@neptuneenergy.com. It has been issued as part of the [TECH PARTNER] Technical Partner membership of the Energy Institute.
IMPORTANT: This document is subject to a licence agreement issued by the Energy Institute, London, UK. It may only be used in accordance with the licence terms and conditions. It must not be forwarded to, or stored, or accessed by, any unauthorised user. Enquiries: e:pubs@energyinst.org t:
+44 (0)207 467 7100
GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
Contents continued
Page
E.3.11 Communication in contract services���������������������������������������� 117
E.4 CHECK�������������������������������������������������������������������������������������������������� 118
E.4.1 Measuring performance���������������������������������������������������������� 118
E.4.2 Investigating accidents/incidents/near misses �������������������������� 119
E.5 ACT ������������������������������������������������������������������������������������������������������ 119
E.5.1 Reviewing performance���������������������������������������������������������� 119
E.5.2 Learning lessons���������������������������������������������������������������������� 120
Annex F
Corrosion risk assessment and planning���������������������������������������������������������� 121
F.1 Introduction ������������������������������������������������������������������������������������������ 121
F.2 PLAN������������������������������������������������������������������������������������������������������ 121
F.2.1 Policy�������������������������������������������������������������������������������������� 121
F.2.2 Planning���������������������������������������������������������������������������������� 122
F.2.3 Work planning������������������������������������������������������������������������ 123
F.2.4 Resource planning������������������������������������������������������������������ 124
F.3 DO�������������������������������������������������������������������������������������������������������� 125
F.3.1 Risk profiling �������������������������������������������������������������������������� 125
F.3.2 Organisation �������������������������������������������������������������������������� 127
F.3.3 Implementing the plan������������������������������������������������������������ 128
F.4 CHECK�������������������������������������������������������������������������������������������������� 129
F.4.1 Measuring performance���������������������������������������������������������� 129
F.4.2 Investigating accidents/incidents/near misses �������������������������� 129
F.5 ACT ������������������������������������������������������������������������������������������������������ 129
F.5.1 Reviewing performance���������������������������������������������������������� 129
F.5.2 Minimise high risk ������������������������������������������������������������������ 130
F.5.3 Learning lessons���������������������������������������������������������������������� 130
Annex G
Implementation and analysis���������������������������������������������������������������������������� 131
G.1 Introduction ������������������������������������������������������������������������������������������ 131
G.2 PLAN������������������������������������������������������������������������������������������������������ 131
G.2.1 Policy�������������������������������������������������������������������������������������� 131
G.2.2 Planning���������������������������������������������������������������������������������� 131
G.2.3 Barriers and mitigation������������������������������������������������������������ 133
G.2.4 Monitoring������������������������������������������������������������������������������ 133
G.2.5 Unplanned activities���������������������������������������������������������������� 135
G.2.6 Opportunity based visual inspection���������������������������������������� 135
G.2.7 Material and corrosion damage reporting�������������������������������� 135
G.2.8 Data gathering and storage���������������������������������������������������� 135
G.3 DO�������������������������������������������������������������������������������������������������������� 136
G.3.1 Risk profiling �������������������������������������������������������������������������� 136
G.3.2 Organisation �������������������������������������������������������������������������� 136
G.3.3 Implementing the plan������������������������������������������������������������ 136
G.3.4 Data gathering������������������������������������������������������������������������ 137
G.3.5 Inspection data covering �������������������������������������������������������� 137
G.4 CHECK�������������������������������������������������������������������������������������������������� 137
G.4.1 Measuring performance���������������������������������������������������������� 137
G.4.2 Data storage �������������������������������������������������������������������������� 138
G.4.3 Data analysis �������������������������������������������������������������������������� 138
G.4.4 Anomaly reporting������������������������������������������������������������������ 139
G.4.5 Investigating accidents/incidents/near misses �������������������������� 140
This document is issued with a single user licence to the EI registered subscriber: bob.conder@neptuneenergy.com. It has been issued as part of the [TECH PARTNER] Technical Partner membership of the Energy Institute.
IMPORTANT: This document is subject to a licence agreement issued by the Energy Institute, London, UK. It may only be used in accordance with the licence terms and conditions. It must not be forwarded to, or stored, or accessed by, any unauthorised user. Enquiries: e:pubs@energyinst.org t:
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G.5 ACT ������������������������������������������������������������������������������������������������������ 142
G.5.1 Reviewing performance���������������������������������������������������������� 142
G.5.2 Facility status review���������������������������������������������������������������� 142
G.5.3 Routine tactical review������������������������������������������������������������ 142
G.5.4 Annual review ������������������������������������������������������������������������ 143
G.5.5 Corrective action �������������������������������������������������������������������� 147
G.5.6 Learning lessons���������������������������������������������������������������������� 147
Annex H
Audits������������������������������������������������������������������������������������������������������������������ 148
H.1 Introduction ������������������������������������������������������������������������������������������ 148
H.2 PLAN������������������������������������������������������������������������������������������������������ 148
H.2.1 Policy�������������������������������������������������������������������������������������� 148
H.2.2 Planning���������������������������������������������������������������������������������� 148
H.3 DO�������������������������������������������������������������������������������������������������������� 149
H.3.1 Risk profiling �������������������������������������������������������������������������� 149
H.3.2 Organisation �������������������������������������������������������������������������� 149
H.3.3 Implementing the plan������������������������������������������������������������ 149
H.4 CHECK�������������������������������������������������������������������������������������������������� 149
H.4.1 Measuring performance���������������������������������������������������������� 149
H.4.2 Investigating accidents/incidents/near misses . . . . . . . . . . . . . 150
H.5 ACT ������������������������������������������������������������������������������������������������������ 150
H.5.1 Reviewing performance���������������������������������������������������������� 150
H.5.2 Learning lessons���������������������������������������������������������������������� 150
This document is issued with a single user licence to the EI registered subscriber: bob.conder@neptuneenergy.com. It has been issued as part of the [TECH PARTNER] Technical Partner membership of the Energy Institute.
IMPORTANT: This document is subject to a licence agreement issued by the Energy Institute, London, UK. It may only be used in accordance with the licence terms and conditions. It must not be forwarded to, or stored, or accessed by, any unauthorised user. Enquiries: e:pubs@energyinst.org t:
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
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I.4.3 DO������������������������������������������������������������������������������������������ 173
I.4.4 CHECK������������������������������������������������������������������������������������ 176
I.4.5 ACT���������������������������������������������������������������������������������������� 176
I.5 Microbially influenced corrosion ������������������������������������������������������������ 177
I.5.1 Introduction���������������������������������������������������������������������������� 177
I.5.2 Carbon and low alloy steel������������������������������������������������������ 179
I.5.3 Stainless steels and other active/passive alloys ������������������������ 179
I.5.4 Copper and nickel alloys �������������������������������������������������������� 180
I.5.5 Non-metallic materials������������������������������������������������������������ 181
I.5.6 PLAN�������������������������������������������������������������������������������������� 181
I.5.7 DO������������������������������������������������������������������������������������������ 182
I.5.8 CHECK������������������������������������������������������������������������������������ 185
I.5.9 ACT���������������������������������������������������������������������������������������� 186
I.6 Dead leg corrosion �������������������������������������������������������������������������������� 186
I.6.1 Introduction���������������������������������������������������������������������������� 186
I.6.2 PLAN�������������������������������������������������������������������������������������� 188
I.6.3 DO������������������������������������������������������������������������������������������ 189
I.6.4 CHECK������������������������������������������������������������������������������������ 192
I.6.5 ACT���������������������������������������������������������������������������������������� 193
I.7 Galvanic corrosion���������������������������������������������������������������������������������� 194
I.7.1 Introduction���������������������������������������������������������������������������� 194
I.7.2 PLAN�������������������������������������������������������������������������������������� 197
I.7.3 DO������������������������������������������������������������������������������������������ 198
I.7.4 CHECK������������������������������������������������������������������������������������ 200
I.7.5 ACT���������������������������������������������������������������������������������������� 200
I.8 Weldment corrosion������������������������������������������������������������������������������ 201
I.8.1 Introduction���������������������������������������������������������������������������� 201
I.8.2 PLAN�������������������������������������������������������������������������������������� 204
I.8.3 DO������������������������������������������������������������������������������������������ 206
I.8.4 CHECK������������������������������������������������������������������������������������ 207
I.8.5 ACT���������������������������������������������������������������������������������������� 208
I.9 Grooving corrosion of pipelines�������������������������������������������������������������� 208
I.9.1 Introduction���������������������������������������������������������������������������� 208
I.9.2 PLAN�������������������������������������������������������������������������������������� 211
I.9.3 DO������������������������������������������������������������������������������������������ 212
I.9.4 CHECK������������������������������������������������������������������������������������ 213
I.9.5 ACT���������������������������������������������������������������������������������������� 213
I.10 Flange face corrosion ���������������������������������������������������������������������������� 214
I.10.1 Introduction���������������������������������������������������������������������������� 214
I.10.2 PLAN�������������������������������������������������������������������������������������� 216
I.10.3 DO������������������������������������������������������������������������������������������ 217
I.10.4 CHECK������������������������������������������������������������������������������������ 219
I.10.5 ACT���������������������������������������������������������������������������������������� 219
I.11 Atmospheric external corrosion�������������������������������������������������������������� 219
I.11.1 Introduction���������������������������������������������������������������������������� 219
I.11.2 PLAN�������������������������������������������������������������������������������������� 222
I.11.3 DO������������������������������������������������������������������������������������������ 223
I.11.4 CHECK������������������������������������������������������������������������������������ 226
I.11.5 ACT���������������������������������������������������������������������������������������� 227
I.11.6 External corrosion of specific plant and structure
item types ������������������������������������������������������������������������������ 227
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IMPORTANT: This document is subject to a licence agreement issued by the Energy Institute, London, UK. It may only be used in accordance with the licence terms and conditions. It must not be forwarded to, or stored, or accessed by, any unauthorised user. Enquiries: e:pubs@energyinst.org t:
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I.12 Corrosion under insulation �������������������������������������������������������������������� 248
I.12.1 Introduction���������������������������������������������������������������������������� 248
I.12.2 Challenging the need for insulation – PLAN/CHECK���������������� 249
I.12.3 Corrosion probability assessment – PLAN/CHECK�������������������� 249
I.12.4 Consequence or criticality ������������������������������������������������������ 255
I.12.5 Risk-based prioritisation – DO�������������������������������������������������� 255
I.12.6 Other considerations for inspection ���������������������������������������� 257
I.12.7 Monitoring and measuring performance – CHECK������������������ 259
I.12.8 Audit – ACT���������������������������������������������������������������������������� 260
I.12.9 PLAN�������������������������������������������������������������������������������������� 261
I.12.10 DO������������������������������������������������������������������������������������������ 262
I.13 Stress corrosion cracking and localised corrosion of stainless
steels in chloride environments�������������������������������������������������������������� 263
I.13.1 Introduction���������������������������������������������������������������������������� 263
I.13.2 Environments�������������������������������������������������������������������������� 265
I.13.3 Factors affecting corrosivity and tendency for degradation������ 265
I.13.4 Degradation mechanisms�������������������������������������������������������� 268
I.13.5 Mitigation ������������������������������������������������������������������������������ 272
I.13.6 PLAN�������������������������������������������������������������������������������������� 273
I.13.7 DO������������������������������������������������������������������������������������������ 273
I.13.8 CHECK������������������������������������������������������������������������������������ 274
I.13.9 ACT���������������������������������������������������������������������������������������� 274
I.14 Erosion/corrosion������������������������������������������������������������������������������������ 275
I.14.1 Erosion mechanisms���������������������������������������������������������������� 275
I.14.2 PLAN�������������������������������������������������������������������������������������� 276
I.14.3 DO������������������������������������������������������������������������������������������ 279
I.14.4 CHECK������������������������������������������������������������������������������������ 282
I.14.5 ACT���������������������������������������������������������������������������������������� 282
I.15 Black dust in gas pipelines���������������������������������������������������������������������� 284
I.15.1 Introduction���������������������������������������������������������������������������� 284
I.15.2 Black powder formation and sources�������������������������������������� 286
I.15.3 PLAN�������������������������������������������������������������������������������������� 288
I.15.4 DO������������������������������������������������������������������������������������������ 288
I.15.5 CHECK������������������������������������������������������������������������������������ 289
I.15.6 ACT���������������������������������������������������������������������������������������� 289
I.16 Mercury cracking������������������������������������������������������������������������������������ 290
I.16.1 Introduction���������������������������������������������������������������������������� 290
I.16.2 PLAN�������������������������������������������������������������������������������������� 293
I.16.3 DO������������������������������������������������������������������������������������������ 294
I.16.4 CHECK������������������������������������������������������������������������������������ 296
I.16.5 ACT���������������������������������������������������������������������������������������� 297
I.17 Caisson corrosion ���������������������������������������������������������������������������������� 297
I.17.1 Introduction���������������������������������������������������������������������������� 297
I.17.2 Caisson types and specific corrosion threats���������������������������� 299
I.17.3 PLAN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 308
I.17.4 DO������������������������������������������������������������������������������������������ 308
I.17.5 CHECK������������������������������������������������������������������������������������ 309
I.17.6 ACT���������������������������������������������������������������������������������������� 310
This document is issued with a single user licence to the EI registered subscriber: bob.conder@neptuneenergy.com. It has been issued as part of the [TECH PARTNER] Technical Partner membership of the Energy Institute.
IMPORTANT: This document is subject to a licence agreement issued by the Energy Institute, London, UK. It may only be used in accordance with the licence terms and conditions. It must not be forwarded to, or stored, or accessed by, any unauthorised user. Enquiries: e:pubs@energyinst.org t:
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
Contents continued
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I.18 Hydrogen failure mechanisms���������������������������������������������������������������� 310
I.18.1 Introduction���������������������������������������������������������������������������� 310
I.18.2 PLAN�������������������������������������������������������������������������������������� 313
I.18.3 DO������������������������������������������������������������������������������������������ 314
I.18.4 CHECK������������������������������������������������������������������������������������ 314
I.18.5 ACT���������������������������������������������������������������������������������������� 315
Annex J
Mitigation of oil and gas production and processing corrosion threats�������� 316
J.1 Corrosion mitigation by chemical treatments������������������������������������������ 316
J.1.1 Continuous ���������������������������������������������������������������������������� 316
J.1.2 Intermittent���������������������������������������������������������������������������� 317
J.1.3 Delivery systems���������������������������������������������������������������������� 317
J.1.4 Corrosion control and integrity management chemicals���������� 318
J.1.5 Oilfield flow assurance chemicals�������������������������������������������� 321
J.1.6 Oilfield process chemicals�������������������������������������������������������� 324
J.2 Mitigation by organic coatings and linings���������������������������������������������� 325
J.2.1 Introduction���������������������������������������������������������������������������� 325
J.2.2 PLAN�������������������������������������������������������������������������������������� 327
J.2.3 DO������������������������������������������������������������������������������������������ 328
J.2.4 CHECK������������������������������������������������������������������������������������ 330
J.2.5 ACT���������������������������������������������������������������������������������������� 330
J.2.6 Additional information coating deterioration guidelines���������� 331
J.3 Corrosion mitigation by corrosion resistant alloys ���������������������������������� 331
J.3.1 Introduction���������������������������������������������������������������������������� 331
J.3.2 PLAN�������������������������������������������������������������������������������������� 335
J.3.3 DO������������������������������������������������������������������������������������������ 335
J.3.4 CHECK������������������������������������������������������������������������������������ 336
J.3.5 ACT���������������������������������������������������������������������������������������� 336
J.4 Mitigation by cathodic protection���������������������������������������������������������� 336
J.4.1 Introduction���������������������������������������������������������������������������� 336
J.4.2 PLAN�������������������������������������������������������������������������������������� 338
J.4.3 DO������������������������������������������������������������������������������������������ 338
J.4.4 CHECK������������������������������������������������������������������������������������ 340
J.4.5 ACT���������������������������������������������������������������������������������������� 342
J.5 Corrosion mitigation by process control and environmental
modification������������������������������������������������������������������������������������������ 343
J.5.1 Introduction���������������������������������������������������������������������������� 343
J.5.2 Water removal/dehydration ���������������������������������������������������� 344
J.5.3 Deaeration������������������������������������������������������������������������������ 344
J.5.4 pH control������������������������������������������������������������������������������ 345
J.6 Corrosion mitigation of hydrotest waters������������������������������������������������ 346
J.6.1 Hydrotesting �������������������������������������������������������������������������� 346
J.6.2 Hydrotest mediums ���������������������������������������������������������������� 346
J.6.3 Microbial corrosion������������������������������������������������������������������ 347
J.6.4 Mitigation measures���������������������������������������������������������������� 347
J.6.5 Drainage and drying���������������������������������������������������������������� 348
J.6.6 Wet storage���������������������������������������������������������������������������� 349
J.6.7 Preservation���������������������������������������������������������������������������� 349
10
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Contents continued
Page
Annex K
Performing failure investigations �������������������������������������������������������������������� 351
K.1 Level of investigation required���������������������������������������������������������������� 351
K.2 Who leads the investigation? ���������������������������������������������������������������� 352
K.3 The investigation team �������������������������������������������������������������������������� 352
K.4 Starting the investigation ���������������������������������������������������������������������� 353
K.4.1 The plan���������������������������������������������������������������������������������� 353
K.4.2 Securing and collecting the evidence�������������������������������������� 353
K.5 Who conducts the laboratory investigation�������������������������������������������� 354
K.6 Scopes of work�������������������������������������������������������������������������������������� 355
K.7 Causation study ������������������������������������������������������������������������������������ 355
K.8 Terms of reference for failure investigation �������������������������������������������� 355
K.9 Reporting���������������������������������������������������������������������������������������������� 356
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
Figure I.21 Severe corrosion at the weldment (deep groove along the weld) indicating
that weld metal preferentially corrodes in CO2 environment���������������������������������� 201
Figure I.22 Severe weldment corrosion in contact with hydrocarbon condensate
containing only a small amount of water and saturated with CO2�������������������������� 201
Figure I.23 The four steps in the formation of groove corrosion: (1) the formation of
films/scales; (2) erosion of film/scale at/near the 6 o' clock position; (3) formation
of a galvanic couple and (4) corrosion attack forming a groove38 �������������������������� 210
Figure I.24 Flange face corrosion�������������������������������������������������������������������������������������������� 215
Figure I.25 Flange face corrosion revealed following breaking of the flange joint and
surface cleaning���������������������������������������������������������������������������������������������������� 215
Figure I.26 External corrosion of a pipe at a pipe support. Both the pipe and the support
are corroding at the crevice formed between the two. The coating is also
breaking back as it under-rusts in the crevice at the edge�������������������������������������� 221
Figure I.27 Heavy under-rusting of the paint film on a flange�������������������������������������������������� 221
Figure I.28 Handrail corroded by leak of firefighting foam concentrated chemical ������������������ 221
Figure I.29 Top coat breakdown, enhanced corrosion under pipe support (clamp) ������������������ 228
Figure I.30 Gross corrosion on module cladding���������������������������������������������������������������������� 229
Figure I.31 Structural corrosion concentrated along edges, welds etc. ������������������������������������ 229
Figure I.32 Corrosion on cupronickel pipe ������������������������������������������������������������������������������ 229
Figure I.33 Damaged grating requiring replacement���������������������������������������������������������������� 232
Figure I.34 Decking in need of recoating�������������������������������������������������������������������������������� 232
Figure I.35 Unacceptable corrosion on rails ���������������������������������������������������������������������������� 233
Figure I.36 Corroded mesh in need of replacement ���������������������������������������������������������������� 233
Figure I.37 Quantitative assessment example: grating assessment ������������������������������������������ 235
Figure I.38 Handrail assessment���������������������������������������������������������������������������������������������� 239
Figure I.39 Grating assessment ���������������������������������������������������������������������������������������������� 240
Figure I.40 Inspection and prioritisation of handrail repairs������������������������������������������������������ 241
Figure I.41 Inspection and prioritisation of handrail repairs������������������������������������������������������ 241
Figure I.42 Localised bolt corrosion ���������������������������������������������������������������������������������������� 243
Figure I.43 Significantly corroded bolts requiring replacement ������������������������������������������������ 243
Figure I.44 Major bolt corrosion���������������������������������������������������������������������������������������������� 244
Figure I.45 Reinstated piping system �������������������������������������������������������������������������������������� 244
Figure I.46 Corroded cable tray���������������������������������������������������������������������������������������������� 246
Figure I.47 Corroded cable ladders������������������������������������������������������������������������������������������ 246
Figure I.48 Corroded hand wheel�������������������������������������������������������������������������������������������� 247
Figure I.49 Valve body corrosion �������������������������������������������������������������������������������������������� 248
Figure I.50 CUI examples�������������������������������������������������������������������������������������������������������� 261
Figure I.51 Annular SCC of duplex production tubing attributed to oxygenated
calcium bromide brine ������������������������������������������������������������������������������������������ 265
Figure I.52 Internal SCC of 22Cr duplex resulting from chloride concentration effects ������������ 266
Figure I.53 SCC experienced on a cold worked dome end section of a previously
insulated vessel������������������������������������������������������������������������������������������������������ 267
Figure I.54 Evidence of corrosion taking place beneath label on 316L line ������������������������������ 267
Figure I.55 Localised oxidation at stainless steel weld�������������������������������������������������������������� 268
Figure I.56 Pitting corrosion on 316L hydraulic piping ������������������������������������������������������������ 269
Figure I.57 Crevice corrosion at clamp location on 316 tubing������������������������������������������������ 270
Figure I.58 Stress corrosion cracking on 316 fitting ���������������������������������������������������������������� 271
Figure I.59 Examples of erosion mechanisms�������������������������������������������������������������������������� 275
Figure I.60 Basis of an erosion and erosion corrosion control scheme/management���������������� 278
Figure I.61 Parts of the production system that typically suffer from erosion62�������������������������� 280
Figure I.62 Black powder particles������������������������������������������������������������������������������������������ 285
Figure I.63 Damaged trim cage of a PCV-710�������������������������������������������������������������������������� 285
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Tables
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
FOREWORD
Corrosion is first and foremost a safety risk which has to be understood and managed. Once the
safety risks associated with corrosion are managed control of the associated economic risks will
generally follow.
Corrosion has the potential to cost between 2 and 4 % of a company's turnover. The NACE
International report on the costs of corrosion suggests that approximately 25 % of this cost could
be saved by application of effective corrosion management, which presents an opportunity to make
significant savings and hence improve profitability for Operators.
Definitions of corrosion:
NACE/ASTM G193: ‘Corrosion is the deterioration of a material, usually a metal, that results from a
chemical or electrochemical reaction with its environment.’
ISO 8044: ‘Physicochemical interaction between a metal and its environment that results in changes
in the properties of the metal, and which may lead to significant impairment of the function of the
metal, the environment or the technical system, of which these form part.’
NASA: ‘Corrosion can be defined as the degradation of a material due to a reaction with its
environment. Degradation implies deterioration of physical properties of the material. This can be a
weakening of the material due to a loss of cross-sectional area, it can be the shattering of a metal due
to hydrogen embrittlement, or it can be the cracking of a polymer due to sunlight exposure. Materials
can be metals, polymers (plastics, rubbers, etc.), ceramics (concrete, brick, etc.) or composites-
mechanical mixtures of two or more materials with different properties.’
After the success of previous editions, this second edition of the Energy Institute (EI)'s Guidance on
corrosion management in oil and gas production and processing has been updated to:
(a) align with the Health and Safety Executive (HSE)'s revised guidance on Managing for Health
and Safety1 HSG65 2013;
(b) update the corrosion mechanisms;
(c) incorporate the lessons learned from the HSE's Ageing and Life Extension Programme KP42;
(d) highlight the applicability of this document to onshore oil and gas processing plant;
(e) consider Human Factors.
This guidance document was revised in conjunction with specialists from UK Offshore Operators and
Materials and Corrosion Engineering Consultants competent in corrosion control in the offshore oil
and gas industry.
Input to this revision was gained through working group meetings and individual contributions. The
information gathered has been collated and reviewed to identify commonalities in the approaches
taken to corrosion management across the industry.
The guidance is laid out such that the initial sections 1, 2 and 3 provide the overview of corrosion
management, whilst the details are contained in a series of Appendices. This approach is designed to
assist the reader to dip in and out of the document to obtain the information they need. For example,
Annex A provides details in the Structured Framework for Corrosion Management.
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
This guidance offers good practices for the management of corrosion for:
−− offshore hydrocarbon production installations, and
−− onshore hydrocarbon processing plant.
By following these guidelines operators of hydrocarbon production and processing facilities should
improve:
−− safety;
−− regulatory compliance;
−− reliability;
−− availability;
−− longevity, and
−− profitability.
Whilst this guidance was produced by members of the UK's offshore hydrocarbon production
industry, it has widespread applicability to onshore oil and gas production, oil and gas processing
terminals, and potentially to similar process industries across the world.
This publication has been compiled for guidance only and whilst every reasonable care has been taken
to ensure the accuracy and relevance of its contents, the Energy Institute, its sponsoring companies,
the document writer and the Working Group members listed in the Acknowledgements who have
contributed to its preparation, cannot accept any responsibility for any action taken, or not taken,
on the basis of this information. The Energy Institute shall not be liable to any person or company
for any loss or damage which may arise from the use of any of the information contained in any of
its publications.
This guidance may be reviewed from time to time and it would be of considerable assistance for any
future revision if users would send comments or suggestions for improvements to:
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
ACKNOWLEDGEMENTS
The EI wishes to record its appreciation of the work carried out by the following individuals over the
project duration:
*Special thanks to those who took on roles as lead drafters and reviewers for the various specialist
Annexes.
Technical drafting and editing: Andy Duncan, Intertek (with additional input by Dr Rachel Barson,
Steve Hodges, Dr Gareth John, Dr Steve Turgoose, Dr Mick Schofield, Dr Jim Stott, Kevin Waterton).
This second edition guidance was coordinated and managed by Dr Cameron Stewart, Energy Institute,
Upstream Technical Manager.
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
Since its introduction, this EI corrosion management guidance document has become established as
a key reference for good practice in the management of corrosion. The guidelines have been utilised
worldwide with the principal aim of improving both safety and productivity by reducing incidents
related to corrosion.
The document has its origins in the UK HSE’s Offshore Technology Report 044 Review of corrosion
management for offshore oil and gas processing, published in 2001 as part of a drive by the
Regulator for improvement in corrosion management practices to help reduce loss of containment
frequencies. The document, authored by CAPCIS, relied on the participation of a wide range of
industry stakeholders for input and contributions of good practice examples based on practical
experience.
In 2006, the EI’s Corrosion Management Working Group was formed as an initiative identified by UK
Oil and Gas and the HSE Key Programme 3 findings. The primary remit was to update and enhance
OTR 2001/044, again drawing upon the experience and participation of industry stakeholders to
identify commonalities in approaches to corrosion management and agreed good practice. The
update was compiled by the late Mike Pursell, published in 2008 by the EI and has gained widespread
industry acceptance.
In addition to the corrosion management guidance document, the Corrosion Management Working
Group (Corrosion Management Committee (CMC) since 2012) has gone on to produce numerous
publications on specific topics of significance to the industry, including external corrosion, fabric
maintenance, microbiologically influenced corrosion, downhole corrosion management and erosion.
The CMC continues to operate an extensive portfolio of working groups to address gaps in industry
guidance, with current activity ranging from ageing of non-metallic materials to valve integrity in
both upstream and downstream applications.
In 2015, the CMC identified a need to revise the 2008 edition of the corrosion management
guidance document in order to recognise the update of HSE publication HSG65, Managing
for Health and Safety. Although this revision was originally envisaged to be a minor update,
as discussion progressed this became a more extensive revision of the document in the HSG65
format, which also included many new sections deserving of particular treatment. Specifically, the
legislative framework and pertinent regulations have been clarified and new coverage of aspects
such as human factors and competency added. On the technical side, new guidance on degradation
threats such as mercury and hydrogen embrittlement/cracking have been added as well as new
sections on mitigation techniques.
Thanks are extended to the members of the CMC and their organisations for their participation,
contributions and critical review. In particular, the CMC would like to thank the technical author,
Andrew Duncan of Intertek for his expertise and diligence in the process of developing the publication.
It is hoped that this new revision of the document will prove as successful as previous versions in
providing an invaluable resource for those involved in the corrosion management process, from junior
engineer level up to senior management.
The safety of personnel remains of paramount importance in the prevention of incidents through
effective corrosion management. However, it should be stressed that control of corrosion is a key
factor in minimising the potential for unplanned production outages, the financial implications of
which can vastly outweigh the cost of implementation.
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
EXECUTIVE SUMMARY
This second edition of the EI's Guidance on corrosion management in oil and gas production
and processing provides general principles, engineering guidance and requirements for improving
corrosion management practices in oil and gas production and processing. It has been produced
by an experienced oil and gas industry work group with the objectives of:
−− Reducing the number of corrosion related hydrocarbon releases and other safety related and
environmentally damaging outcomes.
−− Identifying good practices for setting up an optimal corrosion management scheme.
−− Providing an overview of the top corrosion threats to production and processing facilities
downstream of wellheads.
−− Improving the safety profile of hydrocarbon installations.
−− Improving equipment reliability.
−− Improving equipment availability.
−− Improving profitability.
The pragmatic application of the Corrosion Management Plan (CMP) requires Duty Holder/Operator
senior management to be engaged and to actively participate in supporting members of the Corrosion
Management Team, to achieve their goals.
In this document corrosion management (CM) is defined as 'the part of the overall management
system that develops, implements, reviews and maintains the corrosion management policy and
strategy'.
The Duty Holder/Operator of the hydrocarbon producing/processing asset should have a high level
Integrity Management Policy which sets the scene for the CMP to operate within and to comply with.
This guidance document includes CM strategy requirements which should be considered normal
practice.
Persons leading the Corrosion and Integrity teams responsible for managing corrosion should have
extensive experience in the subject, and where the Team Manager does not have the requisite
technical experience they must have suitably competent staff to support them.
The HSE states that competence can be described as ‘the combination of training, skills, experience
and knowledge that a person has and their ability to apply them to perform a task safely. Other
factors, such as attitude and physical ability, can also affect someone's competence.’
The layout of this second edition is based on the elements of the UK HSE's HSG65 Managing for
health and safety model which describes the PLAN-DO-CHECK-ACT approach which was published
in 2013:
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
Risk
Planning profiling
Organising
Policy
PLAN DO
Implementing
your
plan
ACT CHECK
Learning Measuring
lessons performance
Investigating
Reviewing accidents/
performance incidents/
near misses
This document contains references to compliance with UK and European law. Where this document
is used outwith these geographical areas local laws shall apply as the minimum requirement.
Annex A provides information on the framework for corrosion management within the approach of
PLAN-DO-CHECK-ACT.
Annex B provides information for the legal basis for corrosion management, including initial
reference to UK and EU Regulations.
Annex C is a new section containing information relating to the management of Ageing and Life
Extension (ALE) of hydrocarbon producing and processing assets.
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
Annex G gives advice on implementation and analysis of corrosion management systems (CMSs).
Annex I contains information on most of the corrosion threats experienced in the oil and gas
production and processing industry.
Annex L offers a checklist for ensuring corrosion management is being handled effectively.
The complexity of a CMS will depend on the known and potential threats, the size of the operation,
and the anticipated productive longevity of the asset. These factors will affect the number of
personnel required to be involved to manage integrity of the asset. Further factors such as the extent
of outsourcing of the technical functions will also have an impact.
An effective CMS should have risk assessments for all safety critical and safety related elements,
which should have effective management processes in place to ensure both the availability and
effectiveness of barriers to failure due to corrosion, so far as is reasonably practicable (SFAIRP).
Practical experience from the United Kingdom Continental Shelf (UKCS) has shown
that an effective CMS, coupled with the commitment of the Duty Holder/Operator and
their service providers, can lead to major improvements in safety, environmental protection, reliability
and profitability in oil and gas production operations. These findings are transferable to onshore oil
and gas processing facilities.
Corrosion is first and foremost a safety risk which has to be understood and managed. Once the
safety risks associated with corrosion are managed, control of the associated economic risks will
generally follow.
In the UK's 1971 Hoar report3, and more recently in the 2002 USA Cost of Corrosion Study4
undertaken by NACE International, it is identified that corrosion costs between 3 % and 4 % (3,1 %
for the recent USA study) of a nation's Gross Domestic Product (GDP), which for an individual
business company is equivalent to 3 to 4 % of turnover. These percentages can add significant
costs to a Duty Holder/Operator's operations.
The Cost of Corrosion reports estimate that some 25 % of the cost relating to corrosion damage
could be saved by the judicious application of corrosion management techniques. This indicates a
significant opportunity to improve safety and profitability.
Corrosion in the oil and gas production and processing industries can occur on both the internal and
external surfaces of equipment. Because this equipment handles potentially hazardous fluids such
as hydrocarbon liquids and gases, they are usually referred to as Safety Critical Elements (SCEs). In
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the context of the 2015 Offshore Safety Case Regulations, Environmentally Critical Elements (ECEs)
should also be considered. It is likely that all SCEs will be ECEs. SCR2015 now refers to SECEs.
In the oil and gas production and processing industries most SECEs are fabricated from carbon steels;
however, where the corrosion and environmental degradation threats may be intolerable for safety
or economic reasons corrosion resistant alloys (CRA) such as duplex stainless steels, and high nickel
alloys may be required. Alloys may also be used to manage potential high temperature and low
temperature materials threats.
Corrosion in the oil and gas production and processing industry is managed in a number of ways,
with the choice of technique(s) being selected on their ability to work effectively over the forecasted
asset life cycle, combined with the cost of applying and maintaining the technique(s):
−− Corrosion inhibitor (CI) chemicals are used to manage internal corrosion in carbon steel
pipelines.
−− Biocides are used to control sulfate reducing bacteria (SRB).
−− Scale inhibitor chemicals are used to control scaling precipitates.
−− Wax inhibitors are used to control wax deposition.
−− Metallurgical solutions may be used to control sulfide stress corrosion cracking (SSCC) and
hydrogen induced cracking (HIC) by controlling the hardness of the steel and by using steel
with low levels of inclusions.
−− Corrosion resistant alloys (CRAs) may be used to manage intolerable corrosion threats and
extremes of temperatures.
−− Cathodic protection (CP) can be used to protect the external surfaces of buried or submerged
pipelines and structures and also of the internal surfaces of vessels.
−− Coatings can be used to protect the external surfaces of buried or submerged pipelines
and structures and also of the internal surfaces of vessels. Coatings are also used on above
ground/surface steel work which is exposed to marine environment corrosion.
−− Design may be used to minimise corrosion, for example by using swept bends to reduce
erosion, and by avoiding dead legs in process piping.
In conjunction with the selected CM techniques it is essential to deploy corrosion monitoring methods
which measure the corrosivity of the fluids, and non-destructive testing (NDT) techniques which
measure the wall thickness of the SECE. The data from the monitoring should be trended to forecast
the future criteria of non-conformance (CONC) so that early corrective action can be taken to avoid
loss of integrity.
This EI Corrosion Management guidance document sets out systems which are required to be put into
place to achieve safe and effective CM processes for oil and gas production and processing facilities.
These systems are aligned with the UK HSE's third edition of HSG65, which describes the PLAN-DO-
CHECK-ACT approach. The HSE guidance document says that the revised HSG65 shows how it can
help achieve a balance between the 'systems' and 'behavioural' aspects of management. It also treats
health and safety management as an integral part of good management generally, rather than as a
stand-alone system. It is within this same context that the CMS falls within the company's integrity
policy, and is designed to enable the Company's integrity policy to be delivered effectively.
The guidance contained in this document is not meant to be exhaustive, and new
approaches to CM and corrosion monitoring are continuously being developed. It is
recommended that companies involved with hydrocarbon production and processing, and the
service providers, should generate additional guidance and tools to ensure their CMSs are effective
at ensuring risks are as low as reasonably practicable (ALARP).
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The influence of leadership in ensuring the CM strategy is effective in keeping risks ALARP is essential.
Since the publication of the 2008 Guidelines the following corrosion mechanisms have been
identified as those which are the most difficult to accurately find and quantitatively inspect for.
These are shown in Table 1.
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1 INTRODUCTION
1.1 PURPOSE
It is recognised within the oil and gas production industry that effective CM significantly
contributes to better asset integrity and achieves:
−− Compliance with:
– statutory health, safety and environment requirements, and
– corporate health, safety and environment requirements.
−− Improved safety management.
−− Reduced environmental risks.
−− Improved process plant and structural integrity.
−− Improved plant availability and hence profitability.
−− Reduced unplanned maintenance and hence costs.
−− Reduced deferment costs.
−− Optimisation of mitigation, monitoring and inspection costs.
−− Improved working environment.
This document has been written to provide CM guidance to individuals and organisations
active within offshore and onshore oil and gas production and processing facilities. In addition
to corrosion management guidance there are practical examples of good industry practice.
In this document CM is defined as 'that part of the overall management system that develops,
implements, reviews and maintains the corrosion management policy and strategy'.
The corrosion policy provides a framework for the identification of corrosion threats and
potential consequences, and for the development and implementation of risk control
measures.
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This guidance is written to address CM within the UK and EU Regulatory frameworks for offshore
hydrocarbon production installations (Annex B). However, it is applicable to similar facilities
anywhere in the world provided local laws are complied with as a minimum.
The approaches described in this guidance can successfully be applied to most aspects of
onshore hydrocarbon production and processing.
However, the principles identified in this document are likely to be applicable to these areas
provided they are applied by a competent Technical Specialist.
CM considers those threats to process plant integrity arising from deterioration and failure
mechanisms arising from, but not limited to:
−− corrosion related mechanisms;
−− corrosion: general, localised, pitting
– CO2, H2S, amine, soils, water, et al.
−− flow influenced corrosion;
−− corrosion fatigue;6
−− microbially influenced and assisted corrosion;
−− stress corrosion cracking;
−− hydrogen induced cracking;
−− galvanic corrosion;
−− preferential weld corrosion;
−− metallurgy and microstructural influenced corrosion;
−− defective microstructure, and
−− liquid metal embrittlement.
For efficient CM of an asset the usual approach would be for the Duty Holder/Operator to
have a well-defined corrosion support function. This may consist of:
−− a centralised corrosion group supporting all assets;
−− corrosion groups supporting specific asset(s), or
−− a combination of both.
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Whichever way the function is fulfilled it is preferred that the Duty Holder/Operator has
available in-house competent persons who are capable of interacting with other engineering
and science functions within the company and also service providers.
Because CM activities may be undertaken by several persons there should be a clear structured
framework with defined roles and responsibilities.
This guidance focuses on CM during production operations. However, it is essential to get the
basis of design correct because this is the first opportunity to manage the corrosion related
risks at an early and cost-effective stage, with the preferred option being to design them out.
Many hydrocarbon producing installations are mature and likely to experience corrosion
problems which have not been designed out; these guidelines have particular applicability to
these assets.
Hydrotesting and mothballing are included in this document to address the corrosion threats
these pose to the longevity of assets. Experience has shown that a number of in-service
failures may have their origins traced back to the hydrotesting process undertaken during
commissioning.
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Previous editions of this guidance have been based upon the framework of the HSE's HSG65
Managing for health and safety which until 2013 followed the POPMAR model of Policy,
Organising, Planning, Measuring Performance, Auditing and Review.
The new HSG65 describes the relationship between the revised PLAN-DO-CHECK-ACT
approach and conventional health and safety management and also process safety, which is
contained in HSG65's Table 2 and reproduced here.
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Risk
Planning profiling
Organising
Policy
PLAN DO Implementing
your
plan
ACT CHECK
Learning Measuring
lessons performance
Investigating
Reviewing accidents/
performance incidents/
near misses
The purpose of HSG65 is to help provide a framework for organisations to comply with their
legal duties to put into place suitable arrangements to manage health and safety.
This guidance is an intrinsic part of assisting companies operating in the oil and gas production
industry not only to fulfil their health and safety obligations, but also to improve operational
reliability and hence profitability.
The form of HSG65 is such that it is likely to be able to be followed within almost all National
legal frameworks, thereby enabling Duty Holders/Operators to comply with local laws and
Regulations.
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Note: in accordance with The Offshore Installations (Safety Case etc.) Regulations 2015 'Duty
Holder' means:
−− in relation to a production installation, the operator, and
−− in relation to a non-production installation, the owner.
Note: in accordance with the guidance of the Control of Major Accident Hazards Regulations
2015, an 'operator' means:
In common parlance the terms 'Duty Holder' and 'Operator' are interchangeable.
In relation to this second edition guidance, the CHECK section of HSG65 requires Duty
Holders/Operators to consider:
−− Measurement of performance:
– to ensure the plan has been implemented;
– assess effectiveness of the corrosion threats are being managed;
– whether the CM aims are being achieved;
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2.1 PLAN
2.1.1 Purpose
The company policy(s) sets the direction for the management of corrosion and degradation
risks to ensure they are ALARP in order to improve the assets' safety profile and improve
operational reliability.
A plan is essential to delivering the company's corrosion management policy, which itself
must also comply with the Company's Health And Safety Policy.
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Risk
Planning profiling
Organising
Policy
PLAN DO Implementing
your
plan
ACT CHECK
Learning Measuring
lessons performance
Investigating
Reviewing accidents/
performance incidents/
near misses
The UK's Health and Safety laws and supporting Regulations make a number of references
to integrity management. In addition, there is a requirement for hydrocarbon operations
within UK waters to comply with the European Union's Offshore Safety Directive 2013/30/
EU.
Compliance with UK law and EU Directives is covered in more detail in Annex B of this
guidance document.
It is beyond the scope of this document to address the wider geographical legal
requirements for CM of potentially hazardous installations, other than to state that Duty
Holders/Operators and their service providers must comply with local laws as a minimum.
Where local laws fall below the normal standards required and expected by international
companies it is recommended the higher standards be followed.
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2.1.4.1 General
Company policies are a stated course of action which should reflect the vision of the
organisation and a genuine commitment to action. This view is reflected in HSE's Energy
Division Offshore oil and gas sector strategy8, that requires that the offshore industry
demonstrates effective leadership in managing major hazard risks and which also encourages
industry cooperation and leadership in health and safety. The Company Policy is typically a
short document, possibly just one page, which sets out the company's high level intentions.
Company strategies are the action plans which provide the means by which the policy is
implemented. There are likely to be several strategies to address a number of actions which
need to be undertaken to ensure that the Policy is delivered in a timely manner.
This section identifies key aspects that contribute toward an effective policy and strategy for
the management of corrosion.
Because of the central nature of the Company Policy and Strategy to delivering effective and
safe CM they should be widely communicated. An effective method for communication of
the Policy and Strategy is to undertake corrosion awareness activities which usually involve
offshore poster campaigns and presentations to platform personnel.
2.1.5 Policy
Companies and their organisations should have in place Policies to manage the hazards9
(anything that may cause harm to people and/or the environment) and risks8 (the chances
of being harmed) associated with safety, health and environmental protection. This
combination which includes the environment has acquired greater importance since the
introduction of the EU's Offshore Safety Directive 2013/30/EU.
The company's policy should address the hazards and risks associated with ageing and
life extension (ALE), and to demonstrate they are taking a long-term view of integrity and
safety management. Further information and good practice guidance is available, such
as the EI Guidelines on the corrosion management of offshore oil and gas production
facilities: addressing asset ageing and life extension (ALE), and HSE's KP4 Report and
recommendations.
Whilst the company's policy may consider threats to its profitability and business interruption,
these must not override or conflict with those that seek to manage the hazards and risks
associated with safety, health and environmental protection.
It is reasonable for the company's Policy to either be specific to CM, or for it to form a part
of its wider Integrity Management Policy.
To encourage compliance with the CM it should be signed and issued by the most senior
Manager of the facilities to which it relates.
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At Departmental level, and sitting below the company's overall CM/Integrity Policy, there
should be a detailed Corrosion Management Policy which considers:
−− Who should be considering the corrosion threats:
– corrosion engineers;
– production chemists;
– integrity engineers, and
– inspection engineers, et al.
−− What general corrosion threats should be considered.
−− Where the corrosion threats are being considered:
– specific assets/installations;
– piping;
– vessels;
– flowlines, and
– pipelines, etc.
−− Why the corrosion threats need to be managed:
– regulatory compliance;
– safety;
– longevity;
– availability;
– reliability, and
– profitability.
−− How the threats may be managed:
– chemical treatments;
– materials selection;
– coatings;
– CP, and
– environmental modification, etc.
There are no international references providing an overview of CM; however, there are
several which address the details of corrosion control, which will be covered elsewhere in
this document.
In HSE's Plant ageing study research report RR50910 and Plant ageing study research report
RR82311, ageing and ageing plant are defined as:
'Ageing is not about how old your equipment is; it is about its condition, and how that is
changing over time. Ageing is the effect whereby a component suffers some form of material
deterioration and damage (usually, but not necessarily, associated with time in service) with
an increasing likelihood of failure over the lifetime
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Work published by Professor Vinnem12 of the Norwegian University of Science and Technology
(NTNU) in 2010 states that:
'It is not possible to demonstrate a correlation between leak frequency and the age of an
installation'.
A safety management system (SMS) is a formalised approach to managing the hazards and
risks associated with hydrocarbon production and processing.
For the offshore industry, an SMS is a requirement placed upon the Duty Holder/Operator
by the Offshore Installations (Offshore Safety Directive) (Safety Case etc.) Regulations 2015,
Regulation 813, to have a document for its safety and environment management system. This
document should include:
−− the organisational structure;
−− responsibilities;
−− practices;
−− procedures;
−− processes;
−− resources for determining and implementing the corporate major accident prevention
policy, and
−− must include a description of the organisational arrangements for the control of
major accidents
For onshore hazardous industries, the requirement to have a major accident prevention
policy (MAPP) is placed upon Duty Holder/Operators in Regulation 7 of the Control of Major
Accident Hazards (COMAH) Regulations 201514:
−− '(2) A major accident prevention policy must—
(a) be designed to ensure a high level of protection of human health and the
environment;
(b) be proportionate to the major accident hazards;
(c) set out the operator's overall aims and principles of action, and
(d) set out the role and responsibility of management, and its commitment towards
continuously improving the control of major accident hazards'.
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2.1.10 Strategy
A CM strategy document should exist which describes the methods by which the policy is to
be implemented.
The strategy should describe the links between the participants responsible for delivering
the CM policy. This is particularly important where there are partnerships between the Duty
Holder/Operator, consultants and contractors.
Duty
Duty Holder/ Duty Holder/
Holder/
Operator’s Operator’s Integrity
Operator
Health and Safety Policy
Policy
Onshore Safety
Offshore Verification/
Report
Competent Person
The strategy should undergo review whenever there are forecast or known significant
changes in operations or company policy and, otherwise, at set intervals. When appropriate
the strategy should be updated on the basis of the findings of such reviews.
The strategy should address the forecast asset life and/or life extension.
The strategy should align with any separate plans that conform to statutory legal
requirements.
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2.2 DO
Risk
Planning profiling
Organising
Policy
PLAN DO Implementing
your
plan
ACT CHECK
Learning Measuring
lessons performance
Investigating
Reviewing accidents/
performance incidents/
near misses
Figure 4: HSG65 DO
2.2.1 Purpose
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'A risk is the likelihood that a hazard will actually cause its adverse effects, together with a
measure of the effect. It is a two-part concept and you have to have both parts to make sense
of it. Likelihoods can be expressed as probabilities (e.g. 'one in a thousand'), frequencies (e.g.
'1000 cases per year') or in a qualitative way (e.g. 'negligible', 'significant', etc.)'.
In the field of CM the focus is on identifying the corrosion related threat, the rate at which
it has been propagating, the rate at which it is likely to propagate in the future, and hence
when it is likely to manifest itself as a risk to: people, environment and business.
A Corrosion Risk Assessment System (CRAS) allows threats and their potential consequences
to be identified and the risks they present to be ranked. As a result plans can be made to
apply resources to combat the significant risks and to mimimise effort being wasted on
insignificant risks.
At the design stage the CRAS can be based on theoretical considerations combined with
personal and industry experience.
Throughout the life of the facility the CRAS should be refocused and refined as a consequence
of operational experience and inspection history.
At the design stage the task is to plan activities in both design and construction and in initial
operations. At this stage there are opportunities to eliminate some risks completely and
achieve inherent safety through process design and the use of resistant materials.
Planning is made both at the strategic level, which outlines the key choice of barriers to
the threats, and at the tactical level where the activities to implement, and to monitor the
effectiveness of, those barriers are identified and written down.
A CRAS may be undertaken in accordance with one or more of the following methodologies:
−− API RP 580 Risk based inspection;
−− DNV RP G101 Risk based inspection of offshore topsides static mechanical equipment;
−− NACE 10367 High level corrosion risk assessment methodology for oil and gas
production systems, or
−− equivalent recognised CRAS guidance.
In accordance with the EU Offshore Safety Directive, all Safety and Environmentally Critical
Elements (SECE) must be identified and logged in a suitable database.
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except for—
(a) plant which is part of the safety and environmental-critical elements for that
installation, and
(b) aircraft or equipment to which regulation 18 of the PFEER Regulations applies.
For the purposes of clarity, in the majority of cases SCEs and ECEs will be the same, hence
from hereon only SECEs will be referred to.
The Duty Holder/Operator will usually identify and record Business Critical Elements, but in
terms of risk management these are subservient to SECEs.
The corrosion threats to the integrity of SECEs and the likelihood they will fail must be defined.
Where possible the rate of deterioration of SECEs should be determined by extrapolation
of verified inspection data and/or theoretical calculation using process data. Examples of
theoretical calculations include:
−− CO2 corrosivity models;
−− oxygen corrosivity models, and
−− microbially influenced corrosivity models.
The consequences of a corrosion related failure which may occur in the event of an unplanned
release of hazardous material from the process is a separate calculation to that for the
corrosion risk. The consequences relate to the potential for:
−− persons who may be harmed or killed (potential for loss of life, PLL);
−− environmental damage, and
−− business interruption.
In accordance with the EU Directive the potential for personnel and environmental harm
must be determined; however, note that for the purposes of a CRAS study this may be done
on a semi-quantitative basis and there is no requirement to perform a full Quantitative Risk
Assessment (QRA). A QRA is usually the responsibility of the Process Safety Department.
The probability of a corrosion related failure of each SECE and its consequences on people
and the environment should be calculated to determine a Risk Rank which should be used
to prioritise the allocation of resources to manage the risks using inspection and corrosion
mitigation techniques.
The CRAS method followed must be documented and should be verified by a third party to
ensure validity.
The internal and external environment of SECEs subject to CRAS must be recorded.
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The CRAS should be reviewed at a frequency commensurate with the risk and when operating
conditions are, or are forecasted to be, subject to a significant change. A significant change
may include:
−− increased water cuts;
−− increased H2S levels;
−− increased CO2 levels;
−− new process streams entering the system, and
−− appearance of a widespread unmanaged risk requiring urgent action.
2.2.4 Organising
2.2.4.1 Purpose
Effective management and practices are required to deliver the CM policy and strategy.
This section provides a framework and examples of how a CMS helps in the allocation of roles
and responsibilities both within the Duty Holder/Operator's organisation and contractor/sub-
contractor organisations.
2.2.4.2 General
The management of corrosion and its consequences usually crosses a number of departments
and will frequently extend beyond the Duty Holder/Operator to consultants and contractors.
'make and give effect to such arrangements as are appropriate, having regard to the nature
of his activities and the size of his undertaking, for the effective planning, organisation,
control, monitoring and review of the preventive and protective measures16'.
Because of the common practice of using both Duty Holder/Operator staff and also service
providers, it is important to ensure the CM culture extends to all those involved.
Competency should be achieved through the combination of17: training, skills, and experience
to ensure that corrosion and integrity personnel have the ability to perform their tasks
effectively.
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A CM and Integrity team should exist with responsibilities for coordination, cooperation and
communication, to ensure the highest reasonably practicable levels of safety across assets,
and to ensure responsibility and accountability for CM. For very small organisations this is
likely to rely substantially on service providers.
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Table 3: Criteria of non-conformance
Equipment
Risk level
Potential
consequences
Priority
Reason
Mitigating actions
Estimated date to fail
criteria of
non-conformance
Operational risk
assessment required?
42
pipe Low leak, deferred P3 No
injection = MAWT + 1 mm seawater replacement yyyy
production
Planned yy/yy/
Turbine fuel piping High Fire, power loss P1 Fatigue crack in SBT vibration Yes
replacement yyyy
The criteria for allocating the risk level should be based upon the Corporate risk matrix, an example of which is provided in Table 4.
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Consequence of Safety Env Ops Likelihood of occurrence
Occurrence
GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
A B C D E
> 20 yrs 10 to 5 to 2 to < 2 years
20 yrs 10 yrs 5 years
5 Catastrophic Multiple fatalities Extreme impact > $10 M Extreme
4 Severe Fatality Severe impact $1 M to $10 M
3 Critical Major injury Major impact $100 K to $1 M High
2 Marginal Minor injury Minor impact $10 K to 100 K Medium
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1 Negligible No injury No impact < $10 K Low
GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
The roles and responsibilities of managerial and technical personnel should be clearly
defined within the organisation and ideally on a functional organogram. More information
is contained within Annex E.
Where service providers deliver significant technical support they should share their
organograms with the Duty Holder/Operator.
Particular areas of concern which may require specialist expertise should be identified;
examples may include:
−− sour service;
−− marginal corrosion inhibitor (CI) performance of high corrosivity high flow rate gas
streams, and
−− CRAs operating close to their safety margins, et al.
Personnel involved with CM should have the time and resources needed to fulfil their
responsibilities.
The interfaces and their responsibilities between Duty Holder/Operators and service providers
should be clear to avoid the potential for contradictory instructions.
2.2.4.4 Competence
The HSE states that competence18: can be described as the:
'combination of training, skills, experience and knowledge that a person has and their ability
to apply them to perform a task safely'.
Other factors, such as attitude and physical ability, can also affect someone's competence.
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For persons working at the level of professional Senior Corrosion Engineer in the oil and
gas industry there is a reasonable expectation they will have a degree (or equivalent) in a
relevant22 numerate scientific subject (Bachelor of Science, BSc, Bachelor of Engineering,
BEng) with associated training and experience and preferably be a Chartered Engineer (or
equivalent).
However, there are successful examples of Technician grade personnel becoming competent
by training and experience. It is for each employing organisation to define and document
the competency expectations for each level of Corrosion, Materials and Integrity Engineer,
from the recruitment stage to Technical Authority level. Any competency gaps should be
managed by supervision, training and development.
For those working in deep specialist subsets of corrosion engineering, specific qualifications
and experience are usually required. For example a specialist in Microbially Induced Corrosion
(MIC) would be expected to have qualifications in biology and/or microbiology.
Training should be planned and implemented as part of the corporate policy and procedures
for ensuring competency for defined roles.
Performance should be routinely assessed and additional training and experience provided
to assure competence.
For highly specialised matters which extend beyond core materials and corrosion
engineering, the advice of experienced engineers/scientists should be sought. Examples of
this may include:
−− Microbiologists, Production Chemists and Reservoir Engineers for reservoir souring
studies.
−− Corrosion Engineers and Process Engineers for complex pipeline corrosion studies.
−− Specialised Metallurgists for CRAs.
Personnel involved with CM should understand their roles, the risks, processes and procedures.
They should understand the technical limitations of themselves and those for whom they are
responsible.
2.2.4.5 Communication
Relevant information relating to CM and in particular known risks must be disseminated to
those persons identified on the roles and responsibilities organogram.
Written procedures, work instructions and guidelines should be developed and shared with
relevant personnel.
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Key roles in Duty Holder/Operators and service providers contributing to the CMT should be
identified and circulated with relevant corrosion and integrity related data.
The CMT should identify meeting frequencies to review the status of: actions; planning and
budgets. Minutes of the meetings should be taken, approved and circulated.
2.2.4.6 Cooperation
The 2014 Wood Report23 on Maximising Recovery From The UKCS identifies the need to
encourage and facilitate greater industry collaboration; this applies within companies,
between companies and external organisations. It is important to avoid 'knowledge silos'.
The purpose of cooperation is to improve safety, reliability and business continuity.
Personnel responsible for managing corrosion risks should consult and seek information from:
−− managers;
−− designers;
−− operations and maintenance engineers;
−− inspection departments;
−− corrosion engineers, and
−− service providers where necessary.
Relevant staff should be consulted for technical opinions and involved in planning and
reviewing performance.
Coordination with service providers should be achieved with clear documented guidance.
Cooperation should be maintained with external bodies to share information which can
improve the wider levels of safety and business continuity in the industry. This may be
achieved through technical fora and trade bodies.
2.2.5.1 Purpose
To ensure effective implementation of the CMPs to ensure risks are ALARP.
Leading and lagging Key Performance Indicators (KPIs) should be used to ensure corrective
actions are taken in a timely manner.
2.2.5.2 General
Implementing the CMPs should be consistent with the corporate strategic and tactical plans
for safety and integrity management.
Training and corrosion awareness activities should be undertaken in accordance with the
CMP timetable, to ensure that installation personnel in particular understand and can work
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effectively to the procedures and instructions. Where personnel are required to work to new
procedures and written schemes of examination (WSoEs) they should have suitable training
and toolbox talks prior to being deployed for the first time.
This section identifies important aspects which contribute towards effectively implementing
the CMP and is focused on corrosion management in the operational phase of an installation's
life.
It should be noted that CMPs should be initiated at the design phase and during the design
and construction phases to enhance the opportunities to improve inherent safety.
To ensure that the risks to the asset/installation are controlled SFAIRP, implementing the plan
includes both:
−− Implementing the mitigation activities which provide barriers to the corrosion risk.
−− The monitoring and inspection activities which ensure the mitigation activities remain
effective. This includes:
– corrosion rate monitoring;
– process monitoring;
– non-destructive inspection;
– data collection;
– data analysis;
– reporting, and
– corrective actions.
2.2.5.3 Implementation
The CMP should be translated into written practical instructions, with allocated responsibilities,
to enable it to be carried out, such as:
−− planned maintenance routines;
−− operating instructions;
−− WSoE;
−− work packs, and
−− reporting lines.
Physical locations for corrosion and inspection monitoring should be identified on Piping
and Instrumentation Diagrams (P&ID), isometrics or Process Flow Diagrams (PFD) as
appropriate.
The reporting routes should be defined. This is particularly important for critical defect
findings which may need a rapid response.
There should be written procedures and instructions which identify the CoNC for SECEs,
which for piping and vessel wall thicknesses is normally the calculated Minimum Allowable
Wall Thickness (MAWT). It is normal practice to identify warning levels before attaining CoNC.
Anomaly reports, which relate to an agreed Performance Standard, are required to capture
those corrosion and inspection activities which have identified defects.
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In order to ensure that defects are made safe in a timely manner there should be a
documented procedure which enables prioritisation of defects and hence repair and
maintenance action.
There should be a procedure for Opportunistic Based Visual Inspections (OBVI) which fall
outwith the normal corrosion and integrity management plans.
Reporting procedures should identify where planned activities have not been performed and
identify what should be done to manage the shortfall.
CM, corrosion monitoring and inspection data should typically be stored in electronic format
in a common location to enable sharing with those involved. Password protection may be
necessary to prevent unintentional data changes.
To obtain full value from the data they should be trended using graphical and statistical
means to forecast future risks to enable corrective action to be taken in a timely manner.
Where monitored values fall outwith the allowable performance limits (e.g. pipe or vessel
wall thickness, or underdosing/overdosing of a production chemical) they must be recorded
and sent through the correct reporting routes in accordance with the prioritisation
and escalation procedures so that assessments can be made and corrective measures
implemented.
CM, corrosion monitoring and inspection data should be reviewed and validated by
a competent person other than the data collector. Consideration should be given to
measurement uncertainties when performing data analyses, for example, different types of
ultrasonic testing devices may have intrinsic different accuracies.
Where appropriate, a review of CM, corrosion monitoring and inspection data should be
undertaken by competent person(s) and a clear statement made regarding the current
condition and continuing suitability of the work equipment. It is appropriate to do this when
the data indicate the equipment:
−− is at or near its retiral criterion/CONC;
−− is likely to reach the retiral criterion/CONC before the next measurement date, or
−− if it is likely to reach the retiral criterion/CONC before the cessation of field life.
Data reviews must be carried out immediately where there is found to be imminent risk to
personnel and equipment.
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The findings of the installation verification scheme (SCR15 Regulations 19, 20,
21) should be included in the CM review, particularly where a non-conformance
has been identified by letter ('note of reservation') from the Verification Body.
The results of the data reviews should be used to update the CRAS and determine if the risk
profile has changed. Any changes to the corrosion risk profile should be input into the CM
programme and used to revise the RBI programme.
Corrective actions arising from the data review and completion time scales should be captured
in an information system that allows implementation and action close-out to be tracked.
Where corrective actions are a temporary arrangement, periodic reviews are required to
consider both their effectiveness and monitor implementation of a permanent solution.
Note that temporary actions may be required to be subject to a formal Operational Risk
Assessment (ORA) logged in the installation's ORA system.
Unexpected failures and near misses are learning opportunities; there should be a system in
place to review these events, undertake a Root Cause Analysis (RCA) and feed the results into
both the CMS and the SMS to prevent recurrence.
There should be procedures in place to govern: reporting, analyses and corrective actions.
Functional responsibilities for data analyses, determination of corrective actions and their
implementation should be identified. The technical functions responsible for determining the
suitability, investigation and corrective actions should be defined.
A key finding of HSE's KP4 report on A&LE of offshore installations is the need to trend data
to determine when the future CONC is likely to be reached. This requirement is emphasised
here because a combination of data extrapolation and statistical analysis can be used to
estimate when the CONC will be reached.
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2.3 CHECK
Risk
Planning profiling
Organising
Policy
PLAN DO Implementing
your
plan
ACT CHECK
Learning Measuring
lessons performance
Investigating
Reviewing accidents/
performance incidents/
near misses
2.3.1 Purpose
Within the CHECK section of HSG65 it requires the Duty Holder/Operator to:
−− monitor performance
−− investigate accidents and incidents
For the purposes of CM this requires implementation of the policy by measurement against
agreed standards to identify where, when and why improvement is needed.
This section considers key aspects which contribute towards the effective monitoring and
measurement of performance of the CMS, and also implementation of the plan.
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Measuring performance is key to establishing whether the CMP is fit-for-purpose, and it also
forms the basis for continuous improvement to keep risks ALARP.
For each asset/installation Duty Holder/Operators should undertake regular proactive and
reactive monitoring to measure the extent to which:
−− the CMP is being met;
−− the effectiveness of the CMP in controlling corrosion related risks to ALARP, and
−− the extent to which the CMP meets the corporate integrity policy objectives.
KPIs should be selected that are meaningful, relevant and practicable, to measure the
performance of the corrosion management strategy, its implementation and its place within
the facility's SMS.
KPIs should contain target values for the performance limits of barriers to corrosion, which
must be relevant to the engineered design of the installation including the nominal design
life or revised forecasted cessation of production data. Where a new cessation of production
date is identified these targets should be subject to engineering review.
KPIs should enable the demonstration of the degree of success of the CMP, as well as
identifying trends that enable corrective action in a timely manner.
KPIs should indicate how well the CMP is being implemented (execution of the plan):
−− leading indicators (proactive).
2.3.4 Responsibility
Approval of the KPIs should be reviewed by the functional management of those accountable
for meeting them and agreement sought for the measures and the targets.
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Those responsible for carrying out the measured activities should report results at the required
frequency to the accountable supervisor to agree an interpretation and present them to
management.
The results from all teams involved with delivering the CMP should be collated by the CMT
(see also Annex E Organisation), which should recommend corrective action where necessary.
2.3.5 Frequency
The frequency of measuring the performance of the CMP should be set so that any corrective
actions can be effected in a timely manner before risks become unacceptable.
The frequency of measuring the performance of the CMP should be such that it is possible to
get a meaningful assessment of change, taking into account potential errors of measurement.
The frequency of measuring the performance of the CMP should increase where the rate of
non-conformances is observed to increase.
Where measured deviations from the CMP are observed to be consistently decreasing in
number there may be an opportunity to reduce the monitoring frequency.
The results of measuring the performance of the CMP should be collated and assessed
to identify both unique and common failings. This analysis should be presented to Duty
Holder/Operator decision makers at frequencies which enable them to manage risks in a
timely manner.
Where there is evidence of persistent failure to meet the KPIs, particularly where the
consequence is to increase the risk profile, it should be investigated to determine the root
cause and put in place a permanent solution.
It is common for the productive operating life of oil and gas fields to exceed the original
nominal design life and go into the life extension phase. This likelihood should be anticipated
and the KPIs used or adapted to ensure barriers for safety will be effective beyond the design
life.
Personnel responsible for implementing the CMP should maintain contact with those
responsible for determining the date of cessation of production so that the CMP can be
updated to address any concerns over reduced barriers to failure.
Failure investigation is a complex subject which may involve the collaboration of a number
of specialists. All investigations should adopt a thorough and systematic approach, but each
investigation should be scoped on its own merits.
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Failures of plant and equipment are often a result of an uncontrolled incident or occurrence,
so an essential part of any investigation is ensuring the safety of those undertaking the site
investigation.
A failure investigation should be aimed at not only identifying the mechanism of failure but
more importantly the circumstances which led to the failure, i.e. the cause, so corrective
actions can be implemented to prevent a recurrence of the failure. Establishing the mechanism
and cause of any failure are essential parts of any RCA.
Failure investigation does not lend itself to a tick box approach. Each failure investigation
should be approached with an open mind. In many instances the investigation is a process
of elimination where possible failure mechanisms are considered then discounted as results
become available, allowing the investigator to focus on the real issues leading to the failure
of the component/item.
It is important before starting any investigation to get a basic understanding of the problem
so individuals with the correct skill set and experience can be engaged or consulted.
Having this background information allows the investigator to devise an overall plan for
the investigation which improves efficiency and can save costs in the long term. An outline
of what may need to be asked to allow an investigation plan to be developed is presented
in Annex K.
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2.4 ACT
Risk
Planning profiling
Organising
Policy
PLAN DO Implementing
your
plan
ACT CHECK
Learning Measuring
lessons performance
Investigating
Reviewing accidents/
performance incidents/
near misses
2.4.1 Purpose
Duty Holder/Operators should ensure that systematic reviews of the performance of the CMP
are undertaken. These should be based on:
−− data from the monitoring of system performance, and
−− independent audits by third parties not directly associated with implementing the
CMP.
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The findings from the review process should enable organisations to feed back into the CM
policy and strategy to:
−− achieve continuous improvement of safety and integrity performance;
−− keep up to date with the changing production requirements;
−− ensure compliance with statutory requirements, and
−− contribute to business plans.
The audit should provide an independent and objective comparison between the CMP and
the maintenance management system which implements corrective actions.
The purpose of an audit is to ensure that the CMP is working effectively to keep risks ALARP,
and that the associated procedures are being followed.
The results of audits should be used to improve the CMP and the strategy.
Reviews of the CMP and its implementation should include key relevant technical persons
from the Duty Holder/Operator and service providers. These persons/technical functions may
include:
−− Corrosion TA;
−− Integrity TA;
−− Production Chemistry TA;
−− NDT service provider liaison Engineer, and
−− Production Chemicals service provider liaison.
The CMP review process should be endorsed by a level of management with the authority to
implement recommendations for necessary changes.
Reviews should consider leading and lagging KPIs and assess the effectiveness of the
processes and procedures in meeting the KPIs.
The review frequencies should be in keeping with the risk profile so that safety and integrity
improvements are made in a timely manner.
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Corrective actions from the reviews should feed back into the CMP strategy and where
necessary into the installation's SMS.
The potential for new techniques and technologies to improve the risk profile should be
considered.
The reports should include a summary for senior management and include graphs showing
extent of compliance with KPIs. An effective approach to providing overview information to
management in a readily accessible format is to use a dashboard.
Good performance and promotion of good practice should be identified in the reviews.
The audit should review the performance of the CMS and is normally carried out by an
independent party (either an external contractor or an independent technical authority not
directly involved with the running of the facility in question).
The purpose of reviewing the performance of the CMS is to ensure there is an active process
for ensuring it is working effectively.
The lessons learned from the review of the performance and audit should be linked back
to the original Policy which set the scene for the corporate CMP.
The audit should cover review of the management processes that are being employed to
ensure continuing integrity of the facility. The audit can cover all aspects of:
−− implementation of procedures and processes;
−− competencies;
−− checks in place, and
−− compliance with the process and procedures.
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The audit will draw on input from reviews of the facility corrosion status and management
against KPIs etc, but it is not a detailed technical review of mitigation, monitoring and
inspection data. Rather, it aims to determine whether the procedures in place are fit-for-
purpose and are being properly implemented to ensure the relevant performance targets
are able to be achieved.
The checklist contained in Annex L may be used to assess the effectiveness of the CMS.
Not all specific items on the checklists can be covered or tested during each review, but a
selection of aspects should be reviewed in detail. It should be noted that not all identified
findings will arise purely from the checklists and that Engineers should exercise judgement.
Evidence for those aspects that are examined or tested should be based on:
−− documentation, and/or
−− personnel interviews.
Both the internal staff and consultant/contractor staff activities should be subject to review
and audit.
The overall audit/review should be summarised in a report for review by appropriate Senior
Management to allow comparison during future reviews. Improvement actions raised should
be recorded, responsibilities allocated, given target completion dates and tracked until
complete.
Audits should be carried out objectively and in accordance with an established checklist.
The audit should cover the activities of the Duty Holder/Operator and service providers.
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The person(s) carrying out the audits should be competent in CM practices and in performing
audits.
The auditor(s) should be independent of both the operational and functional teams that
are directly involved in implementing the installation's CMS.
Where non-compliance is identified, corrective action and time to implement the actions
should be agreed with the auditee.
Audit reports should be made available to the installation management and the CMT.
Where an installation's operating life has been, or is likely to be, extended, the audit should
establish whether the CMP remains fit-for-purpose for the new cessation of production date.
The audit should determine whether the CMP addresses the issue of managing the ALE
process.
The audit should establish whether the implementation of the CMP is managing the ALE
risks.
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3 HUMAN FACTORS
3.1 INTRODUCTION
Whilst this is a corrosion technical document, it should be recognised that the development
and implementation of any CMS is undertaken by people and because of this, there is the
possibility of error.
The HSE identifies the importance of competence and organisation to minimising risks,
wherein it defines human factors:
'Human factors refer to environmental, organisational and job factors, and human and
individual characteristics, which influence behaviour at work in a way which can affect health
and safety'25
To summarise, human factors is concerned with what people are being asked to do (the task
and its characteristics), who is doing it (the individual and their competence) and where they
are working (the organisation and its attributes), all of which are influenced by the wider
concerns of society, both local and national.
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In 2006 a RAF Nimrod MR2 reconnaissance aircraft XV230 exploded over Afghanistan, killing
all on board. The subsequent independent Nimrod Review28 led by Lord Haddon-Cave QC
identified several Human Factors failings which contributed to the loss of the aircraft and
consequent loss of life.
A Human Factors issue Lord Haddon-Cave refers to in the Nimrod Review findings is
'normalisation of deviance' wherein frequently observed failings in performance and safety
become the norm.
The acceptance of events that are not supposed to happen was originally described by
sociologist Diane Vaughan29 as the 'normalisation of deviance'.
Personnel working in such environments become conditioned over time to regard this
condition as normal and hence acceptable, giving rise to the phenomenon of 'normalisation
of deviance'. This human condition was also attributed to have contributed to the loss of the
NASA Challenger spacecraft in 1986 (seven deaths) and the King's Cross Underground fire
in 1987 (80 deaths).
Examples of normalisation of deviance in the oil and gas industry may include acceptance of:
−− degraded paintwork and corroded piping;
−− corroded handrails and walkways;
−− leaking valve stems;
−− high MCDR backlogs;
−− incomplete lists of SECEs, and
−− incomplete plant drawings.
3.2 PLAN
3.2.1 Policy
Minimising the potential for failures resulting from Human Factors requires consideration of:
−− competency of individuals working in all aspects of the corrosion and integrity
management activities;
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−− the organisation being suitable for the size of the enterprise being undertaken, and
−− verification activities and peer review to ensure activities are being performed
satisfactorily.
Human Factors interventions will not be effective if they consider these aspects in isolation.
The scope of Human Factors includes organisational systems and is considerably broader
than traditional views of human factors/ergonomics. Human Factors can, and should, be
included within a good Safety Management System so it can be examined in a similar way to
any other risk control system.
3.2.2 Planning
Activities to be conducted during initial planning include identifying the key Human Factors
issues within the organisation or project by:
−− obtaining input from staff;
−− studying accident reports;
−− performing risk assessments, and
−− shadowing end-users to observe tasks in progress.
3.3 DO
Human Factors issues should be incorporated into risk assessments for all safety critical
procedures.
Actions and measures that will help prevent accidents/failures should be identified. Feedback
from performance reviews and investigations into accidents/incidents/near misses will
provide information on the progress and the current status of risk control arrangements
and highlight gaps that require remedial action.
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3.3.2 Organisation
A clearly defined management structure and series of processes are required to achieve the
agreed outcomes.
The roles include the operations manager, supervisors, operations staff, contractors and any
external staff and will include consideration of the following components:
−− roles, responsibilities and accountabilities;
−− competence;
−− communication of critical information, and
−− cooperation between all parties.
Responsibilities should be written into job descriptions and should have the necessary
authority and resources and should be channelled through clear reporting lines.
Clear leadership is required to raise awareness of the issues relating to Human Factors and
gain acceptance for any changes required. Other specific tasks include:
−− designing and overseeing the implementation of solutions to Human Factors issues;
−− involving staff and their representatives in the implementation process, and
−− auditing, routine monitoring and status reviews.
3.4 CHECK
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Investigations should identify whether human factors lie at the root cause or are a contributing
factor. The reasons for unsatisfactory performance by staff and any underlying failures in the
management system should be identified.
3.5 ACT
Periodic status reviews should assess the overall performance of the system, the performance
of individual elements, audit findings and factors, such as changes in organisational structure,
production, technology or new legislation, It should be based on monitoring data and be
an ongoing process, enhanced by establishing responsibilities and accountabilities for the
implementation of remedial actions.
Additionally, reviews should be conducted by the management team and based on audit
results and performance measurement reports. It should identify any gaps, what, if any,
changes are needed and findings should be circulated to all stakeholders. Objectives
for continual improvement should be defined through the development of plans and
nominated individuals from the management team should be responsible for overseeing any
recommended changes, and corrective actions.
The conclusions drawn from performance reviews will be communicated to all stakeholders
and staff as appropriate. The management should be responsible for seeing through any
recommended changes with the aim of continuous improvement.
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ANNEX A
STRUCTURED FRAMEWORK FOR CORROSION MANAGEMENT
The CMS should provide a framework compatible with the requirements of the Operator's
safety and environmental management policies and procedures for ensuring the integrity of
the installation and its processing equipment. One way of achieving this is to follow the HSE's
framework HSG65, which has the approach of:
−− PLAN
−− DO
−− CHECK
−− ACT
Where deficiencies are identified the revised plans should be implemented in a timely manner
to achieve safe and economic operations.
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Risk
Planning profiling
Organising
Policy
PLAN DO Implementing
your
plan
ACT CHECK
Learning Measuring
lessons performance
Investigating
Reviewing accidents/
performance incidents/
near misses
The size of the team(s) involved with developing and implementing the CMP will be
dependent upon the size and complexity of the hydrocarbon production system. A single
well platform will require significantly fewer integrity management resources than a multi-
well platform which also has subsea completions. It is incumbent upon the Duty Holder/
Operator to have suitable and sufficient resource arrangements relative to the size of the
undertaking to ensure safe operations.
The CMS requires a high level of technical input. Competent persons should be used to
undertake the corrosion risk assessments for safety critical andsafety related equipment and
also for the planning and implementation of CM and corrosion monitoring activities. The
persons performing the CRAS and developing the CM strategies should understand the
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consequences (benefits and potential threats) associated with the materials of construction
(CRA versus carbon-steel), the process fluid corrosivity, water cuts, age of the production
system and the maintenance strategies adopted.
With respect to the maintenance strategies, these should be designed to ensure that the
equipment is suitable for the conditions under which it operates and remains safe to operate
to cessation of production (CoP) SFAIRP. Within this context it should be noted that where the
Duty Holder/Operator knows and has documented the CoP date, it is reasonable to operate
a reduced frequency of maintenance, provided the condition of the equipment is known, its
rate of degradation is known and it is forecasted to be operating within its CONC to CoP.
To achieve this requires the Duty Holder/Operator to have an effective physical monitoring
programme in place (e.g. NDT) and the data trended to enable a demonstration that the
equipment will be fit-for-purpose to CoP.
Experience from the oil and gas production and processing industry shows that the
development and implementation of CRASs, RBIs and CMSs, coupled with commitment from
the Duty Holder/Operator and service providers, leads to significant improvements in integrity
management and hence safety. There are also consequential financial and environmental
benefits accrued by reducing the risk of unplanned downtime and leak frequency.
Experience shows that the CMS will only work effectively if it is a live documented system,
which is used, reviewed, audited and improved on a regular basis. The continuous loop
of the PLAN-DO-CHECK-ACT process described in HSG65 demonstrates this requirement.
The frequency of review and audit is a function of the rate of change of conditions and
functionality.
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ANNEX B
LEGAL BASIS FOR CORROSION MANAGEMENT
It is anticipated that all countries will have a legal basis for ensuring the safety and integrity of
potentially hazardous plant and equipment. This guidance will help Duty Holders/Operators
to comply with their legal duties in the countries within which they operate.
Because this document was drawn up in the UK and the contributors are familiar with UK
law, there is a greater reference to UK law; however, there is reference to European Union
Law and Directives and international law.
It is for the Duty Holder/Operator to ensure they comply with local laws and to ensure they
have competent persons able to work within the local legislative framework. Where local
laws fall below the normal standards required by international companies it is recommended
that the higher standards should be followed.
EU Directive:
Safety of offshore oil and gas operations and amending Directive 2013/30EU: Articles 2, 3,
11, 19
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United Kingdom
In the UK, Duty Holders/Operators have a legal duty to put in place suitable arrangements
to manage health and safety as an integral part of the organisation. HSG65 identifies the
essentials of managing health and safety as:
−− leadership and management;
−− a trained/skilled workforce, and
−− the involvement of people.
HSG65 links the need for having suitable arrangements to the wider risk management issues
as described in Figure B.1.
Leadership
The basis for the UK's health and safety regime is the Health And Safety At Work etc. Act
1974 (HSWA) which identifies the responsibilities of employers to those in their employ and
those not in their employ.
… 'maintenance of plant and systems of work that are, so far as is reasonably practicable,
safe and without risks to health', and
…'so far as is reasonably practicable as regards any place of work under the employer's
control, the maintenance of it in a condition that is safe and without risks to health and
the provision and maintenance of means of access to and egress from it that are safe and
without such risks', and
…'to use the best practicable means for preventing the emission into the atmosphere from
the premises of noxious or offensive substances and for rendering harmless and inoffensive
such substances as may be so emitted'.
These legal requirements have clear applicability to hydrocarbon production and processing
facilities and introduce the idea of the need to maintain equipment and manage risks, of
which CM is a part.
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The term 'So Far As Is Reasonably Practicable' (SFAIRP) is interchangeable with another
term 'As Low As Reasonably Practicable' (ALARP), which is simply described as weighing a
risk against the trouble, time and money needed to control the risk.
According to the HSE31 'Deciding whether a risk is ALARP can be challenging because it
requires duty-holders and us to exercise judgement. In the great majority of cases, it can be
decided by referring to existing 'good practice' that has been established by a process
of discussion with stakeholders to achieve a consensus about what is ALARP. For
high hazards, complex or novel situations, we build on good practice, using more
formal decision making techniques, including cost-benefit analysis, to inform our
judgement'. One of the purposes of this second edition is to present the good practice
required to keep risks ALARP.
Supporting the HSWA is a range of Regulations which Duty Holders/Operators are required
to consider to keep risks ALARP, some of which are specific to offshore installations, some are
specific to onshore installations and others cover both:
These Regulations form the legal basis of many of the activities relating to CM, including the
requirements to undertake corrosion risk assessments and to have mitigation methods in
place to manage the consequences of corrosion.
This document is written to provide examples of good practice for the development of CM
systems, and against which an existing scheme can be assessed.
The document generally refers to the requirements included in the UK's goal setting legislative
regime, which allows the Duty Holder/Operator or service provider to develop a suitable
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system to achieve the aims and with which to demonstrate compliance. This approach is
likely to be applicable to all but the most prescriptive of legislative jurisdictions, for which
consideration must be made to ensure compliance.
The Regulatory regime applicable to the UK's offshore installations places a requirement on
the Duty Holder/Operator to ensure, SFAIRP, that work equipment (SCEs) 'is maintained in an
efficient state, in efficient working order and in good repair'. This requires the integrity of the
process plant and associated structures to be maintained to keep risks ALARP to ensure that
equipment can be operated safely and a safe working environment maintained.
This Regulatory regime requires the creator of the risk (the Duty Holder/Operator) to provide
a system of work such that the risks to health and safety are reduced to ALARP, i.e. where
to do more would suffer a grossly disproportionate increase in cost to the reduction in risk.
This requires the operator to assess the risks and plan for appropriate risk control measures,
including the elements of a CM scheme. Figure 9 demonstrates the ALARP principle from
the HSE website.
1 × 10–3 (workers)
1 × 10–4 (public)
Relevant good
practice
plus Tolerable if
Risk reduction ALARP
measures
plus
Gross
disproportion
1 × 10–6 (all)
Relevant
good
practice Broadly
acceptable
UK offshore legislation consists of a hierarchical framework (see Figure B.3) where each level
provides further detail on how to achieve the fundamental requirement set by the HSWA for
a safe system of work. The Regulations provide a risk based lifecycle approach and prescribe
goal-setting requirements i.e. the Regulations define outcomes but not how these are to
be achieved. The management of corrosion is therefore not specifically identified within
legislation. However, the law implicitly requires corrosion, as a foreseeable hazard, to be
managed such that the risk to health and safety arising from corrosion is ALARP.
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Health and Safety at Work, Etc. Act 1974 Primary
Legislation
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Those parts of a hydrocarbon pipeline which are on an offshore installation or within the
500 metre safety zone of the installation are subject to the same Regulations as offshore
installations.
PSR define the interaction with PSSR. HSWA provides the dominant requirement to provide a
safe system of work for both offshore and onshore.
Beneath the Regulations are Approved Codes of Practice (ACOP) (Figure B.3) which describe
preferred or recommended methods that can be used (or standards to be met) to comply
with Regulations and the duties imposed by the HSWA etc. Act. ACOPs are issued by the
Health and Safety Executive and are not compulsory unless otherwise stated; however
following the guidance will normally be enough to comply with the law.
Beneath the ACOPs the HSE also issues guidance to the Regulations which is not compulsory
and Duty Holder/Operators are free to take other action; however, following the guidance
will normally be enough to comply with the law.
Each of the supporting Regulations contains requirements which will impact on CM, which
can be separated into Risk Assessment and Integrity:
B.3.1 MHSWR
Identify the duties placed upon employers which require that risk assessments (Reg. 3) shall
be undertaken (e.g. Corrosion Risk Assessment). MHSWR also identify that a risk prevention
hierarchy shall be followed (Reg. 4 and Schedule 1) as follows:
(a) avoiding risks;
(b) evaluating the risks which cannot be avoided;
(c) combating the risks at source;
(d) adapting the work to the individual, especially with regard to the design of
workplaces, the choice of work equipment and the choice of working and production
methods, with a view, in particular, to alleviating monotonous work and work at a
predetermined work-rate and to reducing their effect on health;
(e) adapting to technical progress;
(f) replacing the dangerous by the non-dangerous or the less dangerous;
(g) developing a coherent overall prevention policy which covers technology, organisation
of work, working conditions, social relationships and the influence of factors relating
to the working environment;
(h) giving collective protective measures priority over individual protective measures, and
(i) giving appropriate instructions to employees.
In this list, CRASs are primarily associated with (a), (b), (c), (e), and (g).
Require the Duty Holder/Operator to prepare a document setting out its safety and
environmental management system known as the Corporate Major Accident Prevention
Policy (MAPP), which 'establishes the overall aims and arrangements for controlling the risk
of a major accident and how those aims are to be achieved and those arrangements put into
effect by the officers of the duty holder'.
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For onshore hazardous plant the onshore COMAH Regulations 2015 require that businesses
'Take all necessary measures to prevent major accidents involving dangerous substances.
Limit the consequences to people and the environment of any major accidents which do
occur'. This is the onshore equivalent of the new offshore SCR15 2015 Regulations in that
it combines responsibilities for the prevention of major accident hazards and also the effects
on the environment.
Because both COMAH and SCR15 are supportive Regulations to HSWA they both operate to
the ALARP principle and are similar in many ways.
Regulation 8 of COMAH requires that 'Every operator of an upper tier establishment must
prepare a safety report for the purposes of –
(a) Demonstrating that a major accident prevention policy and a safety management
system for implementing it have been put into effect in accordance with the
information set out in Schedule 3.
(b) Demonstrating that the major accident hazards and possible major accident
scenarios in relation to the establishment have been identified and that the
necessary measures have been taken to prevent such accidents and to limit their
consequences for human health and the environment.
(c) Demonstrating that adequate safety and reliability have been taken into account
in the design, construction, operation and maintenance of any installation, storage
facility, equipment and infrastructure connected with the establishment's operation
which are linked to major accident hazards inside the establishment.
(d) Demonstrating that an internal emergency plan has been prepared in accordance
with regulation 12, which includes sufficient information to enable an external
emergency plan to be prepared.
(e) Providing sufficient information to the competent authority to enable decisions to be
made regarding the siting of new activities or developments around establishments.’
The COMAH Safety Report is equivalent to the Offshore Safety Case document.
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Require a Major Accident Prevention Document (MAPD) to be produced for each major
accident hazard pipeline. The MAPD is the pipeline equivalent of the Offshore Safety Case
document and the onshore Safety Report and is required to demonstrate that risks have been
evaluated and an adequate safety management plan is in place. This will include provisions
for corrosion management. The MAPD is documented evidence which describes how the
Operator has assessed the risks from Major Accidents Hazards and has an appropriate safety
management system to control those risks.
B.4.1 PUWER
1998 applies onshore and offshore and places duties on persons and companies who own,
operate or have control over work equipment to ensure they are suitable, safe for use and are
maintained. PUWER defines work equipment as any machinery, appliance, apparatus, tool or
installation for use at work. The term 'installation' does not refer to an offshore installation,
but to a piece of work equipment installed for use.
Apply to onshore and offshore hydrocarbon installations and their associated wells. Onshore
wells also have to comply with the Borehole Sites and Operations Regulations 1995. DCR
1995 require the installation and its associated wells to be designed, constructed and
maintained to ensure its integrity is ensured.
Apply to offshore installation and identify the goals for the preventive and protective measures
which are necessary for managing fire and explosion hazards, and for emergency response of
offshore installations. The Regulations require that persons are protected from the effects of
fire and explosion, and that there are provisions in place for evacuation, escape and rescue
from the installation.
Apply to onshore pressure systems and cover the safe design and use of pressure
systems. 'The aim of PSSR is to prevent serious injury from the hazard of stored energy
(pressure) as a result of the failure of a pressure system or one of its component parts'. A
significant feature of PSSR is a requirement to have a written scheme of examination (WSE)
certified or drawn up by a competent person (CP) setting out the nature and frequency of
examinations in accordance with the degree of risk.
Require a pipeline to be able to withstand the forces arising from its operation, the fluids
carried, and the external forces and chemical processes it may experience, so that persons
are protected from risk to their health or safety. Similar to other Regulations, PSR require
pipelines to be examined and maintained safely.
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After the Deepwater Horizon incident in the Gulf of Mexico in 2010, the European
Commission (EC) initiated a review of the safety of offshore oil and gas operations from
which was generated Offshore Directive in June 2013; 2013/30/EU32. The objective of the
Directive is to reduce as far as possible the occurrence of major accidents related to offshore
oil and gas operations and to limit their consequences. The Directive contains requirements
relating to licensing, environmental protection, emergency response and liability, in addition
to safety.
'The objective of this Directive is to reduce as far as possible the occurrence of major
accidents relating to offshore oil and gas operations and to limit their consequences,
thus increasing the protection of the marine environment and coastal economies against
pollution, establishing minimum conditions for safe offshore exploration and exploitation
of oil and gas and limiting possible disruptions to Union indigenous energy production,and
to improve the response mechanisms in case of an accident'.
The intentions of the Directive are to bring greater control of both the offshore safety
risks and the environment consequences of those risks. One of the consequences of this is
that the HSE and the Department of Business, Energy and Industrial Strategy (BEIS)/Offshore
Petroleum Regulator for Environment and Decommissioning (OPRED) have now established
the Offshore Safety Directive Regulator (OSDR).
Whilst the EU Directive is broadly based upon the UK's OSCR, there are some modifications
which the HSE has implemented in the Offshore Installations (Offshore Safety Directive)
(Safety Case etc.) Regulations 2015. DECC has also introduced new Regulations to implement
environmental and licensing requirements.
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for the purpose of identifying the measures he needs to take to comply with the requirements
and prohibitions imposed upon him by or under the relevant statutory provisions and by Part
II of the Fire Precautions (Workplace) Regulations 1997.
(2) Every self-employed person shall make a suitable and sufficient assessment of:
(a) the risks to his own health and safety to which he is exposed whilst he is at
work, and
(b) the risks to the health and safety of persons not in his employment arising
out of or in connection with the conduct by him of his undertaking.
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for the purpose of identifying the measures he needs to take to comply with the requirements
and prohibitions imposed upon him by or under the relevant statutory provisions.
(3) Any assessment such as is referred to in paragraph (1) or (2) shall be reviewed by the
employer or self-employed person who made it if:
(a) there is reason to suspect that it is no longer valid; or
(b) there has been a significant change in the matters to which it relates, and
where as a result of any such review changes to an assessment are required,
the employer or self-employed person concerned shall make them.
(4) An employer shall not employ a young person unless he has, in relation to risks to the
health and safety of young persons, made or reviewed an assessment in accordance
with paragraphs (1) and (5).
(5) In making or reviewing the assessment, an employer who employs or is to employ a
young person shall take particular account of:
(a) the inexperience, lack of awareness of risks and immaturity of young persons;
(b) the fitting-out and layout of the workplace and the workstation;
(c) the nature, degree and duration of exposure to physical, biological and
chemical agents;
(d) the form, range, and use of work equipment and the way in which it is
handled;
(e) the organisation of processes and activities;
(f) the extent of the health and safety training provided or to be provided to
young persons, and
(g) risks from agents, processes and work listed in the Annex to Council Directive
94/33/EC(1) on the protection of young people at work.
(6) Where the employer employs five or more employees, he shall record—
(a) the significant findings of the assessment, and
(b) any group of his employees identified by it as being especially at risk.
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(4) In this regulation 'suitable' means suitable in any respect which it is reasonably
foreseeable will affect the health or safety of any person.
Regulation 5: Maintenance
(1) Every employer shall ensure that work equipment is maintained in an efficient state,
in efficient working order and in good repair.
(2) Every employer shall ensure that where any machinery has a maintenance log, the
log is kept up to date.
Regulation 6: Inspection
(1) Every employer shall ensure that, where the safety of work equipment depends on
the installation conditions, it is inspected:
(a) after installation and before being put into service for the first time; or
(b) after assembly at a new site or in a new location,
to ensure that health and safety conditions are maintained and that any deterioration can be
detected and remedied in good time.
(3) Every employer shall ensure that the result of an inspection made under this regulation
is recorded and kept until the next inspection under this regulation is recorded.
(4) Every employer shall ensure that no work equipment—
(a) leaves his undertaking; or
(b) if obtained from the undertaking of another person, is used in his undertaking,
unless it is accompanied by physical evidence that the last inspection required
to be carried out under this regulation has been carried out.
(5) This regulation does not apply to—
(a) a power press to which regulations 32 to 35 apply;
(b) a guard or protection device for the tools of such power press;
(c) work equipment for lifting loads including persons;
(d) winding apparatus to which the Mines (Shafts and Winding) Regulations
1993(1) apply;
(e) work equipment required to be inspected by regulation 29 of the Construction
(Health, Safety and Welfare) Regulations 1996(2).
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(3) The risk assessment shall be reviewed by the employer regularly so as to keep it up
to date and particularly if:
(a) there is reason to suspect that the risk assessment is no longer valid; or
(b) there has been a significant change in the matters to which the risk
assessment relates including when the workplace, work processes, or
organisation of the work undergoes significant changes, extensions or
conversions;
and where, as a result of the review, changes to the risk assessment are required, those
changes shall be made.
(4) Where the employer employs five or more employees, the employer shall record
the significant findings of the risk assessment as soon as is practicable after that
assessment is made, including in particular:
(a) the measures which have been or will be taken by him pursuant to these
Regulations;
(b) sufficient information to show that the workplace and work processes are
designed, operated and maintained with due regard for safety and that,
in accordance with the Provision and Use of Work Equipment Regulations
1998(1), adequate arrangements have been made for the safe use of work
equipment, and
(c) where an explosive atmosphere may occur at the workplace and subject to
the transitional provisions in regulation 17(1) to (3), sufficient information to
show:
(i) those places which have been classified into zones pursuant to
regulation 7(1);
(ii) equipment which is required for, or helps to ensure, the safe
operation of equipment located in places classified as hazardous
pursuant to regulation 7(1);
(iii) that any verification of overall explosion safety required by regulation
7(4) has been carried out, and
(iv) the aim of any co-ordination required by regulation 11 and the
measures and procedures for implementing it.
(5) No new work activity involving a dangerous substance shall commence unless:
(a) an assessment has been made, and
(b) the measures required by these Regulations have been implemented.
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(4) The following measures are, in order of priority, those specified for the purposes of
paragraph (3)(a):
(a) the reduction of the quantity of dangerous substances to a minimum;
(b) the avoidance or minimising of the release of a dangerous substance;
(c) the control of the release of a dangerous substance at source;
(d) the prevention of the formation of an explosive atmosphere, including the
application of appropriate ventilation;
(e) ensuring that any release of a dangerous substance which may give rise
to risk is suitably collected, safely contained, removed to a safe place, or
otherwise rendered safe, as appropriate;
(f) the avoidance of:
(i) ignition sources including electrostatic discharges, and
(ii) adverse conditions which could cause dangerous substances to give
rise to harmful physical effects, and
(g) the segregation of incompatible dangerous substances.
(5) The following measures are those specified for the purposes of paragraph (3)(b):
(a) the reduction to a minimum of the number of employees exposed;
(b) the avoidance of the propagation of fires or explosions;
(c) the provision of explosion pressure relief arrangements;
(d) the provision of explosion suppression equipment;
(e) the provision of plant which is constructed so as to withstand the pressure
likely to be produced by an explosion, and
(f) the provision of suitable personal protective equipment.
(6) The employer shall arrange for the safe handling, storage and transport of dangerous
substances and waste containing dangerous substances.
(7) The employer shall ensure that any conditions necessary pursuant to these Regulations
for ensuring the elimination or reduction of risk are maintained.
(8) The employer shall, so far as is reasonably practicable, take the general safety
measures specified in Schedule 1, subject to those measures being consistent with
the risk assessment and appropriate to the nature of the activity or operation.
B.6.5 Offshore installations (offshore safety directive) (safety case) regs 2015
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of risks of a major accident that are a result of the operator's operations and for
continuously improving control of those risks so as to ensure a high level of protection
at all times.
(6) A duty holder must:
(a) implement the corporate major accident prevention policy throughout its
offshore oil and gas operations, and
(b) set up appropriate monitoring arrangements to assure effectiveness of the
policy.
(7) In this regulation and Schedule 1, 'officer of the duty holder' in relation to:
(a) a body corporate, other than a limited liability partnership, means a director
or secretary;
(b) a limited liability partnership, means a member;
(c) a partnership or a limited partnership, means a partner of that partnership or
limited partnership, and
(d) a body unincorporate (other than a partnership or limited partnership),
means a member of the body.
(8) In paragraph (7)(a) 'director' has the meaning given in section 250 of the Companies
Act 2006(1).
(9) In this regulation (but not this paragraph) a reference to a duty holder or operator
includes a reference to a well operator.
(10) Paragraph (2)(b) does not apply to a well operator.
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B.6.6 The offshore installations (Prevention of Fire, Explosion, and Emergency Response)
regulations (PFEER)
Regulation 5: Assessment
5.—(1) The duty holder shall perform, and thereafter repeat as often as may be appropriate
a process (in this regulation called 'an assessment') described in paragraph (2) in
relation to the installation.
(2) An assessment shall consist of:
(a) the identification of the various events which could give rise to:
(i) a major accident involving fire or explosion; or
(ii) the need (whether or not by reason of fire or explosion) for
evacuation, escape or rescue to avoid or minimise a major accident;
(b) the evaluation of the likelihood and consequences of such events;
(c) the establishment of appropriate standards of performance to be attained by
anything provided by measures for:
(i) ensuring effective evacuation, escape, recovery and rescue to avoid
or minimise a major accident, and
(ii) otherwise protecting persons from a major accident involving fire or
explosion, and
(d) the selection of appropriate measures.
(3) The duty holder shall:
(a) record the assessment (including each repetition of it);
(b) keep the record at an address in Great Britain, and
(c) notify the Executive of such address.
B.6.7 Offshore installations and wells (design and construction etc) regulations 1996
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Regulation 8: Materials
8. The operator shall ensure that no fluid is conveyed in a pipeline unless it is composed
of materials which are suitable.
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Regulation 6: Installation
6. The employer of a person who installs a pressure system at work shall ensure that
nothing about the way in which it is installed gives rise to danger or otherwise impairs
the operation of any protective device or inspection facility.
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(4) References in paragraphs (2) and (3) to the suitability of the scheme are references to
its suitability for the purposes of preventing danger from those parts of the pressure
system included in the scheme.
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(6) The user of an installed system and the owner of a mobile system which has been
examined under this regulation shall ensure that the system is not operated, and no
person shall supply such a mobile system for operation, after (in each case):
(a) the date specified under paragraph (5)(b), unless the repairs or modifications
specified under that paragraph have been completed, and the changes in
the established safe operating limits so specified have been made; or
(b) the date specified under paragraph (5)(c) (or, if that date has been postponed
under paragraph (7), the postponed date) unless a further examination has
been carried out under the scheme of examination.
(7) The date specified in a report under paragraph (5)(c) may be postponed to a later
date by agreement in writing between the competent person who made the report
and the user (in the case of an installed system) or owner (in the case of a mobile
system) if:
(a) such postponement does not give rise to danger;
(b) only one such postponement is made for any one examination, and
(c) such postponement is notified by the user or owner in writing to the enforcing
authority for the premises at which the pressure system is situated, before
the date specified in the report under paragraph (5)(c).
(8) Where the competent person referred to in paragraph (7) is the user (in the case of
an installed system) or owner (in the case of a mobile system) the reference in that
paragraph to an agreement in writing shall not apply, but there shall be included in
the notification under sub-paragraph (c) of that paragraph a declaration that the
postponement will not give rise to danger.
(9) The owner of a mobile system shall ensure that the date specified under paragraph
(5)(c) is legibly and durably marked on the mobile system and that the mark is clearly
visible.
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(4) Without prejudice to the generality of paragraph (3), every operator must in particular
provide such assistance as is necessary to the competent authority to enable it to:
(a) carry out inspections and investigations, and
(b) gather any necessary information, in connection with the performance of its
functions under these Regulations.
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(7) An operator must implement its major accident prevention policy by a safety
management system.
(8) A safety management system must:
(a) satisfy the requirements in paragraph 1 of Schedule 2, and
(b) address the matters specified in paragraph 2 of that Schedule.
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ANNEX C
AGEING AND LIFE EXTENSION
Management of ALE falls within the same category as Corrosion and Integrity Management,
with the significant difference that ALE should be more forward looking and requires Duty
Holders/Operators to anticipate future corrosion and degradation risks SFAIRP.
ALE management is not clearly addressed in UK law in that the law requires Duty
Holders/Operators to consider reasonably foreseeable risks, but does not define the time
frame. The law requires Duty Holders/Operators to undertake risk assessments to ensure risks
are ALARP, but similarly, the time frame is not defined.
Reasonable foreseeability may be described as that which a reasonable person would be able
to predict or anticipate what the harmful consequences of their actions or inactions will be.
For example:
−− A 6 inch schedule 80 carbon steel crude oil flowline has a measured corrosion rate
of 2 mm per year and a wall thickness of 11 mm. It is reasonably foreseeable that,
unless mitigating methods are put into place, perforation and hence a leak is likely to
occur within five and a half years, and that, because the pipe requires wall thickness
for structural integrity as well as pressure containment, failure will occur earlier.
−− A reservoir into which untreated seawater has been injected for a number of years
is likely to become contaminated with SRB (depending on the pressure, temperature
and salinity). It is therefore reasonably foreseeable that the SRB will generate hydrogen
sulfide (H2S) which, in turn, will cause the reservoir to sour, resulting in H2S being
produced and increasing the risk of SSCC of susceptible materials of construction.
Perhaps the nearest the legislation gets to identifying a time frame is in the Offshore Safety
Case Regulations, Regulation 13, wherein it states a duty holder shall thoroughly review a
current safety case within five years of:
−− the date on which the executive accepted that current safety case, and
−− the date of the previous review.
The key requirements for understanding and managing the corrosion related effects of ALE
of production and processing facilities are:
−− To engage with Reservoir Engineers to use future reservoir predictions to forecast
changes to the corrosion and degradation risk profile.
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−− To engage with Project, Production and Pipeline Engineers to forecast the corrosion
and degradation effects of new production streams from other fields onto a hub
platform.
−− To trend inspection data to forecast the CoNC and hence the retiral date of SCEs.
−− To improve safety by sharing knowledge with others also working in the field of CM.
−− Be aware of, and understand the correlations between, corrosion related degradation
mechanisms and frequency of failures and to undertake mitigating actions in a timely
manner.
−− The Duty Holder/Operator should have ultimate responsibility for corrosion and
degradation management even where the work is being performed by service
providers.
−− Ensure there are complete SCE lists so that the corrosion risk assessment study is
carried out on all relevant equipment.
−− Ensure all drawings; P&IDs, isometrics and PFDs, are up-to-date to ensure RBIs relate
to known SCEs.
−− Ensure that Original Equipment Manufactured (OEM) skids and their piping and
vessels are logged in the SCE list to ensure corrosion risk assessment and RBIs are
carried out on them.
−− Continue development of NDT techniques to allow accurate identification and
quantification of defects, especially occluded defects.
CRASs drive both the RBI programme and also the CM activities (chemical treatment,
corrosion monitoring, sampling, etc). The HSE's KP4 report indicated that CRASs and RBIs
were well developed in the North Sea. However, there was evidence to suggest that not all
SCEs were in the requisite databases, meaning they were not subject to CRAS or RBI and
hence at risk of undetected corrosion.
As an installation approaches its nominal design life it would be good practice to review the
CRASs and RBIs as soon as possible to ensure they remain fit-for-purpose for the new period
until the CoP. The time in advance of the installation's nominal design life for this review
should reflect the size and complexity of the asset.
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It is essential to trend and extrapolate inspection data so they can be used to forecast when
the CONC will be met.
To support and verify the extrapolation process, future possible failure and deterioration
risks should be considered. This process requires collaboration with Reservoir Engineers and
Project Engineers to understand what changes may occur in the future. This requirement
enhances the need for the corrosion engineering function to be a part of management of
change procedures and reviews.
Where a future change to the corrosion and degradation risk profile is determined, the
barriers to failure should be reviewed to ensure they remain suitable. Potential changes
could include introduction of new process fluids from other reservoirs and pipelines, reservoir
souring, and extension of the installation life beyond the original nominal design life. Where
the existing CM strategies are considered to be no longer effective following the changes,
new management strategies should be put into place as soon as reasonably practicable.
Figure C.1 shows the importance of data trending to forecast the future CoNC date so that
early CM programmes can be implemented to ensure the asset is fit-for-purpose to the
revised CoP date.
Piping Thickness vs Cessation of
Production
NWT
Ide
ali
sed
Need improved corrosion
Wall thickness (mm)
WT
tre management to achieve new
nd
los COP date
s
Need improved
corrosion management
to achieve nominal
design life
MAWT/ASME B31.3
MAWT/ASME B31.4
Operating Life/Years
If there is excessive expenditure in ensuring the asset remains in pristine condition to CoP
this leads to reduced economic viability and profitability. However, an asset which is in good
condition at the end of its operating life has the potential for redeployment of some of its
equipment, thereby providing some additional return on the initial investment.
If there is insufficient expenditure on ensuring the asset remains fit-for-purpose and safe to
operate, SFAIRP, it is much more likely to suffer corrosion and consequent loss of integrity. The
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
consequences of unplanned shutdowns and hydrocarbon leaks can lead to unsafe situations
and be costly when taking into account the lost production, repairs and clean-up operations.
For Floating Production and Storage Offload assets (FPSOs) the economic need to ensure
the installation and its plant are maintained to remain in good condition is more important
because the entire facility can be moved from one field to another.
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
ANNEX D
APPROACHES TO GOOD PRACTICE
D.1 INTRODUCTION
This section provides general guidance for the implementation of the management steps
described in the main section of the document and also examples of good practice in
implementing those steps.
The primary objective of CM is minimising the risk of harm to individuals and to the
environment arising from leaks and structural failures caused by corrosion. Taking action to
eliminate these risks and therefore the costs that arise both directly and indirectly from them
will also avoid concurrent loss of plant availability and the cost of repair. It will also avoid the
loss of reputation and investor confidence that can be damaging to a company's business
ambitions.
Loss of hydrocarbon containment or structural failure of oil and gas processing facilities due
to corrosion can result in severe consequences on:
−− safety;
−− the environment;
−− business interruption;
−− economic viability;
−− asset value, and
−− company reputation
Analysis of data on reported offshore hydrocarbon releases ranks corrosion as the second
most frequent initiating factor leading to a loss of containment, with failures of joints and
flanges the most frequent.
Predicting the rate of degradation of SCEs due to corrosion carries some uncertainties because
corrosion is inherently a stochastic process. The amount of uncertainty is reduced by having
effective CMSs in place which combine proactive and reactive measures. For example, the
use of corrosivity modelling algorithms can be used to forecast the likely rates of corrosion in
the system; the use of flow modelling software can be used to identify areas of high shear
stresses which are likely to increase intrinsic corrosion rates and diminish the effectiveness of
CIs.
CM activity therefore has a commercial pay-off as well as providing vital support to safety and
environmental objectives.
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SUITABLE MATERIALS OF CHEMICAL COATINGS &
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ce i f g i on io ity In pew ic cr
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
nt nt du pr
Co Co R e I m
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
D.3 PLAN
D.3.1 Policy
The CM policy provides a key element in the corporate asset integrity management plan, in
giving direction to systems of control and documentation that ensure that the integrity of
asset/installation components is maintained and that the safety of personnel is assured.
The aim of the policy is to ensure that the organisation and individuals involved with the
management of materials degradation deliver a sound and robust system to provide safe
operations.
D.3.2 Purpose
The CM policy provides a key element in the corporate asset Integrity Management Plan, in
giving direction to systems of control and documentation that ensure that the integrity of
field components is maintained and that the safety of personnel is assured.
The aim of the policy is to ensure that the organisation and individuals involved with the
management of materials degradation deliver a sound and robust system to provide safe
operations.
A basis for a common approach to setting the corrosion policy and the objectives for ensuring
integrity of a potentially hazardous system is outlined as follows.
A policy is permanent, carrying the authority of the most senior manager of the
asset/installation to which it applies. It is a directive which specifies the aims and objectives of
how major operational issues should be handled over the anticipated life cycle of an asset. It
forms the basis for the preparation of:
−− strategies;
−− organisation structures;
−− performance standards;
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−− procedures, and
−− other managerial processes.
The CM policy documents the principles for achieving its long term aims and objectives,
which are principally no leaks and no risks.
The CM policy will usually take its lead from the company policy to ensure high levels of
safety and environmental protection.
Below the CM policy will be a number of procedures which identify the methods by which
the policies are delivered. Figure D.2 shows the relationships between the Duty Holder/
Operator's Policy, Strategy and Procedures.
The CM strategy is a statement of the methods by which the overall policy is implemented.
Regulatory compliance
Strategies for
ensuring safety, Policy for ensuring
health and asset integrity
environmental
Procedures for
Strategies for
ensuring safety,
corrosion
health and
management
environmental
Corporate policies must have clear, high-level objectives for managing safety, health and the
environment which are in keeping with the regulatory regime in which the asset operates.
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Whilst the majority of Duty Holders/Operators incorporate their CMP within the asset's
integrity policy, some have separate and specific CMPs.
Examples of aims and objectives that may be included in a typical CMP could include one or
more of the following:
−− To be consistent with the requirements of the corporate safety requirements,
environmental considerations, regulatory requirements and the long-term business
objectives of the company.
−− To comply with the asset integrity management policy.
−− No leaks or emissions, or pursue reduction of emissions and, where reasonably
practicable, eliminate them.
−− To eliminate or minimise the effects of materials, deterioration on the safety, integrity
and availability of operated assets.
−− Minimum 20 % reduction of corrosion related failures year on year.
−− Trend inspection data to be forecasted to identify when the CoNC will occur.
−− All corrosion mitigation methods to be >95 % effective.
Some organisations further break down their policy statements into more specific
expectations or objectives for each major activity.
There are broadly four routes to establishing the policy, for which Duty Holder/Operators
may use:
−− Conduct all CM/asset integrity activities in-house using staff Specialists, who develop
the corrosion policy and strategy.
−− Appoint specialist consultants to set up the corrosion policy and corrosion strategy
for ratification by the operators.
−− Appoint a single specialist consultant to cover all activities.
−− Appoint different specialists (internal/external) for specific activities such as setting up
the system and procedures, operating the system and verifying/auditing the system.
The Policies and associated Strategies and Procedures form the basis for the management of
the asset to measure and audit the effectiveness of the CM organisation.
Duty holders/operators should develop KPIs to measure the extent to which the policy
objectives are met and enable timely corrective measures to be taken.
D.3.4 Planning
The details of a CMS depend on the installation's process design, the process fluids being
handled, and the operator's safety and integrity management policies.
The CMP should be considered a 'live' document which is subject to continuous review and
kept up-to-date as the asset ages and process streams change, to ensure the asset remains
safe and fit to operate. For assets which have been operating for a number of years the
practicability of CM options depends on the effectiveness of the maintenance regime and
the economics of the asset to CoP.
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The CMPs and strategies may differ significantly between new build facilities and existing/
ageing assets. Preparing the CMS at the project design stage enables current good practices
to be implemented which will have a positive influence on the asset life. Options for existing
facilities will be constrained by features of the original design, such as the choice of materials.
Highly corrosive environments may need CRAs, or for where carbon steels (CSs) are specified,
the deployment of highly efficient CIs with high availability.
For an asset where the produced fluids are sour, or have become sour during the field
life, the materials of containment must either be specified to NACE MR 0175 (ISO 15156)
requirements, or have properties which are demonstrably equivalent.
Both the materials selection strategy and CM strategy should ensure that, as a minimum,
the nominal design life is achieved with minimal unnecessary maintenance which would be
associated with premature degradation. From the experience of ageing structures and assets
in the North Sea it is recommended that at least an additional five years is added to the
nominal design life to provide a cushion for decommissioning.
Due to the vagaries of the oil and gas market it is extremely difficult to forecast what
additional life should be added to the nominal design life to account for the potential for
life extension due to enhanced oil recovery or increased oil prices. The potential for life
extension of the asset should be considered regularly, and the integrity data associated with
the asset should be regularly trended to determine when the CONC will occur to ensure that
the CONC date exceeds the cessation of production date. Where data trending indicates
the CONC date will occur before the CoP date early action should be to taken rectify the
potential risks.
The asset development plan, and hence the corrosion management plan, should identify
the SCEs that are built into the asset's design and also the performance limits on which they
are based, so that corrective actions can be made in a timely manner to operate within the
design limits.
Where corrosion modelling indicates potentially high degradation rates, designers should
perform life cycle costings to determine the options of investing in the relatively high capital
costs of CRAs and their lower maintenance and inspection costs, against the lower capital
costs of CS but with the likelihood of higher inspection, maintenance and CI costs.
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Inherent safety requires a barrier to corrosion that is permanent and requires no further
supporting activity. However, in some cases the introduction of an inherently safe barrier to
one threat may introduce another threat; an example is described in D.3.5.4.
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Option 1 requires (i) additional capital finance to install duplex stainless steel pipe, (ii) a subsea
temperature monitoring and alarm system, (iii) subsea CP monitoring and alarm system.
Option 2 requires an operational CMP to monitor CI injection and injection rate and to
implement scheduled inspection and pigging. This will incur additional costs for:
−− CI;
−− pigging;
−− periodic intelligent pig inspection;
−− pigging facilities;
−− on-line corrosion monitoring, and
−− non-destructive inspection.
One major factor that will impact on the CMS is the planned asset life. The CMS should be
based on the long-term corporate strategies and objectives for the asset/installation, and
therefore the corrosion risks need to be appraised against these objectives when planning
and implementing the corrosion control activities to meet the required asset life.
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A platform has been in operation for over four years and has a fixed CoP date based on the
known recoverable reserves. During the period leading up to the expected abandonment
limited inspection and maintenance were carried out – consistent with the requirements
based on the planned abandonment date.
About a year before the platform is due to be abandoned the decision is taken to bring on
a new marginal field using extended reach drilling. This, together with other changes in the
production process, means the platform has a new economically viable life extension of an
additional six years.
However, the financial benefits of the extended asset life may be reduced due to the
additional costs of maintenance/repair/replacement of components that, because of the
previous operating regime, may be unviable for the remaining life.
If the options for the future of the asset had been made known to the relevant teams
at an early stage, a different operating and maintenance regime would likely have been
incorporated leading up to the introduction of the new field, with potential savings in the
overall operational cost over the remaining life.
With advancing technology, asset life expectancy is frequently extended beyond the original
nominal design life. It is therefore important when extending field life beyond design limits to
be able to accurately understand the remaining integrity of SECEs and also the effectiveness
of the CMSs.
Life extension is likely to require reappraisal of corrosion risks and the introduction of changes
to the CMS.
The CMS should match with the forecast asset life, and because of this the future business
and operational requirements for an asset should, where practicable, be made known to
those responsible for setting and implementing the CMS. For example:
Example 2: Strategy for internal protection of new and existing separator vessels
Because of the combination of volume and pressure, some of the most safety critical
components in offshore oil and gas production are the vessels used to separate gas, oil and
water. In many cases the corrosion conditions are such that CSs alone may not be sufficient
to ensure adequate operational life.
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Various options are available to provide an acceptable life, which include application of
internal coatings and linings, usually combined with internal CP, or using CRAs as a weld
overlay or liner. The selection of the most appropriate technique will be dependent on
whether the corrosion problem is identified before fabrication or in service. In the latter
case, internal CP can be used successfully to provide the necessary corrosion control for
carbon steel vessels.
D.5 DO
In order to fulfil the requirements to ensure that risks are identified in a timely manner and
that preventative measures are put into place the Corrosion Risk Assessment Study should be
prepared before the production facility is commissioned.
Duty Holders/Operators should have in place policies and strategies for managing those
hazards and risks which may adversely affect safety, health and the environment.
D.5.2 Organisation
To ensure the installation and its plant are safe from corrosion related degradation, SFAIRP,
the operator should engage competent specialist advice. It is preferred that the operator has
at least one competent Corrosion and/or Integrity Engineer from their own organisation in-
house, but where this is not feasible for cost or availability reasons they should use competent
specialist consultants and contractors to act on their behalf.
The outcome of the CRAS will be to develop a corrosion management system which will
ensure the corrosion related threats are identified and that the consequential risks are
managed to be ALARP.
D.6 CHECK
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CM is also concerned with safeguarding the facilities and the avoidance of business
interruption, therefore the policies should also address these issues, as not all corrosion
related failures will also have an impact on safety or the environment.
D.7 ACT
The CMS should be regularly reviewed at a frequency in keeping with the rate of the risks
changing and also when there is a significant change such as:
−− significant changes in process fluids such as water cut, H2S, scaling tendency;
−− a new source of hydrocarbons coming onto the installation;
−− change of ownership;
−− approaching nominal design life;
−− life extension, and
−− when considering CoP.
Although there are examples of gas production facilities where the process conditions have
not changed for many years, thereby not requiring substantive changes to the CRAS, it is still
necessary to perform a formal review and log the findings to demonstrate that this remains
the case. This formalises the process and the findings and provides evidence the process has
been completed in a suitable and sufficient manner. There have been instances of offshore
gas producing installations with many years of benign production suffering corrosion under
insulation (CUI) which has become the primary safety risk.
Learning lessons and taking action to eliminate corrosion threats provides benefits of
promoting safer operation and avoiding:
−− environmental damage;
−− direct and indirect costs;
−− loss of plant availability;
−− repair costs, and
−− loss of reputation.
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ANNEX E
ORGANISATION
E.1 INTRODUCTION
This section provides a framework for, and examples of how, a corrosion strategy helps in the
allocation of roles and responsibilities both within the Duty Holder/Operator's organisation
and consultant/contractor/sub-contractor organisations.
The effectiveness of any policy depends on the leadership, commitment and involvement of
managers and senior staff. Safety and environmental protection are of concern to everyone:
employer, employee and contractor. Cost containment is a common focus. Corrosion should
also be of similar concern. A positive safety, health and environment culture and a 'corrosion
culture' results in fewer threats to individuals and less damage to the integrity of a facility.
E.2 PLAN
E.2.1 Policy
The approach to organisation is related to the Company Integrity policy and Strategy with the
aim of keeping threats ALARP.
E.2.2 Planning
The following key roles should be addressed. Note that these are role titles. Companies’ CM
strategies may use different post titles for these roles and may combine two or more of these
roles into one post. They may also allocate other roles to similar post titles.
−− The Operations Manager often has overall responsibility for the integrity of the
installation, and as such, must ensure that suitable effective arrangements are put in
place to manage corrosion and undertake monitoring and inspection. The role has
responsibility for:
– resourcing operational activities and leading operations management;
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Personnel should always be aware of their own competencies and should not engage in
making decisions and judgements in areas where they do not have adequate knowledge.
Management must always look to engage suitably competent personnel.
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The key competence requirements for the following key roles should be addressed:
−− Technical Authority:
– Comprehensive knowledge of CM standards and practices and their application
within the organisation. Appropriate professional qualification, education, and
training.
−− Integrity team leader/manager:
– has knowledge and understanding of the roles, responsibilities and CM structure
operated by the organisation;
– is experienced in successful review of processes and procedures;
– has experience of CRA and CMTs used offshore, and has the ability to apply
them;
– has knowledge of inspection methods, their application and limitations, and
– has appropriate professional qualification, education, and training.
−− Corrosion/materials engineer:
– familiarity with relevant standards and specifications;
– has knowledge of materials selection;
– can identify, justify and apply measures required to minimise risks from corrosion;
– has experience of corrosion risk assessments, and
– appropriate professional qualifications, education, and training.
Most operators contract out at least part of their corrosion management activity and there
are many different scopes defined and contractual relationships agreed. Examples that have
been implemented include:
−− Full corrosion and inspection management services with the operator having just a
small number of Integrity Engineers to provide the customer interface and in-house
corrosion consultants to provide specialist support.
−− Integrated corrosion and inspection management team under the management
control of the client.
−− Chemical treatment programme management covering the use of both the supplier's
and competitor's chemicals and including specialist advice and provision of database
facilities.
All four of the key themes have relevance to the success of the operator/contractor relationship
in producing an effective CM outcome.
With respect to roles, responsibility and accountability, it is important that the respective
roles, responsibilities and authorities of the operator and contractor are defined. Where both
parties have a management system in place, the agreement should define which is to be used
and whether, for instance, documentation is issued in operator or contractor format and
whose databases and record systems are to be used.
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E.3 DO
A risk assessment will be performed for the activities performed by each role as required by
the Company Health, Safety and Environment Policy, which will be supported by the Integrity
Policy.
E.3.2 Organisation
A CMS helps to define and allocate the roles and responsibilities both within the Duty Holder/
Operator's organisation and contractor/sub-contractor organisations.
The mandatory and preferred qualifications and experience should be clearly specified in job
descriptions so that the accountability and scope of responsibility of each team member are
unambiguous.
Ideally, organograms should show lines of accountability and cooperation associated with
any contract posts.
Design
information
Integrity Operations
manager information
Maintenance
information
Inspection
information On-line Fluid Process
monitoring sampling monitoring
information information information
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Engineering
manager
Analyse inspection
results CTA
Inspection Inspection
work packs reports Investigations RBI
Inspection engineer
Corrosion Health
monitoring Corrosion engineer reports
Supervise Do NDT
NDT
Corrosion inhibition Corrosion
Integrity manager management
performance
Microbiology
113
Scale management
management Documentation
Corrosion inhibition Initial audits
Scale
management
management
Demulsif ier
Production chemistry
management Raise paper work
Integrity engineer orders
Chemical
usage Approve
Asphaltene work packs
management Chemical Review Corrosion &
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effetiveness Manage inspection Inspection reports
contract
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The purpose of implementing the plan is to ensure risks are ALARP and that it is undertaken
in a cost-effective manner.
The roles and responsibilities of the corrosion team members in the planning and
implementation of CM activities should be clearly defined. The following aspects should be
considered:
−− the operational responsibility for implementation;
−− the functional responsibility and technical authority for specification, analysis and
recommendation, and
−− the responsibility and authority that is to be exercised by contracted bodies.
In different organisations different post holders will carry out similar roles. The important
thing is to ensure that all responsibilities are unambiguously allocated.
A TA for corrosion should be identified and the strategy that is adopted should describe
the links between the parties involved with the CM. This is particularly important where
relationships between the Owner, Contractor, Specialist Subcontractors and Consultants
exist.
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A good example for determining the level of competence required for a particular activity,
as well as the degree of competence provided by individuals, has been developed by the
HSE, Institution of Engineering Technology and the British Computer Society which may be
adapted for use in the offshore oil and gas industry to apply to CM issues.
The competence system should retain records of assessment and supporting documents,
accessible for the purposes of audit and/or review.
The availability of standards for the competence of personnel in the roles across the CM
structure is also important. There is considerable variation in availability and formality:
The TA and the Integrity Team Leader should have appropriate professional standing through
education and experience, as discussed. Professional qualifications should be in an appropriate
discipline, preferably at the UK Chartered Engineer level[4] as well as in the corrosion discipline,
if this level is not available. A minimum of five years' experience is normally required to
achieve the necessary level of competence; however, the experience must be appropriate to
the area of TA.
In Europe, there are no institutions offering degree level academic qualifications in corrosion
technology. It is therefore appropriate to develop competence through:
−− a relevant first degree;
−− education in general corrosion science and technology at a post graduate level, and
−− experience in oil and gas corrosion technology.
It is possible to gain knowledge of general corrosion science and technology over a period of
time through work experience and/or in association with MSc and PhD degrees by research
and thesis. Training courses extending from a few days to two weeks are available from a
number of sources that cover a basic introduction to corrosion science and engineering and
can, therefore, provide an entrance to the subject. Classroom-based training can be acquired
using university courses on a modular basis where available.
Experience in oil and gas corrosion technology is normally gained through work experience.
Some of the specialist short courses on offer provide an introduction to oil and gas corrosion.
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Where general and oil and gas corrosion knowledge is obtained through experience, rather
than through formal postgraduate study, competence needs to be assessed in a structured
manner, normally by a corrosion TA. It is estimated that two years structured experience is
required to gain adequate general corrosion knowledge plus a further two years for oil and
gas corrosion knowledge. However, these timescales are only indicative and it should be
confirmed that fully appropriate competence has been attained though assessment.
Where qualifications are held and experience has been gained then the relevancy of the
specific corrosion knowledge has to be taken into consideration e.g. an authority in internal
corrosion, may not necessarily be competent in some aspects of CP of subsea facilities.
Professional qualifications for corrosion specialists are provided in the UK by the Institute
of Corrosion[6], in their Professional Member grades (MICorr or FICorr). Whilst these
demonstrate the possession of a level of knowledge in corrosion technology they do not
guarantee that the holder possesses a broad general understanding of corrosion or oil- and
gas-specific knowledge.
The HSE in its guidance for the Pressure System Safety Regulations[7], and the United
Kingdom Accreditation Service[8] both give requirements for the qualification and experience
of inspection engineers engaged in developing inspection schemes for pressure systems,
conducting inspections and interpreting the results. These are expanded upon by EEMUA[9]
in their guidance document. Generally they can be taken as the minimum for inspection
engineering personnel working within the oil and gas production industry.
The requirements for NDT vocational technician qualifications are well developed in some
areas and are well described by various national and international standards and codes of
practice, for ASNT[10], CSWIP[11], PCN[12] qualifications. However these NDT qualifications
together with their associated training and tests have all been developed for application to
fabrication. Therefore, not all practitioners are competent to apply their skills to the detection
and quantification of in-service corrosion defects. Therefore, technician competence should
be verified by tests and/or a review of work in the in-service context.
Some roles do not require specific corrosion and inspection related skill, for instance the
operations team members and supervisors who are responsible for chemical injection, gas
drying operation, etc. Similarly nor do some managers who are accountable for some of
the specialist activity but do not undertake it themselves. In these instances a corrosion
awareness programme can be used to provide staff with background knowledge and foster
an understanding of the criticality of their roles to CM. Also short courses on specialist topics
and oil and gas corrosion can be used. It is important, however, in both cases that the
content is targeted to provide the right messages.
In addition to the need for personnel to have technical skills appropriate to their role, and
knowledge and understanding of the area for which they are responsible, it is necessary that
they possess appropriate behavioural skills relating to, for example, appropriate attention to
detail, interpersonal skills and problem solving abilities.
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Competence has relevance to both the contractor's organisation and the contractor's
personnel.
The requirements for contractor's staff are the same as for operator's staff and the operator
should ensure that the contractor either has a sound competence assurance system or they
should assess the competence of contractor's staff themselves.
The impact of the contract terms on the contractor's team competence should be carefully
considered. The ability to employ personnel at a given level of competence may be influenced
significantly by the remuneration on offer. In a contract situation this in turn will depend
on the rates in the contract and the margin that the contractor is seeking to obtain. In one
example, the operator would agree the remuneration of personnel with the contractor and
provide an agreed margin for burdens and profit and thus have control over these factors.
Communication may require particular effort especially if the operator and contractor are
physically separated in different offices. A decision has to be made whether to co-locate
the contractor's and operator's personnel and if not, how to overcome communication
issues. Many operators have benefited from hosting contractor personnel in the office-based
management team where they can directly interact and share access to intranet, file server
and database resources. In other cases it has been possible to use remote access methods to
share these resources and also use video links and conference call techniques to engage the
contractor.
Whatever the methods involved, it is important that the contractor's personnel can perform
effectively in their roles. In particular, appropriate contractor personnel must be part of the
corrosion management team.
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E.4 CHECK
The purpose of measuring performance is to ensure the work is being carried out in
accordance with the plan and in an efficient manner and to identify any gaps present in the
organisational structure.
Once the necessary skills, expertise and experience for each role have been defined, the
development of individual training plans and ongoing assessment of personnel are essential.
This ensures that the competence of individuals is appropriate for their current role. It also
enables the requirements for further training to be identified, not just for the current role
but also for personal development into future roles and for professional and technical
development.
The CMT is a key concept for the development of cooperation. In an operation of any
size many parts of the organisation will play an important part in CM. For that reason it is
appropriate to form a CMT to mutually own the corrosion management process and foster
cooperation in making it work effectively. The CMT will meet routinely, usually with the
responsible Integrity Manager in the chair and the Corrosion Engineer providing the technical
and administrative support. The rest of the team may include:
−− a production representative, to provide information on well performance and well
operations;
−− an operations or maintenance representative, to provide information on plant
operation and performance issues;
−− an inspection representative, to provide a summary of inspection results and
information on anomalies;
−− the chemical treatment specialist, to provide information on the treatment
programme, and
−− Subsea and pipeline engineers, to provide information on subsea inspection results
and anomalies.
Some of these players may be operator's staff and some may be from service contractors or
specialist suppliers.
A team may be set up for one asset or field or alternatively for a group of assets. It depends
largely on how the individual assets and asset groups are supported organisationally, internally
and by service contractors and suppliers. In organisations that have central or group level
support for corrosion, the central/group specialist can be represented on the local team to
bring in wider knowledge and learning from other assets and areas.
In achieving cooperation, regard should be given to aligning the aims of the contractor and
the operator. Most contractors will find it in their interest to share the operator's aims with
regard to safety and mechanical integrity, as one successful contract in this respect will help
secure others. It is this win-win outcome that facilitates effective cooperation.
Relationships that are key for cooperation should be shown on the organogram.
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Investigation of failures in the organisational structure can generate information that may
reduce the likelihood of recurrence.
A real example of what can go wrong with process modifications occurred on an ageing
production system where, due to increasing water cut, it was decided to change the system
from a three-phase separator (i.e. oil, water and gas) to a two-phase separator (i.e. oil-water
emulsion and gas) process. Consequently, the oil-water emulsion passed through pipework
that had been originally manufactured in carbon steel, on the basis that essentially only dry
oil would be present.
The change in process had been made without reference to corrosion/materials engineers
and without reference to the original design assumptions used in the material selection.
Significant corrosion was subsequently found in the pipework downstream of the separators
and upstream of the CI injection point.
The solution adopted was to move the inhibitor injection point to immediately downstream
of the separators and to increase the inhibitor dosage significantly.
In addition to others being aware of the need to involve the corrosion specialists, the
Corrosion and Integrity role holders must also know how the operator's change management
process works and must be able to use it effectively when proposing improvement changes
in corrosion mitigation.
E.5 ACT
It is important to learn from past experience to improve CM and safety performance. Experience
and knowledge gained should be incorporated into future organisational structures.
The CMT (see E.4.1) is a key vehicle for communication between the key players. All
appropriate team members should be involved in sharing of information from analysis of
corrosion incidents:
−− root cause analysis;
−− process metallurgical reviews, and
−− implications for other areas on the plant.
Communication within the operator's organisation as a whole, and with its relevant
contractors, is also highly important to achieve understanding and obtain support in meeting
objectives. CM depends not only on those that have direct responsibility for CM activities
but also other engineering and operations personnel, on procurement, finance and human
resource functions and on management at large. An ongoing corrosion awareness initiative
can be used by the technical specialists and the CMT to communicate with the organisation
as a whole.
Corrosion Awareness training programmes, aimed at the non-specialist, have been found to
improve overall levels of CM performance. An inspection technician, maintenance operator
or process chemist, who has a better understanding of corrosion and material degradation,
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including how it manifests itself, what causes it and the different options for control, ensures
that:
−− Signs of corrosion/damage are recognised at an early stage – allowing remedial
measures to be put in place before damage requires major work.
−− The reasons for the detailed requirements for inspection and monitoring are better
understood – improving efficiency and cooperation.
−− The effects of corrosion control measures are better understood – again improving
efficiency and cooperation.
The workforce should also be involved. The workforce are the eyes and ears around the
installation. Their involvement is important particularly for external corrosion. There are many
ways to communicate to the workforce:
−− safety meetings;
−− poster campaigns, notice boards and leaflets, and
−− videos, newsletters and presentations.
Corrosion awareness training for the workforce should concentrate on the recognition of
corrosion problems and guidance on significance. There should also be guidance on the
effective reporting of problems.
Lessons should be learned from experience with regard to organisation. Any failures related
to the organisation structure or any gaps identified should be addressed accordingly.
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
ANNEX F
CORROSION RISK ASSESSMENT AND PLANNING
F.1 INTRODUCTION
Identification of hazards, the assessment of threats and agreement on the planned activities
to mitigate those threats and monitor for effective implementation are a fundamental
requirement of the management process. CMPs must relate to the policy and any strategy
already determined.
Planning and implementation are the largest single part of any CMP. Planning is the basis
of an ordered and purposeful CM programme and CRA is used to identify and prioritise the
elements of the plan.
F.2 PLAN
F.2.1 Policy
Planning and implementation are the largest single part of any CM process.
Planning is the foundation of an ordered and purposeful CM programme and corrosion risk
assessment is used to identify and prioritise the elements of the plan.
Identification of hazards, the assessment of threats and agreement on the planned activities
to mitigate those threats and monitor for effective implementation are a fundamental
requirement of the management process. Plans must relate to the policy and any strategy
already determined.
Planning and implementation often make use of company guidelines, industry codes and
international standards. Checks are needed to determine whether they are appropriate and
effective for each particular asset.
The ownership of actions and responsibilities relating to the CMP are vital to successful
operation. As part of this process the operator should keep appropriate records of planning
and implementation to allow full transparency of the process.
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Similarly, the plan for a UK onshore terminal should be aligned to relevant provisions of its
COMAH MAPP and Safety Report, and plans for UK pipelines should align to the Major
Accident Prevention document required by the Pipeline Safety Regulations.
Planning and Implementation constantly and rapidly influence each other through the
internal flow of information. This constant 'self-regulation' works within the overall framework.
F.2.2 Planning
Planning should commence with a formal process to identify the components on a facility
that have a threat of degradation due to corrosion. The most common approach to this is to
conduct a corrosion risk assessment.
If a corrosion threat cannot be removed (usually achieved by a design change), then it has to
be mitigated by a barrier. Mitigation is achieved through the use of:
−− materials of construction changes;
−− coatings;
−− CP, and
−− chemical inhibition.
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performance limit, the monitoring method and frequency and the immediate action
procedure following nonconformity.
Performance limits should define acceptance/rejection criteria for the system or
component. The standard should be sufficiently quantitative such that it can be
measured consistently.
In practice, elements of the plan will have been determined during the design phase
and the plan should derive from the materials and corrosion strategies developed as
the basis for design.
The strategic plan may be part of a larger plan that considers other types of integrity
threat. In the UK, offshore operations must be aligned with the verification scheme;
onshore, to the COMAH safety plan and, for pipelines, to the major accident
prevention document.
Often a QRA or a safety assessment is developed and used as a basis for design,
or for integrity assurance in operation. In such cases the strategic plan should be
aligned not only to the threats identified in the QRA or safety assessment, but also
to assumptions regarding barriers/mitigation that have been used as the basis for
the QRA or safety assessment. This should be done at the design stage initially, but
because both documents may be revised due to changes in operation, the alignment
of the two should be maintained.
−− Tactical planning and scheduling is the second part of the process of detailed and
specific monitoring and inspection activities and events. For example, one item of
the strategic plan may require all pipework and vessel metal loss not to exceed the
design corrosion allowance. RBI planning will then assess the individual vessels and
pipework corrosion loops/circuits to determine the required inspection interval for
each circuit.
Offshore verification activities and planned inspection should be scheduled together
where joint witnessing is required.
Work planning requires the scheduling and integrating of the mitigation, inspection and
monitoring activities within the overall asset strategy, and identifying the preferred deployment
of mitigation inspection and monitoring resources and technology.
Planned and scheduled activities are best triggered as part of the organisation's normal work
management processes. For instance:
−− Process plant inspection activities, CP monitoring activities and monitoring equipment
servicing often reside as routines and events in planned maintenance databases.
−− Instrument output such as temperatures and gas dew point, are programmed into
the Digital Control System (DCS).
−− Manually managed inhibitor injection is included in operation instructions.
As a result, CM is not a standalone process and the scheduling of activities is integrated with
the operations and maintenance plans for any particular facility.
Work planning leads on to the development of work scopes and work packs for campaign
activities in the implementation process.
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The work plans identify or imply both the personnel and physical resources needed for
implementation.
Elements of the plan determined during the design phase should lead to the design and
construction of physical resources, e.g. inhibitor injection, gas drying and measurement
instrumentation.
Resources needed to execute the plan in the operational phase must be put in place and
include:
−− The operator's organisation and personnel. This will need to be integrated with the
resources needed by plans for technical support to other assets and plans for other
operational and maintenance activities.
−− Contracts for support personnel and specialist services, e.g. inspection, CP survey,
fabric maintenance, scaffolding, cleaning, etc.
−− Equipment and spares needed for the operator's own servicing activities.
Suitable planning processes need to be in place to manage the supply of personnel and
equipment to meet demands. Where inspection tasks require shutdown, or work at height
or over the side and subsea, offshore, long-term planning and commitment are essential
to secure the required resource so that inspection and fabric maintenance activities are not
delayed. Plans in the oil and gas industry can change with little notice, e.g. an unplanned
shutdown may bring forward the opportunity to carry out an inspection. Planning must
include a process to accommodate this.
The RBI methodology takes the criticality ranking (i.e. the risk of corrosion) and a grade,
which is a rating of confidence in the knowledge of the equipment item condition and of
the corrosion process, and combines them to produce an inspection interval. The interval is
therefore restricted if little is known so it increases the assurance that inspection is carried out
before deterioration is excessive.
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F.3 DO
A CRAS is a formal review that identifies the probability of a corrosion-related failure and its
consequences relating to the loss of containment and the consequential hazards should a
failure occur (see Figure F.1).
The purpose of the corrosion risk assessment is to rank the static equipment in relation to its
corrosion threats and make it possible to identify options to remove, mitigate or manage the
threats. It is a necessary precursor to strategic planning.
In the operational phase of the asset life cycle, the primary intent of the corrosion risk
assessment is to guide the inspection and corrosion monitoring activities in order to track
planned or known deterioration and to detect and measure unplanned corrosion problems.
The corrosion risk assessment is also used as the initial step for RBI systems.
Corrosion risk is normally expressed as the product of the probability of corrosion related
failure and the consequences of such a failure, where:
−− Probability of failure is estimated based upon the types of corrosion damage expected
to occur on a component.
−− Consequence of failure is measured against the impact of such a failure evaluated
against a number of criteria, which as a minimum would include safety, environmental
and operational impacts, resulting from a loss of containment.
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RISK
To the Environment
Repair Costs
Loss of Production
Shutdown Time
To Company Reputation
Mobilisation Costs
OPERATIONS
HAZARDS
To People
el
nn o
rs
Pe
l
ne
n-
n
No
o
rs
Pe
pH2S
re
tu
ra
pe
Process Conditions
m
Te
Environmental Conditions
t
s er
De
ine
ar
M
il
So
Material of Construction
Material of Construction
INTERNAL
THREATS
Consequence
Probability
X
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In each case the process facilities should be assessed for risks on the basis of:
−− internal corrosion threat;
−− external corrosion threat;
−− safety/hazard consequence;
−− environmental consequence, and
−− operability consequence.
Ideally the corrosion risk assessment identifies the corrosion/degradation threats to each
item of process equipment, assesses the remaining life, and feeds the information back into
the overall risk assessment and control system. The CRAS may also be used to assign priorities
for corrosion monitoring and CM procedures, including input into RBI planning.
As part of any CRAS, the sensitivity of the predicted corrosion rate to changes in the different
parameters (e.g. CO2, H2S, temperature, pressure, flow rate, water cut, etc.) should be
assessed. This will allow identification of the more critical parameters, where changes (in
some cases even small changes) over the facility’s operational life may be required.
Increasingly, Monte Carlo analysis methods are being applied to the predicted conditions, to
identify the likely range and distribution of corrosion over the range of operating conditions.
This allows a more reasonable approach to assessing risk, rather than relying on worst-case
scenarios.
F.3.2 Organisation
The Duty Holder responsible should ensure that the information inputs are correct but will
also improve the operation's buy-in to the risk assessment and also the RBI programme that
will normally follow from it.
In relation to the facility, the CRAS requires the input of current knowledge of:
−− operating parameters;
−− operating mode;
−− current design and original design;
−− history of failure;
−− metal loss, and
−− a current understanding of consequences of failure.
Up-to-date design and operating information, and inspection and monitoring history will be
required to conduct the corrosion risk assessment.
The Corrosion Engineer will normally collate and conduct an initial assessment of the data
and generate the corrosion rate predictions. The corrosion threat ranking and consideration
of the consequences of failure should involve a team consisting of, as a minimum:
−− the Corrosion Engineer;
−− an Inspection Engineer, with knowledge of inspection history, and
−− operations representative(s) with knowledge of current facility operation and
consequences of failure.
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The purpose of implementing the plan is to ensure risks are ALARP and that it is undertaken
in a cost-effective manner. The CMS document should describe the particular policies,
strategies, organisation, plans, implementation processes, review and audit which are to be
adopted for the facility's operation.
The detailed techniques and procedures to be used and followed during the implementation
phase should be clearly identified and developed. Written procedures are required for all
aspects of implementation of the CMPs in order to ensure consistency in the data collection,
definition of CONC and specification of clear lines of authority and reporting.
Procedure Notes
Preparation of a Specifying and implementing cleaning, access, etc. techniques
pressure system for to be used to identify the extent of the corrosion risk
inspection
Vessels, tanks and Specifying and implementing cleaning, access, etc. techniques
heat exchanger to be used to identify the extent of the corrosion risk
inspection
Pipework inspection Specifying and implementing cleaning, access, etc. techniques
to be used to identify the extent of the corrosion risk
Pipework corrosion Specifying and implementing cleaning, access, etc. techniques
monitoring surveys to be used to identify the extent of the corrosion risk
Topsides deck, riser Specifying and implementing cleaning, access, etc. techniques
and caisson inspection to be used to identify the extent of the corrosion risk
Underwater structural Specifying and implementing cleaning, access, etc. techniques
inspection to be used to identify the extent of the corrosion risk
Fabric maintenance Survey of coating condition
survey
Corrosion under Specifying and implementing cleaning, access, etc. techniques
insulation assessments to be used to identify the extent of the corrosion risk
Erosion monitoring Specifying and implementing cleaning, access, etc. techniques
to be used to identify the extent of the corrosion risk
Corrosion monitoring Removing and processing coupons, replacing probes,
servicing downloading data from local storage, etc.
Collection and Checking injection rates, tank levels
interpretation of
chemical analysis data
Cathodic protection Measuring potentials, on-off potentials
surveys
Inspection reporting Recording and reporting findings
Urgent reporting of Reporting of anomalies requiring immediate action
non-conforming plant
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Procedure Notes
Corrosion and Severity, frequency, time to repair
materials damage
reporting
Identification and Checking injection rates, tank levels
implementation of
corrosion inhibition
Root cause analysis of Process for preserving failed items and to undertake the
corrosion failures investigation
Annual corrosion Team required to undertake the review
status review and
follow-up
Records Organising paper records
administration
Corrosion monitoring Use of databases
databases
F.4 CHECK
The corrosion risk assessment model should be maintained as a live database throughout the
asset life, requiring regular review of the data utilised and the assumptions used.
The results of the corrosion monitoring and inspection activities should be fed back into the
corrosion risk assessment model to validate its assumptions, or modify them accordingly.
A review during a period of changing conditions will ensure the risk ranking remains valid. A
review during a period of stable conditions will allow refinement of the model's assumptions
and can be used to justify a reduction in conservatism and reduce the risk rating of items.
The results of an investigation of in-service failures can be used in the corrosion risk assessment
to help reduce the likelihood of recurrence.
F.5 ACT
For non-stable process conditions detailed reassessment would normally be required at least
annually.
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For stable process conditions, with good historical trend data, the regular review could consist
of simply validating the process conditions and that confirming the assumptions used in the
corrosion risk assessment are still valid, rather than running the entire risk assessment every
time.
Case examples exist where, by running the corrosion risk assessment several times during
the first few years' operation of an asset (based on a better understanding of the actual, as
opposed to theoretical, conditions) has resulted in progressively fewer items being considered
as 'high-risk', thus reducing the requirements for inspection.
An important element in CRASs and planning is learning lessons from problems and failures,
but also from successes.
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ANNEX G
IMPLEMENTATION AND ANALYSIS
G.1 INTRODUCTION
Planning and implementation forms the largest single part of any CM process.
Successful implementation of the strategic and tactical plans depends on bringing the
required resources (e.g. equipment and competent personnel) together with suitable
instructions for the implementation task and the reporting requirement. It is heavily
dependent on the performance of personnel and all of the organisational elements come
into play.
Planning and Implementation continuously and rapidly influence each other through
the internal flow of information. This constant 'self-regulation' works within the overall
framework.
G.2 PLAN
G.2.1 Policy
The approach to implementation and analysis is related to the company integrity policy and
strategy with the aim of keeping threats ALARP.
G.2.2 Planning
The CM Strategy will define the approach to Plan implementation and the analysis of
collected data.
These are the details of activities that are scheduled in the Planned Maintenance (PM)
database. The routine should either contain all the instructions required to define the activity
to the technician who carries it out or it should refer to appropriate procedures and work
instructions. If the routine stands alone it is important that it contains the performance limit
and instructions on the immediate action to be taken if the limit is exceeded.
PM Routines (PMR) are used for a wide variety of CM activities and use of the PM
system is preferred because the database will usually automatically issue a work order
to trigger the activity just prior to being due. So routines are used, for instance, to
trigger inspections, monitoring equipment servicing and CP surveys in order that
they are implemented at the required intervals. PM work orders can be issued to the
in-house operations, maintenance and inspection teams and to external contractors and
service companies.
Usually activities can be linked so that, for instance, an order can be issued for preparatory
cleaning and access provision as well as the order for inspection. Activities can be tagged
as dependent on shutdowns and other events so that their execution can be appropriately
managed.
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Operating instructions and measurements programmed into the plant control system:
−− Operating instructions should be provided to the operations technicians to specify
when tasks are to be undertaken.
−− Schedules should be provided to specify chemical treatment rates. Calculation
methods or ready reckoners should be provided to calculate the rates where they
derive from other parameters such as combinations of flow rate and water cut.
−− The instructions should specify the action to be taken if performance limits are
exceeded either relating to manual measurements by the technician (e.g. oxygen
content of water samples) or plant control system alarms (e.g. a gas stream water
dew point moving out of specification).
−− The facility's Distributed Control System (DCS) can in some cases be programmed to
react directly to parameters that exceed their limits. In other cases an alarm can be
initiated for operator action (e.g. if an inhibitor pump stops running).
−− The data collected by the DCS will normally be held in a database (or 'historian')
for a given length of time. Arrangements should be made to download records to
corrosion monitoring databases or for direct incorporation into analysis and into
status reports.
Work packs can be produced and issued with the work order. They are used where sufficient
information cannot be fully included in the PM routine. Work packs can include:
−− work pack completion form/punch list form;
−− responsibilities and coordination requirements;
−− work scope;
−− procedures/work instructions (copies or references);
−− work orders;
−− drawing index and key drawings;
−− report forms;
−− change control forms and change records;
−− daily report forms;
−− previous anomaly history, and
−− correspondence, e.g. queries and responses.
The work packs should include the performance limits of where measurements or
observations are being made. These can be included against items in a scope list or may
be included in procedures. The procedures should include instructions regarding the
immediate action to be taken if performance limits are exceeded.
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Mitigation is inherently proactive and includes those barriers to corrosion failure that are
put in place as a result of initial threat assessments for design. This includes measures
like the use of CRAs, fluids processing such as gas drying and facilities and plans for
chemical inhibition. It also includes those things that can be planned to occur, such as
fabric maintenance.
Nevertheless, mitigation can be reactive and new measures can be taken when proactive
measures fail or unexpected corrosion mechanisms appear. This is essentially a type of
corrective action, which is discussed as follows.
G.2.4 Monitoring
Each barrier will have a performance indicator and its allowable limit that should not be
exceeded. It is necessary, therefore, to monitor the appropriate parameter and ensure that
the performance limit is not exceeded.
Reactive monitoring/inspection will normally be limited to off-line systems, and are also
normally aimed at quantifying the extent/distribution of any deterioration that has occurred.
Corrosion inspection and monitoring are key activities in ensuring asset integrity and control
of corrosion.
Field data and the results of laboratory evaluations should be trended to obtain up-to-date
corrosion information. Management decisions on equipment condition, prediction of
remnant life and requirements for chemical treating are only as good as the information
input provided from field experience.
Table G.1 gives examples of inspection and monitoring related to the performance limits for
various threats.
Consideration should also be given to the following points during the design of monitoring
programmes and analysis/interpretation of data:
−− Use of inspection data obtained during fabrication and pre-service testing can provide
baseline information.
−− Comparison of regular/continuous in-line/on-line monitoring data with less frequent
off-line inspections is needed to calibrate monitoring and establish acceptable
correlation for a particular production system.
−− Measurements from single points ('key point' UT and insert probes) should be
treated as suspect for the quantification of metal loss unless confirmed by back-up
information from other sources. Successive measurements can, however, be used to
infer trends in corrosivity.
−− Procedures should ensure that appropriate process data/information on water
cuts/CO2 / H2S contents is input into the corrosion data bank for later comparison
with corrosion trends.
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In-line systems cover installation of devices directly into the process, but which need to be
extracted for analysis, e.g. corrosion coupons, bio-studs, etc.
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Off-line monitoring/inspection is mainly achieved through the use of inspection and NDT
techniques, which include:
−− visual;
−− manual ultrasonic;
−− radiography;
−− pulsed eddy current;
−− magnetic flux leakage, and
−− time of flight diffraction (ToFD).
The use of alternative methods of detection should be considered in the light of any new
findings recorded. New inspection and monitoring technologies should also be evaluated
and considered as part of an ongoing system improvement process.
All activity should be planned at the strategic level. However, important events lie outside the
framework of the tactical plans that are delineated by RBI, etc. Procedures need to be in place
to capture the data presented by unplanned events.
Procedures should be in place to capture and report on corrosion and materials failures or
near misses. The MCDR procedure should be set up to facilitate rapid reporting of events and
the determination of corrective action by, or endorsed by, the appropriate TA.
The procedure relies on the workforce at the facility identifying and reporting corrosion
damage. To make this effective the MCDR process should a subject in the corrosion awareness
programme.
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It is important that, irrespective of the reporting route, certain features are facilitated:
−− Measured values that exceed allowable performance limits (PLs) must be highlighted
and reported as a matter of urgency to the function responsible for immediate action
in the case of non-conformance. For instance, data collected by the DCS should be
monitored by an alarm function and data collected by NDT should be compared to
acceptance criteria by the technician.
−− Special reporting routes should be identified for data that require urgent attention
to prevent failure.
G.3 DO
A risk assessment will be performed for each activity as required by the Company Health
Safety and Environment Policy and Integrity Policy.
G.3.2 Organisation
The duty holder is responsible for the implementation of the Plan and ensuring that all
required data are collected and analysed appropriately.
Successful implementation of the plan depends on bringing the required resources, e.g.
equipment and competent personnel, together with suitable instructions for implementation
of the task and the reporting requirement. It is heavily dependent on the performance of
personnel and all of the organisational elements that come into play.
The purpose of implementing the plan is to ensure risks are ALARP and that it is undertaken
in a cost-effective manner.
Planned tasks should be implemented through instructions written into, for instance:
−− planned maintenance routines;
−− operating instructions;
−− measurements programmed into the plant control system;
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Typically the data gathered, and their typical sources, will include:
−− process conditions, highlighting any changes (from the DCS data historian);
−− chemical analysis (from plant logs or service company reports);
−− inhibitor quantities (from plant logs);
−− inhibitor Injection up time (from DCS historian or plant log);
−− inhibitor residual (from chemical supplier's analysis report);
−− bacterial analysis (from service company reports);
−− visual observations (from operator or inspector's report);
−− corrosion monitoring data;
−− weight loss coupons, (from service company reports);
−− ER probes (from DCS historian or service company reports);
−− LPR probes (from DCS historian or service company reports);
−− field signature method (FSM) (from service company reports);
−− fixed ultrasonic measurement systems (from inspector or service company reports);
−− galvanic probes (from DCS historian or service company reports);
−− erosion/sand probes (from DCS historian or service company reports), and
−− CP survey data (from service company reports).
Not all inspection and monitoring systems are required or applicable for all assets/installations
and their use will be dependent on the type of corrosion process and material damage that
is expected.
G.4 CHECK
The purpose of measuring performance is to ensure the implementation and analysis is being
conducted in accordance with the plan in an efficient manner.
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During the planning and implementation stage, careful consideration of data storage,
data management and data analysis is required. Electronic data storage is considered
beneficial by many operators for ease of data management. However, manual paper-based
systems are also used successfully, especially for smaller or mature assets. In either case,
careful consideration should be given to the upkeep of data, where and how they are stored,
and who requires access to them. The latter point is particularly important where several
different organisations are engaged in the corrosion management process.
The person responsibility for data collation and data analysis should be clearly identified, and
the reporting structure evident. The reporting period of corrosion data should be in keeping
with the potential safety impact of the data assessed, and should be delivered on time.
Presenting the data in graphical displays/spread sheets assists the data interpretation.
Databases are available that allow measurements from different sources to be displayed on a
common time base. This enables changes in corrosion rate to be correlated with mitigation
measures and changes in operating parameters.
There are many uncertainties associated with corrosion monitoring and inspection data,
resulting from limitations of techniques, variability of corrosion, human performance
variables, etc. In using data to develop trends rates, remnant lives, etc., consideration should
be given to the reliability of the data.
It is important to question any data value that is uncharacteristic. It may signal a step change,
but on the other hand it may have simply been incorrectly recorded or be in some other way
in error. All data should be validated to avoid erroneous data being used.
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All valid data will, nevertheless, have an inherent unreliability; therefore, it is important to
consider the precision of the results when comparing a result to a particular performance
standard, or calculating a rate of change, etc.
Some operators and consultants use statistical analysis based on extreme value statistics
(EVS) to optimise the results of inspection programmes. For corrosion inspection, EVS provides
a method for reliably extrapolating limited information, and can, for example, identify the
most probable largest pit in a system.
In other cases, for instance, a simple comparison of the mean of two sets of readings can
reveal the order of difference between them.
Where wall thickness measurements are not taken at exactly the same sample point on each
successive inspection a simple analysis is not possible. However, meaningful data analysis can
still be obtained by using basic statistics.
Theoretical example: two separate inspections were carried out 18 months apart on a
production header by two different inspection companies who obtained 21 readings in the
first survey and 26 readings in the second.
Whilst some of the readings may have been taken at nominally the same point, it was not
possible to carry out a 'like-for-like' comparison, and originally it was concluded that the data
therefore had no value. Simple statistical analysis based on comparison of the means showed
that the average wall thickness had reduced by 1,1 mm over the 18-month inspection period
and that this change was statistically significant, at a 1 % level of significance, where a 1 %
level of significance implies that the chance of reaching a wrong conclusion is ≤1 %.
Anomaly reporting, responsibilities and procedures should be in place to ensure that, when
anomalies are identified, they are reported in a timely manner and recommendations for their
resolution are acted upon. As discussed previously, inspection reporting and corrosion and
material damage reporting procedures should provide for fast track reporting of dangerous
anomalies. The reporting structure for anomalies is particularly important where alliances are
in place between the asset owner and one or more contractors.
Anomaly data should be reviewed on a priority basis to ensure that dangerous anomalies
receive the most urgent attention.
The reporting format should be structured to ensure the key features and problems are
clearly evident, along with actions to be achieved.
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In keeping with company policy, a record should be kept of accidents/incidents and near
misses when implementing the plan.
If a serious failure or near miss occurs, or if persistent shortcomings in performance have not
been corrected, an RCA can be performed to ensure that corrective action is directed at the
root cause or causes.
Often, corrosion incident investigations tend to be either very extensive or limited to the
metallurgical evaluation of the failure.
Normal company incident investigation procedures may be very resource-intensive and hence
only justifiable for major incidents.
In such cases, the best results may be gained by the employment of a specialist in RCA
techniques to guide Corrosion and Management System Specialists in appropriate directions,
taking an independent view.
The Bow Tie model of barriers shown in Figure G.1 may be useful for identifying the root
cause of corrosion related failures.
During the investigation consideration should also be given to CMS elements described in
other parts of this document. Annex K may be used to identify relevant factors by working
through the list, identifying relevant questions and assessing the responses.
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Materials of
construction
Condition of
Chemical automatic
injection shutdown systems
Risk-based Condition of
Inspections deluge system
inspection
Coatings
Condition of
escape routes
Policy
Materials of construction:
−− Suitable for duty?
−− Appropriate design used?
−− Operated within the design envelope?
Inspections:
−− Were they conducted correctly using the appropriate technique/procedure?
−− At correct intervals?
−− Human factors?
Policy:
−− Were the policies appropriate for the operations?
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Cathodic protection:
−− Correctly designed?
−− Operated correctly?
Coatings:
−− Correct specification?
−− Correct application?
−− Correct maintenance?
Risk-based inspection:
−− Risks assessed correctly?
−− Correct input data used?
−− Risk reviewed when required?
Corrosion management:
−− Have changes in production conditions/equipment items/operational changes been
accounted for?
Chemical treatment:
−− Correct chemicals used?
−− Correctly dosed?
−− Equipment, e.g. pump, failure?
−− Chemical under/over-dosing?
G.5 ACT
It is important to learn from past experience in order to improve future CM and safety
performance. The knowledge gained should provide feedback to benefit future CMPs.
Reviews of all mitigation, monitoring and inspection data, should be carried out periodically
by a competent person.
Their prime objective is to provide a clear statement of condition and continued suitability for
use. This can be for an item, a section of the facility or the whole facility.
It is common to use CMT meetings to conduct frequent reviews of data on an ongoing basis.
These may be held at intervals of between one and three months depending on the stability
of corrosion trends and the effectiveness of barrier activity. As these reviews consider recent
results of barrier/mitigation, corrosion and process monitoring and inspection activity, they
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are considered to be tactical reviews and will be used to look for short-term corrective action
requirements.
MCDRs and/or OBVI information should be reviewed monthly and summarised at the CMT
meeting. They should also review the effectiveness of corrosion control matrices.
A traffic light status system should be used to present information. A summary of the status
of each section and the required actions and the concerns and issues should be formed into
a summary review for the asset/installation and delivered to the facility manager.
It usual to hold a wide ranging review annually for each section of an asset/installation. The
corrosion and inspection specialists will review all the data and publish them in a suitable format.
These reports should give a statement of the suitability of the equipment for ongoing service
and identify actions that are required to ensure it is safe to operate to CoP.
High levels of detail may not be suitable for all functions and the format of traffic light summary
may be used to display an overview to summarise the overall status and issues for a total facility
for the information of senior management, Figure G.1 and Table G.2 show examples.
It is good practice to hold a peer review sessions of the data. They should consider all the
reports for the sections of the facility to identify any shortcomings and to endorse the facility
sections' statuses.
The difference between short-term and annual reviews is the period over which the data are
collected for the review. The output of the review can include:
−− assessment of the current corrosion risks and their changes;
−− a summary of mitigation activity;
−− a summary of inspection activity and results;
−− a summary of corrosion monitoring and results;
−− an assessment of current conditions and suitability for continued operation;
−− recommendations for action required, and
−− ongoing issues and concerns.
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Relevant information (e.g. changes in corrosion trends, significant wall thickness loss, loss of
mitigation effectiveness) and lessons learned should not only be fed back into the corrosion
risk assessment but also into the strategic and tactical plans.
These facility status reviews should be considered in the process for CMS review that is part
of performance review.
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A B C D E
Has occurred Happens Happens
Has occurred Has occurred
in world-wide several times several times
in other part in specific
Severity industry but per year in per year in
of the part of
not in specific same location
organisation organisation
organisation organisation or operation Consequence Likelihood
Microbially
3. Critical influenced corrosion
145
on topsides
Likelihood Reducing
No clear plan for resolution or anticipated difficult
for the corrosion team to resolve
2. Marginal
A plan has been identified for resolution and is
in progress
Coating failure on
vessel A plan is in place and is well underway or the solution
1. Negligible is being monitored prior to removal from matrix
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Consequence reducing
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
CORROSION Internal Carbon steel separator vessel with carbon steel pipework
RISKS including bridle pipework
The biggest internal corrosion threat is considered to be dead
leg corrosion in the bridle pipework
External Atmospheric corrosion (due to marine environment) is
considered to be the biggest external threat on the vessel
INSPECTION Internal UT of vessel revealed no corrosion issues
RESULTS UT revealed up to 10 % WT loss in low points of bridle
pipework
External Previous visual inspections did not reveal any areas of
significant general/localised corrosion on vessel
CORROSION MONITORING Weight loss coupons situated at 1st stage separator indicated
low rates of general corrosion and localised corrosion
Bacteria enumeration was previously low. However, there has
been a steady increase in bacterial count over the last 5 years
CHEMICAL TREATMENT/ Corrosion inhibitor currently injected upstream of the 1st stage
MITIGATION ACTIVITIES separator
CURRENT ASSESSMENT The 1st stage separator is in a suitable condition for continued
service
Further inspection will be required for the bridle pipework for
potential dead leg corrosion
Superficial atmospheric corrosion on vessel externally. Vessel is
suitable for continued service
ACTION REQUIRED Immediately 3 months 6 months
Further NDT to Consider Conduct inspection
confirm if dead extending to determine if
leg corrosion is bacterial surveys. further mitigation
present at low Revisit vessel measures are required
points in vessel RBI to revise (i.e. removal of
bridle pipework. inspection unnecessary pipework)
Flush with biocide interval
and corrosion
inhibitor if
required
Reviewed by: Jane Doe Date: 29 Jan 2016
Peer reviewed by: BE, NH, DH, FW Date: 14 Feb 2016
Integrity Engineer Approval: Bob Smith Date: 15 Feb 2016
Status: RED Issue: Potential dead leg corrosion requires immediate
investigation
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Once the barrier/mitigation and corrosion monitoring and inspection data have been
collected and analysed, the necessary corrective action(s) required need to be identified
and put into place. The options available will depend upon the type of facility and the nature
and extent of the anomaly identified.
The practicality and economic impact of different options will depend on the life cycle stage
of the facility i.e. new build, major refurbishment or existing and ageing asset. Certain
corrective actions may be taken quickly whilst others, particularly improvement actions, may
require time to implement. It is important that corrective action requirements are registered
in a monitored list and that progress towards implementation is tracked, especially if a
dispensation is given to continue operation pending action. Various methods employing text
or spreadsheet lists and a variety of databases have been used successfully.
Relevant information and lessons learned should be fed back into the corrosion risk
assessment document.
Lessons learned following all reviews should not only be fed back into the corrosion risk
assessment but also into the strategic and tactical plans.
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ANNEX H
AUDITS
H.1 INTRODUCTION
Audits are performed to appraise the effectiveness of the CMS and to provide an independent
view of performance and identify opportunities for improvement.
Audits are an essential check on the performance of the CMS and will normally be carried
out by an independent party. In principle, the audit would cover a review of the management
processes being employed to ensure the continued integrity and maintenance of equipment.
The audits cover all aspects of:
−− implementation of procedures and processes;
−− competency;
−− checks in place, and
−− compliance.
Audits do not review the achievement of performance targets, but do review the processes
and procedures aimed at achieving those targets, and determine if the procedures for
ensuring that they are being achieved are being appropriately implemented. Where activities
are identified as not being conducted in accordance with the procedures and processes they
will be defined as non-compliant.
H.2 PLAN
H.2.1 Policy
Offshore UK, the Safety Case Regulations (SCR) require the Duty Holder/Operator to
demonstrate that adequate arrangements for audits have been put in place.
H.2.2 Planning
To allow time for auditing, reporting, corrective action, close-out and stabilisation of the
improved system, the duration of the audit cycle will generally need to be two to three years.
In addition to complete CM audits, more frequent internal audits should be carried out
covering specific procedures or implementation in specific units or by specific functions.
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H.3 DO
A risk assessment should be performed for each activity as required by the Company Integrity
Policy.
H.3.2 Organisation
Audits should be carried out by persons sufficiently independent to ensure that their
assessment is objective.
In most instances, audits are carried out by independent organisations on behalf of the
Duty Holder/Operator. The Duty Holder/Operator is usually responsible for ensuring that
appropriate remedial action is taken.
This process will ensure that the audit cannot be closed-out until all actions are cleared.
Audits may be carried out by either external third party organisations or by an in-house
independent consultancy group. In all cases, it is important that the auditors are not directly
involved in the day-to-day operation of the CMS and are trained in audit practice.
The more frequent audits relating to specific aspects of the assets or functions can be carried
out by in-house personnel, provided they are appropriately independent of production and
trained in audit practice.
The success of audits depends on the implementation and maintenance of a fully auditable
structured framework including clearly defined responsibilities and roles.
Audits should be carried out by trained, competent persons. Where outside organisations
are employed for independent audits, the individuals should be appropriately competent.
The audits will include review of procedures, review of records and discussions with relevant
company personnel. Audit reports should include progress results and recommendations.
Highlights from the annual audit reports and all in-house audits should be disseminated to
all relevant personnel. Details of the in-house audits and findings should be made available
to the independent auditing body prior to the annual audit.
H.4 CHECK
Checks should be in place to ensure all activities are compliant with procedures and processes.
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Checks to ensure that procedures and processes are being complied with include:
−− Review of documentation and records to assess conformance.
−− Review of records of non-conformances and incidents to ensure that.
– Appropriate investigation was undertaken in accordance with the procedures.
– Any investigation was effective and that any necessary changes to procedures
and processes to prevent recurrence have been developed.
– Changes have been incorporated into the procedures and processes.
– Changes are being implemented.
– Tracking of specific procedures and processes to ensure compliance, including
competency of responsible individuals, departments and organisations including
correct implementation, reporting and reaction.
Audits do not include identifying the cause of incidents/accidents/near misses, but rather
ensuring that the procedures and processes are in place to respond appropriately.
H.5 ACT
It is important to learn from past experience in order to improve the auditing process. The
results are fed back into the planning strategy.
−− wherever non-compliances are identified; this should result in the following
programme:
−− investigation of cause(s);
−− assessment of changes to procedures/processes to prevent recurrence;
−− implementation of changes, and
−− when a non-compliance is identified, the audit should not be closed-out until the
appropriate changes have been implemented.
Lessons learned from audit findings should be fed back into the policy and planning strategies.
The CMS audit is often carried out as part of a general audit of an organisation's operation.
However, for the most benefit to be gained, it is important that the results, in particular the
recommendations and list of improvement actions identified in the audit, are recorded within
the CMS and its improvement action tracking system.
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ANNEX I
OIL AND GAS PRODUCTION AND PROCESSING CORROSION
THREATS AND MITIGATION
The sections of this Annex give overviews of the top corrosion threats and main corrosion
mitigation methods encountered in oil and gas production and processing. Each section
overview describes the threat or mitigation itself and then describes how it is managed by
reference to the CM model.
The sections have been written by members of the work group and reflect one professional
view of the threat or mitigation method and its management. They may be used as an
introduction to each topic and as a stepping stone to wider sources of information and
advice. They should not be seen as a complete guidance to the topic.
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I.1.1 Description
Carbon dioxide (CO2) corrosion35, 36 is usually the main corrosion mechanism for carbon steel
materials exposed to produced fluids from oil and gas reservoirs. It is also called 'sweet
corrosion' and takes place in the gas-water-hydrocarbon multiphase system.
CO2 is a naturally occurring component of reservoir fluids and is an acid gas; when dry,
CO2 is itself not corrosive at temperatures encountered within oil and gas production
systems, but is so when dissolved in the water phase (in proportion to its partial pressure)
to form carbonic acid (H2CO3). One of the mechanisms proposed and widely accepted in
the industry was postulated by de Waard et al(1) where the carbonic acid then partially
dissociates to form the bicarbonate ion, which can further dissociate to yield the carbonate
ion in both instances increasing the acidity by releasing an H+ ion:
H2CO3 + e− H+ + HCO3(2)
It is recognised that solutions containing dissolved CO2 (and hence H2CO3) are more
corrosive to CS than solutions of strong acids, such as hydrochloric (HCl) or
sulfuric (H2SO4), at the same pH, due to the large reservoir of CO2 meaning the H2CO3 is
not depleted. The corrosion rate of CS is directly related to the concentration of the CO2
(expressed as mole % or volume % in the gas phase) and the total pressure, known as CO2
partial pressure. The corrosion rate also increases with temperature but at higher temperatures
(greater than ~60 °C) in produced waters the formation of iron carbonate (FeCO3) can reduce
the corrosion rate by increasing the pH and buffering the solution.
The solubility limit of iron carbonate salts (FeCO3) may be exceeded above certain
temperature and pH combinations causing it to precipitate. This iron carbonate precipitate
may form a protective film depending on the solution composition, pressure, temperature
and flow dynamic. Iron carbonate films/scales are prone to removal leading to both pitting
and general forms of metal loss, depending on flow conditions.
CO2 corrosion is associated with the water phase, and is therefore likely to be located where
water is consistently in contact with the metal surface. Such areas are typically around the
6 o'clock position in piping; however, CO2 corrosion may also be seen around the 12 o'clock
position where uninhibited water vapour condenses on the metal surface in ToL corrosion
(see next paragraph). CO2 corrosion is also likely in dead legs and other water traps, including
irregularities at welds. In the presence of high velocity flow, its effect on CO2 corrosion is
exacerbated by increasing the mass transfer of the corrosion products toward and away from
the metal surface.
CO2 corrosion manifests itself in many forms, general wall loss, 'mesa' type attack, and
pitting. Localised and pitting corrosion most commonly occurs in areas of turbulence and
sometimes at the root of welds. Generally, corrosion may occur in gas compression or gas
overhead systems if the steel surface is completely water wetted. Pitting generally leads
to small hole sized leaks. Mesa attack occurs by the breakdown of protective scale (above
~60 °C). Preferential weld or heat affected zone (HAZ) attack may also occur especially in
Ni-containing welds particularly in gas or condensate systems with low chloride condensed
water and low conductivity. Another mechanism associated with CO2 corrosion is top of the
line (TOL) corrosion which is due to the condensation of water containing dissolved CO2 and
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usually occurs in wet gas pipelines and in stratified flow regime. Weldments and HAZ can be
more severely affected by CO2 corrosion than parent material, where in the welds the filling
material tends to be slightly anodic to the parent steel, causing the weld metal to corrode at a
higher rate than the parent. HAZ can also be susceptible due to microstructure changes from
the welding process. Other susceptible areas to CO2 corrosion are regions other than HAZ
where the metal has been heated and the microstructure has changed, known as ringworm
corrosion when in the upset region of piping such as well tubulars.
CO2 corrosion is also affected by the presence of H2S and organic acids, chlorides, and
oxygen. The presence of H2S in combination with CO2 will influence the corrosion on
carbon steel. Low concentrations of H2S in the presence of CO2 can reduce the corrosion
rate due to the formation of protective FeS corrosion product scale. However, localised
pitting corrosion may result where the scale becomes disrupted or damaged. Turbulent
flow and also the presence of formation water with high chloride levels can damage the
protective scale; this is called flow influenced corrosion. Flow influenced corrosion is distinct
from erosion–corrosion and is primarily a corrosion process aided by chemical dissolution
and mass transfer.
In condensed waters, typically found in processed gas systems, corrosion may be very
aggressive due to low pH conditions as a consequence of there being no buffering effect
from the bicarbonate ions that are usually present in produced waters. The presence of
organic acids in produced fluids will also impact corrosivity.
In boiler feed water and steam condensate systems CO2 (along with carbonate ions) is
produced in the boiler by decomposition of bicarbonate ions. The CO2 dissolves in condensed
steam, and forms carbonic acid.
Various CO2 predictive models have been developed that take inputs of the main factors that
impact CO2 corrosion rate and either empirically (from historical field and laboratory datasets)
or mechanistically derive a corrosion rate. These models must be used with caution and a
knowledge of how they handle the various factors such as benefit from scaling etc.
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−− inhibition;
−− presence of Glycol, and
−− shear stress due flow hydro-dynamics.
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I.1.2 PLAN
I.1.2.1 Policy
Safety, environmental and commercial policies influence the choice of strategies for mitigation
and monitoring/inspection.
I.1.2.2 Planning
The CMS plan may be part of a wider Integrity Management Plan and CMS. For offshore
installations the strategy plan should be in line with the verification scheme. For onshore
plants, inspection schemes will be part of statutory WSE for pressure systems.
Tactical plans may jointly cover activities relating to other related internal corrosion
mechanisms, e.g. CO2 corrosion, PWC, deadleg corrosion, MIC, corrosion under deposits.
The plans should be translated into an executable plan and schedule for implementation.
The CMS needs to specify the plan with the activities to be carried out to reduce the identified
risk of CO2 corrosion ALARP. These activities can include:
−− mitigation measures;
−− monitoring methods and frequencies;
−− definition of KPIs;
−− anomaly management, and
−− organisational responsibilities for planning, execution, mitigation, monitoring and
reporting.
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I.1.3 DO
The probability of CO2 corrosion occurring can be predicted with consideration given to
following factors:
−− CO2 and H2S composition (mol %) in the gas phase;
−− water chemistry (pH, including bicarbonate and VFA, 12 ion analysis, CI residuals);
−− operating conditions (pressure and temperature);
−− microbial analysis;
−− Flow dynamics (gas/oil/water flowrates) including velocity and solids content;
−− material type;
−− on-line corrosion monitoring data (probes and weight loss coupons historical data);
−− CI testing and qualification using representative electrodes in the simulated process
environment;
−− quantitative predicted corrosion rates for the anticipated mode of corrosion,
e.g. localised, uniform, and
−− inspection observations and NDT data analysis.
I.1.3.2 Organising
All personnel involved should be made aware of the factors affecting CO2 corrosion including
preferential weldment corrosion and be vigilant to recognise the indications of, or changes
that are likely to cause or exacerbate, these.
Personnel should respond appropriately to any condition recognised to pose a threat and
rectify the situation through effective communication with the relevant organisations.
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The collected data can be plotted to identify any correlations between process conditions,
treatment changes and inspection/corrosion rate trends. Statistical analysis can be applied to
enhance the value of NDT data.
Specialist asset management databases are available to help organise this information.
Corrosion damage reports and maintenance reports should also be stored with the data so
as to be traceable.
The data gathered, with the aid of specialist database/tools, should be analysed in order to:
−− trend the uniform or localised corrosion rate;
−− assess if the mitigation implemented is able to reduce CO2 corrosion risk effectively;
−− determine root cause of any process upsets, e.g. change in operating pressure due to
hydrates, CI injection underdosing due to lack of availability, and
−− predict the likely corrosion rate and remaining life of the system or vessel.
I.1.4 CHECK
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The investigation will be in accordance with the CM strategic plan which may be part of a
wider Integrity Management Plan.
The root cause analysis of CO2 corrosion failures or management system failures will be
investigated with the appropriate corrective action(s) recommendation.
I.1.5 ACT
I.2.1 Introduction
Sour service is broadly understood to mean environments (typically multiphase, wet gas or
produced water) in which more than a certain level of H2S is present. There is no universal
threshold of H2S that defines 'sour'.
Hydrogen sulfide (H2S) is an exceedingly toxic gas, which poses a very serious health and
safety threat. It is present naturally in some oil and gas reservoirs and it can be generated by
anaerobic bacterial activity during production, most commonly when sulfate-containing water
(e.g. seawater) is injected for enhanced recovery. It can also be generated in downstream
plant during production, processing and storage operations. H2S is fairly stable, though it can
be oxidised to elemental sulfur by reaction with strong oxidisers such as oxygen, Fe³+ and Cl2.
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H2S readily dissolves in water at the temperatures and pressures encountered in many
production situations to form an acidic aqueous electrolyte which is corrosive to some
metallic materials. Usually the acidifying effect (and hence the contribution to corrosion) of
H2S is less than that of CO2 and hence the fundamental corrosion is essentially CO2 corrosion.
The main effects brought about by the presence of H2S on the corrosion of steel are the
formation of iron sulfide corrosion products and the promotion of uptake of atomic hydrogen
(H0) formed during corrosion.
When iron sulfide forms on the steel surface (rather than precipitating away from the
surface) it creates a film that can be protective, by reducing the general (CO2) corrosion
rate. That reduction can be dramatic (a factor of 100 reduction or greater) but present
knowledge does not allow its modelling or prediction. The degree of protection depends on
several factors including temperature, water chemistry and pH. Incomplete surface coverage
allows localised attack in the form of sulfide pitting. The metal penetration rate within the
pits is considered to be of the order of (and sometimes greater than) the sulfide-free CO2
corrosion rate. Inhibition of sulfide pitting is problematic and it is likely that, once pits have
initiated and grown to a critical depth, inhibitors cannot penetrate the pits and nor can
sulfide ions to film the active site. Some CIs can increase the sulfide pit penetration rate.
The majority of the H0 generated in the cathodic reaction of the corrosion process combines
forming hydrogen molecules (H2) which diffuse away with the process fluid. (At normal
operating temperatures and pressures molecular hydrogen does not diffuse into steel.)
However some of the H0 can enter the corroding metal. The presence of an iron sulfide film
on the metal surface increases the proportion of that hydrogen that enters the metal. This
hydrogen can cause embrittlement, cracking and blistering of susceptible metals.
I.2.2 SSC
Sulfide stress cracking (SSC) affects carbon and low alloy steels and martensitic stainless
steels. Cracking is the result of application of a tensile stress to a metal embrittled by the
presence of H0. It is therefore essentially hydrogen embrittlement of a susceptible metal, with
corrosion being the source of the hydrogen. The role of sulfide is to encourage a significant
proportion of the H0 to enter the steel, by preventing the formation of molecular hydrogen
on the metal surface.
As the risk of hydrogen embrittlement (HE) reduces with increasing temperature (i.e. mobility
of the hydrogen atoms in the steel lattice) the risk of SSC also reduces in the same manner.
However, SSC is a very rapid cracking mechanism, therefore even a short time, especially at
near ambient temperature (such as when a component cools during a process interruption),
is sufficient to cause cracking. It is therefore unsafe to use a susceptible steel for use in sour
service on the basis that the process normally operates at temperature high enough that HE
would not be significant.
The dominant factor in determining a steel's resistance to SSC is its hardness. Empirically it
has been found that steels of hardness below 22 HRC rarely fail in sour service, therefore this
hardness value was adopted as the original criterion for SSC-resistant steel. More recently
it was recognised that the H0 flux into the steel is also a significant factor and currently
the risk of SSC is defined in terms of the combination of the H2S content and pH of the
aqueous phase in contact with the corroding steel. The steel's hardness is a function of its
microstructure and heat treatment condition. Guidelines for the selection of SSC resistant
steels therefore specify acceptable heat treatments as well as imposing limits on hardness
and some other parameters.
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SSC is a rapid cracking mechanism, therefore it is unsafe to use a susceptible steel in sour
service with the intention of using inspection as a control option. SSC frequently results in
catastrophic failure, i.e. no warning by a small leak.
I.2.3 SCC
A number of CRAs are susceptible to stress corrosion cracking (SCC) in sour service. Whereas
SSC is essentially hydrogen embrittlement, SCC is an anodic process in the same way as
classic chloride SCC of austenitic stainless steels. The role of the sulfide ion is to prevent the
natural repassivation process that occurs on CRAs (within pits and cracks); in this way sulfide
acts synergistically with chloride ions to initiate and propagate pits and cracks. The presence
of a high enough tensile stress results in SCC.
I.2.4 HIC
Carbon and low alloys steels are susceptible to hydrogen-induced cracking (HIC). Note
that the terminology of hydrogen degradation mechanisms varies across industries and
between scientists and engineers. The terminology employed in this Annex is that adopted
by NACE. In HIC, the H0 diffuses (harmlessly) through the steel until it reaches trap sites
where it combines to form hydrogen molecules. Sites where this occurs include planar
inclusions (typically MnS) and regions of anomalous microstructure (e.g. banding) produced
by segregation of impurity and alloying elements in the steel. Cracking is planar in character
(as the MnS inclusions in rolled plate are parallel to the surface) and cracks can join these
planes, resulting in step-wise cracking (SWC).
There is no clear H2S threshold for HIC. The risk of HIC increases with H2S content of the
aqueous phase and cracking can occur at very low H2S contents if the pH is low, i.e. if the
corrosion rate (and hence the flux of H0) is high.
The risk of HIC reduces with increasing service temperature as the probability of the hydrogen
atoms falling into traps reduces. Some users consider the risk of cracking is negligible
above 65 °C.
No externally applied stress is required for the formation of HIC. This form of cracking
typically occurs in lower strength steel that is rolled; this includes plate steel used for
the manufacture of vessels and seam-welded pipe. The adoption of modern steelmaking
practice has resulted in the incidence of HIC having reduced over the past 40 years.
Specifying a maximum sulfur content or calcium treatment (which creates round CaS
inclusions in place of flat MnS inclusions) reduces the risk of HIC occurring. However,
to ensure resistance to HIC it is necessary to test each heat in accordance with NACE
TM0284. Less commonly other product forms including forgings, castings and seamless
pipe can suffer HIC.
Typically HIC progresses sufficiently slowly to allow its monitoring (by inspection) so as to
prevent catastrophic failure in even a susceptible steel.
Other H2S cracking mechanisms are much less commonly encountered. These include
stress-oriented hydrogen-induced cracking (SOHIC), in which HIC cracks progress under the
influence of an applied or residual stress (usually at welds) and soft-zone cracking (SZC), which
is a form of SSC that occurs in regions of low yield strength material (typically associated with
a weld in carbon steel).
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Figure I.10: Example of pitting corrosion on internal surface of flow line due to
hydrogen sulfide corrosion producing stress raising features and resultant lateral
cracking from the pits
Figure I.11: Example of SSC in a susceptible steel matrix showing both intergranular
and trans-granular crack propagation features
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I.2.5 PLAN
I.2.5.1 Policy
H2S-induced cracking can cause catastrophic failure of pipelines, piping, vessels and valves
resulting in the release of hydrocarbons and toxic gas. Company's Integrity Policy and Strategy
should therefore be to avoid such failures or at least to keep the risk ALARP.
I.2.5.2 Planning
The CMS for any plant operating in sour conditions will include planning for the prevention
of H2S-induced corrosion and cracking.
This involves establishing whether H2S is present in a process stream or whether it may be
present at a future date, e.g. by reservoir souring or incorporation of future tie-ins.
I.2.6 DO
Activities may include reviewing materials of construction of the existing facility for their
resistance to H2S corrosion and cracking.
H2S corrosion (i.e. sulfide pitting) can sometimes be controlled by inhibitor treatment but this
is not always easy or even possible. Internal coating of vessels may be more cost-effective
than inhibition. It is not usually practical to internally coat piping, therefore if the corrosion
allowance is insufficient to accommodate the rate of pit penetration, piping may require to
be replaced (typically in a CRA).
SSC and SCC can only be prevented by correct material selection, therefore changes to
some materials of construction may be required. Coating and inhibition are not appropriate
corrosion control measures for SSC and SCC.
HIC can usually be monitored (it progresses slowly in all but the most aggressive conditions)
if access for an appropriate inspection technique is available. This provides advance warning
of the need for replacement.
I.2.6.2 Organising
That part of the Duty Holder which is responsible for managing corrosion risks should
arrange for the preparation of mitigation measures to control any anticipated H2S corrosion
and cracking degradation.
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If extensive changes are required to materials of construction this will normally require a
major shutdown.
I.2.7 CHECK
SSC and SCC are rapid cracking mechanisms, therefore it is not routine practice to inspect for
these forms of cracking, hence the performance of material selection as a corrosion control
method is not normally measured. Inspection for cracking could be conducted but this is not
likely to be cost-effective; cracking would be very isolated and hence difficult to find.
Failure by H2S corrosion could indicate a more widespread concern such as the corrosion
rate (general or pitting) being higher than predicted, or the inability of an inhibitor to control
corrosion.
Failure by SSC or SCC generally indicates that the material of construction is susceptible to
cracking in the operating environment, but occasionally that cracking may have been caused
by unexpected localised events (such as concentration of chloride ions on a heat exchange
surface) or upset conditions (temperature spike or oxygen ingress).
Any failure should be reviewed in terms of its possible more widespread relevance to the
remainder of the facility.
I.2.8 ACT
The performance of any inhibitor used to control general or localised corrosion on CS should
be reviewed in order to assess whether the inhibitor is functioning correctly and to inform
any decision as to whether dose rates might be reduced. Although this might be achieved
by study of corrosion monitoring data, more reliable data should be derived from piping and
vessel inspections (wall thickness records and visual inspection for pitting).
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The results of investigations into failures, particularly unusual failures and those occurring
in circumstances where the material would not be expected to fail, should be disseminated
in-house and, where possible, in the public domain.
Unexpected and unexplained H2S cracking failures have the potential for advancing the
industry's understanding of the H2S limits for the materials of construction used widely in
sour service applications.
I.3.1 Introduction
Amines are used to remove the acid gases H2S and CO2 from produced gas.
Amines are not corrosive towards the materials of construction used to fabricate amine
absorption systems. However, the acid gases (H2S and CO2) are corrosive and hence the
corrosion threat is greatest in the rich amine streams.
The corrosivity of amine streams is generally defined in terms of the acid gas loading (moles
of H2S and CO2 per mole of available amine) and operating temperature. The ratio of H2S to
CO2 and their absolute contents (partial pressures) are also factors in corrosivity. Significant
rates of general corrosion are encountered in these systems, therefore the incorporation of a
corrosion allowance into the design is a primary corrosion control method.
As-welded or cold worked carbon and low alloy steels are susceptible to SCC in amine service.
Some contaminants in amine streams are corrosive towards carbon steel and stainless steels.
Contaminants in amine systems include:
−− Amine degradation products; heat stable amine salts and organic acids (formic,
oxalic, acetic and propionic) formed by reaction with oxygen originating in the
amine storage tank or make up water or air drawn in at leaking seals on pumps and
compressors.
−− Chloride ions (originating in the make-up water) build up over time and cause
corrosion of stainless steels in amine systems.
−− Solids, in the form of particulate material, contribute to erosion corrosion and
damage to protective films.
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Amine corrosion is often localised in the form of pitting or grooving, with under-deposit
corrosion and galvanic corrosion also occurring. Increasing velocity or turbulence increases
corrosion rates by degassing the H2S and CO2 from solution and by removing protective iron
sulfide films. This erosion corrosion particularly affects pumps and areas of impingement in
vessels; in piping, flow rates are controlled to minimise erosion corrosion. In conditions where
the corrosion rate of CS is unacceptably high, austenitic stainless steels (principally 316/316L)
are selected although 12 % Cr grades are sometimes used.
I.3.2 PLAN
I.3.2.1 Policy
Because amine cracking can cause catastrophic failure of piping, vessels and valves, resulting
in the release of hydrocarbons and toxic gas with potential catastrophic consequences a CM
policy should be generated to comply with the Company's Integrity Policy and Strategy to
manage the risks to the ALARP principle.
I.3.2.2 Planning
Because of the potential risks associated with operating an amine plant the Duty
Holder/Operator should generate a plan to manage those risks.
The functional responsibility for managing the degradation of the amine plant should
generate a time based written plan which identifies the work which needs to be undertaken
to manage the threats and consequences:
−− corrosion threats assessment;
−− RBI plan;
−− WSoE;
−− reporting lines;
−− reporting frequency for:
– overview status, and
– major condition assessments.
−− how the plan complies with the Regulatory requirements;
−− frequency of reviewing the CMS, including identifying when:
– unplanned events should trigger a review, and
– new process conditions are known to occur due to changes in feedstock.
The CMS for amine plant will include planning for the control of amine corrosion and
prevention of cracking.
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I.3.3 DO
The CTA will identify the rate of corrosion degradation and the risk of cracking, which will
form the basis of managing the risks.
The CMS for amine plant will include planning for the control of amine corrosion and
prevention of cracking.
I.3.3.2 Organisation
The Duty Holder/Operator is required to have a suitable and sufficient organisation for
managing the potential degradation risks associated with operating an amine plant to
manage those risks to ALARP.
The Duty Holder/Operator should identify the functional responsibilities for managing the
corrosion related degradation of their amine plant. This will include identifying the function(s)
responsible for:
−− generating and reviewing the CTA;
−− generating and reviewing the RBI;
−− generating and reviewing the WSoE;
−− inspecting the plant;
−− reporting the findings of inspections;
−− prioritising the findings according to risk;
−− acting on anomalies identified from inspections;
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The competencies of the functions responsible for carrying out the tasks should be identified.
Ideally a 'dashboard' should be generated which provides management with a quick method
of understanding the plant condition and risks – a traffic light system could be used.
The RBI should be transferred onto P&IDs and isometrics so that the NDT Operators can enact
the WSoE onto the plant in a consistent manner.
For each inspection location the CONC should be identified in the WSE so the NDT Operator
can make an immediate assessment of the risk, which will be followed up by a more detailed
calculation by the responsible person in the office. The CONCs for each critical plant items
should be compared to an agreed Performance Standard.
Where anomalies are identified an anomaly report should be created which should be issued
in a timely manner to the persons responsible for doing more detailed assessments and
acting upon those assessments.
All inspection findings must be logged in a system which is suitable and sufficient for
the size of the operation and the associated risks. At its most basic level this may be
satisfactorily performed by using electronic spreadsheets. At a higher level there are
sophisticated databases which can be populated with all the requisite data including CONC
and Performance Standards which will automatically calculate the risk of failure and when
the inspection should take place. it is for the Duty Holder/Operator to decide the required
level of sophistication of the data management system.
I.3.4 CHECK
KPIs should be generated against which the CMS and the measurement of plant condition
can be compared.
Corrosion rates in amine systems can be measured by corrosion monitoring. Not all
online monitoring techniques are appropriate because iron sulfide films can be electrically
conductive. The film can bridge the electrodes in LPR probes, preventing meaningful data
acquisition. ER probes tend to underestimate corrosion rates in sulfide environments because
the sulfide film carries some of the measurement current.
Corrosion rates increase with increasing temperature, therefore coupons and probes may
under-report corrosion rates on heat transfer surfaces.
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Amine cracking is a rapid mechanism, therefore it is not routine practice to inspect for
this form of cracking, hence the performance of material selection as a corrosion control
method is not normally measured. Inspection for cracking could be conducted but this is
not likely to be cost-effective; cracking would be very isolated and hence difficult to find.
Failure by amine corrosion could indicate a more widespread concern such as the corrosion
rate (general or pitting) being higher than predicted.
Failure by cracking generally indicates that PWHT was not undertaken, or was not performed
correctly.
Any failure should be investigated in order to derive any information that may have more
widespread relevance to the remainder of the facility. A failure investigation should be aimed
at not only identifying the mechanism of failure but more importantly the circumstances
which led to the failure, i.e. the cause, so corrective actions can be implemented to prevent
a recurrence of the failure. Typically, failure investigations involve a mechanistic study to
determine how containment was physically lost e.g. the type of corrosion (general, pitting,
under-deposit, microbiological etc.), the type of cracking/fracture (ductile, brittle, fatigue);
then a causation study tries to establish what the circumstances were that caused the
component to fail by a particular mechanism. In the case of unusual, or difficult to diagnose
failures, a full RCA may be beneficial. The RCA takes the findings of the failure investigation
further by considering all factors that may have resulted in the failure of a component and
uses techniques that are effective in exploring some of the other contributors to failures, such
as the human and economic factors. Properly performed, failure investigations and RCAs are
critical steps in the overall problem-solving process and are key ingredients for correcting and
preventing failures thereby achieving higher levels of reliability.
The results of investigations into failures, particularly unusual failures and those occurring
in circumstances where the material would not be expected to fail, should be disseminated
in-house and, where possible, in the public domain.
I.3.5 ACT
The continued safe operation of amine systems depends on regular review of the
performance of materials of construction and the corrosion mitigation measures in use.
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The CMS should be reviewed at a frequency in keeping with the inspection findings from the
plant; i.e. if rapid corrosion is being identified then the CMS is evidently ineffective and must
be changed as soon as reasonably practicable.
At its lowest level, the team responsible for the CMS and inspection of the plant should
undertake an annual review.
The next level of review would be competent persons who are not directly responsible for
the plan.
The preferred option for reviewing the effectiveness of the CMS is by competent third parties
with no direct involvement with the facility on which the amine plant is operating.
Where it is identified through experience or by formal review of the CMS, that the criteria
for the rate of degradation of the plant are not being met, these lessons should be fed back
into the CMS to ensure that the intent of the Corporate Policy and the Integrity policy are
being met.
Feeding the lessons learned back into the CMS ensures continuous improvement of safety
and of the CMS.
I.4.1 Introduction
This guide covers oxygen corrosion for seawater lift and distribution (seawater), firewater
(FW) and seawater injection (water injection) systems. Oxygen is present in the seawater
lifted from the ocean at a level of approximately 8 ppm and reacts with carbon steel to
form various iron oxides, most of which offer little mechanical strength, thereby eventually
compromising the integrity of the corroded components (seawater).
When oxygen is present, the corrosion mechanism of iron proceeds further as ferric
hydroxide is formed as corrosion product. Once formed, ferric hydroxide is not protective
and acts as an accelerating agent to produce ferric oxide.
Oxygen corrosion is easily recognised by the large pits produced. Oxygen pitting begins
at weak points in the ferric oxide layer and continues at the same location. The type of
pit developed is influenced by the pH making them bigger at low values. When the pH
increases, a protective oxide film is more effectively maintained, resulting in pits of smaller
circumference. Active oxygen pits contain reduced black oxide along the concave surface of
the pit, while the surrounding area above the pit becomes covered with ferric oxide – as seen
in Fig X_ . Black iron oxide indicates that the pit is active, whereas the presence of red iron
oxide indicates no activity.
Beside the pH and oxygen, the presence or macro- and micro-organisms also affects the
corrosivity of the seawater by the products of their metabolism and by the degradation of
biomass, while the oxygen content provides the driving force for the corrosion reactions.
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The temperature also affects the corrosion process in two different ways; firstly it directly
affects the corrosion reaction exponentially as well as having an effect on the solubility of
oxygen in the seawater. The higher the temperature, the lower the solubility of oxygen in
the water.
There are other factors to consider when assessing dissolved oxygen in seawater corrosion;
one of them is the flow rate, as it has also been shown that the transport of oxygen to the
cathode surface is profoundly affected by the flow rate of the seawater making the corrosion
rate nearly linearly dependent on the flow rate. Another factor to consider is the salinity of
the seawater which also affects the dissolved oxygen content. The higher the salinity, the
lower the oxygen content. In addition to that, the salinity of the seawater also increases
the electrical conductivity of the seawater as an electrolyte compared to the fresh water
conductivity, thereby increasing the corrosion rate.
The potential threat to stainless steel equipment from oxygen corrosion is localised pitting
corrosion and/or chloride SCC, which also can be addressed with the use of duplex or super-
austenitic stainless steel and CRAs that will give resistant to crevice corrosion at certain given
temperatures and conditions.
The effective control of microbial activity reduces the potential for FeS film formation and
solid deposition, both of which accelerate oxygen-related corrosion. Copper/nickel alloys
are frequently used in low flow areas of seawater systems due to their excellent corrosion
resistance.
Figure I.12: Pitting corrosion at 6 o'clock position that resulted in a leak in a spool-
piece on an outlet of a flotation unit upstream of a water injection pipeline. Pit < 1
cm diameter. Also corrosion is noted on the flange face
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I.4.2 PLAN
I.4.2.1 Policy
The plan for managing oxygen corrosion should fit in with the corporate Policy for integrity
management, with safety, environmental and commercial policies influencing the choice of
strategies for mitigation and monitoring/inspection. The key areas of concern will include
the water injection system, the water winning system and the firewater distribution system.
Responsibilities should be allocated for monitoring corrosivity, wall thickness loss and
management of corrosion.
I.4.2.2 Planning
There should be plans in place to prioritise and manage the risks associated with the systems
subject to oxygen corrosion, with the water winning and firewater systems being allocated
the highest priority on the basis of safety. Loss of water injection is a business risk and hence
lower priority.
I.4.3 DO
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Seawater injection strongly influences production capability and repair or replacement costs
due to poor corrosion control may be substantial. Seawater injection systems operate at high
pressure and the consequences of a leak could cause harm to persons in the vicinity, which
must be avoided.
The environmental risks associated with seawater systems are low/negligible due to their
non-hazardous nature.
The maximum flow rate of seawater for effective deaerator tower operation should be
defined and not exceeded in order to minimise the risk of erosion-corrosion.
I.4.3.2 Organisation
Organisational roles may include:
−− Corrosion and Materials Specialists:
– lead on risk assessment, planning and analysis
−− Production Chemical specialists and chemical suppliers:
– lead on risk assessment, planning and analysis
−− Facilities Operations teams:
– lead on mitigation implementation, for example following procedures for
water quality control
−− Inspection Engineers and NDT contractors:
– lead on metal loss measurement
−− Pipeline Engineers:
– lead on metal loss measurement
Communication activities should aim at increasing awareness of the factors that influence
oxygen corrosion to ensure the impact of operating changes are fully understood, and at
raising awareness of the safety, environmental and commercial consequences of failure.
CRAS should include oxygen corrosion metal loss rate which can be determined from a
combination of:
−− quantitative corrosion rate forecast, e.g. Oldfield, Swales and Todd models;
−− corrosion monitoring – LPR probes and coupons;
−− microbiological measurements, including planktonic levels and sessile levels from
biostuds and coupons;
−− inspection observations and measurements, and
−− leaks and failure reports.
The oxygen corrosion threat will normally be addressed in the CMPs/matrix to specify:
−− mitigation methods;
−− performance targets;
−− monitoring methods and frequencies;
−− immediate action required on non-conformance;
−− organisational responsibilities for mitigation, monitoring and immediate action;
−− operating instructions;
−− plant instrumentation and data collection via DCS;
−− elements of RBI schemes;
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Rate measurements and predictions can often give very different results and all have
considerable uncertainty of measurement or prediction. Judgement is required to produce a
useful result. The CM Plans may be part of a wider integrity management plan. For offshore
installations the strategic plan should be in line with the verification scheme.
CMPs should be reviewed and revised to meet changing operating conditions, either at a
fundamental or tactical level.
Tactical plans may include measures to address the causes of increased oxygen levels. These
may include deanerator tower (DA Tower) antifoam injection, pump seal maintenance,
increased biocide treatment or increased oxygen scavenger injection.
Implementation should be carried out in accordance with plan. Results obtained from
maintenance activities may be useful (see notes and comments).
Note that seawater testing of deluge systems may result in the blockage of nozzles with
corrosion products and hence loss of performance and ineffective containment of a fire and
control of a potential major accident.
Water injection pump maintenance: loss of seal integrity may permit oxygen ingress.
LPR probe fouling: fouling with FeS may lead to short-circuiting of the probe elements and
consequently erroneous high corrosion rate readings.
Performance indicators are likely to cover disposal of seawater overboard if oxygen level
is excessive. A controlled increase in oxygen scavenger may be necessary to temporarily
compensate for poor DA performance.
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I.4.4 CHECK
Comparison of oxygen corrosion rate predictions, oxygen levels, coupon results, LPR data
and carefully-selected wall thickness data will help to understand the likely degradation rates
and the reliability of each dataset.
Determine if existing corrosion control measures are achieving the necessarily low levels of
oxygen and/or low rates of wall loss and whether improved monitoring is required.
The root cause of excessive oxygen corrosion may be due to the primary factor, i.e. a high
oxygen level or it may be due to secondary factors such as microbial contamination, solid or
marine solid material.
I.4.5 ACT
I.4.5.1 Audit
Activity for the management of oxygen corrosion should be included in CMS audits.
The CMS should achieve the objectives of the policy by maintaining the integrity of the water
injection pipeline throughout the design life.
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I.5.1 Introduction
Microbially-influenced corrosion (MIC) remains one of the biggest threats to oil and gas
installation integrity. Existing strategies tend to focus on dead legs, whereas experience has
shown the threat to be more widespread, including flowing wet oil pipelines. Water-injection
systems are at high risk, especially produced water reinjection (PWRI) and MIC can prevail
in drains systems of all installations. MIC also occurs in: plant and pipelines under wet
lay-up: following hydrotest or subject to 'mothballing'; the water bottoms of oil storage
tanks including diesel tanks; cooling water systems and firewater systems.
Inspection is notoriously unreliable at detecting MIC, given its extremely localised nature,
but sampling and subsequent chemical treatment provide the best available control strategy,
However, often the management of MIC can be unstructured due to lack of recognition of
the threat and the implementation of inappropriate mitigation measures.
I.5.1.1 Example 1
The classic morphology of severe MIC in carbon steel, is shown in Figure I.14. MIC was
mediated by SRB (SRP) in 8 mm wall thickness CS drain system pipework, described as a
'slops line', which failed after four years of service.
Fluids were 96 % water, 4 % crude oil, low partial pressure of CO2, pH~6, ambient
temperature or just above.
There was slime formation with proliferation of SRB (SRP) under slime. Sulfides on the surface
of metal sections were detected by the lead acetate test.
The solution was to minimise stagnation, apply more frequent and consistent batch biocide
treatment and in the longer term consider material change to CRA.
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I.5.1.2 Example 2
Microbiologically-assisted, chloride induced pitting attack of an active/passive alloy, AISI 316L
austenitic stainless steel is shown in Figure I.15. 5 mm wall thickness at a newly constructed
and hydrotested chemical plant. Initially, there was a futile attempt to clamp the leaks until
eventually hundreds were discovered, leading to complete write-off of pipework.
Untreated water was stagnant for three months with heating up to 50 °C locally during the
day, ambient temperature ~30 °C.
High population density of total bacteria and SRB. Massive slime formation. Proliferation of
SRB in anaerobic zone under slime. Sulfides on surface of metal sections.
The solution was to conduct future hydrotests using steam condensate or with filtered
water treated with a biocide and trisodium phosphate equal to five times the chloride
concentration. Following hydrotest, excess water to be blown out with warm, dry air to
60 °C. Heat to be applied to pipes wherever possible. Drying was assisted by flushing with
methanol where possible.
I.5.1.3 Example 3
A gunmetal impellor (red brass 88 % copper with tin and zinc additions), Figure I.16 from a
seawater pump in a polluted harbour. The pump ran without problems for many years, with
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throughput of aerated seawater then was shut in for one year. SRB proliferated in stagnant
polluted water., The impellor severe shallow pitting merging into generalised corrosion. The
corrosion product was copper sulfide.
The solution was to avoid stagnation where possible. If the pump really must be shut in
for a prolonged period with stagnant seawater, add a biocide (minimum 1 000 ppmv
polyhexamethylene biguanide) and a specific compatible copper alloy ci(benzotriazole or
tolyltriazole).
The ways in which metabolic activities of certain microorganisms bring about or contribute
to corrosion may be broadly categorised as follows:
a) Direct chemical action of metabolic products such as organic acids or reduced sulfur
compounds, especially sulfides.
b) Generation of an electrochemical cell by deposition of cathodic and conducting
metal sulfides, often in conjunction with mechanism a).
Localised electrochemical effects due to changes in oxygen concentration, pH, etc, which
establish local differential cells, often in conjunction with mechanisms a) and b). The physical
presence of the biomass in itself contributes to this mechanism.
MIC problems have been widely documented in carbon and low alloy steel piping systems,
storage tanks, cooling towers, water injection systems and pipelines. Carbon and low alloy
steels are widely used due to their low cost. Though mild steel components can be coated or
lined for internal corrosion protection, biofilms can form at flaws in the surface of coatings.
Numerous cases have also been documented where microorganisms have caused disbonding
of coatings from the underlying metal and delamination of the coatings creating an ideal
environment for further MIC.
The MIC mechanism may involve acid attack by: organic acids generated under deposits
by anaerobic bacteria; differential aeration cells due to localised bacterial consumption of
oxygen; SRB-mediated corrosion or a combination of these processes. The most widely
encountered MIC mechanism is that mediated by SRB, more correctly termed SRP, growing
in complex biofilms with other micro-organisms.
The corrosion pattern is localised, generally in the form of shallow pitting attack, with
maximum pitting rates significantly in excess of 1 mm/year in the more severe cases. It often
occurs in the absence of oxygen and at near-neutral pH i.e. conditions that standard corrosion
theories would suggest as being benign.
MIC of active/passive materials such as stainless steels can be regarded as a special case
of chloride-induced crevice or pitting attack, which occurs at combinations of chloride
concentrations and temperature that would normally be considered 'safe' for a particular
material. Contrary to popular belief, MIC mediated crevice corrosion is more common than
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MIC pitting corrosion. Microbial metabolites, especially sulfides and other reduced sulfur
compounds allow pitting which can propagate at electrochemical potentials close to the
minimum for metastable pitting, which would normally be expected to harmlessly repassivate.
Most workers believe that the presence of at least some oxygen is required to initiate the
process.
Very severe crevice corrosion, of 1 to 2 mm depth in six months, has been observed on
alloys UNS S30403, UNS S31603 and lean duplex UNS S32101 exposed to severe biofilm
conditions. A lesser, but still severe, amount of crevice corrosion, to a maximum depth of
~0,5 mm has been observed on the 22 chrome duplex alloy UNS S31803 over the same
period. 25 chrome super duplex material is probably only susceptible to MIC under the most
extreme biofilm conditions and at temperatures probably ≥ 30 °C and in the presence of
high chloride concentrations.
Copper alloys find use in seawater piping systems and heat exchangers and are susceptible
to MIC. MIC observed in copper alloys includes pitting and dealloying. Higher alloying
content in copper usually results in a lower corrosion resistance. Although MIC has been
found in both 70/30 and 90/10 Cu/Ni alloys, more problems have been documented with
70/30 than 90/10 Cu/Ni alloys. MIC has also been documented in brass (Cu-30Zn-1Sn),
aluminium brass (Cu-20Zn-2Al) and aluminium bronze (Cu-7Al-2.5Fe). High strength Cu-Ni
alloys are susceptible to SCC in the presence of ammonia which can be produced by heavy
accumulations of biofouling.
Nickel alloys are often used for applications subject to high velocity water environments,
including heat exchangers, pumps, turbine blades and valves, as they have a higher resistance
to erosive wear than copper alloys. However, some nickel alloys are susceptible to pitting
and crevice corrosion under stagnant water conditions and static periods can lead to MIC.
Monel 400 (66,5Ni-31,5Cu-1,25Fe) has been found to be susceptible to under-deposit MIC.
Pitting corrosion, inter-granular corrosion and dealloying of nickel have all been observed
with this alloy in the presence of SRB (SRP). Ni-Cr alloys have been found to be generally
more resistant to MIC.
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Non-metallics, including coating and linings, that find service in the petroleum production
industry are generally highly cross-liNked, highly chemically resistant polymers such as
phenolics, epoxy-phenols, epoxy powder coatings, polyurethanes, GRE and polyethylene
liners. Many of these materials are also extensively used for water pipelines in the water
supply industries, so there is a lot of experience as to their characteristics and behaviour.
There is little or no evidence that microbiological degradation presents a concern for these
types of materials in the context of oilfield fluid handling systems. As well as the materials
being at the highly degradation-resistant end of the non-metallic materials spectrum, most
microbial degradation of polymers in general, which is often cosmetic more than structural,
is mediated by aerobic fungi, which rarely proliferate in saline waters or in deaerated
environments.
I.5.6 PLAN
I.5.6.1 Policy
Safety, environmental and commercial policies influence the choice of strategies for mitigation
and monitoring/inspection:
−− the choice of MIC resistant materials is rarely an option because of high cost, and
−− inspection is unreliable at detecting MIC, given its extremely localised nature.
Models for the prediction of MIC exist and are worthwhile but they much are less developed
and less reliable than other corrosion models, for example for CO2 or oxygen corrosion
models – MIC models tend to give worst case predictions, which may or may not actually
occur in practice.
Sampling and careful trending of microbiological data often provide the best guide to MIC
corrosion risk. Biofilm ('sessile' bacteria) data from coupon or biostud analysis are more
reliable than water testing results. Trended data are more reliable than single point analyses.
I.5.6.2 Planning
The CM strategic plan may be part of a wider Integrity Management Plan. For offshore
installations the strategic plan should be in line with the verification scheme.
Chemical treatment with biocides, either continuous chlorination or batch treatment with
organic biocide, often provides the best available MIC control strategy, especially when
combined with frequent pigging, in the case of pipelines.
Minimising stagnation, especially in the presence of untreated fluids and maximising flushing
is important.
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Where applicable (e.g. tank bottoms), well maintained coating and/or CP systems provide
reliable protection against MIC.
I.5.7 DO
I.5.7.2 Organisation
All personnel involved should be made aware of the factors affecting MIC and be vigilant to
recognise the indications of, or changes that are likely to cause, MIC.
Personnel should respond appropriately to any condition recognised to pose a threat and
rectify the situation through effective communication with the relevant organisations.
All personnel involved should be made aware of factors giving rise to MIC, the visual
appearance of MIC and its highly localised nature and any changes in processes that may
alter the risk of MIC e.g. changes in operation temperatures, changes in salinity of fluids,
down-time and stagnation, changes in pigging frequency or chemical injection patterns and
should effectively communicate such information to colleagues and associated organisations
involved.
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a) and b) lead on risk assessment, planning and analysis; b) and c) lead on mitigation
implementation, for example biocide selection and monitoring of bacterial trends, and d)
and e) lead on metal loss measurement.
The output from the risk assessment includes mitigation, monitoring and inspection activities.
These activities require discussion on a regular basis to ensure MIC management tactics are
effective.
In the absence of a permanent engineering solution, flushing dead legs can reduce the MIC
threat. This option is particularly important for operational dead legs. Ideally, dead legs should
be flushed with fluids that contain biocide to inhibit microbial growth. Flushing dead legs
with untreated fluids can reduce the threat of corrosion by removing deposits and preventing
microbial biofilms becoming established. However, this can replenish the nutrient supply,
which can exacerbate microbial growth. This should be taken into consideration when
deciding upon a mitigation strategy.
Flushing of dead legs should be considered in any system that is subject to continuous or
regular application of batch biocide treatment. Continuous chlorination of the raw seawater
systems means that stagnant zones and operational dead legs in the seawater systems should
be flushed regularly, e.g. firewater ring mains.
In plant with seawater injection systems, consideration should be given to flushing dead legs
during the regular batch biocide treatment of the system.
Although biocide treatment of production and drains systems is less common, it can be
employed when microbial growth has become established.
Biocide treatment is generally ineffective if deposits are present, which can shield areas of
bacterial activity. Solids removal is therefore essential prior to chemical treatment.
Chemical treatment target levels and flushing requirements should be reviewed on a regular
basis and modifications made if required.
Inspections should be targeted at locations where water and deposits can collect, allowing
microbial activity to develop. This is dependent upon the orientation and configuration of
the pipework:
−− Bottom third of any horizontal piping between the 4 and 8 o'clock position.
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−− Off-takes originating from the lower half of horizontal lines; inspection will be
targeted at low spots, bottom of vertical sections, horizontal sections, above closed
valves, etc.
−− Unless dead legs can be removed they must be inspected at a prescribed interval
identified during the risk assessment process.
−− Sections of off-takes close to the main line which is the source of bacteria, nutrients
and heat.
−− Lowest parts of vessel bridle work, together with any associated level gauges.
−− Upstream of concentric reducers.
Locations where previous corrosion or erosion has reduced the wall thickness.
The results of periodic bacterial counts to NACE TM0194 (2014) as well as chlorine and
biocide dosing data are useful in understanding the ongoing MIC threat.
For water injection, in adequately chlorinated water, no viable bacteria should be detected.
Pipework upstream of deaerators is usually CuNi or GRP, 0,5 to 0,7 ppm free chlorine is
recommended. If it is duplex or carbon steel, 0,2 to 0,3 ppm (excess chlorination causes
pitting corrosion). Copper/chlorine dosing systems are usually poor and not recommended.
The high surface area of packing in deaerators provides an ideal environment for SRB.
Elevated numbers are often due to poor/ineffective biociding. Biocide should be dosed to
the deaerator inlet and dosing optimised.
In fast flowing water injection systems even low numbers of planktonic SRB can be associated
with elevated numbers of sessile SRB.
For production systems, even in hot systems, check dead legs and vessel bridles for
low temperature SRB (m-SRB), as m-SRB can gain access via feed from drains vessels to 2nd
stage separators. The main concern regarding SRB is in base of uncoated CS vessels and
pipework, where they proliferate under deposits. Generally state that inspection frequencies
should reflect the enhanced risk threat of MIC in these locations. If biocide is required select
a non-foaming formulation.
For drains systems the main concern is SRB in the base of uncoated CS vessels and pipework
where they proliferate under deposits. Inspection frequencies should reflect enhanced risk
of MIC in these locations. Recommend local biocide dosing if no operational/environmental
concerns.
Most fire hydrants and monitors are pressurised dead legs, receiving water from a ring main
(either from seawater system or fresh water onshore). Potential for dosing biocide is very
limited. Chemical cleaning may be allowed if biofouling is severe. Regular, planned high
speed flushing should be implemented where problems are observed.
In nitrite inhibited cooling waters systems of correct concentration (1 000 to 2 000 mg/litre)
SRB should not be detected. If SRB counts are positive, check nitrite, chloride and pH levels
regularly. The main concern with TVC (GHB) is that elevated numbers may result in poor heat
transfer across heat exchangers.
Nitrate-reducing bacteria (NRB) monitoring should be every three months. Check pH,
which should be 8,5 to 10,5. (this pH range should slow down bacterial growth). High NRB
numbers may result in rapid loss of nitrite inhibitor. Drain and clean or add suitable biocide.
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I.5.8 CHECK
Biocide batch dose injection, frequency duration and concentration vs. plan, where
appropriate e.g. water injection and produced fluids.
Planktonic and sessile TVC (also called GHB) and SRB (SRP) counts vs. targets. Table 7 in
IP Document titled Guidelines for the management of microbially influenced corrosion in
oil and gas production provides MIC risk/criticality guidelines based on extinction dilution
technique for bacterial counts as per NACE TM0194 (2014) for different oilfield fluids, such
as water injection, firewater, cooling systems, produced fluids and drains.
Other, molecular, techniques such as quantitative polymerase chain reaction (QPCR) and
Fluorescence in situ Hybridisation (FISH) may also be used.
In addition, any change in the operating status of oilfield water systems should be used to
help understand whether the MIC threat has increased or decreased.
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The investigation will be in accordance with the CM strategic plan which may be part of a
wider Integrity Management Plan.
The root cause of excessive MIC may be due to the primary factor, i.e. failure of treatments to
control or it may be due to secondary factors such as solids and scales, which make biocide
treatment more difficult.
I.5.9 ACT
Determine if existing MIC control measures are achieving the necessarily low levels of MIC
and whether improved monitoring is required.
Capture and roll-out lessons learned based on the outcome of performance review.
I.6.1 Introduction
Historically, the management of dead legs on an installation has been problematic, primarily
because of the large numbers of dead legs that usually exist. Guidance is provided here for
identifying and managing internal corrosion of dead legs in hydrocarbon production. The
objective is to outline methods, which can be used in conjunction with the RBI procedure,
primarily to:
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−− Assess the probability for the occurrence of dead leg corrosion which can then be
utilised within the risk matrix to establish the overall risk of dead leg corrosion.
−− Mitigate the risk of dead leg corrosion.
A dead leg is a section of pipework or vessel which contains hydrocarbon fluids and/or
water under stagnant conditions (either permanently or intermittently), or where there is no
measurable flow. More precisely, a dead leg is any segment of piping extending below the
horizontal plane of the pipe which can become a trap for water, sediment or other corrosive
materials. Furthermore, a broad definition of a dead leg includes dead ends, which refer to
piping that does not extend below the horizontal plane of the pipe yet contains stagnant
fluids.
The following also need to be considered as dead legs or potential dead legs:
−− lines from vessels or piping to PSVs (normally closed), and
−− instrument tappings/connections.
Drains pipework at
the base of vessels
Pipework sections used intermittently A section of pipework not in the Pipework sections upstream or
e.g. bypass lines and non-operating normal flow, but which cannot be downstream of a closed valve
sections of spaded equipment isolated from the normal flow e.g. where the intention is to keep the
obsolete lines valve closed
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Some systems are by the nature of their mode of operation (no flow/slow flow/intermittent
flow) more susceptible to dead leg corrosion and these should be considered to be 'dead leg
systems' e.g. drains, firewater, recovered oil and relief lines.
Examples of dead legs are illustrated in Figure 36. The key causes of corrosion in dead legs
are:
−− Bacteria, usually SRB, which proliferate in stagnant, oxygen-free water where appropriate
nutrients are available. They oxidise organic components in water and reduce sulfate ions
to produce hydrogen sulfide as part of their metabolism. These processes are discussed
in Annex I.5.
−− Under-deposit corrosion caused by the presence of sand or corrosion products and
where the mechanisms can vary.
In oxygenated systems, anodic areas can exist under deposits due to differential aeration. In
production systems, a number of factors can be involved, such as locally high acidity within
pits and the reduced ability of inhibitors to penetrate deposits:
−− Depletion of CIs over time leading to loss of protection.
−− In systems containing a gas phase and water, water condensation may occur in dead
legs if the temperature is lower than the process. This condensed water will contain
any corrosive species from the process, e.g. CO2 and organic acids, but will generally
not contain treatment chemicals such as CIs.
Operational dead legs frequently exhibit greater degradation rates than permanent dead legs
for the following reasons:
−− bacterial and nutrient replenishment;
−− warming, which increases bacterial activity and corrosion rates, and
−− replenishment of cathodic reactants such as oxygen and CO2.
Conversely, some operational dead legs may also have a regular supply of treatment chemicals.
I.6.2 PLAN
I.6.2.1 Policy
As a matter of policy, the Duty Holder/Operator should seek to assure the continued integrity
of all sites with the aim of minimising risk to personnel, environment and business from the
threat of dead leg corrosion.
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I.6.2.2 Planning
The strategy by which the objectives of the policy can be achieved may be divided into a
number of discrete areas:
−− elimination/reduction of the risk through removal of any unnecessary dead legs;
−− identification of pipework/locations at risk;
−− mitigation of the threat (flushing and chemical treatment);
−− prioritisation of inspection activity: based upon consequences of failure and
probability of dead leg corrosion, and
−− definition of inspection scope: type of inspection, coverage and frequency.
I.6.3 DO
Dead legs exist in all process systems. Some systems have demonstrated that they have a
more significant threat of dead leg corrosion than other systems. Where large numbers of
dead legs have to be managed, it is important that the appropriate resource is applied to
these high threat systems, particularly when the consequence of failure is also high.
It may therefore be useful to carry out an initial assessment at a general facilities level, to
ensure systems which are particularly susceptible to dead leg corrosion are identified. This
prioritisation should give a high weighting to the 'probability' of dead leg corrosion.
Guidance on susceptibility of systems to dead leg corrosion is provided in Table I.1. This
information is based on experience from three facilities in the North Sea sector.
Table I.1: Guidance for assessment of probability for dead leg corrosion to occur
Potential dead legs should initially be identified using the latest revision of the P&IDs. Piping
isometrics and fabrication drawings, where available, can be used to provide an indication
of the orientation of the dead leg. In practice, it may be more efficient to establish the
orientation of the dead legs during line-walking, rather than reviewing isometrics.
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The existence and orientation of dead legs should then be confirmed by a competent person
walking the system to check the accuracy and completeness of the listing.
Factors to be considered when assessing the probability for dead leg corrosion to occur
within a given system include:
−− fluid composition – aqueous phase/presence of sulfates/presence of nutrients/oxygen
ingress/possibility of condensation of water;
−− temperature;
−− materials of construction – e.g. CRAs are not immune, but are less prone to dead leg
corrosion than carbon steel;
−− pipe wall thickness (thinner wall pipework may have higher priority);
−− microbial status;
−− deposit potential;
−− operation – stagnant/intermittent/continuous;
−− presence of biocide;
−− presence of CI, and
−− history of corrosion.
Table I.2: An example probability assessment for dead legs in oil-water systems
An accurate record of the dead legs that exist on a facility is required (commonly known
as the dead leg register). This is normally carried out as part of the CRAS for each process
system. Alternatively, it can be carried out as a separate exercise if this is considered more
appropriate.
This register should contain all physical dead legs and, as far as practicable, all operational
dead legs. Typically, this would be done by system. The record should be maintained as a live
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document throughout the life of an installation and updated to reflect both physical changes
in the plant and changes in the mode of operation.
The dead leg record should be integral with, or linked to (either electronically or by a process)
the inspection database.
I.6.3.2 Organisation
Organisational roles that can be involved in the management of dead legs include:
−− Corrosion and Materials Specialists;
−− Microbiological Specialists;
−− Process Engineers and plant operators;
−− Production Chemists, and
−− Inspection Engineers and NDT contractors.
Process engineers and plant operators should assist in identification of dead legs and those
dead legs which are not normally flowing and/or are mothballed.
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Activity for the management of dead leg corrosion should be included in CMS audits.
I.6.4 CHECK
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In addition, any change in the status of dead legs should be used to help understand whether
the MIC threat has increased or decreased.
The dataset identified under leading performance indicators will provide assistance to the
corrosion engineer in understanding whether the MIC threat associated with dead legs is
under control.
The investigation will be in accordance with the CM strategic plan which may be part of a
wider integrity management plan.
The root cause of dead leg corrosion may be due to the primary factor, i.e. failure of treatments
to control or it may be due to secondary factors such as accumulation of deposits, which
make chemical treatments more difficult.
I.6.5 ACT
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I.7.1 Introduction
Galvanic corrosion can occur at the junction of dissimilar metals coupled together in a suitable
electrolyte, typically an aqueous environment or a wet atmosphere where oxygen is present.
The more noble metal (cathode) is protected by sacrificial corrosion of the less noble metal
(anode). The anode corrodes at a higher rate than it would if it were not connected to the
cathode. The relative exposed surface areas of the anode and cathode also have a significant
effect – the corrosion rate of the anode can be high if there is a small anode-to-cathode ratio.
Internal galvanic corrosion is a particular concern in aerated seawater systems which are
particularly susceptible due to high levels of oxygen, chlorine and iron in the water. Production
systems exposed to a water phase may be less susceptible due to the absence of oxygen
and if the production water has lower conductivity than seawater. Dry gas systems are less
susceptible due to the lower proportion of water present and generally low conductivity of
any electrolyte present.
External corrosion is exacerbated in bimetallic couples, for example, dissimilar metals flange
connections, CS bolts in stainless steel or CRA flanges. The severity of the environment
depends upon climatic conditions; it is low in dry or low-humidity regions, moderate in
temperate and semi-arctic regions and in open rural locations, and high in regions with high
humidity such as tropical and marine locations and also in polluted industrial atmospheres.
In addition to the factors mentioned, others will need to be taken into account:
−− resistance to ionic current flow of the electrolyte.
−− resistance to current flow (by electron conduction) in the conducting materials and
the quality of the connection between them, and
−− the polarisation resistance of both the anode and the cathode.
The severity of galvanic corrosion when two dissimilar metals are in contact will depend upon
the following factors:
−− Electrode potential.
The potential of any alloy, even in seawater, can be changed by a variety of factors
such as temperature, velocity, chemical treatment etc. However, the relative ranking
of alloys usually remains unchanged by these factors.
−− Electrode polarisation.
Depending on the particular metals and the environment, electrode polarisation is
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the magnitude of the shift in the potential of the anode to a more electropositive
value and the cathode to a more electronegative value.
−− Variable potential.
The corrosion potential of an individual metal can change and, in certain circumstances,
the polarity of the galvanic couple can change. This is mainly affected by changes in
pH, temperature and whether oxygen is present.
−− Environment.
Factors relating to the electrolyte (water) such as pH, chemical composition,
conductivity and the dissolved oxygen content will affect galvanic couples.
−− Area ratio.
The corrosion rate of an anode will be higher when coupled to a cathode with a
relatively larger surface area.
−− Aeration and flow rate.
In aerobic aqueous solutions where the cathodic reaction is controlled by the
reduction of dissolved oxygen, the reaction rate will depend on the rate of diffusion
of oxygen from the bulk solution to the metal surface. Therefore, both the reactant
concentration and flow rate (transport to the surface) will affect severity and extent
of bimetallic corrosion in the same way as single metal corrosion.
−− Metallurgy.
Differences in specific mechanical properties between nominally similar coupled
metals or alloys can arise from cold working and heat treatment, for example,
resulting in galvanic behaviour.
In weldments, local changes in chemical composition at the weld bead and the heat
affected zone of the parent metal can lead to galvanic corrosion. The specific issues
relating to weldments are described further in Annex I.8.
Alloys of a common type can have differing composition; thus 90/10 cupronickel can
be anodic to 70/30 alloy and austenitic stainless steels are cathodic to the martensitic
stainless steels.
−− Exposure time.
The corrosion rate of both coupled and non-coupled metals/alloys generally decreases
with exposure time due to:
– a reduction in oxygen diffusion through both electrolyte and any corrosion
product present thus limiting the cathodic reaction;
– the corrosion product protecting anodic areas on the metal surface, and
– the development of magnesium and calcium containing calcareous deposits
on the surface of the metal may offer a degree of corrosion protection thus
decreasing the rate of galvanic corrosion.
In contrast, where corrosion products are water-permeable, the rate of galvanic
corrosion can increase because wet conditions are maintained at the surface and can
be more aggressive than the bulk environment.
The development and permeability of corrosion products on the surface of dissimilar
metals in contact can lead to a reduction in coupled corrosion rate over time.
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Figure I.19: Galvanic corrosion between a copper and carbon steel galvanised pipe
connected by a dielectric union
Although the magnitude of the potential difference alone is not enough to determine
the probability of galvanic corrosion to occur, as a rule of thumb, the galvanic potential
difference between two dissimilar metals in contact, in a severe environment such as
offshore/marine, should not exceed 0,15 V. For a normal ambient environment such as a
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Most seawater resistant grades of stainless steels and Ni-Cr-Mo alloys can be considered
compatible with each other but any of them will promote galvanic corrosion on less noble
alloys such as cupro-nickel and monel; all CRAs will promote corrosion of CS.
Connection of CS to titanium alloys should also be avoided where a risk of galvanic corrosion
or hydrogen charging of the titanium alloy may occur e.g. titanium alloy heat exchangers
(tubes and tubesheets) combined with coated CS (e.g. a water box). Any holidays or defects
in coatings on CSs will result in very high penetration rates of the steel.
I.7.2 PLAN
I.7.2.1 Policy
Safety, environmental and commercial policies influence the choice of strategies for mitigation
and monitoring/inspection.
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−− Visual inspection and UT can be used to detect galvanic corrosion e.g. incorrect bolt
specification in flange.
I.7.2.2 Planning
The CMS plan may be part of a wider Integrity Management Plan and CMS Strategy. For
offshore installations the strategy plan should be in line with the verification scheme. For
onshore plants, inspection schemes will be part of statutory WSoE for pressure systems.
Tactical plans may jointly cover activities relating to other related corrosion mechanisms,
e.g. corrosion under deposit; external atmospheric corrosion.
The plans should be translated into an executable plan and schedule for implementation.
The CMS needs to specify the plan with the activities to be carried out to reduce the identified
risk of galvanic corrosion to ALARP. These activities can include:
−− current mitigation methods;
−− monitoring methods and frequencies;
−− definition of KPIs;
−− anomaly management, and
−− organisational responsibilities for planning, execution, mitigation, monitoring and
reporting.
I.7.3 DO
The probability of galvanic corrosion occurring can be predicted with consideration given to
following factors:
−− dissimilar metals in contact;
−− electrochemical potential difference between the two metals (see galvanic series);
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−− the ratio of area between the two metals (cathode versus anode surface area);
−− presence of coating or cladding;
−− fluid service (wet or dry), corrosiveness, chemical injection, volatiles (dead crude);
−− presence and the conductivity of an electrolyte;
−− temperature, and
−− inspection observations and NDT data analysis.
I.7.3.2 Organisation
All personnel involved should be made aware of the factors affecting preferential weldment
corrosion and be vigilant to recognise the indications of, or changes that are likely to cause,
weld corrosion.
Personnel should respond appropriately to any condition recognised as posing a threat and
rectify the situation through effective communication with the relevant organisations.
The collected data can be plotted to identify any correlations between process conditions,
treatment changes and inspection/corrosion rate trends.
Specialist asset management databases are available to help organise this information.
Corrosion damage reports and maintenance reports should also be stored with the data so
as to be traceable.
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Those data, with the aid of specialist database/tools, should be analysed in order to:
−− trend the uniform or localised corrosion rate;
−− assess if the mitigation implemented is able to reduce corrosion risk effectively, and
−− predict the likely corrosion rate and remaining life of the system or vessel.
I.7.4 CHECK
The RCA of weld corrosion failures or management system failures will be investigated with
the appropriate corrective action(s) recommendation.
The investigation will be in accordance with the CM strategic plan which may be part of a
wider Integrity Management Plan.
I.7.5 ACT
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I.8.1 Introduction
PWC does not affect stainless steels although corrosion is often localised at welds for a variety
of reasons including chemical composition, microstructure, surface roughness and heat tint.
Figure I.21: Severe corrosion at the weldment (deep groove along the weld)
indicating that weld metal preferentially corrodes in CO2 environment
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With manual metal arc (MMA) electrodes, the weld metal is heavily deoxidised resulting in a
fine dispersion of small oxides in the molten metal which act as nucleation sites for acicular
ferrite, which produces a tough final product. These inclusions, together with possible
increases in manganese and silicon, can lead to rapid weld metal corrosion.
With tungsten inert gas (TIG) root runs, the corrosion is often increased due to the
deliberate addition of up to 1 % silicon to the welding wire to ensure adequate weld metal
fluidity. The silicon forms SiO2 inclusions in the weld root which may act as sites for corrosion
to initiate, perhaps by causing weaknesses in semi-protective corrosion product films.
An arbitrary 1 % Ni limit was set in accordance with NACE MR01-75 Materials for Sour
Service. These recommendations have also been applied to sweet systems. 1 % w Ni-
containing weld consumables should be used to minimise the risk of PWC. Although
satisfactory for the majority of applications, there have been instances where severe PWC
has occurred in sweet environments under certain conditions.
A wide variation in composition is possible within any single pipe specification. The
specifications are typically based on mechanical requirements with few compositional
restrictions and this must be considered when selecting the consumable for a particular
application.
Manufacturers of line pipe, primarily using scrap, produce steels which can have significant
levels of residuals, e.g. Ni, Cr, Cu, Mo etc.
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A trend emerged which suggests that the most severe preferential corrosion of Ni weld metal
occurs under wet gas operating conditions, although it has also been observed in oil lines.
It is thought that the effects of high conductivity can limit the 'throwing power' and hence
localise the attack with regard to preferential corrosion of Ni-containing weldments.
I.8.1.6 Seawater
Ni-containing weld metals have been widely used in seawater applications, without selective
attack of the weld metal or HAZ. In seawater, the corrosion rates of both weld and parent
metal are largely controlled by oxygen mass transfer, therefore the inherent corrosion rate
of the weld metal cannot be larger than that of the parent. Under these circumstances,
preferential corrosion of weldments will not occur.
I.8.1.7 Inhibitors
The severity of selective attack on 1 % Ni weldments can only be explained if there is a
large difference between the intrinsic corrosion rates of the weld and parent metals.
Therefore, it is thought that some weldment failures have been associated with under-dosing
of inhibitors.
With sub-optimum dosing and/or a long precorrosion period highly selective attack of the
weld metal can occur.
In both cases, the problem arises from the inability of the inhibitor to protect the weld metal,
while it does protect the parent. This results in the weld corrosion rate being higher than that
of the parent metal and can result in the weld becoming anodic, although galvanic currents
are a comparatively small contribution to the overall corrosion behaviour.
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−− rough surface condition, creating sites for the attachment of biofilms and hence
increasing the risk of MIC, and
−− poor surface profile, creating a stress concentration effect at the weld toe, hence
increasing the risk of SCC.
Heat tint on and adjacent to welds made with inadequate shielding results in reduction
of corrosion resistance of affected areas. Heat tint consists of a heterogeneous oxide
composed primarily of iron and chromium above a chromium-depleted layer of base metal.
The defects, internal stresses and composition of the heat-tint oxide make it a poor barrier
to any corrosive media that might initiate localised corrosion in the chromium-depleted
layer of base metal. There are no universally agreed criteria for what degree of heat tint is
acceptable and whether it should be removed.
I.8.2 PLAN
I.8.2.1 Policy
Safety, environmental and commercial policies influence the choice of strategies for
mitigation and monitoring/inspection. Mitigation strategy options include:
−− Appropriate choice of welding method:
– Welding should be carried out with high rather than low arc energy to give
slower cooling rates around the weld zone with correspondingly softer
microstructural constituents, thus avoiding formation of the harder transformed
structures, bainite and martensite.
– Appropriate choice of filler material, e.g. Ni/Cu containing filler1, matching
consumable or hybrid weldment.
– Avoiding weldments where possible.
– Stringent control of weldment quality, e.g. control of microstructure, weld
dimension, and low porosity.
−− Use of CI2,3.
−− Use of coating3.
−− Use of CP, this however, can lead to HE of weldments3.
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Notes:
−− The use of Ni containing filler materials should be used with consideration given to
the conductivity of the environment.
−− Laboratory testing of the CI with the weldment is highly recommended.
−− Should these mitigations fail or become inadequate, the corrosion of weldments can
be significant.
Note 4:
−− Detection and measurement of PWC by NDT is difficult. UT, RAD and TOFD all have
limitations.
I.8.2.2 Planning
The CMS plan may be part of a wider Integrity Management Plan. For offshore installations
the strategic plan should be in line with the verification scheme.
Tactical plans may jointly cover activities relating to other corrosion threats. Onshore
inspection schemes will be part of statutory WSoE for pressure systems.
The defined strategic plan needs to be translated into a tactical plan and schedule for
implementation.
The CMS plan needs to specify the activities to be carried out to reduce the identified risk of
weldment corrosion to ALARP initially by correctly identifying the risk. Activities can include:
−− mitigation methods;
−− monitoring methods and frequencies;
−− measurable performance targets;
−− immediate action required in event of non-conformance;
−− anomaly criteria and reporting requirements, and
−− organisational responsibilities for mitigation, monitoring and immediate action.
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I.8.3 DO
The probability of PWC occurring can be predicted with consideration given to:
−− the welding procedure used;
−− the type of weld; e.g. CS matching consumable, nominally 1 % Ni weld metal;
−− the chemical composition of the parent pipe and the weld metal;
−− the weldment environment; e.g. flow rates, pH, temperature;
−− the likelihood of scale forming on the weldment surface;
−− the electrolyte conductivity;
−− CI testing using representative segmented weldment electrodes in the simulated
process environment;
−− quantitative predicted corrosion rates for the anticipated mode of corrosion;
−− on-line corrosion monitoring data and results, and
−− inspection observations and measurements.
I.8.3.2 Organisation
All personnel involved should be made aware of the factors affecting PWC and be vigilant to
recognise the indications of, or changes that are likely to cause, weld corrosion.
Personnel should respond appropriately to any condition recognised to pose a threat and
rectify the situation through effective communication with the relevant organisations.
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The collected data can be plotted to identify any correlations between process conditions,
treatment changes and inspection/corrosion rate trends. Statistical analysis can be applied to
enhance the value of NDT data.
Specialist asset management databases are available to help organise this information.
Corrosion damage reports and maintenance reports should also be stored with the data so
as to be traceable.
These data gathered, with the aid of specialist database/tools, should be analysed in order to:
−− trend the weld corrosion rate;
−− assess if the mitigation implemented is able to reduce weld corrosion risk effectively;
−− determine root cause of any process upsets, e.g. CI unavailability due to a broken
pump that resulted in increased weld corrosion rate, and
−− predict the likely corrosion rate and service life of the weldment.
I.8.4 CHECK
The investigation will be in accordance with the CM strategic plan which may be part of a
wider Integrity Management Plan.
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The RCA of weld corrosion failures or management system failures will be investigated with
the appropriate corrective action(s) recommendation.
I.8.5 ACT
I.9.1 Introduction
In water injection systems, grooving corrosion can result from a combination of debris at the
bottom of the pipeline, a loss of microbial control and specific flow dynamics.
As well as being an issue in water injection systems, grooving corrosion has been a
significant cause of degradation in Russian and western Siberian oil pipelines, where it
typically occurs in large diameter horizontal pipelines that carry three-phase oil, gas and
water.
Grooving corrosion is distinct from preferential weld corrosion. PWC is related to metallurgy,
whereas grooving corrosion is a form of erosion-corrosion and therefore better described as
an electro-physical mechanism.
Grooving occurs at, or close to, the 6 o'clock position in pipelines, it may be many centimetres
wide and continue along the pipeline for a number of metres (~12 m) or even for several
kilometres.
In water injection lines, corrosion rates of 1–2,5 mm/y have been observed. In the Siberian
oil pipelines, experimental work determined that rates of attack were typically 4–8 mm/y but
could be as high as 18 mm/y in some instances.
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I.9.1.1 Initiation
The precursors for initiation of grooving corrosion in water injection lines are:
(a) Solids: If filters become blocked or damaged, sand and crustaceans may pass
through because the filter has been bypassed rather than repaired. In addition, solids
may form inside the lines due to inadequate dissolved oxygen control.
(b) Microbial proliferation: loss of microbial control results in proliferation of SRB.
Colonies are established on the internal walls of the pipeline.
(c) Flow dynamics: the flow rate is not sufficiently high to maintain the suspension of
solids in water. Solids may be transported along the bottom of the pipe depending
on the pipeline diameter and the density and size of the solids.
Factors a) and b) largely result from poor management of water injection lines.
The precursors for the development of grooving corrosion in three-phase oil pipelines are
similar:
−− stratified flow;
−− water drop-out in the line;
−− a surface scale/film or microbial film, and
−− solid particles (e.g. sand) present in the process fluids.
I.9.1.2 Mechanism
Grooving corrosion is a combination of erosion and corrosion mechanisms, typically caused
by the localised disruption of surface films/scales by particulate matter continually tumbling
along the bottom of the pipeline. The mechanism for grooving corrosion can be described as:
−− the continuous removal of the protective film and activation of the bare metal
surface, and
−− the formation of an active galvanic couple between the bare metal and the pipe
surface that is covered with the protective film.
The overall process of grooving corrosion can be described in four steps and is illustrated in
Figure I.23 below:
1. Development of Fe3O4, FeCO3, CaCO3, FeS films/scales and/or biofilm resulting from
corrosion, microbial activity or precipitated from free water present at the bottom of
a pipe.
2. Mechanical action of abrasive particulates in the fluids flowing along the bottom
of the pipe eroding the film/scales at the 6 o'clock position due to the flowing
conditions and the abrasive action of particulates at the bottom of the pipeline.
3. Continuous exposure of the bare metal around the 6 o'clock area leads to the
development of a galvanic couple between the bare metal (anode) and the remaining
pipe (cathode) with a ΔE of ~100–200 mV.
4. Accelerated corrosion continues in the grooved region of the pipe due to the effect
of a small anode (groove) coupled to a large cathode (rest of the pipe).
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Figure I.23: The four steps in the formation of groove corrosion: (1) the formation of
films/scales; (2) erosion of film/scale at/near the 6 o' clock position; (3) formation of
a galvanic couple and (4) corrosion attack forming a groove38
The size and depth of the groove will depend upon both flow and pipeline topography.
Higher velocity flow will produce narrow deep grooves and slower flow will produce shallow
and broad grooves. Generally the width and depth of the groove is inversely related; as one
decreases the other increases. This is thought to be due to the reaction driven by the ratio
of the anode-to-cathode area and mass transfer effects of the reactants. Grooves generally
form in horizontal spools, although grooving has been known to occur in vertical risers.
External UT survey can be used to identify areas where grooving in a pipeline is likely to occur
based on predictive modelling.
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Flow Assurance can be used to determine whether grooving has occurred in a pipeline; it
cannot determine the exact location, rate or extent of attack.
The expected topside and well pressures are predicted using flow assurance modelling.
If the actual measured pressures deviate from the predicted values this can indicate the
development of grooving corrosion. Depending on the flow rate, a reduction in the expected
pressure can result from increased volume in the pipeline, indicating that a channel is present.
Conversely, increased well pressure can occur as a result of debris build-up.
I.9.1.4 Mitigation
In general, pipelines that have been managed well throughout their life, i.e. equipment
maintained in good working order, appropriate chemical treatment, frequent cleaning pig
and biocide treatments etc., tend not to succumb to grooving corrosion.
Once grooving corrosion manifests, it will continue to propagate even if effective mitigation
measures are introduced, albeit at a slower rate.
The recommended actions in order to avoid the initiation of grooving corrosion include:
−− a strategic microbial survey regime to monitor the effectiveness of the chemical
control programme;
−− maintain sessile and planktonic populations to <102 cells per cm2 to control the
threat;
−− dissolved oxygen (DO) concentrations should be limited in the range 5–10 ppb and
monitored continuously, and
−− particulate solids should be controlled by fine filtration of seawater.
I.9.2 PLAN
I.9.2.1 Policy
Safety, environmental and commercial policies influence the choice of strategies for mitigation
and monitoring/inspection.
I.9.2.2 Planning
The CMS plan may be part of a wider Integrity Management Plan. For offshore installations
the strategic plan should be in line with the verification scheme.
Tactical plans may jointly cover activities relating to other corrosion threats. Onshore
inspection schemes will be part of statutory WSoE for pressure systems.
The defined strategic plan needs to be translated into a tactical plan and schedule for
implementation.
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The CMS plan needs to specify the activities to be carried out to reduce the identified risk of
grooving corrosion to ALARP. Activities can include:
−− monitoring methods;
−− measurable performance targets, and
−− organisational responsibilities for mitigation, monitoring and immediate action.
I.9.3 DO
The probability of grooving corrosion occurring may be assessed with consideration given to
the following:
−− the flow regime;
−− the presence of a surface film/scale;
−− solid particles in the process fluids;
−− inspection observations and measurements, and
−− monitoring data.
I.9.3.2 Organisation
All personnel involved should be made aware of the factors affecting grooving corrosion and
be vigilant to recognise the indications of, or changes that are likely to lead to, it.
Personnel should respond appropriately to any condition recognised to pose a threat and
rectify the situation through effective communication with the relevant organisations.
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Specialist asset management databases are available to help organise this information.
Corrosion damage reports and maintenance reports should also be stored with the data so
as to be traceable.
These data should be analysed in order to assess if the mitigation implemented is able to
reduce the grooving corrosion risk effectively.
I.9.4 CHECK
The investigation will be in accordance with the CMS plan which may be part of a wider
integrity management plan.
The RCA of grooving corrosion failures or management system failures will be investigated
with the appropriate corrective action(s) recommendation.
I.9.5 ACT
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I.10.1 Introduction
The term 'flange face corrosion' (FFC) is used to describes the internal corrosion occurring
on the flange faces of pressure system components. It is conceivable that FFC could arise
from the external environment; however, this is very rarely the case and the discussion
in this management guide is restricted to FFC arising due to the internal pressure system
environment. The external corrosion of flanges and flange bolting is addressed in I.11.
The FFC mechanism is similar to crevice corrosion and tends to remain undetected until
the flange is dismantled to allow internal access to the pressure system or when corrosion
damage progresses to the point of failure and a leak occurs.
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Figure I.25: Flange face corrosion revealed following breaking of the flange joint
and surface cleaning
Seawater systems are particularly prone to FFC due to the corrosivity of the medium (i.e.
oxygenated seawater) in contact with the internal surfaces of the flange. CS sections of
seawater systems, such as coarse seawater filters and pipe spools, are typical locations that
are prone to FFC.
Mitigation measures used to eliminate and/or reduce the occurrence of FFC include internal
coating of rebated flanges, weld overlaying sealing areas of flange faces with high Ni-
containing CRA metal, correct selection of gasket and retaining ring types, external protection
of flanges to avoid water ingress.
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In recent years NDT inspection has taken great strides, amongst others in the development
of advanced Phased Array UT (PAUT) inspection technique. The development of PAUT for
flange face inspection has enabled FFC to be detected from external surfaces without the
need to split the flange; the technique has been demonstrated on piping flanges from
as small as ¾". The main restriction to the flange face coverage of the technique is the
restricted access to the flange surface due to the presence of the bolt heads and nuts; this
restriction often prevents 100 % inspection of the flange face.
I.10.2 PLAN
I.10.2.1 Policy
The Duty Holder/Operator should manage the continued integrity of all sites with the aim of
minimising risks to personnel, environment and business from the threat of FFC.
The Policy should cover all integrity risks and should provide direction in many areas of
corrosion risk management, amongst these FFC.
Including FFC in the Integrity Management Policy and therefore having a systematic approach
to managing and mitigation against the mechanism will not only improve the integrity of the
site, but also contribute to improved uptime of the facility. FFC that goes undetected until
a leak occurs, or if the mechanism is found unexpectedly in a turnaround (shutdown), may
result in extensive plant unavailability and consequently significant commercial loss.
I.10.2.2 Planning
The CMS plan may be part of a wider Integrity Management Plan. For offshore installations,
the strategic plan should be aligned with the verification scheme. For onshore processing
facilities in the UK, the inspection scheme for the pressure equipment is part of statutory
PSSR WSoE.
Tactical inspection plans for FFC may jointly cover activities relating to other corrosion threats.
The planning of the activities required to initially determine the process systems risk of FFC
and subsequently determining suitable mitigation and inspection activities is key to achieving
the requirements of the CMPy.
The activities that are required to be carried out may be divided into discrete areas:
(a) Elimination/reduction of the risk, through:
– the use of gasket/insulating material compatible with the base flange material
and the process fluids;
– regular monitoring via inspection of the flange to monitor ongoing integrity of
the flange joints, and
– and by specifying and using correct torqueing procedures.
(b) Identification of equipment at risk, through:
– screening of flanges to a predefined set of rules that identify the risk criteria, and
– creation and maintenance of a disturbed flange register.
(c) Prioritisation of inspection activity based on:
– consequences of failure, and
– system history.
(d) Definition of inspection scope, detailing:
– type of Inspection;
– frequency of inspection, and
– activities to be implemented as part of flange dismantling.
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Both planned and opportunistic inspections should include the inspection of flange faces
where possible, especially for systems where a significant threat of FFC has been identified.
I.10.3 DO
The FFC threat will normally have a number of line items in the CMS plan matrix to specify:
−− mitigation methods;
−− performance standards;
−− monitoring methods and frequencies, and
−− immediate action required on non-conformance.
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I.10.3.2 Organising
Organising the activities and assessments required for the management of FFC is a multi-
discipline responsibility and will need all areas of the plant organisation to work together
both in terms of making resources available and in terms of ensuring roles and responsibilities
are well understood and communicated.
Organisational roles that are normally required to be involved in the management of FFC
include:
−− Corrosion and Materials Specialists;
−− Process Engineers;
−− Plant operators;
−− insulation materials suppliers and applicators;
−− Facilities Maintenance teams;
−− Inspection Engineers and NDT contractors;
−− Structural and Mechanical Engineers, and
−− Piping Engineers and piping designers.
It is possible that the inspections may need to be brought forward or pushed out, to fit with
other planned works; however, the implications of such delays for flange integrity must in
each case be understood and addressed.
The outcome from the application of this strategy will be a rolling programme of flange
inspections scheduled within the maintenance management system (MMS).
The implementation of a mechanical flange break inspection campaign should provide for
flange face repairs according to approved procedures, e.g. welding or coating resurfacing
undertaken according to system requirements and within the installations work permit
system requirements.
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I.10.4 CHECK
All Integrity Management systems set up for the facility shall include ways of measuring
performance of the activities being carried out, in this case, the FFC management.
The investigation will be in accordance with the CMS plan which may be part of a wider
Integrity Management Plan.
The RCA of FFC failures or management system failures will be investigated with the
appropriate corrective action(s) recommendation.
I.10.5 ACT
I.11.1 Introduction
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equipment (including pipes, valves, bolted flanges, vessels) and mechanical equipment
(including cranes, turrets etc.) on offshore installations and onshore upstream terminals.
Although the threat is important for CSs certain threats also apply to CRA and aluminium
alloy structures.
External corrosion is a form of oxygen corrosion. General corrosion will occur where surfaces
are continuously or intermittently wetted with aerated water. However, higher localised losses
occur due to differential aeration effects in which a corrosion cell is set up between corroding
(anodic) areas that are depleted in oxygen and (cathodic) areas rich in oxygen due to their
proximity to the air/water interface. Airborne salt contamination can increase corrosivity and
the tendency for pitting.
Classically differential aeration can occur between the corroding centre of a water droplet
and the edges that are in contact with the air. Various forms of crevice corrosion are
generally the most damaging. Corrosion occurs preferentially inside the crevice where there
is oxygen depletion. A crevice is formed, for instance, where pipe is held against a support,
where grating is set in an angle frame, where labels and signs are attached, where bolts
pass through bolt holes, etc. A crevice can also form at the edge of a coating where it has
broken down and this is the primary cause of rusting when coatings deteriorate. Steel with
thick and strong coatings may be more susceptible to corrosion under coating due to more
severe corrosion occurring in a deepening edge crevice between the damaged coating and
the sub-straight, under-rust, compared to areas with thinner and weaker coating where the
coating may readily break back to a new edge.
Where rust films form, such as in a water droplet or at a coating edge, the moisture-saturated
rust can form a site for further localised corrosion due to the oxygen depletion beneath it.
This leads to the formation of rust scabs.
Stainless steels, whilst generally more resistant, can still suffer localised corrosion where
oxygen is absent such as in crevices or under deposits. At temperatures over about 40 °C in
combination with salt contamination, stainless steel items under stress can fail by SCC.
Generally, marine atmospheric external corrosion rates are quite low, i.e. not more than
0,2 mm/yr; however, some conditions cause much higher rates, even up to 1,0 mm/yr. These
include:
a) Continuous exposure to salt water, e.g. from deluge systems, from overhead leaks
and in splash zones. The highest rates are found on hot risers in the splash zone, and
where salt water leaks onto hot pipes.
b) Where water is trapped particularly where the water is hot or salt laden.
c) Leaks of more corrosive fluids impacting the steel surface, e.g. dripping well treating
acids, anti-scale treatment chemicals.
Where the condition for external galvanic corrosion exists this can significantly increase the
local corrosion rate as identified in b) and described in I.7.
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Figure I.26: External corrosion of a pipe at a pipe support. Both the pipe and the
support are corroding at the crevice formed between the two. The coating is also
breaking back as it under-rusts in the crevice at the edge
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I.11.2 PLAN
I.11.2.1 Policy
The strategy employed for managing atmospheric external corrosion will be influenced by
the company Safety, Environmental and Commercial policies. The company policies will
greatly influence the choice of strategies for mitigation and monitoring/inspection deployed
in relation to atmospheric external corrosion.
I.11.2.2 Planning
The CMS plan may be part of a wider Integrity Management Plan. For offshore installations,
the strategic plan should be in line with the verification scheme. For onshore UK facilities, the
inspection plan shall be described in the statutory WSoE as defined in PSSR.
The Strategy may be determined during design stage taking into account life cycle cost.
Organic coatings and low alloy steel, together with attention to design details, is the most
common approach (see J.2 for more information). Metallic coatings and use of resistant
materials are mainly used for situations where safety risk dictates, or the lifetime cost justifies,
the choices. Composites and aluminium are often employed for weight reduction as well as
corrosion avoidance.
Coating maintenance is a 'high ticket' item in maintenance budgets and the strategy may
attempt to find an optimum between coating maintenance cost and repair and refurbishment
cost, where safety and environmental considerations allow.
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Whilst the coating on a steel structure is in reasonable condition, the strategy may focus
on coating condition and on coating maintenance. Later, where the coating is allowed to
break down, or be seen to be breaking down, the strategy shall address options and risk
associated with deferring coating maintenance and allowing corrosion to occur where there
is an effective corrosion allowance (ECA). Where ECA is considered, it must be noted that
similar items in the same structure may have a variety of ECAs due to varying structural
utilisation. Pipework and vessel corrosion allowances are generally provided to allow for
internal corrosion and the ECA for external corrosion (if any) depends on the actual internal
corrosivity.
Where corrosion has already occurred due to coating degradation the strategy will need to
concentrate on the remaining substrate condition and on determining fitness-for-purpose,
followed by suitable mitigation to restore protection or implementing repair, as appropriate.
Where painting maintenance has been extensively deferred and potential corrosion damage
to the substrate is widespread, structural, piping and operational discipline experts shall be
consulted to assist with considerations of the consequences of failure as well as prioritisation
of the mitigation choice. Aim to minimise damage to grating supports as replacement/repair
requires considerable effort.
I.11.3 DO
Published exposure trials will rarely match the user's conditions closely. Coating performance
is dependent on a large range of factors. Judgement is required in adopting appropriate
values.
The atmospheric corrosion threat will normally have several line items in the CMS plan matrix
to specify:
−− mitigation methods;
−− KPIs;
−− monitoring methods and frequencies;
−− immediate action required on non-conformance, and
−− organisational responsibilities for mitigation, monitoring and immediate action.
Particular consideration shall be given to light section structures (e.g. grating, floor plating,
hand railing, enclosures) and thinner wall small bore piping, all of which may have a safety
critical function.
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It should be noted that UK Health and Safety legislation requires work equipment to be
'maintained in an efficient state, in efficient working order and in good repair'. If the
integrity of a structure is tolerant to the maximum amount of corrosion loss that might
occur over its life, then a strategy to omit coating maintenance may be considered, although
it should be borne in mind that such strategies may be challenged by the UK Regulator,
who may seek demonstration that all reasonably foreseeable risks arising from such an
approach have been identified and are being managed to ALARP. Furthermore, factors such
as possible alternative use, life extension, unacceptable appearance and safety threats from
falling corrosion product should be considered.
Unless a degree of metal loss is acceptable, monitoring frequencies must allow coating
deterioration to be trended so that maintenance occurs before metal loss is structurally
significant.
Tactical plans may jointly cover activities relating to other corrosion threats. Proprietary
database driven risk based methodologies for coating maintenance programme planning
exist and may be utilised to develop overview of a facility's coating condition and to run
maintenance and repair scenarios to optimise the fabric maintenance benefit and spend.
Onshore inspection schemes will be part of the statutory WSoE for pressure systems
under PSSR.
If risk based approaches are used the consequences of failure must include consideration of
the loss of function of structural items such as loss of escape routes, hazards from dropped
objects and loss of positive pressure capability of enclosures.
I.11.3.2 Organising
Organising the activities and assessments required for the management of external corrosion
is a multi-discipline responsibility and will need all areas of the plant organisation to work
together, both in terms of making resources available and in terms of ensuring roles and
responsibilities are well understood and communicated.
Organisational roles that are normally required to be involved in the management of flange
face corrosion include:
a) Corrosion and materials specialists.
b) Coating materials suppliers and applicators.
c) Specialist contractors for coating maintenance planning.
d) Facilities maintenance teams.
e) Inspection Engineers and NDT contractors.
f) Coating Inspection technicians.
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a) and c) lead on risk assessment, planning and analysis; d) leads on mitigation implementation
with support from b); e) leads on metal loss measurement and visual assessment; f) leads
on coating condition survey; e) and (g) work on defect assessment.
Either specialist personnel or the inspection team may engage in coating condition evaluation
but in either case appropriate training should be provided. The coating maintenance
contractors may provide the training.
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External corrosion trends are usually followed on a qualitative basis although coating
breakdown data can be trended more quantitatively.
Trending coating breakdown allows the point of corrective action to be forecast allowing
coating maintenance to be planned for in advance. This prevents metal loss occurring if a
backlog of work is created.
I.11.4 CHECK
The strategic plan should give performance targets for coating deterioration limits.
The investigation will be in accordance with the CMS plan which may be part of a wider
integrity management plan.
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The RCA of external corrosion failures or management system failures will be investigated
with the appropriate corrective action(s) recommendation.
I.11.5 ACT
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have resulted in the coating on the pipe being removed prior to welding or burned-
off during the welding process, the pipe wall is particularly exposed.
Figure I.29: Top coat breakdown, enhanced corrosion under pipe support (clamp)
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Acceptance criteria:
Degree of rusting, Ri4 (BS EN ISO 4628 Part 3) is normally identified as the point where
action is required to plan for coating maintenance. Failure to carry out coating maintenance
at this point may lead to excessive metal loss and/or to more extensive preparation and
painting. The resulting build-up of maintenance backlog can be so great that it is not
possible to restore the facility's fabric to the required state within its remaining life.
Where corrosion has occurred due to coating degradation the strategy will need to
concentrate on substrate condition and on determining fitness-for-purpose and then on
restoring protection or requiring repair, as appropriate. Design codes and fitness-for-purpose
methods (e.g. API 579) can be used for piping and vessels. Structural analysis should be
used to determine the fitness of primary structure. Where painting maintenance has been
extensively deferred and potential corrosion damage to the substrate is widespread, it may
be necessary to adopt a risk based approach to survey and assessment and to prioritisation
of repair that brings considerations of the consequences of failure into play. Deferment of
repair or replacement requires a demonstration that such plant and equipment will remain in
a safe condition until the rescheduled maintenance activity is completed. As a minimum, the
demonstration should include:
−− Physical assessment of the extent of the degradation including area and depth.
−− Engineering assessment of the suitability of the corroded member for the intended
service including upset/extreme event condition. This should be in accordance with
recognised standards.
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For safety critical items consideration may be given to verification by the ICP.
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Care should be taken when inspecting corroded and damaged grating and handrails which
may be insecure especially if testing strength by pushing on/pulling on items.
Acceptance criteria:
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support the maximum expected load. Criteria can be found in various standards
(e.g. NORSOK standard C-002) and in manufacturers' documentation, as well as
developed from design principles.
−− If a qualitative approach is used, the extent of deterioration should be categorised to
a set of standard condition descriptions and corrective action taken according to a
sufficiently conservative set of rules.
In addition:
−− Handrails, stanchions and infill mesh surfaces should not have degraded to such an
extent that people could suffer punctures or lacerations, and/or lead to snagging of
clothing.
−− In addition to a. and b., for pedestrian traffic, the deflection of floor panels under the
design load shall not exceed 10 mm or 1/200th of the span, whichever is the lesser.
The difference in level between a loaded and a neighbouring unloaded flooring shall
not exceed 4 mm (BS4592-0:2006).
−− Grating tread corrosion or deformation should not be allowed to let large objects
drop through and present a hazard to those working below. A 20 mm ball can be
used to test openings.
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Detailed offshore survey to confirn fitness for purpose of grating/tread system and
quantify panels/treads/support steelwork to be replaced
Determine load carrying capacity based upon Determine load carrying capacity based upon
estimated condition by replacement date [Note 3] estimated condition by replacement date [Note 5]
235
than actual load than actual load
requirements for this requirements for this
area? [Note 4] area?
Yes No Yes No
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Grating is OK steel grating panel or stair tread for required to ensure integrity
structure is OK
replacement of supporting steelwork
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Notes:
1. For corroded grating panels or treads, break off loose corrosion product and obtain
thickness measurements at the worst spots on at least two load bearing bars local
to mid-span and near the supports. Determine average indication of remaining
thickness based upon these measurements. The thickness of the load bearing bars
should be measured using Vernier calipers.
2. With loss of protective coating, default steel corrosion rates (for the UK N Sea) can
be used as follows: (a) external walkway/deck, above main deck, 0,20 mm/yr,(b)
internal naturally ventilated modules, 0,10 mm/yr, (c) internal fully enclosed modules,
0,05 mm/yr.
3. As an example, the following tables provide an indication of the safe load carrying
capacity of a typical rectangular pattern grating for various bar thicknesses and spans.
The tables are based upon a grating with 40 mm deep load bearing bar at 40 mm
centres and with a serrated top surface. The loads take into account a deflection limit
of span/200 or 10 mm, whichever is less.
4. The operator must ensure that the assessment that is used, and any safe load tables,
are appropriate for the grating actually in use and in any event approved by the
operator's engineering authority. Note: minimum acceptable thickness of a load
bearing bar is 2,0 mm, despite a panel's span and loading criteria.
5. Generally, grating used for walkways with no wheel loads is designed for a uniformly
distributed load of 5 kN/m. Concentrated loads may need to be considered for
specific areas where machinery or other items could be placed on the grating.
6. The load carrying capacity of all steel support structures should be calculated where
the metal loss exceeds 1 mm or 10 % of wall thickness, whichever is the less.
Table I.4: Concentrated load (kN) applied over area of 300 mm × 300 mm
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Table I.5: Maximum lateral load (kN/m) for 48,3 mm diameter post (material
grade 43A, Fy = 275 N/mm2)
Table I.6: Maximum lateral load (kN/m) for 1,5-inch NB schedule 40 post (48,3 OD ×
3,7 WT, Fy = 240 N/mm2)
Notes:
For corroded handrail panels, break off loose corrosion product at the critical locations and
obtain an estimate of the remaining wall thickness. The thickness of the handrail post, etc.
can be obtained directly using an ultrasonic thickness gauge or else indirectly using digital
calipers to measure the diameter and then estimating the thickness assuming negligible
internal corrosion.
Tables I.5 to 8 provide an example of the lateral load carrying capacity of handrails based
upon a range of post spacings and various levels of corrosion at the base of posts or at the
sockets for removable types of handrails. The operator must ensure that the assessment that
is used, and any safe load tables, are appropriate for the handrailing actually in use and in
any event approved by the operator's engineering authority.
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Table I.7: Maximum lateral load (kN/m) for 60,3 mm diameter socket (material grade
43A, Fy = 275 N/mm2)
Table I.8: Maximum lateral load (kN/m) for 2-inch NB schedule 40 socket (60,3 OD ×
3,9 WT, Fy = 240 N/mm2)
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Is
capacity
greater than
actual load
requirements for
this area?
NO YES
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Safe working load (SWL) for grating based on calculation or supplied by manufacturer.
P1 Replace panel immediately or otherwise make area safe (e.g. overlay scaffold boards,
barrier-off areas etc.).
P2 Plan to replace grating in six-month time frame. Carry out follow-up inspection of all areas
at six-month intervals to assess further deterioration.
P3 Plan to replace within twelve months. Carry out follow-up inspection of all areas at
six-month intervals to assess further deterioration.
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P1 Replace section immediately or otherwise make safe area (e.g. scaffold pole strengthening,
barrier-off area, etc.). Where handrail cannot be immediately replaced corrective action should be
completed within three months. Repair panels and replace clips immediately or make area safe.
P2 Plan to replace handrail within six months. Carry out follow-up inspection of all areas at
six-month intervals to assess further deterioration. Carry out local repair to the corroded area.
Fit new cuff links as soon as possible.
P3 Plan to replace within twelve months. Carry out follow-up inspection at six-month intervals
to assess further deterioration.
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P1 Make ladder safe (e.g. barrier-off ladder, erect alternative access using scaffolding etc.).
Corrective action should be completed within three months.
P2 Corrective action should be completed within six months. Carry out follow-up inspection
of all areas at six-month intervals to assess further deterioration.
P3 Corrective action should be completed within 12 months. Carry out follow-up inspection
of all areas at six-month intervals to assess further deterioration.
I.11.6.3 Bolting
A typical oil and gas installation contains a very large number of bolted joints in the structural
members, mechanical plant and process plant. Management of joint integrity over the life of
an installation is crucial for the SCEs which includes management of bolt corrosion. Allowing
bolts and nuts to corrode leads to:
−− increased risk to personnel from working with seized bolts;
−− increased maintenance time, and
−− affects plant and structural integrity.
From light to heavy corrosion. Studs can lose thickness and thread form. Nuts can lose shape
through corrosion of the flats.
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Implement a risk based CMS based on identification of the likelihood of bolt corrosion and
the consequence of bolted joint failure. For pressure systems this should form a part of the
bolted joint integrity management system as outlined in EI Guidelines for the management
of the integrity of bolted joints for pressurised systems47.
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−− Coatings (hot dip galvanised or zinc/nickel coated – best with service of up to eight
years). Structural bolting is normally covered in the same coating system as the main
structure and if maintained can have a very long life.
−− Bolt material (stainless steel is clearly better than low alloy steel although the former
is expensive and more likely to fail through SCC in appropriate conditions).
−− Flange material (in particular low alloy steel bolts in contact with stainless steel
flanges).
−− Diameter of bolts (smaller diameter bolts are likely to fail earlier through corrosion
than larger diameter bolts).
Bolt preservation systems consisting of applying two pack system of inhibited grease or
covering with plastic caps or wrapping in Denso tape have been used with varying success.
Performance of plated and galvanised bolting can also be significantly improved if coating
is also applied. Applying a multi-coat paint system has also proved successful. In order to
prevent water ingress from flange faces some Duty Holder/Operators now require the joint
to be sprayed with inhibited oil and sealed with Denso tape.
Several systems for flange and bolt encapsulation with thick resin based coatings with an
integral CI spray or brush applied systems exist and have been proven to provide very good
long-term protection.
Visual inspection is the most commonly used system for monitoring degradation,
supplemented by sample removal of bolts for closer examination. A very important
additional benefit of gathering sample bolts is that they can be used to provide actual
mechanical property data if and when required. Specialised phased array UT systems for
bolt inspection are available but not widely used.
Acceptance criteria:
−− Bolts with mechanical damage to the stressed plain shanks or threaded portions or
cracks in any portion should be replaced.
−− Bolts, studs and screwed fasteners suffering corrosion along the shank to such an
extent that the thread is no longer discernible or the diameter has been reduced by
10 % of the nominal value should be replaced.
−− Bolt heads and nuts corroded to such an extent that cross-flats dimension has been
reduced by 10 % should be replaced.
−− If stud shank is no longer protruding beyond the top of the nut then the stud and
nut should be replaced.
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Acceptance criteria:
−− The general requirement according to BS EN 61537:2007, Cable management –
Cable tray systems and cable ladder systems is that cable tray systems and cable
ladder systems shall be so designed and so constructed that in normal use, when
installed according to the manufacturer's or responsible vendor's instructions, they
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ensure reliable support to the cables contained therein. They shall not impose any
unreasonable hazard to the user or cables. In addition, cable tray systems and
cable ladder systems shall provide adequate mechanical strength and all system
components shall have adequate resistance against corrosion in accordance with
Table 7 of BS EN 61537:2007.
−− In order to demonstrate this the cable tray and ladder systems should be in a condition
to comply with the physical test requirements outlined in BS EN 61537:2007.
−− Cable trays over walkways must be maintained in suitable condition to ensure that
escape routes are kept clear as required by PFEER. Regulation 14.
−− Galvanised cable trays, ladders and associated fittings should be replaced once the
coating has disappeared and active corrosion has commenced as it is unlikely to
satisfy the specified standards.
I.11.6.5 Valves
External surfaces of valves49, including flanges, hand wheels, levers, supports, actuator
mechanisms and casings, stems etc., should be protected from the highly corrosive offshore
environment in order to ensure that their function is not impaired. Although corrosion
resistant materials are used to some extent, most installations still have a large number of
low alloy steel valves that require active CM.
247
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I.12.1 Introduction
The term 'corrosion under insulation' (CUI) describes the external corrosion of insulated
piping and vessels that occurs beneath insulation following water ingress. Water can also
form due to condensation ('sweating') on equipment or internal cladding surfaces.
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Over the past decade CUI has continued to represent a major challenge for offshore and
onshore facilities and has been responsible for inventory releases leading to health, safety
and environmental incidents and lost production. Many operators, however, manage CUI
very effectively via a sound tactical approach grounded in correct understanding of how the
risk changes over asset lifetime and beyond. The updates made to this CUI Annex focus on
the following areas which can define effective integrity management:
−− key differences between CS and CRAs;
−− timing for thorough inspections typically range from 5–20 years;
−− insulation removal is still the most effective form of thorough inspection;
−− predictability and definition of prone areas;
−− suitability of Non-Intrusive Inspection (NII) techniques;
−− limitations of probability assessment – the pitfalls to avoid;
−− consideration for live equipment insulation removal;
−− permanent and partial permanent removal of insulation, and
−− increased rupture threat for under-inspected CS.
The following public domain guidance documents are available. The recent revision of EFC
No: 55 acknowledges few meaningful developments since the original 2008 edition:
−− EFC WP13 WP15 Corrosion under insulation (CUI) guidelines (revised edition) No: 55,
edited by Dr. Stefan Winnik.
−− UK HSE Semi Permanent Circular (SPC)/Tech/Gen 18 Corrosion under insulation of
plant and pipework, V3.
−− NACE SP0198 (2010) The control of corrosion of metals under thermal insulation
and fire proofing materials – a systems approach.
−− EI Guidelines for the design, installation and management of thermal insulation
systems.
Typically requires process engineering assistance. Permanent removal does not eliminate
corrosion especially at elevated temperature ranges, but the advantage is that the corrosion
of uninsulated equipment is visually easier to detect and monitor by CVI. In fact, insulation
typically protects the majority of equipment from the influence of weathering and persistent
dripping onto non-insulated, higher temperature equipment can result in high corrosion
rates similar to those experienced with CUI.
There is some positive experience with partial permanent insulation removal at piping
prone areas such as vertical to horizontal bends, small bore attachment locations and pipe
supports. This reduces water ingress points and consigns CUI activities to discrete sections.
Probability and consequence of failure combine to give a risk. Risk table categories can drive
priorities for inspection periods, inspection coverage/technique and coating maintenance or
coating reinstatement priorities.
There are different methods for CUI probability assessment and all can be effective providing
the limitations are acknowledged and catered for in the output risk-based schemes. It is
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possible to target a method to a particular asset. The following points need to be catered for
in any probability assessment:
−− General:
– CUI can be more aggressive than atmospheric corrosion because it can generate
more prolonged wetting and concentrate salts.
– The amount of wetting is an important consideration – of course full immersion
in water is more aggressive than atmospheric exposure and CUI can range
between these two extremes.
– All insulation systems will inevitably have weak points which allow water
ingress, dating from commissioning and also due to in-service damage or poor
reinsulation. Water ingress sites are not all reliably identifiable by visual inspection
of insulation.
– For external water sources (not sweating), CUI typically affects only 5–10 % of
insulated equipment. For sweating, CUI affects 100 %. Prone areas are often
predictable but for piping represent the majority of length.
– Water penetrates and degrades coatings sometimes very quickly.
– This means that 100 % prone area inspection is needed to provide full assurance
of the condition of critical equipment for external water sources but that %
inspection can be used for sweating.
– It is good practice to frequently inspect the surrounding environment for
persistent sources of water for all critical equipment i.e. by interim CVI or routine
thermography surveys. Persistent water sources impacting insulated equipment
require prompt action.
– In North Sea/temperate climates, sweating tends to drive low corrosion rates and
is typically an ageing issue for thin-walled equipment.
– Vulnerable CS is more likely to fail from CUI than vulnerable CRAs.
−− Carbon steel:
– The role of inspection is especially important or High Value compared to other
threats because there is no reliable barrier or barrier monitoring method.
– Stripping insulation to allow visual inspection is the most effective inspection
method.
– Coatings are degraded more rapidly by water and damage is more likely
compared with CRAs because of the absolute certainty of corrosion initiating
when the metal is wetted and the voluminous corrosion product accelerates
disbondment.
– CUI occurs over a wide temperature range and corrosion rates are somewhat
predictable but cumulative wetting isn't. Coating life and remaining life are
therefore unpredictable, but there ARE patterns in collected typical time-to-
failure data which support typically successful inspection periodicities.
– Probability or likelihood of failure increases with age.
– Both corrosion rate and coating life are influenced strongly by the degree of
wetting and temperature. Higher temperatures can offset wetting and cumulative
metal loss due to dry-out periods, which explains why the amount of wall loss
over time can often be quite similar in spite of the wide range of corrosion rates
(typically ~0,1 to 1 mm/yr). The presence of water and temperature can control
commonly observed coating lives (typical ranges of 30+ down to <two yrs for
(the lower bound for non-immersion grades) and 60+ down to five yrs for
Thermally Sprayed Aluminium (TSA) coating.
– Coatings can degrade by means other than water (high/cyclic temperature
and/or ageing/mechanical damage or poor application (uncontrolled field
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conditions) but the former may be sample inspected and the latter is typically
random/localised and less likely to coincide with wetted sites.
– Early failures of coated equipment are possible but rare, the majority manifest
after 16–20 years but this will represent wall loss well beyond corrosion
allowance.
– Early failures from five–16 yrs are associated with weathering at elevated
temperature of thin-walled equipment or unusually persistent wetting (combined
with efficient water trap geometries) of medium-walled equipment or absence
of a coating.
– There is opportunity to optimise field coating maintenance requirements
beneath insulation. Coatings only significantly extend life for equipment that
experiences mild CUI conditions that typically would not fail during operating
life had no coating been present. During operating life, quality of insulation
practice may be more important than coating reinstatement. Field-applied paint
coatings may delay replacement for a few years for significantly thinned or
SBC equipment. TSA coatings may have more of a beneficial effect on some
equipment during design life.
−− Corrosion resistant alloys:
– Crevice corrosion can affect austenitic stainless steels or, rarely, duplex grades.
– SCC is reported for austenitic and duplex grades.
– Threshold temperatures exist for crevice/pitting and SCC for different alloys.
– Vulnerable insulated CRAs do not always suffer from CUI when water and
chlorides are present. More parameters need to coincide to trigger and sustain
corrosion, both environmental and metallurgical. Though many of these
parameters cannot be measured, high vulnerability based on a laboratory
defined threshold temperatures does not necessarily translate to high probability
for uncoated CRAs.
– Originally applied coating life tends to be longer for CRAs, especially for TSA or
paint coating/aluminium foil combinations.
– Periodic inspection for pitting or cracking for uncoated alloys is of limited value
in pre-empting failure because once corrosion has initiated it can progress
rapidly to failure. Periodic inspection of coating condition may have some value
if coating breakdown is identified before water ingress triggers damage.
– Inspection to confirm the presence of a coating in the first place is important.
Once a failure has occurred inspection plays a role in identifying the extent of
the damage. If bare metal must be inspected it ought to be two–three yearly at
prone areas to be effective and of course this would require high coverage and
is not practical.
– CS bolted joints and mixed metal piping supports do require inspection
though galvanic uplift of the corrosion rate of CS bolting appears
offset by the protection offered by flange geometry.
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removal for highly critical equipment, but at extended intervals compared with
CS and not <20 yrs or through inspections at end of design life.
– Note many perform % inspection to monitor ageing CS bolted joints (see later
for CRA bolt specification).
−− Influential probability or likelihood parameters – an approach based on
temperature, cyclic operation, material and presence of coating (especially for CRAs)
is powerful in early to mid-life, age and nominal thickness can optimise efforts over
different timescales (this does not apply to CRA cracking).
−− Chlorides – the presence of chlorides under insulation should be considered
ubiquitous in the North Sea and coastal onshore environment. Leachable chlorides
from the insulation material are also a source of chlorides but this is more significant
in non-marine locations. In marine environments chlorides will be present even
without the contribution from insulation, whether the water source is condensation,
rain, distilled or seawater. Chlorides are in the atmosphere and dissolve in water and
can then concentrate during insulation dry-out periods.
−− Temperature – CS equipment operating out with the range −4 °C to +175 °C
with no significant cyclic temperature component will have very low probability of
CUI within asset lifetime, but this assessment requires confidence checks on actual
temperature, cyclic operation frequency and independent assessment of dead legs.
For CS the highest probability temperature range could be considered as 30 or
50–120 °C. API 580/1 and DNV RP-G101 provide typical corrosion rates based
on temperature geographical location and a 'severity of environment' parameter
that is hard to predict.
Note for CRAs there is no maximum temperature limit (e.g. SCC cooling cycles from
temperatures in excess of 175 °C can allow wetted equipment to crack quickly,
though often extended down-time is needed based on downstream experience and
this can be factored into probability assessment accordingly). For CRAs, industry
agreed threshold temperatures should be used to assess vulnerability to crevice
corrosion and cracking respectively. For CRA SCC the highest possible operating (not
mean) operating temperature should be used.
In the absence of clearly documented MoC for aged equipment it can be difficult
to rely on the temperature having always been within a certain range. In addition,
care should be taken to avoid assigning an item that is only a few degrees over a
critical limit to a reduced probability category. Different temperature ranges should
not factor too highly in the probability assessment but can help to set timing of
thorough inspections.
If heat tracing is present then the higher of the operating temp and heat tracing set
point should be used for the assessment.
−− Age – for CS and to some extent stainless steel crevice corrosion and pitting,
probability increases with age and for thin-walled equipment, i.e. <6 mm for 300
series austenitics.
Chloride stress corrosion cracking (CSCC) is considered as a random failure
mechanism and age-independent.
For CS especially, do not let low temperature probability criteria drive sustained
minimal inspection of highly critical systems for asset life and beyond. For example,
critical ambient temperature, aged equipment may eventually drive failure but the
reduced corrosion rates will typically only affect thinner wall components.
−− CRAs – the risk assessment process needs to consider multiple components:
– crevice/pitting (temperature, alloy, thickness);
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CS, in severe CUI conditions (wetted significantly, elevated temperature within CUI
range) TSA, though it may increase life by say five–seven years, does not significantly
reduce life cycle inspection costs or required inspection coverage. Early TSA coated
CS CUI failures have been observed in the field and are typically due to:
– Not meeting the specification (i.e. a paint coating rather than seal coating or not
achieving adequate film thickness).
– Severe prolonged wetting of high temperature surfaces at water traps. It is often
difficult to achieve adequate TSA thickness for small diameter pipe.
– Exposure of TSA coatings to saline crevice conditions i.e. multiple paint coatings
applied rather than one porous seal coating.
– For CRAs, long-term TSA performance is proven by downstream experience.
−− Location of equipment – take care when considering location of equipment
as an influential parameter, especially offshore. Of course experience shows that
CUI is most often severe at fully exposed and weathered locations compared with
inside an offshore partial or semi enclosed module where exposure to water is often
limited to periodic deluge. However, this is not the right way to manage critical and
ageing weather-sheltered equipment, as some serious CUI failures and damage have
occurred in internal modules.
This is because water can travel beneath insulation and be collected by attached
pipework and delivered to internal module equipment by gravity run-off. Other
sources can appear at any time in between inspections. For example, water leaks or
freeze/melt cycles of above piping. Rainwater collection paths can also be persistent.
Direct firewater deluge exposure can be sufficiently aggressive to cause SCC of CRAs
if the equipment is vulnerable.
Avoid methods which downgrade probability for sheltered items by use of an 'inside/
outside' tick box, such that the lower probability for critical equipment translates
to lower risk and minimal inspection coverage and timing over asset life. If there
is a regular history of reliable detailed engineering assessment of environment the
internal equipment CUI inspection scheme may be assigned a reduced probability or
an extended interval.
−− Inspection history – it is important not to use individual equipment history of no
failures or no significant inspection findings to reduce probability to downgrade the
next cycle of inspection requirements, even if the inspection was 100 % removal. This
is because water ingress paths and water sources can change between inspection
dates.
Some probability assessments assign two probabilities: one (constant) that drives
the probability governing inspection/maintenance, assuming water will ingress
and the other (time-dependent) demonstrating the reduction of probability for a
finite period based on the effectiveness of the inspection, providing all anomalies
are followed up. In other words, a high probability reduction is achieved in
between inspections for high inspection effectiveness and a low % inspection
would not achieve sufficient probability reduction to sufficiently reduce the risk
for high consequence equipment. The time-dependent 'mitigated' probability can
flag under-inspected equipment priorities. Credit for inspection can be assigned
for CRAs and CS by using inspection effectiveness tables to define high to low
inspection coverage/technique combinations and these can be linked to probability
reduction.
Inspection history for each system needs to be reviewed and considered. For example,
the dates of the last full strip to bare pipe of the systems needs to be ascertained.
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−− Wetting – it is considered good practice to assume the presence of water can occur
between inspection cycles. However, interim CVI or regular thermography can reveal
a known or observed persistent source of water with an unknown timescale or
duration and this should always trigger priority investigation.
This is best addressed by an approach based on pressure and inventory type, where the
priority is gas-containing or volatile NGL systems with high pressure. Table I.9 is included as
guidance on a criticality ranking of lines based on fluid service.
However, within all the hydrocarbon categories there could be high and low consequence
examples (i.e. fuel gas <4 barg and methanol system at 400 barg or compression gas at
180 barg or multiphase low and high Gas Oil Ratio (GOR) at 10 or 150 barg) – it is best to
agree safety related consequence of failure rule sets with the technical safety discipline.
Rupture failure can occur if areas of deep uniform metal loss are left undetected for many
years, especially for thicker walled, high pressure equipment and the safety and financial
consequence of failure is much more significant than for the typical corrosion hole release.
Ageing CS equipment not proven to have been subject to suitable 100 % prone area
inspection and operating in the CUI temperature range and containing high energy inventory
can present a serious risk.
If the probability assessment is based on broad criteria then typically risk will be already
biased towards consequence of failure or criticality.
Some operators assign priority colour-coded regions in the risk table used for corrosion risk
assessment, which may have numbers further prioritising within colour-coded regions.
Inspection schemes can be assigned to various risk table regions. Some further bias towards
consequence by assigning more rigorous inspection schemes to the higher consequence
equipment.
Risk is generally more powerful if it is expressed in the same language as the corporate risk
table. If this is attempted then the differences between risk of a leak and operational safety
risk should be clearly set out – they are not the same, though they are typically the same for
financial risk.
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The risk assessment method needs to be designed to deliver consistent application of the
strategy, not the other way around. Some methods set fixed inspection intervals but define
increasingly effective inspections over time, i.e. to acknowledge that probability and risk
increase with age or time since the last 100 % inspection.
For CRAs 4 and 8 CS bolted joints may drive inspection. For CS enough joints will be covered
by the parent material requirements.
It is not considered good practice to prove NII techniques in the field without removal of
insulation.
It is not considered good practice to use NII to wholly substitute any thorough inspection for
critical equipment which is considered significantly overdue for a thorough inspection.
In practical terms it may be useful to compare NII costs with insulation removal costs as, if the
latter is well organised, it can be competitive.
Other uses for NII are to screen to help direct priorities for backlog inspections, or for
certain vessel geometries or as a pre-screening tool for live insulation removal for equipment
considered overdue for inspection, or for lower risk equipment.
The key components of a CUI RBI scheme are inspection interval, inspection technique/s and
coverage. Typically, the intervals and strategies listed as follows have proven successful to
date for CS:
−− High risk – a two–five yearly CVI (with insulation removal at damaged areas and
a low typically 10–20 % of prone areas and in addition areas which show visible
signs of water egress, insulation damage or staining) combined with a 7–10 yrly
full inspection (with 100 % insulation removal or combined with NII only in locations
where NII is judged effective).
−− Medium/high or medium risk – as with high risk, but five-yearly and 10–20 yearly
respectively for the 100 % inspection, depending on criticality, which can be
staggered by inspecting 50 % across two inspections but still addressing all visibly
identifiable prone areas. For medium risks dealing with very low pressure or non-gas/
NGL inventories then 30–50 % insulation removal or prone area approach combined
with NII may be employed.
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−− Low risk – five–10 yearly GVI or alternative low resource strategy, depending on risk
matrix, potentially with insulation removal at damaged areas. Operators applying
such strategies as may result in an increased risk of failure, should be prepared to
demonstrate under scrutiny by the regulator, that all reasonably foreseeable risks
arising have been identified and managed to ALARP.
Ambient temperature CS may increase from low risk to high risk after 20 years of age and so
the strategy changes in late life.
There are optimisation advantages in employing a nominal thickness-based approach for the
timing of thorough inspection; it may be time-consuming to plan especially for piping but it
can reward in field activity savings.
CRAs, with a few exceptions, could be treated as medium and low risk.
For CRAs, the typical prone areas listed (for water ingress) must coincide with smaller sized
bolted (CS) joints, welds (if SCC is possible, including top of line water ingress locations) and
pitting/crevice corrosion of austenitics or duplexes is possible at crevices, under stickers or
heat tracing tape.
For any material, cladding can cause fretting of vibrating equipment (CRA or CS) as can
personal protection cages, supporting late life 100 % inspection.
Non-steam heat tracing itself does not appear to be a prone area for water ingress but could
cause elevated corrosion if water is present in terms of elevated temperature.
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Any areas found with such deterioration should be evaluated for refurbishment and the
insulation reinstated where required to correct specifications.
For CRAs coating maintenance is a primary management strategy but again focusing on the
higher risk equipment and assessed coating condition. Some duty holders have used Re 2
paint condition as a trigger for recoating. Re 2 is in accordance with the criterion in ISO 4628.
TSA can be applied in the field but aluminium wrap is also very effective.
The outcome from the application of a CUI strategy will be a rolling programme of equipment
inspections scheduled within the MMS. However, it is often the case that strategies
change quickly due to almost overnight changes in awareness of good practice, and the
rolling programme turns into a five year backlog of intensive work with potential adverse
consequences on integrity.
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−− Too cold – equipment operating <5 °C can frost and ice if inspected online. NII is
suitable for this unless where corrosion product staining or insulation damage is
evident.
−− Too hot – traditionally, equipment operating >70–80 °C has been deemed from a
safety perspective to require SD removal, but this equipment typically is suitable for
replacement of insulation with cages and also cages are not always needed i.e. at
height. Insulation removal AND reinstatement work have been carried out on 300 °C
systems applying safety assessments with regard to personnel protection. In general
most very hot equipment insulation work >2 m height consists of permanent removal
and is therefore more easily executed from a safety perspective.
If the equipment is very overdue for inspection, for example (16–20 yrs+) aged CS with no
full insulation strip history, consideration should be given to the risk of failure caused by
inspection. Threats include insulation removal and physical human weight placed on thin
wall piping. Good working practice should eliminate the latter. Risk of causing a failure by
insulation removal activities is unlikely for CRA and bolted joints and possible for carbon
steel, especially for low pressure systems, where most leaks are caused by attempts to 'clean
up' surface or remove insulation entangled with corrosion product.
−− Aim for offline inspection if equipment has not been inspected commensurate with
risk and risk is high (older, under-inspected CS equipment). If this is not possible, use
the following prior to insulation removal:
– FLIR camera pre-survey and post-insulation removal follow-up (particularly for
critical system bolted joints, CRAs, and open module/onshore systems).
– Staged HOLDs during insulation removal such as splitting cladding to reveal
whether insulation is soaked and ensuring that any surface preparation or
interaction with corrosion product is undertaken under the external surface
preparation guidance (typically prove via NII > 3–5 mm remaining wall or as
according to MAWT vs actual minimum measured wall).
Note: plants which have executed inspection cycles, techniques and coverage
commensurate with risk and this guidance i.e. successive complete insulation
strips for high risk equipment, should remain at low risk from online insulation
removal.
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Overall review of these together with verification findings for offshore installations and audit
results. Corrective action in strategy if indicated.
Particular attention should be paid to understanding true backlogs in inspection (i.e. not
just by due date but by examining whether enough inspection has been carried out).
Fabric maintenance activity should be controlled by rules sets; it is not always necessary or
cost-effective.
The relationship to budget and resource constraints should be examined. The advice of the
ICP should be sought in relation to safety critical items.
The effectiveness of CM activities, including the CUI programme will be included in the
planned integrity management system audits. The intention of the audit process is to provide
assurance that the CUI management programme is proceeding according to plan AND that
the strategy used to produce the plan is not flawed AND that all critical equipment has
records of adequate CUI inspection.
An annual audit and review plan for the Integrity Management System shall be developed
and maintained by the Duty Holder/Operator for each site. All aspects of CM, including the
CUI programme, may be audited against the checklist provided in Annex L of this document.
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I.12.9 PLAN
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
Increased effort in planning is always high value and rewarded in implementation phases
and asset performance. Fieldwork can focus on the highest risks first for any given budget.
I.12.10 DO
I.12.10.1 Organisation
Organisation roles that can be involved in CUI management include:
−− Engineering and senior managers.
−− Integrity managers.
−− Corrosion and materials specialists.
−− Process engineers and plant operators.
−− Insulation materials suppliers and applicators.
−− Specialist contractors for insulation removal.
−− Facilities maintenance teams.
−− Inspection engineers and NDT contractors.
−− Structural and mechanical engineers.
−− Asbestos specialist companies for very old roughly pre-1980 insulated equipment.
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I.13.1 Introduction
Stainless steels are employed in the upstream oil and gas industry for a wide variety of
applications. The majority of applications take advantage of the resistance to corrosion
in comparison with CS, where the additional CAPEX of selecting an alloy resistant to
corrosion in the given environment compares favourably with the OPEX or feasibility
of corrosion mitigation. Other applications exploit properties such as high temperature
oxidation resistance (310S in flare equipment), low temperature fracture toughness
(austenitics such as 316 in relief piping and cryogenic process), low magnetic permeability
(manganese austenitics in non-magnetic drilling equipment) and tendency for contamination
(potable water service, fuel handling and upstream of compressors).
A wide variety of stainless alloys is used in the industry, with the composition and heat
treatment condition dictated by the particular application requirements, e.g. for corrosion
resistance and strength. Examples of commonly applied grades and their applications are
shown in Table I.10.
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Corrosion resistance is primarily a function of composition, with alloys ranging from the
leanest 13Cr-type alloys at one end of the spectrum to the highly alloyed superaustenitic
and hyperduplex grades at the other. The concentration of the primary alloying elements
chromium and molybdenum is increased across this spectrum to improve the resistance to
corrosion. Other alloying elements such as nickel, nitrogen, copper, tungsten, niobium and
titanium can enhance corrosion resistance in specific grades or environments.
Stainless steels rely on the stability of a protective chromium-rich oxide film to resist corrosion,
the capability of which is principally dictated by composition. This film provides resistance to
substrate oxidation in conditions where it remains intact; however, it can be dissolved in
strongly acidic conditions, resulting in general corrosion. In upstream oil and gas conditions,
risk of localised degradation due to partial disruption of the passive film is more prevalent
with the chloride ion being the main protagonist.
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I.13.2 Environments
Internal service can be broadly categorised into oxygenated and nominally oxygen-free
service. The former primarily pertains to untreated seawater service, either for firefighting/
utility purposes or for process cooling. Treated seawater, e.g. for water injection
applications, may contain small quantities of oxygen by design, through upset vacuum/
chemical scavenging treatments or unintentional external ingress. Oxygen-free aqueous
chloride conditions are predominantly associated with reservoir waters in the production
system.
In addition to natural waters, either from the reservoir or lifted from the sea, synthetic chloride
(and bromide) brines are regularly used in drilling and completion applications where contact
with stainless steels is common. These clear brine fluids typically contain very high dissolved
solids concentrations to maximise density, so for halide systems it is essential to control pH
and oxygen.
As indicated in the previous section, one of the primary differentiators in service environment
for stainless steels is the presence of oxygen, the reduction of which presents a cathodic
reaction to accompany the substrate oxidation process. Lower grade stainless steels such as
13Cr and 316 are successfully used in oxygen-free production conditions where corrosion
threats arise from dissolved acid gases. In such applications, these comparatively lean grades
have sufficiently low depassivation pH to resist corrosion even at elevated temperatures and
chloride concentrations. For oxygenated internal/external conditions, application envelopes
for specific grades are considerably more restricted. This should be borne in mind when
considering risks of oxygen introduction to systems designed for oxygen-free service.
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Temperature and chloride concentration are two other dominant factors for the suitability of
a stainless steel in a given application. Together with in situ pH, these parameters are the key
drivers for increased alloying requirements in low H2S, oxygen-free service. Temperature is
also a controlling parameter for resistance in oxygenated service, with the tendency for
localised corrosion and SCC increasing with temperature. There is also an effect of biofilm
to be considered, particularly for natural waters, relating to potential ennoblement and
cathode reduction efficiency. Where chlorination is used to control bacterial activity, excessive
concentrations have the effect of increasing corrosion potential.
For external service there is a limit to the effect of temperature, particularly in uninsulated
conditions, in view of the tendency for free water at temperatures approaching boiling
point. The downside of operation at elevated temperature in a saliferous environment is
the tendency for evaporation and concentration of salts on the surface of the material.
Evaporation effects and localised increases in chloride concentration can also occur in internal
production conditions if small amounts of formation water in contact with a gas phase are
exposed to a significant pressure drop, e.g. across a choke or level control valve.
Figure I.52: Internal SCC of 22Cr duplex resulting from chloride concentration effects
Local environmental effects promoting greater corrosivity can also be created by the
introduction of contact/retention features such as clamps, deposits, stickers, etc. An
environment with severity outwith design intent can also be created by the combination
of compromised insulation integrity and deluge activity. Use of materials which can leach
chloride or are chloride-bearing, e.g. inks, insulation materials, etc, can also result in increased
localised corrosivity. Coupling of dissimilar materials can result in accelerated localised attack
of the less noble alloy. For stainless steels, this is primarily an issue for oxygenated internal
environments, i.e. seawater service, where coupling with more noble materials such as
graphite, nickel alloys or higher alloy stainless grades.
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Figure I.53: SCC experienced on a cold worked dome end section of a previously
insulated vessel
Figure I.54: Evidence of corrosion taking place beneath label on 316L line
In addition to the severity of the service conditions, the resistance of a stainless steel to
degradation in aqueous chloride environments can be compromised by a number of other
factors. Such factors include microstructural anomalies (formation of intermetallic or carbide
phases, depleting alloy content locally), excessive oxidation in service or during fabrication
(heat tint) depleting the surface of alloy content, free iron surface contamination, use of high
sulfur free machining versions of a grade and intentional or incidental cold work.
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At elevated corrosion potential levels, stainless steels are at risk of localised passive film
breakdown and where chlorides are present the tendency to repassivate is impaired, resulting
in pitting corrosion. Pitting corrosion is a stochastic phenomenon, the prediction of which
relies on an understanding of numerous parameters with pitting tendency/time expressed
in terms of a statistical distribution. Of more practical use is the concept of a critical pitting
temperature (CPT), which should be regarded as a soft limit above which the probability of
pitting is significant. Example CPTs for bulk materials are shown in Table I.11.
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Crevice corrosion occurs in stainless steels at sites where the passive film is impaired by
the presence of a surface restriction to oxygen access. Repassivation is not possible in such
conditions and hydrolysis of liberated substrate ions plus migration of chloride ions to the
anodic site result in a very aggressive local environment, with commensurate corrosion rates.
Crevice geometry is a significant factor in the tendency for corrosion, together with more
universal aspects such as temperature. Crevices can be formed by a variety of means, such
as support clamps, flange faces, deposits, etc. It should be noted that critical temperatures
for crevice corrosion are significantly lower than those for pitting, as indicated in Table I.11.
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The resistance of a stainless steel to localised corrosion in chloride environments is very much
a function of the alloy content. This is can be expressed in the form of a Pitting Resistance
Equivalent Number (PREN), calculated from formulae derived from corrosion testing. A
common version of the PREN formula is shown here, although there are a number of variants
containing different coefficients and other elements such as tungsten.
Intergranular corrosion in stainless steels pertains, in the main, to the situation where
the formation of grain boundary chromium carbides during thermal treatment, e.g. from
fabrication, results in chromium denuded zones which exhibit lower resistance to corrosion.
The mechanism is avoided by the used of low carbon or stabilised grades.
Additionally, given that tensile stress is required for the mechanism to operate, the level
of service and residual stress influences SCC risk and is affected by various factors from
fabrication and operation, i.e. global stress level, localised cold work, fabrication stresses,
geometrical stress raisers, presence of pits, etc.
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In comparison with austenitic and duplex stainless grades, nickel-free ferritic and martensitic
stainless steels are highly resistant to chloride SCC but Ni-containing grades can be susceptible.
Localised corrosion and SCC can also be experienced in internal, oxygen-free chloride service
environments. Threshold levels are less well-defined than atmospheric service, but stainless
steel grades are successfully employed at temperatures well above their respective limits
for oxygenated service in such environments. Additional factors such as H2S concentration
and bacterial activity influence the tendency for internal mechanisms over and above the
common parameters such as chloride concentration, residual stress, etc.
Intergranular cracking is normally associated with sensitised materials, but can also occur
in high strength stainless steels, i.e. precipitation hardened martensitic grades. In this case,
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exposure to atmospheric chloride environments can result in hydrogen stress cracking where
hydrogen is generated by anodic corrosion processes.
I.13.5 Mitigation
Stainless steels are typically selected as a means of CM, so application of any additional
corrosion mitigation will usually arise from differing service severity on internal and external
surfaces. The primary means of corrosion mitigation would be to select a higher stainless
steel grade with alloying content capable of withstanding both internal and external service
environments; however, there can be economic and practical aspects associated with this
approach which favour mitigation instead.
Where the stainless steel is appropriate for internal conditions but susceptible to external
corrosion or cracking mechanisms, the application of barrier coatings is often specified.
Organic coatings and thermally sprayed aluminium are employed depending on criticality
and operating temperature requirements. Protective coatings are typically specified for
service under insulation as a contingency against water ingress in the event of the clad and
insulation system being breached.
Prevention of surface salt concentration on hot pipework, and reducing the potential for
insulation ingress can be achieved by minimising seawater deck-wash or deluge exposure.
In recent years, where insulation is required for personnel protection it has been common to
utilise open mesh guards instead, in order to remove the risk of CUI. In such instances, care
should be taken to mitigate risk of crevice corrosion at support ring contact points. Crevice
corrosion is also a recognised issue in relation to smallbore tubing clamps. Where the grade
of stainless steel is susceptible to crevice corrosion at the operating temperature, precautions
should be taken to mitigate against the mechanism. Approaches employed to date have used
inhibited polymers, specific design geometry/materials and barrier coatings.
Welded equipment has the potential for localised susceptibility to degradation where
control of oxidation has been inadequate. Where detrimental oxidation (and/or ferrous
contamination) has occurred, this can be removed by pickling and passivation treatments.
Whilst this is typically applied during fabrication, remedial electrochemical or chemical
treatments can be applied in situ.
For internal chloride degradation mechanisms, the use of chemical inhibition is not
common for stainless steels, but instances of retrospective application when an issue has
been detected in service are known. More commonly, chemical treatments to address
corrodents are applied, principally pH modification and oxygen removal. Physical treatment
is to remove oxygen, e.g. by vacuum, are also common. Dilution with condensed water is
applied in situations where internal evaporation can result in chloride concentration effects
downstream of valves.
The risk of galvanic corrosion of a lower grade stainless steel connected to a more noble alloy
generally indicates that the original material selection is questionable. Where the risk exists,
typical mitigation measures would include isolation of the dissimilar materials or coating of
the cathode.
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I.13.6 PLAN
I.13.6.1 Policy
Localised corrosion and SCC of stainless steels can result in failure of pressurised process
equipment, with the potential consequence of hydrocarbon release. The operating company's
integrity policy and strategy should therefore be directed to prevent such failures or at least
to keep the risk ALARP.
Where a residual risk from mitigation of localised corrosion or cracking exists, the CMP
should recognise the implications of failure of relevant equipment and stipulate appropriate
treatment in the CMS.
I.13.6.2 Planning
Where stainless steels have been selected specifically to mitigate against envisaged corrosion
mechanisms in service, the expectation would be that appropriate selection using reliable
established guidelines or specific qualification testing would be the primary planning
aspect. This would be augmented by an appropriate level of surveillance to confirm design
assumptions during service life.
Where mitigation measures to protect the stainless steel material itself require to be
implemented, e.g. by coating or physical/chemical treatment, control and monitoring
measures require to be in place.
For these two scenarios, the CMS should include planning for the prevention of chloride-
induced corrosion and cracking in stainless steels via the relevant combination of inspection
and control activity.
I.13.7 DO
I.13.7.2 Organising
That part of the Duty Holder which is responsible for managing corrosion risks in operation
should arrange for the development of mitigation measures to control any anticipated
chloride corrosion and cracking threat. It should be apparent that this may involve multiple
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parts of the organisation, given the widespread application of these materials, i.e. downhole,
subsea, topside, pipelines, etc.
The functions responsible for undertaking the following activities are to be identified by the
Duty Holder:
−− corrosion threat assessment and RBI generation/review;
−− inspection activities, findings review and completion of RBI loop;
−− remediation of anomalies found, and
−− application and monitoring of chemical and physical treatments.
It is important that the purpose of control activities and the implications of poor implementation
are effectively communicated to the responsible functions in the organisation.
I.13.8 CHECK
I.13.9 ACT
The results of investigations into failures, particularly unusual failures and those occurring
in circumstances where the material would not be expected to fail, should be disseminated
in-house and, where possible, in the public domain. By the same token, the organisation
should actively participate in industry technical groups in order to benefit from the experiences
of other operators.
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
I.14 EROSION/CORROSION
Erosion
The progressive loss of material from a solid surface due to mechanical interaction between
that surface and a fluid, multi-component fluid or solid particles carried within the fluid.
Erosion-corrosion
A conjoint action involving corrosion and erosion in the presence of a moving corrosive fluid
or a material moving through the fluid, leading to accelerated loss of metal.55
Erosion56, 57, 58, 59, 60, 61 often causes localised grooves, pits or other distinctive directional
patterns in locations of elevated velocity in comparison to corrosion degradation.
Choke Valve 316 Stainless Steel Valve Impeller Copper Nickel Alloy
Colander
Erosion that occurs in process pipework is mainly due to particulate erosion caused by
sand or proppant from well clean-up entrained in the produced fluid. Erosion rates are
particularly dependent on the particle or fluid velocity and the total mass of solids in a system.
The erosive nature of solid particles is dependent on a number of factors including, but not
limited to:
−− fluid or particle velocity;
−− total mass of particles;
−− particle shape;
−− particle hardness;
−− particle size;
−− hardness of equipment material;
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Erosion of steels will not usually occur in solid-free fluids even at very high velocities.
In the absence of any solids, erosion by non-corrosive fluids in steel is not significant at
velocities below the process piping design velocity limits to prevent severe pressure drops
(~30 m/s). The conditions required for liquid droplet erosion are unlikely to occur in correctly
designed production pipework systems.
Cavitation is rare in oil and gas production systems except in chokes, control valves and
pump impellers, as the operating pressure is generally much higher than liquid vaporisation
pressures. Cavitation occurs when the pressure is reduced below the vapour pressure of
the liquid, bubbles are formed and then collapse generating shock waves of sufficient
amplitude to damage pipework.
I.14.2 PLAN
I.14.2.1 Policy
The EI Guidelines on sand erosion and erosion-corrosion management may be used
as guidance to develop the erosion and erosion-corrosion management aspects of
the Company Integrity Policy and Strategy in order to manage the risk of failure ALARP.
I.14.2.2 Planning
A clear sand management strategy to optimise production without compromising safety
or environmental considerations can be an effective means to control erosion problems. It
should be updated regularly based on experiences and future requirements, in particular, after
sand-related incidents and to account for system modifications and changes in operating
conditions. Implementation of changes and modifications may fall with the remit of the
company MoC system.
The CMS should/shall define the approach to plan implementation and the analysis of
collected data. A corrosion control scheme/management matrix should be used to define
the requirement to maintain the integrity of the topsides static equipment and associated
pipelines by a programme of mitigation against, and by monitoring of, applicable degradation
mechanisms. The corrosion control scheme/management matrix should/shall:
−− identify locations where erosion and erosion-corrosion degradation may be
anticipated;
−− identify asset-specific management activities to mitigate and monitor plausible
threats;
−− reference PMRs;
−− define performance limits or indictors to ensure that monitoring and mitigation
data are reviewed appropriately to prevent loss of integrity and impact on personnel
safety, environment and the business;
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IDENTIFY EROSION AND EROSION CORROSION RISKS FOR THE ASSET
Item identity
MITIGATION BARRIERS
Item location
Materials and process THREAT MONITORING
The barrier/mitigation activity:
parameters
Operating Guidelines
The likelihood of failure by
erosion or erosion-corrosion Downhole Sand Exclusion BARRIER MONITORING
The measurement method to
threats Desanders, Filters, etc. determine the success of the
The consequences of mitigation Corrosion/erosion allowance barrier against the identified
failure threat REMEDIAL ACTION(S)
Erosion resistant materials The measurement method for
The performance limit for that the effectiveness of the barrier
Piping and completion design measurement
to reduce velocity and The performance limit for that
changes of direction The monitoring activity: measurement The action(s) required on non-
conformity to the performance
Inspection The monitoring activity:
The location of the threat, measurement
278
barrier and monitoring activity Sand (acoustic) Monitoring Inspection
Online Erosion Monitoring Sand (acoustic) Monitoring Responsibility for action on non-
Process Parameters (velocity Online Erosion Monitoring conformity
inferred from pressure)
The frequency of monitoring, or
The frequency of monitoring, or the basis on which frequency
the basis on which frequency should be determined
should be determined
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
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I.14.3 DO
Various erosion models have been developed from experimental observation of erosion and
fall into three broad categories:
−− empirical models that are simple mass or volume loss equations e.g. API RP 14E;
−− mechanistic models based on fluid and particle properties and flow rates e.g. Salama
Equation, DNV RP O501, SPPS Software – University of Tulsa, Sandman Software,
and
−− complex models requiring detailed input using computational fluid dynamics or finite
element analysis.
Figure I.61 illustrates some of the locations in a production system that can be particularly
susceptible to erosion. Care should be taken when considering sand production rates for
erosion assessment purposes. A high sand rate may be tolerable in low-velocity flow for
short durations and a low sand rate can cause significant damage over a long duration at
high-velocity.
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Flare
choke
internals Compressor vulnerable to
& outlet rust particles & sand
Xmas tree
& flow line downstream
of choke
Gas
Export
bends downstream of
reduced-bore valves Mostly fines
Sand accumulation in
separator could cause
sand carryover and
restrictions in valve subsequent pipeline
well (sliding internals Primary separator inhibition issues
sleeves, SSSVs,
ESDs, ICDs etc.)
Oil
Export
separator
mesh failure in nozzles (liquid) Pump wear
partially blocked
sand screen pump wear
Mostly fines – pipework
vulnerable at high rates
Figure I.61: Parts of the production system that typically suffer from erosion62
I.14.3.2 Organising
Definition of clear responsibility, accountability, and ownership of erosion and erosion-corrosion
management activities should be included the corrosion control scheme/management matrix.
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Communication activities should aim at increasing awareness of the factors that influence
erosion and erosion-corrosion to ensure the impact of operating changes are fully understood.
Many erosion problems can be avoided by using good design to reduce the likelihood of
loss of containment due to erosion damage, such as:
−− corrosion/erosion allowance;
−− erosion resistant materials;
−− piping and completion design to reduce velocity and changes of direction (correctly
sized chokes, larger bore pipework, minimising flow restrictions and number of
bends);
−− designing and operating to avoid areas of rapid decompression which could cause
cavitation, and
−− adhering to design velocity limits (see Table I.13).
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I.14.4 CHECK
I.14.5 ACT
Operational restrictions such as pressure restrictions and velocity limits may be placed
on the operating envelopes of individual wells or systems if the original design becomes
inadequate. Some operators require solids risk assessments using erosion modelling and
sand tests as part of the management of solids-producing wells. Limitations may be placed
on the tubing head pressure (THP) or the choke opening position and recorded in the well
operating guidelines (WOGL) in order to operate with tolerable erosion rates.
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Computational Fluid Dynamics flow simulation can be used to assess systems that are
close to acceptable limits, in highly-convoluted pipe sections and in geometrically complex
components such as valves. Ultimately it may be necessary to redesign and replace piping in
order to avoid or minimise future degradation by erosion or erosion-corrosion.
Where industry safety alerts (Step Change, HSE etc.) are issued their applicability to the
Company assets should be assessed and documented to demonstrate that the risk of
failure is ALARP. If necessary the Corrosion Control Scheme/Management Matrix should
be updated with the appropriate monitoring and mitigation to address the threat.
Location: AssetName
Corrosion control Annual review of corrosion control scheme.
scheme review Comment on last update and reference/link and
state next planned update
Design envelope Scheduled analysis achieved or not for CO2, H2S,
mercury etc., pressure, temperature. Comment if
within acceptable parameters and required actions
if not
Fluids monitoring Scheduled ion analysis achieved or not and
comment on significance of any changes in Fe,
Mn, Cl− etc from fluid sampling, and any required
actions e.g. inhibitor suitability
Chemicals and Target dose rates achieved or not. Target corrosion
corrosion inhibition inhibitor residuals sampled for and achieved or
not. Comment if within acceptable parameters and
required actions if not
Monitoring retrieval Planned visits vs actual visits. Last site visit summary
and service visits of work executed and report reference
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I.15.1 Introduction
Black powder (BP) formation is a long-standing problem in gas pipelines, which is related to
corrosion of uncoated carbon steel in the presence of water.
BP can accumulate during cleaning pig operations of dry gas lines and has the potential to
cause blockages.
Comprehensive field and laboratory testing has identified that the two sources are:
−− formation of BP in the carbon steel pipelines due to reaction between iron (Fe) with
condensed water containing one or more of: carbon dioxide (CO2), hydrogen sulfide
(H2S), oxygen, and
−− BP carryover from gas production and processing facilities the main constituents of
BP has been found to be either is iron oxide (FeO) or iron sulfide (FeS).
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FeO is found in the form of magnetite (Fe3O4). Goethite (α-FeO(OH)) is also present and a
small amount of lepidocrocite (γ -FeO(OH)), as well as iron carbonate (FeCO3). These are
common hydrated iron oxides that are found in corrosion products. Some BP samples have
been found to also contain mercury and radioactive Pb-210 and Po-210. Research has also
shown that BP is regenerative and is formed as a product of internal corrosion in the presence
of condensed water containing H2S, CO2 or oxygen.
BP particles are very hard and jagged, (see Figure I.62), which makes them erosive to pipeline
fittings and components particularly when accelerated, due to flow restrictions, inside
pressure control valves where they can severely erode valve trim cages as shown in Figure
I.63.
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Table I.15 shows some BP corrosion compounds and their potential sources. In addition, FeS
is formed by the reaction of H2S with Fe.
Table I.15: Black powder corrosion compounds and their potential sources constituent
sources formation reaction
The main cause for the internal corrosion was determined to be the presence of condensed
water containing CO2, oxygen, and H2S. While CO2 and H2S are inherently part of the
processed gas, the source of oxygen is related to ingress from leaks at low pressure points
throughout the systems or because of maintenance activities. Studies indicated that oxygen
ingress even in ppb level could cause corrosion and subsequently BP formation in the
presence of condensed water. The source of the condensed water is related to inadequate
gas dehydration, which results in exceeding the maximum allowable level. Subsequently,
water potentially condenses on the inner walls of the pipeline due to high water dew point.
Condensed water, coupled with corrosive elements such as CO2, H2S and oxygen, even
in small amounts, as low as ppm levels, can result in internal corrosion and formation of
corrosion products (e.g. BP), namely: FeCO3, FeS and iron oxides.
The common chemical forms of FeS include pyrrhotite, troilite, mackinawite, pyrite and
marcasite, ferric sulfide, smythite and greigite. Pyrophoric FeS is formed in the gas stream
where H2S exceeds the concentration of oxygen. FeS in the chemical forms of mackinawite,
smythite and greigite are typical indicators of microbial activity in the gas pipeline.
Additionally the confirmation of SRB and acid producing bacteria (APB) in the pipeline
is a positive indication that microbial corrosion exists. The SRB microbes Clostridium and
Desulfovibrio deulfuricans consume sulfates and produce H2S. While APB microbes do not
produce H2S, they supply nutrients and provide hospitable environments for SRB to grow.
On way FeS results from SRB mediated corrosion would be during hydrotest and/or wet
lay-up, as corroborated by the presence of SRB activity. Sulfur, in its elemental form, is also
present in BP in small quantities. The origin of this sulfur is from the oxidation of FeS during
air-drying of the line.
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high CO2 and/or HS with wet environment in contact with CS piping and equipment. Most
of the formed BP is expected to be captured in the inlet slug catchers/filters and gas treating/
dehydration units. The captured solids including BP will end up in the process streams such
as water, condensate, amine and TEG. Efficient filtration of these streams is critical to avoid
any negative efficiency or reliability impacts for the associated process units. However, some
BP will uncontrollably pass through to the network with sales gas; no further corrosion can
occur if the line remains dry – i.e. with no free water present. There should be no ongoing
corrosion in the absence of process upsets and no ongoing accumulation of BP, other than
old material removed during pigging operations.
If, however, future process upsets give rise to free water, then there is a risk of reinitiation
of accelerated corrosion due to the presence of surface films containing wet elemental
sulfur in contact with dissolved H2S (from the production gas). In this instance, the corrosion
product would be FeS, rather than iron oxide.
I.15.3 PLAN
I.15.3.1 Policy
Primarily, regular pigging is required to remove the remaining elemental sulfur from the
pipeline.
If process upsets result in free water in an otherwise dry gas line, there is the threat of
initiation of accelerated corrosion due to the presence of surface films containing wet
elemental sulfur in contact with dissolved H2S (from the production gas).
Company's Integrity Policy and Strategy should therefore be to avoid such circumstances or
at least to keep the risk ALARP.
I.15.3.2 Planning
The CMS will indirectly address the prevention of damage by BP by considering the susceptibility
of all materials of construction to this threat and the expected production conditions.
I.15.4 DO
However, the small amount of elemental sulfur in the powder suggests there may have
been MIC during the pre-commissioning stage and if future process upsets give rise to free
water, then there is a risk of reinitiation of accelerated corrosion due to wet sulfur.
I.15.4.2 Organisation
All personnel involved should be made aware of the factors relating to BP and be vigilant to
recognise the indications of, or changes that are likely to result in, a corrosion threat.
Personnel should respond appropriately to any condition recognised to pose a threat and
rectify the situation through effective communication with the relevant organisations.
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I.15.5 CHECK
The investigation will be in accordance with the CM strategic plan which may be part of a
wider integrity management plan.
The RCA of any incident relating to BP or management system failures will be investigated
with the appropriate corrective action(s) recommendation.
I.15.6 ACT
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I.16.1 Introduction
Elemental mercury condenses to liquid upon cooling below its dew point, and can remain
in this state over a wide range of temperatures common to oil and gas production and
processing environments. The liquid is easily identifiable due to its unique silvery white colour
and is also known as quicksilver for its mobility.
Figure I.67: Mercury (symbol – Hg, atomic number – 80, atomic mass – 200.59)
Elemental mercury (hereinafter referred to as mercury or Hg) is the primary mercury species
responsible for damage to equipment. Mercury and its compounds are also toxic and present
environmental and health hazards, the impact of which is not within the remit of this
discussion. Even at its lowest concentrations, mercury can degrade certain materials, creating
potential risks to the integrity of the facilities. The principal degradation mechanism that
leads to failure is Mercury Liquid Metal Embrittlement (Hg-LME).
Hg-LME refers to either a loss of ductility of a solid metal or its fracture below the normal
yield stress due to intergranular penetration of liquid mercury. When liquid mercury diffuses
into the grain boundaries of a solid metal, the material loses its strength and ductility, and
intergranular cracking occurs. The crack surface is typically brittle in appearance and may
appear to have a coating or monolayer of mercury. It is not necessary for the solid metal to
be saturated in mercury and a very small amount (microgram) of liquid mercury is sufficient
to cause this effect in susceptible metals.
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The liquid mercury must be in direct contact with the bare metal surface, and a metal surface
with a uniform, adherent oxide layer may not experience any direct contact unless the oxide
layer is disrupted. Therefore, plastically deformed surfaces with fresh metal exposed or stress
raisers which lead to easy rupture of surface protective films are likely initiation points for
Hg-LME. Locations where the surface films are removed either by erosion or chemical action
which expose underlying metal, will also be affected.
Tests conducted by Case and McIntyre (NACE Corrosion 2010, paper 10294) confirmed that
the following materials common to the oil and gas industry, are immune to Hg-LME:
−− ASTM A516 Gr 70 carbon steel;
−− ASTM A193 Gr B7 alloy steel;
−− AISI 317 austenitic stainless steel;
−− AISI 410 martensitic stainless steel;
−− Alloy C-276 (UNS N10276), and
−− Commercially Pure Gr 2 Titanium.
Use of duplex stainless steels in mercury service has also been successful. Aluminium alloy
5083 and Monel alloy 400 (UNS N04400) showed significant embrittlement in these tests.
This agrees with reports of service failures of these alloys in mercury service. Other Nickel
based alloys without chromium, such as Nickel 200 (UNS N02200) and Monel K-500 (UNS
N05500) can also be susceptible. Failure of a ASTM A353 9 % Nickel steel storage tank was
recently reported and subsequent tests have revealed the susceptibility of A353 9 % Nickel
base metal and weld heat affected zones to Hg-LME (NACE Corrosion 2013, paper 2701).
Although pure titanium resists Hg-LME, titanium alloys with aluminium additions may also
show susceptibility under dynamic conditions.
Mercury can cause cracking, when in contact with the following alloys:
−− aluminium based alloys of all types;
−− copper based alloys of all types, and
−− nickel based alloys without chromium (Nickel 200, Monel 400 and Monel K-500).
Contact with solid (frozen) mercury has not been shown to produce any attack. Contact
with mercury vapour is normally not harmful unless condensation occurs.
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Figure I.68: Mercury emerging from crack on aluminium heat exchanger (cold box)
Figure I.69: Close-up of crack on storage tank floor plate showing mercury droplets
(centre)
Other key threats posed by mercury on metals are amalgamation and amalgam corrosion.
Amalgamation occurs when a solid metal dissolves to form a liquid solution with mercury.
Mercury only forms a liquid solution with specific metals, primarily: aluminium; tin; gold;
silver and zinc; of these, only aluminium has mechanical significance. The tightly adhering
aluminium oxide layer (Al2O3) formed when aluminium reacts with oxygen can protect the
metal from amalgamation. Where the aluminium oxide layer is breached, either by abrasion,
chemical attack, or thermal and mechanical strains, mercury can wet the underlying surface
and amalgamation can occur. The rate of amalgamation will depend on the microstructural
condition.
Susceptible alloys and welds can be severely affected. The result of amalgamation is a loss of
mechanical strength, particularly at welds where the grain boundary chemistry and residual
stress make this area more susceptible to attack than the base metal.
The first step in the amalgam corrosion process is the formation of an amalgam whereby a
solid metal, on contact with liquid mercury, dissolves into the liquid mercury. If water vapour
or liquid water is in contact with the amalgam, this can result in uniform surface attack or
localised pitting on the underlying metal. Amalgam corrosion only occurs at temperatures
where liquid water can exist and the process is self-propagating as long as water is available
and the mercury continues to wet the metal surface.
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All aluminium alloys are susceptible to amalgam corrosion to varying degrees under a wide
range of conditions. Amalgam corrosion only develops in the form of pits if the mercury
deposits are not continuous and liquid water is available. A feature of amalgam corrosion of
aluminium is the production of hydrated aluminium oxide and hydrogen corrosion products.
The reaction rate is extremely rapid with a rate of penetration in excess of 1 mm/y (NACE
Corrosion Survey Database). The hydrated aluminium oxide corrosion products are observed
to grow as filaments from the metal surface, appearing very dramatically and rapidly.
I.16.2 PLAN
I.16.2.1 Policy
Hg-LME and amalgam corrosion can cause catastrophic failure resulting in a process safety
incident e.g. hydrocarbon release, fire and explosion. Numerous incidents regarding these
failures have been reported worldwide and are available in the public domain. The Duty
Holder’s CMP and strategy should therefore be to avoid such failures or reduce the risk to
ALARP.
I.16.2.2 Planning
The first step in planning for the prevention of Hg-LME and amalgam corrosion in oil and
gas production, is to determine whether mercury is present in the process stream or whether
it may be present from future tie-ins or new wells coming online. A variety of techniques is
available for determination of mercury concentration in field samples including:
−− atomic fluorescence spectrometry;
−− gold film mercury detection, and
−− calorimetric analysis.
Quantifying the mercury levels, identifying and characterising the mercury species and
compounds, and the distribution across the process systems can be undertaken either on
a one-off basis, or as part of a longer-term monitoring programme. Common industry
standards for sampling and measurement of mercury concentration are:
−− ISO 6978-1 Natural gas – Determination of Mercury – Part 1: Sampling of Mercury
by chemisorption on Iodine.
−− ASTM D7623-10 Standard test method for total Mercury in crude oil using
combustion-Gold amalgamation and cold vapor atomic absorption method.
−− ASTM D7622-10 Standard test method for total Mercury in crude oil using combustion
and direct cold vapor atomic absorption method with Zeeman background correction.
−− ASTM D7482-15 Standard practice for sampling, storage, and handling of
hydrocarbons for Mercury analysis.
The sampling and analysis programme should be documented so that all involved fully
understand the requirements and expectations. It should have clearly stated objectives with
written definition of responsibilities through every step of the programme.
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I.16.3 DO
Focus should be on systems and components where mercury is likely to be present in the
liquid phase and where crack initiation and propagation may be encouraged by factors
such as stress, abrasive wear and chemical action. An estimate of the conditions at which
mercury vapour will condense to the liquid phase for varying mercury concentrations and
gas pressures, is available from published data. Computer models can also be used to predict
the formation of liquid mercury in a process facility and estimate the distribution of mercury
across the systems.
Significant quantities of mercury can be adsorbed onto the surface of metals from
the vapour phase and released when changes in conditions occur. Also, during trips,
shutdowns or upsets when the streams are cooled, mercury levels can reach the saturation
limit, resulting in coalescing of droplets to form a free elemental mercury phase. There
is indication that even a mono-atomic layer of mercury could cause Hg-LME in sensitive
materials, thus systems carrying only mercury vapour cannot be ignored, although they
might be assigned a lower priority in terms of action.
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NO YES
System/
equipment Material
operates under YES susceptible to
mercury attack YES
stress or history
of mercury or susceptibility
related attack unknown
NO
NO
NO YES
I.16.3.2 Organisation
Organisational roles that can be involved in managing this threat include:
−− Corrosion and Materials Specialist;
−− Process Engineer;
−− Mechanical Engineer;
−− Plant Operators, and
−− Inspection Engineer.
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mercury deposition and because the low temperatures required to liquefy gas usually
condense mercury as well. The cryogenic heat exchanger is referred to as a cold box
and is typically manufactured from aluminum.
−− Review of materials and replacement of susceptible components
Detailed review of construction materials is required to ensure that no susceptible
alloy is present in the zones where mercury deposition is possible. Where there is no
information on the performance of an alloy in mercury service, it is recommended to
undertake the Hg-LME test programme in the laboratory to evaluate its susceptibility.
Common test methods are:
– constant load tests in liquid Hg, and
– slow strain rate tests in liquid Hg and Hg vapour
The safest approach, if mercury condensation is predicted in specific parts of the
facilities, is to remove any materials considered to be susceptible to attack and
replace with mercury tolerant materials.
−− Inspection of critical areas
The usual aim of inspection is to detect the onset of a corrosion process, or monitor
that the rate of attack is within a preset safe limit. The problem in considering
inspection as a means of monitoring Hg-LME is that the initiation phase is virtually
undetectable. After initiation, the propagation of attack is extremely rapid and does
not permit timely corrective action. For this reason, it is not considered possible to
inspect for Hg-LME on any component. Nevertheless, inspection is invaluable for
monitoring amalgam corrosion and to verify or refute predictions obtained from
computer models for liquid mercury presence.
I.16.4 CHECK
KPIs can be used for measuring the performance of mercury removal systems. Several
factors affect the efficiency of mercury removal systems and it is not uncommon for the
units to allow mercury deposition due to damage to the beds, feed composition changes,
presence of impurities, etc. Therefore, the mercury content upstream and downstream
of the removal unit should be monitored periodically. Once the bed becomes spent (i.e.
exhausted its capacity to remove mercury), it should be promptly taken out of service for
the adsorbent material to be removed and disposed of appropriately.
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Failures should be investigated to derive any information that may have more widespread
relevance to the remainder of the facility. The failure investigation should be aimed at not
only identifying the mechanism of failure but also the circumstances which led to the failure,
so that corrective actions can be implemented to prevent a recurrence.
I.16.5 ACT
I.17.1 Introduction
In oil and gas industry applications, caissons are generally considered to be tubular
components which provide a means of conveyance between the sea and the platform
topside. Applications include: housing of pump strings utilised for lifting seawater; liquids/
solids disposal; hydrocarbon liquids separation/recovery and containment/protection of risers
and other assets. Depending on the application, caissons can be of substantial dimensions,
i.e. up to 1,5 m in diameter, 75 m in length and weighing up to 50 tonnes. Therefore
the consequences of failure in terms of dropped object damage to primary structure and
submerged assets such as pipelines can be severe.
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The dominant degradation mechanisms affecting the risk of caisson failure are fatigue
cracking and internal corrosion63, 64, with operator respondents to a survey published by iicorr
in 200965 indicating that internal corrosion was the prevalent mode of failure. Additionally,
the two mechanisms can operate together, with corrosion exacerbating fatigue crack
propagation and influencing initiation by reducing the cross-sectional area or providing an
initiation feature, e.g. pits, preferential weld attack, etc.
The prevailing failure mode for caisson deadweight supports is through fatigue cracking in
the structural weld details; this is caused by the stress concentrations and the high cyclic
loading transferred though the deadweight support.
Figure I.72: Example of cracking propagating from a localised internal corrosion defect
Whilst some caisson designs have used polymer composites, superduplex stainless steel and
even titanium, the majority of caissons installed to date have been manufactured from CS.
Given the demanding conditions to which they are exposed both externally and internally,
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coupled with the potential consequences of failure and high cost of in situ remediation/
replacement, management of caisson corrosion in design and service is worthy of specific
focus.
The external corrosion aspects are common across caisson types and can include atmospheric,
splash and submerged zones, with differing protection requirements based on exposure
severity and operating temperature. Many caissons will possess all three zones, whilst
some terminate in the atmospheric zone or, in the case of suction caissons, will be fully
subsea. Mitigation of external corrosion utilises the conventional options such as corrosion
allowance, organic/metallic coatings, CP etc. Other coating systems for enhanced corrosion
protection, fire protection or avoidance of marine growth accumulation, may be employed
in the splash zone. The mitigation of external corrosion is covered in more detail in I.11.
Internal corrosion threats for disposal caissons arise from corrodent species in the aqueous
phase. For untreated seawater disposal, e.g. from a once-through cooling system, the severity
of conditions is governed primarily by the presence of oxygen, the temperature of the waste
stream, and the flowrate (velocity), especially if particulates in the form of sand and/or scale
exist in the flow.
For produced water disposal, dissolved acid gases may also be present, although the
concentration will typically be low given that the water will have experienced low pressure
separation upstream. Residual CI may also be present. Produced water disposal is becoming
less common as a result of environmental restrictions on hydrocarbon discharge and disposal
wells are often favoured for this requirement. It is worthy of note that an interface in a
produced water disposal caisson will exist, where warm, potentially high chloride, oxygen-free
formation water will commingle with aerated seawater to produce a localised environment
with significant corrosivity. Depending on flow conditions, such an environment also has the
potential for promoting MIC.
The nature of the construction sequence for caissons often means that individual coated
sections are field/site welded into the structure in situ, in order to develop the full caisson
length. This presents a challenge for the internal coating of the field weld, in terms of access
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and quality control, and caisson failures due to omission of the coating in this area have
been experienced. One means of avoiding the need for localised coating application at field
welds is to use localised overlay of CRA; however, this construction method is to be used
with caution, as even where the CRA is coated to the maximum extent in order to avoid
adverse bimetallic interaction at holidays on the CS side, there remains a risk of localised
accelerated bimetallic corrosion if coating breakdown on the CS is experienced. This should
be reflected in the inspection strategy. Latterly, technology based on repair of buried water/
sewer systems has been developed to apply a more robust composite liner over the entire
caisson length, either in construction or remediation phases.
As discussed previously, other options for corrosion mitigation of disposal caissons include
the use of reinforced polymer composites and solid or clad CRAs. The former option requires
specific assessment of mechanical characteristics, including support arrangements, whilst
the latter is primarily a question of cost versus benefit, although some additional technical
challenges from the use of solid duplex stainless steel or titanium under external CP require
consideration.
These caissons are constructed with internal compartments, baffles, etc, to aid the
separation process. For CS caissons, this places an additional emphasis on the need
to ensure the internal barrier coating is fully continuous, particularly where the
construction sequence involves field welds. As with disposal caissons, there have been
separator caisson failures attributed to localised corrosion as a result of discontinuous
coating coverage. Other aspects of the design complexity are associated with the ability
to perform inspection on critical areas of the caisson and the pump itself, i.e. the potential
for mechanical damage, etc. These aspects are discussed further in the following sections.
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Vent
Oil Out
Open Solids/Closed
Drains Drains
L.A.T.
Solids/Closed
Drains
Open
Drains
Quiescent
Areas
Flowing
Zones
Sampler
Clean Water
Outlet
Figure I.73: Schematic diagram of a separator caisson, depicting the complex nature
of the internals
On the flow characteristics, whilst lower flow rates and semi-stagnant zones may be seen
as positive from a flow-assisted corrosion perspective in comparison with disposal caissons,
the nature of the fluid presents a high risk of MIC where coating is degraded or absent.
The combination of hydrocarbon nutrient source, commingled waters, oxygen and low
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flow are all clear contributors to an MIC risk, in addition to the corrosivity associated with
oxygenated warm waters. Whilst the use of a lining is the primary mitigation method
for the protection of CS caissons, biociding should be employed to control the
bacterial threat.
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As with other caisson types, the external corrosion threats and mitigation strategies are
common with general structure, so are not discussed further.
Pump (2 or 3 stages)
with anodes fitted
Centralisers
Suction strainer
(several sets)
Hypochlorite dosing
ring
Anti-fouling unit
(supported from motor)
Figure I.76: Schematic diagram of example seawater lift pump caisson, showing key
components
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For the internal surface of CS caissons, the two means of corrosion prevention are internal
coating and, where submerged, CP. CP is most typically applied in the form of sacrificial
anode bracelets/shells connected to the pump riser string and supported at the flanged
joints. It is essential that the continuity between the anode bracelet and the riser string is
confirmed during installation. Electrical continuity with the caisson is typically via the topside
riser connection to the structure and requires to be confirmed during commissioning.
The design of the CP system is required to achieve polarisation of both the pump string and
the caisson metallic surfaces. Due to the flow around the pump, the antifouling chlorination
and the mixture of materials of construction between the pump bowl, the pump string
and the caisson the conventional approaches to CP design, e.g. DNV RP-B401, have been
found to be inappropriate for the internal caisson, surface and riser string geometry and CP
modelling is suggested as a prudent approach to optimising design66. The CP design should
define a life expectation for the sacrificial anodes in order to plan for replacement in the
pump maintenance schedule, i.e. when the pump string is retrieved to surface.
One of the main issues with achieving protection of exposed caisson surface is the ability to
distribute ionic current through the seawater in the pump/caisson annulus to areas of tight
clearance, e.g. at the motor/pump67 The tendency in design is to maximise pump size for
performance considerations and minimise caisson diameter. The need to provide localised
sacrificial protection in this area is therefore highlighted.
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Figure I.77: Finite element CP analysis showing ineffective protection at the pump/
motor restriction67
In these restricted zones, lack of polarisation of both the CS and CRA surfaces can give
rise to unfavourable galvanic couples and accelerated corrosion. Furthermore, where the
caisson bore has been coated, this area is prone to localised damage due to contact with
the pump string (pump string centraliser contact is another potential source of damage),
which can exacerbate corrosion due to relative anode/cathode size. It is therefore good
practice to coat the pump string in order to minimise this effect (also to reduce anode
consumption) and some caisson designs do not use internal coating in the submerged
region to mitigate the risk of creating highly localised anodic surfaces on the caisson.
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Although not the subject of this section, a further consideration for CP is the risk of HISC
in duplex and superduplex stainless steel pump strings. The risk is mitigated using measures
recommended in DNV RP-F112, particularly coating of susceptible areas such as welds. Other
approaches, such as removing anodes or using low voltage anodes, introduce the risk of
accelerated consumption and/or underprotection of the caisson and pump string materials
which require protection, i.e. 22Cr duplex stainless steel.
As mentioned, there are other factors which can increase corrosivity for the caisson, particularly
in the pump intake area. Firstly, where there are turbulent conditions, additional mechanical
action and oxygen transport will be present. Secondly, where chlorination is employed for
anti-fouling purposes, the dosing requires to be controlled in order not to expose the caisson
to this additional oxidising species.
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I.17.3 PLAN
I.17.3.1 Policy
Caisson failure and the resultant risk of a large dropped object carries the potential for a
serious incident from damage to primary structure or pressurised systems. Other consequences
of caisson failure include downgraded situations in the event of loss of firewater capacity
or production impact from loss of cooling water disposal. Despite these highly significant
consequences, caisson failures are not uncommon in the oil and gas industry and the cost
of replacement of a failed caisson in situ can run into millions of pounds. The Duty Holder's
structural Integrity Management Policy should be to avoid such failures or reduce the risk
to ALARP.
I.17.3.2 Planning
The mitigation of caisson corrosion is strongly influenced by decisions made at the design
stage, where the details on materials, coatings, CP, etc, are decided. It is important that the
operator Materials and Corrosion Specialist be involved in the project design phase in order
to provide operational experience and ensure robust options are selected. Equally, it is crucial
that specifications and quality requirements are adhered to during fabrication, especially
where site welds are employed.
In the operational phase, the Duty Holder requires to implement corrosion mitigation
and inspection activities identified during the design stage and subsequent in-service risk
profiling, in order to minimise deterioration in service.
I.17.4 DO
Consequence of failure – the location of the caisson within the structure, potential trajectory
on failure and location of vulnerable pipelines/structure is the primary consideration.
Other considerations include the potential cost of replacement and the implications of
unavailability, e.g. for firewater, cooling water, etc.
Probable modes of failure – in some instances the mode of failure may be predictable
based on inspection findings, design review, etc, and inspection may be targeted to address
particular concerns, e.g. fatigue cracking at dead weight supports. The mode of failure will
naturally influence consequence of failure, i.e. failure above the dead weight support or at
the bottom of a lift caisson may have lesser consequences.
Construction details – risk assessment should make use of available information on the
caisson design and materials selection to identify any particular vulnerabilities in coating
integrity, CP coverage, contact damage from pump centralisers, etc.
Previous inspection findings – as with any risk based approach, the consideration of
previous equipment condition is a key aspect, particularly where coating repairs, structural
reinforcement or other modifications have been implemented.
Mitigation performance – review of the mitigation activity should be considered in the risk
assessment for operational assets. Examples of mitigation performance may include anode
change-out interval, CP monitoring where implemented and control of bacteria in disposal
caissons.
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I.17.4.2 Organisation
Organisational roles that can be involved in managing caisson integrity include:
−− Structural Engineer/TA who typically has overall responsibility for caissons.
−− Corrosion and Materials Specialist in the design and operational review.
−− Inspection Engineers who work closely with the structural and corrosion engineers in
the inspection activity.
−− Process Engineers where active mitigation is employed, e.g. biociding of separator
caissons.
−− Mechanical Engineer for aspects related to lift pumps, e.g. planning for anode
bracelet replacements.
I.17.5 CHECK
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I.17.6 ACT
I.18.1 Introduction
In ductile materials including austenitic stainless steels and aluminium alloys, no marked
embrittlement may occur, but there may still be a significant reduction in tensile ductility
(% elongation or % reduction in area).
Delayed brittle failure is a form of HE seen in high strength structural steels, titanium alloys
and aluminium alloys.
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H0 can react chemically with some metals, including titanium, forming brittle metal hydride
precipitates.
Hydrogen may also affect the plastic flow behaviour of metals which can reduce fatigue and
creep properties.
Cracking resulting from the precipitation of internal hydrogen 'fisheyes' in forgings, welds
and castings etc. is not addressed in this section.
High temperature hydrogen damage mechanisms are not addressed in this section. HTHA
(which affects steels operating at temperatures above ~400 °C in hydrogen environments)
is the result of hydrogen molecules dissociating, generating hydrogen atoms that dissolve
in the steel then react with the carbon in solution in the steel to form methane gas.
Sources of H0 include:
−− Cathodic protection – some hydrogen is generated on the surface of the
protected component. Subsea equipment, buried pipelines, jacket structures etc.
are therefore potentially at risk. The risk for CS is largely a function of CP potential
and the strength/hardness of the steel. The protected material can be polarised
to a very negative potential in impressed current systems, whereas in sacrificial
anode systems it cannot be polarised further than the anode open circuit potential;
this can result in a requirement for potential limiting devices in such systems. In
duplex stainless steels this mechanism is termed HISC; the risk of HISC depends
on the potential applied by the CP, the microstructure of the steel (specifically
the austenite spacing), hardness and the strain condition. DNV Recommended
Practice RP-F112 provides guidance on the design of duplex stainless steel subsea
equipment exposed to CP. Titanium is also at risk from damage when cathodically
protected to potentials more negative than ~−0,85 VSCE.
−− Electroplating – hydrogen is evolved on the component being electroplated. Zinc
electroplated fasteners are at significant risk of HE therefore it is standard practice
to remove the H0 from high strength steel fasteners by a 'relief bake'. Sensitive
materials (i.e. high strength steels) can be embrittled by the H0 generated during
the pickling stage of the hot dip galvanising process and by that generated during
corrosion of the zinc in wet conditions.
−− Corrosion – H0 generated at the cathode can enter the corroding metal (e.g. CS
or martensitic stainless steel) and cause embrittlement. In sour service the risk of
embrittlement is enhanced because a sulfide surface film encourages a higher
proportion of the hydrogen to enter the steel; the presence of a sufficient tensile
stress can cause the embrittled steel to crack (SSC). In a lower strength/hardness
steel that hydrogen may instead cause blistering if it combines to form hydrogen
molecules at inclusions, laminations etc. Depending on the exact conditions, this
may be termed hydrogen blistering, HIC, SOHIC or SWC. When dissimilar metals
are in direct contact in a sour environment the H0 generated on the corroding (least
noble) metal can diffuse through to the more noble metal (even though it is not
corroding), causing it to become embrittled. Tensile stress can result in cracking,
this is termed hydrogen stress cracking (HSC) or 'galvanically induced HSC'. When
dissimilar metals are coupled together in a non-sour environment there is some
risk of hydrogen damage to the cathodic metal but in practice this seems to be
confined to that of hydride damage of titanium at temperatures above ~80 °C, the
hydrogen resulting from galvanic corrosion of steel pipework. (Note that hydride
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−− High strength fasteners and chains – there have been numerous instances of high
strength bolting (any strength grade over 8) and chains (including mooring chains)
exposed to liquid water or atmospheric service. A recent high profile example is the
HE of tower anchor rods and seismic stabiliser rods (galvanised) on Oakland/San
Francisco Bay Bridge 69. These high strength steel components failed while being
loaded, but delayed cracking can also occur later in service. A number of crane
collapses have been attributed to the HE of connecting and slewing ring bolts.
−− Hub clamps – a 1″ diameter Vector 'Techlok' pipework clamp connector
catastrophically failed on an offshore production platform in December 2014,
causing a gas release70. Hydrogen generated during atmospheric corrosion of the
clamp caused the cracking of the steel which was 48–50 HRC, well above the
intended 22 HRC, due to poor control of heat treatment in the manufacturing
process.
I.18.2 PLAN
I.18.2.1 Policy
Hydrogen damage mechanisms can cause catastrophic failure of components such as:
pipelines; valves; fasteners; structural elements etc. fabricated from carbon and low alloy
steels; martensitic stainless steel; duplex stainless steel and titanium alloys. A company's
Integrity Policy and Strategy should therefore be to avoid such failures, or at least to keep
the risk ALARP.
I.18.2.2 Planning
The CMS will indirectly address the prevention of damage by hydrogen degradation by
considering the susceptibility of all materials of construction to these mechanisms.
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I.18.3 DO
I.18.3.2 Organising
That part of the Duty Holder which is responsible for managing corrosion risks should ensure
that hydrogen damage mechanisms are included in any Corrosion Threats Assessment
Studies that are conducted.
I.18.4 CHECK
The design and material selection should be reviewed and the level of susceptibility fully
assessed and determined as specified in the Planning and Corrosion Management Strategy
Risk Profiling.
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I.18.5 ACT
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ANNEX J
MITIGATION OF OIL AND GAS PRODUCTION AND PROCESSING
CORROSION THREATS
This section addresses oilfield chemicals associated with corrosion control and flow assurance
control, including:
−− corrosion inhibition;
−− bacteria control;
−− scavenging (oxygen and hydrogen sulfide);
−− mothballing and preservation;
−− mineral scales control;
−− wax control;
−− pour point depressants;
−− asphaltene control;
−− drag reducers;
−− hydrate inhibition;
−− foam control;
−− flocculants;
−− crude oil dehydration/desalting, and
−− water quality or water clarification.
In general, oilfield chemicals can be applied continuously or intermittently and are injected
with pumps to overcome the system pressure.
The decision to implement batch or continuous injection should consider the following
factors:
−− Batch injection is implemented where downhole CI is required, but it is too difficult
or too expensive to install downhole chemical injection facilities for continuous
injection.
−− Bull heading is the only mode of application to protect all wetted surfaces from fluid
inflow into the well.
−− Batch is preferred for very long residence time vessels where the dose rate of
continuous injection would be impractically low.
−− In pipelines with stratified flow, the top of the line may only be protected by batch
treatment between pigs.
J.1.1 Continuous
Chemicals are usually injected continuously, either because this is required for process
control, as in the case of demulsifiers, or because it is the most cost-effective method of
application, as in most CI applications. For continuous application, the dose rate must
be optimised to satisfy the requirements of cost-effectiveness and to limit the impact of
secondary issues caused by the treatment e.g. high CI dose rate is known to cause oil/
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water emulsion problems which affect the oil/water separation and water quality. The
point of application must be upstream of the location at which the chemical is required
to act in flowing systems to ensure adequate mixing with the process fluids and optimum
effectiveness, and the pump system must be capable of accurately delivering relatively
small volumes correctly sized to deliver the required chemical volume for long periods at
process pressures.
J.1.2 Intermittent
Intermittent treatments are used where short-term high dose rates are required to obtain
the desired effects or where continuous treatment is impracticable e.g. some downhole
treatments, pipeline pigging, etc.
A batch treatment is where a very high dose rate (hundreds of ppm to percentages) is
applied for a limited period. A typical example could be the periodic dosing of biocides into
a system or for long-term corrosion and integrity protection during mothballing operations.
A special form of intermittent treatment is the batch treatment used downhole. The
chemical to be applied is used to displace the produced fluids from the tubing string into the
reservoir, leaving the batch treatment soaking the tubing string. After the soak period
(typically hours) the well is brought back on-line to push the chemical from the tubing string
and surface equipment, leaving a residual protective film. This method may be used to apply
CIs to protect tubing where there are no means of applying continuous injection.
Squeeze applications are used downhole to protect tubing and topside equipment. The
chemical is pumped via the tubing string into the formation. During the soak period it is
allowed to absorb or precipitate onto the rock and when the well is brought back into
production the scale inhibitor very slowly leeches back into the water as it is being produced,
effectively protecting the wellbore and tubing string. As a general guide, one third of the
chemical is permanently lost to the formation, a third is returned immediately the well goes
back on stream and the remaining third is returned over a long period to provide the action
required. The most widely used example of this application technique is the control of
downhole scale deposition using scale inhibitors, which are typically diluted to 10–20 % into
a suitable carrier brine (e.g. inhibited seawater) in the main treatment stage.
Oilfield chemicals are invariably applied by accurately calibrated pumping systems or skids.
They should, as a minimum, comprise a pump which can deliver chemical at the required
rate and accuracy, a method of measuring the delivery rate of chemical and a chemical
storage tank adequately sized to carry enough chemical to be compatible with the logistics
of supply and distributions.
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Many oilfields chemicals, including some CIs, are very aggressive to materials in their neat
condition, therefore delivery system materials including injection quills, must be selected to
withstand those aggressive conditions.
The aim is to use the minimum concentrations to control and reduce corrosion to an
acceptable level, in line with the operating life of the facility. In a system it is not possible
to achieve 100 % inhibition of the internal pipework; typically, 95–99 % inhibition is more
realistic.
A typical continuous concentration range is 5–100 ppm, which, for a chemical having
solubility in all phases present, would be on total fluids. In the case of acidisation treatment
inhibition for well stimulations, the typical inhibitor concentration range would be 1–5 % of
the acid volume.
A number of alternative methods of treating oil/gas production wells also exist based on
intermittent batching of inhibitor into the well. Infrequent batching of large quantities of
inhibitor into the produced fluids, through a suitable downhole injection point, can produce
persistent filming.
J.1.4.2 Batch
Batch treating main oil lines and wet gas lines may be used to ensure good filming of the
metal surface, followed by continuous injection at a low level (5–10 ppm) to maintain and
repair the film. Batch treating is, however, generally used where continuous treatments
present technical difficulties. The CI should, where possible, be diluted in solvent for batch
treatments, downhole injection and gas lines.
J.1.4.3 Continuous
More than one application location may be required in order to compensate for depletion
of CI as the fluids move through the system.
Injection should be as far upstream as practicable, just upstream of a turbulent region (bend,
valve and pump) to ensure good mixing.
For protection of pipelines/transfer lines, injection should be downstream of the final process
oil/water separation stage if the separation process may be upset by the CI or high partition
losses to the separated water phase would occur.
CIs may also be applied to control corrosion in closed systems such as cooling/heating
medium systems. For instance, inorganic nitrite inhibitor may be added to cooling water. The
concentration is usually maintained at >1 000 ppm by adding measured volumes via a header
tank rather than via a pump skid.
The primary source of data for monitoring CI performance is from corrosion monitoring
devices such as coupons and/or probes. Corrosion monitoring provides the most rapid
information relating to the corrosivity of the fluids and therefore the effectiveness of the CI.
Corrosion monitoring data should be used to optimise the CI dose rate to give the specified
required corrosion rates, both for general and pitting corrosion. Corrosion coupons give
a historical integrated corrosion rate for the relatively long period that they were installed
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and therefore need to be correlated with the CI consumption for the same period. Where
suitable conditions exist, probes can be used to provide rapid data for much shorter periods,
or virtually instantaneously in the case of electrochemical devices.
CI residuals should be determined periodically by chemical analysis. This does not provide
information as to whether the CI is effective but it does indicate whether it is present at the
sample point at the specified minimum concentration.
Total and dissolved iron levels from the brine in a system that is treated with CI are useful
data to capture for trending purposes at a weekly frequency (refer to NACE SP0192-2012).
If production rates are steady a sharp increase in iron level in the brine could indicate that
accelerated corrosion is occurring.
Note that iron coming from the reservoir matrix (minerals such as siderite) can make it
appear there is more corrosion occurring. However, iron coming out of the steel from corrosion
can precipitate as solids lowering the iron count and make it appear there is less corrosion.
For CS pipelines the iron level can be correlated with manganese for corrosivity assessment.
J.1.4.4 Biocides
Biocides are usually applied as batch treatments sized to produce the maximum effectiveness,
unless it has been conclusively shown that low continuous dose rates are effective in
controlling bacterial activity. Batch treatments are designed for a short contact time (hours)
where the objective is to kill all of the organisms present.
The relationship between required contact time and biocide concentration is not linear
e.g. if 200 ppm for six hours is recommended, 400 ppm for three hours may not be effective.
If a biocide batching regime is proving to be ineffective when applying the same chemical,
e.g. on a weekly basis, a second biocide chemistry can be used in rotation with the first
chemical, i.e. biociding is still a weekly occurrence, but each chemical will be used fortnightly.
The advantage of this practise is the bacteria do not develop a resistance to one specific
biocide chemistry.
The dose rate is directly dependent upon the concentration of dissolved oxygen in the
system water, the performance of the deaerator tower and indirectly dependent upon the
available reaction time. Site tests should be performed to confirm the required dose rate.
A target of no more than 3,2 mg/l residual sulfite is desirable for removal of any increases in
oxygen levels from leaks.
Oxygen scavenger should be applied far enough upstream to allow adequate time for
the scavenging reactions. Where possible, potential sources of oxygen ingress should be
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eliminated to aid the scavenging process. Oxygen scavenger should not be applied at
locations where oxygen ingress would consume the available scavenger without the desired
effect of removing oxygen from the system fluids e.g. 'open' topped tanks.
Corrosion monitoring results may give an indirect indication of the unwanted presence of
oxygen. Most organic CIs are ineffective in the presence of oxygen therefore a significant
increase in corrosion rate in the presence of CI, when all other related parameters are
unchanged, may indicate the presence of dissolved oxygen.
Liquid scavengers, such as triazines may be injected directly into the gas stream through an
atomising quill. This ensures that there will be improved efficiency and further downstream
there will be a gas scrubber, which removes the unreacted triazine and the reaction
products. The use of aldehyde based scavengers is more common when treating crude oil
or multiphase lines.
Vessels, piping and columns should be drained, purged and cleaned and all fluids and
associated debris from the piping should be removed by flushing.
Serious corrosion during water-filled out of service lay-up is a risk unless an effective chemical
treatment package is applied throughout all the wetted surfaces of the asset, and that the
package is dosed at the correct concentration. The risk is especially acute for out-of-service
periods in excess of 18 months because the greatest risk is MIC, mediated by SRB, which
require time to grow and proliferate in order to cause accelerated localised corrosion.
These concepts apply to extended wet lay-up of newly commissioned pipelines and
equipment, following hydrotest and pre-commissioning as well as mothballing of pre-
existing equipment.
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Incompatibility between oxygen scavenger and biocide is common, in which case oxygen
scavenger may have to be dosed with a contact time of several minutes in advance of biocide.
For stainless steels, including duplex steels, there is a severe risk from chloride-induced pitting
or crevice corrosion during wet lay-up in the presence of chloride-containing water, the
initiation of which may be 'microbially-assisted' by biofilms, especially SRB.
Oxygen scavenger should be added in addition to biocide for waters containing greater
than 250 mg/litre chloride, because these materials are marginal at best for high chloride
water under stagnant conditions, especially at susceptible welds. In theory, pitting or crevice
corrosion cannot propagate unless supported by the consumption of oxygen on the general
metal surface outside of the pits.
The use of a CI is not required and is of no value for high chloride water in contact with CRA
materials.
Very good control of biocide dosing is needed and the biocide must have proven long-term
effectiveness, otherwise the residual scavenger may 'feed' SRB.
In order to be effective, the chemical should be deployed correctly. For example, injection
of scale inhibitor into a production system must be upstream of the mixing location of
incompatible waters.
Even though scale inhibitors may be applied intermittently in the form of squeezes, sufficient
concentration must always be present in the fluids to prevent deposition of scales. In the
case of squeezes, large volumes of scale inhibitor are 'lost' initially, in order to ensure the
minimum required concentration after acceptable elapsed times, i.e. the concentration of
scale inhibitor with time is a logarithmic decay.
For continuous injection applications, more than one injection location may be required
to compensate for possible depletion of available scale inhibitor as the fluids move through
the system.
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Scale inhibitor performance is difficult to monitor in the field. The minimum concentration for
effectiveness in laboratory tests should have been determined during the selection process.
From this, a minimum concentration in the field brine should be specified.
Scale inhibitors are consumed by scaling mineral species and may also be consumed
through sequestering elements such as iron. Water samples should be taken and stabilised
appropriately at the furthest upstream location in the system where scale deposition must
be avoided.
Plant inspection records may provide historical evidence for scale inhibition. Visual examination
should reveal the presence or absence of scale deposits. Whenever pipework/plant is opened up
or replaced in systems protected by scale inhibitor, it should be examined and reported upon for
any presence of scales.
Samples of scale deposits may be removed for analysis to determine the scale composition.
Deposits can occasionally be contaminated with Low Specific Activity (LSA) scale, also
known as NORM (Naturally Occurring Radioactive Material). Prior to handling the solids,
the radiation level should be checked by a suitably qualified person using a Geiger counter.
Advice should be sought on the radiation level permissible for solids analysis.
Scale coupons can be exposed in a system to test for scaling indications in a similar manner
to strip corrosion coupons. The flat side contains several small holes of varying diameter to
induce turbulence. Scale build-up is assessed visually, i.e. they are useful for qualitative rather
than accurate quantitative evaluations.
The chemical injection location should be upstream of the point/temperature at which the
first wax crystals can form. An exception to this may be made if the primary mode of action
of the wax inhibitors is as a surfactant or dispersant and it is not practicable to apply the
chemical when the crude oil is above the cloud point (temperature at which wax deposition
first occurs).
Where wax inhibitors are deployed to prevent wax depositions in pipelines, wax inhibitor
performance may be indirectly monitored by recording the increase in required pumping
pressure or ∆P (friction losses) with time. Wax inhibitor performance in pipelines can also be
monitored by analysis of the solids contents of pig traps.
Wax inhibitors may also be used in conjunction with demulsifiers to alleviate dehydration
difficulties caused by precipitation of waxes when the crude temperature falls below the
cloud point. The wax inhibitor and demulsifier performance is then monitored indirectly by
separation efficiency.
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The PPD has to be present in the bulk crude at the required concentration at all times to reduce
the high pipeline pumping pressures and start-up problems following a shutdown, therefore
the injection point must be upstream of the point/temperature at which the first wax crystals
begin to form and upstream of the pipeline/flowline which contains the susceptible crude oil
(whichever is furthest upstream).
The prime performance indicator for PPDs is laboratory measurement of yield stress from oil
samples collected periodically from the pipeline of interest. It is also possible to measure the
pour point of the treated crude oil in a laboratory at site using the ASTM D5853 method.
Methanol and ethylene glycol (MEG) are the main products deployed, and in order to be
effective they should be added continuously at concentrations typically 10–50 % based on
the aqueous phase. Alternatively they may be added as a slug dose to pipelines and wells at
start-up or prior to shut-in periods.
In downhole completion systems where capillary ('macaroni') tubing already exists continuous
injection may be possible.
Asphaltene inhibitors can be squeezed into the formation; however, these inhibitors are
necessarily oil soluble, resulting in a short functional lifetime for the inhibitor.
Injection must be at the beginning of the pipeline to achieve the required objective of
reducing friction losses.
The performance of drag reducers is monitored through pipeline pump pressure and flowrate
requirements.
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J.1.6.1 Flocculants
The purpose of flocculants is to aid water filtration or the removal of oil from water (where
they are termed 'reverse demulsifiers'). They are often applied at low doses in conjunction
with other chemicals, immediately upstream of water filters or occasionally to oily water
treatment plant. For oily water treatment they must be applied after the primary separation
of oil and water so as not to interfere with that process and still be present at sufficient
concentration to perform the required function.
Flocculants are deployed to increase the efficiency of filtration operations. The only effective
method of monitoring their performance is to monitor the performance of the filtration
package of interest.
Three major analytical procedures are usually employed to determine filtration efficiency:
(a) particle counters;
(b) gravimetric/membrane techniques, and
(c) ViPA (visual process analyser).
These three techniques allow the percentage efficiency of particle removal of a certain size
to be determined as well as an overall solids removal efficiency (as defined by weight). Most
filtration performance specifications are designed on both number particle removal efficiency
and total weight solids removal.
J.1.6.2 Antifoams
The required mode of action for antifoams in oilfield operations is to prevent the formation
of foams and the removal of foams after they form, therefore the chemical should be
applied immediately upstream of the vessels to be treated to avoid the possibility of affecting
upstream processes. The required dose rates of effective antifoams are very low. Care must
be taken to avoid over-treatments which could stabilise the foams.
Antifoam performance can be rapidly monitored from separation process performance. Fall
off in performance can be immediately indicated by such as high level alarms caused by
liquids carryover into the gas system. Both the optimum dose rate is obtained and product
performance is monitored through observing separator performance.
J.1.6.3 Demulsifiers
Demulsifiers are usually applied continuously at relatively low treatment rates to assist the
efficient separation of oil and water. In some specialised applications, such as for the removal
of emulsion pads, which can develop in tanks, short-term batch treatments at relatively high
treatment rates may be deployed.
Demulsifiers should be injected as far upstream of the separation facilities as possible to give
maximum benefit.
Demulsifier performance directly affects the system process performance. Demulsifiers are
utilised to enable oil/water separation during both dehydration and desalting operations.
The efficiency of both operations is directly related to demulsifier performance.
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The performance of reverse demulsifiers is monitored rapidly and directly through their
effect on effluent water treatment plant performance. Reverse demulsifier performance is
monitored through oil-in-water results obtained from downstream samples.
There are several methods available for measuring oil-in-water, one of the most common
being infrared absorbance. Oil is extracted from the sample with a suitable solvent such
as Tetrachloroethylene (TTCE) or hexane and absorbance of infrared light compared to
standards.
J.2.1 Introduction
Coatings are a primary method of corrosion protection, predominately used for protection
against atmospheric external corrosion. They are also used for protection from seawater
corrosion subsea and from a wide range of environments internally in processing plant.
Reference should also be made to Guidelines for the management of coatings for external
corrosion protection.
Most coatings are applied as relatively thin films of organic resin materials containing finely
ground inorganic pigments and fillers conveyed in a solvent, either organic or aqueous. These
are usually applied in a number of functional coats – a primer, for surface tolerance and
corrosion inhibition, a build coat for thickness and a topcoat for appearance. From a practical
point of view these coatings are generally the easiest to apply by spray, brush, etc. Nearly all
coatings used for external atmospheric protection are of this type, as well as some subsea
and internal coatings.
Some coatings are solvent-free, applied by airless spray or trowel and used for more
demanding applications including many internal protection applications. The build thickness
is higher and usually only one or two coats are used. These types of coating can also be
applied hot in piping spools, but this is a shop process.
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Figure J.82: Airless spray unit coating pipe internally with solventless epoxy coating
There are many special coating types, often thick film. Pipelines traditionally used fibre
reinforced bitumen and coal tar based coatings, but now use a variety of shop-applied
multi-layer coatings that include, for example, fusion bonded epoxy and thermoplastic layers
(i.e. three layer polyolefins).
Figure J.83: Multilayer pipeline coating – fusion bonded epoxy, copolymer adhesive
and polypropylene
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−− Surface preparation to remove contaminants and provide a key for coating adhesion.
Grit blasting, if acceptable, is much better than power and hand tool methods.
−− Design to avoid sharp edges, rough areas (e.g. weld caps) and difficult to reach
places where film thickness may not be achieved. Additional (stripe) coats are typically
required for such geometric features.
J.2.2 PLAN
J.2.2.1 Policy
Safety, environmental and commercial policies influence the choice of strategies for
mitigation and monitoring/inspection. Coating strategy depends mainly on the required life
and life cycle costing, which may be determined during the design phase.
J.2.2.2 Planning
Surface preparation and coating of all types needs careful quality control with attention to:
−− surface finish and cleanliness;
−− prepared surface profile;
−− paint film thickness;
−− curing and intercoat times, and
−− temperature and humidity conditions.
Blast cleaning provides the best surface preparation results, but in the operational phase this
may give rise to unacceptable contamination of plant areas and ignition hazards. Solvent
based materials may be a hazard. HP water blasting or hand tool preparation may be used
for preparation and water based paints for coating. However, both produce an inferior
coating life.
For accessible external coatings, the coating's maintenance is a 'high ticket' item in
maintenance budgets. The initial strategy may attempt to find an optimum between the
initial coating quality and cost and the coating maintenance costs that follow. Subsequent
maintenance strategy is generally one of the following:
−− Reactive maintenance following reports from inspection or coating condition survey.
Works where items are readily accessible, e.g. onshore plant and manned topsides.
−− A planned programme based on survey and prediction of coating breakdown. This is
better for inaccessible areas, e.g. splash zones and unmanned platforms.
−− Substrate condition monitoring, then coating maintenance only if metal loss trends
towards the limit for the planned item life. Requires engineering assessment of the
coated item, which is outside the scope of this section, but is considered in more
detail in I.11.
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−− Repair or replacement of the coated item if metal loss exceeds the limit, without
coating maintenance. Requires engineering assessment of the coated item, which is
outside the scope of this section, but is considered in more detail in AI.11.
Maintenance strategy needs to take account of operational restrictions for surface preparation
and painting when choosing methods and materials. This includes consideration of damage
to, and contamination of, plant areas, difficulties working on hot plant, ignition hazards, etc.
Normally inaccessible internal and subsea coatings will initially be chosen on lifetime
considerations. Coatings on subsea structures and pipelines are never replaced. Internal
coatings in vessels and tanks can be replaced at shutdown, but the lost revenue penalties
and cost of installing a high quality coating need to be taken into account in the life cycle
cost.
J.2.3 DO
Corrosion mitigation by coatings will feature in the CMS plan matrix alongside:
−− performance targets, usually in terms of coating breakdown;
−− monitoring by visual survey and survey frequency;
−− action required on non-conformance, and
−− organisational responsibilities for mitigation, monitoring and remedial action.
Tactical plans may jointly cover activities relating to other corrosion threats. There are some
proprietary database driven risk based methodologies for coating maintenance programme
planning.
Specific monitoring and inspection methods are generally confined to visual inspection.
Subsea, this will normally be by ROVs. For coating above water, Annex K, in BS EN ISO
12944-8 could be used for the measurement of coating deterioration.
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The CM strategic plan may be part of a wider Integrity Management Plan. For offshore
installations the strategic plan should be in line.
J.2.3.2 Organisation
The organisational roles that can be involved include:
(a) Corrosion and Materials Specialists;
(b) Coating Materials Suppliers and applicators;
(c) specialist contractors for coating maintenance planning;
(d) Facilities Maintenance Teams;
(e) subsea inspection teams;
(f) Inspection Engineers;
(g) Coating Inspection Technicians.
Those taking on the roles of (a) and (c) lead on risk assessment, planning and analysis; (d)
leads on mitigation implementation with support from (b), (e)., (f) and (g). who also takes a
lead on coating condition surveys.
Either specialist personnel or the inspection team may engage in coating condition
evaluation, but in either case appropriate training should be provided. The coating
maintenance planning contractors may provide condition evaluation training.
The main factors influencing coating deterioration are location and temperature. Coating
breakdown may look bad, but may not need urgent action unless it has led to serious
corrosion loss.
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J.2.4 CHECK
Breakdown of coating vs. expected life, however, can be used as a reactive (lagging) indicator.
The investigation will be in accordance with the CMS plan which may be part of a wider
Integrity Management Plan.
J.2.5 ACT
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Assessment of the coating condition72 can be carried out using Annex K in BS EN ISO 12944-8.
The following criteria are suggested to establish the recommended action.
Notes:
(a) Normally only the degree of rusting is relevant to corrosion loss resulting from coating
deterioration.
(b) 'Degree of rusting' is a measure of the extent of coating breakdown and not a
measure of metal loss. However, at Ri5 coating breakdown will have advanced to a
degree at which metal loss may be expected.
(c) For items sensitive to metal loss it is advisable to trend coating deterioration and
forecast when Ri4 may be reached and plan in advance for coating maintenance that
avoids corrosion loss of the substrate metal.
J.3.1 Introduction
There is no standardised definition of CRA. For the purposes of this document, a CRA is a
metallic material that is resistant to general and localised corrosion by oilfield environments
that are corrosive to CSs. This definition is in line with those adopted by NACE MR0175 and
ISO 21457.
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In practice, the term CRA covers stainless steels and alloys of nickel, copper, titanium and
cobalt. It excludes low alloy steels but includes some highly alloyed steels such as 9Cr-1Mo.
CRAs that do not find widespread use in process or utility systems in the oilfield include alloys
of aluminium, zinc and tin. Aluminium alloys are used for some structural applications, but
selection of a suitable grade is critical for successful service in offshore, marine and coastal
environments.
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The selection of CRAs is usually justified by considering life cycle costing, i.e. when the higher
CAPEX cost of their purchase at the fabrication stage reduces the OPEX costs associated with
the corrosion control options (inhibition, coatings, inspection etc.) required to achieve the
same service life with CS.
Depending on a number of factors, including the diameter of pipelines and pipework, the size
and pressure rating of vessels, the complexity of the manufacturing process (number of branches
and hence welds) etc., it can be most economic to use CRAs in the form of cladding or overlay
on a CS substrate, rather than in solid form. The strength of the product is provided by the steel
substrate; many CRAs are of lower yield strength than carbon steel, especially when used in the
solution annealed condition as is often the case for sour environments. Typically, a minimum
thickness of 2 or 3 mm of CRA is present; this layer provides the required corrosion resistance
for the service environment incorporating a safety margin against under-thickness, defects in,
and mechanical damage to, the CRA layer etc. CRAs commonly used in the form of cladding
include type 316L stainless steel, Alloy 625 and Alloy 825. External corrosion protection of the
steel substrate is typically provided by conventional anti-corrosion coatings, plus CP in the case of
buried or subsea equipment.
Plate steel can be purchased in clad form; the item of equipment (typically a vessel or larger
diameter pipeline) is then fabricated from that plate. The clad plate itself is manufactured
by roll bonding and explosive methods. The more common roll bonding involves hot rolling
CRA plate with the CS plate; diffusion of atoms across the interface creates a metallurgical
bond. Explosive bonding involves detonating an explosion in such a way as to force the CRA
and CS plates together; this causes deformation of the surfaces of both layers, creating a
mechanical bond.
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Seamless piping and smaller diameter pipelines (up to ~12–14") typically employ CRA cladding
or lining. Clad piping is made by thermo-mechanically processing (essentially extruding) a
CRA pipe within a CS pipe to achieve a metallurgical bond between the components. Lined
pipe is manufactured by inserting a CRA liner into the pre-heated CS pipe then hydraulically
expanding it but this produces limited bonding. Some CRAs, including 904L austenitic stainless
steel, can only be used in the form of lining or roll cladding because they are susceptible to
deleterious metallurgical changes if heated to the temperatures required for heat treatment
of the CS pipe when this is part of the cladding process.
A further technique is weld metal overlay. The CRA is deposited onto the CS substrate by
a welding process. This can be used for the fabrication of pipe but with obvious limitations
of geometry. It is used for strip cladding CS vessels after manufacture. Most commonly this
technique is used in the manufacture of discrete items such as valves; Alloy 625 is widely
used for Christmas tree valves.
The selection of CRAs can also be justified by their contribution to reducing the likelihood
of in-service failure (due to corrosion), particularly where the consequence of that failure is
severe in terms of safety, the resultant loss of production or environmental damage. However
,the process for justifying the selection of CRAs for this reason is complicated because the
limits of operation of each alloy (in terms of temperature, chloride content, pH etc.) are not
fully established for some grades. Where corrosion data are unavailable, and the engineer
considers it beneficial, application-specific qualification testing may be undertaken. One
consequence of this incomplete knowledge is that incorrect alloy selection can result in a more
rapid failure (e.g. through pitting corrosion) than CS would suffer in the same environment
through general corrosion. This problem is compounded by the difficulty in inspecting for
localised corrosion and SCC. More often, these issues probably result in conservatism in the
selection process, which in turn wastes money and the earth's resources.
Some CRAs can be susceptible to external corrosion and SCC in the marine atmosphere
and some industrial atmospheres. The oxidising nature of the external environment can
result in it being more corrosive than the (usually reducing) process environment. External
degradation is not visible on thermally insulated equipment but it can lead to catastrophic
failure.
The correct selection of CRAs for specific operating conditions normally considers the
following points:
−− The corrosion resistance of most CRAs is provided by a thin passive film (Cr2O3-rich
oxide film in the case of stainless steels). While that film is completely intact the
general corrosion rate is essentially nil (typically of the order of microns per year),
therefore no corrosion allowance is included in the design of items fabricated from
these materials.
−− In some circumstances the passive film can be completely removed from the
metal surface. Environments that can remove the passive film include strong acids
(therefore care is required to minimise exposure to well stimulation acids and
certain acid cleaning/descaling solutions), very strong alkalis and strongly oxidising
conditions. When the passive film is lost, general corrosion rates can be very high,
typically of the order of those on CS in the same environment.
−− Of greatest concern is the partial loss of the passive film from the metal surface. This
is most frequently due to the presence of chloride ions in the process stream and is
exacerbated by either oxidising conditions (including oxygen and chlorine) or reduced
sulfur species (sulfide, thiosulfate etc.). In these conditions CRAs become susceptible
to localised corrosion (pitting and crevice corrosion) and SCC mechanisms.
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Non-normal operation (including commissioning and upset conditions) can initiate localised
corrosion that then continues to propagate in normal operating conditions. Common
problems include leak testing (hydrotesting with water not meeting strict levels of cleanliness
or that is extended for unforeseen reasons can result in MIC), brief temperature excursions
(e.g. when the flow of cooling water to a heat exchanger is interrupted) and the ingress of
oxygen (at faulty pump seals or when a vessel is opened for inspection).
J.3.2 PLAN
J.3.2.1 Policy
Localised corrosion mechanisms tend to result in leak before break failures. However SCC can
cause catastrophic failure of components such as pipelines, valves, fasteners etc. fabricated
from CRAs. Additional failure modes apply to CRA clad and lined components. Company's
Integrity Policy and Strategy should therefore be to avoid such failures or at least to keep the
risk ALARP.
J.3.2.2 Planning
The CMS will indirectly address the risks associated with the use of CRAs and mandate the
use of appropriate inspection techniques to detect degradation by all the mechanisms to
which they are susceptible in normal operation, commissioning and upset conditions.
The American Society for Testing Materials (ASTM73) has a range of test methods for
determining the resistance of metals to: SCC; pitting corrosion; crevice corrosion; weldments.
J.3.3 DO
J.3.3.2 Organising
That part of the Duty Holder which is responsible for managing corrosion risks should
ensure that the risks associated with CRAs are fully addressed in any Corrosion Threats
Assessment Studies that are conducted.
CRAs in use in environments (normal operating or upset) in which they are susceptible to
SCC or a high rate of localised corrosion should be replaced if the consequence of failure in
service is severe and/or if the operator cannot be confident that the inspection programme in
place will provide early warning of degradation.
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J.3.4 CHECK
The failure in service of a CRA could indicate a more widespread problem such as:
−− incorrect material selection for a stream;
−− the use of defective material for fabrication;
−− inadequate QA procedures or material identification by the Operator, a contractor
or supplier, and
−− the process environment, external environment or upset condition is more aggressive
than anticipated.
J.3.5 ACT
The safe limits of use of CRAs are not fully understood, therefore any information relating to
failures in conditions in which the material was expected to be resistant is of great benefit
to the industry.
J.4.1 Introduction
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the structure/facility to receive protection, a suitable anode which can supply a potential
difference and both being in the same suitable electrically conducting environment.
CP is one of the main techniques used for protecting onshore buried or subsea pipelines
and structures against non-atmospheric external corrosion. CP can also be used to provided
internal protection in process vessels and storage tanks and can also be used for under tank
bases.
External protective coatings are normally used in conjunction with CP, to reduce the
amount of current required to be supplied by sacrificial anodes and/or transformer-rectifiers
to protect the at risk equipment/structures. In marine environments, calcareous deposits
(CaCO3 /Mg(OH)2) form also as a by-product of polarisation on the protected metal surface
(due to the increase in localised pH), these deposits act as an in situ coating, significantly
reducing the protection current required and their presence can be taken as an inference that
the item has been sufficiently polarised to mitigate corrosion.
Hybrid systems of the two principal CP methods tend to be comparatively rare, difficult to
manage and can be expensive. There may, however, also be a particular case where there is
some delay between full installation of a impressed current system and sacrificial anodes are
used as an interim protection measure.
The planned activities to ensure effective operation of the CP system should be correctly
implemented and the obtained monitoring data should be reviewed and properly analysed.
Measurement requirements to confirm protection may include: pipe-to-seawater/soil
potentials; anode current outputs; visual inspection of anode dimensions; pipeline/structure
isolation testing, etc.
Under protection is identified by instantaneous off potentials more positive than −0,8 V
(Ag/AgCl/Seawater) for Aerobic and −0,9 V (Ag/AgCl/Seawater) for anaerobic environments
respectively. Anaerobic environments may be commonly found in closed spaces such as
tanks, or in seabed mud or under heavy fouling and there may exist a potential for microbial
corrosion due to the consumption of dissolved oxygen.
For onshore equipment, the typical protection basis utilised is a potential in the range −0,85 V
to −1,15 V when measured using a Cu/CuSO4 standard reference electrode.
The other most commonly used criterion is the on/off potential which must be lower than
that of the freely corroding potential by 100 mv or greater.
It is important to note that overprotection can be a serious problem where high strength
steels such as duplex stainless steels are concerned due to susceptibility to HISC. Mitigation
includes mechanical design and materials related measures (refer specifically to DNV-RP-F112
for Duplex Stainless Steels) and potential limiting methods such as diode control.
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There are a significant number of relevant standards for the use and application of CP
generated by a number of National and international bodies and a number of the most
relevant are shown in the following section.
The full design basis should be defined in the early stages of design including proper
considerations of commissioning, possible out of service periods and decommissioning.
J.4.2 PLAN
J.4.3 DO
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Notes:
CP design basis should include the basis of design, surface area considerations, current
demand calculations (Initial, Mean and Final) and project-specific requirements in terms of
maintainability and system life.
Drawings are required including anode distribution, detailed design, manufacturing and
installation (including connections), transformer rectifier documentation including capacity,
control etc.
Sacrificial anodes should be supplied with all required testing and materials specification
certificates.
J.4.3.2 Organisation
A person/owner with overall responsibility for the CP system should be clearly identified (one
example being Materials and Corrosion Technical Authority).
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J.4.4 CHECK
It is important to define a holistic monitoring plan for CP systems. This should include regular
or periodic monitoring as well as longer term CP assessment and techniques applied also to
investigate anomalies, assess their significance and define remediation.
One example is standard monitoring using fixed reference test points with follow-up on
a longer frequency or, if anomalies are noted, using a more detailed survey such as Close
Interval Potential (CIPs) survey for an onshore pipeline.
The following shall be used as reactive performance indicators for both galvanic anode and
impressed current CP:
−− Signs of under-protection (examples may include general or localized corrosion
damage or rust discolouration etc.) marine growth and over-protection (examples
of which may include heavy calcareous deposits close to anodes) during potential
survey analysis.
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Notes:
If interference is identified, the chances of stray current corrosion being present are very high.
Visual inspection data should be carefully assessed (e.g. coating damage, anode condition,
connection cables, seals, corrosion damage etc.). Typically, visual inspection of anodes on
marine structures indicates anode condition and provides a basis for estimating future
anode life, ideally using metal gauges/calipers to provide a more accurate measure of anode
consumption.
Because potentials are not generally uniform over the surface of a cathodically protected
structure in seawater, the reference electrode must be placed relatively close to the surface
to accurately measure steel-to-water potential at any point and should always be as close
as possible. The higher resistivities in brackish waters can sometimes create issues in
measurement and this effect should be carefully analysed.
For structures in shallow water depths or vessels and where strong currents are not a
problem, the simplest method of checking level of protection is to suspend a reference
electrode from deck This may also be accomplished using an ROV and stab or proximity
potentials and is particularly of benefit under hull on vessels or in deep waters.
For completely buried pipelines it can be important to place the reference electrode directly
over the structure. There may be significant issues in respect of dry high resistivity soils, as the
voltage drop may turn out to be a significant factor.
Additional information such as, water temperature at the seabed: oxygen concentration at
the seabed,;pipe burial depth (if buried) and identification of exposed span lengths and
locations; water flow rates at the seabed, including seasonal changes if relevant etc. may be
included for offshore CP assessment. It is important in brackish waters to confirm resistivity
and impacts of reference electrode location.
Close interval potential surveys (CIPS-see SP0207-2007), direct current voltage gradient
(DCVG) surveys, C-scan survey etc. are only some of the techniques which may be used for
carrying out CP potential measurements. For onshore pipelines regular survey assessment
using test leads is typically designed in and may be located at ~one mile intervals. It is
important in more detailed surveys to confirm the area and point of minimum protection.
Inspection observations for onshore pipelines relate to 'digs' to investigate potential anomalies
for onshore pipelines or which may relate to diver/ROV assessments offshore.
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A more detailed assessment should be planned in the range three to five years or to follow
up any anomalies observed.
The planned maintenance activities to ensure effective operation of the CP system should be
correctly implemented and the obtained data should be reviewed and analysed.
The investigation will be in accordance with the CMS plan which may be part of a wider
Integrity Management Plan.
J.4.5 ACT
Performance review should include the following activities with appropriate corrective actions
identified in the overall CP strategy, organisation and planning activities if need be:
−− carry out ongoing review of transformer current/voltage trends for ICCP systems;
−− quarterly and annual reviews of potential measurement values;
−− annual review of performance measures, in particular the assessment of reactive
indicators and overall trends;
−− RCA of any visual findings or significant changes in potential measurement readings;
−− review of maintenance and replacement activities, and
−− review of impacts on system design lifetime.
Note:
Root causes may be many and varied, including: coating breakdown; stray current corrosion
as a result of interference; anode wastage; deterioration of anode/cathode connection(s);
deterioration of anode or CP cables, breakdown or degradation of electrical equipment
(e.g. power supplies).
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CP systems do deteriorate over time and this is not only related to the consumption of
sacrificial anode material.
A detailed plan should be produced to correct any audit findings and confirm future design
lifetime in relation to management aspects and future expected system operation.
J.5.1 Introduction
In addition to the materials selection and the application of a corrosion allowance, where
some deterioration of the component part is permitted within the design lifetime, other
common control methods are employed. These methods are often based on a physical
modification of the environment, examples of which are discussed in this section.
The primary aspect from a production perspective is that of separation where oil, gas and
water streams are effectively removed from each other to allow a better approach to the
correct corrosion control of these production streams. Heating may also be required when
the temperature is low to better promote separation and to reduce the water content of any
produced oil. There may also be additional downstream equipment utilised to remove high
levels of salts.
Additional mechanical equipment may be utilised to further mitigate against the consequences of
flow aspects and slugging of production fluids. The use of demisters to remove liquid droplets
from gas streams and the use of screens or post-separation, the use of hydrocyclones for the
removal of sand/solids is often employed.
Good operational monitoring and control can be a highly effective management approach
and can help in the early detection of damaging constituents such as sand or H2S. Following
detection, these species can then be managed by shut-in of wells, rerouting or possible
application of chemical scavengers, system flushing to prevent the build-up of damaging
corrosion species such as excessive levels of chlorides or heat stable salts.
Temperature control can also play an important role in the minimisation of corrosion aspects
by reducing corrosion reaction rates/kinetics or by ensuring critical thresholds/boundaries are
not crossed in terms of enabling a particular mechanism which may be related to either local
corrosion e.g. pitting or a potential for cracking to take place.
Proper filtration for the removal of constituents or particles can be beneficial in respect of
minimising any potential for under-deposit or microbial corrosion.
Velocity is a key control parameter in a wide range of applications. API14E is often applied for
materials in service without the presence of appreciable solids . Some materials have specific
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limits and the effects of seawater on CuNi materials can be appreciable when the velocity is
not controlled in the range 0,5–2,5 m/s. There are also limits on the applicability of corrosion
inhibition at high velocities, usually defined using a shear stress relationship.
There are also a considerable number of other related corrosion mitigation means such as
chemical treatment, including not only the control of pH, but also where scavengers are used
to remove damaging corrodent species such as oxygen or H2S. Careful design of chemical
treatments including mixing is essential as some chemicals which can be beneficial when
diluted are corrosive in their own rights and are hence damaging.
Some of the key aspects briefly discussed here are expanded upon in the following specific
sections.
In the case of oil production, target water levels in streams are typically less than 0,5–2,0 %,
but this is also related to whether the water may be fully entrained or may drop out and
accumulate. There are a number of rules of thumb dependent on water cut values which
may commonly range from 5–40 % however, this is dependent on associated flow patterns
and minimum velocity rules which can be difficult to achieve in practice. The type of
hydrocarbon liquid has a significant influence in this regard, e.g. water separates readily from
light condensates.
In gas streams dehydration may be accomplished by direct cooling of hot gas streams; as
the saturated water vapour content decreases with either increased pressure or decreased
temperature, the liquid phase is then separated. Conversely, for water saturated gas, another
means of corrosion mitigation is to reduce water condensation through the use of insulation,
bearing in mind that this may introduce a CUI risk. Other dehydration treatments rely on
the use of absorption and liquid desiccants such as TEG or adsorption using solid desiccants
as in the case of molecular sieve, and there are cases where a combination may be applied.
There are some limitations in either absorption or adsorption techniques which are usually
associated with the presence of impurities or build-up of contaminants over time.
A simple control basis is typically applied in gas systems where the constituents are well
known. This control measure usually requires careful monitoring to ensure that the stream
does not approach within a minimum of 10 °C of the stream dewpoint and should also
acknowledge potential effects of pressure drop within equipment or over valves, the impacts
of start-up/shutdown and loss of efficiency of dehydration systems over time. There are
often little or no additional control measures applied as it can be difficult to reliably predict
where condensation will take place and hence siting of corrosion probes or coupons may
provide little valuable information unless based on historical data, or drop-out is predicted.
J.5.3 Deaeration
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Oxygen is most commonly an issue in oil and gas production within source waters including
seawater or waters to be used within systems such as steam and condensate. Oxygen provides
a major pitting challenge on its own, and in combination with other corrosion mechanisms
can be extremely damaging.
Oxygen removal is required to reduce the potential for oxygen corrosion but also has the
added benefit of potentially reducing the level of any microbiologically influenced activity
present.
Careful control and monitoring is required to avoid what can often be quite significant
corrosion with both on-line monitoring and alarms being utilised. On-line measurement of
oxygen is comparatively commonplace but can be difficult to maintain reliably if there is
no redundancy built-in. Corrosion probes provide a good measure of system performance
typically using LPR probes but longer term reliability issues can be experienced and often ER
probes are utilised in combination to provide a longer term more reliable basis.
Efficient deaeration is also necessary within some ancilliary systems, with one example being
boiler and condensate corrosion. This also requires careful control of oxygen and the ppb
levels required are taken as function of pressure and which can again only be achieved by a
combination of mechanical and chemical treatments.
Gas blanketing can be used to try and minimise any impacts associated with oxygen corrosion
however, for any conventional nitrogen generator there is always likely to be some residual
oxygen present, commonly in the range 2–3 %. This can have a significant aspect particularly
in H2S-containing environments and can lead to the generation of free sulfur.
J.5.4 pH control
pH control typically sits under the section on chemical treatment; however, there are several
specific oil and gas applications which deserve specific consideration.
The pH stabilisation technique is a method commonly used for control of sweet corrosion in
wet gas pipelines and is a well established and studied method for control of CO2 corrosion,
typically using amine treatment plants. The pH in a CO2 environment is mainly determined
by the bicarbonate in the water and the CO2 partial pressure. An increase in the pH value
will reduce the bare steel corrosion rate and it will also promote the formation of protective
films. One of the biggest challenges with pH stabilisation is the risk for scaling, and a reliable
prediction of expected quantities of formation water is required. The design is normally more
complex than traditional systems and considerations of any potential interaction with MEG
systems and regeneration is essential. In partial pH stabilisation this may be combined with a
film-forming CI which is beneficial when some formation water is expected to be produced.
Organic acids will accumulate over time when using MEG also and may lead to other top-of-
line corrosion issues.
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J.6.1 Hydrotesting
Conventional oil and gas materials such as carbon steel and CRAs can suffer significant
damage due to corrosion when waters are improperly used in hydrotesting. There are many
instances of failure occurring shortly after hydrotesting as a result of the use of either poor
quality water sources or improper water treatment.
Corrosion may be general or local in nature, which is found to be due to effects such as
crevice corrosion, pitting, differential aeration effects or, as is often the case, MIC.
This is considered of particular relevance when the water used will be left stagnant over an
extended period as this can often lead to an increased propensity to under-deposit corrosion
or MIC due to the settlement of debris or solids.
There are often difficulties in unplanned extensions in hydrotesting and duration and
hence even when some maximum critical period is defined, chemical treatment is often
applied as a matter of course. One simple rule of thumb is that if water is considered to
be stagnant for a period of seven days or more, the water should always require chemical
treatment.
The potential for corrosion and the requirement for treatment necessary before hydrotesting
is strongly dependent on water source and this is usually either sea, river, or potable water.
The chosen source is usually that of the least contaminated but which is the most readily
available. Other water sources which could be used dependent on availability may also
include demineralised water or condensate.
Potable water is considered the best option for hydrotesting because it is low in chlorides and
solids, but it is also the most expensive and not always readily available and may still need
chemical treatment.
When seawater is used it should be sourced from a location free from external contamination
e.g. typically more than 20 m above the seabed and at least 15 m below the sea surface.
There is no maximum allowable chloride content of waters used in the testing of CSs.
However, the lowest chloride content water source available (i.e. conforming to other water
quality requirements) should typically be used. The maximum allowable chloride content for
stainless steels and nickel base alloys is typically taken as <50 ppm. In specific cases the use
of waters with low chloride contents could also be considered by use of simply flushing.
Higher chloride content waters may sometimes be used in cases with no viable economic
alternative (e.g. pipelines with a high internal volume dictating the need for seawater as a
hydrotest fluid). Chemical treatment is typically always required for high chloride content
waters in contact with CRAs.
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Anaerobic (very low oxygen) waters should not typically be used, as they may be indicative of
substantial contamination by chemicals and/or bacteria.
It may be possible to use alternatives to water (e.g. hydraulic fluids) which may be considered
for use in hydrotesting or the wet preservation of equipment. These should, however, be
treated to the same standards as required for hydrotest waters to ensure that all corrosion
mechanisms are properly controlled.
MIC is one of the most prevalent types of corrosion that occurs because of the development
of microorganisms. The uncontrolled use of waters has the greatest risk of MIC because
solids or organic materials may also be present.
The corrosion effects of MIC are usually seen initially at the bottom of pipes, vessels, or
at weld positions, where solids and also bacteria can settle. Bacteria form colonies which
can result in the formation of local concentration cells, and acids may be formed as
by-products which can significantly increase corrosion rates. Biocides can help to prevent
MIC at appropriate dosage rates providing they can contact the metal surface appropriately.
One critical aspect of corrosion due to hydrotest waters relates to the contact period. This
critical time period is sometimes taken as a function of Microbial activity where the cell
numbers exceed typically 105 when measured using MPN (Most Probable Number). This can
also be related to the initial concentration of bacteria in the source water, temperature and
the sulfate content.
The potential for system corrosion during hydrotest can also be mitigated by:
−− reduction in hydrotest duration;
−− reduction in the volume of any solids present using filtration;
−− reduction of oxygen present by use of a scavenger;
−− microbial control by the use of biocides, and
−− application of CIs.
A reduction in contact time be effective in limiting potential for microbial growth and hence
potential corrosion damage.
Filtration is considered an important control aspect and all natural waters for hydrotest
should be filtered using a 50 micron filter. Filtration reduces the amount of sediment entering
the pipeline or equipment and decreases the potential for MIC and under-deposit corrosion.
The use of raw unfiltered seawater is not considered to be acceptable.
Oxygen control is often considered even more critical for CRAs than CSs, because of the
greater susceptibility to crevice corrosion effects.
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DemineraliSed water, high purity steam condensate and potable water generally are not
required to employ filtration. Seawater and all brackish waters, however, should be filtered
to remove all particles greater than 50 μm.
Oxygen scavengers can sometimes be eliminated for non-critical equipment or where the
impacts of corrosion can be considered as negligible when consuming all the dissolved
oxygen.
There may, however, be some potential for interaction between any chemicals used and
compatibility and interaction aspects should be assessed specifically with chemical vendors.
Oxygen scavengers are usually added after filtration and must be given enough time to react
before other chemicals such as biocides are injected.
To determine if the water was effectively treated by any biocides, sampling may take place in
advance of treatment and as a normal process samples should be collected before and after
treating, following standard sampling and culturing procedures e.g. NACE TM0194-2004,
Field monitoring of bacterial growth in oil and gas systems.
Cleaning may also be required in addition to the use of biocides to ensure the surface of
any biofilm is stressed and to ensure more effective biocide contact with the metal surface
e.g. biocide treatments should be scheduled to take place as soon as practicable after any
pipeline pigging run.
CIs are sometimes applied if the duration is likely to be significant or where even minimal
rusting is not permitted.
There may also be issues post-hydrotest and these are typically related to either incomplete
draining and drying, and consideration should be given during design, if feasible to the
proper drainage of any equipment to be hydrotested.
Drain hydrotest water from the system and dehydrate as quickly as reasonably practical,
minimising exposure times. Where it is not possible to drain an intervention may be required
to remove water using manual cleaning and drying.
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Hydrotest water which has been chemically treated may not be able to be directly discharged
into the sea. It must meet environmental regulation requirements and may require treatment.
Chemical manufacturers should be consulted on the correct disposal procedures to meet
environmental guidelines.
J.6.7 Preservation
The required degree of preservation is primarily a function of the time for which a plant is to
be standing idle and primarily there should be some consideration of the economic viability
of preservation over simply that of future replacement.
Preservation is usually not required where the item will become obsolete or has already
undergone significant deterioration or the cost of preservation is likely to exceed 30 % of its
estimated future replacement cost.
Many preservation procedures require some maintenance or the use of utilities during the
out of service period.
Idle and retired pressure vessel equipment should be physically disconnected from remaining
active process equipment. It is not considered acceptable to isolate using valves that may
allow it to be accidentally reintroduced to service. Equipment and piping should also undergo
rigorous inspection prior to be placed back into service.
The equipment should be drained of inventory and then cleaned prior to preservation using
desiccants, oils or inert gases ensuring adequate sealing.
The preservation required for the exterior of an equipment should be determined largely by
the local corrosion conditions and the condition of any protective coating or covering, as in
the case of insulation.
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
Preservatives shall be renewed periodically, and flange covers reinstalled. Equipment, including
specifically heat exchangers should be inclined such that there is no possibility of water
hold-up within tubes or other vulnerable areas during the period of storage.
Longer term preservation is typically accomplished using an inert gas purge such as dry N2 at
a pressure typically >5 psi. Periodic review is required of pressure maintenance and to ensure
sealing is maintained.
For CRAs, and clad materials it may be acceptable to store filled with dry clean air, provided
no extraneous material contamination can take place. Vessels, equipment and piping of
austenitic stainless steel should be thoroughly cleaned and dried internally because deposits
or pockets of water can lead to serious local corrosion issues. Water containing chlorides may
cause SCC or pitting and there is also the possibility of MIC.
Insulated equipment shall have the insulation system maintained on an appropriate interval
to prevent the ingress of water. This also applies to the regular maintenance of external paint
systems relied upon for corrosion protection.
Inspect fireproofing at regular intervals and maintain in good condition, paying particular
attention to places where rainwater can penetrate.
In general, non-ferrous alloys should be kept clean and free from deposits externally to avoid
any potential for localised corrosion where not painted or shielded. Rotating equipment is
considered to be a special case and should be as per OEM specified requirements. Lubrication
systems should be circulated on an ongoing basis. Wherever water is being used for
preservation, inhibitor levels shall be checked on a regular basis.
Non-metallics can degrade due to exposure to direct sunlight, heat and general weathering,
which will cause deterioration of most plastic and rubber-based materials. Protection usually
involves shielding or covering but lifetime is still usually considered to be short and these will
usually require replacement.
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
ANNEX K
PERFORMING FAILURE INVESTIGATIONS
A generic outline of the steps that may be adopted as part of a failure investigation is shown
in Figure K.1.
Detailed site inspection to assess the extent of the Creates an appropriate team to provide specialist input
problem. Record and preserve critical samples to the investigation and assist with site inspection
Physical destructive Obtain data of the operation Obtain details of the design Research the plant operat- Carry out simulated
examination and up to and including the time and build of both ing, inspection and mainte- testing and modelling
analysis of the samples containment was lost. This equipment and process nance records
collected from site to may include obtaining
establish the failure witness statements from
mechanism staff
There are normally two distinct stages to any failure investigation which are either conducted
in series or parallel to each other. The first stage is the mechanistic study to determine how
containment was physically lost e.g. the type of corrosion (general, pitting, under-deposit,
microbiological etc), the type of cracking/fracture (ductile, brittle, fatigue); this study often
involves detailed examination. The second part is the causation study. This stage of the
investigation tries to establish what the circumstances were that caused the component to
fail by a particular mechanism.
A full RCA takes the findings of the failure investigation further by considering all aspects
that may have resulted in the failure of a component and uses techniques that are effective in
exploring some of the other contributors to failures, such as the human and economic factors.
Properly performed, failure analysis and RCA are critical steps in the overall problem-solving
process and are key ingredients for correcting and preventing failures, thereby achieving
higher levels of reliability.
Not all incidents of LOPCs require a full investigation. For example, a leaking potable water
tap may be caused by a worn or faulty washer. Instigating a full investigation in this instance
would serve little purpose and would be disproportionate to the problem in question.
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
Once a significant loss of containment has been discovered or reported, senior management
should assign a suitably experienced individual to drive and be responsible for the
coordination, management and completion of the investigation. This individual will not be
expected to cover all aspects of the investigation themselves. The candidate should have:
−− a thorough, analytical and logical approach to his/her work;
−− be assertive and a good communicator;
−− have good working knowledge and understanding of materials, manufacturing
methods and testing/examination techniques;
−− have good working knowledge and understanding for the affected facility plus
general/chemical/process engineering principles;
−− be familiar with how to conduct this type of investigation;
−− have a good working knowledge of what resources/specialists may be required to
assist in various aspects of the investigation, and
−− be empowered by senior management to investigate the problem.
The constitution/make-up of the investigation team will be dictated by the problem in hand
and may change and/or require input from other specialists as the investigation proceeds. The
investigation team may require input from both in-house resources and external consultants.
Figure K.2 gives an example of a team make up.
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Corporate/local HSE
Plant operation
Process/chemical/mechanical/materials
engineering specialists
Technical centre
External consultants
A basic understanding of the events leading up to the loss of containment and the
fluids/products which have been lost is an essential part of formulating any investigation
plan. A generic outline of the steps that may be adopted as part of an investigation is shown
in Figure K.1.
As failures of plant and equipment are often a result of an uncontrolled incident or occurrence,
an essential part of any investigation is ensuring the safety of those undertaking the hands on
investigation. All safety concerns must be fully assessed and appropriate procedures adopted
to mitigate any health and safety risks throughout the course of the investigation.
One of the most important first steps, where safety permits, is taking control of the damaged
component/item at an early stage (as soon as possible), especially if the more detailed
examination and analysis is to be carried out by others.
Once the site has been made safe, it is imperative for the 'first person on the ground',
be it the appointed Lead Investigator or Facility Manager, to preserve whatever evidence is
available. Both hard physical evidence (e.g. damaged items) and soft evidence (operating
records, witness statements etc.) should be preserved as quickly as possible because, in some
instances, evidence (including witness statements) can degrade with time.
It may be advisable for the Lead Investigator to delegate the site work to third party experts
in this type of 'forensic' engineering investigation or at least seek advice on sampling
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Control of the incident site is particularly important with regard to physical evidence and may
involve locking the incident site down. Inappropriate recording, poor/delayed sampling and
bad preservation of samples can introduce elements of doubt or limit the extent and range
of detailed examination/analyses possible.
Once the Lead investigator has an overall appreciation of the problem he can then devise
what additional inspection, if any, is required before sampling begins. If further inspection,
NDE e.g. dye penetrant inspection, at site is required, which may result in compromising
some of the hard evidence (e.g. corrosion deposits), then ensure that the evidence is sampled
prior to doing the additional NDE.
It is important to record the detail of the area of damage and to show how this relates to
the item as a whole. For example, showing a close-up photograph of a crack in a pipeline is
of little use if you are not able to determine from the photograph where in the pipeline the
crack is located. Photograph the crack and take general shots putting the location of the
crack into context, e.g. is it near to a flange?, is it at the 6 o'clock position?, etc.
Component samples should be taken and stored in such a way as to prevent further
damage during handling or degradation (e.g. protect from corrosion) in storage/transit. If
components have to be sectioned (e.g. a piece cut out of a pipeline), then this must be done
away from any features of possible interest. Hot cutting e.g. using oxyacetylene or plasma
cutting should be avoided if at all possible. If it cannot be avoided then any hot cuts must
be a minimum of 300 mm away from any possible features of interest that may be important
in the investigation. If samples are removed using an abrasive disc cutter then any cuts must
be a minimum of 100 mm away from any features of interest.
Great care must be taken in the removal and preservation of fractured/cracked components.
These must be carefully handled to prevent any crack/fracture surfaces suffering secondary
mechanical damage or corrosion which could remove the fine detail on the crack/fracture
surface which would allow positive identification of the cracking/fracture mechanism by
detailed examination. Under no circumstances should mating fractures be pressed back
together; this will inevitably lead to secondary damage.
Where samples are to be transferred to a laboratory for further examination, ensure that they
are adequately packed and protected to prevent handling and corrosion damage in transit.
It is essential that the entity undertaking this stage of the investigation has qualified and
experienced specialists with a proven track record of undertaking this type of work. The
success of this stage of the investigation is entirely dependent on the experience and
interpretation of findings by the specialist investigator(s). Unless specialists exist in-house
this stage of the investigation should be carried out by an approved and experienced
independent third party consultancy. Splitting of samples and sending different parts
of the same investigation to different specialists should be avoided. The laboratory
examination should be carried out or controlled/coordinated by one entity.
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There are no standard ways of completing the detailed laboratory examination of samples;
the tasks completed and analysis/testing undertaken are entirely dictated by the problem
being investigated and should be devised following an initial assessment of the samples by
the investigator. This stage of the investigation will almost certainly involve destructive testing
and so there will be permanent changes to the evidence. The sequencing of tasks should be
carefully thought through to limit any interference between the tasks.
It is frequently useful to include comparators in the lab investigation e.g. undamaged parts
of the same item/component or new unused items/components.
All aspects from the design, installation and commissioning, inspection and maintenance histories
through to the operation of the component or plant may need to be researched as part of
the causation study. It is not only important to look at the individual item that has failed, but
also how plant process upsets elsewhere may influence the operation and performance of the
failed item/component. Sources of information will range from the OEM to the plant records.
Literature and internet searches are also useful sources of information. Very often witness
statements of the individuals operating or directly controlling a component or piece of plant are
not officially recorded, so discussing the lead-up to a failure with these individuals can provide
valuable information in determining the cause of a failure. It should be noted that the greater the
time lapse between an incident occurring and interviewing witnesses will decrease accuracy of
recollection and increase the likelihood of discrepancies between witnesses.
Causation studies are not confined to desk top studies alone; they may involve simulated
testing or modelling. Replicating a failure under lab conditions is the ultimate way of
demonstrating that the mechanism and cause of failure have been accurately identified by
the investigator.
The terms of reference for the investigation detail the objectives (scope) and expected outcomes
(deliverables e.g. report) of each investigation. These will vary slightly from investigation to
investigation and should be agreed in advance. The main terms of reference (TOR) of any
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investigation should be aimed at not only identifying the mechanism(s) of failure but more
importantly the circumstances which led to the failure, i.e. the cause(s), so corrective actions
can be implemented to prevent a recurrence of the failure.
K.9 REPORTING
The report should clearly set out the results of all the investigations completed. It should set
down the background to the problem, and discuss the findings in a logical and systematic
way before coming to a conclusion. In many instances it will not be possible to be absolutely
certain with regard to the mechanism and cause of failure. In these instances, having gone
through reasoned arguments, the investigator, based on his experience and knowledge,
should state the most likely mechanism and cause of failure.
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Materials Methods
357
containment
due to leak at
a flange
Fitter used
inappropriate
Torque not uncalibrated
correctly applied Inadequate management of task, usual
supervisor off sick stand-in didn’t know equipment
during fitting of
the bolts that the fitter assigned was not Pipework subjected to high
competent/trained to do the work. vibration due to worn pump
shaft coupling.
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bolts from unapproved
supplier on cost basis
GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
People Environment
Figure K.3: Example fishbone diagram for the causes leading to a leaking flange
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
Technique Notes
Dye penetrant This uses either a coloured dye or fluorescent dye solution (sensitive to
inspection (DPI) ultraviolet light), applied to a clean surface. The dye penetrates cracks
and defects by capillary action. The excess solution is wiped off and a
quick drying matt spray developer is applied to the surface of the metal.
The dye stains the developer at defects. DPI will only detect surface
breaking defects
Magnetic particle The magnetic particle technique uses a spray fluid containing magnetic
inspection (MPI) particles. A magnetic field is applied across the material using either
a permanent magnet or an electro-magnet. A white matt spray paint
is often used to coat the substrate to improve the observation and
delineation of defects. The presence of a crack is indicated by a line of
magnetic particles which congregate at the discontinuity in the magnetic
field adjacent to the defect area. The surface of the material being
examined must be clean, dry and free from corrosion products. MPI will
only detect surface breaking or just subsurface defects in ferromagnetic
materials
Ultrasonic A transducer converts electrical signals to high frequency mechanical
inspection (UT) vibrations (sound). These waves (ultrasonic waves) are transmitted
through materials at a velocity which is dependent upon the properties
of the material and are reflected from either discontinuities within
the bulk material (e.g. defects) or from the back wall and collected by
a receiving transducer. Measurement of the time of reflection of the
ultrasound waves is used to estimate the thickness of the metal and
intermediate traces can indicate the location and length or size of cracks
or discontinuities
Radiography X-rays or gamma rays are able to penetrate materials and detect
subsurface defects. The depth of penetration is dependent upon the
beam energy, the density of the metal and its thickness. A photographic
emulsion plate placed on the opposite side of the material to the
radioactive source records a shadow graph, on which the darker parts
represent the more easily penetrated areas and the lighter parts are those
which are less easily penetrated. Restrictions in use due to health and
safety issues
Eddy current Eddy current techniques are useful for detecting pits and cracks in metal
inspection surfaces. The technique depends upon the detection of anomalies in
eddy currents produced in metallic surfaces in an alternating magnetic
field. The eddy currents produce a back electromagnetic force (EMF)
in the exciting coil, or in a secondary detection coil, which may be
amplified and analysed. A probe is traversed across the surface of the
material being examined and the changes in the back EMF analysed. The
equipment is relatively simple and comprises a generator, a detection coil
within a suitable probe and an analyser
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Technique Notes
Positive materials Examination to determine that the materials used in the fabrication of
identification vessels conform with the requirements of design specifications
(PMI)
on-site This technique is essentially non destructive although it does require the
metallography surface of the component to be polished and etched. This can obviously
be a problem in some structures as the surface preparation damages
protective coatings such as paint films plating etc.
A small area of the surface of a component is ground back using
progressively finer grades of abrasive papers. The surface is then polished
back using diamond paste impregnated pads to a 1 pm finish then
etched. Etching uses a variety of different chemicals dependent on the
material being examined. The etch reveals the microstructure of the
material. Careful examination of the microstructure is then undertaken
using portable microscopes
In many instances a more detailed examination of the microstructure is
required using fixed laboratory microscopes and/or scanning electron
microscopes. To get round this replicas are taken of the prepared and
etched areas. Polymer sheets (normally based on acetate) are softened
and laid onto the prepared areas. This moulds to the surface. The sheet is
allowed to harden and is then carefully lifted off
Portable The hardness of a component is a measure of a material’s resistance to
hardness testing plastic deformation. It generally involves forcing some form of indenter
into the surface of a material under a fixed or known load; the 'stronger'
the material the smaller the indentation. By measuring the size of the
indentation a measure of the material’s hardness is obtained. Hardness is
often one of the mechanical properties specified for a material. In many
materials such as steel the hardness can be directly converted into a
tensile strength using standard charts
As with many types of testing the results obtained from portable
hardness testes are dependent on the knowledge, skill and experience
of the operator. In the right hands these tests produce results that are
comparable to laboratory based equipment
359
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
ANNEX L
CHECKLIST FOR ASSESSMENT OF CORROSION MANAGEMENT IN
OIL AND GAS PRODUCTION AND PROCESSING FACILITIES
L.1 INTRODUCTION
The checklist (Table L.1) covers all the different areas of the CMS as described in the main
document, and is intended to be used by auditors to confirm that the CMS is being properly
implemented, and by individuals/organisations in setting up CMSsto ensure that all the
necessary actions and tasks are incorporated.
This checklist covers all the different aspects of a corrosion management system and as such
the entire checklist may not be applicable to the management system of particular facility
operators.
Reference should be made to the sections and items in the guideline document and the
informative information in Annexes A – H in order to interpret the questions.
In particular, auditors should bear in mind the scope of the document. The following terms
should be taken to include at least the scope described:
−− Item – vessel, pipe, structural member, pipeline section, subsea assembly:
−− Monitoring – on-ine corrosion rate and erosion monitors, on-line analysers and
instruments, sampling and chemical analysis, CP monitoring.
−− Inspection – vessel and pipework visual inspection, wall thickness NDT, subsea visual
inspection of pipelines, manifolds and structures, on-line inspection of pipelines,
visual survey of coating condition.
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
ANNEX M
INTERNATIONAL STANDARDS AND GUIDES RELATING TO
CORROSION MANAGEMENT
ENERGY INSTITUTE
ASME
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
API
ISO
15156 Petroleum and natural gas industries – Materials for use in H2S-containing
environments in oil and gas production
15589-2 (MOD) Petroleum and natural gas industries – Cathodic protection of
pipeline transportation systems
NACE
DNV
EEMUA
194 Guidelines for materials selection and corrosion control for subsea oil and gas
production equipment
NORSOK
367
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
ANNEX N
BIBLIOGRAPHY
ADCO
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EEMUA 193 Recommendations for the training and development and competency assessment
of inspection personnel
EFC 16 Guidelines on materials requirements for carbon and low alloy steel for H2S-Containing
environments in oil and gas production
EFC 17 Corrosion resistant alloys for oil and gas production: Guidance on general requirements
and test methods for H2S service
EFC 23 CO2 corrosion control in oil and gas production – Design considerations
EFC 55 Corrosion under insulation (CUI) guideline, Produced by EFC WP13 and WP15, ed. S
Winnik, ExxonMobil
L112 Safety of pressure systems. Pressure Systems Safety Regulations 2000. Approved Code
of Practice, 2nd edition
HSG65 Successful health and safety management, 2nd edition
HSR 2002 002 Offshore hydrocarbon release statistics and analysis, 2002. HID statistics
report, http://www.hse.gov.uk/offshore/statistics/hsr2002/hsr2002.pdf
PBN 99/4 Evaluation of process plant corrosion/erosion incidents
HID CI 5B Under-lagging corrosion of plant and pipework
OTI 95 635 A test method to determine the susceptibility to cracking of linepipe steels in
sour service
369
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13680 Corrosion-resistant alloy seamless tubes for use as casing, tubing and coupling stock
– Technical delivery conditions
15510 Stainless steels – Chemical composition
7539-7 Corrosion of metals and alloys – Stress corrosion testing – Part 7: Slow strain rate
testing
12747:2011 Petroleum and natural gas industries – Pipeline transportation systems –
Recommended practice for pipeline life extension
370
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Fundamentals of designing for corrosion control: A corrosion aid for the designer, R.J.
Landrum
MR0176 Metallic materials for sucker-rod pumps for corrosive oilfield environments
TPC 3 Microbiologically influenced corrosion and biofouling in oilfield equipment
TPC 5 Corrosion control in petroleum production, H G Byars, 2nd edition
MR0175/ISO 15156-1 Materials for use in H2S-containing environments in oil and gas
production – Part 1: General principles for selection of cracking-resistant materials
TM0177 Laboratory testing of metals for resistance to sulfide stress cracking and stress
corrosion cracking in H2S environments
TM0198 Slow strain rate test method for screening corrosion-resistant alloys (CRAs) for stress
corrosion cracking in sour oilfield service
TM0284 Evaluation of pipeline and pressure vessel steels for resistance to hydrogen-induced
cracking
Corrosion/97, Paper 58, Rippled strain rate test for CRA sour service materials selection, W J
R Nisbet, R H C Hartman, G van den Handel
Corrosion 2003, Paper 03179, Application of internal corrosion modelling in the risk
assessment of pipelines, Gartland,Per O, Johnsen, Roy and Ingar Øvstetun, Ingar
RP0192 Monitoring corrosion in oil and gas production with iron counts
RP0497 Field corrosion evaluation using metallic test specimens
RP0775 Preparation, installation, analysis, and interpretation of corrosion coupons in oilfield
operations
Technical Committee Report 1C187 Use of galvanic probe corrosion monitors in oil and gas
drilling and production operations
Technical Committee Report 3D170 Electrical and electrochemical methods for determining
corrosion rates
Technical Committee Report 3T199 Techniques for monitoring corrosion and related
parameters in field applications
Field guide for investigating internal corrosion of pipelines, R Eckert
NORSOK
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Recommended guidelines for the assessment and documentation of service life extension
of facilities
SINTEF
A15322 Ageing and life extension for offshore facilities in general and for specific systems
Other
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
ANNEX O
DOCUMENT REFERENCES
[1] http://www.hse.gov.uk/pubns/priced/HSG65.pdf
[2] http://www.hse.gov.uk/offshore/ageing/kp4-report.pdf
[3] http://www.iom3.org/corrosion-committee/corrosion-committee-board
[4] https://www.nace.org/Publications/Cost-of-Corrosion-Study/
[5] EI Guidelines for the materials selection and corrosion management of downhole
production and injection well equipment
[6] EI Guidelines for the avoidance of vibration induced fatigue failure in process
pipework, 2nd edition
[7] HSG 65 http://www.hse.gov.uk/pubns/books/HSG65.htm
[8] http://www.hse.gov.uk/offshore/offshore-oil-and-gas.pdf
[9] http://www.hse.gov.uk/risk/faq.htm
[10] www.hse.gov.uk/research/rrpdf/rr509.pdf
[11] http://www.hse.gov.uk/research/rrpdf/rr823.pdf
[12] Analysis of root causes of major hazard precursors (hydrocarbon leaks) in the
Norwegian offshore petroleum industry, Reliability Engineering and System Safety,
95/11, 2010, pp 1142–1153, Vinnem, Hestad, Kvaløy & Skogdalen
[13] http://www.legislation.gov.uk/uksi/2015/398/regulation/8/made
[14] http://www.legislation.gov.uk/uksi/2015/483/pdfs/uksi_20150483_en.pdf
[15] http://www.hse.gov.uk/risk/theory/alarpglance.htm
[16] The Management of Health and Safety at Work Regulations 1999
[17] http://www.hse.gov.uk/competence/what-is-competence.htm
[18] http://www.hse.gov.uk/competence/what-is-competence.htm
[19] www.hse.gov.uk
[20] http://www.engc.org.uk/
[21] http://www.engc.org.uk/engcdocuments/internet/Website/UK-SPEC%20third%20
edition%20(1).pdf
[22] Chemistry, Physics, Mechanical Engineering, Metallurgy, Chemical Engineering,
Maths
[23] https://www.gov.uk/government/uploads/system/uploads/attachment_data/
file/471452/UKCS_Maximising_Recovery_Review_FINAL_72pp_locked.pdf
[24] E.g. Institute of Corrosion, National Association of Corrosion Engineers, Institute of
Materials, Institute of Mechanical Engineers
[25] http://www.hse.gov.uk/humanfactors/introduction.htm
[26] http://www.hse.gov.uk/humanfactors/jee.htm
[27] https://www.energyinst.org/technical/human-and-organisational-factors/human-
factors-top-ten
[28] An independent review into the broader issues surrounding the loss of the RAF
Nimrod MR2 Aircraft XV230 in Afghanistan in 2006.
[29] The challenger launch decision: Risky technology, culture and deviance at NASA, The
University of Chicago Press Diane Vaughan.
[30] Health & Safety At Work etc Act 1974
[31] http://www.hse.gov.uk/risk/theory/alarpglance.htm
[32] http://www.hse.gov.uk/offshore/directive.htm
[33] HSE: The Safety Report Assessment Manual
[34] Fire, Explosion and Risk Assessment Safety Case Assessment Topic Guidance
[35] de Waard C, Lotz U (1994) Prediction of CO2 Corrosion of Carbon Steel EFC
Publication No 13. The Institute of Materials, London
374
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[36] de Waard C, D.E Williams (1975) Prediction of Carbonic Acid Corrosion in Natural
Pipelines, First International Conference on the Internal and External Protection of
Pipes, BHRA, Cranfield, UK
[37] NORSOK standard M-001, Rev. 5, Sept. 2014
[38] Zav'yalov, V. V., "Corrosion of Oilfield Pipelines", Protection of Metals, Vol. 39, No. 3,
2003, pp. 274–277.
[39] EEMUA 200 Guide to the specification, installation and maintenance of spring
supports for piping
[40] EI Guidelines for the integrity management of corrosion under pipe supports (CUPS)
[41] BS 4592-0:2006 + A1:2012, Industrial type flooring and stair treads – Part 0: Common
design requirements and recommendations for installation
[42] BS 4592-1:2006 Industrial type flooring and stair treads – Part 1: Metal open bar
gratings – specifications
[43] BS5395-3:1985 Stairs, ladders and walkways – Part 3 Code of Practice for the design
of industrial type stairs, permanent ladders and walkways
[44] NORSOK Standard C-002, Architectural components and equipment, edition 3, June
2006
[45] MMS Safety Alert 194: Guardrails (https://www.bsee.gov/sites/bsee.gov/files/safety-
alerts/safety/safety-alert-no-194.pdf)
[46] PD 6484:1979 Commentary on corrosion at bimetallic contacts and its alleviation
[47] EI Guidelines for the management of the integrity of bolted joints for pressurised
systems
[48] BS EN 61537:2007, Cable management – Cable tray systems and cable ladder
systems
[49] National Physical Laboratory, Guides for good practice In corrosion control – Pumps
and valves, http://www.npl.co.uk/lmm/docs/pumps.pdf
[50] HSE Offshore Information Sheet 7/2007 Stress corrosion cracking of duplex stainless
steel piping systems in hot chloride service.
[51] HSE RR129 Review of external stress corrosion cracking if 22 %Cr duplex stainless
steel.
[52] Chloride Stress Corrosion Cracking of Duplex Stainless Steels in the Absence of
Oxygen, HSE Research Report 298, 2005.
[53] NORSOK Standard M-001, Materials Selection.
[54] ISO 21457 Materials selection and corrosion control for oil and gas production
systems
[55] Definition from NACE Corrosion engineers’ reference book, 3rd edition
[56] NACE Corrosion engineer's reference book, 3rd edition
[57] EI Guidelines on sand erosion and erosion-corrosion management
[58] BS EN ISO 13703:2000 Petroleum and natural gas industries — Design and installation
of piping systems on offshore production platforms
[59] DNV RP O501 Erosive wear in piping systems
[60] API RP14E Design and installation of offshore production platform piping systems
[61] HSE RR115, Erosion in elbows in hydrocarbon production systems: Review document
[62] EI Guidelines on sand erosion and erosion-corrosion management
[63] Corrosion problems in seawater pump caissons. Practical solutions. S M Wigen &
H Osvoll. NACE Corrosion 2006, Paper 06105
[64] Internal corrosion protection of offshore sea water pump caissons, R Jacob,
J. Baynham, B. Wyatt & T. Froome, Eurocorr 2016, Paper 65987
[65] Industry survey study report – Offshore caissons integrity, iicorr June 2009
[66] Eurocorr 2016, Paper 65987
[67] NACE Corrosion 2006, Paper 06105
[68] HOIS(13)R6 Guidance on in-service inspection and integrity management of caissons,
375
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[69] https://www.nace.org/CORROSION-FAILURES-San-Francisco-Bay-Bridge-Bolt-Failure.
aspx
[70] HSE Bulletin ED 2-2015, 18/9/2015. Catastrophic failure of a pipework clamp
connector
[71] The standard scales for quantifying coating breakdown are in BS EN ISO 12944
Annex K, parts 1–8.
[72] Photographic and diagrammatic guides to the degree of rusting, etc, are available.
[73] www.astm.org
376
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ANNEX P
GLOSSARY OF TERMS
P.1 TERMS
Phrase Definition
as low as assessment of the risk to be avoided, and an assessment of the sacrifice
reasonably (in money, time and trouble) involved in taking measures to avoid that risk,
practicable and a comparison of the two to ensure there is no gross disproportionation
corrosion the corrosion management programme is that part of the overall
management management system, which is concerned with the development,
programme implementation, review and maintenance of the corrosion policy (HSE OTR
2001/044)
duty holder legally responsible person for the operation and safety of an installation as
defined in the Offshore Safety Case Regulations
hazard that which has the potential to cause harm or damage
installation an offshore structure associated with the drilling and/or production of
hydrocarbons as defined in the Offshore Safety Case Regulations
in-line refers to installation of monitoring equipment directly in the bulk of the
monitoring process, but data acquisition requires extraction of probes or process shut
down for analysis, e.g. corrosion coupons, bio-studs, etc
intrusive requires penetration through the pipe or vessel wall to gain access to the
monitoring interior of the equipment
key performance a measure of performance, preferably quantitative
indicator
non-intrusive monitoring from the outside of the pipe or vessel without having to gain
monitoring access to the interior of the equipment
off-line refers to measurements carried out on the equipment intermittently, for
monitoring example analysis of liquid samples, non-intrusive inspection (e.g. UT, PEC,
radiography, etc)
on-line refers to installation of monitoring equipment for continuous measurement
monitoring/ of metal loss, corrosion rate or other parameters in an operating system.
inspection Data are obtained without the requirement to remove the monitoring
device, e.g. LPR probes, ER probes, fixed ultrasonic transducers, etc
operator the operator of the pipeline is the person who has control of the pipeline at
any time during all stages of its life cycle from the design stage through to
final decommissioning
person a 'person' is an individual or company who has responsibilities for ensuring
the health and safety of employees and service providers when working on
a site for which they have responsibilities
proactive to investigate/review an item without any prior requirement. Use to predict
indicator events rather than to react to them. Also referred to as a leading indicator
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Phrase Definition
so far as is essentially the same as ALARP: assessment of the risk to be avoided, and an
reasonably assessment of the sacrifice (in money, time and trouble) involved in taking
practicable measures to avoid that risk, and a comparison of the two to ensure there is
no gross disproportionation
reactive indicator to investigate/review an item following an incident or some other factor
which prompts the investigation. Also referred to as a lagging indicator
risk the combination of the severity of the effect (the consequences) and the
likelihood of it happening (damage mode and probable frequency)
service provider a contracting or consulting company and/or person providing goods and/or
services to the Duty Holder or Owner of an installation
third party technical persons not directly employed by the Duty Holder or Owner of an
installation
P.2 ABBREVIATIONS
Abbreviation Description
ACOP approved code of practice
ALARP as low as reasonably practicable
ALE ageing and life extension
APB acid producing bacteria
API American Petroleum Institute
ASME American Standards for Mechanical Engineering
ASNT American Society of Non-Destructive Testing
ASTM American Society for Testing and Materials
CI corrosion inhibitor
CM corrosion management
CIP close interval potential
CMT corrosion management team
CMP corrosion management plan
CMS corrosion management system
CONC criteria of non-conformance
CoP cessation of production
CP cathodic protection
CRAS corrosion risk assessment system
CRA corrosion resistant alloy
CSWIP certification scheme for weldment inspection personnel
CTA corrosion threats assessment
DA deaerator tower
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Abbreviation Description
DCR Offshore Installations And Wells (Design And Construction, Etc)
Regulations 1996 (SI 1996/913)
DCS distributed control system
DNV Det Norsk Veritas
DCVG direct current voltage gradient
ECA effective corrosion allowance
EEMUA Engineering Equipment and Materials Users Association
EFC European Federation of Corrosion
EI Energy Institute (formerly the Institute of Petroleum)
EMF electromagnetic force
ER electrical resistance
EVS extreme value statistics
FSM field signature method
HAZ heat affected zone
HIC hydrogen induced cracking
HSC hydrogen stress cracking
HSE Health and Safety Executive
HS&E Health, Safety and Environment
HSG Health and Safety Guide
HSWA Health And Safety At Work Etc Act 1974
ICORR Institute of Corrosion
ILI in line inspection
ISO International Standards Organisation
KPI key performance indicator
LPR linear polarisation resistance
LSA low specific activity
MAPD major accident prevention document
MAWT minimum allowable wall thickness
MCDR material corrosion damage report
MHSWR Management Of Health And Safety At Work Regulations 1992
MIC microbially induced corrosion
MMA manual metal arc
MMS maintenance management system
MPN most probable number
NACE National Association of Corrosion Engineers, NACE International
NII non-intrusive inspection
NDT non destructive testing
OBVI opportunistic based visual inspection
OLI on line inspection
379
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IMPORTANT: This document is subject to a licence agreement issued by the Energy Institute, London, UK. It may only be used in accordance with the licence terms and conditions. It must not be forwarded to, or stored, or accessed by, any unauthorised user. Enquiries: e:pubs@energyinst.org t:
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
Abbreviation Description
OSDSCR The Offshore Installations (Offshore Safety Directive) (Safety Case etc.)
Regulations 2015
PCN personnel certification in non-destructive testing
PEC pulse eddy current
PFD process flow diagram
PFEER Offshore Installations (Prevention of Fire and Explosion, and Emergency
Response) Regulations 1995 (SI 1995/743))
P&ID piping and instrumentation diagram
PMR PM routines
PV pressure vessel
PLL potential for loss of life
PPD pour point depressant
PREN pitting resistance equivalent number
PSV pressure safety valve
PWC preferential weld corrosion
PWHT post weld heat treatment
PWRI produced water re-injection
QRA quantitative risk assessment
RAD radiographic NDT
RBI risk based inspection
RCS risk control system
SCADA Supervisory, Control and Data Acquisition (System)
SCR15 The Offshore Installations (Offshore Safety Directive) (Safety Case etc.)
Regulations 2015
SFAIRP so far as is reasonably practicable
SHE Safety, Health and Environment
SMS safety management system
SRB sulfate-reducing bacteria
SSCC sulfide stress corrosion cracking
TFD time of flight diffraction
TIG tungsten inert gas
TSA thermally sprayed aluminium
TQM total quality management
UK United Kingdom
UKAS United Kingdom Accreditation Service
UKCS United Kingdom Continental Shelf
UKOOA UK Oil and Gas Operators Association (Now UK Oil and Gas)
UT ultrasonic NDT
ViPA visual process analyser
380
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IMPORTANT: This document is subject to a licence agreement issued by the Energy Institute, London, UK. It may only be used in accordance with the licence terms and conditions. It must not be forwarded to, or stored, or accessed by, any unauthorised user. Enquiries: e:pubs@energyinst.org t:
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GUIDANCE FOR CORROSION MANAGEMENT IN OIL AND GAS PRODUCTION AND PROCESSING
Abbreviation Description
VPI vapour phase inhibitor
WSoE written scheme of examination
381
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IMPORTANT: This document is subject to a licence agreement issued by the Energy Institute, London, UK. It may only be used in accordance with the licence terms and conditions. It must not be forwarded to, or stored, or accessed by, any unauthorised user. Enquiries: e:pubs@energyinst.org t:
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Energy Institute (EI), funded by the EI’s Technical
Partners and other stakeholders. The EI’s Technical
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and future issues affecting those operating in the
Energy Institute energy industry.
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This document is issued with a single user licence to the EI registered subscriber: bob.conder@neptuneenergy.com. It has been issued as part of the [TECH PARTNER] Technical Partner membership of the Energy Institute.
IMPORTANT: This document is subject to a licence agreement issued by the Energy Institute, London, UK. It may only be used in accordance with the licence terms and conditions. It must not be forwarded to, or stored, or accessed by, any unauthorised user. Enquiries: e:pubs@energyinst.org t:
+44 (0)207 467 7100