September Attempt Online JEE Main 2021 01

1 SEPTEMBER SHIFT-II CHEMISTRY

1. (c) BOD is the biological oxygen demand. Cleanest water sample 8. (d) The crystal field stabilisation energy (CFSE) and magnetic
will have BOD value equal to (SO 2 ) moment (spin-only) of Co2 + octahedral aqua complex are − 0.8∆ o
3 ppm as clean water could have BOD value of less than 5 ppm. and 3.87 BM respectively.
2. (b) Calamine is the ore of Zn and is found as zinc carbonate
(ZnCO3), where malachite is the ore of copper and is found as eg
copper hydroxide [Cu(OH) 2] and copper carbonate [CuCO3]. 2+
+0.6Do
Co
3. (b) A functional group cannot be reduced by –0.4Do
d-orbital
Na/H 2 as it is not a reducing agent. t2 g
4. (c) According to Arrhenius equation,
CFSE = [( e − in t 2g ) × ( − 0.4) + ( e − in eg ) × 0.6 ] ∆ o
k = Ae −E a /RT
= [5 × − 0.4 + 2 × 0.6] ∆ o
As the temperature increases, rate constant k also increases which
= − 0.8 ∆ o
will generally speed up the process (increase the rate). So, graph
will exponentially increases as in option (c). Magnetic moment (spin only) can be calculated as :
µ = n(n + 2)
5. (a) Aniline reacts with potassium dichromate (K 2Cr2O7 ) to form
1,4-benzoquinone as the product. The nascent oxygen produced (where, µ = spin only magnetic moment and
from K 2Cr2O7 reacts with aniline to form 1,4-benzoquinone with n = number of unpaired electrons = 3
the removal of NH 4+ ion. = 3(3 + 2) = 15 = 3.87 BM
This reaction involves oxidation of aniline.
NH2 O
9. (b) Monomer units of dacron are ethylene glycol and terephthalic
acid.
K2Cr2O7 CH2 OH
+ NH+
4 HO C C OH +
CH2 OH
Aniline O O
O
(A)
1,4-benzoquinone Terephthalic acid Ethylene glycol

6. (c) Ethylbutanoate on reduction with LiAlH 4 and hydrolysis gives

butanol and ethanol. Butanol on further oxidation gives butanoic
acid which has four carbon atoms. The complete reaction is as  C C O CH2 CH2 O
follows
CH 3  CH 2  CH 2  C  O  CH 2  CH 3 O O n
 Dacron
O
Ethylbutanoate ( A ) 10. (a,d) Aromatic compounds are conjugated planar ring system having
+ delocalised π-electron clouds and follows ( 4n + 2) π-electron rule,
 LiAlH4 , H3O
i.e. Huckel’s rule. {n = 0, 1, 2 , K }
↓
CH 3  CH 2  CH 2  CH 2  OH + CH 3  CH 2  OH
Butanol ( B ) Ethanol (a) 10pe– in cyclic conjugation place.
 Oxidation It is aromatic.
↓
CH 3  CH 2  CH 2  C  OH (b) 4pe– in cyclic conjugation
 It is anti-aromatic.
O Å 4pe– in cyclic conjugation.
Butanoic acid (C) (c) CH3
It is anti-aromatic.
7. (b) According to type of reaction for colloid preparation, colloids
6pe– in cyclic conjugation.
have been classified. (d) It is aromatic.
A. Hydrolysis —FeCl3 + 3H 2O → Fe ( OH) 3(sol) + 3HCl
B. Reduction— 2 AuCl3 + 3HCHO + 3H 2O →
2Au(sol) + 3HCOOH + 6HCl 11. (d) The Fe2 + ion has green colour while Fe3 + is yellow in colour.
C. Oxidation— SO2 + 2H 2S → 3S (sol) + 2H 2O 12. (b) trans-but-2-ene forms meso product i.e. 2 identical mesomers
D. Double decomposition— when undergoes electrophilic addition of bromine.
As2O3 + 3H 2S → As2S3(sol) + 3H 2O Br2(CCl4) H Br+ H
Hence, the correct match is ≡≡
[Br—Br]
A → 4, B → 1, C → 3, D → 2. Br
⊕ CH3 CH3
trans-but-2-ene
02 Online JEE Main 2021 September Attempt

H3 C Br+ H H Br NaNO2+HCl Å
H (b) H3C NH2 H3 C NººNCl
CH3
H CH3 p-methylaniline Most stable diazonium
Br s Br CH3 salt due to +H effect
(Identical meso product) ⊕
Or 2 NaNO + HCl
(c) CH 3  CH  NH 2 → H 3C  CH  N ≡≡ N
Br+ Br CH3  
H3C H CH 3 CH 3
H
2-methylethanamine
H H3 C
CH3 Br NaNO2+HCl
H
Br s (Identical meso product) (d) NH—CH3 N—CH3

N-methylaniline N==O
13. (c) Hydrogen peroxide reacts with iodine in basic medium to give I−
(Iodide ion). N-alkyl nitroso amine
I2 + H 2O2 + 2OH − → 2I− + 2H 2O + O2
Diazonium salt is not formed rather N-alkylnitroso amine is formed
14. (d) Propene (C3H 6) undergoes acidic hydrolysis to give A which is as product.
2° alcohol. This alcohol undergoes iodoform reaction in presence ∴ In option (b) the most stable diazonium salt is formed.
of KIO and dil. KOH to give iodoform alongwith potassium salt of 17. (d) Potassium ferrocyanide solution {K 4 [Fe(CN) 6 ]} will give prussian
carboxylic acid.
blue colour when added to ferric chloride (FeCl3) due to formation
This reaction is known as iodoform test. of iron (III)hexacyanoferrate (II).
H+ / H2 O FeCl3 + K 4 [Fe(CN) 6 ] → Fe4 [Fe(CN) 6 ]3
CH 3  CH == CH 2 → CH 3  CH  CH 3
Acidic hydrolysis Iron (III) hexacyanido-ferrate (II)
Propene 
(C3 H6 ) (Prussian blue colour)
OH
(A ) Å
Propan-2-ol 18. (d) (a) Structure of N2O N N––O
KIO/Dil. KOH s + O Å Å O
→ CH 3  C  O K + CHI3
Iodoform (b) Structure of N2O4 N––N
 Iodoform
(B ) O O
O
Potassium salt of O Å O
ethanoic acid (c) Structure of N2O3 N––N
(Postassium acetate) O
(C )
O O
15. (c) Nucleophilic addition of sodium hydrogen sulphite (NaHSO3) to (d) Structure of N2O5
Å Å
N—O—N
carbonyl compound (aldehyde or ketone) involves proton transfer
O O
to form a stable ion.
The oxide without nitrogen-nitrogen bond is N 2O5.
OH
O O 19. (a) For the oxides Li2O, CaO, Na 2O2 , KO2 , MgO and K 2O,
NaHSO3 Transfer of proton C
C ==O C O
S Li2O ⇒ O2−
Carbonyl S s
compound O—H O CaO ⇒ O2−
O
O
Na 2O2 ⇒ O2–
2
Stable ion
(due to conjugation) KO2 ⇒ O−2
Hence, statement I is true. MgO ⇒ O2−
Nucleophilic addition of HCN (hydrogen cyanide) to an K 2O ⇒ O2−
aldehyde/ketone yield cyanohydrin as final product.
∴ Electronic configuration of O2−
2 molecule is
OH
==O
HCN σ1s 2 , σ *1s 2 , σ 2 s 2 , σ * 2 s 2 , σ 2 p z2 , π2 p x2 ≈ π2 p y2 ,
CN π * 2 p x2 ≈ π * 2 p y2
Carbonyl Cyanohydrin
compound Hence, O2−2 is diamagnetic in nature as no unpaired electron is
present.
Hence, statement II is false.
Electronic configuration of O2− is : 1s 2 , 2 s 2 , 2 p 6
16. (b) Primary amines react with NaNO2 and HCl to give diazonium
Hence, O2− is also diamagnetic.
salts.
Electronic configuration of O−2 is :
Å
NH2
NaNO2+HCl
NººNCl σ1s 2 , σ *1s 2 , σ 2 s 2 , σ * 2 s 2 , σ 2 p x2 , π2 p y2 ≈ π2 p z2 ,
(a)
Cl π * 2 p y2 ≈ π * 2 p1z
Propylamine Diazonium salt
Since, unpaired electron is present in π * 2p z orbital.
Therefore, O−2 is paramagnetic in nature.
∴ Only KO 2 is paramagnetic oxide.
 03

20. (d) Iron (Fe) has electronic configuration [Ar] 3d 5 in +3 oxidation −176 
= 57.8 kJ/mol −  298 × kJ [∴1 kJ = 1000 J]
state.  1000 
Electronic configuration of Fe = [ Ar] 3d 6 , 4 s 2 = − 5.352 kJ/mol
3+ 5 | ∆G | = 5.352
Electronic configuration of Fe = [ Ar] 3d .
Hence, answer is 5.
21. (2) Weight of empty LPG cylinder = 14.8 kg
Weight of full LPG cylinder = 29 kg 24. (2) [Ag(NH 3) 2 ][Ag(CN) 2 ] complex dissociates into [Ag(NH 3) 2 ] + and
∴ Weight of gas = 29 − 14.8 = 14.2 kg [Ag(CN) 2 ].
If weight of full LPG cylinder = 23 kg Oxidation of Ag in [Ag(NH 3) 2 ] +
then weight of gas used = 29 − 23 = 6 kg at ambient temperature. Ag + 0 × 2 = + 1
From ideal gas equaiton, pV = nRT Ag = + 1
Weight of solute Oxidation state of Ag in [Ag(CN) 2 ]−
or pV = × RT
Molecular mass of solute Ag + ( −1) × 2 = − 1
W Ag − 2 = −1
or pV = × RT
M ⇒ Ag = + 1
Applying ideal gas to LPG cylinder when gas is full, ∴ Sum of oxidation states of two silver ions in
pV = nRT [Ag(NH 3) 2 ][ Ag(CN) 2 ] complex is 2.
14.2 kg 25. (2) Given, mass of Na = 8g
3.47 atm × V = × RT …(i)
M Molar mass of Na = 23 gmol −1
Applying ideal gas to LPG cylinder when gas is reduced to 23 kg at
ambient temperature, Weight of sodium atom Number of atoms
=
pV = nRT Molecular mass of sodium atom Avogadro’ s number
8.2 kg 8g Number of atoms
p ×V = × RT …(ii) =
M 23 g 6.022 × 1023
Divide Eq. (i) by (ii) 8 × 6.022
Number of atoms = × 1023
14.2 kg RT 23
3.47 × V M Number of atoms = 2.09 × 1023
=
p ×V 8.2 kg × RT
x≈2
M
3.47 14.2 Hence, answer is 2.
=
p 8.2 26. (64) Given, mass of CuSO 4 .5H 2O = 80 g
3.47 × 41 The concentration of copper sulphate solution is x × 10−3 mol/L.
⇒ p= = 2.003 atm
71
Number of moles of solute
Hence, answer is 2. Molarity = …(i)
Volume of solution (L)
22. (2) Zn(OH) 2 q Zn 2+
+ 2OH −
S 2S Molar mass of CuSO4 ⋅ 5H 2O = 63.54 + 32 + 16 × 4
Due to common-ion effect (presence of NaOH) the concentration of = 5 × 18 = 249.54 g/mol
OH − will be (2S + 0.1) ≈ 0.1 Weight of solute
(Q 01
. > > 2 S) Number of moles of solute =
Molecular mass of solute
∴ Solubility of product,
80 g
Ksp = ( 0.1) 2 × S = = 0.32 mol
249.54 g/mol
2 × 10−20 = 0.01 × S
Volume of solution = 5 L
2 × 10−20
⇒ S= = 2 × 10−18 From Eq. (i),
0.01 0.3205
Molarity = = 64.11 × 10−3 mol/L
∴ x=2 5
Hence, answer is 2. ∴ x = 64.11
−1 x ≈ 64
23. (5) Given, ∆H = − 57.8 kJ mol or
∆S = − 176 JK −1 mol −1 Hence, answer is 64.

T = 298 K 27. (2) Energy of photon is given as

nhc
Using Gibb’s free energy relation E= …(i)
λ
∆ G = ∆ H − T∆ S
where, E = energy of photon (50 W),
where, ∆G = change in Gibb’s free energy
n = number of photon
∆H = change in enthalpy
h = Planck’s constant (6.63 × 10−34 Js)
T = temperature
c = speed of light (3 × 108 m/ s)
∆S = change in entropy
∆G = 57.8 kJ/mol − [298 K × ( −176 Jk −1mol−1)] λ = wavelength of light (795 × 10−9 m)
04

E = 50 W = 50 J = energy of photon l κ 1.07 × 106 S m−1

⇒ = = = 26 × 104 m−1 ⇒ x = 26
n × 6.63 × 10−34 J s × 3 × 108 m/ s A G 4.115 Ω −1
50 J =
795 × 10−9 m ∴ Answer is 26.
50 × 795 × 10−9 30. (3) Peptide synthesised by reaction of glycine, leucine, aspartic acid
⇒ n=
6.63 × 10−34 × 3 × 108 and histidine is as follows.
17 20 O O
= 1998.49 × 10 = 1.998 × 10
H2N—CH2—C—OH + H2N—CH—C—OH—H2N—CH—C—OH
⇒ ≈ 2 × 1020
∴ x=2 O CH2 CH2
∴ Answer is 2. Glycine CH—CH2 COOH
28. (173) Spin only mangnetic moment is given as Aspartic Acid
CH3 +
µ S = n(n + 2) BM
Leucine H2N—CH—COOH
where, n = number of unpaired electrons
Electronic configuration of B 2+ is as follows CH2

B 2+ = σ1s 2 , σ *1s 2 , σ 2 s 2 , σ * 2 s 2 , π2 p1y ≈ π2 p z0 N

∴ B 2+ has one unpaired electron, NH
Histidine
µ = 1 (1 + 2) = 3 = 1.73 BM
= 173 × 10−2 BM O O O
∴ x × 10−2 = 173 × 10−2 ∴ x = 173
H2N—CH2—C—NH—CH—C—NH—CH—C—NH—CH—COOH
Hence, answer is 173.
CH2 CH2 CH2
29. (26) Conductance (G) is reciprocal of resistance (R).
1 1 1 CH COOH N
R= or G = = = 4.115 Ω −1
G R 0.243 Ω H3C CH3 NH
Relation between conductance (G), O
l 
conductivity ( κ) and cell constant   is given as 3 peptide linkage  ) are present.
( C NH 
 A
Hence, answer is 3.
Gl
κ=
A