DEXTER TEST SERIES 1.

0 (PAPER-5)

SECTION-A

Single Answer Correct Type Questions

1. 1. How many pairs of species/molecule have same shape but different

hybridization amongst the following:
(i) XeF2, CO2 (ii) I3− , HgCl2 (iii) XeF4, SF4 (iv) SO2, OCl2
(A)1 (B)2 (C)3 (D) 4
2. Use the following data to answer the question below:

H
⎯⎯⎯
2
Ni
→

(H = –28.6 Kcal mol–1)

excess H
⎯⎯⎯⎯⎯
Ni
2
→

Anthracene (H = – 116.2 Kcal mol–1)

Calculate the resonance energy of anthracene:
(A)84 Kcal/mol (B)100 Kcal/mol
(C)110 Kcal/mol (D)116 Kcal/mol

3. O

H2N O
( i) NaOH+Br
⎯⎯⎯⎯⎯⎯
2
→ Pr oduct
+
(ii) H , 

(A) (B)
O H
N
H2N O O

OH
(C) O (D) H2N O
H
N

4. In the given reaction,

( A ) + RMgX ⎯⎯⎯⎯
+
H /H O
→ 3 2
Alcohol (A) can not be
(excess)
(A) R— C — Cl (B) R— C — OC2H5
|| ||
O O
O (D) O
|| ||
R— C — R R— C — H
(C)

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5. Tautomerism is not exhibited by

(A) (B)
CH CH OH O O

(D)
O O

(C) O
O
6. Match the following:
Column-I Column-II
(A) Boric acid (P) sp2 hybridised boron
(B) Diborane (Q) Ring having 6 e– delocalised
(C) Borazine
(D) Boron Nitride (R) Bond having partial double bond
character
(S) sp3 hybridised boron

(A) A→PR B→S C→PQR D→PQR

(B) A→P B→P C→PQ D→PQ
(C) A→R B→S C→PQR D→PQR
(D) A→RS B→PR C→PQ D→PR

7. Equivalent mass of As2S3 and KMnO4 during the formation of H3AsO4, H2SO4 and Mn2+
ions are respectively :
(A) M/2, M/5 (B) M/6, M/5 (C) M/28, M/5 (D) M /14, M/3
8. 0.1 M NaCl and 0.05 M BaCl2 solutions are separated by a semi-permeable
membrane in a container. For this system, choose the correct answer :
(A) There is no movement of any solution across the membrane
(B) Water flows from BaCl2 solution toward NaCl solution
(C) Water flows from NaCl solution towards BaCl2 solution
(D) Osmotic pressure of 0.1M NaCl is lower than the osmotic pressure of BaCl2
9. Glucose reacts with acetic anhydride to form :
(A) hexaacetate (B) tetraacetate
(C) monoacetate (D) pentaacetate

10. R − O − Na + R' X ⎯⎯→ R − O − R' + NaX

Choose incorrect statement regarding the above reaction

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(A)It is a nucleophilic substitution bimolecular reaction

(B)The alkoxide of Na may be primary, secondary or tertiary
(C)The alkyl halide should be primary
(D)It is used to prepare only symmetrical ethers

11. The Ksp of the base M(OH)3 is 2.7  10–11 then the concentration of -OH is:
(A)3  10–3 M (B)4  10–3 M (C)3  10–2 M (D) 4  10–2 M

12.
HNO3 +H2SO4
Cl ⎯⎯⎯⎯⎯⎯
H3C →

Identify the major product

(A) (B)
O 2N
H3C Cl

H3C Cl
NO 2

(C) (D)
NO2
H3C Cl

H3C Cl
O 2N

13. Arrange the following in decreasing order of basicity

(I) Aniline (II) p-nitro aniline
(III) N, N dimethyl aniline (IV) N, N, 2,6 tetramethylaniline

(A)I II  IV  III (B) III  IV  I  II

(C) III  I  IV  II (D) IV  III  I  II

14. The wavenumber of last line of Lyman series of hydrogen spectrum is 109674 cm -
1
. The wave number of H line in Balmer series He+ is?
(A)438696 cm-1 (B)106974 cm-1
(C)30465 cm-1 (D) 60930 cm-1
15. Which of the following is polar and aromatic?
(A) (B)
O

(C) (D) None

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16. The IUPAC name of [Ni (NH3)4] [NiCl4] is:

(A) Tetrachloronickel (II) tetra ammine nickel (II)
(B) Tetraammine nickel (II) tetra chloronickelate (II)
(C) Tetraamminenickel (II) tetrachloronickel (II)
(D) Tetrachloronickel (II) tetra amminenickelate (O)
O
LiAlH4
17. O C NH2

OH
(A) (B)
HO NH2
HO NH2

O
(C) (D)
O NH2
HO NH2

18. Which of the following is not correctly matched ?

(A) Phenol + CHCl3 + NaOH ⎯⎯⎯
→ Salicylaldehyde
heat

(B) Phenol + Phthalic anhydride ⎯⎯⎯

→ Phenetole heat
H2SO4

+
(C) C6H5 — N  NCl
–
⎯⎯⎯→
H3PO2
C6H6
H2O

(D) C6H6 + CH3COCl ⎯⎯⎯→ C6H5COCH3 + HCl

anhyd
AlCl3

19. In the reaction, 4A + 2B + 3C → A4B2C3, what will be the number of moles of product
formed, starting from 1 mol of A, 0.6 mol of B and 0.72 mol of C?
(A) 0.25 (B) 0.3
(C) 0.24 (D) 2.32

20. The stability of dihalides of Si, Ge, Sn and Pb increases steadily in the sequence:

(A)GeX2 < SiX2 < SnX2 < PbX2 (B)SiX2 < GeX2 < PbX2 < SnX2

(C)SiX2 < GeX2 < SnX2 < PbX2 (D)PbX2 < SnX2 < GeX2 < SiX2

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SECTION-B

Numerical/Integer Type Questions

1. The sum of co-ordination number and oxidation state of central metal ion (x)
complex formed, when excess of KCN is added to aqueous solution of copper
sulphate is________.

2. For how many reactions product formation is favoured by decrease in

temperature and pressure?
(1) CO2 ( g) + C ( s ) 2CO ( g) Ho = 172.5 KJ

(2) CO ( g) + 2H2 ( g) CH3OH ( ) Ho = −21.7 KJ

(3) 2O3 ( g) 3O2 ( g) Ho = −285 KJ

(4) H2 ( g) + F2 ( g) 2HF ( g) Ho = −541 KJ

3. The minimum number of carbon atoms for an alkene hydrocarbon to exhibit
optical isomerism is_________

4. What is the molarity of HCl in a solution prepared by dissolving 36.5 g HCl in 123.5
g ethanol if the density of the solution is 0.80 g/ml?

5. The sum of highest possible oxidation states of uranium and plutonium, is

____ :

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ANSWERS

1. C 2. A 3. B 4. D 5. B

6. A 7. C 8. B 9. D 10. D

11. A 12. A 13. D 14. D 15. B

16. B 17. B 18. B 19. C 20. C

1. 5 2. 1 3. 6 4. 5 5. 13

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