The document is a test paper for F.Sc Part II Chemistry, focusing on aldehydes and ketones. It includes multiple-choice questions, short answer questions, and a section requiring explanations of specific chemical reactions and mechanisms. The test assesses knowledge on reactions, properties, and preparation methods related to organic compounds.
The document is a test paper for F.Sc Part II Chemistry, focusing on aldehydes and ketones. It includes multiple-choice questions, short answer questions, and a section requiring explanations of specific chemical reactions and mechanisms. The test assesses knowledge on reactions, properties, and preparation methods related to organic compounds.
The document is a test paper for F.Sc Part II Chemistry, focusing on aldehydes and ketones. It includes multiple-choice questions, short answer questions, and a section requiring explanations of specific chemical reactions and mechanisms. The test assesses knowledge on reactions, properties, and preparation methods related to organic compounds.
The document is a test paper for F.Sc Part II Chemistry, focusing on aldehydes and ketones. It includes multiple-choice questions, short answer questions, and a section requiring explanations of specific chemical reactions and mechanisms. The test assesses knowledge on reactions, properties, and preparation methods related to organic compounds.
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Series Chemistry F.
Sc Part:II Ch:12 Group B ID:
Test :06
Q No: 01Choose the correct answer. Fill the bubble on answer sheet. 1 ×10=10 1.Aldehydes and small methyl ketones react with saturated solution aqueous solution of sodium bisulphate to form crystalline precipitate of adduct: (a)Coloured (b)Blue (c)Green (d)White 2.Aromatic ketones are not given names: (a)IUPAC (b)Latin (c)Trivial (d)English 3.Cannizzaro’s reaction is type of reaction: (a)Self oxidation-reduction (b)Disproportion reaction (c)Addition reaction (d)a and b 4.Which of the following can be used for the oxidative preparation of aldehydes from alcohols? (a)Pt-asbestos (b)FeO and Mo2O3 (c)Na2Cr2O7 and H2SO4(d)All of these 5.Reducing agent which attack carbonyl compound in NaBH4 is: (a)H (b)H- (c)H+ (d)H2 6.Which of the following is unsymmetrical ketone? (a)(CH3)2CO (b)C2H5OC2H5 (c)C3H7COCH2CH2CH3 (d) C2H5CO(CH2)2CH3 7.H-CH2OH→H-X.Here X is: (a)An aldehydic group (b)A carbonyl group (c)A hydroxyl group (d)A carbonyl group 8.For a ketone R-CO-R,R cannot be: (a)Same alkyl (b)Aryl and Alkyl (c) Alkyl and H (d)Different alkyl 9.Which substance does not oxidize easily? (a)CH3CH2CHO (b)HCHO (c)CH3CHO (d)CH3COCH3 10.Strongest reducing agent that can reduce the Tollen’s reagent is: (a)Formaldehyde (b)Benzaldehyde (c)Acetaldehyde (d)Acetone
Subjective
QNo: 02Give the short answers of these questions. (Any six) 2 x 06=12 I. How acetone is prepared from calcium acetate? II. Give reaction to produce alpha-hydroxy acid from aldehyde. III. Discuss the chemistry of Tollen’s test. IV. Fehling’s solution reacts with aldehydes to give red ppt.Justify it. V. Give mechanism of cannizaro’s reaction. VI. Which are those weak oxidizing agents,which can oxidize aldehydes but not the ketones?
Q.No:03 4+4=8 a)Write two methods for the preparation of formaldehyde. b)Explain the mechanism of aldol condensation.
