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David Gonzalo Reyes Silva

The document presents calculations related to the Van Laar activity coefficient, including various data points and graphical representations of the relationship between variables. It includes tables for molar fractions in the vapor phase and pressure data, as well as equations for regression analysis. The results indicate the behavior of a mixture of methyl ethyl ketone and toluene at different temperatures and compositions.

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tarea 3

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David Gonzalo Reyes Silva
3 views29 pages
The document presents calculations related to the Van Laar activity coefficient, including various data points and graphical representations of the relationship between variables. It includes tables for molar fractions in the vapor phase and pressure data, as well as equations for regression analysis. The results indicate the behavior of a mixture of methyl ethyl ketone and toluene at different temperatures and compositions.

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The document presents calculations related to the Van Laar activity coefficient, including various data points and graphical representations of the relationship between variables. It includes tables for molar fractions in the vapor phase and pressure data, as well as equations for regression analysis. The results indicate the behavior of a mixture of methyl ethyl ketone and toluene at different temperatures and compositions.

Copyright:

© All Rights Reserved
Download as XLSX, PDF, TXT or read online from Scribd
Download as xlsx, pdf, or txt
3 views29 pages

tarea 3

Uploaded by

David Gonzalo Reyes Silva
The document presents calculations related to the Van Laar activity coefficient, including various data points and graphical representations of the relationship between variables. It includes tables for molar fractions in the vapor phase and pressure data, as well as equations for regression analysis. The results indicate the behavior of a mixture of methyl ethyl ketone and toluene at different temperatures and compositions.

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© All Rights Reserved
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ec 1

1
2

COEFICIENTE DE ACTIVIDAD CON VAN LAAR


SOLUCIÓN:

GE/RT X1 GE/RT*X1*X2 RT*X1*X2/GE


0 0 0 0
0.032 0.0895 0.39269 2.54655
0.054 0.1981 0.33993 2.94179
0.068 0.3193 0.31286 3.19629
0.072 0.4232 0.29496 3.39030
0.071 0.5119 0.28416 3.51913
0.063 0.6096 0.26472 3.77758
0.051 0.7135 0.24949 4.00819
0.038 0.7934 0.23183 4.31359
0.019 0.9102 0.23246 4.30189
0 1 0.00000 0.00000

RTX1X2/GE vs X1
5.00000
4.31359 4.30189
4.50000
4.00819
f(x) = 2.1749943297347 x + 2.45093595300214 3.77758
4.00000
RTX1X2/GE vs X1
5.00000
4.31359 4.30189
4.50000
4.00819
f(x) = 2.1749943297347 x + 2.45093595300214 3.77758
4.00000
R² = 0.981701396367179 3.39030 3.51913
3.50000 3.19629
2.94179
3.00000 2.54655
2.50000
2.00000
1.50000
1.00000
0.50000
0.00000
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

Pendiente 2.175
Termino Indep 2.4509

A´12 0.408013382839
Solver-----> A´21 0.2161741849597 Pendiente calculada
xi Temperatura(°C) Pvariable
metil-etil-cetona 0.9 78 683.784109562955
tolueno 0.1 78

ON VAN LAAR Y1 1.0012619368417


Y2 1.2126468654102
4.31359 4.30189
4.00819
58
4.31359 4.30189
4.00819
58

0.7 0.8 0.9 1

2.17499925
FRACCION MOLAR EN LA FASE VAPOR, LEY DE RA

A B C Psat(mmHg) yi Ki
7.06356 1261.339 221.969 722.207777 0.9518 1.05752554
6.958505 1346.773 219.693 271.939223 0.0482 0.48226661
Balance de fr 1.0000

TABLA PARA LA GRAFICA

x1 x2 Y1 Y2
0 1 1.5038272865 1
0.1 0.9 1.3215565847 1.00651787
0.2 0.8 1.2072441643 1.02246607
0.3 0.7 1.1328019795 1.04417574
0.4 0.6 1.0832923734 1.06941598
0.5 0.5 1.0501559045 1.09676856
0.6 0.4 1.0281882384 1.12530183
0.7 0.3 1.0140695773 1.15438918
0.8 0.2 1.0055973664 1.18360252
0.9 0.1 1.0012619368 1.21264687
1 0 1 1.24131858

P vs x-y
750
700
650
P vs x-y
750
700
650
600
550
500
450
400
350
300
250
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0
N LA FASE VAPOR, LEY DE RAOULT MODIFICADA, CON PRESION TOTAL IGUAL A LA SEMISUMA DE PRESIONES DE

y1 y2 Presion Balance
0 0.99979687 271.994473 0.99979687
0.27917653 0.72055449 341.876324 0.99973101
0.43933298 0.56042472 396.911297 0.9997577
0.55247133 0.44742044 444.250241 0.99989176
0.64184278 0.35787437 487.572473 0.99971715
0.71747961 0.28215027 528.538195 0.99962989
0.78407482 0.21541321 568.235725 0.99948803
0.84434066 0.15510832 607.169921 0.99944899
0.89986667 0.09970332 645.65142 0.99956999
0.95177298 0.04822666 683.78411 0.99999964
0.99931108 0 722.705666 0.99931108

P vs x-y
P vs x-y

0.4 0.5 0.6 0.7 0.8 0.9 1


LA SEMISUMA DE PRESIONES DE SATURACION PQ NO HAY DATO DE PRESION TOTAL.

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