Test ID : 957

E- mail : gpccnamakkal@gmail.com Website : www.gpccnamakkal.com

.UNIT TEST - 14.

Std : TEST SERIES Max. Marks: 180
Test Date : 02.12.2024 CHEMISTRY Time : 1 Hr.
Note :
For every correct answer four marks will be awarded. For every wrong answer one mark
will be reduced. For unanswered questions zero mark.
Choose the correct answer : 45 x 4 = 180
1. 2,4-dimethyl-3-pentanol is a 6. HBr reacts fastest with

1) Primary alcohol 2) Secondary alcohol 1) 2-Methyl propan-2-ol

3) Tertiary alcohol 4) Dihydric alcohol 2) Propan-1-ol
2. The enzyme which converts glucose to ethyl 3) Propan-2-ol
alcohol is 4) 2-Methyl propan-1-ol
1) Zymase 2) Invertase 7. Assertion (A) : Solubility of n-alcohol in
3) Maltase 4) Diastase water decreases with increase in molecular
3. Ethanol and methanol are miscible in water weight
due to Reason (R) : The hydrocarbon part in
1) Dissociation of water alcohols increases with increasing molecular
weight which permit enhanced hydrogen
2) Their acid character
bonding with water.
3) Allyl groups
1) Both (A) and (R) are true and the (R) is a
4) Hydrogen bonding
correct explanation of the (A)
4. CH3 – CH = CH2 can be converted to propan-
2) Both (A) and (R) are true but (R) is not a
1-ol by oxidation. Which set of reagents
correct explanation of the (A)
among the following is ideal to effect the
3) (A) is true but the (R) is false
conversion
4) Both (A) and (R) are false
1) Alkaline KMnO4
8. Conversion of cyclohexanol into cyclo hexene
2) B2H6 and alkaline H2O2
is most effective in
3) O3/Zn dust
1) Conc. H3PO4/ 2) Conc. HCl
4) H2O/H+
3) Conc. HCl/ZnCl2 4) Conc. HBr
5. Isobutyl alcohol is prepared from the reaction
of 9. Which of the following alcohols would you
expect to form a carbocation most readily in
1) CH3 – CH2 – MgBr and CH3 – CHO
H2SO4?
2) CH3MgBr and CH3 – CH2 – CHO
3) (CH3)2CHMgBr and HCHO
O
|| 1)
4) CH3MgBr and CH3  C  CH3
 2 Test ID : 957
15. CH2  CH2  OH will have the minimum
|
X
2) value of pKa when X is
1) F 2) Cl
3) Br 4) NO2
16. Which of the following reactions will not
3) yield phenol?

1)
4)

10. LiAlH4 converts acetic acid into

1) Acetaldehyde 2) Methane 2)
3) Ethyl alcohol 4) Methyl alcohol
11. Separation of proton is difficult in
1) CH3OH 2) CH3 – CH2 – OH 3)
CH 3
| CH3  CH  OH
3) CH 3  C  OH 4) |
| CH3 4)
CH 3
12. ‘A’ on treatment with ‘Na’ gives ‘B’ and with
17. Select the incorrect statement about Kolbe’s
PCl5 gives C. B and C react together to give
reaction.
diethyl ether. A, B and C are respectively
1) Phenoxide ion is less reactive than phenol
1) C2H5OH, C2H5Cl, C2H5ONa
towards aromatic electrophilic substitution
2) C2H5OH, C2H6, C2H5Cl
2) A weak electrophile CO2 is used in this
3) C2H5OH, C2H5ONa, C2H5Cl reaction
4) C2H5Cl, C2H6, C2H5OH 3) Ortho hydroxyl benzoic acid is formed as
13. The product of reaction then main product
Cu/300 C o
CH3 – CH2 – OH  4) Salicylic acid is formed as the main product
O 18. Phenol is less acidic than
|| 1) Ethanol
1) C2H6 2) CH3  C  CH3
2) O-nitrophenol
3) CH3COOH 4) CH3CHO
3) O-methyl phenol
14. Ethanol cannot be concentrated by fraction
4) O-methoxy phenol
distillation because
1) It is an inflammable liquid
2) Its boiling point is very close to water
19.
3) It forms a constant boiling mixture with
water
4) It is soluble in water in all proportions
 3 Test ID : 957

1) 2) 2)

3) 4) 3)

20. The correct order of strength of acidity of the

following compounds is
4)

23. Match column – I with column – II

Column – I Column – II
A) Phenol + CHCl3 i) Saponification
1) II > I > III > IV 2) I > II > III > IV B) C2H5Br + alc.KOH ii) Ether
3) IV > III > II > I 4) IV > III > I > II C) Williamson synthesis iii) Elimination
reaction
D) CH3COOC2H5 + NaOH iv) Rimer-Tiemann
21.
reaction
1) A-i, B-ii, C-iv, D-iii
Y is
2) A-iv, B-iii, C-ii, D-i
1) 3) A-iv, B-ii, C-iii, D-i
4) A-iv, B-iii, C-i, D-ii
2) 24. Which of the following compound is aromatic
alcohol?

3)

4)
1) I, III, II and IV
22. Which of the following compound can evolve 2) I and IV
CO2 with NaHCO3. 3) II and III
4) I

1)
 4 Test ID : 957
25. Arrange the following compounds in increases 29. An equimolar quantities of ethanol and
order of pKa value propanol are heated with Conc. H2SO4, the
product formed is/are
1) C2H5 – O – C2H5 2) C3H7 – O – C3H7
3) C2H5 – O – C3H7 4) All of these
30. Ethers have lower boiling points than their
corresponding isomeric alcohols because of
1) Hydrogen bonding in alcohols that is absent
1) I > III > II > IV 2) I > II > III > IV in ethers due to low polarity
3) IV = II > III > I 4) IV = II < III < I 2) Hydrogen bonding ethers due to high
26. In the following reaction polarity

CH3 3) Insolubility of ethers in water due to less

| polarity
H 2O/H 
CH3  C  CH  CH 2  . 4) Inertness of ethers as compared to alcohol
|
CH3 31. Unsymmetrical ethers are best prepared by
The major product is 1) Dehydration of alcohols
CH3 2) Reacting Grignard reagent with alkyl halide
| 3) Treating sodium alkoxide with alkyl bromide
1) CH3  C  CH  CH3
| | 4) All the above
OH CH3 32. What will be the final products?
CH3
|
2) HO  CH 2  C  CH 2  CH3
| A and B are
CH3
CH 3
|
3) CH 3  C  CH 2  CH 3
| |
CH 3 OH 1)

CH3
|
4) CH3  C  CH 2  CH3
| |
CH3 OH 2)
27. Phenol can be distinguished from aliphatic
alcohol with
1) Tollen’s reagent 2) Schiff’s base
3) FeCl3 4) HCl 3)
28. In which case methyl-t-butyl ether is formed
1) (C2H5)3CONa + CH3Cl
2) (CH3)3CONa + CH3Cl
3) (CH3)3CONa + C2H5Cl 4)
4) (CH3)2CHONa + CH3Cl
 5 Test ID : 957
33. Phenols does not react with
1) NaHCO3 2) NaOH 2)
3) KOH 4) FeCl3
34. C6H5 OH + CHCl3 + NaOH  Salicyaldehyde.
The electrophile involved in the above reaction
is 3)
1) Dichloro methyl cation
2) Dichloro carbene
3) Trichloromethyl anion
4) Formyl cation
4)
Conc.H2SO4 HNO3
35. Phenol  A  B, Here ‘A’
and ‘B’ are respectively
1) p-hydroxy benzene sulphonic acid, p-nitro
phenol 38.
2) 4-hydroxy benzene-1,3-disulphonic acid,
picric acid Identify the major products P, Q and R in the
3) 4-hydroxy benzene-1, 3-disulphonic acid, sequence of reaction
2,4-dinitro phenol
4) 3-hydroxy benzene sulphonic acid, picric
acid 1)
36. Assertion (A) : In Lucas test, 3o alcohol react
immediately.
Reason (R) : A mixture of anhydrous ZnCl2
and Conc. HCl is called Lucas reagent.
1) Both (A) and (R) are true and the (R) is a
correct explanation of the (A) 2)
2) Both (A) and (R) are true but (R) is not a
correct explanation of the (A) 3)
3) (A) is true but the (R) is false
4) Both (A) and (R) are false

37.

4)

A is

1) 39. When vapours of a secondary alcohol is

passed over heated copper at 573K the product
formed is
 6 Test ID : 957
1) a carboxylic acid 2) an aldehyde 2) X = CH3 – CH = CH2,
3) a ketone 4) an alkene Y = CH3 – CH2 – CH2 – Br,
40. Statement – I : The acidic strength of mono Z = CH3 – CH2 – O – CH2 – CH3
substituted nitro phenol is higher than phenol 3) X = CH3 – CH = CH2,
because of electron with drawing nitro group. Y = CH3  CH  CH3 ,
Statement – II : o-nitrophenol, m-nitrophenol |
and p-nitrophenol will have same acidic Br
strength. Z = CH3 – CH2 – O – CH2 – CH3
1) Both statements I and II are correct 4) X = CH3 – CH = CH2,
2) Both statements I and II are incorrect Y = CH3 – CH2 – CH2 – Br,
3) Statement I is correct, II is incorrect Z = CH3 – CH2 – CH2 – O – CH3
4) Statement I is incorrect, II is correct 43. Compound A and C in the following reaction
41. Which among the following will be most are
readily dehydrated under acidic conditions?

1)
1) Identical isomers
2) Positional isomers
2) 3) Functional isomers
4) Optical isomers
44. Which method can be used to separate o-nitro
3) phenol and p-nitro phenol?
1) Sublimation
2) Distillation
3) Steam distillation
4) 4) Distillation under reduced pressure
45. Which of the following is more soluble in
aqueous solution of sodium hydroxide?
42. X, Y and Z respectively in the sequence
alc.KOH HBr
CH3 – CHBr – CH3   X 
Peroxide Y
CH ONa
Y 
3
Z 1) 2)

Br
|
1) X = CH3 – CH =CH2, Y = CH3  CH  CH 2
|
Br 3) 4)
OH
|
Z= CH 3  CH  CH3

***All the Best***