Material Safety Data Sheet: Section 1 - Product and Company Identification

MATERIAL SAFETY DATA SHEET
3151 05 00 DATE OF PREPARATION May 3, 2011
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NUMBER 3151 PRODUCT NAME KRYLON Magnetic Paint MANUFACTURER'S NAME Krylon Products Group Cleveland, OH 44115
Telephone Numbers and Websites Product Information (800) 247-3268 www.krylon.com Regulatory Information (216) 566-2902 Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 *for Chemical Emergency ONLY (spill, leak, fire, exposure, or accident)
SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS

% by Weight 15 CAS Number 74-98-6 Ingredient Propane ACGIH TLV OSHA PEL Butane ACGIH TLV OSHA PEL Heptane ACGIH TLV ACGIH TLV OSHA PEL OSHA PEL V. M. & P. Naphtha ACGIH TLV OSHA PEL OSHA PEL Toluene ACGIH TLV OSHA PEL OSHA PEL Acetone ACGIH TLV ACGIH TLV OSHA PEL Iron ACGIH TLV OSHA PEL Talc ACGIH TLV OSHA PEL Titanium Dioxide ACGIH TLV OSHA PEL OSHA PEL Units 2500 PPM 1000 PPM 800 PPM 800 PPM 400 500 400 500 PPM PPM STEL PPM PPM STEL Vapor Pressure 760 mm
15
106-97-8
760 mm
142-82-5
50 mm
64742-89-8
300 PPM 300 PPM 400 PPM STEL 20 PPM 100 ppm (Skin) 150 ppm (Skin) STEL 500 PPM 750 PPM STEL 1000 PPM 5 MG/M3 10 MG/M3 2 mg/m3 as Resp. Dust 2 mg/m3 as Resp. Dust 10 mg/m3 as Dust 10 mg/m3 Total Dust 5 mg/m3 Respirable Fraction
12 mm
12
108-88-3
22 mm
15
67-64-1
180 mm
17
7439-89-6
14807-96-6
13463-67-7
SECTION 3 HAZARDS IDENTIFICATION

ROUTES OF EXPOSURE INHALATION of vapor or spray mist.
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EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system.
HMIS Codes Health 2* Flammability 3 Reactivity 1
May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: the liver the urinary system the cardiovascular system the reproductive system SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11.
SECTION 4 FIRST AID MEASURES

EYES: SKIN: INHALATION: INGESTION: Flush eyes with large amounts of water for 15 minutes. Get medical attention. Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. If affected, remove from exposure. Restore breathing. Keep warm and quiet. Do not induce vomiting. Get medical attention immediately.
SECTION 5 FIRE FIGHTING MEASURES

FLASH POINT LEL UEL EXTINGUISHING MEDIA Propellant < 0 F 0.9 12.8 Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat.
SECTION 6 ACCIDENTAL RELEASE MEASURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent.
SECTION 7 HANDLING AND STORAGE

STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION

PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using.
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This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

864 g/l PRODUCT WEIGHT 7.22 lb/gal SPECIFIC GRAVITY 0.87 <-18 - 162 C BOILING POINT <0 - 325 F MELTING POINT Not Available VOLATILE VOLUME 88% EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 7.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) Volatile Weight 51.27% Less Water and Federally Exempt Solvents
SECTION 10 STABILITY AND REACTIVITY

STABILITY Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur
SECTION 11 TOXICOLOGICAL INFORMATION

CHRONIC HEALTH HAZARDS Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint."
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TOXICOLOGY DATA CAS No. 74-98-6
Ingredient Name Propane LC50 RAT LD50 RAT 4HR Not Available Not Available Not Available Not Available Not Available Not Available Not Available Not Available 4000 ppm 5000 mg/kg Not Available 5800 mg/kg Not Available Not Available Not Available Not Available Not Available Not Available
106-97-8
Butane LC50 RAT LD50 RAT 4HR
142-82-5
Heptane LC50 RAT LD50 RAT 4HR
64742-89-8
V. M. & P. Naphtha LC50 RAT LD50 RAT 4HR
108-88-3
Toluene LC50 RAT LD50 RAT 4HR
67-64-1
Acetone LC50 RAT LD50 RAT 4HR
7439-89-6
Iron LC50 RAT LD50 RAT 4HR
14807-96-6
Talc LC50 RAT LD50 RAT 4HR
13463-67-7
Titanium Dioxide LC50 RAT LD50 RAT 4HR
SECTION 12 ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION No data available.
SECTION 13 DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution.
SECTION 14 TRANSPORT INFORMATION

Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) May be classed as Consumer Commodity, ORM-D UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) Canada (TDG) May be classed as Consumer Commodity, ORM-D UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U, ADR (D) IATA/ICAO UN1950, AEROSOLS, 2.1, LIMITED QUANTITY
SECTION 15 REGULATORY INFORMATION

SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element 108-88-3 Toluene 12 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.
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TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory.
SECTION 16 OTHER INFORMATION

This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.
The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information.
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MATERIAL SAFETY DATA SHEET

3151 05 00 DATE OF PREPARATION May 3, 2011

SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS

SECTION 3 HAZARDS IDENTIFICATION

HMIS Codes Health 2* Flammability 3 Reactivity 1

SECTION 4 FIRST AID MEASURES

SECTION 5 FIRE FIGHTING MEASURES

SECTION 6 ACCIDENTAL RELEASE MEASURES

SECTION 7 HANDLING AND STORAGE

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

SECTION 10 STABILITY AND REACTIVITY

SECTION 11 TOXICOLOGICAL INFORMATION

TOXICOLOGY DATA CAS No. 74-98-6

Butane LC50 RAT LD50 RAT 4HR

Heptane LC50 RAT LD50 RAT 4HR

V. M. & P. Naphtha LC50 RAT LD50 RAT 4HR

Toluene LC50 RAT LD50 RAT 4HR

Acetone LC50 RAT LD50 RAT 4HR

Iron LC50 RAT LD50 RAT 4HR

Talc LC50 RAT LD50 RAT 4HR

Titanium Dioxide LC50 RAT LD50 RAT 4HR

SECTION 12 ECOLOGICAL INFORMATION

SECTION 13 DISPOSAL CONSIDERATIONS

SECTION 14 TRANSPORT INFORMATION

SECTION 15 REGULATORY INFORMATION

SECTION 16 OTHER INFORMATION

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