Scribd Logo
Upload

Welcome to Scribd!

  • 50 views

    CHEM 180: Christian MANAHAN Anna Esperanza LEGASPI

    Uploaded by

    Anna Legaspi
    This document outlines the chemicals used in a physical chemistry laboratory course and the waste generated and treatment. It describes various volatile organic solvents, acids, bases, salts, and other chemicals used in 8 exercises. Small amounts of hazardous chemicals like acetone, acids, and bases are generated. The document proposes managing this waste by diluting, neutralizing, collecting recoverable chemicals, precipitating solids, and proper disposal of treated waste down the sink or in solid waste collection.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PPTX, PDF, TXT or read online from Scribd

    CHEM 180: Christian MANAHAN Anna Esperanza LEGASPI

    Uploaded by

    Anna Legaspi
    50 views19 pages
    This document outlines the chemicals used in a physical chemistry laboratory course and the waste generated and treatment. It describes various volatile organic solvents, acids, bases, salts, and other chemicals used in 8 exercises. Small amounts of hazardous chemicals like acetone, acids, and bases are generated. The document proposes managing this waste by diluting, neutralizing, collecting recoverable chemicals, precipitating solids, and proper disposal of treated waste down the sink or in solid waste collection.

    Original Description:

    Chemical waste treatment and disposal chem 111.1 laboratory

    Original Title

    Chem 180

    Copyright

    © Attribution Non-Commercial (BY-NC)

    Available Formats

    PPTX, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    This document outlines the chemicals used in a physical chemistry laboratory course and the waste generated and treatment. It describes various volatile organic solvents, acids, bases, salts, and other chemicals used in 8 exercises. Small amounts of hazardous chemicals like acetone, acids, and bases are generated. The document proposes managing this waste by diluting, neutralizing, collecting recoverable chemicals, precipitating solids, and proper disposal of treated waste down the sink or in solid waste collection.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PPTX, PDF, TXT or read online from Scribd
    Download as pptx, pdf, or txt
    50 views19 pages

    CHEM 180: Christian MANAHAN Anna Esperanza LEGASPI

    Uploaded by

    Anna Legaspi
    This document outlines the chemicals used in a physical chemistry laboratory course and the waste generated and treatment. It describes various volatile organic solvents, acids, bases, salts, and other chemicals used in 8 exercises. Small amounts of hazardous chemicals like acetone, acids, and bases are generated. The document proposes managing this waste by diluting, neutralizing, collecting recoverable chemicals, precipitating solids, and proper disposal of treated waste down the sink or in solid waste collection.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PPTX, PDF, TXT or read online from Scribd
    Download as pptx, pdf, or txt
    of 19

    CHEM 180

    Christian MANAHAN
    Anna Esperanza LEGASPI

    CHEMICAL WASTE TREATMENT AND DISPOSAL


    CHEM 111.1 PHYSICAL CHEMISTRY I LABORATORY

    CHEMICALS USED IN THE COURSE


    VOLATILE ORGANIC SOLVENTS VOLATILE ORGANIC SOLIDS DILUTE ACIDS, BASES , BUFFERS AND DETERGENTS ELECTROLYTES AND HYDRATED SALTS INDICATOR DYES POLYMERS

    VOLATILE ORGANIC SOLVENTS


    ACETONE-(E1-sample, E4-sample, washing, E7, E8-calibration, test liquid) 2-BUTANONE-(E1-sample)

    ETHLY ACETATE-(E1-sample, E7, E8-calibration)

    VOLATILE ORGANIC SOLVENTS


    DICHLOROMETHANE-(E1-sample) ETHANOL-(E1-sample, E6-solvent, E7-

    test liquid)

    VOLATILE ORGANIC SOLVENTS


    METHANOL-(E1sample) n-PROPANOL-(E4sample, E7-test liquid) 2-PROPANOL-(E7-test liquid)

    ORGANIC SOLIDS
    SALICYLIC ACID-(E5-sample) ACETOSALICYLIC ACID-(E5-sample) BENZOIC ACID-(E5-for calibration)

    DILUTE ACID, BASE, BUFFER AND DETERGENT


    HYDROCHLORIC ACID-(E6-reagent) (0.01 M and 0.5 M) SODIUM HYDROXIDE-(E6-buffer preparation) (0.1 M)

    DILUTE ACID, BASE, BUFFER AND DETERGENT


    KH2PO4-K2HPO4 BUFFER-(E6-Buffer) DETERGENT-(E7-sample, E8-washing)

    ELECTROLYTES AND HYDRATED SALTS


    POTASSIUM CHLORIDE-(E7-sample) SODIUM CHLORIDE(E7-sample, E8-reagent)

    ELECTROLYTES AND HYDRATED SALTS


    SODIUM SULFATE-(E7-sample) BORAX (Na2B4O710H2O-(E6-Reagent)(0.01 M and 0.05 M)

    INDICATOR DYE
    BROMTHYMOL BLUE-(E6-sample)

    POLYMER
    SODIUM CARBOXYMETHYL CELLULOSE-(E8sample)

    EXERCISES THAT USES CHEMICALS


    EXERCISE 1-MOLECULAR WEIGHT DETERMINATION BY VAPOR DENSITY METHOD EXERCISE 3-JOULE-THOMSON EXPERIMENT EXERCISE4-VAPOR PRESSURE OF A LIQUID EXERCISE 5-ENTHALPIES OF REACTION EXERCISE 6-THE ACID DISSOCIATION CONSTANT OF AN INDICATOR DYE

    EXERCISE 7-SURFACE TENSION OF PURE LIQUIDS AND SOLUTIONS


    EXERCISE 8-VISCOSITY OF PUR LIQUIDS AND SOLUTIONS

    COURSE EXPERIMENTS SET-UP


    COMPOUNDS ARE MOSTLY CONSUMED MOSTLY AS DILUTE SOLUTIONS MINIMUM AMOUNTS ARE USED DONE BY TWO GROUPS PER CLASS AVERAGE OF 6-9 SECTIONS PER SEMESTER MOST DISPOSAL CAN BE DONE BY DISPOSING TO SINK

    WASTE GENERATION
    EXERCISE EXERCISE 1 EXERCISE 2 EXERCISE 3 EXERCISE 4 EXERCISE 5 EXERCISE 6 EXERCISE 7 EXERCISE 8 HAZARDOUS CHEMICAL WASTE GENERATED None, all samples vaporized None None, gas tank contains inert gas Acetone and Propanol, (<10mL) Salicylic acid, acetyl salicylate, benzoic acid (<0.5g), sample is combusted Bromthymol Blue, HCl, NaOH, Borax, Potassium phosphate buffer (~100mL) Propanol, isopropyl alcohol, acetone, ethyl acetate, ethanol (~100mL), KCl, NaCl, Na2SO4, detergent (~100mL) Ethyl acetate, acetone (~15mL), sodium carboxymethylcellulose (~5 g)

    WASTE
    Acetone, ethyl acetate Propanol, isopropyl alcohol, ethanol Salicylic acid, acetyl salicylate , benzoic acid Bromthymol Blue Phosphate Buffer HCl and NaOH Salts; KCl, NaCl, Na2SO4 Borax, sodium carboxymethylcellulose

    Hazards
    Can cause irritation in contact, fumes can cause chronic effects to respiration, toxic if ingested, atmospheric and water pollutant Irritant upon skin exposure, toxic if ingested and inhaled at high concentration, atmospheric and water pollutant Laboratory grade is toxic if in contact, excessive inhalation of fumes causes nausea May be toxic if ingested, irritant upon contact, may change pH of water and soil

    Generally non toxic, but may affect natural sources upon release and cause eutrophication
    Corrosive and may affect aquatic and terrestrial environment if not neutralized, HCl fumes affect atmospheric environment Affect water quality. Sulfate in acidic solution may contribute sulfuric acid formation. KCl is a known irritant Borax is reactive to some terrestrial and aquatic processes. The polymer may cause clogging of water ways if acculmulated

    WASTE
    Acetone, ethyl acetate Propanol, isopropyl alcohol, ethanol Salicylic acid, acetyl salicylate, benzoic acid Bromthymol Blue Phosphate Buffer HCl and NaOH Salts; KCl, NaCl, Na2SO4 Borax, sodium carboxymethylcellulose

    Treatment/Disposal
    Pool and isolate with RotaVap or distillation, use fractional distillation if found with water or alcohol Dispose to sink after diluting using water Contain recoverable un-combusted samples, collect sooty ashes and contain in solid waste container for land disposal Dilute and set to acceptable pH range, can be disposed to sink

    Stack buffer component, concentrate by evaporating water and obtain salt, can be used for other uses such as agriculture
    Neutralize acid and base waste with each other; can be disposed on sink Dilute and dispose to sink Remove solid and precipitate, contain in solid waste collector and dispose to land

    PROPOSED STRATEGY OF WASTE MANAGEMENT


    DILUTE NEUTRALIZE

    COLLECT AND RECOVER


    PRECIPITATE DISPOSE

    You might also like