Igneous Structures
Igneous Structures
Igneous Structures
Spherical Projection
Stereographic Projection
The outer sphere
is a spherical
projection
Plot points
where poles
intersect sphere
Planes now =
points
But still 3-D
Fig 6.3
Stereographic Projection
Gray plane =
Equatorial Plane
Want to use it as
our 2-D
representation
and project our
spherical poles
back to it
This is a 2-D
stereographic
projection
Stereographic Projection
D and E are spherical
D' and E' are
stereographic
Distance GD' = f()
as 90 D G
as 0 D O
Fig 6.6 of Klein (2002) Manual of Mineral Science, John Wiley and Sons
Stereographic Projection
We can thus use
the angles and
calculate the 2-D
distances from
the center to find
the stereographic
poles directly
Or we can use
special graph
paper and avoid
the calculation
Small circles
Gives angles between any two points on a great
circle
= the angle
between 2
coplanar
lines!!
20o
Stereographic Projection
How to make a stereographic projection of our crystal
Use a contact goniometer to measure the interfacial
angles (also measures normals: poles)
+a 3
90
symmetry elements
Twinning
Twinning
Aragonite twin
Note zone at twin
plane which is
common to each
part
Although aragonite is
orthorhombic, the twin looks
hexagonal due to the 120o O-C-O
angle in the CO3 group
Twinning
Twinning
Mechanisms:
1) Growth
Growth increment cluster adds w/ twin
orientation
Epitaxial more stable than random
Not all epitaxis twins
Twinning
Mechanisms:
1) Growth
Feldspars:
Plagioclase: Triclinic Albite-law-striations
a-c
a-c
Twinning
Mechanisms:
1) Growth
Feldspars:
Plagioclase: Triclinic Albite-law-striations
Twinning
cyclic twinning in
inverted low quartz
Mechanisms:
2) Transformation (secondary)
SiO2: High T is higher symmetry
Twinning
Mechanisms:
2) Transformation (secondary twins)
Feldspars:
Orthoclase (monoclinic) microcline (triclinic)
Monoclinic a-c
(high-T)
b
a-c
Triclinic
(low-T)
b
Twinning
Mechanisms:
2) Transformation (secondary)
Feldspars:
K-feldspar: large K lower T of transformation
tartan twins
Twinning
Mechanisms:
3) Deformation (secondary)
Results from shear stress
greater stress gliding, and finally rupture
Also in feldspars.
Looks like transformation, but the difference in
interpretation is tremendous
Mechanisms:
3) Deformation (secondary)
Results from shear stress. Plagioclase
Mechanisms:
3) Deformation (secondary)
Results from shear stress. Calcite
X-ray Crystallography
X-ray wavelengths are on the same order of
magnitude as atomic spacings.
Crystals thus makes excellent diffraction gratings
Can use the geometry of the x-ray spots to
determine geometry of grating (ie the crystal)
X-ray Crystallography
X-ray generation
W Cathode
Cu Anode
(-)
(+)
electrons
X-rays
X-ray Crystallography
X-ray generation
Continuous & characteristic spectrum (Fig. 7.2)
X-ray Crystallography
Destructive and constructive interference of waves
Bragg Equation:
in phase
in phase
X-ray Crystallography
n=2dsin
n is the order
As soon as the crystal is rotated, the beam ceases
(This is diffraction, not reflection)
Only get diffraction at certain angles!
Relation between and d and
Y
X-ray Crystallography
Methods:
1) Single-Crystal: Laue Method
Several directions simultaneously fulfill Bragg equations
Good for symmetry, but poor for analysis because distorted
X-ray Crystallography
Methods:
1) Single-Crystal:
Precession
X-ray Crystallography
Methods:
2) PowderEasiest
Infinite orientations at once, so only need to vary