Lembar Data Keselamatan Bahan

Lembar data keselamatan bahan
(LDKB)
&
Label
Pendahuluan
Indonesia :
 Depnakertrans : Lembar data Keselamatan Bahan ( LDKB)
Jepang : “ Material safety data sheet”
USA : “Material Safety Data Sheet “
Eropa : “ Safety Data Sheet”
Saat ini ada lebih dari 50.000 bahan kimia yang sering di gunakan.
Setiap tahun 500 – 600 bahan kimia baru di daftarkan, sebagian diantranya
merupakan bahan kimia berbahaya yang memiliki potensi kecelakaan /
PAK terhadap pekerja pada saat operasi maupun penanganan.
Berdasarkan hal ini lah , tersedianya lembar data keselamatan bahan /
MSDS menjadi tugas yang penting.
Bahan Kimia Berbahaya
Bahan kimia dalam bentuk tunggal atau

campuran yang berdasarkan sifat kimia;
fisika atau toksikologi berbahaya terhadap
tenaga kerja, instalasi dan lingkungan.
Terdiri :
– Bahan beracun
– Bahan reaktif
– Bahan mudah meledak
– Bahan oksidator
– Cairan mudah terbakar
– Gas mudah terbakar
International trends
In June 1992, the United Naions Conference on Environment and Development
was held, at which the Human Behaviour Plan for Sustainable Development (
Agenda 21) was adopted.
Chapter 19 of Agenda 21
Environmentally Sound Management Of Toxic Chemicals, Including Prevention Of
Illegal International Traffic in Toxic And Dangerous Products.
•Expanding and accelerating international assessment of chemical risks
•Harmonization of classification and labelling of chemicals
•Information exchange on toxic chemicals and chemicals risks
•Establishment of risk reduction programs
•Strengthening of national capabilities and capacities for management of
chemicals
•Prevention of illegal international tranffic in toxic and dangerous products
•Strengthening international corporation
Sistem LDKB pada beberapa negara
utama
Negara Peraturan Tahun Bahan yang Format
diwajibkan
USA OSH Act ; 1983 Specified None
Hazard Coomunication Standard
Canada On-site hazardous substance information system 1988 Specified Yes
Australia On-site hazardous substance control regulation ; 1986 Specified Yes

National standard on preparation of MSDS
EU ( Directive concerning classification, packaging and 1993 Specified None
European labeling of hazardous substances ;
Union) Committee directive concerning SDS
Korea Ind. Safety and Health Law 1996 Specified Yes
ISO International standard ISO 11014-1 1994 Not Specified None
Japan Guideline on provision of information conc. Safety 1993 Specified Yes

of chem. Substances
Guideline of labeling of chem. Subs. Hazard 1993
Ind. Safety and Health Law 2000
Regulasi di Indonesia
(Kepmenaker No. Kep. 187/Men/1999 )
Pengurus yang :
Menggunakan Lengkapi
Menyimpan dengan :
Memakai LDKB
Memproduksi Label
Mengangkut bahan kimia Ps. 3. Point a
berbahaya,
wajib melakukan
pengendalian ( Pasal 2 )
LDKB dan Label di letakkan di tempat yang mudah

diketahui oleh tenaga kerja dan Pegawai Pengawas
ketenagakerjaan ( Pasal 6 )
Format LDKB
Terdiri dari 16 item besar yang harus diberi penjelasan yang memadai
1. Identitas bahan dan perusahaan
2. Komposisi bahan
3. Identifikasi bahaya
4. Tindakan P3K
5. Tindakan penanggulangan Kebakaran
6. Tindakan mengatasi kebocoran dan tumpahan
7. Penyimpanan dan penanganan bahan
8. Pengendalian pemajanan dan alat pelindung diri
9. Sifat fisika dan kimia
10. Stabilitas dan reaktifitas bahan
11. Informasi toksikologi
12. Informasi ekologi
13. Pembuangan limbah
14. Pengangkutan bahan
15. Informasi perundang-undangan
16. Informasi lain yang diperlukan.
Pengertian Label
:
• selembar kertas,plastik dan lain-lain yang
di lekatkan pada kemasan dan berisi
informasi mengenai bahankimia berbahaya
yang terkandung di dalamnya atau,
• cetakan pada kemasan yang berisi
informasi tentang bahan kimia berbahaya
yang terkandung di dalamnya.
Format Label
Terdiri dari 11 item besar yang harus diberi penjelasan yang memadai
1. Nama produk
2. Identifikasi bahaya
3. Tanda bahaya dan artinya
4. Uraian resiko dan penanggulangannya
5. Tindakan pencegahan
6. Instruksi dalam hal terkena atau terpapar
7. Instruksi kebakaran
8. Instruksi tumpahan atau bocoran
9. Instruksi pengisian dan penyimpanan
10. Referensi
11. Nama, alamat dan no. telp. Pabrik pembuat atau
distributor.
SISTIM TINGKATAN BAHAYA
(NFPA Scale)
FIRE
4 – TITIK NYALA DIBAWAH 23 ˚C
3 – TITIK NYALA 23 ˚C – 37 ˚C
2 – TITIK NYALA 37 ˚C – 93 ˚C
1 – TITIK NYALA DIATAS 93 ˚C
0 – TIDAK BISA TERBAKAR
FIRE
HEALTH REACTIVITY
HEALTH REACTIVITY
4 – MENGANCAM JIWA 4 – REAKSI LEDAKAN
3 – CIDERA BESAR 3 – REAKSI KERAS
2 – CIDERA KECIL SPESIAL 2 – REAKSI PADA KONDISI
1 – CIDERA KECIL WARNING NORMAL
SEMENTARA 1 – REAKSI PADA KONDISI
0 – BAHAYA KECIL ANGKAT
0 - STABIL
Examples of arrangements of GHS
elements (GHS, Annex 6)
A6.1.1 Label for large receptacle (200 litre drum) for transport, emergency response and
workplace audiences
UN 2920 2-methyl tetramethylenexxxxx

Corrosive liquid, flammable, N.O.S. Danger
(2-methyl tetramethylenexxxxx) Causes severe skin burns and
serious eye damage
Highly flammable liquid and vapour
Avoid contact with skin and eyes
Keep away from heat and ignition
sources
First aid:
For skin contact, remove contaminated clothing and wash affected area thoroughly with
water. If irritation develops, seek medical attention.
For eye contact, immediately flush eyes with flowing water for at least 15 minutes and
seek medical attention.
GHS Example Company, Akron, NWT, Canada. Telephone (888) 888-8888
Transport pictograms
4 4 5.1
GHS pictograms
!
Signal words
“Danger” or “Warning”
Used to emphasis hazard and to

discriminate between hazard categories
(level of hazard)
e.g. Acute toxicity category 1 will require

“Danger”, category 4 will require
“Warning”
Hazard statements
A single harmonised hazard statement for

each hazard category within each hazard class
e.g.
 Category 1 Flammable liquid
“extremely flammable liquid and vapour”
 Category 2
“Highly flammable liquid and vapour”

 Category 3 - “flammable liquid and vapour”
 Category 4 - “combustible liquid”

Storage Of Chemicals
• Info sources: MSDS, label or references
• Considerations: temperature, ignition control,
ventilation, segregation
• Segregation - to prevent incompatible
materials from coming into contact
• Should not by simple alphabetical order:
– Acetic acid and acetaldehyde may bring about polymerization reaction
– Copper (II) sulfide and cadmium chlorate may be explosive when mixed

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Lembar Data Keselamatan Bahan

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Lembar data keselamatan bahan

Bahan kimia dalam bentuk tunggal atau

Australia On-site hazardous substance control regulation ; 1986 Specified Yes

ISO International standard ISO 11014-1 1994 Not Specified None

Japan Guideline on provision of information conc. Safety 1993 Specified Yes

LDKB dan Label di letakkan di tempat yang mudah

UN 2920 2-methyl tetramethylenexxxxx

Used to emphasis hazard and to

e.g. Acute toxicity category 1 will require

A single harmonised hazard statement for

“Highly flammable liquid and vapour”

 Category 4 - “combustible liquid”

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