The document summarizes different methods for analyzing batch reactor data including integral and derivative methods. It discusses using the integral method to guess the reaction order, calculate the regression coefficient R, and confirm the order. It then provides examples of applying these methods to analyze first-order and second-order irreversible reactions as well as reversible reactions. Specific problems are presented relating to determining conversion, time to reach a conversion percentage, and reaction rates.
The document summarizes different methods for analyzing batch reactor data including integral and derivative methods. It discusses using the integral method to guess the reaction order, calculate the regression coefficient R, and confirm the order. It then provides examples of applying these methods to analyze first-order and second-order irreversible reactions as well as reversible reactions. Specific problems are presented relating to determining conversion, time to reach a conversion percentage, and reaction rates.
The document summarizes different methods for analyzing batch reactor data including integral and derivative methods. It discusses using the integral method to guess the reaction order, calculate the regression coefficient R, and confirm the order. It then provides examples of applying these methods to analyze first-order and second-order irreversible reactions as well as reversible reactions. Specific problems are presented relating to determining conversion, time to reach a conversion percentage, and reaction rates.
The document summarizes different methods for analyzing batch reactor data including integral and derivative methods. It discusses using the integral method to guess the reaction order, calculate the regression coefficient R, and confirm the order. It then provides examples of applying these methods to analyze first-order and second-order irreversible reactions as well as reversible reactions. Specific problems are presented relating to determining conversion, time to reach a conversion percentage, and reaction rates.
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Chapter 3 Levenspiel:
Interpretation of Batch Reactor
Data CPMonterola Two types of data analysis • 1. Integral • 2.Derivative Integral Method of Analysis of Data Step 1. Guess the reaction order. Step 2. Calculate R based on the reaction order. An R = 0.99 confirms the reaction order. Step 3. Repeat. Irreversible Unimolecular-Type First-Order Reactions The Conversion, XA Irreversible Unimolecular-Type First-Order Reactions Problem 3.1 Levenspiel Problem 3.5 Levenspiel
In a homogeneous isothermal liquid
polymerization, 20% of the monomer disappears in 34 minutes for initial monomer concentration of 0.04 and also for 0.8 mol/liter. What rate equation represents the disappearance of the monomer? Problem 3.7 Levenspiel Seat Work Snake-Eyes Magoo is a man of habit. For instance, his Friday evenings are all alike-into the joint with his week's salary of $180, steady gambling at "2-up" for two hours, then home to his family leaving $135 behind. Snake Eyes's betting pattern is predictable. He always bets in amounts proportional to his cash at hand, and his losses are also predictable-at a rate proportional to his cash at hand. This week Snake-Eyes received a raise in salary, so he played for three hours, but as usual went home with $135. How much was his raise? Irreversible Bimolecular-Type Second-Order Reactions Problem 3.3 Levenspiel Liquid A decomposes by second-order kinetics, and in a batch reactor 50% of A is converted in a 5-minute run. How much longer would it take to reach 75% conversion? Problem 3.27 Levenspiel Irreversible Reaction In Parallel Problem 3.13 Levenspiel Betahundert Bashby likes to play the gaming tables for relaxation. He does not expect to win, and he doesn't, so he picks games in which losses are a given small fraction of the money bet. He plays steadily without a break, and the sizes of his bets are proportional to the money he has. If at "galloping dominoes" it takes him 4 hours to lose half of his money and it takes him 2 hours to lose half of his money at "chuk-a-luck," how long can he play both games simultaneously if he starts with $1000 and quits when he has $10 left, which is just enough for a quick nip and carfare home? Overall Order of Irreversible Reactions from the Half-Life t1/2 Fractional Life Method Problem 3.17 Levenspiel An ampoule of radioactive Kr-89 (half life = 76 minutes) is set aside for a day. What does this do to the activity of the ampoule? Note that radioactive decay is a first-order process. Problem 3.19 Levenspiel Problem 3.23 Levenspiel First-order Reversible reaction First-order Reversible reaction Problem 3.9 Levenspiel Problem 3.25 Levenspiel Problem 3.11 Levenspiel Irreversible Bimolecular-Type Second-Order Reactions
Let M = CA0/CB0 Irreversible Bimolecular-Type Second-Order Reactions