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    Spark Plasma Based Sintering For Solid State Li-Ion Batteries: Overview and Perspective

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    Vipul Parashar
    This document provides an overview of spark plasma sintering (SPS) for solid state Li-ion batteries. It first explains that SPS uses pulsed DC current for internal heating to achieve faster densification and finer grains compared to conventional sintering. It then discusses how conventional Li-ion batteries work using liquid electrolytes and graphite/metal oxide electrodes. Solid state batteries are described as safer replacements that allow for portable, durable designs without leakage. The key materials needed for solid state batteries are outlined as solid electrolytes, electrodes, and active carbon materials. SPS is identified as a better fabrication method than conventional sintering because it is faster, reduces porosity, and achieves nano-sized grains for improved

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    Spark Plasma Based Sintering For Solid State Li-Ion Batteries: Overview and Perspective

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    Vipul Parashar
    37 views17 pages
    This document provides an overview of spark plasma sintering (SPS) for solid state Li-ion batteries. It first explains that SPS uses pulsed DC current for internal heating to achieve faster densification and finer grains compared to conventional sintering. It then discusses how conventional Li-ion batteries work using liquid electrolytes and graphite/metal oxide electrodes. Solid state batteries are described as safer replacements that allow for portable, durable designs without leakage. The key materials needed for solid state batteries are outlined as solid electrolytes, electrodes, and active carbon materials. SPS is identified as a better fabrication method than conventional sintering because it is faster, reduces porosity, and achieves nano-sized grains for improved

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    This document provides an overview of spark plasma sintering (SPS) for solid state Li-ion batteries. It first explains that SPS uses pulsed DC current for internal heating to achieve faster densification and finer grains compared to conventional sintering. It then discusses how conventional Li-ion batteries work using liquid electrolytes and graphite/metal oxide electrodes. Solid state batteries are described as safer replacements that allow for portable, durable designs without leakage. The key materials needed for solid state batteries are outlined as solid electrolytes, electrodes, and active carbon materials. SPS is identified as a better fabrication method than conventional sintering because it is faster, reduces porosity, and achieves nano-sized grains for improved

    Copyright:

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    Download as pptx, pdf, or txt
    37 views17 pages

    Spark Plasma Based Sintering For Solid State Li-Ion Batteries: Overview and Perspective

    Uploaded by

    Vipul Parashar
    This document provides an overview of spark plasma sintering (SPS) for solid state Li-ion batteries. It first explains that SPS uses pulsed DC current for internal heating to achieve faster densification and finer grains compared to conventional sintering. It then discusses how conventional Li-ion batteries work using liquid electrolytes and graphite/metal oxide electrodes. Solid state batteries are described as safer replacements that allow for portable, durable designs without leakage. The key materials needed for solid state batteries are outlined as solid electrolytes, electrodes, and active carbon materials. SPS is identified as a better fabrication method than conventional sintering because it is faster, reduces porosity, and achieves nano-sized grains for improved

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    SPARK PLASMA BASED SINTERING

    FOR SOLID STATE Li-ion BATTERIES:


    OVERVIEW AND PERSPECTIVE

    VAIBHAV SINGH RAJPUT(811521)


    DEPARMENT OF METALLURGY AND MATERIALS SCIENCE
    INDEX
    1. WHAT IS SPARK PLASMA SINTERING(SPS)?
    2. HOW DOES A CONVENTIONAL Li-ion BATTERY WORKS ?
    3. WHY SOLID STATE Li-ion BATTERIES A REPLACEMENT TO
    CONVENTIONAL Li-ion BATTERIES IN CERTAIN APPLICATIONS?
    4. WHAT MATERIALS ARE REQUIRED TO MAKE SOLID STATE Li-ion
    BATTERIES?
    5. WHY SPS A BETTER METHOD TO PRODUCE MATERIALS OF Li-ion
    BATTERIES THAN CONVENTIONAL SINTERING ?
    1.WHAT IS SPARK PLASMA
    SINTERING?
    KEY POINTS:
    1.DC PULSE IS USED.
    2.INTERNAL HEATING RATHER THAN EXTERNAL HEATING.
    3.VERY FAST PROCESS.
    4.HIGHER DENSIFICATION.
    1.WHAT IS SPARK PLASMA
    SINTERING?
    1.WHAT IS SPARK PLASMA SINTERING?
    2. HOW DOES A CONVENTIONAL Li-ion
    BATTERY WORKS ?
     KEY POINTS:
    1.ELECTROLYTE:
    ◦ DISSOLVED IN ORGANIC SOLVENTS

    2.ANODE:
    ◦ GRAPHITE ELECTRODE

    3.CATHODE:
    ◦
    SCHEMATIC AND WORKING OF Li-
    ion BATTERY
    3.WHY SOLID STATE Li-ion BATTERIES ARE A REPLACEMENT TO
    CONVENTIONAL Li-ion BATTERIES IN CERTAIN APPLICATIONS?
    3.WHY SOLID STATE Li-ion BATTERIES ARE A
    REPLACEMENT TO CONVENTIONAL Li-ion
    BATTERIES IN CERTAIN APPLICATIONS ?
    KEY NOTES:
    1. PORTABLE AND LESS SPACE
    2. SAFETY AGAINST MECHANICAL DAMAGE (IF USED IN AUTOMOBILES OR AIRCRAFTS)
    3. NO LEAKAGE
    4. INFLAMMABLE AND SAFE
    5. DURABLE

    TO CAP IT ALL,
    ◦ ALL THESE FEATURES ARE PROVIDED BY SOLID STATE BATTERIES
    4. WHAT MATERIALS ARE REQUIRED TO
    MAKE SOLID STATE Li-ion BATTERIES?
    KEY NOTES:
    1. SOLID STATE ELECTROLYTE
    2. SOLID STATE ANODE
    3. SOLID STATE CATHODE
    SOLID ELECTROLYTE
    REQUIREMENTS FOR SOLID ELECTROLYTE TO BE USED IN Li-ion BATTERIES:
    1. CLEAN INTERFACES
    2. FINE GRAINS
    3. BETTER GRAIN-TO-GRAIN BONDING

    ADVANTAGES:
    1. NO NEED FOR CONTAINMENT AS IN LIQUID ELECTROLYTE
    2. IMPROVED SAFETY AND DURABILITY

    DISADVANTAGES:
    1. LOWER IONIC CONDUCTIVITY
    2. LOWER CURRENT DENSITY
    SOLID ELECTROLYTE
    THEY CAN BE OF TWO TYPES:
    1. POLYMER ELECTROLYTE:
     LESSER FABRICATION COST AND ENHANCED FLEXIBILITY
     LOWER Li-ion CONDUCTIVITY
     LOWER STIFFNESS
     NOT SUITABLE FOR HIGH TEMPERATURE
    2. CERAMIC ELECTROLYTE:
     SUITABLE FOR HIGH TEMPERATURE
     HIGHER STIFFNESS TO BE USED IN HEAVY DUTY APPLICATIONS
    5.WHY SPS A BETTER METHOD TO PRODUCE
    MATERIALS OF Li-ion BATTERIES THAN
    CONVENTIONAL SINTERING ?
    REASONS:
     FAST PROCESS,FINISHED PRODUCT READY IN MINUTES AS COMPARED TO CONVENTIONAL
    SINTERING WHICH TAKES HOURS TO COMPLETE
    5.WHY SPS A BETTER METHOD TO PRODUCE
    MATERIALS OF Li-ion BATTERIES THAN
    CONVENTIONAL SINTERING ?
    REASONS:
    REDUCING POROSITY
    FINER AND NANOSIZED GRAINS IN ORDER TO ATTAIN MECHANICAL STABILITY (SEE FIG)

    CONVENTIONAL PLASMA
    FINAL SOLID PRODUCT(EXAMPLE)
     KEY NOTES:
    ELECTROLYTE:
     (LAG)
    CATHODE:
     (LFP)
    ANODE:
     (LVP)
    ACTIVE MATERIAL:
     CARBON BLACK
    FIG:SCHEMATIC REPRESENTATION OF LI-ION SOLID STATE
    BATTERY
    REFRENCES:
    [1] X.DONG ,F.LU YANG ,X WANG .CHEM PHYS. 112(2) (2008) 596-602.
    [2] N.BALAKRISHNAN,M.TABUCHI,S. KONDO, J.ELECTROCHEM SOC.151(10) (2004) A1539-A1544.
    [3] RAVI KALI,AMARTYA MUKHOPADHYAY. JOURNAL OF POWER SCIENCES 247 (2014) 920-931.

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