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Alkyd Presentation

Resin alkyd is a binder made from the reaction of oils, polyols, and polyacids to form polyester resins. There are two main production processes - the oil/alcoholysis process which involves heating oil, polyol, and polyacid to produce monoglycerides which then react to form alkyd resin, and the fatty acid process which directly reacts fatty acids, polyol, and polyacid to produce alkyd resin. Alkyd resins are classified based on oil content and type of oil used, which determines their drying properties and applications.

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Luthfie Zulkarnaen
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158 views14 pages

Alkyd Presentation

Resin alkyd is a binder made from the reaction of oils, polyols, and polyacids to form polyester resins. There are two main production processes - the oil/alcoholysis process which involves heating oil, polyol, and polyacid to produce monoglycerides which then react to form alkyd resin, and the fatty acid process which directly reacts fatty acids, polyol, and polyacid to produce alkyd resin. Alkyd resins are classified based on oil content and type of oil used, which determines their drying properties and applications.

Uploaded by

Luthfie Zulkarnaen
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PPTX, PDF, TXT or read online on Scribd
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RESIN ALKYD

RESIN = BINDER ????

CAT
ASAL USUL
ALKYD = ALCID = ALCOHOL + ACID
(R’ – OH) (R - COOH)

ESTER + AIR
(R – COO – R’ + H2O)

POLYOL + POLYACID = POLYESTER


OIL + POLYOL + POLYACID = OIL MODIFIED POLYESTER
(RESIN ALKYD)
KLASIFIKASI RESIN ALKYD
1. BERDASARKAN KANDUNGAN OIL

GOLONGAN OIL LENGTH APLIKASI


SHORT OIL < 45% • ACID CURING (MELAMINE
PAINT)
• NC
• BAKING ENAMEL
MEDIUM OIL 46 – 55% • AIR DRYING
LONG OIL 56 – 70% • AIR DRYING
VERY LONG OIL > 70% • APLIKASI KHUSUS
MODIFIED STYRENE, PHENOLIC, • APLIKASI KHUSUS
EPOXY
KLASIFIKASI RESIN ALKYD
2. BERDASARKAN JENIS OIL

GOLONGAN CONTOH OIL TIPE ALKYD


DRYING ALKYD LINSEED, TUNG, DHCO • LONG OIL
SEMI DRYING ALKYD SOYABEAN, TOFA • LONG, MEDIUM,
SHORT OIL
NON DRYING ALKYD COCONUT, CASTOR • SHORT OIL
PROSES PEMBUATAN RESIN ALKYD

1. DUA TAHAP PROSES


= OIL / ALCOHOLISIS PROCESS

2. SATU TAHAP PROSES


= FATTY ACID PROCESS
PROSES PRODUKSI ALKYD
I. OIL / ALKOHOLISIS PROCESS

BAHAN BAKU:
A. OIL
POLYOL
CATALYST
B. POLYOL
POLYACID
ANTIOXIDANT
SOLVENT REFLUX

SOLVENT REFLUX
PROSES PRODUKSI ALKYD
Temp°C
50 50 100 N2 (L/mt)

240°C
End point

2 – 3 jam

180°C
A

Time

MONITOR PROSES
1. CHECK ALKOHOLISIS
2. VISCOSITY
3. ACID VALUE
OIL / ALCOHOLYSIS PROCESS
ALCOHOLYSIS

2 POLYOL 3 MONOGLYCERIDE
OIL
OIL / ALCOHOLYSIS PROCESS
ETERIFIKASI

MONOGLYCERIDE POLYACID

+ AIR

ALKYD n
ALKYD PRODUCTION PROCESSES
1. OIL ALCOHOLYSIS PROCESS

HEATING HEATING DILUTION

OIL
MONO
GLYCERIDE
POLYHYDRIC
ALCOHOL
POLYBASIC ALKYD RESIN
ACID
ALKYD
SOLUTION
POLYHYDRIC
ALCOHOL SOLVENT
PROSES PRODUKSI ALKYD
II. OIL / ALKOHOLISIS PROCESS

BAHAN BAKU:
A. FATTY ACID
POLYOL
POLYACID
ANTIOXIDANT

SOLVENT REFLUX

SOLVENT REFLUX
PROSES PRODUKSI ALKYD
Temp°C
50 50 100 N2 (L/mt)

220°C End point

2 – 3 jam
160°C

1.5 Hours

Time

MONITOR PROSES
1. CHECK VISCOSITY
2. CHECK ACID VALUE
FATTY ACID PROSES

Polyol Fatty acid Polyacid

ALKYD + AIR
ALKYD PRODUCTION PROCESSES
2. FATTY ACID PROCESS

HEATING DILUTION

FATTY ACID

POLYBASIC ALKYD RESIN


ACID
ALKYD
SOLUTION
POLYHYDRIC
ALCOHOL SOLVENT

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