Blending

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Blending

OBJECTIVE

The objective of product blending is to allocate the available


blending components in such a way as to meet product demands
and specifications at the least cost and to produce incremental
products which maximize overall profit.

In practice, all gasolines are blended. Most distillate products, fuel


oils, lubricating oils, and even some solvents are blended. Some
intermediate feed stocks and even some crude feeds to the
pipestills are blended

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Blending

For example, if a refiner sells about one billion gallons of gasoline


per year (about 65,000 BPCD), a saving of one one-hundredth
of a cent per gallon results in an additional profit of $100,000 per
year.

Some points to be remember in connection with blending are


these:

• All the material produced must be utilized. The choice often is,
given several options, which disposition is the most profitable
for a certain stream.

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• Each lot of product shipped must meet all specifications.


• Blending or correcting in another way is required, if one or
more specifications is not met.
• A specification is considered 'critical‘, if a cost is associated with
meeting it.
• Certain properties cannot be attained with hydrocarbons alone,
or are more expensive to produce this way. Additives are used
to provide or improve these properties.

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Product qualities are predicted through correlations that depend


on the quantities and the properties of the blended components.
The desired property PBlend of the blended product may be
determined using the following mixing blend rule:

where Pi is the value of the property of component i and qi is the


mass, volume or molar flow rate of component i contributing to
the total amount of the finished product.

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Another way of finding the blending property is used the blending


indices.
If the property is not an additive property. Blending indices are
used. For example, RVP is not a additive property, since blending
indices are used. A commonly used RVP index is based on an
empirical method developed by Chevron Oil Trading Company
(1971).

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Reid Vapour Pressure Blending


RVP is the vapour pressure at 100 F of a product determined in a
volume of air four times the liquid volume. RVP is not an additive
property. Therefore, RVP blending indices are used. A commonly
used RVP index is based on an empirical method developed by
Chevron Oil Trading Company (1971).

where BIRVPi is the RVP blending index for component i and RVPi
is the RVP of component i in psi.

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Gasoline Octane Number Blending


The octane number is a characteristic of spark engine fuels such as
gasoline. Octane number is a measure of a fuel’s tendency to
knock in a test engine compared to other fuels.

If the octane number of a blend is calculated by the linear addition


of an octane number for each component, the following equation
can be obtained:

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One correction method that uses the octane number index


has been reported by Riazi (2005). The following octane index
correlations depend on the octane number range as follows:

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Flash Point Blending


The flash point is the lowest temperature at which vapours arises
from oil ignites. It indicates the maximum temperature at which a
fuel can be stored without serious hazard. If the flash point of a
petroleum product does not meet the required specifications, it
can be adjusted by blending this product with other fractions.
The flash point of a blend is determined using the following
equation:

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where xvi is the volume fraction of component i, and BIFPi is the


flash point index of component i that can be determined from the
following correlation (Riazi, 2005):

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THANK YOU

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